WO2019093636A1 - Composition de résine thermoplastique et article moulé produit à partir de celle-ci - Google Patents

Composition de résine thermoplastique et article moulé produit à partir de celle-ci Download PDF

Info

Publication number
WO2019093636A1
WO2019093636A1 PCT/KR2018/010015 KR2018010015W WO2019093636A1 WO 2019093636 A1 WO2019093636 A1 WO 2019093636A1 KR 2018010015 W KR2018010015 W KR 2018010015W WO 2019093636 A1 WO2019093636 A1 WO 2019093636A1
Authority
WO
WIPO (PCT)
Prior art keywords
thermoplastic resin
resin composition
zinc oxide
aromatic vinyl
measured
Prior art date
Application number
PCT/KR2018/010015
Other languages
English (en)
Korean (ko)
Inventor
추동휘
김기선
권영철
Original Assignee
롯데첨단소재(주)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020180064628A external-priority patent/KR102161339B1/ko
Application filed by 롯데첨단소재(주) filed Critical 롯데첨단소재(주)
Priority to JP2020515945A priority Critical patent/JP7121113B2/ja
Priority to US16/648,813 priority patent/US11505674B2/en
Priority to CN201880069060.5A priority patent/CN111263789B/zh
Publication of WO2019093636A1 publication Critical patent/WO2019093636A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C01G9/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F1/00—Room units for air-conditioning, e.g. separate or self-contained units or units receiving primary air from a central station

