WO2019046921A1 - Mistura entre um bioestimulante à base de folcisteína e um agrotóxico de interesse obtendo ação potencializadora dos resultados de ordens qualitativa, quantitativa e temporal observados em uma cultura agrícola de uma planta de interesse. - Google Patents

Mistura entre um bioestimulante à base de folcisteína e um agrotóxico de interesse obtendo ação potencializadora dos resultados de ordens qualitativa, quantitativa e temporal observados em uma cultura agrícola de uma planta de interesse. Download PDF

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Publication number
WO2019046921A1
WO2019046921A1 PCT/BR2018/050323 BR2018050323W WO2019046921A1 WO 2019046921 A1 WO2019046921 A1 WO 2019046921A1 BR 2018050323 W BR2018050323 W BR 2018050323W WO 2019046921 A1 WO2019046921 A1 WO 2019046921A1
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WO
WIPO (PCT)
Prior art keywords
methyl
mixture
interest
acetate
folcysteine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/BR2018/050323
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English (en)
French (fr)
Portuguese (pt)
Inventor
Gustavo YEPEZ GIL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arysta LifeScience do Brasil Industria Quimica e Agropecuaria SA
Original Assignee
Arysta LifeScience do Brasil Industria Quimica e Agropecuaria SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP22157259.7A priority Critical patent/EP4059348A1/en
Priority to UAA202002732A priority patent/UA125977C2/uk
Priority to US16/643,998 priority patent/US11388900B2/en
Priority to MX2020002603A priority patent/MX2020002603A/es
Priority to CA3075123A priority patent/CA3075123A1/en
Priority to JP2020514610A priority patent/JP7365333B2/ja
Priority to EP18852950.7A priority patent/EP3679796A4/en
Priority to KR1020207009638A priority patent/KR102646452B1/ko
Priority to CN202210069347.6A priority patent/CN114568442A/zh
Priority to EA202090911A priority patent/EA202090911A1/ru
Priority to CN201880068441.1A priority patent/CN111436187B/zh
Priority to CR20200153A priority patent/CR20200153A/es
Application filed by Arysta LifeScience do Brasil Industria Quimica e Agropecuaria SA filed Critical Arysta LifeScience do Brasil Industria Quimica e Agropecuaria SA
Publication of WO2019046921A1 publication Critical patent/WO2019046921A1/pt
Priority to PH12020500447A priority patent/PH12020500447A1/en
Priority to ZA2020/01421A priority patent/ZA202001421B/en
Anticipated expiration legal-status Critical
Priority to CONC2020/0003263A priority patent/CO2020003263A2/es
Priority to US17/750,623 priority patent/US12185719B2/en
Priority to JP2022194319A priority patent/JP2023025196A/ja
Ceased legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P21/00—Plant growth regulators

Definitions

  • Synergy Generally, it can be defined as a combination of two elements so that the result of that combination is greater than the sum of the results that these elements would have separately. Thus, synergy is only a sum of factors directed towards the same end.
  • [3] - Mixture consists of two or more substances, whether simple or compound, which may be a homogeneous or non-homogeneous solid or liquid mixture.
  • [4] - Homogeneous mixture it is a mixture of substances in which the result of the union process the substances can no longer be identified in isolation as in the beginning.
  • the appearance of the homogeneous blend is uniformity with the naked eye, and are also mixtures which present only one phase.
  • [5] - Plants includes germinating seeds, cuttings, emergent seedlings and established vegetation, including roots and above ground portions, eg, leaves, stems, flowers, fruits, branches, limbs, roots and the like.
  • Plant of agricultural interest any type of plant intended for commercial consumption, which may be edible or non-edible plant, floral or non-floral, trees, grasses (grasses, grasses or grasses).
  • [10] - Biostimulants are substances applied to plants with the goal of increasing nutritional efficiency; increase resistance to stress caused by biotic and abiotic factors; increase productivity and / or improve the quality of the commodity.
  • Growth regulators are substances composed of hormones that, when applied to the plant, act in the different physiological and metabolic processes of plants.
