WO2018193611A1 - 繊維強化樹脂製部品の接続構造および繊維強化樹脂製部品の製造方法 - Google Patents

繊維強化樹脂製部品の接続構造および繊維強化樹脂製部品の製造方法 Download PDF

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Publication number
WO2018193611A1
WO2018193611A1 PCT/JP2017/016000 JP2017016000W WO2018193611A1 WO 2018193611 A1 WO2018193611 A1 WO 2018193611A1 JP 2017016000 W JP2017016000 W JP 2017016000W WO 2018193611 A1 WO2018193611 A1 WO 2018193611A1
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WIPO (PCT)
Prior art keywords
fiber
component
layer
reinforced resin
resin
Prior art date
Application number
PCT/JP2017/016000
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English (en)
French (fr)
Inventor
翔平 倉井
大久保 洋志
Original Assignee
日産自動車株式会社
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Publication date
Application filed by 日産自動車株式会社 filed Critical 日産自動車株式会社
Priority to CN201780089827.6A priority Critical patent/CN110545989B/zh
Priority to JP2019513190A priority patent/JP6844695B2/ja
Priority to PCT/JP2017/016000 priority patent/WO2018193611A1/ja
Priority to US16/500,132 priority patent/US11390043B2/en
Priority to EP17906336.7A priority patent/EP3613565B1/en
Publication of WO2018193611A1 publication Critical patent/WO2018193611A1/ja

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    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B32B7/04Interconnection of layers
    • B32B7/05Interconnection of layers the layers not being connected over the whole surface, e.g. discontinuous connection or patterned connection
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/08Interconnection of layers by mechanical means
    • B32B7/09Interconnection of layers by mechanical means by stitching, needling or sewing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3055Cars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • B32B2260/023Two or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • B32B2262/0269Aromatic polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/08Cars

Definitions

  • the present invention relates to a connection structure for fiber-reinforced resin parts and a method for manufacturing fiber-reinforced resin parts.
  • Patent Document 1 a structure for attaching a second part to a first part made of fiber reinforced resin is known (see, for example, Patent Document 1).
  • Patent Document 1 describes a bonded structure of a carbon fiber reinforced resin material in which a carbon fiber reinforced resin material and a member to be bonded are bonded by a bonding means.
  • the carbon fiber reinforced resin material changes the temperature by overlapping the first laminated portion and the second laminated portion that is in the carbon fiber surface direction orthogonal to the carbon fiber surface direction of the first laminated portion. The linear expansion amount in the overlapping direction due to is reduced.
  • the member to be coupled is fastened to the carbon fiber reinforced resin material with bolts and nuts.
  • the present invention provides the first component even when the connection between the first component and the second component (adhesion by the adhesive) is released by inputting a relatively large load to the first component or the second component.
  • An object is to suppress the separation of the component and the second component.
  • a first component made of fiber reinforced resin
  • a second component made of fiber reinforced resin bonded to the first component
  • a connecting fiber connecting the first component and the second component.
  • a connection structure of fiber reinforced resin parts One end of the connecting fiber is sandwiched between the first fiber layers of the first part, and the other end of the connecting fiber is sandwiched between the second fiber layers of the second part.
  • the second aspect of the present invention is a method for manufacturing a fiber-reinforced resin part.
  • this manufacturing method one end of the connecting fiber is sandwiched between the first fiber layers, and the other end of the connecting fiber is sandwiched between the second fiber layers, so that the gap between the one end and the other end of the connecting fiber is increased.
  • the above-described manufacturing method further includes a step of impregnating the first fiber layer and the second fiber layer with the matrix resin without impregnating the intermediate portion of the connecting fiber with the matrix resin.
  • FIG. 1 is a side view showing a connection structure for fiber-reinforced resin parts according to an embodiment of the present invention.
  • FIG. 2 is a schematic cross-sectional view showing a cross section taken along line AA of FIG.
  • FIG. 3 is a partially enlarged side view showing a state before bonding of the connection structure of the fiber-reinforced resin parts according to the embodiment of the present invention.
  • FIG. 4A is an explanatory diagram of a method for manufacturing a fiber-reinforced resin part according to an embodiment of the present invention.
  • Drawing 4B is an explanatory view of the manufacturing method of the part made from fiber reinforced resin concerning the embodiment of the present invention.
  • FIG. 1 is a side view showing a connection structure for fiber-reinforced resin parts according to an embodiment of the present invention.
  • FIG. 2 is a schematic cross-sectional view showing a cross section taken along line AA of FIG.
  • FIG. 3 is a partially enlarged side view showing a state before bonding of the connection structure of
  • FIG. 4C is an explanatory diagram of the method for manufacturing the fiber-reinforced resin part according to the embodiment of the present invention.
  • Drawing 5A is an explanatory view of the manufacturing method of the part made from fiber reinforced resin concerning the embodiment of the present invention.
  • Drawing 5B is an explanatory view of the manufacturing method of the part made from fiber reinforced resin concerning the embodiment of the present invention.
  • Drawing 5C is an explanatory view of the manufacturing method of the part made from fiber reinforced resin concerning the embodiment of the present invention.
  • FIG. 6A is an explanatory diagram of a method for manufacturing a fiber-reinforced resin part according to an embodiment of the present invention.