Definitions

  • the present invention relates to a thermoplastic resin composition and a molded article produced therefrom. More specifically, the present invention relates to a thermoplastic resin composition for an air-conditioner cross-fan excellent in rigidity, antibacterial properties, weather resistance, and appearance characteristics, and a molded article produced therefrom.
  • thermoplastic resin products containing antibacterial and hygienic functions As the interest in personal health and hygiene and income levels have improved.
  • thermoplastic resin products that have been subjected to antimicrobial treatment that can remove or inhibit bacteria on the surfaces of household products and electronic products are increasing, and development of functional antibacterial material (antibacterial thermoplastic resin composition) having stable and reliable is very important It is an assignment.
  • the inside of the air conditioner is composed of a heat exchanger generating cold water vapor, a filter for filtering dust, a cross fan for blowing out cold air by generating wind, and an air blower. Since the inside of the air conditioner is high in humidity and has a structure that is blocked from the outside partly, it is vulnerable to fungi and bacteria.
  • the filter, the blowing furnace, etc. are secured with antimicrobial effect by using stainless steel and plasma sterilization.
  • the cross fan material requires mechanical properties such as antibacterial property and high rigidity, It is a reality.
  • Inorganic antimicrobial agents containing metal components such as silver (Ag) and copper (Cu) are used for the cross fan material.
  • the antibacterial agent is insufficient in antibacterial power and requires an excessive amount of the antimicrobial agent.
  • There is a disadvantage such as discoloration due to the use of the photoreceptor.
  • thermoplastic resin composition capable of realizing excellent rigidity, antimicrobial property, weather resistance (discoloration resistance), appearance characteristics and the like.
  • An object of the present invention is to provide a thermoplastic resin composition excellent in rigidity, antimicrobial property, weather resistance, appearance and the like.
  • Another object of the present invention is to provide a molded article formed from the thermoplastic resin composition.
  • thermoplastic resin composition is an aromatic vinyl-based copolymer resin; glass fiber; And zinc oxide.
  • the zinc oxide has an average particle size (D50) measured by a particle size analyzer of about 0.5 to about 3 ⁇ ⁇ , a peak A in the region of 370 to 390 nm and a peak of 450 And a size ratio (B / A) of the peak B in the region of from 600 nm to about 600 nm is about 0.01 to about 1.0.
  • the thermoplastic resin composition comprises about 100 parts by weight of the aromatic vinyl-based copolymer resin; About 5 to about 40 parts by weight of the glass fiber; And about 0.1 to about 20 parts by weight of the zinc oxide.
  • the aromatic vinyl-based copolymer resin may be an aromatic vinyl-based monomer and a polymer of a monomer copolymerizable with the aromatic vinyl-based monomer.
  • the zinc oxide has a peak position 2 ⁇ value in the range of 35 to 37 ° in the X-ray diffraction (XRD) analysis, and the crystallite size ) Value may be a crystallite size value of from about 1,000 to about 2,000 A:
  • K is a shape factor,? Is an X-ray wavelength,? Is an FWHM value (degree) of an X-ray diffraction peak,? Is a peak position value (peak position degree).
  • the zinc oxide is dissolved in zinc and then heated to about 850 to about 1000 < 0 > C to form a vapor, then oxygen gas is introduced and cooled to about 20 to about 30 & For about 30 to about 150 minutes.
  • the zinc oxide may have a specific surface area BET of less than or equal to about 10 m < 2 > / g, as measured by a BET analysis instrument, using a nitrogen gas adsorption method.
  • thermoplastic resin composition was measured for an initial color (L 0 * , a 0 * , b 0 * ) using a colorimeter for a 50 mm ⁇ 90 mm ⁇ 3 mm size injection specimen, and measured according to ASTM D4459 (L 1 * , a 1 * , b 1 * ) may be measured in the same manner after 3,000 hours of testing, and then the color change ( ⁇ E) calculated according to the following formula 2 may be about 0.1 to about 2.0:
  • ⁇ L * is a difference (L 1 * -L 0 *) of the test before and after the L * value of
  • ⁇ a * is the difference between (a 1 * - a 0 * ) of the test before and after the a * value is
  • ⁇ b * Is the difference (b 1 * - b 0 * ) between the values of b * before and after the test.
