CN108662897A - A kind of folded burning system of the tunnel oven of foamed ceramic light weight board - Google Patents

A kind of folded burning system of the tunnel oven of foamed ceramic light weight board Download PDF

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Publication number
CN108662897A
CN108662897A CN201810688689.XA CN201810688689A CN108662897A CN 108662897 A CN108662897 A CN 108662897A CN 201810688689 A CN201810688689 A CN 201810688689A CN 108662897 A CN108662897 A CN 108662897A
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China
Prior art keywords
unit
coaming plate
backing plate
light weight
foamed ceramic
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CN201810688689.XA
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Chinese (zh)
Inventor
林�智
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Keda Clean Energy Co Ltd
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Keda Clean Energy Co Ltd
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Priority to CN201810688689.XA priority Critical patent/CN108662897A/en
Publication of CN108662897A publication Critical patent/CN108662897A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/14Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment
    • F27B9/20Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path tunnel furnace
    • F27B9/26Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path tunnel furnace on or in trucks, sleds, or containers
    • F27B9/262Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path tunnel furnace on or in trucks, sleds, or containers on or in trucks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories, or equipment peculiar to furnaces of these types
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories, or equipment peculiar to furnaces of these types
    • F27B9/38Arrangements of devices for charging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories, or equipment peculiar to furnaces of these types
    • F27B9/39Arrangements of devices for discharging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D5/00Supports, screens, or the like for the charge within the furnace
    • F27D5/0031Treatment baskets for ceramic articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories, or equipment peculiar to furnaces of these types
    • F27B2009/305Particular conformation of the furnace
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories, or equipment peculiar to furnaces of these types
    • F27B9/38Arrangements of devices for charging
    • F27B2009/382Charging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/30Details, accessories, or equipment peculiar to furnaces of these types
    • F27B9/38Arrangements of devices for charging
    • F27B2009/384Discharging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27MINDEXING SCHEME RELATING TO ASPECTS OF THE CHARGES OR FURNACES, KILNS, OVENS OR RETORTS
    • F27M2001/00Composition, conformation or state of the charge
    • F27M2001/03Charges containing minerals
    • F27M2001/035China
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)

Abstract

The invention discloses a kind of tunnel ovens of foamed ceramic light weight board to fold burning system, including feeding line, tunnel oven and lower stockline, wherein, the kiln car includes holder, the holder is equipped at least two layers of saggar, every layer of saggar includes backing plate, coaming plate and high temperature resistant paper, and the coaming plate rides upon the surrounding of backing plate, and the high temperature resistant paper is equipped on the backing plate and coaming plate;The feeding line includes at least two feeding unit materials, the feeding unit material includes the cleaning unit for clearing up backing plate, coaming plate, for consolidation or set up the backing plate consolidation unit of backing plate, the first laying unit for being laid with high temperature resistant paper on backing plate, coaming plate for setting up coaming plate on backing plate sets up unit, the second laying unit for being laid with high temperature resistant paper on coaming plate carries out the cloth material unit of cloth in saggar.Using the present invention, realize that multi-laminate is burnt, high degree of automation, production efficiency is high, saves cost and space.

Description

A kind of folded burning system of the tunnel oven of foamed ceramic light weight board
Technical field
The present invention relates to folded burn of ceramic wafer technical field more particularly to a kind of tunnel oven of foamed ceramic light weight board to be System.
Background technology
Basis material used in foamed ceramic comes from ceramics factory's waste material and industrial waste the like waste, and (ceramic polishing is useless Slag or cinder or stone material waste residue etc.), if these wastes are not handled, arbitrarily accumulation or landfill will pollute the environment, Waste resource.
The foamed ceramic product is light-weight with its, intensity is high, fire prevention, antidetonation, heat-insulated, sound insulation, strong modularity, is easy to remove Fortune, it is widely applicable the advantages that gradually start to use in China.Again because its raw material is cinder, ceramic polishing waste residue, slag Etc. solid waste, in terms of resource makes full use of with environmental protection have positive social effect.
The formula system of existing foamed ceramic generally comprises ceramic polishing waste residue and foaming agent, ceramic polishing waste residue dosage compared with It is few, it is mostly 50% or so.For foaming agent addition 1.2% or so, addition is more, and cost is higher.Because of existing hair Bubble brick entirety brick is thicker, and the formula system of the more difficult oxidation of formula system, foamed ceramic determines that it must use tunnel oven Firing, the firing period of tunnel oven are generally 24-26 hours, and firing period is long, and temperature is higher.
Moreover, as shown in Figure 1, foamed ceramic plate made from the prior art, internal to form multilayer stomata.In the mistake of foaming Cheng Zhong, since foamed time is longer, and it is affected by gravity, lower layer's stomata can be crushed so that the whole uniformity of product It is bad.
