WO2018232567A1 - 鞋用除臭剂组合物及其除臭片结构 - Google Patents

鞋用除臭剂组合物及其除臭片结构 Download PDF

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Publication number
WO2018232567A1
WO2018232567A1 PCT/CN2017/089004 CN2017089004W WO2018232567A1 WO 2018232567 A1 WO2018232567 A1 WO 2018232567A1 CN 2017089004 W CN2017089004 W CN 2017089004W WO 2018232567 A1 WO2018232567 A1 WO 2018232567A1
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Prior art keywords
deodorant
shoes
deodorizing
sheet structure
covering layer
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PCT/CN2017/089004
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English (en)
French (fr)
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林信璋
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林信璋
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Priority to PCT/CN2017/089004 priority Critical patent/WO2018232567A1/zh
Priority to CN201710757529.1A priority patent/CN109125774A/zh
Publication of WO2018232567A1 publication Critical patent/WO2018232567A1/zh

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/10—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined specially adapted for sweaty feet; waterproof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/21—Use of chemical compounds for treating air or the like

Definitions

  • the present invention relates to a deodorant composition, and more particularly to a deodorant composition for shoes and a deodorant sheet structure thereof.
  • Foot odor has been plaguing many people.
  • the problem of foot odor is not gender-specific, generally the cause of foot odor is nothing more than high temperature, humidity, sweating and mold infection, Among them, sweating and dampness are one of the biggest causes of foot odor in the feet; the study pointed out that there are 600 sweat glands per square centimeter in the foot, which is a hundred times more than the armpits, especially in the toes.
  • "Nutrition soup” consisting of salt, glucose, vitamins and amino acids.
  • the “nutrition soup” is an excellent diet for bacteria and mold. Therefore, the foot in the sweat gland is very beneficial to the growth of bacteria and mold.
  • Japanese Patent No. 11-147915 discloses a particle composed of a porous crosslinked polymer, and the porous crosslinked polymer contains an aromatic polyethylene compound and an aromatic monovinyl compound, and discloses The particles can be used as an adsorbent for organic matter. However, the adsorption of malodorous components has not been described, and the performance as a deodorant is not sufficient.
  • the polymer particles containing a metal component are such that the polymer particles have the functions of antibacterial property and odor resistance inherently by the metal particles by supporting the metal particles on the porous body.
  • the method has a problem that a reducing agent for reducing a metal salt is required, and the cost becomes high, and the ligand of the metal salt becomes useless when the metal salt is reduced to metal fine particles.
  • Japanese Patent No. 3-157327 discloses a powdered gas composition
  • a powdered gas composition comprising: a hydrophilic inorganic powder such as talc silicic anhydride, kaolin or hydroxyaluminum; and a deuterated petroleum gas and methyl ether.
  • a propellant At least one of a propellant; at least one of a nonionic surfactant and a silicone oil; and ethanol.
  • the powder in the powder gas composition has insufficient dispersibility, and the oily feeling is strong, so that the skin does not feel excellent refreshing feeling of the powder.
  • Japanese Laid-Open Patent Publication No. 5-229925 discloses a liquid sweat-making composition in which a sweating substance such as aluminum chlorohydrate or the like, and an alcohol and a polyether-modified silicone are blended.
  • the sweat-making composition is a polyether-modified silicone and an alcohol to prevent crystallization of the powder in the composition and to suppress white residue of the sweat-making salt.
  • the powder other than the sweating agent is blended in the sweat-absorbing composition to enhance the skin feeling such as refreshing feeling, the effect of suppressing white residue cannot be obtained.
  • Japanese Patent No. 8-12545 discloses a sweating and deodorizing agent containing an astringent such as aluminum hydroxychloride, a bacteriostatic agent such as triclosan, or the like, and containing a specific Spherical silicone rubber powder with liquid oily ingredients. Further, as the oily enamel used for the adjustment, a solid or liquid silicone oil containing a polyoxyalkylene modified polysiloxane is described. However, in the above publication, attention is paid only to the feeling-lifting action of the silicone rubber powder, and there is no mention at all about the improvement in dispersibility of the spherical silicone powder, and the suppression of white residue is not sufficient.