  • Biotic factors can be understood as the sum of all the effects caused by organisms in an ecosystem, which condition the populations that form it.
  • Abiotic factors can be understood as the sum of all the influences that living beings can receive in an ecosystem derived from physical, chemical or physico-chemical aspects of the environment, such as light, solar radiation, temperature, wind, water, soil composition, pressure and others.
  • Folcisteina is an amino acid derivative, whose purpose is to promote biochemical reactions that help in the prevention or reduction of stress caused by abiotic and biotic factors. It also favors the vegetative growth of plants.
  • Agrochemicals also referred to as agricultural pesticides, pesticides, pesticides, biocides, agrochemicals, biologicals or phytosanitary products, are generic names for the various chemical, semiochemical, biochemical or biological products used in agriculture.
  • pesticides or pesticides can be defined as any substance capable of controlling a pest that may pose a risk or inconvenience to populations or the environment. They may also be defined as substances or mixtures of substances intended to prevent or directly kill insects, mites, mollusks, rodenticides, fungi (fungicides), weeds (herbicides) , bacteria (antibiotics and bactericides) and other forms of animal or plant life that are harmful to public health and agriculture.
  • WHO World Health Organization
  • [17] - Agrotoxic of interest defined as any formulation in agrochemical industry and commercially known, with desirable potentiation of its technical effects and minimization of its harmful side effects when applied to an agricultural crop.
  • the invention relates to an inventive solution which finds outstanding benefit in the agricultural sector, with a wide application spectrum, as an aid in the cultivation of all kinds of plants of agricultural interest, for example in the cultivation of rice, maize, sorghum, corn, wheat, barley, oats, cereals (rye), triticale, soybeans, beans (and their varieties such as white beans, azuki), cotton, fruits (such as peaches, apples, pineapple), potatoes, sweet potatoes, canola, flax, peas, lentils, mustard, chickpea, sunflower, seedling alfalfa, onion, pasture (such as grass and alfalfa), cane of sugar, beet, tomato, Stevia, saffron, cassava, cucurbitaceae, among others.
  • the applicant with expertise in technological development in the agricultural sector identified the need to potentiate the results of a crop of a given crop, under the qualitative, quantitative and temporal orders, considering the unavoidable fact that the agricultural crop plants of interest are subject to biotic and / or abiotic factors.
  • pesticides are products used in agriculture to control pests (such as insects, diseases or weeds) that can cause crop damage.
  • Agrochemicals can also be called agricultural pesticides or agrochemicals.
  • a.l Insecticides for the control of insects, mites, nematodes and molluscs.
  • a.2 Fungicides used to control diseases caused by fungi, bacteria and viruses.
  • a.3 Herbicides intended for weed control.
  • herbicide glufosinate ammonium herbicide application using a spray volume of 300 l / ha, in maize culture, carried out by UDI Pesquisa, in Uberlêtia-MG, whose quantitative result (productivity) is described in table 1.
  • DAA Days after application [38] It is important to note that the list of examples reported is not limited to maize, bean and laboratory crops or to the use of pesticides of interest glufosinate ammonium, fomesafem + fluazifop-P-ethylic, propargite and abamectin. performance can be understood in an extensive way for the application of any type of agrochemicals of interest in the most varied agricultural crops, keeping the due differences of performance.
  • the biostimulant mixture based on folcysteine and an agrotoxic of interest leads to a reduction in the stress and / or phytotoxicity effects affecting plants in the development of an agricultural crop when subjected to the isolated application of pesticides interest and consequently results in improved yield and quality of post-harvest fruits / grains.
  • the use of the inventive blend potentiates the qualitative effects of the agrotoxic of interest based on their use in isolation.