In addition, existing tunnel oven firing is all that single layer is burnt in a heap, and it is basic to be manually operated, a large amount of manpower is needed, efficiency is low, It is of high cost.
Invention content
Technical problem to be solved by the present invention lies in providing a kind of folded burn of tunnel oven of foamed ceramic light weight board is System realizes that multi-laminate is burnt, and high degree of automation, production efficiency is high, saves cost and space.
The technical problems to be solved by the invention also reside in, and provide a kind of folded burn of tunnel oven of foamed ceramic light weight board and are System realizes low temperature fast firing, and the foamed ceramic light weight board being fired into is on same section, stomata indifference from top to bottom, Bubble uniformity is high.
In order to solve the above technical problem, the present invention provides a kind of folded burn of tunnel oven of foamed ceramic light weight board to be System, including:Feeding line, for raw material to be carried out cloth on kiln car;Tunnel oven, for by foamed ceramic light weight board green body into Row firing;And lower stockline, for foamed ceramic light weight board to be unloaded;
Wherein, the kiln car includes holder, and the holder is equipped at least two layers of saggar, and every layer of saggar includes backing plate, encloses Plate and high temperature resistant paper, the coaming plate ride upon the surrounding of backing plate, and the high temperature resistant paper is equipped on the backing plate and coaming plate;
The feeding line includes:At least two feeding unit materials for installing saggar and cloth;
The feeding unit material includes:
Cleaning unit for clearing up backing plate, coaming plate;
For consolidation or set up the backing plate consolidation unit of backing plate;
The first laying unit for being laid with high temperature resistant paper on backing plate;
Coaming plate for setting up coaming plate on backing plate sets up unit;
The second laying unit for being laid with high temperature resistant paper on coaming plate;
The cloth material unit of cloth is carried out in saggar.
As the improvement of said program, the holder is equipped at least three layers of saggar, and the feeding line includes at least three Installation unit;
Green body in saggar carries out multi-laminate burning in tunnel oven, to form foamed ceramic light weight board.
As the improvement of said program, the lower stockline includes at least two lower material list for dismantling saggar and blanking Member:
The blanking unit includes;
The first unloading unit for unloading coaming plate;
The second unloading unit for unloading foamed ceramic light weight board;
Third unloading unit for downloading backing plate.
As the improvement of said program, first laying unit includes shop fixtures tissue machine, and the coaming plate sets up unit packet Manipulator is included, second laying unit includes paving side tissue machine;
First laying unit, coaming plate set up unit and the second laying unit is sequentially connected;
The coaming plate is set up unit and is correspondingly arranged with the first unloading unit, and the manipulator unloads the first unloading unit Coaming plate is transplanted on coaming plate and sets up unit.
As the improvement of said program, first laying unit, coaming plate set up unit and the second laying unit is additionally provided with Consolidation machine, the consolidation machine include elevation and subsidence mechanical arm and clap neat component, and the neat component of bat to backing plate and coaming plate clap returns together It is whole.
As the improvement of said program, the cleaning unit be descaling machine, the descaling machine include hairbrush, driving mechanism and Vacuum cleaner system, the driving mechanism driving hairbrush roll.
As the improvement of said program, the backing plate is mullite backing plate, silicon carbide backing plate or cordierite backing plate;
The coaming plate is mullite coaming plate, silicon carbide coaming plate or cordierite coaming plate;
The high temperature resistant paper is aluminum silicate fiber paper.
As the improvement of said program, the foamed ceramic light weight board is mainly by the raw material system of following weight percentage At:
Ceramic polishing waste residue 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1- 4%.
As the improvement of said program, the foamed ceramic light weight board is mainly by the raw material system of following weight percentage At:
Ceramic polishing waste residue 75-95%, clay 0.1-10%, feldspar 0.1-20%, foaming agent 0.1-0.4%, stabilizer 0.1-3%.
As the improvement of said program, the clay is one or more in black mud, kaolin, municipal sludge, ooze;
The foaming agent is silicon carbide or grinding head for polishing reclaimed materials, and the main component of the grinding head for polishing reclaimed materials includes carbon SiClx and resin.
Implement the present invention, has the advantages that:
One, the tunnel oven of foamed ceramic light weight board of the present invention folds burning system, including feeding line, tunnel oven and lower stockline, Wherein, kiln car is equipped at least two layers of saggar, and the green body in saggar carries out multi-laminate burning in tunnel oven, realizes low temperature fast firing, The oxidation reaction phases-time for greatly reducing formula can also grill thoroughly ceramic wafer, improve even if shortening firing period Yield reduces the energy consumption of unit product.Moreover, green body will not be influenced by multiple-layer stacked, it can also be in low temperature, short time It inside grills thoroughly, ensures product quality, substantially increase production efficiency, and the space of tunnel oven can be reduced.
