WO2019120678A1 - Procédé de fabrication de perles parfumées sphériques - Google Patents
Procédé de fabrication de perles parfumées sphériques Download PDFInfo
- Publication number
- WO2019120678A1 WO2019120678A1 PCT/EP2018/078048 EP2018078048W WO2019120678A1 WO 2019120678 A1 WO2019120678 A1 WO 2019120678A1 EP 2018078048 W EP2018078048 W EP 2018078048W WO 2019120678 A1 WO2019120678 A1 WO 2019120678A1
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- Prior art keywords
- oil
- melt
- particles
- fragrance
- container
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
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- 239000011049 pearl Substances 0.000 description 1
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- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
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- 239000004014 plasticizer Substances 0.000 description 1
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- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000010491 poppyseed oil Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000008171 pumpkin seed oil Substances 0.000 description 1
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- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
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- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
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- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
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- 230000000475 sunscreen effect Effects 0.000 description 1
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- 230000008961 swelling Effects 0.000 description 1
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- 229940116411 terpineol Drugs 0.000 description 1
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- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
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- 239000010678 thyme oil Substances 0.000 description 1
- MBDOYVRWFFCFHM-UHFFFAOYSA-N trans-2-hexenal Natural products CCCC=CC=O MBDOYVRWFFCFHM-UHFFFAOYSA-N 0.000 description 1
- DKZBBWMURDFHNE-UHFFFAOYSA-N trans-coniferylaldehyde Natural products COC1=CC(C=CC=O)=CC=C1O DKZBBWMURDFHNE-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- USFMMZYROHDWPJ-UHFFFAOYSA-N trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound CC(=C)C(=O)OCC[N+](C)(C)C USFMMZYROHDWPJ-UHFFFAOYSA-N 0.000 description 1
- ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- WJUFSDZVCOTFON-UHFFFAOYSA-N veratraldehyde Chemical compound COC1=CC=C(C=O)C=C1OC WJUFSDZVCOTFON-UHFFFAOYSA-N 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
Definitions
- the present invention relates to a process for the preparation of spherical fragrance particles, the fragrance particles thus obtained, as well as their use for fragrancing objects, in particular textile fabrics.
- the consumer In the use of detergents and cleaners, the consumer not only aims to wash, cleanse or care for the objects to be treated, but also desires that the treated objects, such as textiles, after treatment, for example after washing, smell pleasant. For this reason in particular, most commercially available detergents and cleaners contain fragrances. Most fragrances, however, are volatile. For this reason, when using conventional washing or cleaning agents after use, especially after washing, only a small proportion of the fragrance used remains on the treated object. As a result, often only a faint scent of the treated object, especially the laundry, goes out, which then already weaker after a short time. Thus, the pleasant feeling of freshness of the treated object disappears after a short time.
- fragrances are used in the form of perfume particles either as an integral part of a washing or cleaning agent, or dosed directly into the washing drum at the beginning of a wash cycle in a separate form. In this way, the consumer can control the fragrance of the laundry to be washed by individual dosage.
- fragrance particles are usually provided in the form of fragrance-containing enamel bodies.
- the at least one carrier polymer ie usually the at least one carrier polymer.
- fragrance particles which can be produced by such known processes, which usually have a lens shape, are described, for example, in European Patent EP 2 496 679 B1.
- fragrance particles in a spherical or at least approximately spherical shape, ie in spherical form, are particularly aesthetically pleasing. These are not only visually appealing, but can also be dosed well and simply.
- the object of the present invention is therefore to provide a method for producing spherical fragrance particles. Surprisingly, it has been shown that spherical fragrance particles can be obtained by dropping a melt into a cooling bath.
- the object underlying the present invention is therefore achieved by a process for preparing water-soluble spherical fragrance particles comprising: a) producing a melt, comprising at least one carrier and at least one fragrance and subsequent
- Drip methods are known from other fields of technology, such as pharmacy.
- a melt which comprises a carrier and at least one perfume has not yet been described with regard to dripping methods for the production of fragrance particles in the field of textile care. It was also not to be expected that can be obtained by the inoculation of spherical fragrance particles, since due to the presence of the fragrance a pain with low viscosity at the same time the lowest possible melting temperature of the carrier or low temperature of the melt is needed.
- the present invention is directed to fragrance particles obtained by the process according to the invention.
- the present invention is directed to the use of corresponding spherical fragrance particles for fragrancing objects, in particular textile fabrics.
- At least one or “at least one” as used herein refers to 1 or more, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or more. In particular, this specification refers to the nature of the agent / compound rather than the absolute number of molecules. Thus, at least one perfume means, for example, that at least one kind of perfume is detected, but also 2.3 or more different types of perfumes may be included.
- Water-soluble as used herein means a solubility in water at 20 ° C of at least 1 g / L, preferably at least 10 g / L, more preferably at least 50 g / L.
- Water-dispersible as used herein means that the corresponding molecule can be dispersed in water at 20 ° C by known methods.
- melt body as used herein preferably refers to a solid that is water soluble or water dispersible and substantially nonporous at standard conditions (20 ° C, 1013 mbar) and obtainable by cooling from the melt dispersions or melts described herein
- melt does not necessarily mean a melt in the thermodynamic sense. So it is generally a flowable at elevated temperature mass, which goes into a solid state at ambient temperature.
- the melt comprises according to the invention at least one perfume.