  • M the mixture obtained between follistatin-based biostimulant and at least one agrotoxic of interest:
  • X folcysteine-based biostimulant, where the concentration in the mixture can be defined as ranging from 0.50 to 2000 g ai / ha;
  • Y at least one agrotoxic of interest, such as:
  • Herbicides In this embodiment, the mixture between folcysteine-based biostimulant and at least one agrotoxic of herbicidal-like (Y1) -type interest is defined by the following formula:
  • compositions used to reduce crop damage may comprise at least one herbicide (Y1) selected from the group of active ingredients: (2,4-D), (2,4-D + picloram), (2,4 (Gibberellic acid + benzyladenine), (acifluorfemodic), (acifluorfemodic + bentazone), (acifluorfem sodium + bentazone), (acifluorfemodic acid + gibberellic acid + kinetin), acellifen), (alachlor + atrazine), alachlor + trifluralin), (aloxidim), (ametrine), (ametrine + clomazone), (ametrine + diurom), (ametrine + diurom + MCPA), (amicarbazone + flumioxazin), (amicarbazone + flazasulfurom), (amicarbazone + hexazinone + diuron), (amicarbazone + clomazone), (amicarbazone + flumioxazin), (
  • Imazametabenzo (imazamyx), (imazapique), (imazapique + imazapyr), (imazapique + imazethapyr), (imazapyr),
  • Fungicides In this embodiment, the folcysteine-based biostimulant mixture and at least one fungicidal-type (Y2) -like pesticide of interest is defined by the following formula:
  • compositions used to reduce lesions in the culture may comprise at least one fungicide (Y2) selected from the group of active ingredients: (2-phenylphenol), (8-hydroxyquinoline sulfate), (copper acetate) acetate (acibenzolar-S-methyl), (benzohydroxamic acid), (dehydroacetic acid, (allyl alcohol), (aldimorph), (ampropylphos), (anilazine), (azaconazole), (sodium azide), sodium azide ), (azithromycin), (azoxystrobin), (azoxystrobin + benzovindiflupir), (azoxystrobin + cyproconazole),
  • fungicide selected from the group of active ingredients: (2-phenylphenol), (8-hydroxyquinoline sulfate), (copper acetate) acetate (acibenzolar-S-methyl), (benzohydroxamic acid), (dehydroacetic acid, (allyl alcohol), (aldimorph), (ampropylpho
  • Metominostrobin (metominostrobin + tebuconazole),
  • Insecticides In this embodiment, the mixture between folcysteine-based biostimulant and at least one pesticide of interest of the insecticidal (Y3) type is defined by the following formula:
  • compositions used to reduce crop damage may comprise at least one insecticide (Y3) selected from the group of active ingredients: (1,4-dimethoxybenzene), (4,8-dimethyldecanal), (5,9-dimethylpentadecane), (abamectin), (mite Neoseiulus californicus), ( acetate), (acequinoyl), (acetamiprid), (acetamiprid + alpha-cypermethrin),
  • Y3 selected from the group of active ingredients: (1,4-dimethoxybenzene), (4,8-dimethyldecanal), (5,9-dimethylpentadecane), (abamectin), (mite Neoseiulus californicus), ( acetate), (acequinoyl), (acetamiprid), (acetamiprid + alpha-cypermethrin),
  • chlorophenyls chloropicrins, chlorpyrifos, chlorpyrifos methyl, clothianidin, codlelure, Cotesia flavipes, coumafos, cryolite, - (CrylAb, CrylAc, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb and Cry34 / 35Abl), (deltamethrin), (demotonS-methyl), (difenotefuran), (diafonurom), (diazinone), (dicofol) (dimethylvinphos), (dimethoate), (disulfoton), (dithianone), (DNOC), (ecklonia max),
  • phosphate (phosphate), (phosphate), (phosphate), (phosphate), (phosphate of calcium), (magnesium phosphide), (zinc phosphide), (phosphine ), (phosmet), (fosthiazate), (phosmet),
  • pyrimidines pyridaben, pyralidyl, pyrimidiphenyl, pyrimidiphenyl, pyrimidiphenyl, pyrimidiphenyl,
  • Solid mixture in the form of soluble powders, granules, pellets, emulsifiable concentrate, impregnated with active ingredients.
  • active ingredients X and (Y) to be adhered to the plant.