Two, feeding line and lower stockline of the invention are equipped with feeding unit material and blanking unit for each layer of saggar, each A feeding unit material include cleaning unit, backing plate consolidation unit, the first laying unit, coaming plate set up unit, the second laying unit and Cloth material unit, each blanking unit include the first unloading unit, the second unloading unit, third unloading unit, feeding unit material and Blanking unit is correspondingly arranged, and with steady ordered can carry out feeding and blanking successively, it is possible to reduce manual labor power is realized complete Automated production greatly improves production efficiency.
Three, the coaming plate of feeding line sets up unit and the first unloading unit of lower stockline is correspondingly arranged, and manipulator is unloaded first The coaming plate of carrier unit unloading is transplanted on coaming plate and sets up unit, reduces the displacement distance between feeding, blanking, is conveniently operated so that The layout of production line is more reasonable, reduces production space.
Four, the raw material of the foamed ceramic light weight board includes ceramic polishing waste residue 70-96%, foaming agent 0.01- 0.6%, stabilizer 0.1-4%, which increase the addition of ceramic polishing waste residue, the addition of ceramic polishing waste residue reaches as high as 96%, while the addition of foaming agent being reduced to 0.01-0.6%.On the basis of this, the manganese dioxide that 0.1-4% is added is steady Determine agent, the uniformity of bubble can be improved, even if in same section, stomata indifference from top to bottom so that the entirety of product Uniformity is good.
Finally, pass through foamed ceramic light weight board good quality, pressure resistance made from above-mentioned folded burning system and folded firing method Degree >=4.5Mpa, bulk density:200-1100Kg/m3, thermal coefficient:≤ 0.15W/m DEG C, combustion rating:A1 grades, water absorption rate: < 2%, radioactive indicator:IRa≤ 1.0, Ir≤1.0。
Description of the drawings
Fig. 1 is the sectional view of prior art foamed ceramic light weight board;
Fig. 2 is that the tunnel oven of foamed ceramic light weight board of the present invention folds the schematic diagram of burning system;
Fig. 3 is the partial enlarged view in the portions A in Fig. 2;
Fig. 4 is the partial enlarged view in the portions B in Fig. 2;
Fig. 5 is the partial enlarged view in the portions C in Fig. 2;
Fig. 6 is the front view of kiln car of the present invention;
Fig. 7 is the left view of kiln car of the present invention;
Fig. 8 is the vertical view of kiln car of the present invention.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made into one below in conjunction with attached drawing Step ground detailed description.
Referring to Fig. 2, the present invention provides a kind of folded burning system of the tunnel oven of foamed ceramic light weight board, including:For will be former Material carries out cloth on kiln car 4, to form the feeding line 1 of green body;For green body to be burnt into, to form foamed ceramic lightweight The tunnel oven 2 of plank;And the lower stockline 3 for unloading foamed ceramic light weight board.
Referring to Fig. 6-8, the kiln car 4 includes holder 41, and the holder 41 is equipped at least two layers of saggar 42, every layer of saggar 42 include backing plate 43, coaming plate 44 and high temperature resistant paper 45, and the coaming plate 44 rides upon the surrounding of backing plate 43, the backing plate 43 and coaming plate The high temperature resistant paper 45 is equipped on 44.
Preferably, the holder 41 is equipped at least three layers of saggar 42, and the green body in saggar 42 carries out more in tunnel oven 2 Stacking is burnt, to form foamed ceramic light weight board.The present invention uses tunnel oven multi-laminate firing method, realizes low temperature fast firing, significantly The oxidation reaction phases-time for reducing formula can also grill thoroughly ceramic wafer even if shortening firing period, improve production Amount, reduces the energy consumption of unit product.Moreover, the present invention uses the method that multi-laminate is burnt, green body will not be by multiple-layer stacked It influences, can also ensure product quality, substantially increase production efficiency, and tunnel can be reduced in low temperature, grill thoroughly in the short time The space of kiln.
It should be noted that the number of plies of the saggar 42 of above-mentioned kiln car can be set according to actual conditions, such as 4, 5,6,7,8,9,10 layers, embodiments thereof is not limited to illustrated embodiment of the present invention.
The backing plate 43 is preferably mullite backing plate, silicon carbide backing plate or cordierite backing plate, has coefficient of thermal expansion small, heat The advantages that shake stability is good, itself is unlikely to deform and cracks, and service life is long.