- This may be an encapsulated perfume or an unencapsulated perfume, for example a free perfume oil. It is also possible according to the invention for both an encapsulated fragrance and an unencapsulated fragrance to be present in the melt and thus also in the resulting spherical fragrance particle.
- "perfume” includes both the perfume itself and perfume precursors or perfume precursors, both in encapsulated and non-encapsulated form.
- the melt may contain as perfume in a microcapsule an encapsulated perfume oil, an encapsulated perfume or an encapsulated perfume precursor or mixtures thereof.
- the microcapsules in addition to the microcapsules, it may also have a perfume or a perfume precursor or a perfume oil which is incorporated in the carrier in an unencapsulated form.
- a perfume or a perfume precursor or a perfume oil which is incorporated in the carrier in an unencapsulated form.
- a fragrance is a chemical stimulating the sense of smell.
- the chemical substance should be at least partially redistributable in the air, i. the perfume should be at least slightly volatile at 25 ° C. If the fragrance is now very volatile, the odor intensity sounds quickly again. However, with lower volatility the odor impression is more sustainable, i. he does not disappear so fast.
- the perfume has a melting point in the range of -100 ° C to 100 ° C, preferably from -80 ° C to 80 ° C, more preferably from -20 ° C to 50 ° C, especially of 30 ° C to 20 ° C.
- the perfume has a boiling point ranging from 25 ° C to 400 ° C, preferably from 50 ° C to 380 ° C, more preferably from 75 ° C to 350 ° C, especially from 100 ° C to 330 ° C is located.
- the fragrance has a molecular weight of 40 to 700 g / mol, more preferably 60 to 400 g / mol.
- fragrance The smell of a fragrance is perceived by most people as pleasant and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses and roots.
- fragrances can also be used to superimpose unpleasant odors or even to provide a non-smelling substance with a desired odor.
- individual fragrance compounds for example, the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons can be used.
- Fragrance compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3- (4-isopropyl-phenyl) -2-methylpropanal), ethylvanillin, Florhydral (3- (3-isopropylphenyl) butanal), helional (3- (3,4-methylenedioxyphenyl) -2-methylpropanal), heliotropin, hydroxycitronellal, lauraldehyde, lyral (3- and 4- (4-hydroxy-4-methyl - pentyl) -3-cyclohexene-1-carboxaldehyde), methylnonylacetaldehyde, Lilial (3- (4-tert-butylphenyl) -2-methylpropanal), phenylacetaldehyde, undecylenealdehyde, vanillin,
- ketone-type perfume compounds are methyl-beta-naphthyl ketone, musindindanone (1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-inden-4-one ), Tartalide (6-acetyl-1,1,1,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso-damascone, damascenone, methyldihydrojasmonate, menthone, carvone, camphor , Koavon (3,4,5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta-ionone, gamma-methyl-ionone, fleuramon (2-heptylcyclopentanone) , Dihydrojasmon, cis-jasmone, iso-E-Super (1- (1,
- Fragrance compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert.
- Fragrance type compounds of the ester type include, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmacyclate.
- DMBCA dimethylbenzylcarbinylacetate
- Ethers include, for example, benzyl ethyl ether and ambroxan.
- the hydrocarbons mainly include terpenes such as limonene and pinene.
- perfume oils may also contain natural perfume mixtures as are available from plant sources. Fragrances of plant origin include essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champagne blossom oil, citrus oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurdy balsam oil, helichrysum oil, Ho Oil, ginger oil, iris oil, jasmine oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine needle oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, labdanum oil
- the fragrances mentioned can be in the form of perfume microcapsules (or also perfume microcapsules) in the melt according to the invention. Likewise, said fragrances may also be present as perfume oil (free fragrance) in a preferred form in addition to the microcapsules.
- the proportion of the at least one perfume in the melt is preferably in the range of 0.1 wt .-% to 20 wt .-%, preferably 1 wt .-% to 20 wt .-%, more preferably 1 wt .-% to 15 Wt .-%, in particular 3 wt .-% to 10 wt .-%, based on the total weight of the melt or the fragrance particles.
- the microcapsules are microcapsules containing the perfume inside, ie the perfume.
- the microcapsules may be water-soluble and / or water-insoluble microcapsules.
- melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules or starch microcapsules can be used.
- the microcapsule in encapsulated form not only the perfume, so the perfume itself have. According to the invention, it can also have a scent precursor.
- Corresponding precursors or fragrance precursors are those compounds which release the actual fragrance only after chemical conversion / cleavage, typically by the action of light or other ambient conditions, such as pH, temperature, pressure or friction, etc.
- Such perfume precursors or perfume precursors may be present both in the form of the microcapsule as perfume in the agent according to the invention. Also included in the invention is that the perfume precursor is processed directly in unencapsulated form with the carriers.
- the melt further comprises at least one carrier.
- the carrier is a polymer.
- the support is preferably selected from polyethylene glycols (PEG), EO / PO block copolymers or highly alkoxylated nonionic surfactants.
- the support is a polyethylene glycol, in particular one having a molecular weight of> 4000 g / mol.
- the molecular weight is the average molar mass.
- Polyethylene glycols having an average molar mass in the range from 4000 g / mol to 15000 g / mol are particularly preferred.
- the polyethylene glycol preferably has an average molar mass in the range from 4000 to 9000, preferably in the range from 4500 to 8500, particularly preferably from 5000 to 8000, very particularly preferably from 5500 g / mol to 7000 g / mol.
