WO2019120779A1 - Fabrication de corps fusibles contenant un parfum - Google Patents

Fabrication de corps fusibles contenant un parfum Download PDF

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Publication number
WO2019120779A1
WO2019120779A1 PCT/EP2018/081295 EP2018081295W WO2019120779A1 WO 2019120779 A1 WO2019120779 A1 WO 2019120779A1 EP 2018081295 W EP2018081295 W EP 2018081295W WO 2019120779 A1 WO2019120779 A1 WO 2019120779A1
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WO
WIPO (PCT)
Prior art keywords
melt
container
melt dispersion
carrier material
water
Prior art date
Application number
PCT/EP2018/081295
Other languages
German (de)
English (en)
Inventor
Thomas Holderbaum
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2019120779A1 publication Critical patent/WO2019120779A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0082—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants

Definitions

  • the present invention relates to a process for producing fused bodies, which comprises preparing a melt dispersion comprising at least one water-soluble or water-dispersible carrier material and at least one solid in a first container; Mixing the thus-obtained melt dispersion with at least one esthetic in a subsequent container and reforming the resulting melt dispersion to obtain solid pastilles.
  • the present invention is further directed to the fins produced by this method, to a detergent or cleaning composition containing them, to the use of such a detergent or cleaner for cleaning textiles or hard surfaces, and to corresponding processes for cleaning textiles or hard Surfaces using such a detergent or cleaning agent.
  • the consumer In the use of detergents and cleaners, the consumer not only aims to wash, cleanse or care for the objects to be treated, but also desires that the treated objects, e.g. Textiles, after the treatment, for example after the wash, smell pleasant. For this reason in particular, most commercially available detergents and cleaners contain fragrances.
  • fragrances are used in the form of perfume pastilles either as an integral part of a washing or cleaning agent, or dosed directly into the washing drum at the beginning of a wash cycle in a separate form. In this way, the consumer can control the fragrance of the laundry to be washed by individual dosage.
  • fragrance pastilles are usually prepared from melt dispersions whose
  • Main component is a water-soluble or water-dispersible carrier material having a suitable melting temperature.
  • fragrance components such as fragrance, peppermint, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate, sulfate
  • melts and solids are added, for example, to influence the viscosity of the dispersion to be processed.
  • manufacturing methods are common in which initially a melt consisting of the carrier material and optionally
  • Solids and other ingredients is produced and the melt thus obtained directly with the fragrance component and possibly other ingredients such as dyes, is mixed.
  • the finished melt is then transformed.
  • enamel bodies which in terms of their density and the desired
  • Adjust moldings The entry of the gas takes place here via a gas line directly into the feed line of the melt, wherein gas and melt are mixed, for example by being introduced together into a mill, for example of the rotor-stator type.
  • gas and melt are mixed, for example by being introduced together into a mill, for example of the rotor-stator type.
  • active ingredients used in particular perfumes and fragrances are exposed to excessive thermal stress.
  • the object of this application was therefore to provide a manufacturing method for enamel bodies, which allow in a simple manner to adjust the density of these bodies without exposing the active substances and active ingredients used to excessive thermal stress.
  • This object has been achieved according to the invention by a multi-stage process, in the framework of which a solid and a gas are incorporated into the molten support material used for the production of fused bodies.
  • the present invention is directed to a process for preparing perfume-containing fusible articles, comprising the following steps:
  • a melt dispersion comprising at least one water-soluble or water-dispersible melted carrier material having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion of step i) with at least one esthetic; and iii) transforming the mixture obtained in step ii) to obtain solid fused bodies, characterized in that in step i) in the molten carrier material and / or the melt dispersion, a gas is incorporated.
  • the present invention is directed to a fuser made in a process as described herein.
  • the present invention is also directed to the use of the fused bodies, prepared by a process as described herein, as fabric care agents, preferably fragrances and / or fabric softeners, for perfuming and / or conditioning fabrics.
  • the present invention is further directed to a laundry or cleaning composition comprising a fuser made by a process as described herein.
  • melt refers to fusible, water-soluble or water-dispersible solids at standard conditions (20 ° C, 1013 mbar) which are obtainable by solidification and remodeling of the melts described herein.
  • the fusible bodies can have any shape.
  • the shaping takes place in particular in step iii) of the described method.
  • Preferred are solid, particulate forms, such as substantially spherical, figurative, scale, cuboid, cylindrical, conical, kugelkalotten- or lenticular, hemispherical, disc or needle-shaped enamel bodies.
  • the fusible bodies may have a gummy-like, figurative design. Because of their packaging properties and their performance profile, hemispherical fusible bodies are particularly preferred.
  • Preferred enamel bodies have in any spatial direction a maximum diameter of between 4 and 15 mm, preferably between 5 and 10 mm.
  • Particularly preferred fusible bodies are characterized by a maximum diameter of 2 to 8 mm, more preferably 4 to 6 mm.
  • such enamel bodies are particularly readily soluble in water and, on the other hand, have a size that is visually appealing to the consumer.
  • 100% hemispheric (hemispherical) particles are characterized by a height to diameter ratio of 0.5.
  • those enamel bodies are also referred to as hemispherical having a height to diameter ratio of 0.25 to 0.49.
  • Particular preference is given to enamel bodies having a height to diameter ratio of 0.35 to 0.45.
  • the weight of the individual enamel bodies is usually between 2 and 150 mg,
  • Water-soluble as used herein means a solubility in water at 20 ° C of at least 1 g / L, preferably at least 10 g / L, more preferably at least 50 g / L.
  • Water-dispersible as used herein means that the support material can be dispersed in water at 20 ° C by known methods.
  • At least one refers to 1 or more, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or more. In particular, this indication refers to the nature of the agent / compound rather than the absolute number of molecules. "At least one perfume” therefore means that at least one type of perfume is detected but also contains two or more different types of perfume can.
  • the present invention is directed to a fumed body manufacturing process such as fragrance pastilles wherein a melt dispersion is prepared in an uninterrupted process sequence and reshaped in a final step.
  • the method as described herein is characterized in that product changes, i. changed composition of the melt dispersion, for example by using a different fragrance and / or
  • a first subject of the present invention is therefore a process for the production of enamel bodies. According to the present invention, the method comprises the steps described below:
  • a perfume-free melt dispersion comprising at least one water-soluble or water-dispersible carrier material and at least one solid is prepared.
