CN1164520A - Pumice foam glass thermal insulation material - Google Patents
Pumice foam glass thermal insulation material Download PDFInfo
- Publication number
- CN1164520A CN1164520A CN 97104741 CN97104741A CN1164520A CN 1164520 A CN1164520 A CN 1164520A CN 97104741 CN97104741 CN 97104741 CN 97104741 A CN97104741 A CN 97104741A CN 1164520 A CN1164520 A CN 1164520A
- Authority
- CN
- China
- Prior art keywords
- pumice
- powder
- thermal insulation
- foam glass
- insulation material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/007—Foam glass, e.g. obtained by incorporating a blowing agent and heating
Abstract
The present invention uses pumice sand powder or volcanic ash (powder) as main raw material, and at the same time, adds flux 20-30% (of main raw material weight), modifier 3-9%, foaming agent 2-5% and stabilizer 1-3%, and makes them pass through such processes of roasting at 750 deg.C and natural cooling so as to obtain the invented pumice foamed glass isulating material with good heat-insulating property and high compression strength. Said invention possesses the advantages of easily available raw material, simple production process and low cost, etc..
Description
The present invention relates to a kind of foam glass thermal insulation material, be used for aspects such as building heat preservation, sound-absorbing, decoration and industrial heat preservation, cold insulation engineering.
It is raw material that present manufacturing multicellular glass is all used glass powder (water glass glass cullet), glass powder is resulting by industrial glass cullet and daily glass cullet, also the valuable mineral raw material is through secondary processing, through oven dry and pulverize, grind instead of part glass powder, make foam glass product after carrying out about high-temperature roasting (1000-1200 ℃) again after the shrend.The starting material source that produces this foam glass product is narrower, technology is more loaded down with trivial details, and production cost is than higher, and range of application is less, can only be applied to than on the special industry heat insulating work.And (2600-2800 unit/M costs an arm and a leg
3), to promote the use of restrictedly, turnout is low.Existing Production Flow Chart such as figure below of producing multicellular glass: (videing infra).
The objective of the invention is to propose a kind of natural mineral float stone lava that utilizes as raw material, particularly utilize pumice sand powder after the fragmentation of float stone lava as the material produce pumice foam glass of roasting pumice foam glass, it is simple that this pumice foam glass has production technique, with low cost, advantages such as the starting material source is abundant, solve the existing glass powder that utilizes and make the cost height that multicellular glass exists, complex process, problems such as starting material sources difficulty, this pumice foam glass can be widely used in industries such as the insulation, cold insulation of building, structures.
Major technique content of the present invention is, this pumice foam glass thermal insulation material is to be main raw material with pumice sand powder or volcanic ash (powder), 20～30% fusing assistants that add pumice sand powder or volcano ashes total amount simultaneously, 3-9% properties-correcting agent, the 2-5% whipping agent, the 1-3% stablizer, naturally cooling makes tabular or block after 850 ℃ of roastings.
The optimum weight ratio that adds fusing assistant, properties-correcting agent, whipping agent, stablizer is respectively 27%, 8%, 1.8%, 0.9% of pumice sand powder or a volcanic ash grain weight amount.
Whipping agent can adopt yellow soda ash, lime carbonate, magnesiumcarbonate etc., saltpetre, SODIUMNITRATE etc., and boric acid, borax, carbon black, silicon carbide, silicon oxide, water glass etc., properties-correcting agent is water glass, and stablizer is a sodium phosphate, and solubility promoter is feldspar, calcite, Bai Shi.
The composition scope of used pumice sand powder or volcanic ash (powder) is in the prescription of pumice foam glass thermal insulation material:
SiO
2：50～70％
Al
2O
3：12％～13％
Fe
2O
3：1.3％～4.5％
MnO：0.06％～0.15％
MgO：4.2％～7.4％
CaO：5.8％～7.0％
K
2O：4.3％～5.7％
Loss on ignition: 1.22%～2.25%
The technological process of production of this float stone cellular insulant is:
At first pumice sand powder or volcano ashes are added fusing assistant, dry back abrasive dust is the 80-110 order; Add properties-correcting agent, whipping agent, stablizer then and mix to stir with forced mixer or ball mill and stirred 2-4 hour, speed is 1250 rev/mins, and the compound after mixing becomes plastic; The inwall of packing into then scribbles in the heat resisting iron of releasing agent (kaolin, refractory mortar) or the mould that stainless steel plate is made detachable board-like unitized construction, carries out the roasting foaming; Roasting can be boiled and carries out in mixing gas furnace, oil oven, the gas furnace boil formula electric furnace or horse of horse, and the temperature difference is at 10-20 ℃ in the stove; Roasting is divided into heating, foaming, stable, annealing four-stage;
Heating phase should not be too fast, prevents that the blank internal-external temperature difference is excessive, but also should not be slow excessively, otherwise produce " dead temperature ", makes blank become the dead volume article.Heat-up rate is 6-8 ℃/minute, and environmental requirement is reduced into neutrality in the kiln, should not form well-oxygenated environment.