- the support is an EO / PO block copolymer.
- the at least one block copolymer is characterized by having a melting point of 44 ° C to 120 ° C, preferably 44 ° C to 80 ° C.
- EO / PO block copolymers suitable according to the invention are composed of blocks of ethylene oxide (EO) and propylene oxide (PO) units.
- block copolymers of the formulas HO- (EO) x (PO) y (EO) z H, HO- (PO) x (EO) y (PO) z H, HO- (EO) x (PO) y (PO) z -H and HO- (EO) x (EO) y (PO) z -H, in which the indices x, y and z are independently an integer from 5 to 500, preferably 10 to 250, more preferably 15 to 100 are.
- the EO content in the block copolymer is greater than 50% by weight, preferably greater than 60% by weight, more preferably greater than 70% by weight, most preferably about 80% by weight .-% is.
- the molecular weight of the PO block is preferably at least 1500 g / mol, particularly preferably 1750 to 3250 g / mol. Melting temperatures typically increase with the molecular weight of the PO block and the proportion of EO.
- the block copolymers preferably have number average molecular weights (Mn) ⁇ 20,000 g / mol, preferably ⁇ 10,000 g / mol. Particular preference is given to molecular weights (Mn) in the range from 4000 g / mol to 9000 g / mol, in particular 6000 g / mol to 8000 g / mol.
- Mn number-average molecular weights
- EO-PO block copolymers having a molecular weight Mn of about 8000 g / mol, an EO content of about 80 wt.% And a molar mass of the PO block of at least 1750 g / mol.
- Such polymers are sold, for example, by the company BASF under the trade name Pluronic ®.
- Pluronic ® PE 6800 and Pluronic ® F 68 are according to the invention very particularly preferred block copolymers.
- the melts may optionally contain at least one further EO / PO block copolymer with a melting point ⁇ 40 ° C.
- the melting point is preferably in the range from 0 ° C to 40 ° C, more preferably from 20 ° C to ⁇ 40 ° C, in particular in the range from 30 ° C to ⁇ 40 ° C.
- suitable EO / PO block copolymers are having a melting point ⁇ 40 ° C are also composed of blocks of ethylene oxide (EO) - and propylene oxide (PO) units.
- block copolymers of the formulas HO- (EO) x (PO) y (EO) z -H, HO- (PO) x (EO) y (PO) z -H, HO- (EO) x (PO) y (PO) z -H and HO- (EO) x (EO) y (PO) z -H, in which the indices x, y and z are independently an integer from 5 to 500, preferably 10 to 250, still more preferably 15 to 100 are.
- the proportion of EO in the block copolymer is less than 50% by weight, preferably about 40% by weight or less.
- the molecular weight of the PO block is preferably ⁇ 3250 g / mol, for example 2750 g / mol or less.
- Corresponding block copolymers having a melting point ⁇ 40 ° C. preferably have number-average molecular weights (Mn) ⁇ 20,000 g / mol, preferably ⁇ 10,000 g / mol. Particularly preferred are molecular weights (Mn) in the range of 2000 to 8000, in particular 2000 to 6000 g / mol.
- Such polymers are also marketed by BASF under the trade name Pluro- nic ®.
- Pluronic ® PE 9400 and Pluronic ® PE 10400 are particularly preferred according to the invention block copolymers.
- the support may thus comprise an EO / PO block copolymer or consist of two or more block copolymers.
- the carrier is a highly alkoxylated nonionic surfactant.
- the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol residue is linear or preferably methyl-branched in the 2-position may be or contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten.
- EO ethylene oxide
- alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
- the preferred ethoxylated alcohols include, for example, Ci 2 -i 4 -alcohols with 3 EO or 4 EO, C9-nn-alcohol with 7 EO, C-s-alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12 Alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C12-14 alcohol with 3 EO and Ci2-is-alcohol with 5 EO.
- the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
- Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
- fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
- nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably
- the melt usually comprises the carrier in an amount of 95% by weight or less.
- the proportion of carrier is preferably in the range of 30 to 95 wt .-%, preferably from 40 to 90 wt .-%, for example 45 to 90 wt .-%, each based on the total weight of the melt or the fragrance particles.
- specific carrier salts may also be used. These specific salts are, in particular, water-containing salts whose partial pressure of water vapor at a specific temperature in the range from 30 to 100 ° C. corresponds to the hhO partial pressure of the saturated solution of this salt.
- the fragrance particles as described herein are prepared from a solution of the carrier material in the water / water of crystallization contained in the composition, and for such a solution, the term “melt” is also used to refer to the state to designate, in which the carrier material dissolves by the elimination of water in its own water of crystallization and thus forms a liquid.
- the term “melt” as used herein thus refers to the liquid state of the composition which results when the temperature is exceeded at which the support material splits off water of crystallization and then dissolves in the water contained in the composition.
- the corresponding dispersion containing the herein described (solid) substances dispersed in the melt of the carrier material is thus also the subject of the invention.
- the corresponding melt / melt dispersion from which it is obtainable is always included. Since these do not differ in composition except for the state of matter, the terms are used interchangeably herein.
- a preferred support material is characterized in that it is selected from hydrous salts whose water vapor partial pressure at a temperature in the range of 30 to 100 ° C corresponds to the FhO partial pressure of the saturated solution of this salt at the same temperature.