  • Japanese Patent No. 11-335254 discloses a gas-gel composition containing a composite powder composed of a heterogeneous organopolysiloxane in an inorganic powder such as aluminum hydroxychloride. And a liquid oil such as isopropyl myristate.
  • the gas gel composition is also the same as Japanese Patent No. 8-12545, and although it has a refreshing feeling of use, it does not sufficiently suppress white residue.
  • An object of the present invention is to provide a deodorant composition, in particular, a deodorant composition for shoes and a deodorant sheet structure thereof, wherein the deodorant can be stably composed and conveniently used, in order to solve the above problems. Shows a stable deodorizing effect.
  • the invention provides a deodorant composition for shoes and a deodorant sheet structure thereof, wherein the deodorant is made of potassium sulphate dodecahydrate which is highly soluble in water (English: Potassium alum, chemical formula: KAl(SO 4 ) 2 ⁇ 12H 2 O) and a composition of sodium carbonate (sodium carbonate, chemical formula: Na 2 CO 3 ) which is easily soluble in water.
  • the deodorant is made of potassium sulphate dodecahydrate which is highly soluble in water (English: Potassium alum, chemical formula: KAl(SO 4 ) 2 ⁇ 12H 2 O) and a composition of sodium carbonate (sodium carbonate, chemical formula: Na 2 CO 3 ) which is easily soluble in water.
  • Another object of the present invention is to provide a deodorant composition for shoes and a deodorant sheet structure thereof, wherein the deodorant sheet has a simple structure, is convenient to use, and can be used by the user to know that the deodorizing failure should be replaced with a new deodorizing sheet. Time point.
  • the invention provides a deodorant composition for shoes and a deodorant sheet structure thereof, wherein the structure of the deodorant sheet is mainly pressed and sealed by a gas-permeable and water-absorbing upper coating layer and a lower coating layer, and sealed therein.
  • the accommodating space is filled with the deodorizing powder, and after the plurality of accommodating spaces are filled with the deodorizing powder, the ridge is slightly raised upward, and a plurality of anti-slip grains are disposed on the bottom surface of the lower cladding layer to be placed thereon.
  • the user's sole When it is used in the shoe, it does not slide, and at the same time, the user's sole can directly contact a plurality of accommodating spaces of the slight ridge, and the deodorizing powder in the accommodating space passes through the upper coating layer which absorbs water and has good gas permeability.
  • the lower coating layer absorbs the sweat, moisture and sterilization at the bottom of the foot, so that the foot stays dry in the shoe, thereby inhibiting the growth of bacteria and mold, and achieving the deodorizing effect.
  • the upper coating layer and the lower coating layer of the deodorizing sheet are a non-woven fabric having good air permeability and water absorption, or a woven fabric having good air permeability and water absorption.
  • Figure 1 is a graph of the degree of deodorization and time of the present invention.
  • Figure 2 is a plan view showing the appearance of the structure of the deodorizing sheet of the present invention.
  • Figure 3 is a schematic cross-sectional view showing the structure of the deodorizing sheet of the present invention.
  • Figure 4 is an exploded perspective view showing the structure of the deodorizing sheet of the present invention placed in the shoe;
  • Fig. 5 is a schematic view showing the use of the deodorant sheet structure of the present invention.
  • the invention provides a deodorant composition for shoes and a deodorant sheet structure thereof, wherein the deodorant is potassium potassium sulfate dodecahydrate which is highly soluble in water (English: Potassium alum, chemical formula: KAl (SO 4 2 ⁇ 12H 2 O) and a composition of sodium carbonate (sodium carbonate, chemical formula: Na 2 CO 3 ) which is easily soluble in water. among them:
  • Potassium aluminum sulfate dodecahydrate also known as: alum, white peony, potassium strontium, potassium aluminum strontium, potassium alum, is a double salt of potassium sulfate and aluminum sulfate containing crystal water.
  • the density was 1.757 g/cm3 and the melting point was 92.5 °C. Loss of 9 molecules of crystal water at 64.5 ° C, loss of 12 molecules of crystal water at 200 ° C, very soluble in water, insoluble in ethanol, odorless. It has the functions of antibacterial, sterilization, disinfection, deodorization and purification of water quality and convergence, and can be used as a traditional Chinese medicine.
