WO2019063562A1 - Procédé pour la préparation d'une mousse de polyuréthane - Google Patents

Procédé pour la préparation d'une mousse de polyuréthane Download PDF

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Publication number
WO2019063562A1
WO2019063562A1 PCT/EP2018/075998 EP2018075998W WO2019063562A1 WO 2019063562 A1 WO2019063562 A1 WO 2019063562A1 EP 2018075998 W EP2018075998 W EP 2018075998W WO 2019063562 A1 WO2019063562 A1 WO 2019063562A1
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WIPO (PCT)
Prior art keywords
chemical compounds
chemical
particle size
size distribution
suspension
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PCT/EP2018/075998
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English (en)
Inventor
Joo-Hee KANG
Ercan Uenveren
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Solvay Sa
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Publication of WO2019063562A1 publication Critical patent/WO2019063562A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2207/00—Foams characterised by their intended use
    • C08J2207/04—Aerosol, e.g. polyurethane foam spray
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/06—Polyurethanes from polyesters

Definitions

  • the present invention relates to processes for the preparation of polyurethane foams comprising a step wherein at least two chemical compounds, of which at least one has a low particle size, release a chemical and/or physical blowing agent by decomposition, polyurethane foams prepared by such processes as well as compositions comprising at least one polyol and a chemical compound with a low particle size capable of releasing a chemical and/or physical blowing agent by thermally- and/or chemically- induced degradation and uses of such compositions.
  • Polyurethane foams can be prepared by reacting an appropriate amount
  • the invention makes available improved polyurethane or modified polyurethane foams as well as improved processes for the preparation of (modified) polyurethane foams. It is an objective of the present invention to provide a process which is safer, more economical and/or more ecological.
  • the invention concerns a process for the preparation of a polyurethane foam or a modified polyurethane foam which comprises chemically and/or physically decomposing at least two chemical compounds so as to provide a blowing agent.
  • at least one of the chemical compounds has a particle size distribution expressed as a D50 of equal to or less than 1000 nm, preferably equal or below 500 nm, more preferably equal to or below 250 nm.
  • the process comprises chemically decomposing at least one of the chemical compounds.
  • the at least two chemical compounds comprise inorganic carbonates, more preferably the at least two chemical compounds comprise inorganic carbonates, preferably the at least two chemical compounds comprise NaHC0 3 , KHCO3, more preferably NaHC0 3 and KHCO3.
  • the at least two chemical compounds comprise (NH 4 )HC0 3 or (NH 4 ) 2 C0 3 . It is understood that the thermal decomposition of (NH 4 )HC0 3 or (NH 4 ) 2 C0 3 would result in the release of NH 3 and thus, in the possible formation of urea groups rather than urethane groups.
  • a foam comprising urea bonds thus formed shall also be deemed to fall under the definition of polyurethane foam.
  • the at least two chemical compounds comprise a hydrate of an inorganic salt, preferably the at least two chemical compounds comprise Na 2 SO 4 '10 H 2 0.
  • Polyurethane foams are generally prepared by contacting two separate compositions.
  • the so-called B-side which generally consists of isocyanates or mixtures of isocyanates.
  • the so-called A-side comprises all other components used in the production of the foam, notably the polyols or mixtures polyols. This definition of the A-side and the B-side is widely followed in Europe and is also used herein.
  • the A-side usually also comprises the blowing agents, flame retardants, catalysts, surfactants and other auxiliary agents.
  • the polyurethane foam can be prepared, for example, by mechanical mixing of A-side and B-side e.g. in a conventional mixer or by spray foaming.
  • the polyurethane foam is prepared by spray foaming.
  • Spray foaming means that A-side and B-side are joined under pressure in a spray nozzle and afterwards are applied directly onto the space where the insulation is required, e.g. a wall, roof or building assembly.
  • Blowing agents are chemical compounds which are capable of producing a cellular structure or matrix during the polyurethane foam formation.
  • Chemical blowing agents are known in the art.
  • the term "chemical blowing agent” is intended to denote a blowing agent which chemically reacts with at least one of the components of the compositions used in the foam blowing process.
  • water can be used as a chemical blowing agent as it forms C0 2 in the reaction with an isocyanate.
  • the C0 2 thus formed is used to create the cellular structure in the foam.
  • the term "chemical blowing agent” as used herein is intended to mean a chemical blowing agent which is formed in the decomposition reaction of at least one of the chemical compounds.