The coaming plate 44 is preferably mullite coaming plate, silicon carbide coaming plate or cordierite coaming plate, has coefficient of thermal expansion small, heat The advantages that shake stability is good, itself is unlikely to deform and cracks, and service life is long.
The high temperature resistant paper 45 refers to the paper that can be subjected to 1220 DEG C of high temperature, preferably aluminum silicate fiber paper, aluminium silicate fiber Dimension paper is made of primary raw material of wet therapy forming process of metal and stone alumina-silicate ceramic fibre cotton, has ideal under high temperature environment Heat-insulated, heat preservation, sealing, electrical isolation, sound-absorbing, strainability.Its thermal capacity is low, thermal conductivity is low, electrical insulation capability is excellent, mechanical Processing performance is excellent, intensity is high, it is anti-tear pull, flexibility it is high.
The feeding line 1 includes:At least two feeding unit material 11 for installing saggar and cloth, wherein on each Material unit 11 includes:
Cleaning unit 111 for clearing up backing plate, coaming plate;
For consolidation or set up the backing plate consolidation unit 112 of backing plate;
The first laying unit 113 for being laid with high temperature resistant paper on backing plate;
Coaming plate for setting up coaming plate on backing plate sets up unit 114;
The second laying unit 115 for being laid with high temperature resistant paper on coaming plate;
The cloth material unit 116 of cloth is carried out in saggar.
The lower stockline 3 includes at least two blanking unit 31 for dismantling saggar and blanking, wherein each blanking Unit 31 includes:
The first unloading unit 311 for unloading coaming plate;
The second unloading unit 312 for unloading foamed ceramic light weight board;
Third unloading unit 313 for downloading backing plate.
Specifically, the cleaning unit 111 is descaling machine, the descaling machine includes hairbrush, driving mechanism and vacuum cleaning System, the driving mechanism driving hairbrush roll.The present invention is by driving the hairbrush rolled and vacuum cleaner system to backing plate, enclosing Plate surface carries out cleaning collection.
First laying unit 113 includes shop fixtures tissue machine, and it includes manipulator 117, institute that the coaming plate, which sets up unit 114, It includes paving side tissue machine to state the second laying unit 115, and first laying unit 113, coaming plate set up the laying of unit 114 and second Unit 115 is sequentially connected, the place for carrying out being laid with high temperature resistant paper, upper coaming plate successively on backing plate, being laid on coaming plate high temperature resistant paper Reason.
The coaming plate is set up unit 114 and is correspondingly arranged with the first unloading unit 311, and the manipulator 117 is unloaded first The coaming plate of unit unloading 311 is transplanted on coaming plate and sets up in the respective layer of unit 114, reduces the displacement distance between feeding, blanking, It is conveniently operated so that the layout of production line is more reasonable, reduces production space.
First laying unit 113, coaming plate set up unit 114 and the second laying unit 115 is additionally provided with consolidation machine, described Consolidation machine includes elevation and subsidence mechanical arm and claps neat component, claps neat component and is set with the neat gas of bat by the appearance and size surrounding of backing plate, coaming plate Cylinder, to after clapping neat station, elevation and subsidence mechanical arm drives to clap neat component and drop to designated position and to boron plate surrounding clap returns kiln car together It is whole, it claps and finishes the neat component rise of elevator drive bat together, kiln car walking goes to next station.
It should be noted that the present invention clears up the descaling machine that unit 111 is selected, commercially available descaling machine is selected;And first The paving side tissue machine that the shop fixtures tissue machine and the second laying unit 115 that laying unit 113 is selected are selected, selects commercially available paper paving machine .
In conjunction with Fig. 2, workflow of the invention is as follows:
One, into feeding line 1, including the feeding unit material 11A of installing bottom layer saggar is carried out, the feed material list of middle level saggar is installed The feeding unit material 11C of first 11B and installation upper layer saggar.
Referring to Fig. 3, passes sequentially through cleaning unit 111 and clear up backing plate and coaming plate, by 112 consolidation pad of backing plate consolidation unit Plate is laid with high temperature resistant paper on backing plate by the first laying unit 113, unit 114 is set up by coaming plate carries out upper coaming plate, passes through Second laying unit 115 is laid with high temperature resistant paper, by 116 cloth of cloth material unit on coaming plate, forms bottom saggar;
It referring to Fig. 4, passes sequentially through backing plate consolidation unit 112 and is laid with backing plate, backing plate coaming plate is cleared up by clearing up unit 111, By 112 consolidation backing plate of backing plate consolidation unit, high temperature resistant paper is laid on backing plate by the first laying unit 113, passes through coaming plate Unit 114 is set up to carry out coaming plate, be laid on coaming plate high temperature resistant paper by the second laying unit 115, by cloth material unit 116 Cloth forms middle level saggar;
It referring to Fig. 5, passes sequentially through backing plate consolidation unit 112 and is laid with backing plate, backing plate coaming plate is cleared up by clearing up unit 111, By 112 consolidation backing plate of backing plate consolidation unit, high temperature resistant paper is laid on backing plate by the first laying unit 113, passes through coaming plate Unit 114 is set up to carry out coaming plate, be laid on coaming plate high temperature resistant paper by the second laying unit 115, by cloth material unit 116 Cloth forms upper layer saggar;
4, the kiln car for being paved with material is finally sent to kiln by supply unit.