  • Drawing 6B is an explanatory view of the manufacturing method of the part made from fiber reinforced resin concerning the embodiment of the present invention.
  • FIG. 6C is an explanatory diagram of the method for manufacturing the fiber-reinforced resin part according to the embodiment of the present invention.
  • connection structure of the fiber-reinforced resin part 1 according to the embodiment of the present invention will be described with reference to FIGS.
  • the fiber reinforced resin part 1 can be applied to a vehicle component such as a hood (bonnet), a door panel, a bumper, a trunk lid, a rear gate, a fender panel, a side body panel, and a roof panel.
  • a vehicle component such as a hood (bonnet), a door panel, a bumper, a trunk lid, a rear gate, a fender panel, a side body panel, and a roof panel.
  • the fiber reinforced resin part 1 is not limited to the structural member for vehicles, but can be applied to various structural members.
  • the fiber-reinforced resin part 1 is mainly composed of a first part 2, a second part 3, and a connection fiber 4.
  • the first component 2 is a component made of fiber reinforced resin having a plurality of first fiber layers 5 and a matrix resin (first resin) 6 impregnated in the first fiber layer 5 ( (See FIG. 4C).
  • the first component 2 of the present embodiment is a vehicle outer panel (fender panel) (not shown).
  • the first component 2 includes a component main body (panel main body) 2a and a first component-side adhesive portion 2b to which the second component 3 is attached.
  • the fibers constituting the first fiber layer 5 are not particularly limited, and various fibers such as carbon fibers, aramid fibers, and glass fibers can be used.
  • the matrix resin 6 is not specifically limited, For example, various thermosetting resins, such as an epoxy resin, a phenol resin, and a polyamide resin, can be used.
  • the matrix resin 6 is not limited to a thermosetting resin, and various thermoplastic resins can be used.
  • the second component 3 is a component made of a fiber reinforced resin including a plurality of second fiber layers 7 and a matrix resin (second resin) 8 impregnated in the second fiber layer 7 ( (See FIG. 4C).
  • the second component 3 is bonded to the first component 2 via the adhesive layer 9 (see FIG. 2). That is, in the present embodiment, the connection between the first component 2 and the second component 3 is not performed using a bolt and a nut, but is performed using an adhesive.
  • the second component 3 of the present embodiment is a bracket for attaching the vehicle outer panel (first component 2) to a vehicle body (not shown).
  • the second component 3 includes a second component-side adhesive portion 3a attached to the first component 2 and attached thereto, a vehicle body attachment portion 3b attached to the vehicle body of the vehicle, a second component-side adhesive portion 3a, and a vehicle body attachment portion 3b. And a connecting portion 3c disposed between the two.
  • the fibers constituting the second fiber layer 7 are not particularly limited, and various fibers such as carbon fibers, aramid fibers, and glass fibers can be used. Further, as the second fiber layer 7, for example, NCF (Non Crimp Fabric), woven fabric (woven fabric), or non-woven fabric (nonwoven fabric) can be used. Further, the matrix resin 8 is not particularly limited, and various thermosetting resins such as an epoxy resin, a phenol resin, and a polyamide resin can be used. The matrix resin 8 is not limited to a thermosetting resin, and various thermoplastic resins can also be used.
  • the adhesive constituting the adhesive layer 9 is not particularly limited as long as sufficient adhesive strength can be obtained.
  • an epoxy resin adhesive and a urethane resin adhesive can be used.
  • the adhesive may be a thermosetting adhesive or a thermoplastic adhesive.
  • the connecting fiber 4 connects the first part 2 and the second part 3. Specifically, one end portion 4a of the connecting fiber 4 (a portion hatched in FIG. 3) is sandwiched between the first fiber layers 5 of the first component 2, and the other end portion 4b of the connecting fiber 4 is placed. (Locations with point hatching in FIG. 3) are sandwiched between the second fiber layers 7 of the second component 3. And the intermediate part 4c between the one end part 4a and the other end part 4b in the connecting fiber 4 is exposed from the first fiber layer 5 of the first part 2 and the second fiber layer 7 of the second part 3. The intermediate resin 4c of the connecting fiber 4 is not impregnated with the matrix resins 6 and 8.
  • one end portion (first component connecting portion) 4a of the connecting fiber 4 is disposed in the intermediate layer (the middle layer in the thickness direction) of the first fiber layer 5, and the other end of the connecting fiber 4 is used.
  • the portion (second component connecting portion) 4b is disposed in the intermediate layer (the middle layer in the thickness direction) of the second fiber layer 7 (see FIG. 4A).
  • the first component connecting portion 4a of the connecting fiber 4 is disposed on the outer layer outside the intermediate layer in the first fiber layer 5, and the second component connecting portion 4b of the connecting fiber 4 is the second fiber. You may arrange
  • the first component connecting portion 4a of the connecting fiber 4 is not arranged on the entire first component 2, but only on a part of the first component 2 (first component-side adhesive portion 2b). Is arranged (see FIG. 3).
  • the second component connecting portion 4b of the connecting fiber 4 is not disposed on the entire second component 3, but is disposed only on a part of the second component 3 (second component side bonding portion 3a). (See FIG. 3).
