WO2019210527A1 - Procédé de traitement de production mat pour textile à base de tissu en coton - Google Patents

Procédé de traitement de production mat pour textile à base de tissu en coton Download PDF

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Publication number
WO2019210527A1
WO2019210527A1 PCT/CN2018/085790 CN2018085790W WO2019210527A1 WO 2019210527 A1 WO2019210527 A1 WO 2019210527A1 CN 2018085790 W CN2018085790 W CN 2018085790W WO 2019210527 A1 WO2019210527 A1 WO 2019210527A1
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WO
WIPO (PCT)
Prior art keywords
cotton fabric
desizing
enzyme
matte
dyeing
Prior art date
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PCT/CN2018/085790
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English (en)
Chinese (zh)
Inventor
朱爱民
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南通市苏中纺织有限公司
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Publication of WO2019210527A1 publication Critical patent/WO2019210527A1/fr

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B6/00Cleaning by electrostatic means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B13/00Treatment of textile materials with liquids, gases or vapours with aid of vibration
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/16Multi-step processes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/40Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using enzymes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Definitions

  • the invention relates to the technical field of textile processing, and more particularly to a method for processing matt production of cotton fabric textiles.
  • Matte is relative to flat light, that is, non-glossy surface. It can avoid light pollution and is convenient to maintain.
  • the matt surface is a bit hairy, like the surface of a frosted glass.
  • Ultrasonic cleaning is the direct and indirect effect of the cavitation, acceleration and direct flow of the ultrasonic waves on the liquid and the dirt, so that the dirt layer is dispersed, emulsified and peeled off to achieve the cleaning purpose.
  • cavitation and direct flow are applied more.
  • the existing ultrasonic cleaning is applied to the surface coating processing industry, machinery industry, electronics industry, medical industry, semiconductor industry, watch and jewelry industry, optics. Industry, textile printing and dyeing industry. However, the application in the textile printing and dyeing industry is limited to the cleaning of finished textiles, and the advantages of ultrasonic cleaning compared to conventional washing cannot be fully utilized.
  • the existing cotton fabric textile processing process adopts high temperature desizing scouring, oxygen bleaching, alkali mercerizing treatment and dyeing after caustic soda.
  • the cotton fiber swells violently, the cross section of the fiber tends to be irregular, and the fabric's hair effect, whiteness, gloss and dyeing properties are greatly improved.
  • the cotton fabric has good gloss and dyeing performance, but the fabric feels poor, and it needs to be improved by soft finishing.
  • the process has large alkali, poor production environment, high cost of waste alkali treatment in production, and high CODcr and PH value of discharged sewage. It is a major problem in the sewage treatment of textile mills.
  • the object of the present invention is to provide a matt production processing method for cotton fabric textiles, which can reduce impurities on the surface of cotton fabric semi-products, significantly improve the matt color effect, and simultaneously produce matt light.
  • Treated cotton fabric textiles are more popular with sensitive skin users.
  • the present invention adopts the following technical solutions.
  • a matt production processing method for cotton fabric textiles comprising the following steps:
  • Step one the desizing process, using desizing enzyme to carry out desizing, after desizing for 45 min, two times of washing, maintaining the temperature of 60 ° C during desizing;
  • Step 2 low-temperature alkali-free boiling and bleaching process, the first step uses high-temperature enzyme desizing, and the second step uses scouring enzyme and hydrogen peroxide to cooperate in boiling-bathing treatment;
  • Step 3 Pre-matia treatment process, the cotton fabric semi-product is placed in clean water for ultrasonic cleaning;
  • Step 4 matt treatment process, after the water in step three is cooled to 55 ° C, the cationic auxiliary agent and cellulase are added for 30 min;
  • Step 5 Dyeing process, dyeing the cotton fabric semi-products in step 4 after normal temperature washing, firstly laying the cloth, then heating to 85 ° C, dyeing for 30 min, adding soda ash for 30 min, washing again, washing after 90 ° C environment Soaked under water, and finally washed;
  • Step 6 The ultra-fine bubble processing step, the dyed cotton fabric semi-product is placed in normal temperature and clear water, and the ultra-fine bubbles are continuously bubbled into the normal temperature and clear water for 5 min;
  • Step VII drying process, stop blasting into ultra-fine bubbles, heating step 6 at room temperature to 60 ° C for 30 min, then pick up the cotton fabric semi-products and put them in a 60 ° C incubator to dry;
  • Step 8 Finally, the cotton fabric semi-products are sequentially subjected to softening, mechanical soft finishing, and small tenter pre-shrinking to produce finished products.
  • the desizing enzyme includes a PVA degrading enzyme, a starch desizing enzyme, and an emu oil HP6.
