WO2018181629A1 - Composition for imparting charry pungent flavor - Google Patents

Composition for imparting charry pungent flavor Download PDF

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Publication number
WO2018181629A1
WO2018181629A1 PCT/JP2018/013065 JP2018013065W WO2018181629A1 WO 2018181629 A1 WO2018181629 A1 WO 2018181629A1 JP 2018013065 W JP2018013065 W JP 2018013065W WO 2018181629 A1 WO2018181629 A1 WO 2018181629A1
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WIPO (PCT)
Prior art keywords
food
composition
weight
present
added
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PCT/JP2018/013065
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French (fr)
Japanese (ja)
Inventor
秀世 吉田
鈴木 理絵
若林 秀彦
Original Assignee
味の素株式会社
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Application filed by 味の素株式会社 filed Critical 味の素株式会社
Priority to JP2019510077A priority Critical patent/JP7172992B2/en
Publication of WO2018181629A1 publication Critical patent/WO2018181629A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L35/00Food or foodstuffs not provided for in groups A23L5/00 – A23L33/00; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor

Definitions

  • the present invention is at least selected from the group consisting of a composition suitably used for imparting a charcoal-like stimulating flavor, a composition suitably used for imparting a cooked incense, a feeling of spice and sweetness. It relates to a composition suitably used to enhance one as well as a composition suitably used to mask unpleasant odors. Moreover, this invention relates to the manufacturing method of the foodstuff using the said composition etc. Furthermore, the present invention provides at least one enhancement method selected from the group consisting of a method for imparting a charcoal-like stimulating flavor using the composition or the like, a method for imparting a cooked incense, a feeling of spice and sweetness, and an unpleasant The present invention relates to an odor masking method.
  • Non-Patent Documents 1 to 3 Non-Patent Documents 1 to 3
  • Patent Document 1 As a technique for obtaining a flavor developed by high-temperature heating, a method using an amino-carbonyl reaction in a powder system that uses as little water as possible has been reported (Patent Document 1). According to this method, a flavor composition can be prepared by utilizing an amino-carbonyl reaction.
  • the material used is powder, there is a problem that a predetermined apparatus is required for the preparation, and reaction control is easy. There is a problem that is not.
  • there is a problem that it is necessary to adjust the composition and preparation conditions according to the food to which flavor is imparted and there is also a problem that the range of use is limited because aroma components other than the desired flavor are also formed as a by-product.
  • the inventors of the present invention have intensively studied the flavor developed by cooking, and as a result, found that the charcoal-like stimulating flavor is one of the main elements constituting the flavor developed by cooking.
  • An object of the present invention is to provide a composition capable of imparting a charcoal-like stimulating flavor, which is one of the main components of the flavor developed by cooking, to a method for imparting a charcoal-like stimulating flavor, etc.
  • the present invention also provides a composition capable of imparting cooked incense (e.g., burning sensation, oily feel, etc.) to foods, a spice sensation, a composition capable of enhancing sweetness, a composition capable of masking unpleasant odor, and a cooking odor (e.g.
  • the present inventors have found that a charcoal-like stimulating flavor can be imparted to foods by combining specific compounds. Furthermore, the present inventors have shown that the combination of the specific compounds can impart a cooked incense (e.g., burning sensation, oily sensation), a spice sensation, a sweetness enhancement, and an unpleasant odor masking. I also found out to get. The present inventors have completed the present invention by further research based on these findings. That is, the present invention is as follows.
  • [1] (A) 2-acetylfuran; (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol; (C) A composition containing furfurylmethyl disulfide.
  • [5] The composition according to any one of [1] to [4], which is added to the food so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
  • [6] containing (B1), and the weight ratio (A: B1) of the content of (A) to the content of (B1) is 1: 0.00005 to 10000, [1] to [5]
  • the weight ratio (A: C) of the content of (A) to the content of (C) is 1: 0.000005 to 1000, according to any one of [1] to [7] Composition.
  • composition according to [10] wherein the heat cooking incense is at least one application selected from the group consisting of a burning feeling and an oily feeling.
  • the weight ratio (A: C) of the addition amount of (A) and the addition amount of (C) is 1: 0.000005 to 1000, according to any one of [15] to [21] the method of.
  • the weight ratio (A: C) of the addition amount of (A) and the addition amount of (C) is 1: 0.000005 to 1000, according to any one of [28] to [34] the method of.
  • the composition which can provide a charcoal-like exciting flavor can be provided.
  • ADVANTAGE OF THE INVENTION the manufacturing method of the foodstuff provided with the charcoal-like stimulating flavor and the imparting method of charcoal-like stimulating flavor can be provided.
  • the charcoal-like exciting flavor can be provided to food, the food which was effectively provided with the flavor (cooking incense) expressed by heat cooking can be provided.
  • a food provided with at least one selected from the group consisting of a burning feeling and an oily feeling can be provided.
  • the foodstuff in which at least one selected from the group which consists of a spice feeling and sweet taste was strengthened, and the foodstuff by which the unpleasant odor was masked can be provided. Since the composition of the present invention is obtained by mixing a specific compound, it can be produced by an apparatus generally used by those skilled in the art, and the production conditions can be easily controlled. Furthermore, the composition of the present invention contains a specific compound, and since it is not necessary to adjust the composition according to the type of food, it can be widely used for various foods.
  • composition of the present invention comprises (A) 2-acetylfuran (CAS registration number: 1192-62-7, which may be simply referred to herein as “(A)”), (B1) 6, 7- Dihydro-5-methyl-5H-cyclopentapyrazine (CAS registration number: 23747-48-0, sometimes referred to herein simply as “(B1)”) and (B2) furfuryl alcohol (CAS registration number: 98-00-0, which may be simply referred to herein as “(B2)”), and (C) furfurylmethyl disulfide (CAS Registry Number: 57500-00-2). In this specification, it is simply referred to as “(C)”).
  • at least one selected from the group consisting of (B1) and (B2) may be referred to as “component group B”. It goes without saying that the component group B may be composed of only one compound.
  • each component of (A), component group B and (C) is not particularly limited, and those produced by methods known per se (for example, chemical synthesis methods, extraction methods, fermentation methods, etc.) are used. It's okay. These components may be commercially available products, and are preferable because they are simple. Alternatively, each component itself may not be used, and a food material containing a large amount of any one or more of each component may be used instead.
  • composition of the present invention may contain at least one selected from the group consisting of (B1) and (B2) as component group B, but more preferably contains both (B1) and (B2). preferable.
  • a preferred embodiment of the composition of the present invention is a composition containing (A), (B1), (B2) and (C).
  • the content of (A) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and since a more preferable effect is obtained, it is preferably 20% by weight or more, More preferably, it is 25% by weight or more. Further, the content is usually 99% by weight or less with respect to the composition of the present invention, and preferably 35% by weight or less, more preferably 31% by weight or less from the viewpoint of cost.
  • the content of (B1) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and a more preferable effect is obtained. Since it is obtained, it is preferably 15% by weight or more, more preferably 18% by weight or more. Further, the content is usually 99% by weight or less with respect to the composition of the present invention, and preferably 30% by weight or less, more preferably 24% by weight or less from the viewpoint of cost.
  • the content of (B2) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and a more preferable effect is obtained. Since it is obtained, it is preferably 40% by weight or more, and more preferably 45% by weight or more. Further, the content is usually 99% by weight or less with respect to the composition of the present invention, preferably 55% by weight or less, more preferably 51% by weight or less from the viewpoint of cost.
  • the content of (C) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and since a more preferable effect is obtained, it is preferably 1% by weight or more, More preferably, it is 1.5% by weight or more.
  • the content is usually 99% by weight or less with respect to the composition of the present invention, and preferably 7% by weight or less, more preferably 5% by weight or less from the viewpoint of cost.
  • the weight ratio (A: B1) of the content of (A) and the content of (B1) in the composition of the present invention imparts flavor more effectively. Therefore, it is preferably 1: 0.00005 to 10,000, more preferably 1: 0.005 to 100, and particularly preferably 1: 0.5 to 1.
  • the weight ratio (A: B2) of the content of (A) and the content of (B2) in the composition of the present invention imparts flavor more effectively. Therefore, it is preferably 1: 0.0001 to 20000, more preferably 1: 0.01 to 100, and particularly preferably 1: 0.5 to 5.
  • the weight ratio (A: C1) of the content of (A) and the content of (C) in the composition of the present invention is preferably 1: 0.000005 to 1000 because it can impart a flavor more effectively. More preferably, it is 1: 0.0005 to 50, and particularly preferably 1: 0.05 to 3.
  • composition of the present invention is not particularly limited, and examples thereof include solid (including powder, granule and the like), liquid (including slurry and the like), gel, and paste.
  • composition of the present invention may comprise only (A), component groups B and (C), but in addition to these, it may further contain a base commonly used in the field of food fragrances. Good.
  • Examples of the base when the form of the composition of the present invention is liquid include water, ethanol, glycerin, propylene glycol, various animal and vegetable oils, and the like.
  • a base when the form of the composition of the present invention is solid for example, starch, dextrin, cyclodextrin, various sugars such as sucrose and glucose, protein, peptide, salt, solid fat, silicon dioxide, and their Examples of the mixture include yeast cells and various powder extracts.
  • composition of the present invention includes, for example, excipients, pH adjusters, antioxidants, thickening stabilizers, in addition to (A), component groups B and (C), Sweeteners (eg, sugars, etc.), acidulants, spices, colorants and the like may be further contained.
  • excipients for example, excipients, pH adjusters, antioxidants, thickening stabilizers, in addition to (A), component groups B and (C), Sweeteners (eg, sugars, etc.), acidulants, spices, colorants and the like may be further contained.
  • composition of the present invention can be performed by a conventional method in the field of food fragrance.
  • the composition of the present invention may be subjected to, for example, concentration treatment, drying treatment, decolorization treatment, etc. alone or in combination.
  • composition of the present invention can be added to foods to impart a charcoal-like stimulating flavor. Therefore, the composition of the present invention is preferably a charcoal stimulating flavor imparting composition.
  • food is a concept that broadly encompasses those that can be taken orally, and includes beverages and seasonings.
  • charcoal stimulating flavor imparting composition is a concept including a charcoal stimulating flavor imparting agent.
  • charcoal-like stimulating flavor is, for example, a fragrance that develops when grilled firewood and the surface of the firewood burns.
  • the presence or absence and degree of charcoal-like stimulating flavor can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
  • “providing” such as a charcoal-like stimulating flavor is not only the addition of a charcoal-like stimulating flavor to a food that does not have a charcoal-like stimulating flavor, for example. It is a concept including further imparting a charcoal-like stimulating flavor to a food product having a charcoal-like stimulating flavor, that is, enhancing the charcoal-like stimulating flavor.
  • the composition of the present invention can be added to the food to impart a cooked aroma. Therefore, the composition of the present invention may be a composition for imparting heat cooking incense.
  • a composition for imparting heat cooking incense is a concept including a heat cooking incense imparting agent.
  • cooked incense refers to a fragrant fragrance that develops when food is cooked at a high temperature (eg, 90 to 700 ° C.).
  • the cooked incense includes a fragrance generated by, for example, fried, baked, fried, roasted, stewed, or the like. The presence or absence and degree of cooking incense can be evaluated by sensory evaluation using a specialized panel.
  • composition of the present invention can also be added to foods as a cooked incense in order to impart a burning feeling and an oily feeling.
  • "baking feeling” refers to the aroma that is felt when the food is baked
  • “oil feeling” refers to the aroma that is felt when the food is fried.
  • cooking incense giving a feeling of firing and imparting an oily feel are part of the function of imparting a cooked incense, respectively. It may be an imparting composition.