Two, the kiln car for being paved with material is burnt into tunnel oven 2, and foamed ceramic light weight board finished product is obtained after firing.
Three, kiln car is after the kiln tail of tunnel oven 2 comes out, and into lower stockline 3, including carries out the lower material list of unloading upper layer saggar First 31A unloads the blanking unit 31C of the blanking unit 31B and unloading bottom saggar of middle level saggar.
It referring to Fig. 5, passes sequentially through the first unloading unit 311 and unloads coaming plate, it is light to unload foamed ceramic by the second unloading unit 312 Lumber downloads backing plate, to dismantle upper layer saggar by third unloading unit 313;
Then, it referring to Fig. 4, passes sequentially through the first unloading unit 311 and unloads coaming plate, foaming is unloaded by the second unloading unit 312 Ceramic light weight board downloads backing plate, to dismantle middle level saggar by third unloading unit 313;
Finally, it referring to Fig. 3, passes sequentially through the first unloading unit 311 and unloads coaming plate, foaming is unloaded by the second unloading unit 312 Ceramic light weight board, to dismantle bottom saggar, 3 end of operation of lower stockline.
With this circulating repetition.
Further, the foamed ceramic light weight board is mainly made of the raw material of following weight percentage:Ceramic polishing is useless Slag 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1-4%.
Preferably, the foamed ceramic light weight board is mainly made of the raw material of following weight percentage:Ceramic polishing is useless Slag 75-95%, clay 0.1-10%, feldspar 0.1-20%, foaming agent 0.1-0.4%, stabilizer 0.1-3%.
Invention increases the additions of ceramic polishing waste residue, while reducing the addition of foaming agent.On the basis of this, add The manganese dioxide stabilizer for entering 0.1-4%, can improve the uniformity of bubble, even if in same section, stomata from top to bottom Indifference so that the whole uniformity of product is good.The stomata of foamed ceramic light weight board entirety section is circular hole, and on to Under pore size it is almost the same, the uniform pore diameter of firing is good.
Manganese dioxide is amphoteric oxide, it is a kind of black powder solid highly stable under room temperature.Meet reducing agent When, oxidisability is shown as, when meeting strong oxidizer, shows as reproducibility.The prior art usually using manganese dioxide as oxidant or Catalyst uses.The present invention is used manganese dioxide as bubble stabilizer, manganese dioxide can by with after the reacting of formula, So that the wall of stomata is toughened up, while keeping the uniformity of formula more preferable, even if indifference if same section hole from top to bottom It is different, it avoids stomata from being crushed, improves the uniformity of bubble, the whole uniformity of product is good.
The foaming agent is silicon carbide or grinding head for polishing reclaimed materials, and the main component of the grinding head for polishing reclaimed materials includes carbon SiClx and resin.Silicon carbide is a kind of expanded material, and the presence of the material makes it in sintering procedure unlike conventional ceramic It shrinks, is expansion instead, to make high-strength light ceramic wafer for building more hold than traditional ceramics plate in size and thickness It is easy to do to big and thick.Grinding head for polishing reclaimed materials is added as substrate raw material, is because grinding head for polishing ingredient itself is exactly silicon carbide And resin, and silicon carbide is exactly the foaming agent added in inventive formulation, so the present invention can subtract the addition of foaming agent As little as 0.01-0.6% reduces the dosage of foaming agent, reduces cost.
Meanwhile the ceramic polishing waste residue of 70-96% is introduced in formula, environment-protective circulating utilization is not only improved, it is also possible that It is internal after the sintering of foamed ceramic light weight board that there is firm similar cellular pore space structure, have environmentally protective, light, square Just it constructs, mitigate the advantages that building load.The addition of ceramic polishing waste residue of the present invention is far longer than existing foamed ceramic plate, Cost is reduced, the recycling to solid waste is reinforced.
The clay is one or more in black mud, kaolin, municipal sludge, ooze.Clay is added in raw material of the present invention And feldspar, silicon, aluminium, potassium, the sodium ingredient ratio in Base Formula can be adjusted, keeps foaming brick wall harder, intensity higher, and further Waste solids are recycled.