  • the solid mixture may be represented by the formula:
  • Ms Solid biostimulant mixture based on folcysteine and at least one agrotoxic of interest
  • X Folcysteine, where the concentration can be defined as ranging from 0.50 to 2000 g ai / ha;
  • Zl Dyes, non-limiting examples being inorganic pigments, such as iron oxide, titanium oxide and Prussian Blue, and organic dyes such as alizarin dyes, azo dyes and metal dyes phthalocyanine;
  • Z2 trace nutrients such as iron, manganese, boron, copper, cobalt, molybdenum and zinc salts;
  • Z3 Adhesive coatings, non-limiting examples being carboxymethylcellulose, natural and synthetic polymers in various forms, such as powders, granules or latex, gum arabic, polyvinyl alcohol and polyvinyl acetate, phospholipids such as cephalins and lecithins, and phospholipids synthetic.
  • the solid mixture (Ms) will preferably be applied by sprinkling and spreading techniques.
  • Liquid mixture in the form of liquid ingredients, solutions, suspensions, emulsions, can be prepared with the active ingredients (X) and (Y) presented in isolation, and when in use are tank mixtures with dilution of the mixture to obtain a liquid solution or emulsions. Alternatively, it can be presented with the components (X) and (Y) already mixed, being sufficient to be diluted to obtain the tank mixture. For both situations, the mixture will preferably be applied by spray and atomization techniques.
  • a mixture or suspension with at least one stabilizing agent (W1) is usually preliminarily prepared with a solvent, or diluent (W2), for the preparation of the liquid mixture. Thereafter, an appropriate amount of adjuvanting agents (W3) is added. A coloring agent (W4) and trace nutrients (W5) can also be added to this preliminary reading. Finally, the folcysteine (X) and the agrotoxic of interest (Y) are added, the final mixing being carried out to a diluted and homogeneous mixing state, ready to be applied to the agricultural crop by spraying, for example.
  • liquid mixture may be represented by the formula:
  • Ml liquid mixture obtained from folcysteine-based biostimulant and at least one pesticide of interest
  • X Folcysteine, the concentration of which is in the range of 0.50 to 2,000 g ai / ha;
  • Y pesticide of interest;
  • W2 diluents which include, for example, a non-polar solvent (W21) immiscible with water, or an aprotic solvent
  • W21 non-polar solvents include, for example, substituted or unsubstituted aliphatic or aromatic hydrocarbons and alkyl esters, which include, without limitation, methyl, ethyl and butyl esters of canola
  • methyl ester is Agent 2416-21 produced by Stepan Company (22 W. Frontage Road, Northfield, Illinois);
  • W21 water-miscible polar aprotic solvents include, for example, alkyl lactates, isopropyl lactate, alkyl carbonates, polyethylene glycols, polyethylene glycol alkyl ethers, polypropylene glycols and polypropylene glycol alkyl ethers, or mixtures thereof;
  • W3 adjuvant agents include, for example, surfactants (emulsifier), culture oil, fertilizers, dispersing agents, compatibility agents, foam activators, suds suppressors, correctives and coloring dyes.
  • An adjuvant may be present in any desired amount.
  • a formulation may contain 1% to 3% adjuvant, 3% to 8% adjuvant, 8% to 16% adjuvant, 17% to 30% adjuvant or 30% or (e.g. % or more) adjuvants;
  • W4 Dyes, non-limiting examples being those inorganic pigments such as iron oxide, titanium oxide and Prussian Blue, and organic dyes such as alizarin dyes, azo dyes and metal dyes phthalocyanine;
  • W5 trace nutrients such as iron, manganese, boron, copper, cobalt, molybdenum and zinc salts.
  • Y Glufosinate ammonium herbicide.
  • Ml Mixture between folcysteine-based biostimulant and agrochemical of interest, glufosinate ammonium herbicide.
  • AI2 Herbicide (AI2)
  • M2 A mixture of Folcysteine-based biostimulant and herbicidal herbicide-based fomesafen + fluazifop-P-ethylic herbicide.