  • thermoplastic resin composition is prepared by inoculating Staphylococcus aureus and Escherichia coli into a specimen of 5 cm x 5 cm in size according to JIS Z 2801 antibacterial evaluation method, culturing at 35 ° C and RH 90% for 24 hours, 3 may be about 2 to about 7, respectively,
  • Antibacterial activity log (M1 / M2)
  • M1 is the number of bacteria after 24 hours of incubation for the blank specimen
  • M2 is the number of bacteria after 24 hours of incubation for the thermoplastic resin composition specimen.
  • the thermoplastic resin composition may have a flexural modulus of greater than about 74,000 kgf / cm 2 measured on a 6.4 mm thick specimen at 2.8 mm / min under ASTM D790.
  • the thermoplastic resin composition comprises a continuous phase of an aromatic vinyl copolymer resin, wherein the glass fiber and the zinc oxide form a dispersed phase, and the ratio of the average particle size (D50) of the zinc oxide to the diameter of the glass fiber is about 1: About 1.7 to about 1: about 200.
  • Another aspect of the present invention relates to a molded article. And the molded article is formed from the thermoplastic resin composition.
  • the shaped article may be a cross fan of an air conditioner.
  • the present invention has the effect of providing a thermoplastic resin composition excellent in rigidity, antimicrobial property, weather resistance, appearance and the like, and a molded article formed therefrom.
  • thermoplastic resin composition according to the present invention comprises (A) an aromatic vinyl-based copolymer resin; (B) glass fibers; And (C) zinc oxide.
  • the aromatic vinyl-based copolymer resin according to one embodiment of the present invention may be an aromatic vinyl-based copolymer resin used in a conventional thermoplastic resin composition for an air-conditioner cross-fan.
  • the aromatic vinyl-based copolymer resin may be a polymer of a monomer mixture comprising a monomer copolymerizable with the aromatic vinyl-based monomer such as an aromatic vinyl-based monomer and a vinyl cyanide-based monomer.
  • the aromatic vinyl-based copolymer resin may be obtained by mixing aromatic vinyl-based monomers and aromatic vinyl-based monomers with a monomer copolymerizable therewith and the like, and the polymerization may be carried out by emulsion polymerization, suspension polymerization, Of the present invention.
  • the aromatic vinyl monomer is at least one monomer selected from the group consisting of styrene,? -Methylstyrene,? -Methylstyrene, p-methylstyrene, pt-butylstyrene, ethylstyrene, vinylxylene, monochlorostyrene, dibromostyrene , Vinyl naphthalene, and the like can be used, but the present invention is not limited thereto. These may be used alone or in combination of two or more.
  • the content of the aromatic vinyl-based monomer may be about 20 to about 90% by weight, for example about 30 to about 80% by weight, based on 100% by weight of the entire aromatic vinyl-based copolymer resin.
  • the impact resistance and fluidity of the thermoplastic resin composition can be excellent in the above range.
  • Examples of the monomer copolymerizable with the aromatic vinyl-based monomer include acrylonitrile, methacrylonitrile, ethacrylonitrile, phenyl acrylonitrile,? -Chloroacrylonitrile, and fumaronitrile.
  • (Meth) acrylic acid and alkyl esters thereof, maleic anhydride, N-substituted maleimide, etc. may be used alone or in admixture of two or more.
  • the content of the monomer copolymerizable with the aromatic vinyl-based monomer may be about 10 to about 80% by weight, for example about 20 to about 70% by weight, based on 100% by weight of the total aromatic vinyl-based copolymer resin.
  • the impact resistance and fluidity of the thermoplastic resin composition can be excellent in the above range.
  • the aromatic vinyl-based copolymer resin has a weight average molecular weight (Mw), as measured by gel permeation chromatography (GPC), of from about 10,000 to about 300,000 g / mol, such as from about 20,000 to about 200,000 g / .
  • Mw weight average molecular weight
  • the thermoplastic resin composition may have excellent mechanical strength and moldability.
  • the aromatic vinyl-based copolymer resin may be a mixture of two or more aromatic vinyl-based copolymer resins having different weight average molecular weights.
  • An aromatic vinyl copolymer resin may be mixed and used.
  • the glass fiber according to one embodiment of the present invention can improve the mechanical properties such as rigidity of the thermoplastic resin composition and can be a glass fiber used in a conventional thermoplastic resin composition for an air conditioner cross fan.
  • the glass fiber may have various shapes such as a fiber shape, a particle shape, a rod shape, an acicular shape, and a flake shape, and may have various shapes such as a circle, an ellipse, and a rectangle.