  • ionization produces Al3+.
  • Al3+ combines with OH ⁇ produced by water ionization to form aluminum hydroxide.
  • the aluminum hydroxide colloidal particles have a positive charge and meet negatively charged silt particles, and the charges are neutralized. .
  • "Sweet alum" can be obtained by adding sodium carbonate.
  • Soda commonly known as soda, soda ash, soda crystals, washing soda, is often called "alkali” in life.
  • Chemical formula: Na 2 CO 3 which is a white powder under normal conditions and is a strong electrolyte. It has a density of 2.532 g/cm 3 and a melting point of 850 ° C. It is soluble in water and has salty properties.
  • sodium carbonate will react with carbon dioxide and water to form sodium hydrogencarbonate: Na 2 CO 3 +CO 2 +H 2 O ⁇ 2NaHCO 3 will also cause side reactions: After carbon dioxide (CO 2 ) is dissolved in water, a portion of the carbon dioxide combines with water to form carbonic acid.
  • a deodorant composition for shoes When the deodorant is placed in the shoe, the hot air and sweat of the foot are absorbed by the non-woven fabric coated with the deodorant and the deodorant is dissolved, so that the smell of the deodorant is accelerated and discharged. Full of the inner space of the shoes to achieve the effect of sterilization and deodorization.
  • the actual test results In a single unit of 2.5 gram dose placed in a shoe and the general normal person sweating ratio and the continuous use of the shoe odor level of 100% as an example, the actual test results:
  • the odor in the shoe can be improved by at least 30% (the amount of deodorant on the first day is about 0.5 g);
  • the odor in the shoes will be improved by at least 60% on the second day (the deodorant consumption of the deodorant is about 0.5 g on the next day);
  • the odor in the shoe can be improved by at least 90% (the amount of deodorant on the third day is about 0.5 g);
  • the improvement of the odor in the shoe can reach 100% (the deodorization amount of the deodorant on the fourth day is about 0.5 g);
  • the odor in the shoe can be improved by 100% (the deodorant on the fifth day is about 0.5 gram);
  • the improvement of odor in the shoes can reach 100% (the amount of deodorant on the sixth day is 0 grams);
  • the odor in the shoe can be improved by 100% (the amount of deodorant on the seventh day is about 0 g);
  • the degree of odor in the shoe was 10% (the amount of deodorant on the eighth day was about 0 g);
  • the degree of odor in the shoe is 20% (the amount of deodorant on the ninth day is about 0 g);
  • the degree of odor in the shoe is 60% (the amount of deodorant on the tenth day is about 0 g);
  • the degree of odor in the shoe is 100% (the amount of deodorant on the eleventh day is about 0 g);
  • Fig. 1 If it is represented by a graph of deodorization degree and time, as shown in Fig. 1. It can be seen that if the deodorant is calculated by the amount of decontamination of 0.5 gram per day, the deodorizing effect reaches the peak on the fourth day, completely deodorizing, and until the seventh day, the deodorizing effect is maintained at the peak stage without odor. On the eighth day, the inside of the shoe will gradually grow due to bacteria, and the shoes will have a slight taste, but it is not obvious. Until the eleventh day, the bacteria in the shoes will multiply, resulting in obvious odor.
  • the deodorant of the present invention can be effective for about seven days; at least 30% of the sterilization and deodorization effects from the first day, and 100% sterilization to the fourth day.
  • the deodorizing effect is effective for up to seven days, and the user does not have any greasy and sticky feeling during the period, and has no adverse effect on the user's skin. Therefore, the deodorant combination for shoes of the present invention is used.
  • the object not only has the effect of eliminating the odor in the shoe, inhibiting the growth of bacteria and mold, and has no adverse effect on the skin of the user.
  • FIG. 2 and FIG. 3 are schematic plan views of the appearance of the deodorizing structure of the present invention and a schematic cross-sectional view of the deodorizing structure.
  • the deodorizing structure of the present invention can be made into a sheet-like body A in a unit dose, and the sheet-like body A is mainly pressed and sealed by the upper cladding layer and the lower cladding layer 1, 2 a plurality of accommodating spaces 3 are disposed in the plurality of accommodating spaces, and the deodorizing agent 4 is assembled in the plurality of accommodating spaces; wherein the bottom surface of the lower cladding layer 2 is provided with a plurality of anti-slip particles 20, and a plurality of accommodating spaces 3 containing the deodorant 4 are slightly raised upward; when used, the sheet A is placed in the shoe 5, as shown in FIG.
