CN106278138A - A kind of high rigidity ceramic tile and preparation method thereof - Google Patents
A kind of high rigidity ceramic tile and preparation method thereof Download PDFInfo
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- CN106278138A CN106278138A CN201610635731.2A CN201610635731A CN106278138A CN 106278138 A CN106278138 A CN 106278138A CN 201610635731 A CN201610635731 A CN 201610635731A CN 106278138 A CN106278138 A CN 106278138A
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- parts
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- ceramic tile
- oxide
- high rigidity
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- 239000000919 ceramic Substances 0.000 title claims abstract description 98
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000002994 raw material Substances 0.000 claims abstract description 36
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 28
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 27
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 27
- 239000011230 binding agent Substances 0.000 claims abstract description 27
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 27
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 27
- 239000004927 clay Substances 0.000 claims abstract description 26
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 25
- 238000000498 ball milling Methods 0.000 claims description 108
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 90
- 150000001875 compounds Chemical class 0.000 claims description 60
- 239000000758 substrate Substances 0.000 claims description 51
- 238000000227 grinding Methods 0.000 claims description 44
- 239000004575 stone Substances 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 19
- 230000000844 anti-bacterial effect Effects 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000010304 firing Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 238000007688 edging Methods 0.000 claims description 8
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 8
- 238000002386 leaching Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 238000002791 soaking Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 4
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 4
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 4
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 4
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- 229910003454 ytterbium oxide Inorganic materials 0.000 claims description 4
- 229940075624 ytterbium oxide Drugs 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000007767 bonding agent Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 238000003763 carbonization Methods 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 230000004083 survival effect Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- -1 vitrified tile Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004899 motility Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a kind of high rigidity ceramic tile, it is made up of the raw material of following weight parts: clay 15 25 parts, Kaolin 20 30 parts, light ceramic 20 40 parts, zirconium oxide 15 parts, aluminium oxide 5 10 parts, silicon oxide 15 parts, carborundum 15 parts, titanium carbide 15 parts, rare earth oxide 13 parts and binding agent 5 10 parts.Accordingly, invention additionally discloses above-mentioned high rigidity ceramic tile preparation method.The present invention can alleviate the weight of ceramic tile significantly, and compared with common ceramic tile, its weight can reduce 50%.And, the hardness of described ceramic tile is high, and the modulus of rupture, breakdown strength, bending strength are the most ideal.
Description
Technical field
The present invention relates to Ceramic Tiles field, particularly to a kind of high rigidity ceramic tile and preparation method thereof.
Background technology
Along with the raising of ceramic tile production technology, the kind of tile product gets more and more, including polished bricks, glazed tile, entire body
Brick, vitrified tile, ceramic mosaic tile etc..The range of application of ceramic tile is wider, from local-style dwelling houses to office building, from indoor to open air, arrives
Place is it can be seen that the figure of ceramic tile.
But the hardness of existing ceramic tile is the highest, it is easily damaged during transport and installation.And existing hardness is high
Ceramic tile is the most heavier, considerably increases the cost of transport.The Ceramic Tiles of prior art is difficult under conditions of low production cost,
Solve hardness and two technical problems of lightweight simultaneously.
Summary of the invention
The technical problem to be solved is, it is provided that a kind of ceramic tile having high rigidity and two advantages of lightweight concurrently,
And the production cost of described ceramic tile is low.
The technical problem to be solved also resides in, it is provided that a kind of ceramic tile having high rigidity and two advantages of lightweight concurrently
Preparation method.
For reaching above-mentioned technique effect, the invention provides a kind of high rigidity ceramic tile, it is by the raw material system of following weight parts
Become:
Clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, oxidation
Silicon 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and binding agent 5-10 part.
As the improvement of such scheme, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 18-23 part, Kaolin
22-28 part, light ceramic 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, carborundum 1-3 part, carbonization
Titanium 1-3 part, rare earth oxide 1-2 part and binding agent 6-8 part.
As the improvement of such scheme, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 20 parts, Kaolin 25 parts,
Light ceramic 30 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts
With binding agent 7 parts.
As the improvement of such scheme, the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, and described antibacterial is
Zinc oxide, copper oxide, ammonium dihydrogen phosphate or lithium carbonate.
As the improvement of such scheme, described rare earth oxide is yittrium oxide, lanthana, cerium oxide or ytterbium oxide；Described
Binding agent is sodium carboxymethyl cellulose.
