WO2018227842A1 - Catalyseur utilisé pour produire un biocarburant riche en aromatiques, et son procédé de préparation - Google Patents

Catalyseur utilisé pour produire un biocarburant riche en aromatiques, et son procédé de préparation Download PDF

Info

Publication number
WO2018227842A1
WO2018227842A1 PCT/CN2017/107943 CN2017107943W WO2018227842A1 WO 2018227842 A1 WO2018227842 A1 WO 2018227842A1 CN 2017107943 W CN2017107943 W CN 2017107943W WO 2018227842 A1 WO2018227842 A1 WO 2018227842A1
Authority
WO
WIPO (PCT)
Prior art keywords
biochar
catalyst
lignin
rich
solution
Prior art date
Application number
PCT/CN2017/107943
Other languages
English (en)
Chinese (zh)
Inventor
卜权
摩根•赫文•马里恩
梁江辉
Original Assignee
江苏大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 江苏大学 filed Critical 江苏大学
Publication of WO2018227842A1 publication Critical patent/WO2018227842A1/fr

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/084—Decomposition of carbon-containing compounds into carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/344—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
    • B01J37/346—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy of microwave energy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the invention belongs to the technical field of biomass catalytic pyrolysis, and in particular relates to a catalyst for producing an aromatic-rich biofuel and a preparation method thereof.
  • biomass energy resources including crops such as corn, wheat and rice, and residues of rice husk and sugar cane agricultural products, which can reach several hundred million tons per year.
  • Biomass has been identified as the most promising raw material for the production of renewable energy.
  • the yield and quality of the obtained liquid oil are low, the selectivity is poor, the catalyst activity is low, and it is easy to be deactivated. Therefore, it is necessary to increase the biomass pyrolysis liquid. The yield and quality of the product.
  • Biochar is a solid product formed by high-temperature pyrolysis of biomass under anaerobic anoxic state, which itself contains some mineral elements. Alkali metal elements such as Ca, Mg, Zn, etc., in addition, biochar has developed voids and specific surface area. Therefore, this study is based on biochar products formed by microwave pyrolysis biomass and is subjected to transition metal oxides. Modification, preparation of a biochar catalyst, using this biochar catalyst to solve the problem of bio-oil yield and quality in pyrolysis experiments.
  • Biomass consists mainly of cellulose, hemicellulose and lignin.
  • lignin accounts for 25% and is the second most abundant organic matter in the world (cellulose is the first).
  • Lignin is a complex phenolic polymer formed from three alcohol monomers (coumaryl alcohol, coniferyl alcohol, sinapyl alcohol).
  • coumaryl alcohol, coniferyl alcohol, sinapyl alcohol a complex phenolic polymer formed from three alcohol monomers.
  • coumaryl alcohol, coniferyl alcohol, sinapyl alcohol coumaryl alcohol, coniferyl alcohol, sinapyl alcohol
  • this study intends to prepare lignin-derived biochar by microwave-assisted pyrolysis and load transition metal oxygen on the surface of biochar produced to regulate the physicochemical properties of lignin-derived biochar catalyst.
  • the conversion rate of raw materials is increased, the formation of carbon deposits is reduced, and the activity, selectivity and service life of the catalyst are improved.
  • the object of the present invention is to provide a catalyst for producing an aromatic hydrocarbon-rich biofuel and a preparation method thereof, so as to obtain a modified catalyst, thereby improving liquid yield and quality in biomass catalytic pyrolysis reaction, specifically in improving raw materials.
  • the conversion rate and the chemical component selectivity of the bio-oil reduce the formation of catalyst coke and increase the activity and selectivity of the catalyst.
  • the present invention uses lignin microwave pyrolysis to derive biochar as a catalyst carrier raw material, reveals the influence of the supported transition metal oxide on the prepared biochar catalyst, and analyzes the prepared transition metal by XRD, SEM and other analytical means.
  • the microscopic morphology of the modified biochar catalyst, the combination of the active component and the carrier, and the distribution state are as follows:
  • a method for preparing a catalyst for producing an aromatic-rich biofuel characterized by comprising the steps of:
  • Step one microwave pyrolysis of lignin to obtain biochar;