  • the upper cladding layer 1 of the sheet-like body A can be utilized. Direct contact with the bottom surface 6 of the user's foot, through the upper cladding layer 1 slightly raised and containing a plurality of accommodating spaces 3 containing the deodorant 4, so that the user's sole 6 can completely feel the bulge (as if massage As shown in FIG. 5, the deodorant agent 4 is melted by the hot air, moisture, and sweat in the upper cover layer 1 and the lower cladding layer 2 which are ventilated and well absorbed, and is emitted.
  • the smell of the deodorizing agent 4 fills the inside of the shoe and fills the smell of the deodorizing agent, thereby achieving sterilization, antibacterial, deodorizing and inhibiting the growth of bacteria and mold in the shoe, and making the foot in the shoe
  • the inside can maintain the effect of being dry and the like.
  • the upper cladding layer 1 and the lower cladding layer 2 may be, for example, a nonwoven fabric which is excellent in gas permeability and water absorption, or a textile fabric which is excellent in air permeability and water absorption.
  • the deodorant agent 4 is a compound of 90% potassium acahydrate potassium carbonate (potassium alum) and 10% sodium carbonate; by virtue of being highly soluble in water, having antibacterial, bactericidal, astringent and deodorizing effects, In order to achieve the purpose of sterilization, antibacterial and deodorization.
  • the accommodating space 3 of the slightly raised ridges becomes flat, whereby the user can know the deodorant 4 of the deodorant 4 At the point of failure, the new deodorizing sheet should be discarded and replaced.
  • the "deodorant composition for shoes and the structure of the deodorant sheet thereof" of the present invention can provide a simple and stable composition and convenient use of the composition of the medicament, and exhibit stable stability.
  • the accommodating space 3 is provided in the plurality of accommodating spaces, and the deodorizing agent 4 is configured to form a deodorizing sheet structure for the shoe; when it is used, the under bag can be used as long as it is placed in the shoe 5
  • the plurality of anti-slip particles 20 designed on the bottom surface of the coating 2 prevent the sliding of the sliding particles in the shoe, and the upper cladding layer 1 directly contacts the bottom surface 6 of the user, and the upper cladding layer 1 is slightly raised and
  • the interior houses a plurality of accommodating spaces 3 for the deodorant 4, so that the bottom surface 6 of the user can It is felt that there is a bulge block like a massage block, and the deodorant agent 4 is melted by the heat, moisture and sweat generated by the upper cover layer 1 and the lower cover layer 2 which are well ventilated and well absorbed
  • Deodorizing the smell of the deodorant 4 filling the inside of the shoe and filling the smell of the deodorizing agent, thereby achieving sterilization, antibacterial, deodorizing and inhibiting the growth of bacteria and mold in the shoe, and making the foot in the foot
  • the inside of the shoe can maintain the effect of being dry and the like.