  • water-dispersible molten support material has a melting temperature of> 30 ° C, preferably> 40 ° C and in particular> 50 ° C.
  • Containers which are suitable for this purpose are generally familiar to the person skilled in the art.
  • the container permits thorough mixing of the components of the melt dispersion to be produced in step i) and further comprises at least one regulatable aperture through which the components of the melt dispersion to be produced in step i) the container can be introduced, and in addition at least one further adjustable opening through which the melt dispersion prepared in step i) can be discharged from the container. Through these openings, inlet and / or outlet stream can be controlled quantity.
  • the first container may be, for example, a mixing unit.
  • the constituents of the melt are heated to a temperature above the melting point of the support material, preferably to a temperature above 40 ° C, more preferably above 50 ° C.
  • the carrier material can already be supplied in molten form and mixed in the first container with the at least one solid.
  • the melt dispersion is transferred from the first container into the subsequent container by pressure, so that the melt dispersion is pumped / pressed from the first container into the subsequent container.
  • Carrier material in principle by heating it to a temperature which is not more than 20 ° C above the melting point of the support material. This also applies if the melting of the carrier material takes place in the first container already described. The melting can be carried out using all customary methods and devices known to the person skilled in the art. According to some embodiments, the thus melted substrate may then be transferred to the first vessel in step i) of the process step a) upstream as described herein to produce the melt dispersion of step i). It is correspondingly desirable that the first container additionally comprises at least one adjustable opening, which allows the introduction of such a melted carrier material. According to some embodiments, the method described herein is characterized
  • the individual flows may optionally be measured by measuring the flow rate of the individual feed streams, i. the melt, the
  • Perfume stream and possibly other streams are controlled. This also allows, for example, adjust the proportions of the individual components.
  • the inventive method is preferably characterized in that the melt dispersion prepared in step i) is transferred from the first container directly into the subsequent container.
  • the production process according to the invention is a sequential one
  • a process sequence as described herein may be continuous or as a batch process, with a continuous process being preferred.
  • the continuous process management makes it possible to change the amount or chemical nature of the esthetics used during operation, for example to stop the supply of perfume in step ii) and to switch the production to an alternative process product. Due to the late-stage metering of the esthetics in step ii), the residual amounts of such a change by the subsequent melt dispersion only from a part of the
  • an advantage of the method as described herein is that production changes are made possible without great expense. Due to the sequential process flow, the components to be supplied in the individual process steps, ie carrier material, solid, dye, perfume and possibly other ingredients, can be exchanged largely separately for alternatives, without the entire
  • the method described herein is characterized in that waste material which is obtained after step ii) in step i) or ii), preferably in step i) is recycled.
  • a gas is incorporated into the melt dispersion in step i).
  • the gas that is introduced may be, for example, air or an inert gas. In various embodiments, it is selected from air, oxygen, nitrogen,
  • Carbon dioxide, argon or helium preferably from air, nitrogen or helium, more preferably air. Air is preferred because it is readily available, inexpensive and the interaction with the components of the melt is well understood. Inert gases may be preferred when the melt contains sensitive ingredients, for example, those that are sensitive to the action of oxygen.
  • Melt bodies made by the methods of the invention and containing gas typically have a density that is less than the density of the solid and liquid materials that form the fuser body.
  • the melt body may have gas inclusions and a density of less than about 0.95 g / cm 3 in various embodiments. When substantially all the particles have a density of less than 0.95 g / cm 3, this means that they float with the use in for example a detergent. This can provide benefits in terms of fragrance release.
  • the density may also be about 0.9 g / cm 3 or less.
  • each fuser may be between about 0.5 to about 50 Vol .-% of the particle of gas, preferably between 1 and 20 vol .-%, more preferably between 2 and 15 vol .-%, most preferably between 4 and 12 vol .-%.
  • the gas inclusions are preferably as small as possible, typically in the range of 1 to 2000 pm, preferably between 5 and 1000, more preferably between 5 and 200, most preferably between 25 to 50 pm in diameter.
  • the incorporation of the gas can be incorporated, for example by means of a feed line in the melt dispersion, for example by means of a supply line, for example by means of a
  • the introduction of the gas is preferably carried out at a pressure above 1.1 bar, in particular above 2 bar.
  • the gas is incorporated by means of an agitator in the molten carrier material and / or in the melt dispersion.
  • the agitators are preferably selected from dissolvers, gassing mixers, jet stirrers, propeller stirrers, blade stirrers, preferably dissolvers,
  • Gassing agitators and jet agitators have the advantage that they allow easy incorporation of both gases and solids.
  • a dissolver is a disc stirrer, which is characterized in that a toothed stirrer disc is mounted on a vertical stirrer shaft, which is in the stirred product, i. here the melt is dipped. The disc settles in rotary motion
  • Stirring disc and agitator, as well as the speed and level are observed, with the appropriate parameters for the expert can be selected based on his expertise.
  • ideal dispersion is achieved when a torus-like flow pattern is established in the stirred material.
  • the gas to be incorporated is preferably above the melt.
  • the gas may be ambient, or a gas is introduced, which is heavier than air, such as carbon dioxide.
  • a closed container can be used, in which the gas can be introduced so that it is above the material to be stirred.
  • Such an arrangement also allows the incorporation of other gases than air.
  • Jet mixers or jet mixers are characterized by a fast rotating rotor and a Deflektorrohr surrounding the rotor. All the above agitators can be used in special embodiments for the incorporation of gas, for example in the form of agitators, which feed the gas via a hollow shaft or into which the gas is introduced via a hollow shaft.
  • Gassing agitators have a rotatable hollow shaft and at least one arranged on this hollow shaft hollow stirring member, wherein the cavity of the stirring member is in communication with the hollow shaft and the melt towards openings.
  • the molten carrier material and / or the melt dispersion in step i) is stirred in a manner which causes the formation of a trombe in the melt.
  • T refers to the flow pattern generated at the liquid surface by a stirrer, also referred to as a donut / donut effect. It comes here by the stirring to form a Torusform the Rhakguts, ie a 360 ° -Drift loftung on the spot. The product is stirred by the rotating
  • Stirring tool e.g. a dissolver disc
  • the material flow is divided and is deflected towards the center.
  • One part runs back to the stirrer at the bottom of the container, the other forms the "donut" on the surface.