  • the presence / absence and degree of firing feeling and oil feel can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
  • the composition of the present invention can be added to a food to enhance at least one selected from the group consisting of spice feeling and sweetness, and the composition of the present invention comprises spice feeling and sweetness as one aspect. It may be at least one enhancing composition selected from the group.
  • “feeling of spice” means a flavor and pungent taste peculiar to spices. The presence / absence and degree of spice feeling and sweetness can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
  • “enhancement” of the feeling of spice means that the flavor and pungent taste peculiar to the spice can be felt as if the spice concentration is increased.
  • the spice in the present invention is not particularly limited as long as it can be generally used for flavoring, spicy seasoning, etc.
  • “enhancement” of sweetness means that sweetness is felt strongly as if the concentration of the sweetening component is increased.
  • the “sweet ingredient” refers to a substance that can exhibit sweetness when contained in the oral cavity.
  • sugar starch sugar (eg, fructose, glucose, maltose, isomerized sugar, syrup, etc.), sugar alcohol (Eg, sorbitol, mannitol, maltitol, xylitol, etc.), saccharides such as fructooligosaccharides; non-saccharide sweeteners such as stevia, glycyrrhizin, thaumatin, saccharin, aspartame, acesulfame potassium and the like.
  • starch sugar eg, fructose, glucose, maltose, isomerized sugar, syrup, etc.
  • sugar alcohol Eg, sorbitol, mannitol, maltitol, xylitol, etc.
  • saccharides such as fructooligosaccharides
  • non-saccharide sweeteners such as stevia,
  • the composition of the present invention can be added to foods in order to mask unpleasant odor, and the composition of the present invention may be a composition for masking unpleasant odor as one embodiment.
  • “unpleasant odor” is a general term for odors that can cause unpleasant sensations mainly due to various animal meat raw materials, seafood raw materials, vegetable raw materials, yeast raw materials, and the like. Specific examples include animal odor, raw odor Examples include blue odor and fermentation odor. Also, “masking” of unpleasant odors means that unpleasant odors are not sensed partially or completely. The degree of masking of unpleasant odor can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
  • the composition of the present invention may be a fragrance composition as one aspect.
  • the “perfume” refers to a food additive used for imparting a fragrance, flavor, taste or the like to food.
  • the composition of the present invention is a fragrance composition for imparting a charcoal-like stimulating flavor or a fragrance composition for imparting cooked incense (eg, a fragrance composition for imparting a burning sensation, an oil A fragrance composition for imparting sensation, etc.).
  • the composition of the present invention may be at least one enhancing fragrance composition selected from the group consisting of spice feeling and sweetness, or an unpleasant odor masking fragrance composition. .
  • the food to which the composition of the present invention can be added is not particularly limited, but as one aspect, those that are desired to be provided with cooked incense are preferable, for example, stir-fried vegetables, fried rice, fried noodles, roasted meat, mapo tofu , Green crab meat, dried yakijin, stir-fried meat vegetables, nasi goreng, grilled rice noodles, fried egg, kinpira burdock, karerou, stir-fried meat, fried meat such as Chinese bowl; steamed vegetables, etc .; grilled fish, yakitori, steak, yakiniku, Sukiyaki, hamburger, grilled vegetables, grilled rice balls, rice crackers, various baked goods (eg, cookies), pizza dough, baked goods such as bread; various fried foods such as fried, fried, deep fried, tempura, and batters and breadcrumbs thereof; Dressing (eg, Japanese style dressing, creamy dressing, Caesar dressing, French dressing, tartar sauce, mayonnaise, etc.); (Eg, steak sauce, ginger
  • Seasonings such as natural seasonings and flavor seasonings; beverages such as coffee, tea, Chinese tea, green tea, cocoa, barley tea, herbal tea; and processed products thereof (eg, food for microwave oven cooking, instant food, Frozen foods, dried foods, etc.).
  • food is a concept that broadly encompasses those that can be taken orally, and includes seasonings, beverages, and the like.
  • natural seasoning refers to a seasoning produced from a natural product as a raw material by a technique such as extraction, decomposition, heating, fermentation, etc., and specific examples thereof include chicken extract and beef extract.
  • Various animal meat extracts such as pork extract, lamb extract; chicken extract, beef bone extract, pork bone extract, etc .; rice cake extract, rice cake extract, glutinous extract, scallop extract, rice cake extract, rice cake extract, Various seafood extracts such as boiled and dried scallop extracts; various node extracts such as bonito extract, bonito extract and soda-bushi extract; various vegetable extracts such as onion extract, Chinese cabbage extract and celery extract; various types such as kelp extract Seaweed extracts; various spice extracts such as garlic extract, pepper extract, pepper extract, cacao extract; yeast extract; various protein hydrolysates; soy sauce, fish sauce, salmon sauce Various fermented seasonings and mixtures thereof, such as miso, processed products and the like.
  • flavored seasoning refers to a seasoning used for imparting the flavor, flavor and taste of a flavor raw material to food, for example, adding sugars, salt, etc. to natural seasonings. Can be manufactured by etc. Specific examples of flavor seasonings include chicken flavor seasonings, beef flavor seasonings, pork flavor seasonings, and other meat-flavored seasonings; salmon flavor seasonings, boiled and dried seasonings, dried scallop flavor seasonings, and crustacean flavors. Various seafood flavor seasonings such as seasonings; various spicy vegetable flavor seasonings; kelp flavor seasonings and the like.
  • the composition of the present invention may be added to foods for which unpleasant odor is desired to be masked.
  • foods include various livestock meat-containing foods, seafood-containing foods (eg, radish Etc.), foods containing vegetables (eg, fried vegetables, soybean hamburger, etc.), extracts (eg, livestock meat extracts, seafood extracts, vegetable extracts, yeast extracts, etc.) or foods containing degradation products thereof, and these Processed products (eg, food for cooking in a microwave oven, instant food, frozen food, dried food, etc.) and the like can be mentioned.
  • the composition of the present invention may be added to foods for which it is desired that the feeling of spice is enhanced, and the type of such food is not particularly limited as long as it contains spices.
  • the thing similar to what was illustrated as a foodstuff to which cooking incense is desired (above-mentioned) etc. are mentioned.
  • the spice concentration of the food is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight, and particularly preferably 0.1 to 1% by weight.
  • composition of the present invention may be added to foods whose sweetness is desired to be enhanced, and the type of such foods is not particularly limited as long as it contains a sweetening ingredient.
  • a sweetening ingredient e.g, mitarashi dango, pudding, etc.
  • beverages e.g, soft drinks, energy drinks, etc.
  • breads dairy products and the like.
  • concentration of sweetening ingredients in the food is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight, and particularly preferably 0.1 to 1% by weight.
  • the food to which the composition of the present invention can be added may be provided (sold, distributed, etc.) in a mode suitable for eating, or requires a predetermined treatment or cooking to become a mode suitable for eating. May be provided (sold, distributed, etc.).
  • a food product to which the composition of the present invention can be added may be provided as a concentrate or the like that needs to be diluted with water or the like in order to be suitable for eating.
  • the method and conditions for adding the composition of the present invention to food are not particularly limited, and can be appropriately set according to the form of the composition of the present invention, the type of food, and the like.
  • the time when the composition of the present invention is added to the food is not particularly limited, and may be added at any time. For example, during the production of the food, after the completion of the food (eg, immediately before eating the food, during the eating of the food, etc. ) And the like. You may add the composition of this invention to the foodstuff raw material before manufacturing a foodstuff.
  • the composition of the present invention When the composition of the present invention is added to stir-fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof, the food can be given more effectively. It is preferable that the concentration of (A) in (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery or processed product thereof) is 0.0002 ppm by weight or more, It is more preferable to add so that it may become 0.02 weight ppm or more, and it is especially preferable to add so that it may become 2 weight ppm or more.
  • the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (A) is 500 ppm by weight or less, more preferably 100 ppm by weight or less, and 10 ppm by weight or less. It is particularly preferable.
  • the concentration of (A) in food refers to the ratio of the weight of (A) added to food to the total weight of the food after addition, for example, (A) is added to food In the case where the food contains components similar to (A) in advance, the weight of the components previously contained in the food is not included in the weight of (A) added to the food.
  • concentration For example, "the density
  • concentration of (A) in food is preferably a concentration at the time of eating.
  • concentration at eating refers to the concentration at the time of eating food.
  • the food to which the composition of the present invention can be added is, for example, a concentrate that needs to be diluted with water or the like to become an aspect suitable for eating, a seasoning that is used by adding to other foods, etc.
  • concentration of (A) in the food may be appropriately adjusted according to the dilution rate, the amount added, and the like.
  • concentration for example, "the density
  • the composition of the present invention contains (B1) and is added to fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof
  • the concentration of (B1) in the food is 0.0001 weight. It is preferably added so as to be at least ppm, more preferably added to be at least 0.02 ppm by weight, and particularly preferably added to be at least 2 ppm by weight.
  • the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (B1) is 100 ppm by weight or less, more preferably 50 ppm by weight or less, and 10 ppm by weight or less. It is particularly preferable.
  • the composition of the present invention contains (B2) and is added to fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof
  • the concentration of (B2) in the food is 0.0005 wt. It is preferably added so as to be at least ppm, more preferably added so as to be at least 0.05 ppm by weight, and particularly preferably added so as to be at least 5 ppm by weight.
  • the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (B2) is 200 ppm by weight or less, more preferably 100 ppm by weight or less, and 20 ppm by weight or less. It is particularly preferable.
  • the composition of the present invention When the composition of the present invention is added to stir-fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof, the food can be given more effectively.
  • concentration of (C) in (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery or processed product thereof) is 0.00001 ppm by weight or more, It is more preferable to add so that it may become 0.002 weight ppm or more, and it is especially preferable to add so that it may become 0.2 weight ppm or more.
  • the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (C) is 300 ppm by weight or less, more preferably 30 ppm by weight or less, and 2 ppm by weight or less. It is particularly preferable.
  • the composition of the present invention When the composition of the present invention is added to a seasoning or the like, it can impart a flavor more effectively, so that the concentration of (A) in the food (seasoning or the like) is 0.002 ppm by weight or more. It is preferable to add so that it may become 0.2 weight ppm or more, It is more preferable to add so that it may become 20 weight ppm or more. In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (A) in the food (condiment etc.) is 50000 ppm by weight or less. It is more preferable to add it so that it may become 10,000 weight ppm or less, and it is especially preferable to add so that it may become 1000 weight ppm or less.
  • the composition of the present invention when the composition of the present invention contains (B1) and is added to a seasoning or the like, the composition of the present invention can impart a flavor more effectively, so in the food (seasoning or the like) (
  • the concentration of B1) is preferably added so as to be 0.001 ppm by weight or more, more preferably added so as to be 0.2 ppm by weight or more, and added so as to be 20 ppm by weight or more. It is particularly preferred that In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (B1) in the food (condiment etc.) is 10,000 ppm by weight or less. It is more preferable to add it so that it becomes 5000 ppm by weight or less, and it is particularly preferable to add it so that it becomes 1000 ppm by weight or less.
  • the composition of the present invention can impart a flavor more effectively, so in the food (seasoning or the like)
  • ( B2) is preferably added so that the concentration is 0.005 ppm by weight or more, more preferably 0.5 ppm by weight or more, and 50 ppm by weight or more. It is particularly preferred that In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (B2) in the food (condiment etc.) is 20000 ppm by weight or less. It is more preferable to add it so that it becomes 10,000 ppm by weight or less, and it is particularly preferable to add it so that it becomes 2000 ppm by weight or less.
  • the concentration of (C) in the food (seasoning or the like) is 0.0001 ppm by weight or more. It is preferable to add so that it may become 0.02 weight ppm or more, It is more preferable to add so that it may become 2 weight ppm or more. In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (C) in the food (condiment etc.) is 30000 ppm by weight or less. It is more preferable that it is added so that it becomes 3000 ppm by weight or less, and it is particularly preferable that it is added so that it becomes 200 ppm by weight or less.