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Abstract

一种鞋用除臭剂组合物及其除臭片结构，其除臭剂是以10％的碳酸钠和90％的十二水合硫酸铝钾比例混合成温和性佳及展现稳定的除臭功效的鞋用除臭剂；而其除臭片结构是由上包覆层（1）及下包覆层（2）胶合压制并密封成内具有多个容置空间（3），并于所述多个容置空间（3）内均装盛有除臭药剂（4）所组构而成；下包覆层（2）底面设有若干个止滑粒（20），多个容置空间（3）均呈现向上微微隆起状，其除臭药剂（4）通过透气、吸水佳的上包覆层（1）及下包覆层（2）得受到鞋内热气、湿气、汗水产生溶化现象并散发出所述除臭药剂（4）的气味，使鞋内充满、布满所述除臭药剂（4）的气味，借此能达到在鞋内杀菌、抗菌、除臭及能抑制细菌、霉菌的孳生，以及使脚部在鞋内能保持干爽等的效果。

Description

鞋用除臭剂组合物及其除臭片结构 技术领域
本发明是有关一种除臭剂组合物，特别是指一种鞋用除臭剂组合物及其除臭片结构。
背景技术
脚臭一直困扰着许多人。脚臭的恶臭气味，就连自己都受不了，更遑论他人侧目掩鼻；脚臭的问题并无性别区分，一般而言会发生脚臭的原因不外乎高温、潮湿、多汗和霉菌感染，其中，多汗、潮湿是脚部发生脚臭的最大的原因之一；研究指出，脚部平均每平方公分有600个汗腺，比腋下多了百倍，尤其是在脚趾部，汗腺会分泌由盐、葡萄糖、维他命、氨基酸组成的“营养汤汁”，所述“营养汤汁”又是细菌、霉菌的绝佳饮食，因此，在汗腺发达的脚部是非常有利于细菌及霉菌的大量滋生繁殖，而大量的细菌及霉菌会留下大量的脂肪酸，也就是“咸鱼气味”、“臭酸气味”等恶臭气味。为了消除脚部在鞋内所散发出来的恶臭气味，现有技术公开有：
如日本专利第11-147915号公报中，其由多孔质交联聚合体所构成的粒子，所述多孔质交联聚合体则包含芳香族聚乙烯化合物，以及芳香族单乙烯化合物，且揭示有可将所述粒子用作可有机物的吸附剂。但是，关于对恶臭成分的吸附并未有记载，其作为除臭剂的性能并不充分。
另于日本专利第9-188778号公开，作为含有金属成分的聚合物粒子，是通过将金属微粒承载于多孔体上，而使聚合物粒具有金属微粒本来所具有的抗菌性及防臭性等功能。但是，所述方法含有下述问题：必需有使金属盐还原的还原剂，因成本变高，且所述金属盐的配位子在将金属盐还原为金属微粒时成为无用物。
在日本专利第3-157327号公报中，揭示有一种粉末气胶组成物，其特征为含有：滑石硅酸酐、高岭土、氯化羟铝等亲水性无机粉体；含有汳化石油气及甲醚中至少一的喷射剂；非离子型界面活性剂及硅酮油中的至少一；以及乙醇。然而，所述粉末气胶组成物中粉体的分散性并不充足，且油腻感强烈，无法使肌肤感到粉体优异的清爽感。
在日本专利第5-229925号公报中，记载有一种液状制汗组成物，其中调配有氯化羟铝等制汗剂物质、与醇类及聚醚改质硅酮。所述制汗组成物是通过聚醚改质硅酮与醇类来防止组成物中的粉末结晶化，并抑制制汗盐类的白色残。然而，于所述制汗组成物中调配有制汗剂以外的粉体以提升清爽感等肌肤感触时，且无法获得白色残留的抑制效果。
在日本专利第8-12545号公报中，揭示有一种制汗消臭剂，其含有氯化羟铝(aluminum hydroxychloride)等收敛剂、玉洁新(triclosan)等制菌或杀菌剂，并含特定的球状硅酮橡胶粉末与液状的油性成分。而作为可调配使用的油性成侚，则记载有包含聚氧化烯改质聚硅氧炕的固形或液状的硅酮油。然而，于所述公报中，仅着眼于硅酮橡胶粉体的感触提升作用，完全未提及对于所述球状硅酮粉末的分散性提升，对于白色残留的抑制并不充足。
在日本专利第11-335254号公报中，揭示有一种气胶组成物，其于氯化羟铝(aluminum hydroxychloride)等无机粉体中，含有异种的有机聚硅氧烷所构成的复合粉体，以及肉荳蒄酸异丙酯等液状油剂。然而，所述气胶组成物也与日本专利第8-12545号一样，虽具有清爽的使用感，但对于白色残留的抑制却不充足。