  • a fibrous glass fiber having a circular and / or rectangular cross section.
  • the glass fibers of the circular cross section may have a cross-sectional diameter of from about 5 to about 20 microns and a length before shaping of from about 2 to about 20 mm, the glass fibers of the rectangular cross-section having an aspect ratio of from about 1.5 to about 10, and the length before processing may be from about 2 to about 20 mm.
  • the rigidity, workability and the like of the thermoplastic resin composition can be improved.
  • the glass fibers may comprise from about 5 to about 40 parts by weight, for example from about 10 to about 30 parts by weight, and especially from about 15 to about 25 parts by weight, based on about 100 parts by weight of the thermoplastic resin.
  • the thermoplastic resin composition may have excellent mechanical properties, appearance characteristics, weatherability, antibacterial properties and the like.
  • the zinc oxide according to one embodiment of the present invention is capable of improving the weather resistance and antibacterial property of the thermoplastic resin composition and is characterized in that it has a peak A of 370 to 390 nm and a peak A of 450 to 600 nm
  • the size ratio (B / A) of the peak B may be about 0.01 to about 1.0, for example about 0.1 to about 1.0, specifically about 0.2 to about 0.7.
  • the size ratio (B / A) of the peak A and the peak B of zinc oxide is less than about 0.01, antimicrobiality and the like may be deteriorated.
  • the ratio B / A is more than about 1.0, the problem of initial discoloration of the thermoplastic resin and the weather resistance have.
  • the zinc oxide may have various shapes and may include, for example, spheres, plates, rods, combinations thereof, and the like.
  • the average particle size (D50) of single particles (the particles do not form secondary particles) measured by using a particle size analyzer (Beckman Coulter's Laser Diffraction Particle Size Analyzer LS I3 320 equipment) is about From about 0.5 to about 3 microns, such as from about 0.8 to about 3 microns. If it is out of the above range, the discoloration resistance, weather resistance, etc. of the thermoplastic resin composition may be lowered.
  • the zinc oxide has a peak position 2 ⁇ value in the range of 35 to 37 ° in X-ray diffraction (XRD) analysis, and the measured FWHM value (Full of diffraction peak the crystallite size value calculated by applying Scherrer's equation (Equation 1) based on the width at half maximum may be about 1,000 to about 2,000 A, for example, about 1,200 to about 1,800 A.
  • the initial color of the thermoplastic resin composition, weather resistance (discoloration resistance), antimicrobial property, mechanical property balance thereof and the like can be excellent.
  • K is a shape factor,? Is an X-ray wavelength,? Is an FWHM value (degree) of an X-ray diffraction peak,? Is a peak position value (peak position degree).
  • the zinc oxide may have a specific surface area BET of less than or equal to about 10 m < 2 > / g, as measured by a BET analytical instrument (Micromeritics Surface Area and Porosity Analyzer ASAP 2020 instrument) To about 7 m < 2 > / g, and the purity may be greater than about 99%.
  • the thermoplastic resin composition may have excellent mechanical properties, discoloration resistance, and the like.
  • the zinc oxide may be prepared by melting zinc in the form of a metal and then heating to about 850 to about 1000 ⁇ , such as about 900 to about 950 ⁇ , And then heating at about 400 to about 900 DEG C, for example, about 500 to about 800 DEG C for about 30 to about 150 minutes, for example, about 60 to about 120 minutes.
  • the zinc oxide may be included in an amount of from about 0.1 to about 20 parts by weight, for example, from about 0.5 to about 10 parts by weight, specifically about 1 to about 5 parts by weight, relative to about 100 parts by weight of the thermoplastic resin.
  • the thermoplastic resin composition may have excellent weather resistance, antibacterial properties, mechanical properties, and appearance characteristics.
  • the thermoplastic resin composition according to one embodiment of the present invention may further include an additive contained in a conventional thermoplastic resin composition.
  • the additives include, but are not limited to, a flame retardant, an antioxidant, a dripping inhibitor, a lubricant, a release agent, a nucleating agent, an antistatic agent, a stabilizer, a pigment, a dye and mixtures thereof.
  • its content may be from about 0.001 to about 40 parts by weight, for example from about 0.1 to about 10 parts by weight, relative to about 100 parts by weight of the thermoplastic resin.