  • the intermediate portion 4c of the connecting fiber 4 is not disposed in the entire width direction region of the first component connecting portion 4a and the second component connecting portion 4b, and the first component connecting portion 4a and the second component connecting portion are not arranged. It is arranged only in a partial region in the width direction of the portion 4b (both end regions in the width direction).
  • connection fiber 4 is embedded in the adhesive layer 9.
  • the connecting fiber 4 may be arranged around the adhesive layer 9 in a state where the first component 2 and the second component 3 are bonded via the adhesive layer 9.
  • connection fibers 4 are not particularly limited, and various fibers such as carbon fibers and aramid fibers can be used. Further, as the connection fiber 4, NCF (Non Crimp Fabric) or woven fabric (woven fabric) can be used. For this reason, the first component connecting portion 4a is sandwiched between the first fiber layers 5 of the first component 2 by sandwiching the first component connecting portion 4a of the connecting fiber 4 so that the first component connecting portion 4a is a common fabric layer with the first fiber layer 5. (That is, a part of the first fiber layer 5).
  • the second component connecting portion 4b is a fabric common to the second fiber layer 7 by sandwiching the second component connecting portion 4b of the connecting fiber 4 between the second fiber layers 7 of the second component 3. Constituting a layer (that is, a part of the second fiber layer 7).
  • RTM Resin® Transfer® Molding
  • the laminated first fiber layer 5, second fiber layer 7, and connection fiber 4 are placed in a molding die 10 for molding.
  • a plurality of first fiber layers 5 may be stacked, and a plurality of second fiber layers 7 may be stacked.
  • matrix resins 6 and 8 are injected into the mold 10 from a resin injection port (not shown), the first fiber layer 5 is impregnated with the matrix resin (first resin) 6, and the second The fiber layer 7 is impregnated with a matrix resin (second resin) 8. Then, in a state where the first fiber layer 5 and the second fiber layer 7 are impregnated with the matrix resins 6 and 8, the matrix resins 6 and 8 are cured (solidified).
  • a sealing resin 11 such as packing is provided in the intermediate portion 4c of the connecting fiber 4 so that the matrix resin is provided in the intermediate portion 4c of the connecting fiber 4.
  • the matrix resins 6 and 8 are prevented from flowing into the portion of the mold 10 where the intermediate portion 4c of the connecting fiber 4 is disposed.
  • the intermediate portion 4c of the connecting fiber 4 is covered with the brittle resin 12 such as acrylic resin, so that the intermediate resin 4c of the connecting fiber 4 is not impregnated with the matrix resins 6 and 8. You may do it. That is, by covering the intermediate portion 4c of the connecting fiber 4 with the brittle resin 12 in advance, the matrix resins 6 and 8 do not flow into the portion of the mold 10 where the intermediate portion 4c of the connecting fiber 4 is disposed. To. In this case, the brittle resin 12 is removed from the intermediate portion 4c of the connection fiber 4 after the matrix resins 6 and 8 are cured (after solidification).
  • the matrix resins 6 and 8 are cured (after solidification).
  • the intermediate portion 4c of the connecting fiber 4 is covered with a soft resin 13 such as polyurethane or polyethylene, so that the intermediate portion 4c of the connecting fiber 4 is impregnated with matrix resins 6 and 8. It may not be allowed to. That is, by covering the intermediate portion 4c of the connecting fiber 4 with the soft resin 13 in advance, the matrix resins 6 and 8 do not flow into the portion of the mold 10 where the intermediate portion 4c of the connecting fiber 4 is disposed. To. In this case, since the soft resin 13 is flexible after curing, it is left without being removed from the intermediate portion 4c of the connecting fiber 4 after the matrix resins 6 and 8 are cured (after solidification). Also good.
  • a soft resin 13 such as polyurethane or polyethylene
  • the first part 2, the second part 3, and the connection fibers 4 are taken out from the mold 10.
  • the intermediate portion 4c of the connecting fiber 4 is in a state that can be freely deformed.
  • the first component 2 and the second component 3 are bonded using an adhesive, whereby an adhesive layer 9 is formed between the first component 2 and the second component 3.
  • an adhesive layer 9 is formed between the first component 2 and the second component 3.
  • connection structure of the fiber reinforced resin component 1 includes a first component 2 having a plurality of first fiber layers 5 and a matrix resin 6 impregnated in the first fiber layer 5, and a first component 2.
  • a second component 3 that is bonded to the component 2 via an adhesive layer 9.
  • This connection structure further includes a connection fiber 4 that connects the first component 2 and the second component 3.
  • the second component 3 includes a plurality of second fiber layers 7 and a matrix resin 8 that is impregnated in the second fiber layers 7.
  • One end 4 a of the connecting fiber 4 is sandwiched between the first fiber layers 5, and the other end 4 b of the connecting fiber 4 is sandwiched between the second fiber layers 7.
  • connection structure of the fiber reinforced resin parts 1 the first part 2 and the second part 3 are connected by connecting fibers 4, and a matrix is provided in an intermediate portion 4 c of the connecting fibers 4. Resins 6 and 8 are not impregnated. For this reason, even if the connection (adhesion by the adhesive) between the first component 2 and the second component 3 is released by the input of a relatively large load to the first component 2 or the second component 3, the connection The connection between the first component 2 and the second component 3 (connection by the connection fiber 4) is maintained by the use fiber 4. Therefore, according to the connection structure of the fiber reinforced resin component 1 according to the present embodiment, it is possible to suppress the first component 2 and the second component 3 from being separated.