  • parts of the stirring tool are released and become visible, which is referred to herein as a "trumpet that extends into the area of the agitator”.
  • Such a process procedure allows the simultaneous homogenization and gas treatment of the melt or melt dispersion.
  • stirrers used may consist of any material customary for such stirrers, but in particular of metal or plastic, for example stainless steel or PTFE
  • agitators with a vertical agitator shaft are preferred.
  • a solid and a gas are added to the molten carrier material in step i).
  • the addition of solid and gas makes it possible to adjust the density of the melt dispersion and thus also the density of the resulting melt body. While the density of the melt dispersion for a given material system is directly related to its viscosity, which in turn has an influence on the deformation behavior of the melt and thus on the final spatial form of the fusible bodies, the density of the fusible bodies is Bulk density and thus for the packing volume of the packaging material used for the packaging of the packaging material of importance.
  • the method makes it possible to adjust the density of the melt before the addition of the esthetics in step ii). In this way, an unnecessarily long processing of the esthetic melt dispersion and thus an unnecessary temperature load on temperature-sensitive aesthetics can be avoided.
  • step ii) the melt dispersion prepared in step i) is mixed with at least one esthetic.
  • step ii) is preferably carried out either (1) in a container downstream of the first container or (2), particularly preferably directly in the outlet stream emerging from the first container.
  • the first and subsequent containers are in communication with each other in accordance with the present invention.
  • Subsequent or “subsequent”, as used in this context, means that the container in question is downstream from the first container, i. the volume flow from the first container passes into this subsequent container at a later process time. But it is quite possible that the exiting from the first container volume flow before other, intermediate container passes.
  • the container comprises at least one adjustable opening, via which the melt dispersion prepared in step i) can be introduced into the container, at least one further adjustable opening, via which the aesthetic (and possibly other components) can be introduced into the container, as well
  • at least one adjustable opening through which the melt dispersion prepared in step ii) can be discharged from the container may, for example, a suitable mixing unit, such. a static mixer, his.
  • mixing may also be accomplished by continuously mixing the at least one esthetics into the effluent stream exiting the first vessel, i. without the
  • the opening through which the at least one esthetic is introduced into the melt dispersion is preferably adjustable.
  • Outflow of the first container can be transferred.
  • the mixing volume of the following container also be the volume of the conduit in which the outlet stream is passed from the first container.
  • the present invention is directed to a method for
  • Production of fragrance-containing enamel bodies comprising the following steps:
  • a melt dispersion comprising at least one water-soluble or water-dispersible melted carrier material having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion of step i) with at least one esthetic, wherein (1) the melt dispersion is transferred to a subsequent container and mixed therein with at least one esthetic, or (2) the at least one esthetics continuously into the outlet stream of the first Container is admixed;
  • step iii) forming the mixture obtained in step ii) to obtain solid fusible materials, characterized in that in step i) in the molten carrier material and / or the melt dispersion, a gas is incorporated.
  • Aesthetic refers to an active or adjuvant which is temperature-sensitive at the temperature used to prepare the melt dispersion in step i), ie which is chemically or physically disintegrated at that temperature.
  • Aesthetic refers more particularly to an active or adjuvant whose use in the fusible bodies is sensory by the consumer.
  • the group of aesthetics includes in particular the fragrances and dyes.
  • the fragrance is preferably used in liquid form, for example as a perfume oil, solution in a suitable solvent or as a slurry of perfume capsules in a typically hydrous solvent.
  • "Liquid” as used in this context means liquid under the conditions of use, preferably at 20 ° C liquid.
  • the at least one perfume is a substantially “dry", i. largely anhydrous component. According to some
  • the method described herein is characterized in that the at least one perfume in the form of perfume capsules and / or perfume oils is used.
  • the dyes are also preferably used in liquid form, for example in the form of an aqueous solution or slurry.
  • aqueous solution or slurry In addition to water, the appropriate
  • Dye formulations also contain organic solvents, in particular polyols.
  • the melt dispersion obtained in step ii) is converted to obtain solid fused bodies. For example, via the above-mentioned opening, which allows the outlet of the melt dispersion produced in step ii) from the following container, the produced melt is fed to the forming.
  • the transformation of the melt obtained after step ii) can be carried out by customary shaping processes. Suitable methods of forming are known to those skilled in the art and involve cooling the melt to a temperature which is below the melting temperature of the support material, so that the melt solidifies and / or then obtains its final shape. Examples include pastillation, dripping, flashing, casting followed by
  • step iii) takes place by means of a cooling belt.
  • a corresponding preferred method comprises the following steps:
  • a melt dispersion comprising at least one water-soluble or water-dispersible melted carrier material having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion of step i) with at least one esthetic, wherein (1) the melt dispersion is transferred to a subsequent container and mixed therein with at least one esthetic, or (2) the at least one esthetics continuously into the outlet stream of the first Container is admixed;
  • step i) solidifying the droplets of the mixture on the steel strip to form solid bodies, characterized in that in step i) a gas is incorporated into the molten carrier material and / or the melt dispersion.
  • the melt dispersion prepared in step i) is discharged by means of a pipeline from the first container and fed to the drop former.
  • the at least one esthetic be continuously introduced into the outflow stream of the first container by means of a further pipeline from a corresponding storage container.
  • a liquid preparation of the aesthetics for example in the form of a solution. The temperature of the esthetic or the liquid
  • Preparation of the esthetics is preferably at least 10 ° C., preferably at least 20 ° C., and in particular at least 30 ° C. below the temperature of the melt dispersion forming the outlet stream, prior to introduction into the outlet stream of the first container. It is further preferred, after the introduction of the esthetic into the melt dispersion, to mix the resulting mixture in the pipeline. Preferably, the mixing takes place by means of a static mixer, which in the pipeline in the flow direction of
  • Melt dispersion is located behind the entry point of the Aesthetic and before the point of entry of the mixture into the drop former.
  • Melt dispersion is preferably at least 10 times, preferably at least 20 times and in particular at least 50 times the diameter of the pipeline.
  • the distance between the end of the static mixer and the point of entry of the pipeline into the drop former is less than 500 times, preferably less than 200 times and in particular less than 100 times the diameter of the pipeline.
  • the diameter of the pipeline whose internal diameter is considered without taking into account the wall thickness.