  • Physical blowing agents are also known in the art.
  • the term "physical blowing agent” is intended to denote a blowing agent which generally does not react chemically with one of the components of the compositions used in the foam blowing process. Suitable physical blowing agents include carbon dioxide, carbon monoxide, nitrogen, and hydrogen. Specifically, carbon dioxide is used as a physical blowing agent.
  • the term "physical blowing agent” as used herein is intended to mean a physical blowing agent which is formed in the decomposition reaction of at least one of the chemical compounds.
  • polyurethane foam is intended to denote polymers resulting essentially from the reaction of polyols with isocyanates. These polymers are typically obtained from formulations exhibiting an isocyanate index number from 100 to 180.
  • modified polyurethane foam is intended to denote polymers resulting from the reaction of polyols with isocyanates that contain, in addition to urethane functional groups, other types of functional groups, in particular triisocyanuric rings formed by trimerization of isocyanates. These modified polyurethanes are normally known as polyisocyanurates (PIR). These polymers are typically obtained from formulations exhibiting an isocyanate index number from 180 to 550.
  • the polyurethane and the modified polyurethane foam is a rigid, closed-cell foam.
  • Any isocyanate conventionally used to manufacture such foams can be used in the process according to the invention. Mention may be made, for example, of aliphatic isocyanates, such as hexamethylene diisocyanate, and aromatic isocyanates, such as tolylene diisocyanate or diphenylmethane diisocyanate.
  • polyol is intended to denote a compound containing more than one hydroxy 1 group in the structure, e.g. the compound may contain 2, 3, or 4 hydroxyl groups, also preferably 5 or 6 hydroxyl groups, and is intended to comprise a polyol of a single defined chemical structure as well as a mixture of polyols of different chemical structures.
  • synthetic polyols are also preferred.
  • polymeric polyols more preferably polyester or poly ether polyols. Suitable examples for polyester polyols include polycaprolactone diol and diethylene glycol terephthalate.
  • polyether polyols include polyethylene glycol, e.g. PEG 400, polypropylene glycol and poly(tetramethylene ether) glycol. Also preferred are polyetherpolyols based on carbohydrates, glycerine or amines. Examples for suitable carbohydrate bases include sucrose and sorbitol. Most preferred are brominated polyether glycols, e.g. polyetherpolyol B 350 (CAS-No.: 68441-62- 3). Especially suitable is the mixture of polyetherpolyol B 350 and triethyl phosphate, which can be obtained under the brand name IXOL® B 251 from Solvay.
  • At least one further component selected from a flame retardant, a foam stabilizer, a catalyst, a surfactant and a co-blowing agent can be added to the B-side or preferably, to the A-Side.
  • the co-blowing agent can be selected from the chemical and/or physical blowing agents as described above.
  • Chemical co-blowing agent as used in this invention is intended to denote a component comprised in the A-side which can react with the isocyanate of the B-side. It is believed that the energy released from this reaction in form of heat is accelerating the further foam producing process.
  • Preferable chemical co- blowing agents include water, NH 3 , primary amines, secondary amines, alcohols, preferably difunctional or trifunctional alcohols; hydroxylamine, and
  • aminoalcohols Especially preferred are bifunctional or multifunctional amines, glycols or glycerols. Suitable examples include diaminoethane, 1,3- diaminopropane and triethanolamine.
  • Preferable physical co-blowing agents comprise alkanes, e.g. propane or cyclopropane, fluorinated alkanes (HFCs) as well as fluorinated alkenes (HFOs).
  • HFCs and HFOs mention may be made, for example, of 1,1, 1 ,3,3- pentafluorobutane (HFC 365mfc), 1,1,1,2-tetrafluoroethane (HFC- 134a), 1,1,1,2,3,3,3-heptafluoropropane (HFC 227ea), 1,1,1,3,3-pentafluorpropane (HFC 245fa), halogenated olefins like HFO-1234yf, HFO-1234zr and HFO- 1233zd, or mixtures of said alkanes and alkenes.
  • HFCs 1,1, 1 ,3,3- pentafluorobutane
  • HFC- 134a 1,1,1,2-te
  • a co-blowing agent In case a co-blowing agent is used, it is preferably used in a range of 1 to 20 wt%, more preferably 2 to 10 wt%, most preferably 3 to 7 wt%, based on the total weight of the A- side.