  • the PVA degrading enzyme is added first, and after 3 h to 3 h, the starch desizing enzyme and the eucalyptus HP6 are added, and after 45 min, the water washing is performed twice.
  • the ultrasonic cleaner in the third step adopts a KQ-1000E medical ultrasonic cleaner.
  • the fresh water is first heated to 60 ° C and then ultrasonically cleaned.
  • the foam floating net is placed on the liquid surface of the dyeing tank during the dyeing, and the surface of the foam floating net is subjected to rough grinding treatment.
  • the heating step 6 is heated to 60 ° C, and the ultrasonic cleaning is performed again.
  • the cotton fabric semi-products are directly picked up and placed in an incubator at 60 ° C to be dried.
  • a white foam floating plate is placed on the liquid surface in the ultrasonic cleaner, and the surface of the white foam floating net is coarsely ground, and the cleaning is finished.
  • a magnifying glass observes the transparency of the bubbles attached to the white foam float.
  • an electrostatic generator is arranged inside the incubator in the seventh step, and the emitting end of the electrostatic generator is in contact with the incubator.
  • the cotton fabric semi-product is placed on the drying rack during the drying process, and the cotton fabric semi-product is not in contact with the incubator and the electrostatic generator.
  • This scheme significantly improves the matt color effect by reducing impurities on the surface of cotton fabric semi-finished products, and the cotton fabric textiles processed by matt production are more popular among users of sensitive skin.
  • step 2 PVA degrading enzyme is added first. After 3h-3h15min, starch desizing enzyme and eucalyptus HP6 are added, and after washing for 45min, two water washings are performed. When the PVA degrading enzyme works for 4h, the cleaning effect is better. The desizing enzyme and the eucalyptus HP6 only need to act for 45 minutes, and the desizing is more reasonable.
  • the ultrasonic cleaner in step 3 uses a new generation of ultrasonic generator using IGBT component inverter power supply, ultrasonic cleaning for 30s directly with clean water, and a new generation ultrasonic generator using IGBT component inverter power supply compared with conventional ultrasonic cleaner High operating stability and long service life make it suitable for the textile industry.
  • the fresh water is first heated to 55 ° C and then ultrasonically cleaned, and the effect of ultrasonic cleaning at 55 ° C is better.
  • the foam floating net is placed on the liquid surface of the dyeing tank, and the surface of the foam floating net is laid with a pile layer.
  • the foam floating net floats on the liquid surface of the dyeing tank, and the dye floating on the liquid surface is effectively reduced.
  • the floating layer of dye adheres to the textile, causing uneven dyeing.
  • the heating step 6 is heated to 55 ° C, and then ultrasonic cleaning is performed again for 30 s.
  • the cotton fabric semi-products are directly taken up in an incubator at 55 ° C to dry, and ultrasonic cleaning is performed. In combination with the ultra-fine bubbles, the cleaning effect is further improved.
  • the soaping in the step 5 is reduced from the conventional 30 minutes to 6 minutes, and the corrosion of the surface layer of the cotton fabric semi-product is reduced by the soaping process.
  • Step 3 and Step 7 In the ultrasonic cleaning process, a white foam floating plate is placed on the liquid surface of the ultrasonic cleaner, and the surface of the white foam floating net is roughly ground, and after the cleaning, a magnifying glass is used for observation.
  • the transparency of the bubbles attached to the white foam floating net can more easily understand the cleaning degree of the cotton fabric textile by observing the bubbles on the white foam floating net.
  • the white color is more convenient to observe the residual of the dye, and the technician can adjust the ultrasonic cleaning time and the ultrasonic frequency. .
  • the electrostatic generator is arranged inside the incubator in step 7.
  • the emitting end of the electrostatic generator is in contact with the incubator, and the semi-product of the cotton fabric is placed on the drying rack during the drying process, and the semi-finished fabric of the cotton fabric is not In contact with the incubator and the electrostatic generator, the electrostatic generator causes the incubator to be electrostatically charged, which facilitates the adsorption of the fly ash produced by the drying of the cotton fabric semi-finished product and improves the quality of the semi-finished cotton fabric.
  • Figure 1 is a flow chart of the process of the present invention.
  • connection may be a fixed connection, a detachable connection, or an integral connection; it may be a mechanical connection or an electrical connection; it may be directly connected, or may be indirectly connected through an intermediate medium, and may be internal to both components. Connectivity.
  • the specific meaning of the above terms in the present invention can be understood in a specific case by those skilled in the art.
  • a matt production processing method for cotton fabric textiles comprising the following steps:
  • Step 1 Desizing step, desizing with desizing enzyme, washing twice after desizing, maintaining temperature of 60 ° C during desizing, desizing enzyme including PVA degrading enzyme, starch desizing enzyme and emu oil HP6