  • thermoplastic resin composition according to one embodiment of the present invention is prepared by mixing the above components and melt-extruding at a temperature of about 200 to about 280 ⁇ , for example, about 220 to about 250 ⁇ , using a conventional twin-screw extruder. .
  • the thermoplastic resin composition comprises a continuous phase of an aromatic vinyl copolymer resin, wherein the glass fiber and the zinc oxide form a dispersed phase, and the ratio of the average particle size (D50) of the zinc oxide to the diameter of the glass fiber is about 1: About 1.7 to about 1: about 200, such as about 1: about 2 to about 1: about 20. Within the above range, the rigidity and creep characteristics of the thermoplastic resin composition can be excellent.
  • thermoplastic resin composition was measured for an initial color (L 0 * , a 0 * , b 0 * ) using a colorimeter for a 50 mm ⁇ 90 mm ⁇ 3 mm size injection specimen, and measured according to ASTM D4459 (L 1 * , a 1 * , b 1 * ) is measured in the same manner after 3,000 hours of testing, and the color change ( ⁇ E) calculated according to the following formula 2 is about 0.1 to about 2.0, From about 0.5 to about 1.0.
  • ⁇ L * is a difference (L 1 * -L 0 *) of the test before and after the L * value of
  • ⁇ a * is the difference between (a 1 * - a 0 * ) of the test before and after the a * value is
  • ⁇ b * Is the difference (b 1 * - b 0 * ) between the values of b * before and after the test.
  • the? A * may be about 1.0 to about 1.5.
  • the weatherability (discoloration resistance) is greatly lowered to such an extent that a color change is visually perceived.
  • the thermoplastic resin composition has antibacterial effect against various bacteria such as Staphylococcus aureus, Escherichia coli, Bacillus subtilis, Pseudomonas aeruginosa, Salmonella, Pneumococcus and MRSA (Methicillin-Resistant Staphylococcus aureus)
  • the antimicrobial activity values calculated according to the following formula 3 were independently in the range of about 2 to about 7 , For example from about 3 to about 6.
  • Antibacterial activity log (M1 / M2)
  • M1 is the number of bacteria after 24 hours of incubation for the blank specimen
  • M2 is the number of bacteria after 24 hours of incubation for the thermoplastic resin composition specimen.
  • the " blank specimen” is a control specimen of the test specimen (thermoplastic resin composition specimen). Specifically, in order to confirm whether or not the inoculated bacteria were normally grown, bacteria were inoculated on a petri dish and incubated for 24 hours in the same manner as the test specimens. The antibacterial activity of the test specimens . In addition, the "number of bacteria" can be counted by inoculating each specimen, culturing it for 24 hours, collecting the inoculated bacterial solution, diluting it, and then growing it into a colony on a culture dish. Colony grows too much, and when century is difficult, divide the divisions and count them, then convert them to actual numbers.
  • the thermoplastic resin composition has a flexural modulus of at least about 74,000 kgf / cm 2 , such as from about 74,500 to about 80,000 kgf / cm 2 , measured on a 6.4 mm thick specimen at 2.8 mm / min, according to ASTM D790. cm < 2 >.
  • the molded article according to the present invention is formed from the thermoplastic resin composition.
  • the antimicrobial thermoplastic resin composition may be produced in the form of a pellet.
  • the pellet may be manufactured into various molded articles through various molding methods such as injection molding, extrusion molding, vacuum molding, and casting molding. Such molding methods are well known to those of ordinary skill in the art to which the present invention pertains.
  • the molded article is excellent in stiffness, antimicrobial property, weather resistance, appearance, balance of physical properties, and is useful as an air-conditioner cross fan or the like.
  • A-1) SAN resin (weight average molecular weight: 80,000 g / mol) polymerized with 68% by weight of styrene and 32% by weight of acrylonitrile was used.
  • A-2) SAN resin (weight average molecular weight: 150,000 g / mol) in which 68% by weight of styrene and 32% by weight of acrylonitrile were polymerized was used.
  • a circular cross section glass fiber having a cross-sectional diameter of 13 ⁇ and a length of 3 mm before machining was used.
  • Average particle size (unit: ⁇ ⁇ ): The average particle size (volume average) was measured using a particle size analyzer (Beckman Coulter Laser Diffraction Particle Size Analyzer LS I3 320 instrument).