  • any flame retardant conventionally used in the manufacture of such foams can be used. Mention may be made, for example, of flame retardants based on phosphorous esters. Suitable examples include triethylphosphat (TEP), tris(2- chlorisopropyl)phosphate (TCPP), dimethylpropane phosphonate (DMPP), diethylethane phosphonate (DEEP)triethyl phosphate, trischloroisopropyl phosphate .
  • TEP triethylphosphat
  • TCPP tris(2- chlorisopropyl)phosphate
  • DMPP dimethylpropane phosphonate
  • DEEP diethylethane phosphonate
  • the amount of flame retardant used generally varies from approximately 0.05 to 50 parts by weight per 100 parts by weight of polyol, preferably 1 to 25, more preferably 10 to 20.
  • Suitable catalysts include compounds that catalyze the formation of the -NH-CO-O- urethane bond by reaction between a polyol and an isocyanate or that activate the reaction between an isocyanate and water, such as tertiary amines and organic tin, iron, mercury or lead compounds. Mention may in particular by made, as tertiary amines, of triethylamine,
  • ⁇ , ⁇ -dimethylcyclohexylamine N-methylmorpholine, N-ethylmorpholine, dimethylethanolamine, diaza[2.2.2]bicyclooctane (triethylenediamine) and substituted benzylamines, such as ⁇ , ⁇ -dimethylbenzylamine, and
  • N,N,N',N",N"-pentamethyldiethylenetriamine Mention may in particular be made, as organic tin or lead compounds, of dibutyltin dilaurate, stannous octanoate and lead octanoate.
  • Other suitable catalysts intended for the manufacture of modified polyurethane (polyisocyanurate) foams include compounds that catalyse the trimerization of isocyanates to triisocyanurates. A mixture of catalysts can also be used.
  • the amount of catalyst used generally varies from
  • the amount of the composition according to the invention is from 1 to 80 parts by weight per 100 parts by weight of polyol. It is preferably from 10 to 60 parts by weight per 100 parts by weight of polyol.
  • foam stabilizer conventionally used in the manufacture of such foams can be used. Mention may be made, for example, of siloxane polyether copolymers. In practice, the amount of foam stabilizer used generally varies from approximately 0.05 to 10 parts by weight per 100 parts by weight of polyol, preferably 0.5 to 3.0, more preferably 1 to 2.
  • thermalally decomposing is intended to denote the
  • the elevated temperature is a result of the exothermic chemical reactions involved in the formation of the foam, e.g. a result of the reaction of an isocyanate with a polyol.
  • the elevated temperature is supplied by an external energy source, more preferably by pre-heating any or all of the components of the A- or B-side or of the equipment used in the foaming process.
  • Elevated temperature is intended to denote a temperature which is above ambient temperature. Suitable temperatures are from 25 to 150 °C, preferably from 35 to 120 °C, more preferably from 50 to 80 °C.
  • a specific example of a thermally-induced decomposition is the decomposition of NaHC0 3 or KHC0 3 .
  • the elevated temperature is above the decomposition temperature of sodium bicarbonate, which is 50 °C, or 100 °C (KHC0 3 ).
  • the chemical compounds releases the chemical and/or physical blowing agent by thermally-induced decomposition. More preferably the chemical compound releases the chemical and/or physical blowing agent by thermally- induced decomposition in the absence of an acidic activator.
  • the A-side or the B-side or both A-side and B-side may be pre-heated before the production of the foam. They may be pre-heated to a temperature of from 25 °C to about 80 °C, preferably from 30 °C to 60 °C, more preferably from 40 to 50 °C. Said pre-heating step may be conducted in the storage tank containing the A- and/or B-side.
  • mixing head itself may be heated to pre-heat the A and/or B-side immediately before the mixing step. If the foam production is performed by a spray foaming process the spray nozzle itself may be heated.
  • the term "chemically decomposing” is intended to denote a decomposition of the chemical compound which is mainly affected by the chemical reaction of the chemical compound with an activator, preferably with a basic or acidic activator.
  • Suitable acidic activators include Bronsted acids, for example carboxylic acids, specifically citric acid, acetic acid and formic acid.
  • the acidic activator can be formed in situ during the foaming process.
  • a suitable example is acetic acid which can be formed in situ from acidic anhydride by reaction with water.
  • NaHC0 3 is used in combination with acidic anhydride.