- the corresponding hydrous salt also referred to herein as a "hydrate” dissolves on reaching or exceeding this temperature in its own water of crystallization, thereby changing from a solid to a liquid state of matter.
- the support materials of the invention exhibit this behavior at a temperature in the range of 40 to 90 ° C, more preferably between 50 and 85 ° C, even more preferably between 55 and 80 ° C.
- the water-soluble carrier materials from the group of hydrous salts described above include in particular the sodium acetate trihydrate (Na (CH 3 COO) 3H 2 O), the Glauber salt (Na 2 SO 4 IOH 2 O) and the trisodium phosphate dodecahydrate (Na 3 PO 4 12 H 2 O).
- a particularly suitable hydrate is sodium acetate trihydrate (Na (CH 3 COO) 3H 2 O), since it dissolves in its own water of crystallization in the particularly preferred temperature range of 55 to 80 ° C, concretely at about 58 ° C.
- the sodium acetate trihydrate can be used directly as such, but it is alternatively possible to use anhydrous sodium acetate in combination with free water, the trihydrate then forming in situ.
- the amount of water used is in less than or more than stoichiometric amount, based on the amount necessary to convert all the sodium acetate to sodium acetate trihydrate, preferably in an amount of at least 60% by weight, preferably at least 70% by weight %, more preferably at least 80%, most preferably 90%, 100% or more by weight of the amount theoretically required to convert all the sodium acetate to sodium acetate trihydrate (Na (CH 3 COO ) 3H2O). Particularly preferred is the superstoichiometric use of water.
- the amount of water exceeds the amount that would theoretically be necessary to convert all of the sodium acetate to the corresponding trihydrate.
- composition containing 50% by weight of anhydrous sodium acetate and no hydrate thereof, at least 19.8% by weight of water (60% of 33% by weight, which would theoretically be necessary to remove all of the sodium acetate into the trihydrate).
- the two particularly preferred support materials are polyethylene glycol and sodium acetate trihydrate.
- the melter according to the invention may additionally contain further ingredients which can be used to adjust desired properties of the melt or of the fragrance particles produced therefrom. These substances described below can each be contained individually or in any desired combinations.
- the melt may further comprise an adsorber material for receiving a fragrance, in particular the non-encapsulated fragrance, inert fillers or auxiliaries, dyes, rheology modifiers, moisture regulators, plasticizers, surfactants or other ingredients such as textile or skin care compounds.
- melt has surfactants, these are in particular anionic surfactants, preferably alkyl sulfate, in particular C 8-12 alkyl sulfates.
- the melt may, for example, comprise one or more adsorbent materials for receiving the fragrance.
- a corresponding adsorber material can be present in amounts of up to 25% by weight, based on the total weight of the melt. The proportion is preferably in the range from 0.0% by weight to 25% by weight, in particular from 0.5% by weight to 20% by weight, preferably from 1% by weight to 15% by weight. or from 3 wt% to 10 wt%, more preferably from 5 wt% to 8 wt%.
- Suitable adsorber materials are, for example, porous inorganic substances, such as, for example, silica.
- Organic substances, such as crosslinked polymers, for example crosslinked polyvinylpyrrolidone, can also be used as the adsorbent material.
- the melt may further comprise fillers or auxiliaries, such as emulsifiers, which for example improve the processability in the preparation or the homogeneity of the distribution of the microcapsules or the perfume in the carrier.
- fillers or auxiliaries are known to the person skilled in the art.
- the melt may further comprise at least one fabric conditioning compound.
- a textile-care compound is in In this context, any compound which imparts a beneficial effect to fabrics treated therewith, such as a fabric softening effect, wrinkle resistance, or the deleterious or detrimental effects that may occur during cleaning and / or conditioning and / or wearing, such as fading , Graying, etc., reduced.
- the fabric care composition may preferably be made from fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof are selected.
- the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
- polysiloxanes and / or cationic polymers as textile-care compounds is advantageous because they not only have a softening effect, but also enhance the perfume impression on the laundry.
- softening clays as textile-care compound is also advantageous because they additionally have a water-softening effect and thus, for example, limescale deposits on the laundry can be prevented.
- a polysiloxane preferably usable as textile softening compound has at least the following structural unit
- R 1 independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
- n 1 to 5000, preferably 10 to 2500, in particular 100 to 1500. It may be preferred that the polysiloxane additionally has the following structural unit: b)
- R 1 C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
- x 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
- Polydimethylpolysiloxanes are known as efficient fabric care compounds.
- Suitable polydimethysiloxanes include DC-200 (ex Dow Coming), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone ® M 5000 (all ex GE Bayer Silicones).
- polysiloxane contains the structural units a) and b).
- a particularly preferred polysiloxane has the following structure:
- Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
- a suitable fabric softening clay is, for example, a smectite clay.
- Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, sodonite clays, sauconite clays and mixtures thereof.
- Montmorillonite clays are the preferred softening clays.
- Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay. The bentonites can be used as powder or crystals.
- Suitable bentonites are sold for example under the names Laundrosil® ® from Sud-Chemie or under the name Detercal by the company Laviosa. It is preferred that the textile-care composition contains a powdered bentonite as textile-care compound.
- Suitable cationic polymers include, in particular, those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 and collectively referred to as "Polyquaternium "Are summarized. In the following, some suitable polyquaternium compounds are listed in more detail.