  • Example 3 Complement to the test performed by T. Cobbucci, in S ⁇ o Jo ⁇ o da Aliança-GO, whose results were revealed in example 2, where 4 replicates and 7 treatments were performed, in the first one (treatment 1 ), plant sampling is maintained without any treatment (Witness), and in the subsequent three (treatments 2, 3 and 4) the mixture between a biostimulant based on Folcysteine and an herbicide of herbicidal interest AI2 (based on fomesafem + fluazifop P-ethyl), which is sprayed in a volume of 200 l / ha of this mixture applied to maize plants in the V4 stage.
  • a biostimulant based on Folcysteine and an herbicide of herbicidal interest AI2 (based on fomesafem + fluazifop P-ethyl)
  • AI2 based on fomesafem + fluazifop P-ethyl
  • AI3 Herbicide + Fungicide
  • M2 mixture between Folcysteine-based biostimulant and agrotoxic of interest, fomesafem + fluazifop-p-ethyl herbicide.
  • M3 mixture between Folcysteine-based biostimulant and pesticide of interest, fungicide based on pyraclostrobin.
  • M2 Mixture between Folcysteine-based biostimulant and agrotoxic of interest, fomesafem + fluazifop-P-ethylic herbicide.
  • M3 Mixture between Folcysteine-based biostimulant and pesticide of interest, fungicide based on pyraclostrobin.
  • Example 5 Laboratory experiment conducted by Unesp in Jaboticabal-SP, with the objective of assessing control of mite control, specifically Tetranychus urt ⁇ cae, with 4 replicates and 4 treatments, the first one (treatment 1 ) a sampling of the plant without any treatment (Witness), the second a sampling only with treatment by isolated Folcisteina (treatment 2), the third a sampling of plant with treatment only with acyrocidal interest of acaricidal AI 4 (based on Propargito), identified as (treatment 3), and the fourth treatment where a mixture of a biostimulant based on Folcysteine and an agrichemical of acaricidal interest AI 4 (based on Propargite), identified as (treatment 4), is used in the laboratory condition. See results presented in the following table: Table 9 Biostimulant
  • X biostimulant based on Folcysteine.
  • Y agrotoxic of interest, propargite-based acaricide.
  • Example 6 Laboratory experiment carried out by Unesp in Jaboticabal-SP, with the objective of measuring control of mites, specifically Tetranychus urticae, with 4 replicates and 4 treatments, the first one (treatment 1 ) a sampling of the plant without any treatment (Witness), the second (treatment 2) being a sampling only with Folcysteine treatment alone, the third (treatment 3) a plant sampling with treatment only with agrotoxic of acaricidal interest AI5, and fourth (treatment 4) a mixture of a biostimulant based on Folcysteine and an agrichemical of acaricidal interest AI5 (based on abamectin), applied in laboratory condition, see results presented in the following table:
  • X biostimulant based on Folcysteine.
  • Y pesticide of interest, acaricide based on abamectin.
  • references to a range of 90-100% includes 91%, 92%, 93%, 94%, 95%, 95%, 97%, etc., as well as 91.1%, 91.2% %, 91.3%, 91.4%, 91.5%, etc., 92.1%, 92.2%, 92.3%, 92.4%, 92.5%, etc., and so on. .
  • Reference to a 90-100% range includes 92.2% to 97.5%, 91.5 to 94.5, etc.
  • Reference to a series of ranges, such as 0.1% to 15% overlapping intervals and between 1% and 10% ranges from 0.1% to 1%, 0.1% to 10%, 1% and 15%, and 10% and 15%.

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  • Life Sciences & Earth Sciences (AREA)
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  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Toxicology (AREA)
  • Botany (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
PCT/BR2018/050323 2017-09-06 2018-09-05 Mistura entre um bioestimulante à base de folcisteína e um agrotóxico de interesse obtendo ação potencializadora dos resultados de ordens qualitativa, quantitativa e temporal observados em uma cultura agrícola de uma planta de interesse. Ceased WO2019046921A1 (pt)

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CN201880068441.1A CN111436187B (zh) 2017-09-06 2018-09-05 基于叶酸杂质10的生物刺激素和感兴趣的农用化学品的共混物
US16/643,998 US11388900B2 (en) 2017-09-06 2018-09-05 Mixture of a folcysteine-based biostimulant and an agrotoxic substance of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest
MX2020002603A MX2020002603A (es) 2017-09-06 2018-09-05 Mezcla de un biostimulante a base de folcisteína y un agrotóxico de interés que da como resultado una acción cuantitativa, cualitativa y potenciadora de resultados relacionada con el tiempo, como se observó en un cultivo agrícola de una planta de interés.