  • the connecting fibers 4 are connected to the first component 2.
  • the second component 3 can be held relatively firmly.
  • One end 4 a of the connecting fiber 4 is arranged in the intermediate layer of the first fiber layer 5, and the other end 4 b of the connecting fiber 4 is arranged in the intermediate layer of the second fiber layer 7.
  • One end portion 4a of the connecting fiber 4 is arranged in the intermediate layer of the first fiber layer 5, and the other end portion 4b of the connecting fiber 4 is arranged in the intermediate layer of the second fiber layer 7, whereby the connecting fiber 4 Can be held more firmly against the first component 2 and the second component 3.
  • the connecting fiber 4 is embedded in the adhesive layer 9.
  • the connecting fiber 4 is embedded in the adhesive layer 9, the connecting fiber 4 (intermediate portion 4 c) is not exposed in a state where the first component 2 and the second component 3 are bonded via the adhesive layer 9. Can be.
  • the connecting fiber 4 may be arranged around the adhesive layer 9.
  • the connecting fiber 4 By disposing the connecting fiber 4 so as to bypass the adhesive layer 9, the connecting fiber 4 (intermediate portion 4 c) can be prevented from interfering with the adhesion between the first component 2 and the second component 3. .
  • the first component 2 is a vehicle outer panel
  • the second component 3 is a bracket for attaching the outer panel to the vehicle body.
  • the one end 4a of the connection fiber 4 is sandwiched between the first fiber layers 5, and the other end 4b of the connection fiber 4 is the second fiber.
  • a step of exposing the intermediate portion 4c of the connecting fiber 4 by being sandwiched between the layers 7 is provided.
  • the first fiber layer 5 and the second fiber layer 7 are impregnated with the matrix resins 6 and 8 without impregnating the matrix resin 6 and 8 into the intermediate portion 4c of the connecting fiber 4, and the matrix A step of solidifying the resins 6 and 8.
  • the fiber reinforced resin part 1 can be efficiently manufactured.
  • one end 4 a of the connecting fiber 4 is sandwiched between the first fiber layers 5, and the other end 4 b of the connecting fiber 4 is sandwiched between the second fiber layers 7.
  • the component 2 and the second component 3 can be held relatively firmly.
  • the first fiber layer 5 and the second fiber layer 7 are impregnated with the matrix resins 6 and 8, while the intermediate portion 4c of the connecting fiber 4 is not impregnated with the matrix resins 6 and 8. Is possible.
  • the intermediate portion 4c of the connecting fiber 4 may not be impregnated with the matrix resins 6 and 8.