  • the composition of the present invention When the composition of the present invention is added to a spice-containing food or processed product thereof, it can impart a more effective flavor.
  • the concentration is preferably added to be 0.00002 ppm by weight or more, more preferably added to be 0.002 ppm by weight or more, and added to be 0.2 ppm by weight or more. It is particularly preferable.
  • the concentration of (A) in the food is 500 ppm by weight or less. It is preferably added so that it is 100 ppm by weight or less, more preferably 10 ppm by weight or less.
  • the composition of the present invention contains (B1) and is added to a spice-containing food or a processed product thereof, the composition of the present invention can impart flavor more effectively.
  • the content of (B1) in the contained food or processed product thereof is preferably 0.00001 ppm by weight or more, more preferably 0.002 ppm by weight or more. It is particularly preferable to add such that it becomes 0.2 ppm by weight or more.
  • the concentration of (B1) in the food is 100 ppm by weight or less. It is preferably added so that it is 50 ppm by weight or less, more preferably 10 ppm by weight or less.
  • the composition of the present invention contains (B2) and is added to a spice-containing food or a processed product thereof, the composition of the present invention can impart flavor more effectively.
  • the content of (B2) in the contained food or processed product thereof is preferably 0.00005 ppm by weight or more, more preferably 0.005 ppm by weight or more. It is particularly preferable to add such that it becomes 0.5 ppm by weight or more.
  • the concentration of (B2) in the food is 200 ppm by weight or less. It is preferable to add so that it may become 100 weight ppm or less, It is more preferable to add so that it may become 20 weight ppm or less.
  • the flavor can be imparted more effectively, so that (C) in the food (a spice-containing food or a processed product thereof) is concerned.
  • the concentration is preferably added to be 0.000001 ppm by weight or more, more preferably added to be 0.0002 ppm by weight or more, and added to be 0.02 ppm by weight or more. It is particularly preferable.
  • the concentration of (C) in the food is 300 ppm by weight or less.
  • it is added so that it may become 30 weight ppm or less, It is especially preferable to add so that it may become 2 weight ppm or less.
  • a food containing the composition of the present invention (sometimes referred to simply as “the food of the present invention” in the present specification) is also provided.
  • the content of the composition of the present invention in the food of the present invention may be appropriately adjusted so that the concentrations of (A), component groups B and (C) in the food of the present invention are within the above-mentioned ranges, There is no particular limitation.
  • the type of the food of the present invention is not particularly limited, but it is desired that a cooked incense is given, that an unpleasant odor is desired to be masked, and that a feeling of spice is enhanced. And those in which sweetness is desired to be enhanced are preferable, and examples thereof include those exemplified as foods to which the composition of the present invention can be added.
  • the present invention relates to a method for producing a food comprising adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It may also be referred to as “the manufacturing method of the present invention”).
  • At least one selected from the group consisting of (B1) and (B2) may be added as component group B, but it is preferable to add both (B1) and (B2). .
  • a preferred embodiment of the production method of the present invention is a food production method including adding (A), (B1), (B2) and (C).
  • the food produced by the production method of the present invention is not particularly limited, but those that are desired to be provided with cooked incense, those that are desired to mask unpleasant odor, and that the feeling of spice is enhanced. Are desirable, and those whose sweetness is desired to be enhanced are preferable, and examples thereof include those exemplified as foods to which the composition of the present invention can be added.
  • component groups B and (C) are added to the food of the present invention.
  • the concentration may be the same as that of each of the food groups (A), component groups B and (C) (described above).
  • the addition of (A), component groups B and (C) is the same as that of (A), component groups B and (C) in the food (condiment etc.) when the food is a seasoning etc.
  • Each concentration can be performed so as to be the same as the respective concentrations (above) of (A), component groups B and (C) in the food when the composition of the present invention is added to the food.
  • the weight ratio of the added amount of (A) and the added amount of each component of component groups B and (C) is the same as the content of (A) and the component groups B and ( It can be set in the same manner as the weight ratio (described above) of the content of each component of C).
  • component groups B and (C) may be added individually, but (A), component groups B and (C) are mixed in advance before addition, and the resulting mixture May be added. Addition of (A), component groups B and (C) may be performed using the composition of the present invention.
  • the order and interval of addition are not particularly limited. For example, the order of (A), component groups B and (C), or the reverse order thereof. May be added.
  • (A), component groups B and (C) may be added simultaneously.
  • the production method of the present invention appropriately includes, in addition to the addition of (A), component groups B and (C) described above, conventional processing steps and cooking steps in the production of food depending on the type of food to be produced. It's okay.
  • a food with a charcoal-like stimulating flavor can be produced.
  • a cooking fragrance can be imparted by imparting a charcoal-like stimulating flavor to food
  • a food with a cooking fragrance e.g., a feeling of baking is imparted.
  • Food, food with an oily feel, etc. can be produced.
  • a food product in which at least one selected from the group consisting of a spice feeling and sweetness is enhanced, and a food product in which an unpleasant odor is masked can be produced.
  • the present invention provides a method for imparting a charcoal-like stimulating flavor comprising adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). In the specification, it may be simply referred to as “the method of applying the present invention”).
  • the application method of the present invention can be carried out in the same manner as the production method of the present invention unless otherwise specified, and preferred embodiments are also the same.
  • the method and conditions for adding (A), ingredient group B and (C) are not particularly limited, depending on the type of food to which (A), ingredient group B and (C) are added. Can be set as appropriate.
  • the time when (A), ingredient group B and (C) are added to the food is not particularly limited, and may be added at any time. For example, during production of the food and after completion of the food (eg, food consumption) Immediately before, during food consumption, etc.). You may add (A), ingredient group B, and (C) to the foodstuff raw material before manufacturing a foodstuff.
  • the imparting method of the present invention a charcoal-like stimulating flavor can be imparted to food.
  • a heat cooking incense can be provided by giving a charcoal-like exciting flavor to food, according to the provision method of this invention, heat cooking incense can be provided to food. Therefore, the application method of the present invention may be a method for applying a cooked incense (e.g., a method for giving a burning feeling, a method for giving an oily feeling, etc.).
  • the food to which a charcoal-like stimulating flavor can be imparted by the imparting method of the present invention is not particularly limited, but those that are desired to be provided with a cooked incense are preferred.
  • the composition of the present invention is added. The thing similar to what was illustrated as a foodstuff to obtain is mentioned.
  • the present invention includes (A), at least one selected from the group consisting of (B1) and (B2), and (C), and at least selected from the group consisting of spice feeling and sweetness
  • An enhancement method (sometimes referred to herein simply as “the enhancement method of the present invention”) is also provided.
  • the enhancement method of the present invention can be carried out in the same manner as the production method of the present invention and the application method of the present invention, and preferred embodiments are also the same.
  • the food that can enhance at least one selected from the group consisting of a spice feeling and sweetness by the enhancing method of the present invention is not particularly limited, but it is desired that the spice feeling is enhanced, and that the sweetness is enhanced. What is desired is preferable, and examples thereof include those exemplified as foods to which the composition of the present invention can be added.
  • the present invention relates to a method for masking unpleasant odors, which comprises adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). Also referred to as “masking method of the present invention”).
  • the masking method of the present invention can be carried out in the same manner as the production method of the present invention and the application method of the present invention unless otherwise specified, and preferred embodiments are also the same.
  • the food that can mask the unpleasant odor by the masking method of the present invention is not particularly limited, but it is preferable that the unpleasant odor is desired to be masked. The same thing is mentioned.
  • the concentration of each component in the used addition solution, the addition amount of the addition solution, and the concentration of each component in the evaluation sample are “addition solution concentration (%)”, “addition amount (mg)” in Tables 2 to 9 below, And “Concentration in sample (ppm)”.
  • the presence and degree of cooked incense is determined by three specialized panels. confirmed. As a result, it was confirmed that the cooked incense (specifically, a flavor as if heated at a high temperature) was imparted to the Chinese rice bowl. (3) The above-mentioned 3. is added to a commercially available yakitori bowl ingredient (frozen food, distributor: Ajinomoto Frozen Food Co., Ltd.).
  • the presence or absence and degree of cooked incense were determined by three specialized panels. confirmed. As a result, it was confirmed that heat-cooked incense (specifically, a flavor baked over charcoal) was added to the yakitori bowl. From the results of the above (1) to (3), by adding at least one selected from the group consisting of (A), (B1) and (B2), and (C), the cooked incense is added to the food. It was confirmed that can be imparted.
  • a cookie was prepared according to the following procedures 1) to 6) (Example 31).
  • the concentration of each component in the used addition solution, the addition amount of the addition solution, and the concentration of each component in the evaluation sample are “addition solution concentration (%)”, “addition amount (mg)”, and “ As shown in “Concentration in sample (ppm)”.
  • Example 31 From the results shown in Table 11, it was confirmed that a feeling of firing can be imparted by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It was done. In addition, the evaluation sample of Example 31 was given a flavor burnt at high temperature and a coffee-like fragrant flavor.
  • the evaluation of the sweetness enhancement effect was carried out by three specialist panels, comparing the evaluation sample with the additive-free product (Mitarashi dango without added solution), confirming the intensity of sweetness, and performing the following evaluation criteria. .
  • evaluation criteria -: The sweetness intensity is weaker than the additive-free product ⁇ : There is no difference in sweetness intensity from the additive-free product +: The sweetness intensity is slightly higher than the additive-free product ++: The sweetness intensity is slightly higher than the additive-free product +++: Sweetness intensity is moderately higher than additive-free products +++: Sweetness intensity is considerably higher than additive-free products +++++: Sweetness intensity is much higher than additive-free products
  • the evaluation of spice sensation enhancing effect, unpleasant odor masking effect, and sweet taste enhancing effect was performed by comparing the evaluation sample with the additive-free product (food without added solution) by the above three specialist panels. ⁇ 9. The same evaluation criteria were used.
  • the evaluation sample of Example 45 (fried fried) evaluated the effect of enhancing the spice feeling, and each evaluation sample of Example 46 (soybean hamburger) and Example 47 (buri radish) was an unpleasant odor (specifically, soybean
  • the evaluation of the masking effect of the blue odor caused by the odor and the raw odor caused by the taste was performed, and the evaluation sample of Example 48 (purine) was evaluated for the sweetness enhancing effect.
  • Table 18 The results are shown in Table 18 below.
  • the composition which can provide a charcoal-like exciting flavor can be provided.
  • ADVANTAGE OF THE INVENTION the manufacturing method of the foodstuff provided with the charcoal-like stimulating flavor and the imparting method of charcoal-like stimulating flavor can be provided.
  • the charcoal-like exciting flavor can be provided to food, the food which was effectively provided with the flavor (cooking incense) expressed by heat cooking can be provided.
  • a food provided with at least one selected from the group consisting of a burning feeling and an oily feeling can be provided.
  • the foodstuff in which at least one selected from the group which consists of a spice feeling and sweet taste was strengthened, and the foodstuff by which the unpleasant odor was masked can be provided. Since the composition of the present invention is obtained by mixing a specific compound, it can be produced by an apparatus generally used by those skilled in the art, and the production conditions can be easily controlled. Furthermore, since the composition of the present invention contains a specific compound and it is not necessary to adjust the composition according to the type of food, it can be widely used for various foods.

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Abstract

The purpose of the present invention is to provide: a composition which can impart a charry pungent flavor to a food; a composition which can be used suitably for imparting a cooked flavor; a composition which can be used suitably for enhancing at least one selected from the group consisting of a spicy flavor and sweetness; a composition which can be used suitably for masking an unpleasant odor; and others. The present invention relates to: a composition containing (A) 2-acetylfuran, at least one component selected from the group consisting of (B1) 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol, and (C) furfuryl methyl disulfide; and others.