Blowing temperature is 750-850 ℃.650-750 ℃ is the stage of being rapidly heated, heat-up rate is 7-10 ℃/minute, because whipping agent is not just to decompose when blowing temperature or react, but part decomposition and reaction have been begun in lower temperature, therefore the unsuitable overstand of this temperature range, otherwise decompose or gas that reaction generates will be overflowed from the space of the base substrate that do not form glassy phase as yet, obtain the foam gas phase so seldom, capacity is big.Only be rapidly heated, whipping agent makes pumice sand also begin to form the glassy phase of conversion when producing a large amount of gas, and in this case, gas but wraps up and can not overflow for the pumice sand glassiness that transforms, and can obtain the little how close pumice foam glass in hole.When temperature is raised to blowing temperature, need constant temperature 45-60 minute, gas phase is fully produced, it is perfect to foam.
Steady stage is called quick cooling stages again, i.e. 850-620 ℃ of interval is with 15-20 ℃/minute speed of cooling, with the pumice foam glass cooling, its purpose is to make glassiness cooling curing, the foam stabilization of formation, between 620-400 ℃, cooling rate can be slow slightly, is generally 5-7 ℃/minute.
Annealing stage is very big to the intensity effect of pumice foam glass, because pumice foam glass is a porous material, heat conductivility is poor, so it is slow that annealing speed is wanted, temperature is between 400-260 ℃ the time, cooling rate is 0.7-1 ℃/minute, naturally cools to room temperature or refrigeration cooling below 260 ℃ in annealing furnace.
Therefore technique effect of the present invention is that this float stone glass heat-insulating material is attached most importance to pumice sand or volcano ashes and wanted raw material to make, and has material extensively to be easy to get, and cost is low, advantages of cheap price, but the constructing in the industry of widespread use construction industry and insulation, cold insulation.The processing method of producing float stone glass heat-insulating material in addition is simpler than the processing method of existing production foam glass thermal insulation material, manufactures easily.In addition, with the pumice foam glass thermal insulation material good heat insulating that this method is produced, ultimate compression strength height.Its performance is: unit weight 290～313kg/m
2, ultimate compression strength 2.5～3.5MPa (capacity 310～313kg/m
2), thermal conductivity 0.058～0.061W/mk (capacity 300～313kg/m
3), weight loss is 0%～1.5% behind 15 circulating freezing resistances, use temperature-200～+ 600 ℃.
The realization embodiments of the invention are:
1, adopt the waste material pumice sand powder (Kedong, Heilongjiang Province pumice sand) of natural pumice lava mineral, its composition is:
Al
2O
3：11.9％ SiO：50.45％
CaO：5.80％ Fe
2O
3：1.28％
Na
2O：3.24％ MgO：4.21％
Loss on ignition: 1.22% (above-mentioned all be weight percentage)
By 80 mesh sieves, other adds 27% fusing assistant, 8% properties-correcting agent, and 1.8% whipping agent, 0.9% stablizer were puddled 4 hours, and admixtion is contained in the fireproof die, and charge amount is 30% of a mould kiln amount.The mould of charged is sent in the kiln, be heated to 750 ℃ with 6 ℃/minute heat-up rates, be warmed up to 850 ℃ with 8 ℃/minute heat-up rate again, 850 ℃ of following constant temperature 40 minutes, cool to 620 ℃ with 15 ℃/minute speed of cooling then, drop to 400 ℃ with 5 ℃/minute speed of cooling again, anneal with 1 ℃/minute speed of cooling in 400～260 ℃ of intervals, in annealing furnace, naturally cool to room temperature, the demoulding at last.
Embodiment 2: adopt the composition of the waste material pumice sand powder of natural pumice lava mineral to be: (Changbai Mountain float stone)
Al
2O
3：8.90％ SiO
2：71.08％
CaO：2.77％ Fe
2O
3：3.17％
Na
2O：9.36％ MgO：0.93％
K
2O:3.78% loss on ignition: 2.25% (above-mentioned all be weight percentage)
By 110 mesh sieves, other adds 29% fusing assistant of pumice sand grain weight amount, and 8% properties-correcting agent, 2.5% whipping agent, 1.3% stablizer mix and stirred 3.5 hours, and in the fireproof mould of packing into then, charge amount is 25% of a mould unit weight.And mould sent in the kiln, with 750 ℃ of 6 ℃/minute heat-up rate heating, again with 8 ℃/minute heat-up rate, be warmed up to 850 ℃, cool to 620 ℃ with 15 ℃/minute speed of cooling then 850 ℃ of following constant temperature 30 minutes, drop to 400 ℃ with 5 ℃/minute speed of cooling again, anneal with 1 ℃/minute speed of cooling in 400～260 ℃ of intervals, in annealing furnace, naturally cool to room temperature, the demoulding at last.