Accordingly, invention additionally discloses the preparation method of a kind of high rigidity ceramic tile, including:
1, raw material is weighed by following weight parts: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide
1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and bonding
Agent 5-10 part；
2, raw material stirring is mixed 30-60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
4, by ball milling material under the pressure of 30-50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200-1500 DEG C, and firing time is 30-60min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
As the improvement of such scheme, step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60-70mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 50-59mm at second time ball milling
Reason；
Compound through second time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 40-49mm at third time ball milling
Reason；
Compound through third time ball-milling treatment is carried out at the 4th ball milling with the zirconia ball grinding stone of a diameter of 30-39mm
Reason.
As the improvement of such scheme, step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm.
As the improvement of such scheme, described compressing pressure is 38-48Mpa；
The water content ＜ 1% of dried base substrate；
The temperature burnt till is 1350-1450 DEG C, and firing time is 40-50min.
Enforcement there is advantages that
The present invention provides a kind of high rigidity ceramic tile, and its composition of raw materials is: clay 15-25 part, Kaolin 20-30 part, light ceramic
20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare-earth oxidation
Thing 1-3 part and binding agent 5-10 part.Use above-mentioned composition of raw materials, can significantly alleviate the weight of ceramic tile, with common ceramic tile phase
Ratio, its weight can reduce 50%.And, the hardness of described ceramic tile is high, and case hardness is 1600-2000HV, and the modulus of rupture reaches
110-150MPa, breakdown strength is 1800-2000N, and bending strength is 400-450 Mpa.
Additionally, the preparation technology of described high rigidity ceramic tile is simple, process control is simple, and equipment requirements is simple, effectively
Save production cost, applied range.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, the present invention will be made the most detailed below
Describe.
The invention discloses a kind of high rigidity ceramic tile, it is made up of the raw material of following weight parts:
Clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, oxidation
Silicon 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and binding agent 5-10 part.
Preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 18-23 part, Kaolin 22-28 part, Lightweight ceramic
Grain 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, carborundum 1-3 part, titanium carbide 1-3 part, rare earth oxygen
Compound 1-2 part and binding agent 6-8 part.
More preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 20 parts, Kaolin 25 parts, light ceramic 30
Part, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 7
Part.
It should be noted that light ceramic, using clay or flyash, biological sludge is primary raw material, is roasted by high temperature
Burn, expanded form, light ceramic as a kind of light-weight aggregate, have that density is little, intensity is high, water absorption rate is big, be incubated, heat insulation, fire-resistant,
The features such as antidetonation.
It is excellent that zirconia material itself has high rigidity, high temperature, high tenacity, high wearability and chemical resistance etc.
Physical and chemical performance；And aluminium oxide itself also possesses that mechanical strength is high, hardness greatly, dielectric loss is little frequently, high-temperature insulation resistance is high, resistance to
Chemical corrosivity and the heat conductivity excellent combination technical performance such as well.
Titanium carbide has high rigidity, high-melting-point and anti abrasive performance；Carborundum has stable chemical performance, heat conductivity
The advantages such as height, thermal coefficient of expansion is little, anti-wear performance good, high rigidity (Mohs' hardness is 9.5 grades).Tests prove that, by above-mentioned material
The ceramic material that material obtains with zirconium oxide, silicon oxide and alumina composite, can significantly improve the hardness of ceramic tile.
To sum up, the present invention, based on clay and Kaolin, adds a certain amount of light ceramic, and is aided with special ratios
Zirconium oxide, aluminium oxide, silicon oxide, carborundum and titanium carbide, can effectively reduce the weight of ceramic tile, and can also ensure that it has height
Hardness.
Further, the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, and described antibacterial is zinc oxide, oxidation
Copper, ammonium dihydrogen phosphate or lithium carbonate.Described antibacterial acts on jointly with other raw materials of high rigidity ceramic tile so that high rigidity ceramic tile
Having antibiotic and sterilizing ability, the survival rate of the antibacterial on its surface is less than 50%, and the survival rate of mycete is less than 30%.
Described rare earth oxide is preferably yittrium oxide, lanthana, cerium oxide or ytterbium oxide, but is not limited to this.
Described binding agent is preferably sodium carboxymethyl cellulose, but is not limited to this.
Accordingly, invention additionally discloses the preparation method of a kind of high rigidity ceramic tile, including:
1, raw material is weighed by following weight parts: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide
1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and bonding
Agent 5-10 part；
Preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 18-23 part, Kaolin 22-28 part, light ceramic
25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, carborundum 1-3 part, titanium carbide 1-3 part, rare-earth oxidation
Thing 1-2 part and binding agent 6-8 part.
More preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 20 parts, Kaolin 25 parts, light ceramic 30
Part, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 7
Part.
Further, the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, and described antibacterial is zinc oxide, oxidation
Copper, ammonium dihydrogen phosphate or lithium carbonate.Therefore, described high rigidity ceramic tile also has antibiotic and sterilizing ability, depositing of the antibacterial on its surface
Motility rate is less than 50%, and the survival rate of mycete is less than 30%.
Described rare earth oxide is preferably yittrium oxide, lanthana, cerium oxide or ytterbium oxide, but is not limited to this.
Described binding agent is preferably sodium carboxymethyl cellulose, but is not limited to this.
2, raw material stirring is mixed 30-60min, obtain compound.
3, compound is carried out four ball millings, obtain ball milling material.
Concrete, described four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60-70mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 50-59mm at second time ball milling
Reason；
Compound through second time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 40-49mm at third time ball milling
Reason；
Compound through third time ball-milling treatment is carried out at the 4th ball milling with the zirconia ball grinding stone of a diameter of 30-39mm
Reason.
As the further preferred scheme of four ball millings, comprising:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm.
4, by ball milling material under the pressure of 30-50Mpa compressing, obtain base substrate；
Preferably, described compressing pressure is 38-48Mpa.
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
Preferably, the water content ＜ 1% of dried base substrate.
6, carry out dried base substrate soaking glaze.
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200-1500 DEG C, and firing time is 30-60min；
Preferably, the temperature burnt till is 1350-1450 DEG C, and firing time is 40-50min.
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
With specific embodiment, the present invention is further elaborated below
Embodiment 1
One, formula: clay 15 parts, Kaolin 20 parts, light ceramic 20 parts, zirconium oxide 1 part, aluminium oxide 5 parts, silicon oxide 1 part,
Carborundum 1 part, titanium carbide 1 part, rare earth oxide 1 part and binding agent 5 parts.
Two, preparation method:
1, raw material is weighed by following weight parts: clay 15 parts, Kaolin 20 parts, light ceramic 20 parts, zirconium oxide 1 part, aluminium oxide
5 parts, silicon oxide 1 part, carborundum 1 part, titanium carbide 1 part, rare earth oxide 1 part and binding agent 5 parts；
2, raw material stirring is mixed 30min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 30Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200 DEG C, and firing time is 30min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 2
One, formula: clay 18 parts, Kaolin 22 parts, light ceramic 25 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts,
Carborundum 2 parts, titanium carbide 2 parts, rare earth oxide 2 parts, binding agent 7 parts, antibacterial 1 part；
Two, preparation method:
1, raw material is weighed by following weight parts: clay 18 parts, Kaolin 22 parts, light ceramic 25 parts, zirconium oxide 2 parts, aluminium oxide
7 parts, silicon oxide 2 parts, carborundum 2 parts, titanium carbide 2 parts, rare earth oxide 2 parts, binding agent 7 parts, antibacterial 1 part；
2, raw material stirring is mixed 40min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 40Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1350 DEG C, and firing time is 50min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 3
One, formula: clay 20 parts, Kaolin 25 parts, light ceramic 30 parts, zirconium oxide 3 parts, aluminium oxide 8 parts, silicon oxide 3 parts,
Carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 8 parts.
Two, preparation method:
1, raw material is weighed by following weight parts: clay 20 parts, Kaolin 25 parts, light ceramic 30 parts, zirconium oxide 3 parts, aluminium oxide
8 parts, silicon oxide 3 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 8 parts；
2, raw material stirring is mixed 50min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 45Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1400 DEG C, and firing time is 50min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 4
One, formula: clay 22 parts, Kaolin 28 parts, light ceramic 35 parts, zirconium oxide 4 parts, aluminium oxide 9 parts, silicon oxide 4 parts, carbon
SiClx 4 parts, titanium carbide 4 parts, rare earth oxide 3 parts, binding agent 9 parts, antibacterial 2 parts；
Two, preparation method:
1, raw material is weighed by following weight parts: clay 22 parts, Kaolin 28 parts, light ceramic 35 parts, zirconium oxide 4 parts, aluminium oxide 9
Part, silicon oxide 4 parts, carborundum 4 parts, titanium carbide 4 parts, rare earth oxide 3 parts, binding agent 9 parts, antibacterial 2 parts；
2, raw material stirring is mixed 60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1450 DEG C, and firing time is 50min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 5
One, formula: clay 25 parts, Kaolin 30 parts, light ceramic 40 parts, zirconium oxide 5 parts, aluminium oxide 10 parts, silicon oxide 5 parts,
Carborundum 5 parts, titanium carbide 5 parts, rare earth oxide 3 parts and binding agent 10 parts.