Description

炭様の刺激的な風味を付与するための組成物Composition for imparting a charcoal-like stimulating flavor
 本発明は、炭様の刺激的な風味を付与するために好適に用いられる組成物、加熱調理香を付与するために好適に用いられる組成物、スパイス感及び甘味からなる群より選択される少なくとも一つを増強するために好適に用いられる組成物、並びに、不快臭をマスキングするために好適に用いられる組成物に関する。また、本発明は当該組成物等を利用した食品の製造方法に関する。さらに本発明は、当該組成物等を利用した炭様の刺激的な風味の付与方法、加熱調理香の付与方法、スパイス感及び甘味からなる群より選択される少なくとも一つの増強方法、並びに、不快臭のマスキング方法に関する。 The present invention is at least selected from the group consisting of a composition suitably used for imparting a charcoal-like stimulating flavor, a composition suitably used for imparting a cooked incense, a feeling of spice and sweetness. It relates to a composition suitably used to enhance one as well as a composition suitably used to mask unpleasant odors. Moreover, this invention relates to the manufacturing method of the foodstuff using the said composition etc. Furthermore, the present invention provides at least one enhancement method selected from the group consisting of a method for imparting a charcoal-like stimulating flavor using the composition or the like, a method for imparting a cooked incense, a feeling of spice and sweetness, and an unpleasant The present invention relates to an odor masking method.
 食品に付与され得る風味の一つとして、加熱調理により発現する風味がある。当該風味は、一般に、食品を加熱したときに、これに含有されている成分が分解されたり、あるいは当該成分同士で反応したりすることによって、加熱前には存在しなかった揮発性物質等が発生した結果、発現すると考えられている。 As a flavor that can be imparted to foods, there is a flavor that is manifested by cooking. In general, when the food is heated, the flavor is decomposed by the components contained therein or reacted with each other, so that volatile substances that were not present before the heating are removed. As a result of the occurrence, it is thought to develop.
 加熱調理により発現する風味を得るために、例えば、アミノ-カルボニル反応やカラメル化反応等が利用されており、いわゆる「リアクションフレーバー」として多くの技術が知られている(非特許文献1~3)。しかしながら、これらの技術における反応の多くは水溶液中で行われるため、「炒め」や「焼き」等の高温加熱により発現する風味を再現することは困難であった。 For example, amino-carbonyl reaction, caramelization reaction, and the like are used to obtain a flavor expressed by cooking, and many techniques are known as “reaction flavors” (Non-Patent Documents 1 to 3). . However, since most of the reactions in these techniques are carried out in an aqueous solution, it has been difficult to reproduce the flavor that is manifested by high-temperature heating such as “stir-fried” or “baked”.
 高温加熱により発現する風味を得る技術として、水をなるべく使用しない粉体系でのアミノ-カルボニル反応を利用する方法が報告されている(特許文献1)。当該方法によればアミノ-カルボニル反応を利用してフレーバー組成物を調製し得るが、用いられる材料が粉体であるため、調製に所定の装置が必要になるという問題や、反応の制御が容易でないという問題がある。また、風味を付与する食品に応じて組成や調製条件を調整する必要があるという問題や、所望の風味以外の香気成分も副成されるため使用範囲が限定されるという問題もある。 As a technique for obtaining a flavor developed by high-temperature heating, a method using an amino-carbonyl reaction in a powder system that uses as little water as possible has been reported (Patent Document 1). According to this method, a flavor composition can be prepared by utilizing an amino-carbonyl reaction. However, since the material used is powder, there is a problem that a predetermined apparatus is required for the preparation, and reaction control is easy. There is a problem that is not. In addition, there is a problem that it is necessary to adjust the composition and preparation conditions according to the food to which flavor is imparted, and there is also a problem that the range of use is limited because aroma components other than the desired flavor are also formed as a by-product.
特開2005-198505号公報JP 2005-198505 A
 本発明者らは、加熱調理により発現する風味について鋭意検討した結果、炭様の刺激的な風味が、加熱調理により発現する風味を構成する主要な要素の一つであることを見出した。 The inventors of the present invention have intensively studied the flavor developed by cooking, and as a result, found that the charcoal-like stimulating flavor is one of the main elements constituting the flavor developed by cooking.
 本発明は、加熱調理により発現する風味の主要な構成要素の一つである炭様の刺激的な風味を食品に付与できる組成物、炭様の刺激的な風味の付与方法等の提供を目的とする。
 また本発明は、加熱調理香(例えば、焼成感、油調感等)を食品に付与できる組成物、スパイス感、甘味を増強できる組成物、不快臭をマスキングできる組成物、加熱調理香(例えば、焼成感、油調感等)の付与方法、スパイス感、甘味の増強方法、不快臭のマスキング方法等の提供も目的とする。
An object of the present invention is to provide a composition capable of imparting a charcoal-like stimulating flavor, which is one of the main components of the flavor developed by cooking, to a method for imparting a charcoal-like stimulating flavor, etc. And
In addition, the present invention also provides a composition capable of imparting cooked incense (e.g., burning sensation, oily feel, etc.) to foods, a spice sensation, a composition capable of enhancing sweetness, a composition capable of masking unpleasant odor, and a cooking odor (e.g. It is also an object of the present invention to provide a imparting method, a feeling of baking, an oily feeling, a feeling of spice, a method of enhancing sweetness, a masking method of unpleasant odors, and the like.
 本発明者らは、上述の課題を解決するべく種々検討した結果、特定の化合物を組み合わせることによって、炭様の刺激的な風味を食品に付与し得ることを見出した。
 さらに本発明者らは、当該特定の化合物の組み合わせが、加熱調理香(例えば、焼成感、油調感)を付与し得ること、スパイス感、甘味を増強し得ること、また不快臭をマスキングし得ることも見出した。
 本発明者らは、これらの知見に基づいてさらに研究を重ねることによって、本発明を完成するに至った。
 即ち、本発明は以下の通りである。
As a result of various studies to solve the above-mentioned problems, the present inventors have found that a charcoal-like stimulating flavor can be imparted to foods by combining specific compounds.
Furthermore, the present inventors have shown that the combination of the specific compounds can impart a cooked incense (e.g., burning sensation, oily sensation), a spice sensation, a sweetness enhancement, and an unpleasant odor masking. I also found out to get.
The present inventors have completed the present invention by further research based on these findings.
That is, the present invention is as follows.
[1](A)2-アセチルフランと、
 (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
 (C)フルフリルメチルジスルフィドと
を含有する組成物。
[2]食品における(A)の濃度が0.0002~500重量ppmとなるように食品に添加される、[1]記載の組成物。
[3](B1)を含有し、食品における(B1)の濃度が0.0001~100重量ppmとなるように食品に添加される、[1]又は[2]記載の組成物。
[4](B2)を含有し、食品における(B2)の濃度が0.0005~200重量ppmとなるように食品に添加される、[1]~[3]のいずれか一つに記載の組成物。
[5]食品における(C)の濃度が0.00001~300重量ppmとなるように食品に添加される、[1]~[4]のいずれか一つに記載の組成物。
[6](B1)を含有し、(A)の含有量と(B1)の含有量の重量比(A:B1)が、1:0.00005~10000である、[1]~[5]のいずれか一つに記載の組成物。
[7](B2)を含有し、(A)の含有量と(B2)の含有量の重量比(A:B2)が、1:0.0001~20000である、[1]~[6]のいずれか一つに記載の組成物。
[8](A)の含有量と(C)の含有量の重量比(A:C)が、1:0.000005~1000である、[1]~[7]のいずれか一つに記載の組成物。
[9]炭様の刺激的な風味付与用である、[1]~[8]のいずれか一つに記載の組成物。
[10]加熱調理香付与用である、[1]~[8]のいずれか一つに記載の組成物。
[11]加熱調理香付与が、焼成感及び油調感からなる群より選択される少なくとも一つの付与である、[10]記載の組成物。
[12]スパイス感及び甘味からなる群より選択される少なくとも一つの増強用である、[1]~[8]のいずれか一つに記載の組成物。
[13]不快臭のマスキング用である、[1]~[8]のいずれか一つに記載の組成物。
[14][1]~[13]のいずれか一つに記載の組成物を含有する食品。
[15](A)2-アセチルフランと、
 (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
 (C)フルフリルメチルジスルフィドと
を添加することを含む、食品の製造方法。
[16]食品における(A)の濃度が0.0002~500重量ppmとなるように(A)を添加する、[15]記載の方法。
[17]食品における(B1)の濃度が0.0001~100重量ppmとなるように(B1)を添加することを含む、[15]又は[16]記載の方法。
[18]食品における(B2)の濃度が0.0005~200重量ppmとなるように(B2)を添加することを含む、[15]~[17]のいずれか一つに記載の方法。
[19]食品における(C)の濃度が0.00001~300重量ppmとなるように(C)を添加する、[15]~[18]のいずれか一つに記載の方法。
[20](B1)を添加することを含み、(A)の添加量と(B1)の添加量の重量比(A:B1)が、1:0.00005~10000である、[15]~[19]のいずれか一つに記載の方法。
[21](B2)を添加することを含み、(A)の添加量と(B2)の添加量の重量比(A:B2)が、1:0.0001~20000である、[15]~[20]のいずれか一つに記載の方法。
[22](A)の添加量と(C)の添加量の重量比(A:C)が、1:0.000005~1000である、[15]~[21]のいずれか一つに記載の方法。
[23]食品が、炭様の刺激的な風味が付与された食品である、[15]~[22]のいずれか一つに記載の方法。
[24]食品が、加熱調理香が付与された食品である、[15]~[22]のいずれか一つに記載の方法。
[25]加熱調理香が付与された食品が、焼成感及び油調感からなる群より選択される少なくとも一つが付与された食品である、[24]記載の方法。
[26]食品が、スパイス感及び甘味からなる群より選択される少なくとも一つが増強された食品である、[15]~[22]のいずれか一つに記載の方法。
[27]食品が、不快臭がマスキングされた食品である、[15]~[22]のいずれか一つに記載の方法。
[28](A)2-アセチルフランと、
 (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
 (C)フルフリルメチルジスルフィドと
を添加することを含む、炭様の刺激的な風味の付与方法;加熱調理香の付与方法(好ましくは、焼成感及び油調感からなる群より選択される少なくとも一つの付与方法);スパイス感及び甘味からなる群より選択される少なくとも一つの増強方法;不快臭のマスキング方法。
[29]食品における(A)の濃度が0.0002~500重量ppmとなるように(A)を食品に添加する、[28]記載の方法。
[30]食品における(B1)の濃度が0.0001~100重量ppmとなるように(B1)を食品に添加することを含む、[28]又は[29]記載の方法。
[31]食品における(B2)の濃度が0.0005~200重量ppmとなるように(B1)を食品に添加することを含む、[28]~[30]のいずれか一つに記載の方法。
[32]食品における(C)の濃度が0.00001~300重量ppmとなるように(C)を食品に添加する、[28]~[31]のいずれか一つに記載の方法。
[33](B1)を添加することを含み、(A)の添加量と(B1)の添加量の重量比(A:B1)が、1:0.00005~10000である、[28]~[32]のいずれか一つに記載の方法。
[34](B2)を添加することを含み、(A)の添加量と(B2)の添加量の重量比(A:B2)が、1:0.0001~20000である、[28]~[33]のいずれか一つに記載の方法。
[35](A)の添加量と(C)の添加量の重量比(A:C)が、1:0.000005~1000である、[28]~[34]のいずれか一つに記載の方法。
[1] (A) 2-acetylfuran;
(B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
(C) A composition containing furfurylmethyl disulfide.