发明内容
本发明的目的在于，为解决上述问题，提供一种除臭剂组合物，特别是提供一种鞋用除臭剂组合物及其除臭片结构，其除臭剂可安定组成并方便使用，展现稳定的除臭功效。
本发明提供一种鞋用除臭剂组合物及其除臭片结构，其除臭剂是由极易溶于水的十二水合硫酸铝钾(英语：Potassium alum，化学式：KAl(SO4)2·12H2O)和易溶于水的碳酸钠(英语：sodium carbonate，化学式：Na2CO3)组成物。
本发明的另一目的在于，提供一种鞋用除臭剂组合物及其除臭片结构，其除臭片结构简单、使用方便且能让使用者知道其除臭失效应该更换新除臭片的时间点。
本发明提供一种鞋用除臭剂组合物及其除臭片结构，其除臭片结构主要是由透气、吸水性佳的上包覆层及下包覆层胶合压制并密封成内具有多个容置空间填充除臭粉体所构成，借所述多个容置空间内填满除臭粉体后向上微微隆起，及于下包覆层底面设若干个止滑粒，使其于置入鞋内使用时不致滑动，同时能让使用者的脚底直接接触微微隆起的多个容置空间，所述等容置空间内的除臭粉体，通过吸水、透气性佳的上包覆层及下包覆层，吸收脚底部的汗水、湿气及杀菌，令脚部在鞋内保持干爽，进而抑制细菌、霉菌的孳生，达到除臭的效果。
作为优选的方案，除臭片的上包覆层及下包覆层为透气、吸水性佳的无纺布或透气、吸水性佳的纺织布料。
为了对本发明的上述及其他方面有更佳的了解，下文特举较佳实施例，并配合所附图式，作详细说明如下：
附图说明
图1是本发明的除臭程度与时间的曲线图；
图2是本发明的除臭片结构外观平面示意图；
图3是本发明的除臭片结构结构剖面示意图；
图4是本发明的除臭片结构放置于鞋内的分解示意图；
图5是本发明的除臭片结构使用实施例示意图。
图中标记说明：
(1)…上包覆层            (2)…下包覆层；
(20)…止滑粒             (3)…容置空间；
(4)…除臭药剂            (A)…片状体。
具体实施方式
本发明是提供一种鞋用除臭剂组合物及其除臭片结构，其除臭剂是由极易溶于水的十二水合硫酸铝钾(英语：Potassium alum，化学式：KAl(SO4)2·12H2O)和易溶于水的碳酸钠(英语：sodium carbonate，化学式：Na2CO3)组成物。其中：
十二水合硫酸铝钾，又称：明矾、白矾、钾矾、钾铝矾、钾明矾，是含有结晶水的硫酸钾和硫酸铝的复盐。密度1.757g/cm3，熔点92.5℃。64.5℃时失去9个分子结晶水，200℃时失去12个分子结晶水，极易溶于水，不溶于乙醇，无气味。具有抗菌、杀菌、消毒、除臭及净化水质与收敛的作用，可用做中药。反应式：Al2(SO4)3+K2SO4+24H2O→2KAl(SO4)2·12H2O。明矾溶于水后电离产生了Al3+，Al3+与水电离产生的OHˉ结合生成了氢氧化铝，氢氧化铝胶体粒子带有正电荷，与带负电的泥沙胶粒相遇，彼此电荷被中和。加入碳酸钠可得“中性明矾”。
碳酸钠俗名苏打(soda)、纯碱(soda ash、soda crystals)、洗涤碱(washing soda)，生活中亦常称“碱”。化学式：Na2CO3，普通情况下为白色粉末，为强电解质。密度为2.532g/cm3，熔点为850℃，溶于水，具有盐的通性。在不断通入二氧化碳气体的情况下，碳酸钠会与二氧化碳、水共同反应生成碳酸氢钠：Na2CO3+CO2+H2O→2NaHCO3同时会发生副反应：
Figure PCTCN2017089004-appb-000001
二氧化碳(CO2)溶于水后，一部分二氧化碳会与水化合，形成碳酸。
碳酸钠遇酸会发生剧烈反应，同时生成二氧化碳：
Na2CO3+2H+→2Na++CO2+H2O
在水溶液中，碳酸钠会完全电解为碳酸根与钠离子，碳酸根会发生水解：
CO3 2-+H2O→HCO3 -+OH-