- Celquat® H 100 or Celquat® L200 available as Celquat® H 100 or Celquat® L200 (ex National Starch)
- Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
- Quaternary ammonium polymer salt obtainable by reaction of the ethyl methacrylate / -abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
- Polymeric quaternary ammonium salt which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
- Polymeric quaternary ammonium salt which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
- Polymeric quaternary ammonium salt which is obtainable by reaction of polyvinyloctadecyl ether with 2,3-epoxypropylamine.
- Polyquaternium-31 (CAS number: 136505-02-7)
- Polyquaternium-32 (CAS number: 35429-19-7)
- Polyquaternium-37 (CAS number: 26161-33-1)
- Synthalen® CR (ex 3V Sigma)
- Polyquaternium-44 (CAS number: 150595-70-5)
- the amount of fabric care compound in the melt may, in various embodiments, be from 0.1% to 15%, and preferably from 1% to 12%, by weight. Bentonite is preferably used in an amount of up to 5% by weight, typically in amounts of from about 1% to 2% by weight.
- the melt is made from the ingredients described. It preferably has a viscosity (Texas Instruments AR-G2 rheometer, plate / plate, 4 cm diameter column 1100pm; shear rate 10/1 sec) of 1500 mPa »s or less, more preferably 1000 mPa» s or less. Particularly preferred is a viscosity between 50 and 1000 mPa » s, in particular between 100 and 800 mPa » s. This is preferred, since a dripping out of spherical particles is made possible in this way. This is then dripped, creating liquid spherical drops.
- a viscosity Texas Instruments AR-G2 rheometer, plate / plate, 4 cm diameter column 1100pm; shear rate 10/1 sec
- a viscosity between 50 and 1000 mPa » s, in particular between 100 and 800 mPa » s. This is preferred, since a dripping out of spherical particles is made possible in
- spherical particles in the sense of the present invention also include those which have only an approximately spherical shape, that is to say an aspect ratio of from 0.7 to 1.3, preferably from 0.8 to 1.2, in particular from 0.9 to 1, 1 have.
- the particles preferably have a diameter in the range from 1 mm to 10 mm, in particular from 1 mm to 5 mm, preferably from 2 mm to 4 mm.
- the particles are particularly soluble in water and at the same time for the consumer in a visually appealing size.
- the carrier is inventively chosen so that it has a good water solubility as suitability for later use.
- the melting point must be in an area where fragrances can be well incorporated, but not destroyed, so that they retain their fragrant properties.
- the carrier should be non-toxic and ecologically safe.
- the cooling or cooling can preferably be done by means of air and / or cooling liquid.
- Cooling with air can take place, for example, with conditioned air in countercurrent. This is particularly promising if the diameter of the fragrance particles is as small as possible. Here, the heat capacity of the air is sufficient to allow a rapid solidification of the melt into hard, solid spheres.
- cooling with coolant is possible.
- the melt is dripped directly into the cooling liquid. It is also possible to cool the melt both by means of air and by means of cooling liquid. This is done by first cooling the drops with air and then dripping into cooling liquid. By cooling in a cold gas atmosphere, especially in conditioned air, a solidified shell is formed, which guarantees dimensional stability during subsequent dripping into the cooling liquid.
- the density of the solidified droplets may be smaller or larger than that of the cooling liquid. Usually, it is smaller than that of the cooling liquid. Accordingly, the solidified droplets float on the surface of the cooling liquid and can be skimmed off or collected via an overflow.
- the main task of the cooling bath is to remove the melt drops after dropping heat, so that they solidify as quickly as possible.
- Any suitable one is suitable for this purpose Liquid as a coolant in the cooling bath. If the particles are removed very quickly after dripping, even water can be used. However, water is not preferred because the particles therein dissolve at least superficially and become sticky. Also, it is technically not easy to remove the particles so fast that they do not dissolve.
- liquids in a first preferred embodiment those liquids are used which have a reduced dissolving power for the constituents contained in the perfume particles, in particular the carrier material and the perfume.
- the dissolving power of water for PEG or other carriers can be reduced, for example, by the addition of salt or water-miscible solvents.
- a more preferred cooling fluid is therefore a saline solution
- salt solution is understood as meaning a solution of an inorganic or organic salt in a concentration such that the dissolution of the carrier polymer is retarded to such an extent that the particles can be harvested.
- Suitable salts are, for example, sodium chloride or sodium sulfate.
- water-miscible solvents such as glycols, glycerol
- other polar substances such as sugars, sugar alcohols, or the like, which reduce solvent quality for PEG or other carriers, may be added to the water.
- Volatile hydrocarbons for example pentane, hexane, hepane, alcohols (ethanol, (iso) -propanol, etc.) or even volatile silicone oils may preferably be used for this purpose.
- Another preferred cooling fluid is therefore a volatile hydrocarbon, alcohol or volatile silicone. Volatile in this context means that the corresponding compounds have a boiling temperature of 120 ° C or less.
- a halogenated, preferably fluorinated, particularly preferably perfluorinated organic compound as the cooling liquid.
- Perflourated hydrocarbons for example perfluorohexane
- perfluorohexane are in many cases characterized by a high stability, inertness and non-toxicity.
- due to a high GWP they can be harmful to the environment.
- This is avoided when using the liquid perfluoro (2-methyl-3-pentanone) as a cooling bath. It does not dissolve the carrier or the perfume, is non-flammable, non-toxic and harmless to the environment.
- Another advantage is the high density. This causes the particles to float on the coolant and thus be easily harvested by skimming or overflow.