  • BET surface area (unit: m 2 / g): The BET surface area was measured with a BET analyzer (Micromeritics Surface Area and Porosity Analyzer ASAP 2020 instrument) using a nitrogen gas adsorption method.
  • Purity (unit:%): Purity was measured using TGA thermal analysis at a temperature of 800 ° C.
  • PL size ratio (B / A): According to the photoluminescence measurement method, the spectrum emitted from a He-Cd laser (KIMMON company, 30 mW) having a wavelength of 325 nm at room temperature is measured by a CCD detector The temperature of the CCD detector was maintained at -70 °C. (B / A) of the peak A in the 370 to 390 nm region and the peak B in the 450 to 600 nm region was measured.
  • the injection specimen was subjected to PL analysis by injecting a laser into the specimen without any additional treatment.
  • the zinc oxide powder was placed in a pelletizer having a diameter of 6 mm and pressed to form a flat specimen. Respectively.
  • K is a shape factor,? Is an X-ray wavelength,? Is an FWHM value (degree) of an X-ray diffraction peak,? Is a peak position value (peak position degree).
  • the above components were added in the amounts as shown in Table 2, and then extruded at 230 ⁇ to prepare pellets.
  • the pellets were extruded at a temperature of 230 ° C. and a mold temperature of 60 ° C. in a 6 Oz extruder at 80 ° C. for 2 hours or more, .
  • the properties of the prepared specimens were evaluated by the following methods, and the results are shown in Table 2 below.
  • ⁇ L * is a difference (L 1 * -L 0 *) of the test before and after the L * value of
  • ⁇ a * is the difference between (a 1 * - a 0 * ) of the test before and after the a * value is
  • ⁇ b * Is the difference (b 1 * - b 0 * ) between the values of b * before and after the test.
  • Antibacterial activity value Staphylococcus aureus and E. coli were inoculated on a 5 cm x 5 cm specimen according to JIS Z 2801 antibacterial evaluation method, and cultured at 35 ° C and RH 90% for 24 hours. Respectively.
  • Antibacterial activity log (M1 / M2)
  • M1 is the number of bacteria after 24 hours of incubation for the blank specimen
  • M2 is the number of bacteria after 24 hours of incubation for the thermoplastic resin composition specimen.
  • Appearance evaluation A specimen having a size of 90 mm x 50 mm x 2.5 mm was prepared, and the presence or absence of a flow mark was visually observed. Without the flow mark, it can be estimated that the compatibility of the thermoplastic resin composition is improved.
  • Example Comparative Example One 2 One 2 3 (A) (% by weight) (A1) 37.5 37.5 37.5 37.5 37.5 (A2) 62.5 62.5 62.5 62.5 62.5 62.5 (B) (parts by weight) 20 20 20 20 20 (C1) (parts by weight) 2 4 - - - (C2) (parts by weight) - - 4 - - (D) (parts by weight) - - - 4 - Color change ( ⁇ E) 1.0 0.5 3.0 3.5 3.5
  • the antibacterial activity value E.
  • thermoplastic resin composition of the present invention is excellent in rigidity (flexural modulus), antibacterial properties (antibacterial activity value), weather resistance (color change ( ⁇ E)), heat resistance ) And the like are all excellent.
  • Comparative Example 1 in which zinc oxide (C2) having a PL size ratio (B / A) of more than 1.0 (9.8) was used instead of zinc oxide of the present invention and Comparative Example 2 in which silver antimicrobial agent was applied, The appearance characteristics and the like were deteriorated.
  • Comparative Example 3 in which zinc oxide was not used, it was found that the weather resistance, antibacterial property and the like were lowered.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention est caractérisée en ce qu'elle comprend un copolymère à base de vinyle aromatique, une fibre de verre et de L'oxyde de zinc, l'oxyde de zinc ayant une taille de particule moyenne (D50) d'environ 0,5 à 3 µm telle que mesurée par un analyseur de taille de particule, et un rapport de taille (B/A) du pic B, couvrant la plage de 450 à 600 nm, pour le pic a, couvrant la plage de 370 à 390 nm, d'environ 0,01 à 1,0 lors de la mesure de photoluminescence. La composition de résine thermoplastique présente d'excellents résultats en termes de rigidité, de propriétés antibactériennes, de résistance aux intempéries, d'aspect extérieur et analogues.
PCT/KR2018/010015 2017-11-08 2018-08-30 Composition de résine thermoplastique et article moulé produit à partir de celle-ci WO2019093636A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2020515945A JP7121113B2 (ja) 2017-11-08 2018-08-30 熱可塑性樹脂組成物及びこれから製造された成形品
US16/648,813 US11505674B2 (en) 2017-11-08 2018-08-30 Thermoplastic resin composition and molded article produced from same
CN201880069060.5A CN111263789B (zh) 2017-11-08 2018-08-30 热塑性树脂组合物和由其制备的模制品