  • the lignin raw material is weighed according to the required amount and placed in a quartz flask reactor, and the microwave pyrolysis parameter is set to a reaction temperature of 500 ° C, and the microwave power is 750 W,
  • the lignin pyrolysis reaction occurs more completely, so that pure biochar is obtained, and the reaction time is set to 30 minutes;
  • Step 2 Preparation of biochar powder: The biochar is poured out from the quartz flask reactor and cooled to room temperature; since the lignin is pyrolyzed in the microwave, it is easy to form a block-like biochar product.
  • the lignin-derived biochar produced by microwave pyrolysis is first pulverized into fine powder, and then sieved to ensure uniformity of size, thereby obtaining a biochar powder;
  • Step three repeatedly washing the biochar powder with deionized water to remove contaminants from the biochar powder structure and open the surface pores of the biochar to obtain pure biochar powder;
  • Step 4 drying the pure biochar powder in an oven at 105 ° C for 15 h to remove excess water to obtain a dried biochar powder;
  • Step 5 dissolving the weighed zinc salt in deionized water to obtain a solution A, and adding the dried biochar powder to the solution A under continuous stirring to obtain a solution B; the metal element in the zinc salt The mass ratio is 5% of the selected biochar;
  • Step six using a magnetic stirrer to continuously stir the solution B, to obtain a solution C;
  • Step 7 the solution C is subjected to suction filtration and molding to obtain a shaped columnar particulate material, which is then dried in an oven to obtain a product 1;
  • Step 8 calcining the product one through a high-temperature tube furnace in a mixed gas atmosphere of nitrogen and hydrogen to crystallize and shape, thereby preparing a final product, that is, a modified biochar catalyst loaded with a transition metal;
  • the volume ratio of nitrogen to hydrogen in the mixture is 99:1.
  • the lignin raw material in the first step is a commercial lignin.
  • the zinc salt in the fifth step is Zn(NO 3 ) 2 .6H 2 O, and the mass ratio of the zinc salt to the dried biochar powder is 5%.
  • Step 6 specifically, the solution B was placed on a magnetic stirrer, a magnetic stir bar was added to the solution, and stirring was continued for 6 hours in a water bath at 60 ° C.
  • the step 7 is specifically: suction filtration, molding is to put a layer of filter paper in the Buchner funnel and then connect the Buchner funnel to the vacuum pump, and the solution C is suction filtered in the prepared Buchner funnel, and the filter paper is retained after the suction filtration.
  • the residue was then made into a columnar particle having a diameter of 5 mm and a length of 7 mm using a plastic tube to facilitate use in experiments.
  • Step 7 The drying conditions were specifically vacuum dried in an electric oven at 105 ° C for 15 h.
  • step 8 in a tube furnace, a mixed gas having a flow rate of 60 mL/min was used to maintain an oxygen-deficient atmosphere, and crystallization was performed at a temperature of 550 ° C for 4 hours.
  • a catalyst for producing an aromatic-rich biofuel which is produced by the above method.
  • the present invention has a beneficial effect.
  • the transition metal modified biochar catalyst prepared in the invention maintains the characteristic mode of the biochar topology, and the modified biochar catalyst still maintains a regular structure. It shows that the dispersibility of the modified biochar catalyst is still good.
  • the XRD pattern of the biochar modified with zinc salt has a more prominent peak than the unmodified biochar catalyst, which is a high crystal formed by substances other than the framework material, and also indicates the peak. It is caused by the addition of zinc, while the other peaks are consistent with the peak of the biochar catalyst. From the SEM analysis, the main crystal particles and their agglomerates can be slightly changed in the sample with the addition of zinc salt. Compared with the biochar without metal addition, the single crystal size of the zinc-doped sample is slightly reduced, and the surface is slightly reduced. More smooth.
  • Figure 1 is an XRD diffraction pattern of the effect of the zinc salt of the present invention on a modified biochar catalyst
  • FIG. 3 is an analysis diagram of the bio-oil component of the modified catalyst and the un-catalyzed lignin/PE microwave co-pyrolysis reaction product of the present invention
  • FIG. 4 is a flow chart of a method of the present invention.
  • FIG. 40 g of the lignin biomass feedstock was weighed and placed in the reaction flask without the addition of a heating agent, so that the resulting coke was as pure as possible. Nitrogen gas was introduced for 15 min before the start of the experiment to maintain an oxygen-free atmosphere.