  • the chemical compound releases the chemical and/or physical blowing agent by chemically- induced decomposition, more preferably in the presence of an acidic activator, most preferably in the presence of citric acid, acetic acid, polyphosphoric acid and/or formic acid.
  • the acid activator is a dicarboxylic acid, e.g. oxalic acid, malonic acid, succinic acid, glutaric acid or adipic acid.
  • the acid activator is preferably comprised in the A- side.
  • the acid activator is added via a third line to the spraying nozzle simultaneously during the spray foaming process.
  • the chemical compound releases both a chemical and a physical blowing agent. More preferably, the chemical compound releases both a chemical and a physical blowing agent by thermally- induced decomposition.
  • the chemical compound is an inorganic carbonate.
  • the inorganic carbonates are suitably selected from carbonates and bicarbonates.
  • examples of inorganic carbonates include LiHC0 3 , Li 2 C0 3 , Na 2 C0 3 , K 2 C0 3 , KHC0 3 , Rb 2 C0 3 , Cs 2 C0 3 , CsHC0 3 , BeC0 3 , MgC0 3 , Mg(HC0 3 ) 2 , CaC0 3 , Ca(HC0 3 ) 2 , SrC0 3 , BaC0 3 , MnC0 3 , FeC0 3 , CoC0 3 , NiC0 3 , CuC0 3 , Ag 2 C0 3 , ZnC0 3 , CdC0 3 , A1 2 (C0 3 ) 3 , T1 2 C0 3 , PbC0 3 , (NH 4 ) 2 C0 3 , NH 4 HC0 3 , (BiO)
  • At least one of the chemical compounds is a hydrate of an inorganic salt, more preferably the hydrate of a salt of an alkaline metal or an alkaline earth metal, most preferably Na 2 S0 4 - 10 H 2 0.
  • the at least one of the chemical compounds has a particle size distribution expressed as a D50 of equal to or above 10 nm, preferably equal to or above 50 nm, more preferably equal to or above 100 nm.
  • the particle size distribution expressed as a D50 is equal to or higher than 1 nm, preferably equal to or higher than 10 nm. More preferable is from 25 to 250 nm, most preferably between 50 and 150 nm. Specifically, from 60 to 100 nm.
  • the particle size distribution according to the present invention is given as a D50 value meaning that 50% of a sample's mass is comprised of particles smaller than the given value.
  • the particle size distribution can be measured using a Laser Diffraction Particle Size Analyser (Beckmann Coulter® LS 230). The sample is added to the instrument where it is added to an isopropanol medium at room temperature.
  • Chemical compounds with a particle size distribution in the inventive range are commercially available. Alternatively, they can be prepared, for example by controlled precipitation from suitable starting materials. For example, NaHCC>3 with a suitable particle size distribution can be precipitated from a saturated solution of sodium chloride by addition of ammonium bicarbonate, filtrated and collected.
  • Chemical compounds with a particle size distribution in the inventive range can also be prepared by reducing the particle size of the chemical compound.
  • this reduction in particle size is performed in a mill.
  • a particularly suitable mill is a ball mill, also called planetary mill, bead mill or pearl mill.
  • a loose solid grinding medium is agitated together with the chemical compound to achieve a milling and/or grinding effect.
  • the solid grinding medium comprises hard objects made for example of flint, steel, glass or ceramic, e.g. zirconia.
  • the shape of the grinding medium may vary and can be selected for example from a sphere, an ovoid, a polyhedron, or a torus.
  • a sphere is especially suitable.
  • the size of the grinding medium is from 0.01 to 1.00 mm, preferably between 0.03 to 0.10 mm, more preferably around 0.05 mm.
  • the particle size of the chemical compound can also be reduced by co- milling.
  • the chemical compound is subjected to a milling step in the presence of co-grinding agent, preferably a co-grinding agent having a greater hardness than the chemical compound.
  • co-grinding agent preferably a co-grinding agent having a greater hardness than the chemical compound.
  • hardness refers to the hardness according to the Mohs scale.
  • Suitable examples for co-grinding agents include silica, sand, zeolithes, and oxides of metals, preferably alkaline metals or alkaline earth metals, such as Ce0 2 , Zr0 2 , MgO or ZnO.
  • the co-milling can be performed according to the procedures as disclosed in US5466470.
  • the co- milling agent can preferably also be a chemical compound capable of releasing a chemical and/or physical blowing agent.