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2017-0147949 2017-11-08
KR20170147949 2017-11-08
KR1020180064628A KR102161339B1 (ko) 2017-11-08 2018-06-05 열가소성 수지 조성물 및 이로부터 제조된 성형품
KR10-2018-0064628 2018-06-05

Publications (1)

Publication Number Publication Date
WO2019093636A1 true WO2019093636A1 (fr) 2019-05-16

Family

ID=66438959

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2018/010015 WO2019093636A1 (fr) 2017-11-08 2018-08-30 Composition de résine thermoplastique et article moulé produit à partir de celle-ci

Country Status (1)

Country Link
WO (1) WO2019093636A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11034620B2 (en) 2016-12-20 2021-06-15 Lotte Chemical Corporation Composition for artificial marble
US11505674B2 (en) 2017-11-08 2022-11-22 Lotte Chemical Corporation Thermoplastic resin composition and molded article produced from same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1135787A (ja) * 1997-07-24 1999-02-09 Techno Polymer Kk 抗菌性熱可塑性樹脂組成物
KR20100087603A (ko) * 2009-01-28 2010-08-05 주식회사 단석산업 미립상의 산화아연의 연속 제조방법 및 그 장치
JP2011137068A (ja) * 2009-12-28 2011-07-14 Sumika Styron Polycarbonate Ltd 抗菌性に優れた熱可塑性樹脂組成物およびそれからなる成形品
KR20150017706A (ko) * 2012-05-15 2015-02-17 바스프 에스이 제제화가 용이한 산화아연 분말

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1135787A (ja) * 1997-07-24 1999-02-09 Techno Polymer Kk 抗菌性熱可塑性樹脂組成物
KR20100087603A (ko) * 2009-01-28 2010-08-05 주식회사 단석산업 미립상의 산화아연의 연속 제조방법 및 그 장치
JP2011137068A (ja) * 2009-12-28 2011-07-14 Sumika Styron Polycarbonate Ltd 抗菌性に優れた熱可塑性樹脂組成物およびそれからなる成形品
KR20150017706A (ko) * 2012-05-15 2015-02-17 바스프 에스이 제제화가 용이한 산화아연 분말

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
VIJAYARAGHAVAN, RAJAGOPALAN: "Insight into the Mechanism of Antibacteria 1 Activity of ZnO: Surface Defects Mediated Reactive Oxygen Species Even in the Dark", LANGMUIR, vol. 31, no. 33, 2015, pages 9155 - 9162, XP055570351, DOI: doi:10.1021/acs.langmuir.5b02266 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11034620B2 (en) 2016-12-20 2021-06-15 Lotte Chemical Corporation Composition for artificial marble
US11505674B2 (en) 2017-11-08 2022-11-22 Lotte Chemical Corporation Thermoplastic resin composition and molded article produced from same

Similar Documents

Publication Publication Date Title
WO2019190068A1 (fr) Composition de résine thermoplastique et article moulé produit à partir de cette dernière
WO2018080013A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de celle-ci
WO2020222449A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de celle-ci
WO2012144781A2 (fr) Matériau composite de polymère biodégradable
WO2019031694A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de ladite composition
WO2012053698A1 (fr) Composition de résine polycarbonate et produits moulés l'utilisant
WO2019124855A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de cette dernière
WO2019093636A1 (fr) Composition de résine thermoplastique et article moulé produit à partir de celle-ci
WO2019066193A1 (fr) Composition de résine thermoplastique résistante aux rayonnements ionisants et article moulé comprenant celle-ci
WO2018124657A1 (fr) Composition de résine thermoplastique et article moulé fabriqué avec celle-ci
WO2019132371A1 (fr) Composition de résine thermoplastique et produit moulé formé à partir de celle-ci
WO2019132575A1 (fr) Composition de résine thermoplastique et article moulé fabriqué à partir de celle-ci
WO2018070631A1 (fr) Composition de résine thermoplastique, et produit moulé produit à partir de cette composition
WO2012086867A1 (fr) Composition de résine copolymère acrylique
KR102161339B1 (ko) 열가소성 수지 조성물 및 이로부터 제조된 성형품
WO2022025416A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de celle-ci
WO2020138785A1 (fr) Composition de résine thermoplastique et produit moulé formé à partir de celle-ci
WO2020040504A1 (fr) Composition de résine de polycarbonate et produit moulé optique la comprenant
WO2019132385A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de celle-ci
WO2022114589A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de celle-ci
WO2019083147A1 (fr) Composition de résine thermoplastique et produit moulé fabriqué à partir de celle-ci
WO2018124614A1 (fr) Composition de résine thermoplastique
WO2019078479A1 (fr) Composition de résine thermoplastique et produit moulé formé à partir de celle-ci
WO2018117603A1 (fr) Composition pour marbre artificiel
WO2021107540A1 (fr) Composition de résine thermoplastique et produit moulé formé à partir de celle-ci

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18875346

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2020515945

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18875346

Country of ref document: EP

Kind code of ref document: A1