  • Drop former with rotating, perforated outer drum The portion of the tubing that is within the drum of the drop former is referred to below as a supply channel for distinction from the previous tubing.
  • the feed channel extends
  • the introduced into the feed channel mixture exits from the feed channel preferably located at the bottom of the feed channel bores from the feed channel on a distributor or nozzle bar, which in turn rests against the inside of the rotating, perforated outer drum.
  • the mixture passes through the distributor or nozzle bar and is subsequently discharged from the holes of the rotating outer drum to a steel band located below these holes.
  • the distance between the outside of the rotating perforated outer drum and the surface of the steel strip is preferably between 5 and 20 mm.
  • a further mixer can be arranged in the feed channel.
  • This is preferably a dynamic mixer, for example a helix arranged rotatably within the feed channel.
  • Mixture of melt dispersion and aesthetics in the pipeline to the exit from the rotating, perforated outer drum of the drop former preferably less than 20 seconds, more preferably less than 10 seconds and in particular between 0.5 and 5 seconds.
  • External drum is preferably between 1000 and 10000 mPas.
  • the droplets of the mixture discharged from the drop former are solidified into solid melt bodies.
  • the period of time between the dropping of the mixture on the steel strip and the complete solidification of the mixture is preferably between 5 and 60 seconds, more preferably between 10 and 50 seconds and in particular between 20 and 40 seconds.
  • the solidification of the mixture is preferably supported by a cooling and
  • the cooling of the drops applied to the steel strip can be direct or indirect.
  • direct cooling for example, cooling by means of cold air can be used.
  • the indirect cooling of the drops by cooling the underside of the steel strip by means of cold water.
  • the carrier material suitable for use in a method as described herein may be any carrier material commonly used in the art for the purposes of making perfume pastilles.
  • the at least one carrier material may be a water-soluble or water-dispersible
  • Carrier polymer the specified melting temperature of> 30 ° C
  • the method described herein is characterized in that the at least one carrier material is selected from water-soluble or water-dispersible carrier polymers having a melting point of> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols , particularly preferably polyethylene glycol.
  • the at least one carrier polymer is characterized in that it has a melting point of 48 ° C to 120 ° C, preferably from 48 ° C to 80 ° C.
  • “Water-soluble”, and “wasserdipsergierbar” have the meanings given above.
  • the at least one carrier polymer is selected from polyalkylene glycols.
  • those polyalkylene glycols are suitable which have an average molecular weight (M n ) of> 1000 g / mol, in particular> 1500 g / mol, preferably a middle one Molecular weight between 3,000 and 15,000, more preferably having an average molecular weight between 4,000 and 13,000, more preferably having an average molecular weight between 4,000 and 6,000, 6,000 and 8,000 or 9,000 and 12,000, and most preferably between about 4,000 and about 6,000 g / mole.
  • M n average molecular weight
  • polyalkyl glycols are suitable which have a melting point between 40 ° C and 90 ° C, in particular in the range of 45 to 70 ° C.
  • polyalkylene glycols useful in the context of the present invention are polypropylene glycol and polyethylene glycol.
  • the at least one carrier polymer is preferably polyethylene glycol.
  • the at least one carrier polymer is a polyethylene glycol having an average molecular weight (M n) of> 1500 g / mol, preferably an average molecular weight from 3000 to 15,000, more preferably having an average molecular weight from 4000 to 13,000, more preferably has an average molecular weight between 4,000 and 6,000, 6,000 and 8,000 or 9,000 and 12,000, and most preferably from about 4,000 or about 6,000 g / mol.
  • such a polyethylene glycol is characterized by a melting point in the range of 45 to 70 ° C, preferably 50 to 65 ° C, more preferably 50 to 60 ° C.
  • “About” or “approximately” as used herein in connection with Numerical value means the numerical value ⁇ 10%, preferably ⁇ 5%.
  • a molecular weight of about 6000 g / mol thus means 5400-6600 g / mol, preferably 5700-6300 g / mol.
  • the at least one carrier polymer is employed in an amount such that the resulting fusible body, i. the perfume pastille contains from 30 to 95% by weight, preferably from 35 to 85% by weight, for example 40 to 80 or 40 to 78% by weight, based on the total weight of the fusible body of the carrier polymer.
  • specific carrier salts may also be used. These specific salts are, in particular, water-containing salts whose partial pressure of water vapor has a certain value Temperature in the range of 30 to 100 ° C corresponds to the hhO partial pressure of the saturated solution of this salt.
  • the fuser as described herein is prepared from a solution of the carrier material in the water / water of crystallization contained in the composition, and for such a solution, the term “melt” is also used to refer to the state to designate, in which the carrier material dissolves by the elimination of water in its own water of crystallization and thus forms a liquid.
  • the term “melt” as used herein thus refers to the liquid state of the composition which results when the temperature is exceeded at which the support material splits off water of crystallization and then dissolves in the water contained in the composition.
  • the corresponding dispersion containing the herein described (solid) substances dispersed in the melt of the carrier material is thus also the subject of the invention. So if in the
  • a preferred support material is characterized in that it is selected from hydrous salts whose water vapor partial pressure at a temperature in the range of 30 to 100 ° C corresponds to the FLO partial pressure of the saturated solution of this salt at the same temperature. This results in the corresponding hydrous salt, also referred to herein as a "hydrate", reaching or exceeding that temperature in its own state
  • the support materials of the invention exhibit this behavior at a temperature in the range of 40 to 90 ° C, more preferably between 50 and 85 ° C, even more preferably between 55 and 80 ° C.
  • the water-soluble carrier materials from the group of hydrous salts described above include in particular the sodium acetate trihydrate (Na (CH 3 COO) 3H 2 O), the Glauber salt (Na 2 SO 4 IOH 2 O) and the trisodium phosphate dodecahydrate (Na 3 PO 4 12 H 2 O).
  • a particularly suitable hydrate is sodium acetate trihydrate (Na (CH 3 COO) 3H 2 O), since it dissolves in its own water of crystallization in the particularly preferred temperature range of 55 to 80 ° C, concretely at about 58 ° C.
  • the sodium acetate trihydrate can be used directly as such, but it is alternatively possible to use anhydrous sodium acetate in combination with free water, the trihydrate then forming in situ.
  • the amount of water is in less than or more than stoichiometric amount relative to the amount necessary to convert all of the sodium acetate to sodium acetate trihydrate.