The present invention uses tunnel oven multi-laminate firing method, wherein the process for calcining includes:
(1) it is warming up to T1, T1It it is 800-900 DEG C, and in T10-30min is kept the temperature, wherein, the liter for being warming up to 400 DEG C by 0 DEG C Warm rate is 10-20 DEG C/min, and T is warming up to by 400 DEG C1Heating rate be 1-8 DEG C/min;
(2) it is warming up to T2, T2It is 1150-1220 DEG C, and 0-60min is kept the temperature in the highest temperature, wherein by T1It is warming up to T2's Heating rate is 1-8 DEG C/min;
(3) slow cooling, by T2The rate of temperature fall for being cooled to 600 DEG C is 3-9 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall is 1-4 DEG C/min.
Preferably, the process for calcining includes:
(1) it is warming up to 800-900 DEG C, and keeps the temperature 0-30min at 800-900 DEG C, wherein the liter for being warming up to 400 DEG C by 0 DEG C Warm rate is 15 DEG C/min, and the heating rate for being warming up to 800 DEG C by 400 DEG C is 5 DEG C/min;
(2) it is warming up to 1150-1220 DEG C, and 0-60min is kept the temperature in the highest temperature, wherein is warming up to 1150 DEG C by 800 DEG C Heating rate is 5 DEG C/min;
(3) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1150 DEG C are 6 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall be 2 DEG C/min.
Foamed ceramic light weight board obtained by the present invention is done into technology detection, it is as a result as follows:
Project The present invention
Compression strength ≥4.5Mpa
Bulk density 200-1100Kg/m3
Thermal coefficient ≤0.15W/m℃
Combustion rating A1 grades
Water absorption rate < 2%
Radioactive indicator IRa≤ 1.0, Ir≤1.0
Therefore, the present invention is on the basis of solving foamed ceramic light weight board internal porosity, it is ensured that it has good Compression strength, and heat insulation effect is good, good flame resistance, and radioactive indicator is low.
With specific embodiment, the present invention is further explained below
Embodiment 1
(1) it is formulated:Ceramic polishing waste residue 95.5%, foaming agent 0.5%, manganese dioxide stabilizer 4%.
(2) preparation method:
By raw material batch mixing according to the ratio, and through ball milling, obtain powder;
Powder is subjected to cloth by feeding line on kiln car, then carries out kiln car push-in tunnel oven at three stacking burnings Reason, obtains foamed ceramic light weight board, wherein process for calcining is as follows:(a) 800 DEG C are warming up to, and keeps the temperature 20min at 800 DEG C, Wherein, the heating rate for being warming up to 400 DEG C by 0 DEG C be 10 DEG C/min, the heating rate for being warming up to 800 DEG C by 400 DEG C be 3 DEG C/ min;(b) 1150 DEG C are warming up to, and 40min is kept the temperature in the highest temperature, wherein the heating rate for being warming up to 1150 DEG C by 800 DEG C is 3 ℃/min;(c) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1150 DEG C are 3 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall is 1 DEG C/min;
Foamed ceramic light weight board is unloaded finally by lower stockline.
Embodiment 2
(1) it is formulated:Ceramic polishing waste residue 90%, clay 1%, feldspar 8.8%, foaming agent 0.1%, stabilizer 0.1%.
(2) preparation method:
By raw material batch mixing according to the ratio, and through ball milling, obtain powder;
Powder is subjected to cloth by feeding line on kiln car, then carries out kiln car push-in tunnel oven at three stacking burnings Reason, obtains foamed ceramic light weight board, wherein process for calcining is as follows:(a) 820 DEG C are warming up to, and keeps the temperature 15min at 820 DEG C, Wherein, the heating rate for being warming up to 400 DEG C by 0 DEG C be 15 DEG C/min, the heating rate for being warming up to 820 DEG C by 400 DEG C be 5 DEG C/ min;(b) 1170 DEG C are warming up to, and 30min is kept the temperature in the highest temperature, wherein the heating rate for being warming up to 1170 DEG C by 820 DEG C is 4 ℃/min;(c) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1170 DEG C are 4 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall is 2 DEG C/min;
Foamed ceramic light weight board is unloaded finally by lower stockline.
Embodiment 3
(1) it is formulated:Ceramic polishing waste residue 92%, clay 5%, feldspar 2%, foaming agent 0.2%, stabilizer 0.8%.