  • first fiber layer 5 and the second fiber layer 7 are impregnated with the matrix resins 6 and 8, while the intermediate portion 4 c of the connecting fiber 4 is not impregnated with the matrix resins 6 and 8. It is possible to
  • first fiber layer 5 and the second fiber layer 7 are impregnated with the matrix resins 6 and 8, while the intermediate portion 4 c of the connecting fiber 4 is not impregnated with the matrix resins 6 and 8. It is possible to

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Moulding By Coating Moulds (AREA)
  • Body Structure For Vehicles (AREA)
  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Superstructure Of Vehicle (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

繊維強化樹脂製部品(1)の接続構造は、複数層の第1繊維層(5)および第1繊維層(5)に含浸されるマトリックス樹脂(6)を有する第1部品(2)と、第1部品(2)に接着層(9)を介して接着される第2部品(3)と、を備える。繊維強化樹脂製部品(1)の接続構造は、第1部品(2)と第2部品(3)とを接続する接続用繊維(4)をさらに備える。第2部品(3)は、複数層の第2繊維層(7)および第2繊維層(7)に含浸されるマトリックス樹脂(8)を有する。接続用繊維(4)の一端部(4a)が第1繊維層(5)間に挟持され、接続用繊維(4)の他端部(4b)が第2繊維層(7)間に挟持される。

Description

繊維強化樹脂製部品の接続構造および繊維強化樹脂製部品の製造方法
 本発明は、繊維強化樹脂製部品の接続構造および繊維強化樹脂製部品の製造方法に関する。
 従来から、繊維強化樹脂製の第1部品に、第2部品を取り付けるための構造が公知である(例えば、特許文献1参照)。
 特許文献1には、炭素繊維強化樹脂材と被結合部材とを結合手段によって結合した炭素繊維強化樹脂材の結合構造が記載されている。この結合構造では、炭素繊維強化樹脂材は、第1積層部と、第1積層部の炭素繊維面方向と直交する炭素繊維面方向とされた第2積層部と、を重ねることで、温度変化による重ね合わせ方向の線膨張量を小さくする。また、特許文献1に記載の繊維強化樹脂材の結合構造では、被結合部材は炭素繊維強化樹脂材にボルトおよびナットで締結される。
特開2007-292106号公報
 前述の構造では、第1部品と第2部品とがボルトおよびナットにより締結されるので、第1部品または第2部品への比較的大きな荷重の入力により第1部品と第2部品との接続(ボルトおよびナットによる締結)が解除される可能性は低い。ボルトおよびナットによる締結は、作業性が低く、コスト上昇の要因となり得るため、ボルトおよびナットによる締結から接着剤による接着への変更が検討される。しかしながら、第1部品と第2部品とを接着剤により接着するだけでは、第1部品または第2部品への比較的大きな荷重の入力により第1部品と第2部品との接続(接着剤による接着)が解除され、第1部品と第2部品とが分離することが懸念される。
 そこで、本発明は、第1部品または第2部品への比較的大きな荷重の入力により第1部品と第2部品との接続(接着剤による接着)が解除された場合であっても、第1部品と第2部品とが分離してしまうことを抑制することを目的とする。
 本発明の第1の態様は、繊維強化樹脂製の第1部品と、第1部品に接着される繊維強化樹脂製の第2部品と、第1部品と第2部品とを接続する接続用繊維と、を備える繊維強化樹脂製部品の接続構造である。接続用繊維の一端部が第1部品の第1繊維層間に挟持され、接続用繊維の他端部が第2部品の第2繊維層間に挟持される。
 本発明の第2の態様は、繊維強化樹脂製部品の製造方法である。この製造方法は、接続用繊維の一端部を第1繊維層間に挟み込み、接続用繊維の他端部を第2繊維層間に挟み込むことにより、接続用繊維における一端部と他端部との間の中間部を第1繊維層および第2繊維層から露出させる工程を備える。また、前述の製造方法は、接続用繊維の中間部にはマトリックス樹脂を含浸させずに、第1繊維層および第2繊維層にマトリックス樹脂を含浸させる工程をさらに備える。
 本発明によれば、第1部品または第2部品への比較的大きな荷重の入力により第1部品と第2部品との接続(接着剤による接着)が解除された場合であっても、第1部品と第2部品とが分離してしまうことを抑制することができる。
図1は、本発明の実施形態に係る繊維強化樹脂製部品の接続構造を示す側面図である。 図2は、図1のA-A線断面を示す概略的な断面図である。 図3は、本発明の実施形態に係る繊維強化樹脂製部品の接続構造の接着前の状態を示す部分拡大側面図である。 図4Aは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図4Bは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図4Cは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図5Aは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図5Bは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図5Cは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図6Aは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図6Bは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。 図6Cは、本発明の実施形態に係る繊維強化樹脂製部品の製造方法の説明図である。
 以下、本発明の実施形態を図面と共に詳述する。