  • compositions means that when (anhydrous) sodium acetate is used alone or in combination with a hydrate thereof, preferably the trihydrate, water is also used, the amount of water being at least equal to the amount stoichiometrically necessary to ensure that at least 60% by weight of the
  • Total amount of sodium acetate and its hydrates preferably at least 70 wt .-%, more preferably at least 80 wt .-%, even more preferably at least 90 wt .-%, most preferably at least 100 wt .-%, in the form of sodium acetate trihydrate is present.
  • the amount of water exceeds the amount that would theoretically be necessary to convert all of the sodium acetate to the corresponding trihydrate. This means, for example, that a composition containing 50% by weight of anhydrous sodium acetate and no hydrate thereof, at least 19.8% by weight of water (60% of 33% by weight, which would theoretically be necessary to remove all of the sodium acetate into the trihydrate).
  • the two particularly preferred support materials are polyethylene glycol and sodium acetate.
  • a first particularly preferred method comprises the following steps:
  • water-dispersible molten polyethylene glycol having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion from step i) with at least one perfume, wherein (1) the melt dispersion is transferred to a subsequent container and in this with or at least one fragrance is continuously mixed into the effluent stream of the first container;
  • step i) solidifying the droplets of the mixture on the steel strip to form solid bodies, characterized in that in step i) a gas is incorporated into the molten carrier material and / or the melt dispersion.
  • a second particularly preferred method comprises the following steps:
  • step ii) mixing the melt dispersion from step i) with at least one perfume, wherein (1) the melt dispersion is transferred to a subsequent container and mixed therein with at least one perfume, or (2) the at least one perfume continuously into the outlet stream of the first Container is admixed;
  • step i) solidifying the droplets of the mixture on the steel strip to form solid bodies, characterized in that in step i) a gas is incorporated into the molten carrier material and / or the melt dispersion.
  • the melt dispersion to be produced in step i) comprises at least one solid, for example a filler.
  • the first container for this purpose is preceded by at least one screening device, which passes through the at least one solid before entering the first container is introduced. Consequently, according to some embodiments, the method described herein is characterized in that the at least one solid in step i) preceding step b) passes through at least one screening device. According to some embodiments, the method described herein is characterized in that the at least one solid is selected from the group consisting of
  • Polysaccharides such as starch, in particular maize starch, silicic acids, such as pyrogenic silicic acid, silicates, in particular alkali metal silicates, sulphates, in particular alkali metal sulphates, such as
  • Pentakaliumtriphosphat, halides and carbonates especially alkali metal carbonates, such as sodium carbonate.
  • the at least one solid may be used in an amount of 0.01 to 30% by weight, preferably 1 to 20% by weight, based on the total weight of the fused bodies.
  • the at least a solid has a melting temperature which is above the melting temperature of the carrier material and the temperature prevailing in the described process so as to provide a melt dispersion.
  • Melting temperature of the respective carrier material has. Since the fragrance and color component is temperature sensitive, a low residence time at elevated temperatures can improve the fragrance and color quality of said component, thereby providing a superior end product. According to the present method, this advantage is ensured by the fragrance and / or color component comes into contact with the molten material only immediately before the forming.
  • the method described herein is further characterized in that by mixing the subsequent container or conduit in which the melt dispersion prepared in step i) is mixed with the at least one esthetic (and optionally further components) has comparatively small capacity.
  • the at least one esthetic and optionally further components
  • volume volume if its capacity volume is a maximum of 1500 I, preferably a maximum of 1300 I, especially a maximum of 1000 I, most preferably a maximum of 200 I measures.
  • the method described herein is characterized in that the container from step ii) is a static or dynamic mixer with a capacity of ⁇ 200 l or a stirred tank with a capacity of ⁇ 1200 l.
  • Another component of the enamel bodies prepared as described herein is at least one esthetic.
  • Preferred aesthetics are the fragrances and dyes.
  • a fragrance is an odor-causing chemical substance.
  • the chemical substance should be at least partially redistributable in the air, ie the fragrance should be volatile at 25 ° C, at least to a small extent. If the fragrance is now very volatile, the odor intensity then quickly decreases again. At a lower volatility, the smell impression is more sustainable, ie it does not disappear so quickly.
  • the perfume has a melting point in the range of -100 ° C to 100 ° C, preferably from -80 ° C to 80 ° C, more preferably from -20 ° C to 50 ° C, especially of 30 ° C to 20 ° C.
  • the perfume a boiling point in the range of 25 ° C to 400 ° C, preferably from 50 ° C to 380 ° C, more preferably from 75 ° C to 350 ° C, in particular from 100 ° C to 330 ° C.
  • the fragrance has a molecular weight of 40 to 700 g / mol, more preferably 60 to 400 g / mol.
  • fragrance The smell of a fragrance is perceived by most people as pleasant and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses and roots. Thus, fragrances can also be used to superimpose unpleasant odors or even to provide a non-smelling substance with a desired odor.
  • perfumes individual perfume compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and type
  • Hydrocarbons are used.
  • Fragrance compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3- (4-isopropyl-phenyl) -2-methylpropanal), ethylvanillin, florhydral ( 3- (3-isopropylphenyl) butanal), helional (3- (3,4-methylenedioxyphenyl) -2-methylpropanal), heliotropin, hydroxycitronellal, lauraldehyde, lyral (3- and 4- (4-hydroxy-4-methylpentyl) - 3-cyclohexene-1-carboxaldehyde), methylnonylacetaldehyde, lilial (3- (4-tert-butylphenyl) -2-methylpropanal), phenylacetaldehyde, undecylenealdehyde, vanill
  • Ketone-type perfume compounds are, for example, methyl-beta-naphthyl ketone, muskedanone-1-one (2,3,3,6,7-hexahydro-1,1,3,3,3-pentamethyl-4H-inden-4-one), Tonalid (6-acetyl-1,1,1,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso-damascone, damascenone, methyldihydrojasmonate, menthone, carvone, camphor, koavon (3 , 4, 5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta-ionone, gamma-methyl-ionone, fleuramon (2-heptylcyclopentanone), dihydrojasmon, cis-jasmone , Iso-E-Super (1
  • Fragrance compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butycyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenylpentanol, 3-octanol, 3-phenyl-propanol, 4-heptenol, 4-isopropylcyclohexanol, 4-tert-butycyclohexanol, 6 , 8-dimethyl-2-nonanol, 6-nonene-1-ol, 9-decen-1-ol, a-methylbenzyl alcohol, a-terpineol, Amyl salicylate, benzyl alcohol, benzyl salicylate, ⁇ -terpineol, butyl sal
  • Fragrance type ester compounds are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate,
  • DMBCA dimethylbenzylcarbinylacetate
  • Ethers include, for example, benzyl ethyl ether and ambroxan.