  • a mixture of NaHC03 and NaSC 10H 2 O can be co-milled.
  • the co-milling step is most preferably conducted in a ball mill.
  • the particle size of the chemical compound can be reduced after suspending it in either the B-side or in at least one component of the B-side, e.g. in an isocyanate or a mixture of isocyanates used in the foam blowing process. More preferably, the particle size of the chemical compound can be reduced after suspending it in either the A-side or in at least one component of the A-side, e.g. in at least one polyol used in the foam blowing process. Also preferably, the particle size of the chemical compound can be reduced after suspending it in at least one flame retardant, e.g. in triethyl phosphate and/or trischloroisopropyl phosphate.
  • Another aspect of the invention concerns a process comprising the steps of al) preparing a suspension comprising the first of the at least two chemical compounds and at least one component of the A-side,
  • step al) subjecting the suspension formed in step al) to a treatment to reduce the particle size distribution of the chemical compound
  • step a4) subjecting the suspension formed in step a3) to a treatment to reduce the particle size distribution of the chemical compound
  • the process comprises the steps of al) preparing a suspension comprising the first of the at least two chemical compounds in a milling solvent,
  • step al) subjecting the suspension formed in step al) to a treatment to reduce the particle size distribution of the chemical compound
  • step a4) subjecting the suspension formed in step a3) to a treatment to reduce the particle size distribution of the chemical compound
  • the obtained suspensions can then be used in the preparation of the foams as described above.
  • the treatment to reduce the particle size distribution comprises a milling step, more preferably a milling step using a ball mill.
  • the treatment to reduce the particle size distribution comprises a sonication treatment step. Also preferably, the treatment to reduce the particle size distribution comprises a simultaneous milling and sonication treatment step.
  • the particle size of the chemical compound is reduced by milling in a milling solvent.
  • milling solvent is intended to denote a solvent in which the chemical compound is subjected to a milling step and which is removed before the chemical compound is used for the foam production.
  • the boiling point of said milling solvent is preferably between 50 and 150 °C, more preferably between 60 and 120 °C.
  • suitable milling solvents include alcohols, water, hydrocarbons, hydrofluorocarbons, and chlorinated hydrocarbons.
  • the alcohol is ethanol, propanol, isopropanol, isobutanol.
  • perfluoropolyethers especially the Galden® product range from Solvay Fluor GmbH, specifically Galden® HT55.
  • the concentration of the chemical compound, specifically the NaHC0 3 , in the milling solvent is between 10 and 70 wt%, preferably, 20 to 50 wt%, and more preferably between 30 and 40 wt%.
  • the milling step is performed in the presence of a surfactant.
  • a surfactant avoids the agglomeration and/or aggregation of the chemical compound.
  • “Surfactant” shall denote organic compounds that are amphiphilic, meaning they contain both a hydrophobic group and a hydrophilic group.
  • non-ionic surfactants include without limitation linear alcohol ethoxylates, polyoxy ethylene alkylphenol ethoxylates, polyoxy ethylene alcohol ethoxylates, polyoxy ethylene esters of fatty acids, polyoxy ethylene alkylamines, alkyl polyglucosides, ethylene oxide-propylene oxide copolymers or a combination thereof.
  • Suitable cationic surfactants include without limitation quaternary ammonium salts, ethoxylated quaternary ammonium salts, or a combination thereof.
  • a preferred cationic surfactant may have a carbon chain length of 8-20 carbon atoms.
  • Surfactants having phosphate, carboxylate, sulphonate or sulphate groups as hydrophilic groups are preferred.
  • surfactants having polyether or polyester based side chains as hydrophobic groups are preferred.
  • Preferred polyether based side chains have 3 to 50, preferably 3 to 40, in particular 3 to 30 alkyleneoxygroups.
  • the alkyleneoxygroups are preferably selected from the group consisting of methyleneoxy, ehtyleneoxy, propyleneoxy and butyleneoxy groups.
  • the length of the polyether based side chains is generally from 3 to 100, preferably from 10 to 80 nm.
  • Suitable examples of such surfactants are represented by phosphoric acid derivatives in which one oxygen atom of the P(O) group is substituted by a C3- C10 alkyl or alkenyl radical.
  • the surfactant may be, for example, a phosphoric diester having a polyether or polyester based side chain and an alkenyl group moieties. Alkenyl groups with 4 to 12, in particular 4 to 6 carbon atoms are highly suitable.