CA3075123A CA3075123A1 (en) 2017-09-06 2018-09-05 Blend of a folcysteine-based biostimulant and an agrotoxic of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest
JP2020514610A JP7365333B2 (ja) 2017-09-06 2018-09-05 対象植物の農作物において観察される、定量的、定性的および時間的な効果に対する増強作用をもたらす、フォルシステイン系生物刺激剤と対象の毒性農薬とのブレンド
EP18852950.7A EP3679796A4 (en) 2017-09-06 2018-09-05 MIXTURE OF A FOLCYSTEIN-BASED BIOSTIMULAN AND AN AGROTOXIC SUBSTANCE OF INTEREST THAT LEADS TO A QUANTITATIVE, QUALITATIVE AND TIME-RELATED RESULTS-ENHANCING EFFECT, LIKE IT IS IN AN AGRICULTURAL FARMING
KR1020207009638A KR102646452B1 (ko) 2017-09-06 2018-09-05 관심대상의 식물의 농작물에서 관찰되는 정량적, 정성적 및 시간-관련 결과-강화 작용을 제공하는, 폴시스테인계 생물 자극제와 관심대상의 농약의 블렌드
CN202210069347.6A CN114568442A (zh) 2017-09-06 2018-09-05 基于叶酸杂质10的生物刺激素和感兴趣的农用化学品的共混物
EA202090911A EA202090911A1 (ru) 2017-09-06 2018-09-05 Смесь биостимулятора на основе фолцистеина и представляющего интерес агротоксического вещества, приводящая к количественному, качественному и зависимому от времени улучшающему результаты действию, наблюдаемому на сельскохозяйственной культуре представляющего интерес растения
EP22157259.7A EP4059348A1 (en) 2017-09-06 2018-09-05 Mixture of a folcysteine-based biostimulant and an agrotoxic substance of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest
UAA202002732A UA125977C2 (uk) 2017-09-06 2018-09-05 Суміш біостимулятора на основі фолцистеїну й агротоксичної речовини, що становить інтерес, яка забезпечує підсилюючу результат дію відносно показників кількості, якості та часу, виявлену на сільськогосподарській культурі, що становить інтерес
CR20200153A CR20200153A (es) 2017-09-06 2018-09-05 Mezcla de un biostimulante a base de folcisteína y un agrotóxico de interés que da como resultado una acción cuantitativa, cualitativa y un cultivo agrícola de una planta de interés
PH12020500447A PH12020500447A1 (en) 2017-09-06 2020-03-05 Blend of a folcysteine-based biostimulant and an agrotoxic of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest
ZA2020/01421A ZA202001421B (en) 2017-09-06 2020-03-05 Mixture of a folcysteine-based biostimulant and an agrotoxic substance of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest
CONC2020/0003263A CO2020003263A2 (es) 2017-09-06 2020-03-20 Mezcla de un biostimulante a base de folcisteína y un agrotóxico de interés que da como resultado una acción cuantitativa, cualitativa y potenciadora de resultados relacionada con el tiempo, como se observó en un cultivo agrícola de una planta de interés
US17/750,623 US12185719B2 (en) 2017-09-06 2022-05-23 Mixture of a folcysteine-based biostimulant and an agrotoxic substance of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest
JP2022194319A JP2023025196A (ja) 2017-09-06 2022-12-05 対象植物の農作物において観察される、定量的、定性的および時間的な効果に対する増強作用をもたらす、フォルシステイン系生物刺激剤と対象の毒性農薬とのブレンド

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US17/750,623 Division US12185719B2 (en) 2017-09-06 2022-05-23 Mixture of a folcysteine-based biostimulant and an agrotoxic substance of interest resulting in a quantitatively, qualitatively and time-related result-potentiating action as observed in an agricultural crop of a plant of interest

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