  • Hydrocarbons mainly include terpenes such as limonene and pinene.
  • perfume oils may also contain natural perfume mixtures as are available from plant sources.
  • Fragrances of plant origin include essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champacilla oil, citrus oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurdy balm oil, helichrysum oil, Ho oil , Ginger oil, iris oil, jasmin oil, cajeput oil,
  • Methyl anthranilate p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-beta-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muscone, beta-naphthol ethyl ether, beta-naphthol methyl ether, nerol, n-nonyl aldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, beta-phenylethyl alcohol, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, sandelice, skatole, terpine
  • Cinnamic acid ethyl ester Cinnamic acid ethyl ester, cinnamic acid benzyl ester, diphenyloxide, limonene, linalool, linalyl acetate and propionate, melusate, menthol, menthone, methyl-n-heptenone, pinene, phenylacetaldehyde,
  • the perfume is used as a perfume precursor or in encapsulated form (perfume capsules), especially in microcapsules.
  • the microcapsules may be water-soluble and / or water-insoluble microcapsules.
  • melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used.
  • Perfume precursor refers to compounds that undergo chemical conversion / cleavage, typically by the action of light or other environmental conditions, such as pH, temperature, etc., release the actual fragrance. Such compounds are often referred to as fragrance storage or "pro-fragrance".
  • the amount of perfume in the enamel composition prepared as described herein is preferably between 1 to 20% by weight, preferably 1 to 15% by weight, especially 3 to 10% by weight. %, based on the total weight of the enamel composition.
  • a fused-state composition made in accordance with the present invention may contain at least one dye to enhance the aesthetic appeal of the fuser composition.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, should have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • the dye is a common dye that can be used for different detergents or cleaners.
  • the dye is selected from Acid Red 18 (CI 16255), Acid Red 26, Acid Red 27, Acid Red 33, Acid Red 51, Acid Red 87, Acid Red 88, Acid Red 92,
  • Particularly preferred dyes are water-soluble acid dyes, for example, Food Yellow 13 (Acid Yellow 3, CI 47005), Food Yellow 4 (Acid Yellow 23, CI 19140), Food Red 7 (Acid Red 18, CI 16255), Food Blue 2 (Acid Blue 9, CI 42090), Food Blue 5 (Acid Blue 3, CI 42051), Acid Red 249 (CI 18134), Acid Red 52 (CI 45100), Acid Violet 126, Acid Violet 48, Acid Blue 80 (01 61585), Acid Blue 182, Acid Blue 182, Acid Green 25 (CI 61570), Acid Green 81.
  • Food Yellow 13 Acid Yellow 3, CI 47005
  • Food Yellow 4 Acid Yellow 23, CI 19140
  • Food Red 7 Acid Red 18, CI 16255
  • Food Blue 2 Acid Blue 9, CI 42090
  • Food Blue 5 Acid Blue 3, CI 42051
  • Acid Red 249 CI 18134
  • Acid Red 52 CI 45100
  • Acid Violet 126 Acid Violet 48
  • Acid Blue 80 01 61585
  • Acid Blue 182 Acid Blue
  • water-soluble direct dyes for example Direct Yellow 28 (CI 19555), Direct Blue 199 (CI 74190) and water-soluble reactive dyes, for example Reactive Green 12, and the dyes Food Yellow 3 (CI 15985), Acid Yellow 184.
  • aqueous dispersions of the following pigment dyes Pigment Black 7 (CI 77266), Pigment Blue 15 (CI 74160), Pigment Blue 15: 1 (CI 74160), Pigment Blue 15: 3 (CI 74160), Pigment Green 7 (CI 74260), Pigment Orange 5, Pigment Red 1 12 (CI 12370), Pigment Red 1 12 (CI 12370), Pigment Red 122 (CI 73915), Pigment Red 179 (CI 71 130), Pigment Red 184 (CI 12487 Pigment Red 188 (CI 12467), Pigment Red 4 (CI 12085), Pigment Red 5 (CI 12490), Pigment Red 9, Pigment Violet 23 (CI 51319), Pigment Yellow 1 (CI 28 1 1680), Pigment Yellow 13 (CI 21,100), Pigment Yellow 154, Pigment Yellow 3 (CI 1 1710), Pigment Yellow 74, Pigment Yellow 83 (CI 21 108), Pigment Yellow 97.
  • pigment dyes Pigment Black 7 (CI 77266), Pigment Blue 15 (CI 74160), Pigment Blue
  • the following pigment dyes are used in the form of dispersions: Pigment Yellow 1 (CI 1 1680), Pigment Yellow 3 (CI 1 1710), Pigment Red 1 12 (CI 12370), Pigment Red 5 (CI 12490), Pigment Red 181 (CI 73360), Pigment Violet 23 (CI 51319), Pigment Blue 15: 1 ( CI 74160), Pigment Green 7 (CI 74260), Pigment Black 7 (CI 77266).
  • water-soluble polymer dyes are used, for example Liquitint, Liquitint Blue HP, Liquitint Blue MC, Liquitint Blue 65, Liquitint Cyan 15, Liquitint Patent Blue, Liquitint Violet 129, Liquitint Royal Blue, Liquitint Experimental Yellow 8949-43, Liquitint Green HMC, Liquitint Yellow LP, Liquitint Yellow II and mixtures thereof.
  • Polymer dyes are very particularly preferably used.
  • the most preferred dyes include Acid Blue 3, Acid Yellow 23, Acid Red 33, Acid Violet 126, Liquitint Yellow LP, Liquitint Cyan 15, Liquitint Blue HP and Liquitint Blue MC.
  • the proportion by weight of the dye in the melted body composition is preferably 0.001 to 0.5% by weight, preferably 0.002 to 0.2% by weight.
  • Both the melt dispersion to be prepared in step i) and in step ii) may, in addition to the components already mentioned, comprise further ingredients. Suitable additional
  • Ingredients may, for example and without limitation, be selected from the group consisting of fillers, pearlescers, skin care compounds, fabric care compounds and bittering agents.
