WO2018212552A3 - 내열성이 개선된 메탄 개질 반응용 모노리스 촉매 및 이의 제조방법 - Google Patents
내열성이 개선된 메탄 개질 반응용 모노리스 촉매 및 이의 제조방법 Download PDFInfo
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- WO2018212552A3 WO2018212552A3 PCT/KR2018/005543 KR2018005543W WO2018212552A3 WO 2018212552 A3 WO2018212552 A3 WO 2018212552A3 KR 2018005543 W KR2018005543 W KR 2018005543W WO 2018212552 A3 WO2018212552 A3 WO 2018212552A3
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- WIPO (PCT)
- Prior art keywords
- reforming
- methane
- catalyst
- preparation
- monolith catalyst
- Prior art date
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- 239000003054 catalyst Substances 0.000 title abstract 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract 4
- 238000002407 reforming Methods 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 230000002401 inhibitory effect Effects 0.000 abstract 2
- 238000005245 sintering Methods 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 230000009849 deactivation Effects 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
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Abstract
본 발명은 이산화탄소-메탄 개질 반응용 모노리스 촉매 및 이의 제조방법에 관한 것이다. 상세하게는 개질 반응용 모노리스 촉매를 구성함에 있어서 3주기 이상의 원소 중 2족, 3족, 6족, 13족, 15족, 16족에 해당하는 원소로 이루어진 군으로부터 선택된 하나 이상의 원소를 모노리스 지지체의 표면에 코팅하여 소결 억제층을 형성하고, 상기 소결억제층의 상부에 활성촉매층을 형성함으로써, 고온의 반응에도 열화에 의한 촉매의 비활성화 및 탄소침적 현상을 억제하도록 구성되어, 열적 내구성이 향상된 새로운 형태의 개질 반응용 모노리스 촉매에 관한 것이다.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US16/613,119 US11691128B2 (en) | 2017-05-18 | 2018-05-15 | Thermally stable monolith catalysts for methane reforming and preparing method of the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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KR1020170061870A KR101982773B1 (ko) | 2017-05-18 | 2017-05-18 | 내열성이 개선된 메탄 개질 반응용 모노리스 촉매 및 이의 제조방법 |
KR10-2017-0061870 | 2017-05-18 |
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WO2018212552A2 WO2018212552A2 (ko) | 2018-11-22 |
WO2018212552A3 true WO2018212552A3 (ko) | 2019-01-03 |
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PCT/KR2018/005543 WO2018212552A2 (ko) | 2017-05-18 | 2018-05-15 | 내열성이 개선된 메탄 개질 반응용 모노리스 촉매 및 이의 제조방법 |
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US (1) | US11691128B2 (ko) |
KR (1) | KR101982773B1 (ko) |
WO (1) | WO2018212552A2 (ko) |
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CN114272928B (zh) * | 2022-01-05 | 2023-03-14 | 成都理工大学 | 用于乙酸自热重整制氢的镁钛类钙钛矿型镍基催化剂 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20140132893A (ko) * | 2013-05-08 | 2014-11-19 | 한국화학연구원 | 이산화탄소 개질반응용 모노리스 촉매, 이의 제조방법 및 이를 이용한 합성가스의 제조방법 |
KR20180012558A (ko) * | 2016-07-27 | 2018-02-06 | 한국화학연구원 | 개질반응용 내열성 개선 모노리스 촉매 |
Family Cites Families (12)
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JPS5814950A (ja) * | 1981-07-18 | 1983-01-28 | Nippon Soken Inc | 活性アルミナコ−テイングハニカム構造触媒担体 |
US7566441B2 (en) * | 2004-10-15 | 2009-07-28 | Velocys | Methods of conducting catalytic combustion in a multizone reactor, and a method of making a thermally stable catalyst support |
KR100939437B1 (ko) * | 2006-05-26 | 2010-01-28 | 주식회사 엘지화학 | 탄화수소 분해촉매의 제조방법 |
KR100885310B1 (ko) * | 2007-07-26 | 2009-02-24 | 한국화학연구원 | 피셔-트롭쉬 합성용 코발트/인―알루미나 촉매와 이의제조방법 |
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WO2018212552A2 (ko) | 2018-11-22 |
KR101982773B1 (ko) | 2019-05-27 |
US20210077983A1 (en) | 2021-03-18 |
KR20180126872A (ko) | 2018-11-28 |
US11691128B2 (en) | 2023-07-04 |
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