(2) preparation method:
By raw material batch mixing according to the ratio, and through ball milling, obtain powder;
Powder is subjected to cloth by feeding line on kiln car, then carries out kiln car push-in tunnel oven at three stacking burnings Reason, obtains foamed ceramic light weight board, wherein process for calcining is as follows:(a) 830 DEG C are warming up to, and keeps the temperature 25min at 830 DEG C, Wherein, the heating rate for being warming up to 400 DEG C by 0 DEG C be 15 DEG C/min, the heating rate for being warming up to 830 DEG C by 400 DEG C be 5 DEG C/ min;(b) 1180 DEG C are warming up to, and 0-60min is kept the temperature in the highest temperature, wherein the heating rate for being warming up to 1180 DEG C by 830 DEG C For 5 DEG C/min;(c) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1180 DEG C are 5 DEG C/min, and 50 are cooled to by 600 DEG C DEG C rate of temperature fall be 2 DEG C/min;
Foamed ceramic light weight board is unloaded finally by lower stockline.
Embodiment 4
(1) it is formulated:Ceramic polishing waste residue 88%, clay 2%, feldspar 8%, foaming agent 0.1%, stabilizer 1.9%.
(2) preparation method:
Powder is subjected to cloth by feeding line on kiln car, then carries out kiln car push-in tunnel oven at three stacking burnings Reason, obtains foamed ceramic light weight board, wherein process for calcining is as follows:(a) 850 DEG C are warming up to, and keeps the temperature 30min at 850 DEG C, Wherein, the heating rate for being warming up to 400 DEG C by 0 DEG C be 16 DEG C/min, the heating rate for being warming up to 850 DEG C by 400 DEG C be 5 DEG C/ min;(b) 1200 DEG C are warming up to, and 50min is kept the temperature in the highest temperature, wherein the heating rate for being warming up to 1200 DEG C by 850 DEG C is 5 ℃/min;(c) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1200 DEG C are 6 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall is 2 DEG C/min;
Foamed ceramic light weight board is unloaded finally by lower stockline.
Embodiment 5
(1) it is formulated:Ceramic polishing waste residue 80%, clay 10%, feldspar 7.7%, foaming agent 0.3%, stabilizer 2%.
(2) preparation method:
By raw material batch mixing according to the ratio, and through ball milling, obtain powder;
Powder is subjected to cloth by feeding line on kiln car, then carries out kiln car push-in tunnel oven at three stacking burnings Reason, obtains foamed ceramic light weight board, wherein process for calcining is as follows:(a) 860 DEG C are warming up to, and keeps the temperature 10min at 860 DEG C, Wherein, the heating rate for being warming up to 400 DEG C by 0 DEG C be 17 DEG C/min, the heating rate for being warming up to 860 DEG C by 400 DEG C be 6 DEG C/ min;(b) 1210 DEG C are warming up to, and 30min is kept the temperature in the highest temperature, wherein the heating rate for being warming up to 1210 DEG C by 860 DEG C is 5 ℃/min;(c) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1210 DEG C are 6 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall is 2 DEG C/min;
Foamed ceramic light weight board is unloaded finally by lower stockline.
Embodiment 6
(1) it is formulated:Ceramic polishing waste residue 75%, clay 1.6%, feldspar 20%, foaming agent 0.4%, stabilizer 3%.
(2) preparation method:
By raw material batch mixing according to the ratio, and through ball milling, obtain powder;
Powder is subjected to cloth by feeding line on kiln car, then carries out kiln car push-in tunnel oven at three stacking burnings Reason, obtains foamed ceramic light weight board, wherein process for calcining is as follows:(a) 900 DEG C are warming up to, and keeps the temperature 30min at 900 DEG C, Wherein, the heating rate for being warming up to 400 DEG C by 0 DEG C be 20 DEG C/min, the heating rate for being warming up to 900 DEG C by 400 DEG C be 8 DEG C/ min;(b) 1220 DEG C are warming up to, and 60min is kept the temperature in the highest temperature, wherein the heating rate for being warming up to 1220 DEG C by 900 DEG C is 8 ℃/min;(c) slow cooling, the rate of temperature fall for being cooled to 600 DEG C by 1220 DEG C are 9 DEG C/min, and 50 DEG C are cooled to by 600 DEG C Rate of temperature fall is 4 DEG C/min;
Foamed ceramic light weight board is unloaded finally by lower stockline.
Foamed ceramic light weight board obtained by embodiment 1-6 is done into technology detection, it is as a result as follows:
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than is protected to the present invention The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art should Understand, technical scheme of the present invention can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention And range.