  • phosphoric esters with poly ether/polyester side chains Especially preferred are phosphoric esters with poly ether/polyester side chains, phosphoric ester salts with polyether/alkyl side chains and surfactants having a deflocculating effect, based for example on high molecular mass copolymers with groups processing pigment affinity.
  • the milling solvent is removed after the milling step and a suspension of the chemical compound in the A-side or at least one component of the A-side is prepared, i.e. an exchange of the suspension medium is performed.
  • This exchange can be performed by conventional means, e.g. using a rotary evaporator and a column containing ion-exchange resin.
  • Another aspect of the present invention concerns a (modified)
  • polyurethane foam obtainable by the inventive process as outlined above.
  • said foam comprises cells with an average cell size measured according to ASTM D 3576 from 10 nm to 1 ⁇ , preferably from 50 nm to 500 nm, more preferably from 100 nm to 250 nm.
  • the polyurethane or modified polyurethane foam according to the invention is preferably a rigid closed-cell foam.
  • the polyurethane or modified polyurethane foam can also be selected from a flexible or semi-flexible foam, e.g. for the production of show soles or for padding of saddles, or integral skin foam.
  • the polyurethane foam or modified polyurethane foam is produced by spray foaming.
  • the inventive process is used to produce discontinuous or continuous panels, tubes for pipe insulation, sandwich panels, laminates and block foams.
  • the inventive foam is used for noise cancellation.
  • Still another aspect of the present invention concerns a composition comprising at least one polyol and a chemical compound capable of releasing a chemical and/or physical blowing agent by thermally- and/or chemically- induced degradation wherein the chemical compound has a particle size distribution expressed as a D50 of equal to or less than 1 ⁇ as well as the use of such compositions in the preparation of a polyurethane or modified polyurethane foam.
  • the thermal conductivity of the inventive foams can be measured using the norm "EN 12667: Thermal performance of building materials and products" by means of a guarded hot plate and a heat flow meter.
  • Yet another aspect of the invention concerns a composition
  • a composition comprising at least one polyol and at least two chemical compounds capable of releasing a chemical and/or physical blowing agent by thermally- and/or chemically-induced decomposition wherein at least one of the chemical compounds has a particle size distribution expressed as a D50 of equal to or less than 1000 nm, preferably a composition wherein the at least two chemical compounds comprise NaHC0 3 and KHC0 3 .
  • 13.5 wt% NaHC0 3 (Bicar® from Solvay) was dispersed in a polyol mixture comprising 16.7 g IXOL® B251, 50.0 g Stepanol® 2412 and 33.3 g Voranol® RN 490 by using a PENDRAULIK overhead dissolver at 10000 rpm for 30 min. Subsequently, the resulting mixture was subjected to a milling step in a bead mill DISPERMAT® SL-C 25 (manufacturer: VMA-Getzmann GmbH) using Zr02 beads (diameter: 0.5 mm) at 200 rpm for 12.5 h. Subsequently, the mixture was subjected to a sonication step for 1 h.
  • the particle size distribution of the NaHC0 3 in the resulting suspension was measured as described above and showed a D50 of 0.85 ⁇ .
  • 13.5 wt% KHC0 3 is dispersed in a polyol mixture comprising 16.7 g IXOL® B251, 50.0 g Stepanol® 2412 and 33.3 g Voranol® RN 490 by using a
  • PENDRAULIK overhead dissolver at 10000 rpm for 30 min. Subsequently, the resulting mixture is subjected to a milling step in a bead mill DISPERMAT® SL-C 25 (manufacturer: VMA-Getzmann GmbH) using Zr02 beads (diameter: 0.5 mm) at 200 rpm for at least 10 h.
  • the particle size distribution of the KHCO3 in the resulting suspension is measured as described above and showed a D50 of below 0.5 ⁇ .
  • NaHC0 3 (Bicar® from Solvay) is dispersed in Galden® HT55 by using a PENDRAULIK overhead dissolver at 3000 rpm for 1 hour to give 10 kg of a slurry containing 40 wt% NaHC0 3 .
  • the suspension is grinded by ball milling (Netzsch Zeta® RS) with Zr0 2 beads for 4 h.
  • the particle size distribution expressed as a D50 achieved in this step is from 50 to 150 nm depending on the total milling time.