[2] The composition according to [1], which is added to the food so that the concentration of (A) in the food is 0.0002 to 500 ppm by weight.
[3] The composition according to [1] or [2], which contains (B1) and is added to food so that the concentration of (B1) in the food is 0.0001 to 100 ppm by weight.
[4] The composition according to any one of [1] to [3], which contains (B2) and is added to the food such that the concentration of (B2) in the food is 0.0005 to 200 ppm by weight. Composition.
[5] The composition according to any one of [1] to [4], which is added to the food so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
[6] containing (B1), and the weight ratio (A: B1) of the content of (A) to the content of (B1) is 1: 0.00005 to 10000, [1] to [5] The composition as described in any one of these.
[7] containing (B2), wherein the weight ratio (A: B2) of the content of (A) to the content of (B2) is 1: 0.0001 to 20000 [1] to [6] The composition as described in any one of these.
[8] The weight ratio (A: C) of the content of (A) to the content of (C) is 1: 0.000005 to 1000, according to any one of [1] to [7] Composition.
[9] The composition according to any one of [1] to [8], which is for imparting a charcoal-like stimulating flavor.
[10] The composition according to any one of [1] to [8], which is used for imparting cooking incense.
[11] The composition according to [10], wherein the heat cooking incense is at least one application selected from the group consisting of a burning feeling and an oily feeling.
[12] The composition according to any one of [1] to [8], wherein the composition is for at least one enhancement selected from the group consisting of a spice feeling and sweetness.
[13] The composition according to any one of [1] to [8], which is used for masking unpleasant odors.
[14] A food containing the composition according to any one of [1] to [13].
[15] (A) 2-acetylfuran;
(B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
(C) A method for producing a food, comprising adding furfurylmethyl disulfide.
[16] The method according to [15], wherein (A) is added so that the concentration of (A) in the food is 0.0002 to 500 ppm by weight.
[17] The method according to [15] or [16], comprising adding (B1) so that the concentration of (B1) in the food is 0.0001 to 100 ppm by weight.
[18] The method according to any one of [15] to [17], comprising adding (B2) such that the concentration of (B2) in the food is 0.0005 to 200 ppm by weight.
[19] The method according to any one of [15] to [18], wherein (C) is added so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
[20] including adding (B1), wherein the weight ratio of the addition amount of (A) to the addition amount of (B1) (A: B1) is 1: 0.00005 to 10000, [19] The method according to any one of [19].
[21] including adding (B2), wherein the weight ratio (A: B2) of the addition amount of (A) to the addition amount of (B2) is 1: 0.0001 to 20000, [20] The method according to any one of [20].
[22] The weight ratio (A: C) of the addition amount of (A) and the addition amount of (C) is 1: 0.000005 to 1000, according to any one of [15] to [21] the method of.
[23] The method according to any one of [15] to [22], wherein the food is a food provided with a charcoal-like stimulating flavor.
[24] The method according to any one of [15] to [22], wherein the food is a food to which a cooked incense has been applied.
[25] The method according to [24], wherein the food provided with the cooked incense is a food provided with at least one selected from the group consisting of baking feeling and oily feeling.
[26] The method according to any one of [15] to [22], wherein the food is an enhanced food selected from at least one selected from the group consisting of a spice feeling and sweetness.
[27] The method according to any one of [15] to [22], wherein the food is a food with an unpleasant odor masked.
[28] (A) 2-acetylfuran;
(B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
(C) Charcoal-like stimulating flavor application method comprising adding furfurylmethyl disulfide; Heat-cooking flavoring application method (preferably at least selected from the group consisting of a burning sensation and an oily sensation One application method); at least one enhancement method selected from the group consisting of a spice sensation and sweetness; a masking method for unpleasant odors.
[29] The method according to [28], wherein (A) is added to the food so that the concentration of (A) in the food is 0.0002 to 500 ppm by weight.
[30] The method according to [28] or [29], comprising adding (B1) to the food so that the concentration of (B1) in the food is 0.0001 to 100 ppm by weight.
[31] The method according to any one of [28] to [30], comprising adding (B1) to the food so that the concentration of (B2) in the food is 0.0005 to 200 ppm by weight .
[32] The method according to any one of [28] to [31], wherein (C) is added to the food so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
[33] including adding (B1), wherein the weight ratio (A: B1) of the addition amount of (A) to the addition amount of (B1) is 1: 0.00005 to 10,000 [28] to [32] The method according to any one of [32].
[34] including adding (B2), wherein the weight ratio (A: B2) of the addition amount of (A) to the addition amount of (B2) is 1: 0.0001 to 20000, [33] The method according to any one of [33].
[35] The weight ratio (A: C) of the addition amount of (A) and the addition amount of (C) is 1: 0.000005 to 1000, according to any one of [28] to [34] the method of.
 本発明によれば、炭様の刺激的な風味を付与できる組成物を提供できる。
 本発明によれば、炭様の刺激的な風味が付与された食品の製造方法、並びに炭様の刺激的な風味の付与方法を提供できる。
 また本発明によれば、炭様の刺激的な風味を食品に付与できるため、加熱調理により発現する風味(加熱調理香)を効果的に付与された食品を提供できる。
 本発明によれば、焼成感及び油調感からなる群より選択される少なくとも一つが付与された食品を提供できる。
 本発明によれば、スパイス感及び甘味からなる群より選択される少なくとも一つが増強された食品、不快臭がマスキングされた食品を提供できる。
 本発明の組成物は、特定の化合物を混合することにより得られるため、当業者において一般に利用されている装置で製造でき、その製造条件も容易に制御できる。
 さらに、本発明の組成物は特定の化合物を含有するものであり、食品の種類に応じて組成を調整する必要がないため、様々な食品に広く利用できる。
ADVANTAGE OF THE INVENTION According to this invention, the composition which can provide a charcoal-like exciting flavor can be provided.
ADVANTAGE OF THE INVENTION According to this invention, the manufacturing method of the foodstuff provided with the charcoal-like stimulating flavor and the imparting method of charcoal-like stimulating flavor can be provided.
Moreover, according to this invention, since the charcoal-like exciting flavor can be provided to food, the food which was effectively provided with the flavor (cooking incense) expressed by heat cooking can be provided.
According to the present invention, a food provided with at least one selected from the group consisting of a burning feeling and an oily feeling can be provided.
ADVANTAGE OF THE INVENTION According to this invention, the foodstuff in which at least one selected from the group which consists of a spice feeling and sweet taste was strengthened, and the foodstuff by which the unpleasant odor was masked can be provided.
Since the composition of the present invention is obtained by mixing a specific compound, it can be produced by an apparatus generally used by those skilled in the art, and the production conditions can be easily controlled.
Furthermore, the composition of the present invention contains a specific compound, and since it is not necessary to adjust the composition according to the type of food, it can be widely used for various foods.
(本発明の組成物)
 本発明の組成物は、(A)2-アセチルフラン(CAS登録番号:1192-62-7、本明細書において単に「(A)」と称する場合がある)と、(B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン(CAS登録番号:23747-48-0、本明細書において単に「(B1)」と称する場合がある)及び(B2)フルフリルアルコール(CAS登録番号:98-00-0、本明細書において単に「(B2)」と称する場合がある)からなる群より選択される少なくとも一つと、(C)フルフリルメチルジスルフィド(CAS登録番号:57500-00-2、本明細書において単に「(C)」と称する場合がある)とを含有することを主たる特徴とする。
 本明細書において、(B1)及び(B2)からなる群より選択される少なくとも一つを、「成分グループB」と称する場合がある。当該成分グループBは、一つの化合物のみから構成される場合があることは言うまでもない。
(Composition of the present invention)
The composition of the present invention comprises (A) 2-acetylfuran (CAS registration number: 1192-62-7, which may be simply referred to herein as “(A)”), (B1) 6, 7- Dihydro-5-methyl-5H-cyclopentapyrazine (CAS registration number: 23747-48-0, sometimes referred to herein simply as “(B1)”) and (B2) furfuryl alcohol (CAS registration number: 98-00-0, which may be simply referred to herein as “(B2)”), and (C) furfurylmethyl disulfide (CAS Registry Number: 57500-00-2). In this specification, it is simply referred to as “(C)”).
In this specification, at least one selected from the group consisting of (B1) and (B2) may be referred to as “component group B”. It goes without saying that the component group B may be composed of only one compound.
 (A)、成分グループB及び(C)の各成分の製造方法は、いずれも特に制限されず、自体公知の方法(例えば、化学合成法、抽出法、発酵法等)によって製造したものを用いてよい。これらの成分は市販品を用いてもよく、簡便であることから好ましい。あるいは、各成分そのものを使用せずともよく、各成分のいずれか1種又は2種以上を多量に含有する食品素材を代わりに使用してもよい。 The production method of each component of (A), component group B and (C) is not particularly limited, and those produced by methods known per se (for example, chemical synthesis methods, extraction methods, fermentation methods, etc.) are used. It's okay. These components may be commercially available products, and are preferable because they are simple. Alternatively, each component itself may not be used, and a food material containing a large amount of any one or more of each component may be used instead.
 本発明の組成物は、成分グループBとして、(B1)及び(B2)からなる群より選択される少なくとも一つを含有すればよいが、(B1)及び(B2)を共に含有することがより好ましい。 The composition of the present invention may contain at least one selected from the group consisting of (B1) and (B2) as component group B, but more preferably contains both (B1) and (B2). preferable.
 好適な本発明の組成物の一態様は、(A)、(B1)、(B2)及び(C)を含有する組成物である。 A preferred embodiment of the composition of the present invention is a composition containing (A), (B1), (B2) and (C).
 本発明の組成物における(A)の含有量は、本発明の組成物に対し、通常0.1重量%以上であり、より好ましい効果が得られることから、好ましくは20重量%以上であり、より好ましくは25重量%以上である。また当該含有量は、本発明の組成物に対し、通常99重量%以下であり、コスト的な観点から、好ましくは35重量%以下であり、より好ましくは31重量%以下である。 The content of (A) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and since a more preferable effect is obtained, it is preferably 20% by weight or more, More preferably, it is 25% by weight or more. Further, the content is usually 99% by weight or less with respect to the composition of the present invention, and preferably 35% by weight or less, more preferably 31% by weight or less from the viewpoint of cost.
 本発明の組成物が(B1)を含有する場合、本発明の組成物における(B1)の含有量は、本発明の組成物に対し、通常0.1重量%以上であり、より好ましい効果が得られることから、好ましくは15重量%以上であり、より好ましくは18重量%以上である。また当該含有量は、本発明の組成物に対し、通常99重量%以下であり、コスト的な観点から、好ましくは30重量%以下であり、より好ましくは24重量%以下である。 When the composition of the present invention contains (B1), the content of (B1) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and a more preferable effect is obtained. Since it is obtained, it is preferably 15% by weight or more, more preferably 18% by weight or more. Further, the content is usually 99% by weight or less with respect to the composition of the present invention, and preferably 30% by weight or less, more preferably 24% by weight or less from the viewpoint of cost.
 本発明の組成物が(B2)を含有する場合、本発明の組成物における(B2)の含有量は、本発明の組成物に対し、通常0.1重量%以上であり、より好ましい効果が得られることから、好ましくは40重量%以上であり、より好ましくは45重量%以上である。また当該含有量は、本発明の組成物に対し、通常99重量%以下であり、コスト的な観点から、好ましくは55重量%以下であり、より好ましくは51重量%以下である。 When the composition of the present invention contains (B2), the content of (B2) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and a more preferable effect is obtained. Since it is obtained, it is preferably 40% by weight or more, and more preferably 45% by weight or more. Further, the content is usually 99% by weight or less with respect to the composition of the present invention, preferably 55% by weight or less, more preferably 51% by weight or less from the viewpoint of cost.