通过碳酸钠与十二水合硫酸铝钾对人体肌肤均无不良影响及本身的特性，以10％的碳酸钠和90％的十二水合硫酸铝钾比例混合成温和性佳及除臭功效稳定的鞋用除臭剂组合物。当除臭剂置入于鞋内使用时，脚部的热气和汗水被包覆除臭剂的无纺布吸收并溶化除臭剂，使所述除臭剂的气味得以加速散发出来，并布满整个鞋子内部空间，达到杀菌、除臭的效果。就以一单位2.5公克剂量置入于一只鞋内并以一般正常人出汗比及连续使用的鞋臭程度100％为例，经实际测试结果：
第一天鞋内臭味的改善程度至少可达30％(第一天除臭剂的消秏量约0.5公克)；
第二天鞋内臭味的改善程度至少可达60％(第二天除臭剂的消秏量约0.5公克)；
第三天鞋内臭味的改善程度至少可达90％(第三天除臭剂的消秏量约0.5公克)；
第四天鞋内臭味的改善程度可达100％(第四天除臭剂的消秏量约0.5公克)；
第五天鞋内臭味的改善程度可达100％(第五天除臭剂的消秏量约0.5公克)；
第六天鞋内臭味的改善程度可达100％(第六天除臭剂的消秏量0公克)；
第七天鞋内臭味的改善程度可达100％(第七天除臭剂的消秏量约0公克)；
第八天鞋内臭味产生程度10％(第八天除臭剂的消秏量约0公克)；
第九天鞋内臭味产生程度20％(第九天除臭剂的消秏量约0公克)；
第十天鞋内臭味产生程度60％(第十天除臭剂的消秏量约0公克)；
第十一天鞋内臭味产生程度100％(第十一天除臭剂的消秏量约0公克)；
若以除臭程度与时间的曲线图来表示，如图1所示。可知，除臭剂若以每日0.5公克的消秏量计算，第四天除臭功效达到顶峰，完全除臭，一直到第七天，其除臭效果一直维持在顶峰阶段，毫无臭味，到第八天时，鞋内会因细菌渐渐孳生，鞋内会产生微微味道，但不明显，直至第十一天，鞋内孳生的细菌倍增，致会产生明显的臭味出来。由上述实品实际测试结果证实，本发明的除臭剂的有效日约可达七天之久；从第一天至少有30％的杀菌、除臭效果，至第四天可完全达到100％杀菌、除臭的效果，除臭剂有效日达七日，且其间使用者绝无任何的油腻、粘着的感觉，对使用者肌肤亦无不良影响，是故，本发明的鞋用除臭剂组合物，不仅确实具有消除鞋内臭味、抑制细菌、霉菌的孳生的效果，且对使用者肌肤亦无不良影响。
请参阅图2、图3所示，是本发明的除臭结构外观平面示意图及除臭结构剖面示意图。由附图可知，本发明的除臭结构可以一单位药剂量制成的片状体A，所述片状体A主要是由上包覆层及下包覆层1，2胶合压制并密封成内具有多个容置空间3，并于所述多个容置空间内均装盛有除臭药剂4所组构而成；其中，下包覆层2底面并设有若干个止滑粒 20，而装盛有除臭药剂4后的多个容置空间3均向上微微隆起；于其使用时，只要将所述片状体A放入鞋内5，如图4所示，便可利用所述片状体A的下包覆层2底面若干个止滑粒20，防止所述片状体A在鞋内的可能滑动，同时可利用所述片状体A的上包覆层1直接接触使用者的脚底面6，通过上包覆层1上微微隆起且内装盛有除臭药剂4的多个容置空间3，令使用者脚底面6能完全感觉到有隆起块(犹如按摩块一般)，如图5所示，其除臭药剂4通过透气、吸水佳的上包覆层1及下包覆层2得受到鞋内热气、湿气、汗水产生溶化现象并散发出所述除臭药剂4的气味，使鞋内充满、布满所述除臭药剂的气味，借此能达到在鞋内杀菌、抗菌、除臭及能抑制细菌、霉菌的孳生，以及使脚部在鞋内能保持干爽等的效果。
上述上包覆层1及下包覆层2，可如：透气、吸水性佳的无纺布或透气、吸水性佳的纺织布料。
上述除臭药剂4为90％十二水合硫酸铝钾(potassium alum)与10％碳酸钠(sodium carbonate)的化合物；借其极易溶于水、具有抗菌、杀菌及收敛与除臭等作用，以达到杀菌、抗菌、除臭的目的。
当上述除臭药剂4的会因热气、汗水、湿气的作用产生溶化现象，令微微隆起的容置空间3变成平坦状，借此现象能让使用者知道所述等除臭药剂4的失效时间点应抛弃并所述更换新的除臭片了。