 本発明の実施形態に係る繊維強化樹脂製部品1の接続構造を図1から図3に基づいて説明する。
 繊維強化樹脂製部品1は、例えば、フード(ボンネット)、ドアパネル、バンパー、トランクリッド、リアゲート、フェンダパネル、サイドボディパネル、ルーフパネルなど車両用構成部材に適用することができる。また、繊維強化樹脂製部品1は、車両用構成部材に限定されず、各種構成部材に適用することが可能である。
 図1から図3に示すように、繊維強化樹脂製部品1は、第1部品2と、第2部品3と、接続用繊維4と、から主に構成されている。
 第1部品2は、複数層の第1繊維層5と、第1繊維層5に含浸されるマトリックス樹脂(第1樹脂)6とを有して構成される繊維強化樹脂製の部品である(図4C参照)。本実施形態の第1部品2は、図示しない車両の外板パネル(フェンダパネル)である。第1部品2は、部品本体部(パネル本体部)2aと、第2部品3が接着して取り付けられる第1部品側接着部2bとを有して構成されている。
 第1繊維層5を構成する繊維は、特に限定されず、炭素繊維、アラミド繊維、ガラス繊維など、種々の繊維を用いることができる。また、第1繊維層5としては、例えば、NCF(Non Crimp Fabric)、織物(織布)、不織物(不織布)を用いることができる。さらに、マトリックス樹脂6は、特に限定されず、例えば、エポキシ樹脂、フェノール樹脂、ポリアミド樹脂など、種々の熱硬化性樹脂を用いることができる。なお、マトリックス樹脂6としては、熱硬化性樹脂に限定されず、種々の熱可塑性樹脂を用いることも可能である。
 第2部品3は、複数層の第2繊維層7と、第2繊維層7に含浸されるマトリックス樹脂(第2樹脂)8とを有して構成される繊維強化樹脂製の部品である(図4C参照)。第2部品3は、第1部品2に接着層9を介して接着される(図2参照)。すなわち、本実施形態においては、第1部品2と第2部品3との接続には、ボルトおよびナットによる結合は用いられずに、接着剤による接着が用いられる。本実施形態の第2部品3は、車両の外板パネル(第1部品2)を図示しない車両の車体に取り付けるためのブラケットである。第2部品3は、第1部品2に接着して取り付けられる第2部品側接着部3aと、車両の車体に取り付けられる車体取付部3bと、第2部品側接着部3aと車体取付部3bとの間に配設される連結部3cとを有して構成されている。
 第2繊維層7を構成する繊維は、特に限定されず、炭素繊維、アラミド繊維、ガラス繊維など、種々の繊維を用いることができる。また、第2繊維層7としては、例えば、NCF(Non Crimp Fabric)、織物(織布)、不織物(不織布)を用いることができる。さらに、マトリックス樹脂8は、特に限定されず、例えば、エポキシ樹脂、フェノール樹脂、ポリアミド樹脂など、種々の熱硬化性樹脂を用いることができる。なお、マトリックス樹脂8としては、熱硬化性樹脂に限定されず、種々の熱可塑性樹脂を用いることも可能である。
 接着層9を構成する接着剤は、十分な接着強度が得られるものであればよく、例えば、エポキシ樹脂系接着剤、ウレタン樹脂系接着剤を用いることができる。また、この接着剤は、熱硬化性の接着剤であってもよく、熱可塑性の接着剤であってもよい。
 接続用繊維4は、第1部品2と第2部品3とを接続するものである。具体的には、接続用繊維4の一端部4a(図3中に点ハッチングを付した箇所)が第1部品2の第1繊維層5間に挟持され、接続用繊維4の他端部4b(図3中に点ハッチングを付した箇所)が第2部品3の第2繊維層7間に挟持される。そして、接続用繊維4における一端部4aと他端部4bとの間の中間部4cは、第1部品2の第1繊維層5および第2部品3の第2繊維層7から露出しており、接続用繊維4の中間部4cには、マトリックス樹脂6,8は含浸されてはいない。
 本実施形態においては、接続用繊維4の一端部(第1部品接続部)4aが第1繊維層5の中間層(厚さ方向の真ん中の層)に配置され、接続用繊維4の他端部(第2部品接続部)4bが第2繊維層7の中間層(厚さ方向の真ん中の層)に配置される(図4A参照)。これに限定されず、接続用繊維4の第1部品接続部4aが第1繊維層5における中間層よりも外側の外層に配置され、接続用繊維4の第2部品接続部4bが第2繊維層7における中間層よりも外側の外層に配置されてもよい。
 本実施形態においては、接続用繊維4の第1部品接続部4aは、第1部品2の全体には配置されておらず、第1部品2の一部分(第1部品側接着部2b)のみに配置されている(図3参照)。また、接続用繊維4の第2部品接続部4bは、第2部品3の全体には配置されておらず、第2部品3の一部分(第2部品側接着部3a)のみに配置されている(図3参照)。さらに、接続用繊維4の中間部4cは、第1部品接続部4aおよび第2部品接続部4bの幅方向の全領域には配置されておらず、第1部品接続部4aおよび第2部品接続部4bの幅方向の一部領域(幅方向の両端領域)のみに配置されている。
 第1部品2と第2部品3とを接着層9を介して接着した状態において、例えば、接続用繊維4は、接着層9に埋め込まれる。これに限定されず、第1部品2と第2部品3とを接着層9を介して接着した状態において、接続用繊維4は、接着層9を迂回して配置されてもよい。
 接続用繊維4を構成する繊維は、特に限定されず、炭素繊維、アラミド繊維など、種々の繊維を用いることができる。また、接続用繊維4としては、NCF(Non Crimp Fabric)、織物(織布)を用いることができる。このため、接続用繊維4の第1部品接続部4aを第1部品2の第1繊維層5間に挟持させることにより、第1部品接続部4aは、第1繊維層5と共通のファブリック層(すなわち、第1繊維層5の一部)を構成する。その一方で、接続用繊維4の第2部品接続部4bを第2部品3の第2繊維層7間に挟持させることにより、第2部品接続部4bは、第2繊維層7と共通のファブリック層(すなわち、第2繊維層7の一部)を構成する。
 次に、本実施形態に係る繊維強化樹脂製部品1の製造方法の一例を説明する。
 繊維強化樹脂製部品1を製造する方法には、例えばRTM(Resin Transfer Molding)成形を用いることができる。
 [RTM成形の場合]
 1.積層
 まず、図4Aに示すように、複数層の第1繊維層5を積層すると共に、複数層の第2繊維層7を積層する。この際に、接続用繊維4の第1部品接続部4aを第1繊維層5間に挟み込み、接続用繊維4の第2部品接続部4bを第2繊維層7間に挟み込む。このようにすることにより、接続用繊維4における第1部品接続部4aと第2部品接続部4bとの間の中間部4cを第1繊維層5および第2繊維層7から露出させる。