  • PVA degrading enzyme including PVA degrading enzyme, starch desizing enzyme and emu oil HP6
  • the synergistic effect of PVA degrading enzyme, starch desizing enzyme and eucalyptus HP6 can simultaneously achieve the functions of cleaning the starch dye, cleaning the PVA slurry and improving the cleaning performance of the slurry, compared with the single type of desizing effect of the prior art.
  • Good first add PVA degrading enzyme, after 3h-3h15min, add starch desizing enzyme and eucalyptus HP6, and work together for 45min and then wash twice.
  • PVA degrading enzyme works closer to 4h, the cleaning effect is better, and desizing enzyme and The eucalyptus HP6 only needs to act for 45 minutes, and it is more reasonable
  • Step 2 low-temperature alkali-free boiling and bleaching process, the first step uses high-temperature enzyme desizing, and the second step uses scouring enzyme and hydrogen peroxide to synergistically perform boiling-bathing treatment;
  • Step 3 Pre-matia treatment process, the cotton fabric semi-product is placed in clean water heated to 55 ° C for ultrasonic cleaning, and the ultrasonic cleaner adopts a new generation ultrasonic generator using IGBT component inverter power source, and directly performs ultrasonic cleaning with water.
  • the new generation of ultrasonic generators using IGBT component inverters has higher operational stability and longer service life than traditional ultrasonic cleaners, and is more suitable for the textile industry;
  • Step 4 matt treatment process, after the water in step three is cooled to 55 ° C, the cationic auxiliary agent and cellulase are added for 30 min;
  • Step 5 Dyeing process, dyeing the cotton fabric semi-product in step 4 after being washed at room temperature, firstly laying the cloth, then placing a foam floating net on the liquid surface of the dyeing pool, laying a pile layer on the surface of the foam floating net, foam floating The net floats on the liquid surface of the dyeing tank, and absorbs the incompletely dissolved dye floating on the liquid surface, effectively reducing the floating dye layer adhering to the textile, causing uneven dyeing, and then heating to 85 ° C, dyeing for 30 min, Add soda ash for 30min, wash again, wash with water, then wash with soap at 90 °C, and finally wash with water;
  • Step 6 The ultra-fine bubble processing process, the dyed cotton fabric semi-products are placed in normal temperature and clear water, and the ultra-fine bubbles are continuously blown into the normal temperature water for 5 minutes.
  • the ultra-fine bubble diameter is only 10 ⁇ m, which can easily penetrate into the cotton fabric semi-products.
  • a large number of bubbles dissolve and rupture in water, the highest temperature is about 5500 degrees Celsius in an instant, and about 400 kilometers per hour is generated when the rupture occurs, and a large amount of oxygen anions are generated for sterilization;
  • Step 7 Dry the process, stop the blasting into the ultra-fine bubbles, and then heat the water in the step of heating to the temperature of 55 °C for 30 seconds, and then perform the ultrasonic cleaning for 30 seconds.
  • the cavitation of the ultrasonic cleaning further enhances the cleaning effect on the one hand with the ultra-fine bubbles.
  • Reduce the soaping in step 5 from the traditional 30min to 6min reduce the time required for the soaping process to corrode and clean the surface layer of the cotton fabric semi-finished product, and then pick up the cotton fabric semi-products in an incubator at 60 ° C.
  • an electrostatic generator is arranged inside the incubator, the emitting end of the electrostatic generator is in contact with the incubator, the semi-finished fabric of the cotton fabric is placed on the drying rack during the drying process, and the semi-finished product of the cotton fabric is not associated with the incubator and
  • the electrostatic generator is in contact with each other, and the electrostatic generator makes the incubator carry static electricity, which is convenient for adsorbing the flying floc produced after drying the semi-finished cotton fabric, and improving the quality of the semi-finished cotton fabric;
  • Step 8 Finally, the cotton fabric semi-products are sequentially subjected to softening, mechanical soft finishing, and small tenter pre-shrinking to produce finished products.
  • a white foam floating plate is placed on the liquid surface in the ultrasonic cleaner, and the surface of the white foam floating net is coarsely ground. After the cleaning, the transparency of the bubble attached to the white foam floating net is observed by the magnifying glass, and the observation is carried out.
  • the bubbles on the white foam floating net can more intuitively understand the cleaning degree of the cotton fabric textile, and the white color is more convenient for observing the residual of the dye, and is convenient for the technician to adjust the ultrasonic cleaning time and the ultrasonic frequency.
  • the treatment method uses a pre-matia treatment process, and the ultrasonic cleaning of the cotton fabric semi-products before the matt treatment makes the cotton fabric semi-products desiccate more thoroughly, and is cleaner, and enhances the matt treatment process.
  • the treatment effect, the incompletely dissolved dye floating on the surface of the foam layer floating on the foam floating net in the dyeing process can effectively reduce the uneven dyeing phenomenon, improve the quality of dyeing, and further promote the double action of ultra-fine bubbles and ultrasonic cleaning.