综上所述，本发明“鞋用除臭剂组合物及其除臭片结构”，确实能提供一种对人体肌肤无害且药剂组成成份简单并可安定组成及方便使用，展现稳定的除臭功效的鞋用除臭剂组成物，及结构简单、使用方便与成本低廉且能令使用者知悉其除臭失效应该换新除臭片的时间点的“鞋用除臭片结构”，以10％的碳酸钠和90％的十二水合硫酸铝钾比例混合成温和性佳的鞋用除臭剂；及利用上包覆层1及下包覆层2胶合压制并密封成内具有多个容置空间3，并于所述多个容置空间内均装盛有除臭药剂4所组构成鞋用除臭片结构；于其使用时，只要放入鞋内5，便可利用下包覆层2底面设计的若干个止滑粒20，防止其在鞋内的可能滑动，同时可利用其上包覆层1直接接触使用者的脚底面6，通过上包覆层1上微微隆起且内装盛有除臭药剂4的多个容置空间3，令使用者脚底面6能完全感觉到有隆起块犹如按摩块一般，其除臭药剂4通过透气、吸水佳的上包覆层1及下包覆层2得受到鞋内热气、湿气、汗水产生溶化现象并散发出所述除臭药剂4的气味，使鞋内充满、布满所述除臭药剂的气味，借此能达到在鞋内杀菌、抗菌、除臭及能抑制细菌、霉菌的孳生，以及使脚部在鞋内能保持干爽等的效果。
以上所述实施例仅是为充分说明本发明而所举的较佳的实施例，本发明的保护范围不限于此。本技术领域的技术人员在本发明基础上所作的等同替代或变换，均在本发明的保护范围之内。本发明的保护范围以权利要求书为准。

Claims (4)

  1. 一种鞋用除臭剂组合物，其特征在于，鞋用除臭剂组合物主要是由10％的碳酸钠和90％的十二水合硫酸铝钾的比例混合而成。
  2. 一种鞋用除臭片结构，其特征在于，除臭片结构主要是由上包覆层及下包覆层胶合压制并密封成内具有多个容置空间，并于所述多个容置空间内均装盛有除臭剂所组构而成；其中，下包覆层底面还设有若干个止滑粒，而装盛有除臭剂后的多个容置空间均呈现向上微微隆起状。
  3. 如权利要求2所述鞋用除臭片结构，其特征在于，所述除臭剂主要是由10％的碳酸钠和90％的十二水合硫酸铝钾的比例混合而成。
  4. 如权利要求2或3所述鞋用除臭片结构，其特征在于，除臭片的上包覆层及下包覆层由透气、吸水性佳的无纺布或透气、吸水性佳的纺织布料制成。
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CN2268412Y (zh) * 1996-09-16 1997-11-26 庄琪章 长效纯中药保健除臭鞋垫
JP2000197504A (ja) * 1999-01-07 2000-07-18 Shoei Sangyo Kk インソ―ル
CN2530490Y (zh) * 2001-12-25 2003-01-15 马兴均 药粒按摩保健鞋垫
CN2616095Y (zh) * 2003-04-03 2004-05-19 王辰杰 吸汗鞋垫
CN2667936Y (zh) * 2003-12-11 2005-01-05 黄金龙 一种鞋垫
CN101125214A (zh) * 2007-08-24 2008-02-20 李庆龙 除臭剂

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2268412Y (zh) * 1996-09-16 1997-11-26 庄琪章 长效纯中药保健除臭鞋垫
JP2000197504A (ja) * 1999-01-07 2000-07-18 Shoei Sangyo Kk インソ―ル
CN2530490Y (zh) * 2001-12-25 2003-01-15 马兴均 药粒按摩保健鞋垫
CN2616095Y (zh) * 2003-04-03 2004-05-19 王辰杰 吸汗鞋垫
CN2667936Y (zh) * 2003-12-11 2005-01-05 黄金龙 一种鞋垫
CN101125214A (zh) * 2007-08-24 2008-02-20 李庆龙 除臭剂

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