 本発明の組成物における(C)の含有量は、本発明の組成物に対し、通常0.1重量%以上であり、より好ましい効果が得られることから、好ましくは1重量%以上であり、より好ましくは1.5重量%以上である。また当該含有量は、本発明の組成物に対し、通常99重量%以下であり、コスト的な観点から、好ましくは7重量%以下であり、より好ましくは5重量%以下である。 The content of (C) in the composition of the present invention is usually 0.1% by weight or more with respect to the composition of the present invention, and since a more preferable effect is obtained, it is preferably 1% by weight or more, More preferably, it is 1.5% by weight or more. The content is usually 99% by weight or less with respect to the composition of the present invention, and preferably 7% by weight or less, more preferably 5% by weight or less from the viewpoint of cost.
 本発明の組成物が(B1)を含有する場合、本発明の組成物における(A)の含有量と(B1)の含有量の重量比(A:B1)は、より効果的に風味を付与し得ることから、好ましくは1:0.00005~10000であり、より好ましくは1:0.005~100であり、特に好ましくは1:0.5~1である。 When the composition of the present invention contains (B1), the weight ratio (A: B1) of the content of (A) and the content of (B1) in the composition of the present invention imparts flavor more effectively. Therefore, it is preferably 1: 0.00005 to 10,000, more preferably 1: 0.005 to 100, and particularly preferably 1: 0.5 to 1.
 本発明の組成物が(B2)を含有する場合、本発明の組成物における(A)の含有量と(B2)の含有量の重量比(A:B2)は、より効果的に風味を付与し得ることから、好ましくは1:0.0001~20000であり、より好ましくは1:0.01~100であり、特に好ましくは1:0.5~5である。 When the composition of the present invention contains (B2), the weight ratio (A: B2) of the content of (A) and the content of (B2) in the composition of the present invention imparts flavor more effectively. Therefore, it is preferably 1: 0.0001 to 20000, more preferably 1: 0.01 to 100, and particularly preferably 1: 0.5 to 5.
 本発明の組成物における(A)の含有量と(C)の含有量の重量比(A:C1)は、より効果的に風味を付与し得ることから、好ましくは1:0.000005~1000であり、より好ましくは1:0.0005~50であり、特に好ましくは1:0.05~3である。 The weight ratio (A: C1) of the content of (A) and the content of (C) in the composition of the present invention is preferably 1: 0.000005 to 1000 because it can impart a flavor more effectively. More preferably, it is 1: 0.0005 to 50, and particularly preferably 1: 0.05 to 3.
 本発明の組成物の形態は特に制限されず、例えば、固体状(粉末状、顆粒状等を含む)、液体状(スラリー状等を含む)、ゲル状、ペースト状等が挙げられる。 The form of the composition of the present invention is not particularly limited, and examples thereof include solid (including powder, granule and the like), liquid (including slurry and the like), gel, and paste.
 本発明の組成物は、(A)、成分グループB及び(C)のみからなるものであってよいが、これらに加えて、食品香料分野において慣用の基剤をさらに含有するものであってもよい。 The composition of the present invention may comprise only (A), component groups B and (C), but in addition to these, it may further contain a base commonly used in the field of food fragrances. Good.
 本発明の組成物の形態が液体状の場合の基剤としては、例えば、水、エタノール、グリセリン、プロピレングリコール、各種動植物油類等が挙げられる。
 本発明の組成物の形態が固体状の場合の基剤としては、例えば、澱粉、デキストリン、シクロデキストリン、スクロースやグルコースなどの各種糖類、蛋白質、ペプチド、食塩、固形脂、二酸化ケイ素、およびそれらの混合物、また酵母菌体や各種の粉末エキス類等が挙げられる。
Examples of the base when the form of the composition of the present invention is liquid include water, ethanol, glycerin, propylene glycol, various animal and vegetable oils, and the like.
As a base when the form of the composition of the present invention is solid, for example, starch, dextrin, cyclodextrin, various sugars such as sucrose and glucose, protein, peptide, salt, solid fat, silicon dioxide, and their Examples of the mixture include yeast cells and various powder extracts.
 本発明の組成物は、本発明の目的を損なわない限り、(A)、成分グループB及び(C)に加えて、例えば、賦形剤、pH調整剤、酸化防止剤、増粘安定剤、甘味料(例、砂糖類等)、酸味料、香辛料、着色料等を更に含有してよい。 Unless the object of the present invention is impaired, the composition of the present invention includes, for example, excipients, pH adjusters, antioxidants, thickening stabilizers, in addition to (A), component groups B and (C), Sweeteners (eg, sugars, etc.), acidulants, spices, colorants and the like may be further contained.
 本発明の組成物の製造は、食品香料分野で慣用の手法により行い得る。本発明の組成物は、例えば、濃縮処理、乾燥処理、脱色処理等を、単独で又は組み合わせて施されてもよい。 The production of the composition of the present invention can be performed by a conventional method in the field of food fragrance. The composition of the present invention may be subjected to, for example, concentration treatment, drying treatment, decolorization treatment, etc. alone or in combination.
 本発明の組成物は、炭様の刺激的な風味を付与するために、食品に添加できる。従って、本発明の組成物は、好ましくは炭様の刺激的な風味付与用組成物である。本発明において「食品」は、経口で摂取し得るものを広く包含する概念であり、飲料や調味料等も包含される。また「炭様の刺激的な風味付与用組成物」は、炭様の刺激的な風味付与剤を包含する概念である。 The composition of the present invention can be added to foods to impart a charcoal-like stimulating flavor. Therefore, the composition of the present invention is preferably a charcoal stimulating flavor imparting composition. In the present invention, “food” is a concept that broadly encompasses those that can be taken orally, and includes beverages and seasonings. The “charcoal stimulating flavor imparting composition” is a concept including a charcoal stimulating flavor imparting agent.
 本発明において「炭様の刺激的な風味」とは、例えば、餅を焼き、当該餅の表面が焦げたとき等に発現する香りである。炭様の刺激的な風味の有無や程度は、専門パネルによる官能評価(例えば、後述の実施例に示される官能評価等)によって評価できる。
 また本発明において炭様の刺激的な風味等の「付与」とは、例えば、炭様の刺激的な風味を有しない食品に、炭様の刺激的な風味を新たに付与することだけでなく、炭様の刺激的な風味を有する食品に、炭様の刺激的な風味を更に付与すること、すなわち炭様の刺激的な風味を増強することも含む概念である。
In the present invention, “charcoal-like stimulating flavor” is, for example, a fragrance that develops when grilled firewood and the surface of the firewood burns. The presence or absence and degree of charcoal-like stimulating flavor can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
Further, in the present invention, “providing” such as a charcoal-like stimulating flavor is not only the addition of a charcoal-like stimulating flavor to a food that does not have a charcoal-like stimulating flavor, for example. It is a concept including further imparting a charcoal-like stimulating flavor to a food product having a charcoal-like stimulating flavor, that is, enhancing the charcoal-like stimulating flavor.
 炭様の刺激的な風味を食品に付与することによって、加熱調理香を付与できるため、本発明の組成物は、加熱調理香を付与するために、食品に添加できる。従って、本発明の組成物は、加熱調理香付与用組成物であってよい。「加熱調理香付与用組成物」は、加熱調理香付与剤を包含する概念である。
 本発明において「加熱調理香」とは、食品を高温(例えば、90~700℃)で加熱調理した際に発現する香ばしい香りをいう。加熱調理香には、例えば、炒め、焼き、揚げ、焙焼、煮込み等により発生した香りが含まれる。加熱調理香の有無や程度は、専門パネルによる官能評価によって評価できる。
Since a cooked incense can be imparted by imparting a charcoal-like stimulating flavor to the food, the composition of the present invention can be added to the food to impart a cooked aroma. Therefore, the composition of the present invention may be a composition for imparting heat cooking incense. “A composition for imparting heat cooking incense” is a concept including a heat cooking incense imparting agent.
In the present invention, “cooked incense” refers to a fragrant fragrance that develops when food is cooked at a high temperature (eg, 90 to 700 ° C.). The cooked incense includes a fragrance generated by, for example, fried, baked, fried, roasted, stewed, or the like. The presence or absence and degree of cooking incense can be evaluated by sensory evaluation using a specialized panel.
 本発明の組成物は、加熱調理香として、焼成感、油調感を付与するために食品に添加することもできる。本発明において「焼成感」とは、食品を焼いた際に感じられる香ばしさを、「油調感」とは、食品を揚げた際に感じられる香ばしさをいい、焼成感及び油調感は、加熱調理香に含まれるものである。焼成感の付与及び油調感の付与は、それぞれ加熱調理香の付与機能の一部であり、本発明の加熱調理香付与組成物は、一態様として、焼成感付与用組成物、油調感付与用組成物であってよい。焼成感、油調感の有無や程度は、専門パネルによる官能評価(例えば、後述の実施例に示される官能評価等)によって評価できる。 The composition of the present invention can also be added to foods as a cooked incense in order to impart a burning feeling and an oily feeling. In the present invention, "baking feeling" refers to the aroma that is felt when the food is baked, and "oil feeling" refers to the aroma that is felt when the food is fried. Included in cooking incense. Giving a feeling of firing and imparting an oily feel are part of the function of imparting a cooked incense, respectively. It may be an imparting composition. The presence / absence and degree of firing feeling and oil feel can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
 本発明の組成物は、スパイス感及び甘味からなる群より選択される少なくとも一つを増強するために食品に添加することもでき、本発明の組成物は一態様として、スパイス感及び甘味からなる群より選択される少なくとも一つの増強用組成物であってよい。本発明において「スパイス感」とは、スパイス特有の風味、辛味をいう。スパイス感、甘味の有無や程度は、それぞれ専門パネルによる官能評価(例えば、後述の実施例に示される官能評価等)によって評価できる。
 本発明においてスパイス感の「増強」とは、あたかもスパイス濃度を高めたかのように、スパイス特有の風味、辛味が強く感じられるようになることをいう。本発明におけるスパイスは、食品の風味付け、辛味付け等に一般に用いられ得るものであれば特に制限されないが、例えば、ナツメグ、メース、ガーリック、ローレル、タイム、コショー(例、ブラックペッパー、ホワイトペッパー等)、バジル、ジンジャー、ターメリック、フェンネル、キャラウェイ、チリペッパー、シナモン、マジョラム、ローズマリー、クミン、セロリ、コリアンダー、オニオン等が挙げられ、好ましくは、ナツメグ、メース、ガーリック、ローレル、ブラックペッパー、ホワイトペッパー、バジル、ジンジャー、ターメリック、フェンネル、キャラウェイ、チリペッパー、シナモン、クミン、オニオンであり、より好ましくは、ブラックペッパー、ホワイトペッパー、ガーリック、オニオンである。
 本発明において甘味の「増強」とは、あたかも甘味成分の濃度を高めたかのように、甘味が強く感じられるようになることをいう。本発明において「甘味成分」とは、口腔内に含んだ際に甘味を呈し得る物質をいい、例えば、砂糖、でん粉糖(例、果糖、ブドウ糖、麦芽糖、異性化糖、水飴等)、糖アルコール(例、ソルビトール、マンニトール、マルチトール、キシリトール等)、フラクトオリゴ糖等の糖類;ステビア、グリチルリチン、ソーマチン、サッカリン、アスパルテーム、アセスルファムカリウム等の非糖質系甘味料等が挙げられる。
The composition of the present invention can be added to a food to enhance at least one selected from the group consisting of spice feeling and sweetness, and the composition of the present invention comprises spice feeling and sweetness as one aspect. It may be at least one enhancing composition selected from the group. In the present invention, “feeling of spice” means a flavor and pungent taste peculiar to spices. The presence / absence and degree of spice feeling and sweetness can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
In the present invention, “enhancement” of the feeling of spice means that the flavor and pungent taste peculiar to the spice can be felt as if the spice concentration is increased. The spice in the present invention is not particularly limited as long as it can be generally used for flavoring, spicy seasoning, etc. of food, but for example, nutmeg, mace, garlic, laurel, thyme, cosh (eg, black pepper, white pepper, etc.) ), Basil, ginger, turmeric, fennel, caraway, chili pepper, cinnamon, marjoram, rosemary, cumin, celery, coriander, onion, etc., preferably nutmeg, mace, garlic, laurel, black pepper, white Pepper, basil, ginger, turmeric, fennel, caraway, chili pepper, cinnamon, cumin and onion, more preferably black pepper, white pepper, garlic and onion.