- a particularly preferred cooling liquid in the context of the present invention is therefore perfluoro- (2-methyl-3-pentanone).
- a more preferred cooling fluid is a non-aqueous fluid.
- oils triglycerides but also silicone oils
- These do not dissolve the carrier but may have the disadvantage that, as they wet the particles, they are entrained in a substantial amount into the finished product and contaminate it or make it sticky.
- mineral oils or vegetable oils are particularly suitable as cooling fluid.
- the cooling liquid is therefore a mineral oil or a vegetable oil, in particular a vegetable oil.
- Suitable vegetable oils are, for example, those oils which can also be used as salad oil, such as thistle oil, sunflower seed oil, olive oil, walnut oil, linseed oil, soybean oil, sunflower oil, tall oil, castor oil, tung oil or others.
- vegetable oils derived from oil plants are rich oils.
- the advantage of vegetable oils is that they are inexpensive to obtain, the fragrance particles do not adversely affect and the fragrance particles can easily be separated from the oils, so it can be easily removed from the cooling bath, without the need for special devices are needed. Also, special safety regulations in the handling of these oils are not necessary, so therefore these oils are preferred.
- cooling liquids which are at least partly saturated with the carrier material and / or the perfume is preferred.
- the at least partial saturation may be achieved by dissolving the one or more constituents of the perfume particles in the cooling fluid prior to the start of dripping.
- it is also possible to achieve the at least partial saturation in the context of the production of fragrance particles by the production of the setting of a stationary (equilibrium) state is awaited and the fragrance particles prepared until this condition is discarded or recycled.
- a preferred embodiment of the method is characterized in that at least 90 wt .-%, preferably at least 95 wt .-% and in particular at least 98 wt .-% of the constituents contained in the fragrance particles in the cooling liquid of the cooling bath at the temperature used in the process Cooling bath have a solubility below 10 g / L, preferably below 5 g / L and in particular below 1 g / L.
- cooling liquid wets the surface of the fragrance particles.
- the cooling liquid wets the surface of the fragrance particle only partially, most preferably not at all. The lower the wetting of the particle surface, the lower the residues of the cooling liquid on the particle and the easier the complete removal of the coolant after discharging the fragrance particles from the cooling bath.
- the cooling bath has a temperature which is below the melting temperature of the carrier.
- the melting temperature of the support is preferably 100 ° C or less, preferably 40 ° C to 100 ° C, especially 50 ° C to 90 ° C, more preferably 55 ° C to 80 ° C.
- the temperature of the cooling bath is preferably 50 ° C or less, preferably 40 ° C or less, especially 25 ° C or less, preferably 20 ° C or less, more preferably 15 ° C or less.
- the temperature at which the cooling bath is located is not critical to the present invention as long as it is below the melting point of the above-mentioned melt.
- the temperature of the cooling bath is at least 10 ° C., preferably at least 25 ° C. and in particular at least 35 ° C. below the melting temperature of the carrier.
- the cooling bath does not come into contact with possibly moist ambient air, it can also be cooled significantly below the room temperature.
- This has the advantage that the dripped melt solidifies faster and less "twins” form, that is, particles which cling to the liquid surface before solidification and stick together.
- the surface of the liquid can also be made to flow. As a result, the particles are carried away quickly from the dropping point.
- the flow can be generated by stirring.
- FIG. 1 A schematic structure with a corresponding flow is shown in FIG.
- the melt (1) is placed in a suitable container and dripped into the cooling bath (4) via a dripping nozzle (2). This solidifies particles (3).
- the solidified particles have a lower density than the cooling liquid, so that the particles float on the surface of the cooling liquid. While the melt drips at one end of the cooling bath, there is an overflow (5) at the other end of the cooling bath.
- the cooling liquid together with the solidified particles (3) from the cooling bath (4) and can be collected in a suitable collecting container (6).
- the cooling liquid drains off and can be returned to the cooling bath (4) by means of a circulation pump (7).
- a circulation pump (7) By the circulation pump (7), a flow stream is generated, so that the formation of "twins", ie double particles can be substantially avoided.
- the particles (3) have a higher density than the cooling liquid and collect at the bottom of the cooling bath (4).
- the cooling bath (4) could be designed such that the gravity tapers following down and the particles can be removed according to the bottom of the cooling bath.
- the removal of the particles (3) can for example also be done manually with the aid of a sieve or similar suitable devices from the cooling bath (4). If particles are mentioned in the present application, these are to be understood as meaning the fragrance particles according to the invention.
- step b) of the method according to the invention comprises
- b1) introducing the melt via an inlet (8) into the interior of a container (9), wherein the container (9) has as an outlet a nozzle arrangement (10) with circular openings, and b2) subsequently or simultaneously set in motion of the container (9) by means of a vibration body (1 1), for dripping the melt.
- a melt is now conducted via an inlet (8) into the interior of a suitable container (9).
- a suitable structure of a corresponding device is shown schematically.
- the container (9) is shown in the form of a perforated plate.
- the container (9) may be round or oval in its outer shape, for example. However, it is also possible that the container has quadrangular, rectangular or another shape.
- the container (9) is designed such that it has a cavity in the interior, in which the melt can be introduced via an inlet (8).
- the container (9) has a nozzle arrangement.
- the nozzle assembly (10) has circular openings.
- the container has at least 10, preferably at least 50 and in particular at least 100 circular openings. The more openings the container has, the greater the throughput, ie the more amount of melt can be passed through the container (9) over a certain period of time. Accordingly, the production amount of fragrance particles is large.