Claims (10)

1. a kind of tunnel oven of foamed ceramic light weight board folds burning system, which is characterized in that including:Feeding line is used for raw material Cloth is carried out on kiln car;Tunnel oven, for foamed ceramic light weight board green body to be burnt into;And lower stockline, being used for will Foamed ceramic light weight board is unloaded;
Wherein, the kiln car includes holder, the holder be equipped at least two layers of saggar, every layer of saggar include backing plate, coaming plate and High temperature resistant paper, the coaming plate ride upon the surrounding of backing plate, and the high temperature resistant paper is equipped on the backing plate and coaming plate;
The feeding line includes:At least two feeding unit materials for installing saggar and cloth;
The feeding unit material includes:
Cleaning unit for clearing up backing plate, coaming plate;
For consolidation or set up the backing plate consolidation unit of backing plate;
The first laying unit for being laid with high temperature resistant paper on backing plate;
Coaming plate for setting up coaming plate on backing plate sets up unit;
The second laying unit for being laid with high temperature resistant paper on coaming plate;
The cloth material unit of cloth is carried out in saggar.
2. the tunnel oven of foamed ceramic light weight board as described in claim 1 folds burning system, which is characterized in that on the holder Equipped at least three layers of saggar, the feeding line includes at least three installation units;
Green body in saggar carries out multi-laminate burning in tunnel oven, to form foamed ceramic light weight board.
3. the tunnel oven of foamed ceramic light weight board as described in claim 1 folds burning system, which is characterized in that the lower stockline Include at least two blanking units for dismantling saggar and blanking:
The blanking unit includes;
The first unloading unit for unloading coaming plate;
The second unloading unit for unloading foamed ceramic light weight board;
Third unloading unit for downloading backing plate.
4. the tunnel oven of foamed ceramic light weight board as described in claim 1 folds burning system, which is characterized in that first paving If unit includes shop fixtures tissue machine, it includes manipulator that the coaming plate, which sets up unit, and second laying unit includes paving side paper Machine;
First laying unit, coaming plate set up unit and the second laying unit is sequentially connected;
The coaming plate is set up unit and is correspondingly arranged with the first unloading unit, the coaming plate that the manipulator unloads the first unloading unit It is transplanted on coaming plate and sets up unit.
5. the tunnel oven of foamed ceramic light weight board as claimed in claim 4 folds burning system, which is characterized in that first paving If unit, coaming plate set up unit and the second laying unit is additionally provided with consolidation machine, the consolidation machine includes elevation and subsidence mechanical arm and claps neat Component, the neat component of bat carry out clapping neat consolidation to backing plate and coaming plate.
6. the tunnel oven of foamed ceramic light weight board as described in claim 1 folds burning system, which is characterized in that the cleaning is single Member is descaling machine, and the descaling machine includes hairbrush, driving mechanism and vacuum cleaner system, and the driving mechanism drives brush roll It is dynamic.
7. the tunnel oven of foamed ceramic light weight board as claimed in any one of claims 1 to 6 folds burning system, which is characterized in that institute It is mullite backing plate, silicon carbide backing plate or cordierite backing plate to state backing plate;
The coaming plate is mullite coaming plate, silicon carbide coaming plate or cordierite coaming plate;
The high temperature resistant paper is aluminum silicate fiber paper.
8. the tunnel oven of foamed ceramic light weight board as described in claim 1 folds burning system, which is characterized in that the foaming pottery Porcelain light weight board is mainly made of the raw material of following weight percentage:
Ceramic polishing waste residue 70-96%, clay 0-10%, feldspar 0-20%, foaming agent 0.01-0.6%, stabilizer 0.1-4%.
9. the tunnel oven of foamed ceramic light weight board as claimed in claim 8 folds burning system, which is characterized in that the foaming pottery Porcelain light weight board is mainly made of the raw material of following weight percentage:
Ceramic polishing waste residue 75-95%, clay 0.1-10%, feldspar 0.1-20%, foaming agent 0.1-0.4%, stabilizer 0.1- 3%.
10. the tunnel oven of foamed ceramic light weight board as claimed in claim 8 folds burning system, which is characterized in that the clay It is one or more in black mud, kaolin, municipal sludge, ooze;
The foaming agent is silicon carbide or grinding head for polishing reclaimed materials, and the main component of the grinding head for polishing reclaimed materials includes silicon carbide And resin.
CN201810688689.XA 2018-06-28 2018-06-28 A kind of folded burning system of the tunnel oven of foamed ceramic light weight board Pending CN108662897A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103707401A (en) * 2012-09-28 2014-04-09 江苏金久科技新材料有限公司 Sintering mold for forming of foaming ceramics
CN107860220A (en) * 2017-10-31 2018-03-30 广西旭腾实业集团有限公司 Energy-efficient automation tunnel cave

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103707401A (en) * 2012-09-28 2014-04-09 江苏金久科技新材料有限公司 Sintering mold for forming of foaming ceramics
CN107860220A (en) * 2017-10-31 2018-03-30 广西旭腾实业集团有限公司 Energy-efficient automation tunnel cave

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