In the present invention, “enhancement” of sweetness means that sweetness is felt strongly as if the concentration of the sweetening component is increased. In the present invention, the “sweet ingredient” refers to a substance that can exhibit sweetness when contained in the oral cavity. For example, sugar, starch sugar (eg, fructose, glucose, maltose, isomerized sugar, syrup, etc.), sugar alcohol (Eg, sorbitol, mannitol, maltitol, xylitol, etc.), saccharides such as fructooligosaccharides; non-saccharide sweeteners such as stevia, glycyrrhizin, thaumatin, saccharin, aspartame, acesulfame potassium and the like.
 本発明の組成物は、不快臭をマスキングするために食品に添加することもでき、本発明の組成物は一態様として、不快臭のマスキング用組成物であってよい。
 本発明において「不快臭」とは、主として各種畜肉原料、魚介原料、野菜原料、酵母原料等に起因する、不快感を惹起させ得る臭いの総称であり、具体例としては、獣臭さ、生臭さ、青臭さ、発酵臭等が挙げられる。また不快臭の「マスキング」とは、不快臭が部分的又は完全に感知されなくなることをいう。不快臭のマスキングの程度は、専門パネルによる官能評価(例えば、後述の実施例に示される官能評価等)によって評価できる。
The composition of the present invention can be added to foods in order to mask unpleasant odor, and the composition of the present invention may be a composition for masking unpleasant odor as one embodiment.
In the present invention, “unpleasant odor” is a general term for odors that can cause unpleasant sensations mainly due to various animal meat raw materials, seafood raw materials, vegetable raw materials, yeast raw materials, and the like. Specific examples include animal odor, raw odor Examples include blue odor and fermentation odor. Also, “masking” of unpleasant odors means that unpleasant odors are not sensed partially or completely. The degree of masking of unpleasant odor can be evaluated by sensory evaluation (for example, sensory evaluation shown in Examples described later) by a specialized panel.
 本発明の組成物は、一態様として、香料組成物であってよい。本発明において「香料」とは、香り、風味、味等を食品に付与するために用いられる食品添加物をいう。本発明の組成物は、好適な一態様として、炭様の刺激的な風味付与用の香料組成物あるいは加熱調理香の付与用の香料組成物(例、焼成感付与用の香料組成物、油調感付与用の香料組成物等)であってよい。本発明の組成物は、別の好適な一態様として、スパイス感及び甘味からなる群より選択される少なくとも一つの増強用の香料組成物あるいは不快臭のマスキング用の香料組成物であってもよい。 The composition of the present invention may be a fragrance composition as one aspect. In the present invention, the “perfume” refers to a food additive used for imparting a fragrance, flavor, taste or the like to food. The composition of the present invention, as a preferred embodiment, is a fragrance composition for imparting a charcoal-like stimulating flavor or a fragrance composition for imparting cooked incense (eg, a fragrance composition for imparting a burning sensation, an oil A fragrance composition for imparting sensation, etc.). In another preferred embodiment, the composition of the present invention may be at least one enhancing fragrance composition selected from the group consisting of spice feeling and sweetness, or an unpleasant odor masking fragrance composition. .
 本発明の組成物を添加し得る食品は特に制限されないが、一態様として、加熱調理香が付与されることを所望されるものが好ましく、例えば、野菜炒め、炒飯、焼きそば、回鍋肉、麻婆豆腐、青椒肉絲、干焼蝦仁、肉野菜炒め、ナシゴレン、焼きビーフン、炒り卵、きんぴらごぼう、カレールウ、肉炒め、中華丼等の炒め物;蒸し野菜等の蒸し物;焼き魚、焼き鳥、ステーキ、焼肉、すき焼き、ハンバーグ、焼き野菜、焼きおにぎり、米菓、各種焼き菓子(例、クッキー等)、ピザ生地、パン等の焼き物;から揚げ、フライ、素揚げ、てんぷら等の各種揚げ物及びそのバッターやパン粉;ドレッシング(例、和風ドレッシング、クリーミードレッシング、シーザードレッシング、フレンチドレッシング、タルタルソース、マヨネーズ等);ソース(例、ステーキソース、生姜焼きのたれ、ピザソース、カラメルソース、みたらし団子のたれ、焼肉のたれ、デミグラスソース等);コンソメスープ、ポタージュスープ、クリームスープ、ミネストローネスープ、コーンスープ、トマトスープ等のスープ;天然系調味料、風味調味料等の調味料;コーヒー、紅茶、中国茶、緑茶、ココア、麦茶、ハーブティー等の飲料;及びこれらの加工品(例、電子レンジ調理用食品、インスタント食品、冷凍食品、乾燥食品等)等が挙げられる。
 本発明において「食品」とは、経口摂取し得るものを広く包含する概念であり、調味料、飲料等も含まれる。
 また本明細書において「天然系調味料」とは、天然物を原料として、抽出、分解、加熱、発酵等の手法によって製造される調味料をいい、その具体例としては、鶏肉エキス、牛肉エキス、豚肉エキス、羊肉エキス等の各種畜肉エキス類;鶏がらエキス、牛骨エキス、豚骨エキス等の各種がらエキス類;鰹エキス、鯖エキス、ぐちエキス、帆立エキス、蟹エキス、蝦エキス、煮干エキス、干し貝柱エキス等の各種魚介エキス類;鰹節エキス、鯖節エキス、宗田節エキス等の各種節エキス類;オニオンエキス、白菜エキス、セロリエキス等の各種野菜エキス類;昆布エキス等の各種海藻エキス類;ガーリックエキス、唐辛子エキス、胡椒エキス、カカオエキス等の各種香辛料エキス類;酵母エキス類;各種タンパク加水分解物;醤油、魚醤、蝦醤、味噌等の各種発酵調味料等やその混合物、加工品等が挙げられる。
 また本明細書において「風味調味料」とは、食品に風味原料の香気、風味、味を付与するために用いられる調味料をいい、例えば、天然系調味料に砂糖類、食塩等を加えること等によって製造できる。風味調味料の具体例としては、鶏風味調味料、牛風味調味料、豚風味調味料等の各種畜肉風味調味料;鰹風味調味料、煮干風味調味料、干し貝柱風味調味料、甲殻類風味調味料等の各種魚介風味調味料;各種香辛野菜風味調味料;昆布風味調味料等が挙げられる。
The food to which the composition of the present invention can be added is not particularly limited, but as one aspect, those that are desired to be provided with cooked incense are preferable, for example, stir-fried vegetables, fried rice, fried noodles, roasted meat, mapo tofu , Green crab meat, dried yakijin, stir-fried meat vegetables, nasi goreng, grilled rice noodles, fried egg, kinpira burdock, karerou, stir-fried meat, fried meat such as Chinese bowl; steamed vegetables, etc .; grilled fish, yakitori, steak, yakiniku, Sukiyaki, hamburger, grilled vegetables, grilled rice balls, rice crackers, various baked goods (eg, cookies), pizza dough, baked goods such as bread; various fried foods such as fried, fried, deep fried, tempura, and batters and breadcrumbs thereof; Dressing (eg, Japanese style dressing, creamy dressing, Caesar dressing, French dressing, tartar sauce, mayonnaise, etc.); (Eg, steak sauce, ginger grilled sauce, pizza sauce, caramel sauce, mitarashi dumpling sauce, grilled meat sauce, demiglace sauce, etc.); consommé soup, potage soup, cream soup, minestrone soup, corn soup, tomato soup, etc. Seasonings such as natural seasonings and flavor seasonings; beverages such as coffee, tea, Chinese tea, green tea, cocoa, barley tea, herbal tea; and processed products thereof (eg, food for microwave oven cooking, instant food, Frozen foods, dried foods, etc.).
In the present invention, “food” is a concept that broadly encompasses those that can be taken orally, and includes seasonings, beverages, and the like.
In the present specification, the term “natural seasoning” refers to a seasoning produced from a natural product as a raw material by a technique such as extraction, decomposition, heating, fermentation, etc., and specific examples thereof include chicken extract and beef extract. , Various animal meat extracts such as pork extract, lamb extract; chicken extract, beef bone extract, pork bone extract, etc .; rice cake extract, rice cake extract, glutinous extract, scallop extract, rice cake extract, rice cake extract, Various seafood extracts such as boiled and dried scallop extracts; various node extracts such as bonito extract, bonito extract and soda-bushi extract; various vegetable extracts such as onion extract, Chinese cabbage extract and celery extract; various types such as kelp extract Seaweed extracts; various spice extracts such as garlic extract, pepper extract, pepper extract, cacao extract; yeast extract; various protein hydrolysates; soy sauce, fish sauce, salmon sauce Various fermented seasonings and mixtures thereof, such as miso, processed products and the like.
In the present specification, the term “flavored seasoning” refers to a seasoning used for imparting the flavor, flavor and taste of a flavor raw material to food, for example, adding sugars, salt, etc. to natural seasonings. Can be manufactured by etc. Specific examples of flavor seasonings include chicken flavor seasonings, beef flavor seasonings, pork flavor seasonings, and other meat-flavored seasonings; salmon flavor seasonings, boiled and dried seasonings, dried scallop flavor seasonings, and crustacean flavors. Various seafood flavor seasonings such as seasonings; various spicy vegetable flavor seasonings; kelp flavor seasonings and the like.
 本発明の組成物は、不快臭がマスキングされることを所望される食品に添加されてもよく、そのような食品の種類としては、例えば、各種畜肉含有食品、魚介含有食品(例、ぶり大根等)、野菜含有食品(例、野菜炒め、大豆ハンバーグ等)、エキス(例、畜肉エキス類、魚介エキス類、野菜エキス類、酵母エキス類等)又はその分解物を含有する食品、並びにこれらの加工品(例、電子レンジ調理用食品、インスタント食品、冷凍食品、乾燥食品等)等が挙げられる。 The composition of the present invention may be added to foods for which unpleasant odor is desired to be masked. Examples of such foods include various livestock meat-containing foods, seafood-containing foods (eg, radish Etc.), foods containing vegetables (eg, fried vegetables, soybean hamburger, etc.), extracts (eg, livestock meat extracts, seafood extracts, vegetable extracts, yeast extracts, etc.) or foods containing degradation products thereof, and these Processed products (eg, food for cooking in a microwave oven, instant food, frozen food, dried food, etc.) and the like can be mentioned.
 本発明の組成物は、スパイス感が増強されることを所望される食品に添加されてもよく、そのような食品の種類は、スパイスを含有するものであれば特に制限されないが、例えば、加熱調理香が付与されることを所望される食品として例示したもの(上述)と同様のもの等が挙げられる。食品のスパイス濃度は、好ましくは0.001~20重量%であり、より好ましくは0.01~10重量%であり、特に好ましくは0.1~1重量%である。 The composition of the present invention may be added to foods for which it is desired that the feeling of spice is enhanced, and the type of such food is not particularly limited as long as it contains spices. The thing similar to what was illustrated as a foodstuff to which cooking incense is desired (above-mentioned) etc. are mentioned. The spice concentration of the food is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight, and particularly preferably 0.1 to 1% by weight.