- the circular openings which are arranged on the underside of the container (9), arranged annularly on the outer edge of the container. This means that in the middle of the container (9) no openings are present, but only at the edge of the container (9) openings are to be found. However, it is also possible that the circular openings are distributed homogeneously on the underside of the container (9).
- melt flows from above through the inlet downwards, ie first into the interior of the container and then in the direction of the nozzle assembly and out of the corresponding circular openings out of the container again.
- a melt is passed. Subsequent to the introduction of the melt or even during the container (9) by means of a vibration body (1 1) is set in vibration.
- the vibration is an axial vibration.
- the oscillation can be effected, for example, by means of a plunger, by means of which vibrations are transmitted from the oscillation body (11) to the container (9).
- the nozzles (10) Preferably, the container (9) not completely covered on the underside with circular openings, but annular in the outer region of the container (9). In the middle there is a region without openings, since the vibration body (11) would produce a different droplet image in this area.
- the vibration is basically responsible for producing a uniform droplet image, thereby preserving spherical fragrance particles.
- the circular openings of the container (9) preferably have a diameter in the range of 0.1 mm to 3 mm, in particular in the range of 0.2 mm to 2.5 mm, preferably from 0.5 mm to 2.5 mm, preferably from 1 mm to 2 mm.
- This opening size ensures a sufficiently high throughput, so that an economic manufacturing process is possible. At the same time, this limits the size of the fragrance particles obtained, so that they quickly solidify and dry after leaving the container (9), and at the same time, when they are used, they can quickly dissolve again. In addition, corresponding sizes of the particles are visually appealing to the consumer.
- the size of the particles contained ie the diameter of the particles (fragrance particles) corresponds approximately to twice the diameter of the circular opening of the container (9).
- the container (9) should either dip into the cooling liquid or be mounted just above the liquid level of the cooling liquid such that the energy of the fall and thus the deformation are small. A slight deformation can be reversed by the surface tension of the drops before the final curing.
- the present invention relates to particles (fragrance particles) as obtained by the method according to the invention.
- the particles according to the invention (fragrance particles) have a spherical shape.
- the ingredients correspond to those of the melt.
- the spherical fragrance particles have textile-care compounds as described above, they are used in particular as fragrancing agents in the main wash cycle of an automatic washing or cleaning process.
- the fragrance particles can be added by the consumer in the desired dosage - in addition to the detergent or cleaning agent - into the appropriate Rinsing or directly into the drum of the washing machine are given. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser.
- fragrance particles according to the invention can be used in the wash cycle of a laundry cleaning process and thus already transport the textile-care compound and the fragrance directly to the laundry at the beginning of the washing process so as to be able to develop its full potential. Furthermore, the fragrance particles are easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the particles are accidentally spilled during dosing. The spilled amount can also be removed easier and cleaner.
- the fragrance particle may optionally contain other ingredients.
- these additional ingredients are preferably selected from the group consisting of dyes, pearlescing agents, skin-care compounds, bittering agents and mixtures thereof.
- dyes In order to improve the aesthetic impression of the particles, it can be colored with suitable dyes.
- Preferred dyes the selection of which presents no difficulty to the skilled person, should have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
- the amount is usually 0.0001 wt .-% to 1 wt .-% of dye, preferably 0.001 wt .-% to 0.5 wt .-%.
- the fragrance particles may also contain a pearlescing agent to increase the gloss.
- suitable pearlescing agents are ethylene glycol mono- and distearate and PEG-3-distearate.
- fragrance particles may comprise one or more skin care compounds.
- a skin-care compound is understood to mean a compound or a mixture of compounds which, upon contact of a textile with the composition, attract the textile and, when the textile contacts the skin, confer an advantage on the skin compared with a textile which is not treated with the composition according to the invention has been.
- This advantage can be, for example, the transfer of the skin-care compound from the textile to the skin, a lower water transfer of the skin on the textile or less friction on the skin surface through the textile.
- the skin care composition is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care composition.
- the skin care compound may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care composition.
- the skin care compound may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care composition.
- the skin care compound may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care composition.
- waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
- Plant extracts for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil , Hazelnut oil, jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
- vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil , Hazelnut oil, jojoba oil or canola oil, chamomile, aloe vera and mixture
- higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids;
- higher fatty alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol or 2-hexadecanol,
- esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate, glycerol monostearate, glycerol distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
- hydrocarbons such as paraffins, mineral oils, squalane or squalene
- vitamins such as vitamins A, C or E or vitamin alkyl esters
- sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
- silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
- the amount of skin-care compound is preferably between 0.01% by weight and 10% by weight, preferably between 0.1% by weight and 5% by weight and most preferably between 0.3% by weight and 3 wt .-% based on the total weight of the fragrance particles. It may be that the skin-nourishing compound additionally has a textile care effect. To prevent ingestion of particles by people, especially children, or animals, they may contain a bittering agent such as Bitrex ®.
- Components contained in the fragrance particles are accordingly contained in the melt.
- the present invention furthermore relates to the use of the fragrance particles described herein as textile care agents, preferably fragrancing agents, for the scenting of textile fabrics.
- fragrance particles are brought into contact with the textile fabrics together with a conventional washing or cleaning agent in the (main) wash cycle of a conventional washing or cleaning process.