Abstract

La présente invention concerne un procédé de traitement de production mat pour textile à base de tissu en coton, faisant partie du domaine technique du traitement de textile. Le procédé comprend : une étape de désencollage, dans laquelle une enzyme de désencollage est utilisée pour le désencollage, et un lavage est effectué deux fois après le désencollage; une étape d'ébullition et de blanchiment sans alcali à basse température, dans laquelle une enzyme à haute température est utilisée pour le désencollage et un traitement par procédé de bain de blanchiment par ébullition est réalisé par l'action coopérative d'une enzyme de récurage et de peroxyde d'hydrogène; une étape de traitement pré-mat, dans laquelle le tissu en coton semi-fini est placé dans de l'eau propre et subit un nettoyage par ultrasons; une étape de traitement mat, dans laquelle un agent auxiliaire d'ions positifs et de la cellulose sont ajoutés et une température constante est maintenue; une étape de coloration, dans laquelle une coloration est effectuée après que le lavage à température normale est effectué, c'est-à-dire que cette étape comprend d'abord le placement d'un tissu, la coloration du tissu, l'ajout de carbonate de sodium pour fixer une couleur, le relavage, et la réalisation d'un lavage après savonnage; et une étape de traitement par bulles ultra-petites, dans laquelle des bulles ultra-petites sont soufflées continuellement dans de l'eau propre à température normale. La présente invention réduit les impuretés sur la surface du tissu en coton semi-fini et améliore un effet de couleur mate, et le textile à base de tissu en coton traité par le procédé de traitement de production mat est mieux adapté à une peau sensible.
PCT/CN2018/085790 2018-05-03 2018-05-07 Procédé de traitement de production mat pour textile à base de tissu en coton WO2019210527A1 (fr)

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CN201810415671.2 2018-05-03
CN201810415671.2A CN108625065A (zh) 2018-05-03 2018-05-03 一种棉织物纺织品亚光生产处理方法

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