  • the process described herein is characterized in that the fabric care compound is selected from fabric softening compounds, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors,
  • Inlet preventer Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, and
  • Active substances germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, repellents and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.
  • the method described herein is characterized in that the fabric care compound is a fabric softening compound, preferably selected from polysiloxanes, fabric softening clays, cationic polymers, and mixtures thereof.
  • the melted body composition prepared as described herein may further comprise at least one fabric conditioning compound.
  • at least one fabric conditioning compound is used in this
  • Conditioning and / or wearing may occur, such as fading, graying, etc., reduced.
  • the fabric care composition may preferably be made of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof are selected.
  • the fabric care compound is a fabric softening compound. It is very particularly preferred that the textile-softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
  • polysiloxanes and / or cationic polymers as a fabric care compound in the fuser composition is advantageous because it not only exhibits a softening effect but also enhances the perfume impression on the wash.
  • softening clays as textile-care compound in the melted body composition is advantageous because they additionally have a water-softening effect and thus, for example, limescale deposits on the laundry can be prevented.
  • a fused article composition contains a combination of at least two textile care compounds.
  • the fused-state composition prepared according to the invention contains such textile-care compounds, it is used in particular as a textile care agent or softener or as a constituent of such an agent or else as a constituent of a detergent.
  • Such a fabric conditioner may be in the main wash of an automatic washing or
  • the fused-state composition may, for example, be introduced into the drum together with the washing or cleaning agent
  • a solid fused-state composition prepared as described herein can be used in the wash cycle of a laundry cleaning process and thus already transport the textile-care compound and the perfume directly to the laundry at the beginning of the washing process in order to be able to develop their full potential. Furthermore, this is fixed
  • a preferably usable polysiloxane has at least the following structural unit With
  • R 1 independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
  • n 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
  • polysiloxane additionally has the following structural unit:
  • R 1 C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
  • R 2 , R 3 independently of one another are H or optionally substituted, linear or branched C 1 -C 30 -alkyl, preferably C 1 -C 30 -alkyl which is substituted by amino groups, especially
  • x 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
  • Polydimethylpolysiloxanes are known as efficient fabric care compounds.
  • Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
  • polysiloxane contains the structural units a) and b).
  • a particularly preferred polysiloxane has the following structure:
  • Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
  • a suitable fabric softening clay is, for example, a smectite clay.
  • Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
  • Montmorillonite clays are the preferred softening clays.
  • Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay. The bentonites can be used as powder or crystals.
  • Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa. It is preferable that the textile care composition contains a powdery bentonite as a fabric care compound.
  • Suitable cationic polymers are under the collective name
  • Polyquaternium are summarized. The following is a list of some suitable polyquaternium compounds.
  • Celquat® H 100 or Celquat® L200 available as Celquat® H 100 or Celquat® L200 (ex National Starch)
  • POLYQUATERNIUM-6 (CAS number: 26062-79-3) Definition: Polymer of dimethyldiallylammonium chloride POLYQUATERNIUM-7 (CAS number: 26590-05-6)
  • Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
  • Quaternary ammonium polymer salt obtainable by reaction of the ethyl methacrylate / -abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
  • POLYQUATERNIUM-17 (CAS number: 90624-75-2) Definition: Polymeric quaternary ammonium salt obtainable by reaction of adipic acid and dimethylaminopropylamine with dichloroethyl ether.
  • Polymeric quaternary ammonium salt which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
  • Polymeric quaternary ammonium salt which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
  • Polymeric quaternary ammonium salt obtainable by reaction of polyvinyl octadecyl ether with 2,3-epoxypropylamine.
  • Synthalen® CR (ex 3V Sigma)
  • the fuser composition may include a fabric softening compound and one or more other fabric care compounds.
  • the amount of fabric care compound in the fuser composition may, in various embodiments, be from 0.1 to 15 weight percent, and preferably between 0.5 and 12 weight percent.
  • a textile-care compound is bentonite.
  • the fuser composition may optionally contain other ingredients.
  • it may contain additional ingredients, preferably selected from the group consisting of pearlescing agents, skin-care compounds, bittering agents and mixtures thereof.
  • the enamel composition may contain a pearlescent agent to increase gloss.
  • suitable pearlescing agents are ethylene glycol mono- and distearate and PEG-3-distearate.
  • the enamel composition may comprise a skin care compound.
  • a skin-care compound is understood as meaning a compound or a mixture of compounds which, upon contact of a textile with the detergent, draw on the textile and give an advantage on contact of the textile with skin of the skin compared to a textile which does not interfere with the enamel body of the invention. Composition was treated. This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
  • the skin care composition is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care, make-up composition.
  • the skin care compound may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care, make-up composition.
  • the skin care compound may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care, make-up composition.
  • the skin care compound may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care, make-up composition.
  • waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
  • Plant extracts for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
  • vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof
  • higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids
  • higher fatty alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol,
  • esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate,
  • Cholesterol isostearate glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
  • hydrocarbons such as paraffins, mineral oils, squalane or squalene
  • vitamins such as vitamins A, C or E or vitamin alkyl esters
  • sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
  • silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
  • the amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and most preferably between 0.3 and 3 Wt .-% based on the solid enamel composition. It may be that the skin care compound also has a textile care effect.
  • this may contain a bittering agent such as Bitrex®.
  • composition of some preferred compositions prepared by the method described above can be seen from the following tables (% by weight based on the total weight of the composition unless otherwise specified).
  • the melting body in addition to the support material, the at least one solid, the at least one aesthetic, no further compounds in appreciable amount (ie in amounts> 1 wt .-% based on the
  • Another object of the present invention is a perfume or dye-containing fusible article, which was prepared by a method as described herein.
  • a particular advantage of such a fuser body is the improved fragrance or color quality resulting from a comparatively short residence time of the fragrant or color component at elevated temperatures, i. Temperatures according to the melting temperature of the respective
  • Carrier material is guaranteed.
  • the main component of the fusible bodies prepared as described herein is at least one water-soluble or water-dispersible carrier material, as already described above.
  • the aesthetics-containing fused bodies prepared according to a method as described herein are fusible bodies which are solid at room temperature and temperatures up to 30 ° C, preferably up to 40 ° C.