The pumice foam glass thermal insulation material that adopts above-mentioned compounding method to obtain, its performance is: unit weight 320～450kg/m
2, ultimate compression strength 3～4MPa, folding strength 0.96～1.5MPa, thermal conductivity 0.060～0.063W/mk, water-intake rate are＜5～＜6% (24 hours volume water absorption rates), 15 circulating freezing resistances qualified (the weight loss index is 1.5～2%).Use temperature is-200～+ 600 ℃.
Claims (5)
1, a kind of pumice foam glass thermal insulation material, it is characterized in that this foam glass thermal insulation material is is main raw material with pumice sand powder or volcanic ash (powder), 20～30% the fusing assistant that adds pumice sand powder or volcanic ash grain weight amount simultaneously, the properties-correcting agent of 3-9%, the 2-5% whipping agent, the 1-3% stablizer, naturally cooling makes tabular or block after 750 ℃～850 ℃ roastings.
According to the described pumice foam glass thermal insulation material of claim 1, it is characterized in that 2, the optimum weight ratio that is incorporated in fusing assistant, properties-correcting agent, whipping agent, stablizer is respectively 27%, 8%, 1.8%, 0.9% of pumice sand powder or volcanic ash (powder) weight.
3, according to the described pumice foam glass thermal insulation material of claim 1, it is characterized in that whipping agent can adopt yellow soda ash, lime carbonate, magnesiumcarbonate etc., saltpetre, SODIUMNITRATE etc., boric acid, borax, carbon black, silicon carbide, silicon oxide, water glass etc., fusing assistant feldspar, calcite, Bai Shi, properties-correcting agent is water glass, the stablizer sodium phosphate.
4,, it is characterized in that the composition scope of pumice sand powder or volcanic ash (powder) is SiO according to the described pumice foam glass thermal insulation material of claim 1
2: 50～70%, Al
2O
3: 12%～13%, Fe
2O
3: 1.3%～4.5%, MnO:0.06%～0.15%, MgO:4.2%～7.4%, CaO:5.8%～7.0%, K
2O:4.3%～5.7%, loss on ignition 1.22%～2.25%.
5, the production technique of the described pumice foam glass thermal insulation material of claim 1 is: at first pumice sand powder or volcanic ash (powder) are added fusing assistant, dry back abrasive dust is the 80-110 order; Add properties-correcting agent, whipping agent, stablizer then and mix to stir with forced stirrer or ball mill and stirred 2-4 hour, speed is 1250 rev/mins, and the compound after mixing becomes plastic; The inwall of packing into then scribbles the heat resisting iron or the stainless steel plate of releasing agent (kaolin, refractory mortar) and makes in the mould of the board-like unitized construction of detachable bar, carries out the roasting foaming; Roasting can be boiled and carries out in mixing gas furnace, oil oven, the gas furnace boil formula electric furnace or horse of horse, and the temperature difference is at 10-20 ℃ in the stove; Roasting is divided into heating, foaming, stable, annealing four-stage; The heating phase heat-up rate is 6-8 ℃/minute, and environmental requirement is reduced into neutrality in the kiln, should not form well-oxygenated environment; The foaming stages temperature is 750-850 ℃, and the 650-750 ℃ of stage heat-up rate that is rapidly heated is 7-10 ℃/minute, reaches behind the blowing temperature constant temperature 45-60 minute; Steady stage is called quick cooling stages again, 850-620 ℃ of interval, and with 15-20 ℃/minute speed of cooling cooling, between 620-400 ℃, cooling rate is 5-7 ℃/minute; It is slow that the annealing stage annealing speed is wanted, temperature between 400-260 ℃ the time cooling rate be 0.7-1 ℃/minute, in annealing furnace, naturally cool to room temperature or refrigeration cooling below 260 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97104741A CN1076329C (en) | 1997-03-28 | 1997-03-28 | Pumice foam glass thermal insulation material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97104741A CN1076329C (en) | 1997-03-28 | 1997-03-28 | Pumice foam glass thermal insulation material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1164520A true CN1164520A (en) | 1997-11-12 |