Two, preparation method:
1, raw material is weighed by following weight parts: clay 25 parts, Kaolin 30 parts, light ceramic 40 parts, zirconium oxide 5 parts, aluminium oxide
10 parts, silicon oxide 5 parts, carborundum 5 parts, titanium carbide 5 parts, rare earth oxide 3 parts and binding agent 10 parts；
2, raw material stirring is mixed 60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1500 DEG C, and firing time is 60min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
The ceramic tile (a size of 60*60cm, thickness is 0.8-1cm) of embodiment 1-5 gained is done technology for detection, and result is such as
Under:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Case hardness | 1700HV | 1680HV | 1850HV | 1950HV | 1750HV |
| The modulus of rupture | 120MPa | 145MPa | 131MPa | 148MPa | 137MPa |
| Breakdown strength | 1870N | 1900N | 1980N | 1950N | 1920N |
| Bending strength | 405 Mpa | 410Mpa | 440Mpa | 430Mpa | 420Mpa |
| Weight | 3.7kg | 3.7kg | 3.7kg | 3.7kg | 3.7kg |
It should be noted that described weight measurement is a size of 60*60cm, thickness is the weight of the ceramic tile of 1cm.
In sum, the present invention provides a kind of high rigidity ceramic tile, can significantly alleviate the weight of ceramic tile, with common ceramic tile phase
Ratio, its weight can reduce 50%.And, the hardness of described ceramic tile is high, and the modulus of rupture, breakdown strength, bending strength are the most more managed
Think.Additionally, the preparation technology of described high rigidity ceramic tile is simple, process control is simple, and equipment requirements is simple, effectively saves life
Produce cost, applied range.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (9)
1. a high rigidity ceramic tile, it is characterised in that it is made up of the raw material of following weight parts:
Clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, oxidation
Silicon 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and binding agent 5-10 part.
2. high rigidity ceramic tile as claimed in claim 1, it is characterised in that the composition of raw materials of described high rigidity ceramic tile is as follows: viscous
Soil 18-23 part, Kaolin 22-28 part, light ceramic 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part,
Carborundum 1-3 part, titanium carbide 1-3 part, rare earth oxide 1-2 part and binding agent 6-8 part.
3. high rigidity ceramic tile as claimed in claim 2, it is characterised in that the composition of raw materials of described high rigidity ceramic tile is as follows: viscous
20 parts of soil, Kaolin 25 parts, light ceramic 30 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, carbonization
Titanium 3 parts, rare earth oxide 2 parts and binding agent 7 parts.
4. high rigidity ceramic tile as claimed in claim 3, it is characterised in that the raw material of described high rigidity ceramic tile also includes antibacterial
1-2 part, described antibacterial is zinc oxide, copper oxide, ammonium dihydrogen phosphate or lithium carbonate.
5. high rigidity ceramic tile as claimed in claim 3, it is characterised in that described rare earth oxide is yittrium oxide, lanthana, oxygen
Change cerium or ytterbium oxide；
Described binding agent is sodium carboxymethyl cellulose.
6. the preparation method of the high rigidity ceramic tile as described in any one of claim 1-5, it is characterised in that including:
1, raw material is weighed by following weight parts: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide
1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and bonding
Agent 5-10 part；
2, raw material stirring is mixed 30-60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
4, by ball milling material under the pressure of 30-50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200-1500 DEG C, and firing time is 30-60min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
7. the preparation method of high rigidity ceramic tile as claimed in claim 6, it is characterised in that step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60-70mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 50-59mm at second time ball milling
Reason；
Compound through second time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 40-49mm at third time ball milling
Reason；
Compound through third time ball-milling treatment is carried out at the 4th ball milling with the zirconia ball grinding stone of a diameter of 30-39mm
Reason.
8. the preparation method of high rigidity ceramic tile as claimed in claim 7, it is characterised in that step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm.
9. the preparation method of high rigidity ceramic tile as claimed in claim 7, it is characterised in that described compressing pressure is
38-48Mpa；
The water content ＜ 1% of dried base substrate；
The temperature burnt till is 1350-1450 DEG C, and firing time is 40-50min.
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| CN107417116A (en) * | 2017-06-20 | 2017-12-01 | 安徽省含山瓷业股份有限公司 | A kind of preparation method of the unleaded glaze of domestic ceramics of inexpensive high rigidity |
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