  • the slurry is then evaporated on a rotary evaporator and the solid obtained is re-dispersed in a polyol mixture comprising 16.7 g IXOL® B251, 50.0 g Stepanol® 2412 and 33.3 g Voranol® RN 490 by using a
  • PENDRAULIK overhead dissolver at 10000 rpm for 30 min. Afterwards other components of the A-side are added to this polyol/NaHC0 3 mixture.
  • Two polyol suspensions are formed by mixing of equal mixtures (i.e. each 50wt% of each suspension) of either Examples 1 and la or of Examples la and lb.
  • the resulting suspension are each used to prepare a polyurethane foam using the components as shown in the table below:
  • Polyols, Mixed Bicarbonate Suspension and flame retardant are stirred using a PENDRAULIK overhead dissolver in a 500 mL paper cup. Subsequently, MDI is added and stirring continues at 2500 rpm for 10 s after which the mixture looks uniform and bubbles start to appear. After the stirrer is stopped, the mixture is poured into a 1 L paper cup to allow the foam to expand and cure for at least one day. The foam obtained can be used to prepare discontinuous panels Optionally, 5.5 Part by weight of phoshphoric acid can be added to the A-Side and stirred together with the Polyols, Mixed Bicarbonate Suspension and flame retardant.
  • Example 3 Spray foaming A polyurethane foam (spray foam) is prepared by conventional means using the components as shown in the table below.
  • the Mixed Bicarbonate Suspension as prepared above are used to prepare polyisocyanurate foam using the components as shown in the table below:
  • An MDI index of 200 was applied to prepare the polyisocyanurate foams.
  • 80 g of the Mixed Bicarbonate Suspension prepared as above, the catalyst, the flame retardant and the surfactant are stirred using a PENDRAULIK overhead dissolver in a 500 mL paper cup.
  • MDI is added and stirring continues at 2500 rpm for 10 s after which the mixture looks uniform and bubbles start to appear.
  • the mixture is poured into a 1 L paper cup to allow the foam to expand and cure for at least one day.
  • the foam obtained can be used to prepare discontinuous panels.
  • 5.5 pbw of phosphoric acid is added simultaneously from a separate line using a three-way spraying gun.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

La présente invention concerne des procédés pour la préparation de mousses de polyuréthane comprenant une étape dans laquelle un composé chimique de faible granulométrie libère un agent gonflant chimique et/ou physique par décomposition, des mousses de polyuréthane préparées par de tels procédés ainsi que des compositions comprenant au moins un polyol et un composé chimique de faible granulométrie pouvant libérer un agent gonflant chimique et/ou physique par dégradation induite thermiquement et/ou chimiquement et des utilisations de telles compositions.
PCT/EP2018/075998 2017-09-27 2018-09-25 Procédé pour la préparation d'une mousse de polyuréthane WO2019063562A1 (fr)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4968724A (en) * 1990-05-31 1990-11-06 Arco Chemical Technology, Inc. Hydrated salt systems for controlled release of water in polyurethane foams
US5466470A (en) 1993-07-13 1995-11-14 Church & Dwight Co., Inc. Co-micronized bicarbonate salt compositions
EP1630192A2 (fr) * 2004-07-28 2006-03-01 Inoac Corporation Procedé de preparation de mousses de polyurethane avec sels hydrates comme agent gonflant
US9139683B2 (en) 2009-11-06 2015-09-22 Bayer Materialscience Ag Process for producing a polyurethane foam by means of supercritical or near-critical blowing agent
WO2017144651A1 (fr) * 2016-02-26 2017-08-31 Solvay Sa Procédé pour la préparation d'une mousse de polyuréthane

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4968724A (en) * 1990-05-31 1990-11-06 Arco Chemical Technology, Inc. Hydrated salt systems for controlled release of water in polyurethane foams
US5466470A (en) 1993-07-13 1995-11-14 Church & Dwight Co., Inc. Co-micronized bicarbonate salt compositions
EP1630192A2 (fr) * 2004-07-28 2006-03-01 Inoac Corporation Procedé de preparation de mousses de polyurethane avec sels hydrates comme agent gonflant
US9139683B2 (en) 2009-11-06 2015-09-22 Bayer Materialscience Ag Process for producing a polyurethane foam by means of supercritical or near-critical blowing agent
WO2017144651A1 (fr) * 2016-02-26 2017-08-31 Solvay Sa Procédé pour la préparation d'une mousse de polyuréthane

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