 2.マトリックス樹脂の含浸
 次いで、図4Bに示すように、積層した第1繊維層5、第2繊維層7および接続用繊維4を成形用の成形型10内に入れる。なお、成形型10内において、複数層の第1繊維層5を積層すると共に、複数層の第2繊維層7を積層するようにしてもよい。
 次いで、図4Cに示すように、図示しない樹脂注入口からマトリックス樹脂6,8を成形型10内に注入し、第1繊維層5にマトリックス樹脂(第1樹脂)6を含浸させると共に、第2繊維層7にマトリックス樹脂(第2樹脂)8を含浸させる。そして、第1繊維層5および第2繊維層7にマトリックス樹脂6,8を含浸させた状態において、マトリックス樹脂6,8を硬化(固化)させる。
 3.マトリックス樹脂の含浸抑制方策
 例えば、図5Aに示すように、接続用繊維4の中間部4cに、パッキンなどのシール部材11を配設することにより、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにする。すなわち、成形型10内にシール部材11を配設することにより、成形型10における接続用繊維4の中間部4cが配置された部分にマトリックス樹脂6,8を流入させないようにする。
 また、図5Bに示すように、接続用繊維4の中間部4cを、アクリル樹脂などの脆性樹脂12によって被覆することにより、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにしてもよい。すなわち、接続用繊維4の中間部4cを脆性樹脂12によって予め被覆しておくことにより、成形型10における接続用繊維4の中間部4cが配置された部分にマトリックス樹脂6,8を流入させないようにする。なお、この場合、脆性樹脂12は、マトリックス樹脂6,8の硬化後(固化後)に、接続用繊維4の中間部4cから取り除くようにする。
 また、図5Cに示すように、接続用繊維4の中間部4cを、ポリウレタンやポリエチレンなどの軟性樹脂13によって被覆することにより、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにしてもよい。すなわち、接続用繊維4の中間部4cを軟性樹脂13によって予め被覆しておくことにより、成形型10における接続用繊維4の中間部4cが配置された部分にマトリックス樹脂6,8を流入させないようにする。なお、この場合、軟性樹脂13は、硬化後において可撓性を有するので、マトリックス樹脂6,8の硬化後(固化後)に、接続用繊維4の中間部4cから取り除かずに残すようにしてもよい。
 4.マトリックス樹脂の硬化後(固化後)
 図6Aに示すように、マトリックス樹脂6,8の硬化後(固化後)に、第1部品2、第2部品3および接続用繊維4を成形型10から取り出す。図6Aに示すマトリックス樹脂6,8の硬化後(固化後)の状態においては、接続用繊維4の中間部4cは、自由に変形が可能な状態である。
 そして、図6B及び図6Cに示すように、第1部品2と第2部品3とを接着剤を用いて接着することにより、第1部品2と第2部品3との間に接着層9を形成する。第1部品2と第2部品3とを接着剤を用いて接着する際には、例えば、接続用繊維4の中間部4cを接着層9に埋め込むようにする。また、接続用繊維4が第1部品2と第2部品3との接着の妨げとならないようにするために、接続用繊維4の中間部4cを接着層9を迂回して配置するようにしてもよい。
 以下に、本実施形態による作用効果を説明する。
 (1)本実施形態に係る繊維強化樹脂製部品1の接続構造は、複数層の第1繊維層5および第1繊維層5に含浸されるマトリックス樹脂6を有する第1部品2と、第1部品2に接着層9を介して接着される第2部品3と、を備える。この接続構造は、第1部品2と第2部品3とを接続する接続用繊維4をさらに備える。第2部品3は、複数層の第2繊維層7および第2繊維層7に含浸されるマトリックス樹脂8を有する。接続用繊維4の一端部4aが第1繊維層5間に挟持され、接続用繊維4の他端部4bが第2繊維層7間に挟持される。
 本実施形態に係る繊維強化樹脂製部品1の接続構造においては、第1部品2と第2部品3とは接続用繊維4によって接続されており、この接続用繊維4の中間部4cにはマトリックス樹脂6,8が含浸されていない。このため、第1部品2または第2部品3への比較的大きな荷重の入力により第1部品2と第2部品3との接続(接着剤による接着)が解除された場合であっても、接続用繊維4により第1部品2と第2部品3との接続(接続用繊維4による接続)が維持される。したがって、本実施形態に係る繊維強化樹脂製部品1の接続構造によれば、第1部品2と第2部品3とが分離してしまうことを抑制することができる。
 接続用繊維4の一端部4aが第1繊維層5間に挟持され、接続用繊維4の他端部4bが第2繊維層7間に挟持されるため、接続用繊維4を第1部品2および第2部品3に対して比較的強固に保持することが可能になる。
 (2)接続用繊維4の一端部4aが第1繊維層5の中間層に配置され、接続用繊維4の他端部4bが第2繊維層7の中間層に配置される。
 接続用繊維4の一端部4aが第1繊維層5の中間層に配置され、接続用繊維4の他端部4bが第2繊維層7の中間層に配置されることにより、接続用繊維4を第1部品2および第2部品3に対してより強固に保持することが可能になる。
 (3)例えば、接続用繊維4は、接着層9に埋め込まれる。
 接続用繊維4が接着層9に埋め込まれることにより、第1部品2と第2部品3とが接着層9を介して接着された状態において、接続用繊維4(中間部4c)が露出しないようにすることができる。
 (4)接続用繊維4は、接着層9を迂回して配置されてもよい。
 接続用繊維4が接着層9を迂回して配置されることにより、接続用繊維4(中間部4c)が第1部品2と第2部品3との接着の妨げとならないようにすることができる。
 (5)例えば、第1部品2は、車両の外板パネルであり、第2部品3は、外板パネルを車両の車体に取り付けるためのブラケットである。
 車両の外板パネルまたはブラケットへの比較的大きな荷重の入力により外板パネルとブラケットとの接続(接着剤による接着)が解除された場合であっても、外板パネルとブラケットとが分離してしまうことを抑制することができる。