  • the microwave pyrolysis parameter was set to a reaction temperature of 500 ° C and a microwave power of 750 W. In order to make the lignin pyrolysis reaction more complete, a relatively pure biochar was obtained, and the reaction time was set to 30 minutes. Since lignin is pyrolyzed in the microwave, it is easy to form a block-like biochar product.
  • the lignin-derived biochar produced by microwave pyrolysis is first pulverized into fine powder and then sieved to ensure uniformity of size. Then, the biochar powder was repeatedly washed with deionized water. After washing, it was dried in an oven at 105 ° C for 15 h to remove excess water. This gave a biochar raw material for the preparation of the catalyst.
  • the weighed 10.13 g of Zn(NO 3 ) 2 .6H 2 O was dissolved in excess deionized water, and 40 g of a biochar raw material was added thereto with constant stirring. The solution was placed on a magnetic stirrer and continuously stirred in a water bath at 60 ° C for 6 h.
  • the mixture was filtered, molded, and the formed material was vacuum dried in an electric oven at 105 ° C for 15 h. Then, an oxygen-deficient atmosphere was maintained at a flow rate of 60 mL/min in a nitrogen-hydrogen mixed atmosphere (99:1), and crystallization was carried out at a temperature of 550 ° C for 4 hours to prepare a metal-supported biochar catalyst.
  • XRD characterization was performed to compare the crystal characteristics of the metal zinc modified catalyst and the untreated catalyst, as shown in FIG.
  • the modified molecular sieve catalyst maintains the characteristic pattern of the topological structure of the procatalyst, but a prominent peak formed by the addition of metallic zinc appears, indicating that the modified metallic zinc is loaded into the biochar catalyst.
  • a catalytic pyrolysis experiment was carried out by using a catalytic fixed bed reactor in combination with a microwave pyrolysis apparatus.
  • the raw material used in the test was lignin: firstly weighed 20 g of lignin and 5 g of PE as raw materials in a quartz flask reactor with a capacity of 500 ml, and then added 1 g of activated carbon as a microwave absorbing material and lignin/polyethylene (PE). The mixture was mixed, and the quartz flask reactor was placed in a microwave oven, and 1 g of the prepared catalyst was placed in a catalytic fixed bed reactor.
  • the reaction temperature for setting microwave pyrolysis is 500 ° C, the time is 8 min, and the microwave power is 750 W.
  • the pyrolysis gas is subjected to catalytic reforming reaction through a catalytic fixed bed after microwave pyrolysis reaction, and then rapidly condensed.
  • the bio-oil was collected, and the organic components and catalysts of the bio-oil after the reaction were collected and analyzed by means of GC/MS, SEM and XRD.
  • the microwave pyrolysis experiments of the uncharged catalyst and the added metal zinc modified biochar catalyst were compared. It was found that the catalyst used was significantly more than the bio-oil obtained without the catalyst.
  • the effect of the catalyst on the bio-oil yield was: zinc-bio Carbon catalyst > no catalyst.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Electromagnetism (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un catalyseur utilisé pour produire un biocarburant riche en aromatiques, et son procédé de préparation. Le procédé comprend les étapes consistant à: former une matière première de biocharbon de lignine par pyrolyse par micro-ondes. Le sel de zinc pesé est dissous dans de l'eau désionisée en excès, et broyé, lavé, et la poudre de biocharbon séché est ajoutée pendant l'agitation; la solution est agitée en continu à l'aide d'un agitateur magnétique dans un bain d'eau à 60°C pendant 6 h; puis la solution est filtrée et formée, et est séchée pendant 15 h dans un four à 105°C; ensuite, la cristallisation et la formation sont effectuées dans une atmosphère de gaz mixte, d'azote et d'hydrogène (99 :1), dans un four à tube à 550°C, et un catalyseur à base de zinc-biocharbon modifié est ainsi préparé. Le catalyseur modifié augmente le rendement en bio-huile et la sélectivité des aromatiques obtenus par pyrolyse catalytique de lignine, et peut être appliqué à la technologie associée de conversion catalytique de pyrolyse.
PCT/CN2017/107943 2017-06-15 2017-10-27 Catalyseur utilisé pour produire un biocarburant riche en aromatiques, et son procédé de préparation WO2018227842A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710450449.1A CN107469802B (zh) 2017-06-15 2017-06-15 一种用于生产富芳烃生物燃油的催化剂及其制备方法
CN201710450449.1 2017-06-15