| CN1076329C CN1076329C (en) | 2001-12-19 |
Family
ID=5167473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97104741A Expired - Lifetime CN1076329C (en) | 1997-03-28 | 1997-03-28 | Pumice foam glass thermal insulation material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1076329C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102633484A (en) * | 2012-03-31 | 2012-08-15 | 广东龙湖科技股份有限公司 | Glass bead with honeycomb holes and tile glue with glass bead |
| CN102643013A (en) * | 2012-04-28 | 2012-08-22 | 浙江德和绝热科技有限公司 | Method of using waste glass fiber reinforced phenolic resin molding compound to produce foam glass |
| CN103086587A (en) * | 2013-02-22 | 2013-05-08 | 石河子大学 | Preparation method of expanded vermiculite foam glass insulating material |
| CN105392753A (en) * | 2013-04-24 | 2016-03-09 | 知识产权古里亚有限责任公司 | Expanded lightweight aggregate made from glass or pumice |
| CN105645773A (en) * | 2016-01-20 | 2016-06-08 | 广西丛欣实业有限公司 | Method for preparing high temperature resisting foam glass |
| CN105669038A (en) * | 2016-01-20 | 2016-06-15 | 广西丛欣实业有限公司 | High-temperature-resistant foam glass |
| CN107253824A (en) * | 2017-04-28 | 2017-10-17 | 青岛高智高新科技有限公司 | A kind of foam glass structure and its manufacture method |
| CN108083698A (en) * | 2017-11-29 | 2018-05-29 | 天津中材工程研究中心有限公司 | A kind of inorganic non-metallic solid buoyant material of low-density grade and preparation method thereof |
| CN108640527A (en) * | 2018-08-02 | 2018-10-12 | 巩义市欧洁源环保技术服务有限公司 | It is a kind of to open pass crystallite foam glass sound absorption acoustic material and preparation method thereof more |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86103874A (en) * | 1986-05-29 | 1987-03-25 | 金昌松 | A kind of inorganic heat insulation material and manufacture method thereof |
| CN87101962A (en) * | 1987-03-13 | 1988-03-30 | 四川省涪陵地区垫江县三峡节能产品厂 | Composite silicate heat insulation material and method for making |
| CN1037698A (en) * | 1988-10-09 | 1989-12-06 | 哈尔滨现代应用化学研究所 | Inorganic cellular insulant |
| CN1095698A (en) * | 1993-05-27 | 1994-11-30 | 鞍山市特种保温材料厂 | Flyash, pearlstone system lagging material |
-
1997
- 1997-03-28 CN CN97104741A patent/CN1076329C/en not_active Expired - Lifetime
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102633484A (en) * | 2012-03-31 | 2012-08-15 | 广东龙湖科技股份有限公司 | Glass bead with honeycomb holes and tile glue with glass bead |
| CN102633484B (en) * | 2012-03-31 | 2013-07-31 | 广东龙湖科技股份有限公司 | Glass bead with honeycomb holes and tile glue with glass bead |
| CN102643013A (en) * | 2012-04-28 | 2012-08-22 | 浙江德和绝热科技有限公司 | Method of using waste glass fiber reinforced phenolic resin molding compound to produce foam glass |
| CN103086587A (en) * | 2013-02-22 | 2013-05-08 | 石河子大学 | Preparation method of expanded vermiculite foam glass insulating material |
| CN103086587B (en) * | 2013-02-22 | 2015-12-02 | 石河子大学 | The preparation method of expanded vermiculite foam glass thermal insulation material |
| CN105392753A (en) * | 2013-04-24 | 2016-03-09 | 知识产权古里亚有限责任公司 | Expanded lightweight aggregate made from glass or pumice |
| CN105645773A (en) * | 2016-01-20 | 2016-06-08 | 广西丛欣实业有限公司 | Method for preparing high temperature resisting foam glass |
| CN105669038A (en) * | 2016-01-20 | 2016-06-15 | 广西丛欣实业有限公司 | High-temperature-resistant foam glass |
| CN107253824A (en) * | 2017-04-28 | 2017-10-17 | 青岛高智高新科技有限公司 | A kind of foam glass structure and its manufacture method |
| CN108083698A (en) * | 2017-11-29 | 2018-05-29 | 天津中材工程研究中心有限公司 | A kind of inorganic non-metallic solid buoyant material of low-density grade and preparation method thereof |
| CN108640527A (en) * | 2018-08-02 | 2018-10-12 | 巩义市欧洁源环保技术服务有限公司 | It is a kind of to open pass crystallite foam glass sound absorption acoustic material and preparation method thereof more |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1076329C (en) | 2001-12-19 |
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Granted publication date: 20011219 |
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