 (6)本実施形態に係る繊維強化樹脂製部品1の製造方法は、接続用繊維4の一端部4aを第1繊維層5間に挟み込み、接続用繊維4の他端部4bを第2繊維層7間に挟み込むことにより、接続用繊維4の中間部4cを露出させる工程を備える。この製造方法は、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させずに、第1繊維層5および第2繊維層7にマトリックス樹脂6,8を含浸させる工程と、マトリックス樹脂6,8を固化させる工程と、をさらに備える。
 このようにすることにより、繊維強化樹脂製部品1を効率よく製造することが可能である。特に、接続用繊維4の一端部4aが第1繊維層5間に挟持され、接続用繊維4の他端部4bが第2繊維層7間に挟持されるため、接続用繊維4を第1部品2および第2部品3に対して比較的強固に保持することが可能になる。
 (7)例えば、接続用繊維4の中間部4cにシール部材11を配設することにより、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにする。
 このようにすることにより、第1繊維層5および第2繊維層7にマトリックス樹脂6,8を含浸させる一方で、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにすることが可能である。
 (8)接続用繊維4の中間部4cを脆性樹脂12によって被覆することにより、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにしてもよい。
 このようにすることによっても、第1繊維層5および第2繊維層7にマトリックス樹脂6,8を含浸させる一方で、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにすることが可能である。
 (9)接続用繊維4の中間部4cを軟性樹脂13によって被覆することにより、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにしてもよい。
 このようにすることによっても、第1繊維層5および第2繊維層7にマトリックス樹脂6,8を含浸させる一方で、接続用繊維4の中間部4cにはマトリックス樹脂6,8を含浸させないようにすることが可能である。
 以上、実施例に沿って本発明の内容を説明したが、本発明はこれらの記載に限定されるものではなく、種々の変形および改良が可能であることは、当業者には自明である。
 1 繊維強化樹脂製部品
 2 第1部品
 3 第2部品
 4 接続用繊維
4a 一端部(第1部品接続部)
4b 他端部(第2部品接続部)
4c 中間部
 5 第1繊維層
 6 マトリックス樹脂(第1樹脂)
 7 第2繊維層
 8 マトリックス樹脂(第2樹脂)
 9 接着層
11 シール部材
12 脆性樹脂
13 軟性樹脂

Claims (9)

  1.  複数層の第1繊維層および前記第1繊維層に含浸されるマトリックス樹脂を有する第1部品と、
     前記第1部品に接着層を介して接着される第2部品と、
     前記第1部品と前記第2部品とを接続する接続用繊維と、を備え、
     前記第2部品は、複数層の第2繊維層および前記第2繊維層に含浸されるマトリックス樹脂を有し、
     前記接続用繊維の一端部が前記第1繊維層間に挟持され、前記接続用繊維の他端部が前記第2繊維層間に挟持される
     ことを特徴とする繊維強化樹脂製部品の接続構造。
  2.  前記接続用繊維の前記一端部が前記第1繊維層の中間層に配置され、前記接続用繊維の前記他端部が前記第2繊維層の中間層に配置されることを特徴とする請求項1に記載の繊維強化樹脂製部品の接続構造。
  3.  前記接続用繊維は、前記接着層に埋め込まれることを特徴とする請求項1または2に記載の繊維強化樹脂製部品の接続構造。
  4.  前記接続用繊維は、前記接着層を迂回して配置されることを特徴とする請求項1または2に記載の繊維強化樹脂製部品の接続構造。
  5.  前記第1部品は、車両の外板パネルであり、前記第2部品は、前記外板パネルを前記車両の車体に取り付けるためのブラケットであることを特徴とする請求項1から4のいずれか一項に記載の繊維強化樹脂製部品の接続構造。
  6.  複数層の第1繊維層および前記第1繊維層に含浸されるマトリックス樹脂を有する第1部品と、複数層の第2繊維層および前記第2繊維層に含浸されるマトリックス樹脂を有する第2部品と、前記第1部品と前記第2部品とを接続する接続用繊維と、を備える繊維強化樹脂製部品を製造する方法において、
     前記接続用繊維の一端部を前記第1繊維層間に挟み込み、前記接続用繊維の他端部を前記第2繊維層間に挟み込むことにより、前記接続用繊維における前記一端部と前記他端部との間の中間部を前記第1繊維層および前記第2繊維層から露出させる工程と、
     前記接続用繊維の前記中間部には前記マトリックス樹脂を含浸させずに、前記第1繊維層および前記第2繊維層に前記マトリックス樹脂を含浸させる工程と、
     前記マトリックス樹脂を固化させる工程と、を備える
     ことを特徴とする繊維強化樹脂製部品の製造方法。
  7.  前記接続用繊維の前記中間部にシール部材を配設することにより、前記接続用繊維の前記中間部には前記マトリックス樹脂を含浸させないことを特徴とする請求項6に記載の繊維強化樹脂製部品の製造方法。
  8.  前記接続用繊維の前記中間部を脆性樹脂によって被覆することにより、前記接続用繊維の前記中間部には前記マトリックス樹脂を含浸させないことを特徴とする請求項6に記載の繊維強化樹脂製部品の製造方法。
  9.  前記接続用繊維の前記中間部を軟性樹脂によって被覆することにより、前記接続用繊維の前記中間部には前記マトリックス樹脂を含浸させないことを特徴とする請求項6に記載の繊維強化樹脂製部品の製造方法。
PCT/JP2017/016000 2017-04-21 2017-04-21 繊維強化樹脂製部品の接続構造および繊維強化樹脂製部品の製造方法 WO2018193611A1 (ja)

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US16/500,132 US11390043B2 (en) 2017-04-21 2017-04-21 Fiber-reinforced resin component and method for producing fiber-reinforced resin component
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