Publications (1)

Publication Number Publication Date
WO2018227842A1 true WO2018227842A1 (fr) 2018-12-20

Family

ID=60594817

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/107943 WO2018227842A1 (fr) 2017-06-15 2017-10-27 Catalyseur utilisé pour produire un biocarburant riche en aromatiques, et son procédé de préparation

Country Status (2)

Country Link
CN (1) CN107469802B (fr)
WO (1) WO2018227842A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108774538A (zh) * 2018-05-04 2018-11-09 江苏大学 一种获取生物质催化热解中活性积炭组分的方法
CN109370632A (zh) * 2018-11-16 2019-02-22 江苏大学 一种木质素与低密度聚乙烯共热解制备富芳烃燃料油的方法
CN111634902B (zh) * 2020-06-01 2023-03-28 南京博岭节能环保研究院有限公司 一种木质素热解气二次催化重整制备碳纳米管的方法
CN112010359B (zh) * 2020-07-09 2024-02-13 江苏大学 一种NiO/C纳米复合电极材料及制备方法和应用
CN114931953A (zh) * 2022-06-02 2022-08-23 南昌大学 一种生物质转化为烃类化合物的催化剂制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008127396A2 (fr) * 2006-11-02 2008-10-23 Ohio University Synthèse de solution d'ensembles conjugués de nanotubes en carbone/nanoparticule contenant un métal
CN102239112A (zh) * 2008-06-18 2011-11-09 阿肯色大学理事会 碳-金属纳米复合物和其应用
CN104437361A (zh) * 2014-10-24 2015-03-25 东华大学 一种原位担载制备功能性生物炭的方法
CN106335901A (zh) * 2016-09-20 2017-01-18 中国环境科学研究院 利用单户庭院含重金属生物质制备的生物炭及制法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103691429B (zh) * 2014-01-03 2015-06-10 北京林业大学 用于生物质快速热裂解液化的催化剂及其制备方法和应用
CN104888836B (zh) * 2015-06-05 2018-04-10 中国科学技术大学 一种Mo‑N‑C加氢脱氧催化剂及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008127396A2 (fr) * 2006-11-02 2008-10-23 Ohio University Synthèse de solution d'ensembles conjugués de nanotubes en carbone/nanoparticule contenant un métal
CN102239112A (zh) * 2008-06-18 2011-11-09 阿肯色大学理事会 碳-金属纳米复合物和其应用
CN104437361A (zh) * 2014-10-24 2015-03-25 东华大学 一种原位担载制备功能性生物炭的方法
CN106335901A (zh) * 2016-09-20 2017-01-18 中国环境科学研究院 利用单户庭院含重金属生物质制备的生物炭及制法和应用

Also Published As

Publication number Publication date
CN107469802B (zh) 2021-01-12
CN107469802A (zh) 2017-12-15

Similar Documents

Publication Publication Date Title
WO2018227842A1 (fr) Catalyseur utilisé pour produire un biocarburant riche en aromatiques, et son procédé de préparation
Sheng et al. Hydrothermal carbonization of cellulose and xylan into hydrochars and application on glucose isomerization
Kabakcı et al. Hydrothermal carbonization of various lignocellulosics: Fuel characteristics of hydrochars and surface characteristics of activated hydrochars
Jain et al. Hydrothermal conversion of biomass waste to activated carbon with high porosity: A review
Masoumi et al. Optimized production and characterization of highly porous activated carbon from algal-derived hydrochar
Wang et al. A new route for preparation of hydrochars from rice husk
Ren et al. Effects of loading methods and oxidation degree of support on the tar reforming activity of char-supported Ni catalyst using toluene as a model compound
CN108671960B (zh) 一种高水热稳定性MOFs催化剂、制备及用于纤维素转化制备化学品的方法
CN108085032B (zh) 一种碱金属复合盐催化木屑热解制气的方法
Sani et al. Palm frond and spikelet as environmentally benign alternative solid acid catalysts for biodiesel production
CN112536037A (zh) 生物质炭负载镍铜纳米合金催化剂的制备方法及其在催化裂解焦油中的应用
CN112645304B (zh) 一种重油制备高性能中间相炭微球的方法
CN113387355A (zh) 一种生物质原料制备多孔碳球的方法
CN101723364B (zh) 利用等离子体裂解煤固体产物制备活性炭的方法
Yadav et al. Fabrication of surface-modified dual waste-derived biochar for biodiesel production by microwave-assisted esterification of oleic acid: Optimization, kinetics, and mechanistic studies
Hu et al. One-pot cogeneration of phenol-rich bio-oil, hydrogen-rich gas and solid carbon degradation material from reed
Han et al. Production of phenolic compounds in catalytic pyrolysis of bagasse lignin in the presence of Ca0. 5Pr0. 5FeO3
Zhang et al. Microstructure and electrochemical properties of porous carbon derived from biomass
Lower et al. Catalytic Graphitization of Biocarbon for Lithium‐Ion Anodes: A Minireview
Shen et al. Highly effective synthesis of biomass-derived furanic diethers over a sulfonated zirconium–carbon coordination catalyst in alcohol systems
CN110205159B (zh) 一种焦油熔盐重整定向制备高品质油的方法及产品
CN109456801A (zh) 生物质富氢高能燃气联产纳米二氧化硅复合材料的方法
CN109847755B (zh) 一种生物质基催化剂及其制备方法以及在热解煤方面的应用
KR102320837B1 (ko) 리그닌 해중합 촉매 및 이를 이용하는 리그닌유래 바이오 오일의 제조방법
XIAO et al. One-pot catalytic agroforestry waste cellulose to polyols over self-reducing bifunctional catalysts

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17913989

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17913989

Country of ref document: EP

Kind code of ref document: A1