  • the invention also relates to the use of the enamel body produced as described herein as a fabric care agent, preferably fragrancing and / or fabric softener, for scenting and / or conditioning of textile fabrics.
  • the enamel bodies may be a textile treatment agent, such as, for example, a fabric softener or a part of such an agent.
  • the invention relates to a washing or cleaning agent comprising the fused bodies according to the invention.
  • the inventively produced enamel body in a detergent or cleaning agent is the consumer a textile care washing or cleaning agent ("2in1" washing or cleaning agent) available and he does not need to dose two agents and no separate rinse. Since the enamel bodies produced according to the invention are perfume-containing, the detergent or cleaning agent does not have to be perfumed. Not only does this result in lower costs, it is also beneficial for consumers with sensitive skin and / or allergies.
  • fused bodies described herein are particularly suitable for conditioning textile fabrics and are used together with a conventional washing or
  • a solid detergent or cleaning agent may preferably be mixed with from 1 to 20% by weight, in particular from 5 to 15% by weight, of the enamel body composition according to the invention.
  • a process for preparing perfume-containing fusible articles comprising the steps of: i) preparing a melt dispersion comprising at least one water-soluble or water-dispersible melted carrier material having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion of step i) with at least one esthetic; and iii) transforming the mixture obtained in step ii) to obtain solid fused articles, characterized in that in step i) a gas is incorporated into the molten carrier material and / or the melt dispersion.
  • a process for the preparation of perfume-containing enamel bodies according to item 1, comprising the following steps:
  • a melt dispersion comprising at least one water-soluble or water-dispersible melted carrier material having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion of step i) with at least one esthetic, wherein (1) the melt dispersion is transferred to a subsequent container and mixed therein with at least one esthetic, or (2) the at least one esthetics continuously into the outlet stream of the first Container is admixed;
  • step iii) forming the mixture obtained in step ii) to obtain solid fusible materials, characterized in that in step i) in the molten carrier material and / or the melt dispersion, a gas is incorporated.
  • a melt dispersion comprising at least one water-soluble or water-dispersible melted carrier material having a melting temperature of> 30 ° C as a continuous phase and at least one solid as a disperse phase in a first container;
  • step ii) mixing the melt dispersion of step i) with at least one esthetic, wherein (1) the melt dispersion is transferred to a subsequent container and mixed therein with at least one esthetic, or (2) the at least one esthetics continuously into the outlet stream of the first Container is admixed;
  • step i) solidifying the droplets of the mixture on the steel strip to form solid bodies, characterized in that in step i) a gas is incorporated into the molten carrier material and / or the melt dispersion.
  • Begasungsrlickwerk, Leitstrahlrlickwerk, propeller stirrer, blade stirrer, preferably from the group Dissolver, aeration agitators and Leitstrahlrlickwerk is used.
  • step i) The method according to any one of items 4 or 5, wherein the molten carrier material and / or the melt dispersion in step i) is stirred in a manner which causes the formation of a trombe in the melt.
  • step i) upstream step b) passes through at least one screening device.
  • Carrier material preferably a polyethylene glycol is used.
  • Carrier material is used in an amount such that the resulting fusible body has a weight fraction of Toopolmyers of 30 to 95 wt .-%, preferably from 35 to 85 wt .-% and in particular from 40 to 78 wt .-%.
  • the at least one solid is selected from the group consisting of polysaccharides, silicas, silicates, sulfates, phosphates, halides, and carbonates.
  • Melt dispersion further at least one further component selected from the group consisting of pearlescers, skin care compounds, fabric care compounds and bittering agents.
  • a dye preferably a water-soluble dye, particularly preferably a water-soluble polymer dye is used as aesthetics.
  • waste material which is obtained after step ii), in step i) or ii), preferably in step i) is recycled.
  • Pore volume between 0.5 and 50 vol .-%, preferably between 1 and 20 vol .-%, more preferably between 2 and 15 vol .-% and most preferably between 4 and 12 vol .-%. 26.
  • washing or cleaning agent comprising an aesthetic-containing enamel body according to item 23.

Abstract

La présente invention concerne un procédé de fabrication de corps fusibles esthétiques, consistant à produire une dispersion fusible renfermant au moins une matière de support soluble ou dispersible dans l'eau et au moins une matière solide dans un premier récipient ; à mélanger la dispersion fusible ainsi obtenue avec au moins élément esthétique et à déformer la dispersion fusible ainsi obtenue, de manière à obtenir un corps fusible contenant un élément esthétique. La présente invention concerne également les corps fusibles fabriqués selon ce procédé, un agent détergent ou nettoyant les contenant, l'utilisation d'un tel agent détergent ou nettoyant pour le nettoyage de textiles ou de surfaces dures, ainsi que des procédés correspondants de nettoyage de textiles ou de surfaces dures par utilisation d'un tel agent détergent ou nettoyant.
PCT/EP2018/081295 2017-12-18 2018-11-15 Fabrication de corps fusibles contenant un parfum WO2019120779A1 (fr)

Applications Claiming Priority (2)

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DE102017222994.2 2017-12-18
DE102017222994.2A DE102017222994A1 (de) 2017-12-18 2017-12-18 Herstellung parfümhaltiger Schmelzkörper

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WO2019120779A1 true WO2019120779A1 (fr) 2019-06-27

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016205586A1 (fr) 2015-06-19 2016-12-22 The Procter & Gamble Company Appareil et procédé de formation de particules
US20170114304A1 (en) * 2015-10-23 2017-04-27 The Procter & Gamble Company Packaged composition
WO2018026622A1 (fr) * 2016-08-03 2018-02-08 Henkel IP & Holding GmbH Pastille parfumée pour application de blanchisserie
WO2018129491A1 (fr) * 2017-01-09 2018-07-12 The Procter & Gamble Company Particules de parfum de blanchisserie

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016205586A1 (fr) 2015-06-19 2016-12-22 The Procter & Gamble Company Appareil et procédé de formation de particules
US20170114304A1 (en) * 2015-10-23 2017-04-27 The Procter & Gamble Company Packaged composition
WO2018026622A1 (fr) * 2016-08-03 2018-02-08 Henkel IP & Holding GmbH Pastille parfumée pour application de blanchisserie
WO2018129491A1 (fr) * 2017-01-09 2018-07-12 The Procter & Gamble Company Particules de parfum de blanchisserie

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