- step b) comprises the following steps: b1) introducing the melt through an inlet (8) into the interior of a container (9), wherein the container (9) has as outlet a nozzle arrangement (10 ) having circular openings, and
- the carrier is selected from the group of polymers, preferably from the group of polyethylene glycols, EO / PO block copolymers or highly alkoxylated nonionic surfactants, in particular from the group of polyethylene glycols ,
- the carrier is selected from the group of hydrous salts whose water vapor partial pressure at a certain temperature in the range of 30 to 100 ° C the FLO partial pressure of the saturated solution of this Salt corresponds, in particular sodium acetate trihydrate.
- Composition according to one or more of the items 1 to 9, characterized in that the proportion by weight of the perfume in the total weight of the fragrance particles is 0, 1 wt .-% to 20 wt .-%, preferably 1 wt .-% to 20 wt .-%, more preferably 1 wt .-% to 15 wt .-%, in particular 3 wt .-% to 10 wt .-% is.
- Method according to one or more of the items 1 to 10 characterized in that the cooling bath has a temperature which is below the melting temperature of the carrier.
- Method according to one or more of the items 1 to 12 characterized in that the temperature of the cooling bath 50 ° C or less, preferably 40 ° C or less, in particular 25 ° C or less, preferably 20 ° C or less, especially 15 ° C. or less.
- Method according to one or more of the items 1 to 13 characterized in that the temperature of the cooling bath is at least 10 ° C, preferably at least 25 ° C and in particular at least 35 ° C below the melting temperature of the carrier.
- the cooling bath comprises a cooling liquid selected from water, an aqueous salt solution, water-miscible solvents, oils, hydrocarbons, halogenated hydrocarbons and mixtures thereof.
- the cooling liquid is an oil, in particular a mineral oil or a vegetable oil, preferably a vegetable oil.
- the cooling liquid has perfluoro- (2-methyl-3-pentanone) and in particular consists thereof.
- Spherical fragrance particles obtained by a method according to one or more of the items 1 to 20. Use of fragrance particles according to item 21 for fragrancing objects, in particular textile fabrics. In the following embodiment, the present invention will not be explained further in a nonlimiting manner.
- the particles according to the invention which had approximately spherical shape, were screened off.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Fats And Perfumes (AREA)
- Detergent Compositions (AREA)
Abstract
La présente invention concerne un procédé de fabrication de particules parfumées sphériques, les particules parfumées obtenues par ce procédé, ainsi que leur utilisation pour parfumer des objets, en particulier des textiles.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017222998.5A DE102017222998A1 (de) | 2017-12-18 | 2017-12-18 | Herstellungsverfahren für kugelförmige Duftperlen |
DE102017222998.5 | 2017-12-18 |
Publications (1)
Publication Number | Publication Date |
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WO2019120678A1 true WO2019120678A1 (fr) | 2019-06-27 |
Family
ID=63965635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2018/078048 WO2019120678A1 (fr) | 2017-12-18 | 2018-10-15 | Procédé de fabrication de perles parfumées sphériques |
Country Status (2)
Country | Link |
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DE (1) | DE102017222998A1 (fr) |
WO (1) | WO2019120678A1 (fr) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19746780A1 (de) * | 1997-10-23 | 1999-04-29 | Henkel Kgaa | Verfahren zur Herstellung von Duftperlen |
EP1475078A1 (fr) * | 2003-05-09 | 2004-11-10 | INTERNATIONAL FLAVORS & FRAGRANCES INC. | Particules polymères, méthodes pour leur préparation et leur utilisation |
DE102009003088A1 (de) * | 2009-05-13 | 2010-11-18 | Henkel Ag & Co. Kgaa | Kugelförmige WC-Steine, Verfahren zu ihrer Herstellung und WC-Reinigungskörpchen mit kugelförmigen WC-Steinen |
WO2011056938A1 (fr) * | 2009-11-05 | 2011-05-12 | The Procter & Gamble Company | Additif de parfum de lessive |
-
2017
- 2017-12-18 DE DE102017222998.5A patent/DE102017222998A1/de not_active Withdrawn
-
2018
- 2018-10-15 WO PCT/EP2018/078048 patent/WO2019120678A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19746780A1 (de) * | 1997-10-23 | 1999-04-29 | Henkel Kgaa | Verfahren zur Herstellung von Duftperlen |
EP1475078A1 (fr) * | 2003-05-09 | 2004-11-10 | INTERNATIONAL FLAVORS & FRAGRANCES INC. | Particules polymères, méthodes pour leur préparation et leur utilisation |
DE102009003088A1 (de) * | 2009-05-13 | 2010-11-18 | Henkel Ag & Co. Kgaa | Kugelförmige WC-Steine, Verfahren zu ihrer Herstellung und WC-Reinigungskörpchen mit kugelförmigen WC-Steinen |
WO2011056938A1 (fr) * | 2009-11-05 | 2011-05-12 | The Procter & Gamble Company | Additif de parfum de lessive |
EP2496679B1 (fr) | 2009-11-05 | 2014-10-29 | The Procter and Gamble Company | Additif de parfum de lessive |
Non-Patent Citations (1)
Title |
---|
J. M. NIKITAKIS, ET AL,: "CTFA International Cosmetic Ingredient Dictionary, Fourth Edition,", 1991, COSMETIC, TOILETRY, AND FRAGRANCE ASSOCIATION |
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DE102017222998A1 (de) | 2019-06-19 |
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