 本発明の組成物は、甘味が増強されることを所望される食品に添加されてもよく、そのような食品の種類は、甘味成分を含有するものであれば特に制限されないが、例えば、菓子類(例、みたらしだんご、プリン等)、飲料(例、清涼飲料、エナジードリンク等)、パン類、乳製品等が挙げられる。食品の甘味成分濃度は、好ましくは0.001~20重量%であり、より好ましくは0.01~10重量%であり、特に好ましくは0.1~1重量%である。 The composition of the present invention may be added to foods whose sweetness is desired to be enhanced, and the type of such foods is not particularly limited as long as it contains a sweetening ingredient. (Eg, mitarashi dango, pudding, etc.), beverages (eg, soft drinks, energy drinks, etc.), breads, dairy products and the like. The concentration of sweetening ingredients in the food is preferably 0.001 to 20% by weight, more preferably 0.01 to 10% by weight, and particularly preferably 0.1 to 1% by weight.
 本発明の組成物を添加し得る食品は、喫食に適した態様で提供(販売、流通等)されるものであってよく、又は喫食に適した態様になるための所定の処理や調理を必要とする態様で提供(販売、流通等)されるものであってもよい。例えば、本発明の組成物を添加し得る食品は、喫食に適した態様となるために水等で希釈することを必要とする濃縮物等として提供されてよい。 The food to which the composition of the present invention can be added may be provided (sold, distributed, etc.) in a mode suitable for eating, or requires a predetermined treatment or cooking to become a mode suitable for eating. May be provided (sold, distributed, etc.). For example, a food product to which the composition of the present invention can be added may be provided as a concentrate or the like that needs to be diluted with water or the like in order to be suitable for eating.
 本発明の組成物を食品に添加する方法及び条件は特に限定されず、本発明の組成物の形態や食品の種類等に応じて適宜設定できる。本発明の組成物を食品に添加する時期は特に限定されず、いかなる時点で添加してもよいが、例えば、食品の製造中、食品の完成後(例、食品の喫食直前、食品の喫食中等)等が挙げられる。食品を製造する前の食品原料に本発明の組成物を添加してもよい。 The method and conditions for adding the composition of the present invention to food are not particularly limited, and can be appropriately set according to the form of the composition of the present invention, the type of food, and the like. The time when the composition of the present invention is added to the food is not particularly limited, and may be added at any time. For example, during the production of the food, after the completion of the food (eg, immediately before eating the food, during the eating of the food, etc. ) And the like. You may add the composition of this invention to the foodstuff raw material before manufacturing a foodstuff.
 本発明の組成物は、炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等に添加される場合、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(A)の濃度が、0.0002重量ppm以上となるように添加されることが好ましく、0.02重量ppm以上となるように添加されることがより好ましく、2重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(A)の濃度が、500重量ppm以下となるように添加されることが好ましく、100重量ppm以下となるように添加されることがより好ましく、10重量ppm以下となるように添加されることが特に好ましい。
 本明細書中、「食品における(A)の濃度」とは、食品に添加される(A)の重量の、添加後の食品全体の重量に対する割合をいい、例えば、食品に(A)を添加する前から該食品が予め(A)と同様の成分を含有する場合、食品が予め含有する成分の重量は、食品に添加される(A)の重量に含めない。当該説明は、以下に示す食品における(A)以外の成分の濃度(例えば、「食品における(B1)の濃度」等)についても準用される。
 上述の「食品における(A)の濃度」は、喫食時濃度であることが好ましい。本明細書中、「喫食時濃度」とは、食品を喫食する際における濃度をいう。本発明の組成物を添加し得る食品が、例えば、喫食に適した態様となるために水等で希釈することを必要とする濃縮物や、他の食品に添加して使用される調味料等である場合、食品における(A)の濃度は希釈倍率や添加量等に応じて適宜調整してよい。当該説明は、以下に示す食品における(A)以外の成分の濃度(例えば、「食品における(B1)の濃度」等)についても準用される。
When the composition of the present invention is added to stir-fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof, the food can be given more effectively. It is preferable that the concentration of (A) in (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery or processed product thereof) is 0.0002 ppm by weight or more, It is more preferable to add so that it may become 0.02 weight ppm or more, and it is especially preferable to add so that it may become 2 weight ppm or more. In this case, since the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (A) is 500 ppm by weight or less, more preferably 100 ppm by weight or less, and 10 ppm by weight or less. It is particularly preferable.
In this specification, “the concentration of (A) in food” refers to the ratio of the weight of (A) added to food to the total weight of the food after addition, for example, (A) is added to food In the case where the food contains components similar to (A) in advance, the weight of the components previously contained in the food is not included in the weight of (A) added to the food. The said description is applied mutatis mutandis also about the density | concentration (For example, "the density | concentration of (B1) in a foodstuff" etc.) other than (A) in the foodstuff shown below.
The above-mentioned “concentration of (A) in food” is preferably a concentration at the time of eating. In this specification, “concentration at eating” refers to the concentration at the time of eating food. The food to which the composition of the present invention can be added is, for example, a concentrate that needs to be diluted with water or the like to become an aspect suitable for eating, a seasoning that is used by adding to other foods, etc. In this case, the concentration of (A) in the food may be appropriately adjusted according to the dilution rate, the amount added, and the like. The said description is applied mutatis mutandis also about the density | concentration (For example, "the density | concentration of (B1) in a foodstuff" etc.) other than (A) in the foodstuff shown below.
 本発明の組成物が(B1)を含有し、炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等に添加される場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(B1)の濃度が、0.0001重量ppm以上となるように添加されることが好ましく、0.02重量ppm以上となるように添加されることがより好ましく、2重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(B1)の濃度が、100重量ppm以下となるように添加されることが好ましく、50重量ppm以下となるように添加されることがより好ましく、10重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention contains (B1) and is added to fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof, the composition of the present invention is more Since the flavor can be effectively imparted, the concentration of (B1) in the food (fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery or processed product thereof) is 0.0001 weight. It is preferably added so as to be at least ppm, more preferably added to be at least 0.02 ppm by weight, and particularly preferably added to be at least 2 ppm by weight. In this case, since the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (B1) is 100 ppm by weight or less, more preferably 50 ppm by weight or less, and 10 ppm by weight or less. It is particularly preferable.
 本発明の組成物が(B2)を含有し、炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等に添加される場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(B2)の濃度が、0.0005重量ppm以上となるように添加されることが好ましく、0.05重量ppm以上となるように添加されることがより好ましく、5重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(B2)の濃度が、200重量ppm以下となるように添加されることが好ましく、100重量ppm以下となるように添加されることがより好ましく、20重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention contains (B2) and is added to fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof, the composition of the present invention is more Since the flavor can be effectively imparted, the concentration of (B2) in the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery or processed product thereof) is 0.0005 wt. It is preferably added so as to be at least ppm, more preferably added so as to be at least 0.05 ppm by weight, and particularly preferably added so as to be at least 5 ppm by weight. In this case, since the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (B2) is 200 ppm by weight or less, more preferably 100 ppm by weight or less, and 20 ppm by weight or less. It is particularly preferable.
 本発明の組成物は、炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等に添加される場合、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(C)の濃度が、0.00001重量ppm以上となるように添加されることが好ましく、0.002重量ppm以上となるように添加されることがより好ましく、0.2重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品、菓子類又はそれらの加工品等)における(C)の濃度が、300重量ppm以下となるように添加されることが好ましく、30重量ppm以下となるように添加されることがより好ましく、2重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention is added to stir-fried foods, grilled foods, fried foods, seafood-containing foods, vegetable-containing foods, confectionery or processed products thereof, the food can be given more effectively. It is preferable that the concentration of (C) in (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery or processed product thereof) is 0.00001 ppm by weight or more, It is more preferable to add so that it may become 0.002 weight ppm or more, and it is especially preferable to add so that it may become 0.2 weight ppm or more. In this case, since the composition of the present invention can impart flavor more effectively, the food (stir-fried food, grilled food, fried food, seafood-containing food, vegetable-containing food, confectionery, processed products thereof, etc. ) Is preferably added so that the concentration of (C) is 300 ppm by weight or less, more preferably 30 ppm by weight or less, and 2 ppm by weight or less. It is particularly preferable.
 本発明の組成物は、調味料等に添加される場合、より効果的に風味を付与し得ることから、当該食品(調味料等)における(A)の濃度が、0.002重量ppm以上となるように添加されることが好ましく、0.2重量ppm以上となるように添加されることがより好ましく、20重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(調味料等)における(A)の濃度が、50000重量ppm以下となるように添加されることが好ましく、10000重量ppm以下となるように添加されることがより好ましく、1000重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention is added to a seasoning or the like, it can impart a flavor more effectively, so that the concentration of (A) in the food (seasoning or the like) is 0.002 ppm by weight or more. It is preferable to add so that it may become 0.2 weight ppm or more, It is more preferable to add so that it may become 20 weight ppm or more. In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (A) in the food (condiment etc.) is 50000 ppm by weight or less. It is more preferable to add it so that it may become 10,000 weight ppm or less, and it is especially preferable to add so that it may become 1000 weight ppm or less.
 本発明の組成物が(B1)を含有し、調味料等に添加される場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(調味料等)における(B1)の濃度が、0.001重量ppm以上となるように添加されることが好ましく、0.2重量ppm以上となるように添加されることがより好ましく、20重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(調味料等)における(B1)の濃度が、10000重量ppm以下となるように添加されることが好ましく、5000重量ppm以下となるように添加されることがより好ましく、1000重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention contains (B1) and is added to a seasoning or the like, the composition of the present invention can impart a flavor more effectively, so in the food (seasoning or the like) ( The concentration of B1) is preferably added so as to be 0.001 ppm by weight or more, more preferably added so as to be 0.2 ppm by weight or more, and added so as to be 20 ppm by weight or more. It is particularly preferred that In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (B1) in the food (condiment etc.) is 10,000 ppm by weight or less. It is more preferable to add it so that it becomes 5000 ppm by weight or less, and it is particularly preferable to add it so that it becomes 1000 ppm by weight or less.
 本発明の組成物が(B2)を含有し、調味料等に添加される場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(調味料等)における(B2)の濃度が、0.005重量ppm以上となるように添加されることが好ましく、0.5重量ppm以上となるように添加されることがより好ましく、50重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(調味料等)における(B2)の濃度が、20000重量ppm以下となるように添加されることが好ましく、10000重量ppm以下となるように添加されることがより好ましく、2000重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention contains (B2) and is added to a seasoning or the like, the composition of the present invention can impart a flavor more effectively, so in the food (seasoning or the like) ( B2) is preferably added so that the concentration is 0.005 ppm by weight or more, more preferably 0.5 ppm by weight or more, and 50 ppm by weight or more. It is particularly preferred that In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (B2) in the food (condiment etc.) is 20000 ppm by weight or less. It is more preferable to add it so that it becomes 10,000 ppm by weight or less, and it is particularly preferable to add it so that it becomes 2000 ppm by weight or less.
 本発明の組成物は、調味料等に添加される場合、より効果的に風味を付与し得ることから、当該食品(調味料等)における(C)の濃度が、0.0001重量ppm以上となるように添加されることが好ましく、0.02重量ppm以上となるように添加されることがより好ましく、2重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(調味料等)における(C)の濃度が、30000重量ppm以下となるように添加されることが好ましく、3000重量ppm以下となるように添加されることがより好ましく、200重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention is added to a seasoning or the like, it can impart a flavor more effectively, so the concentration of (C) in the food (seasoning or the like) is 0.0001 ppm by weight or more. It is preferable to add so that it may become 0.02 weight ppm or more, It is more preferable to add so that it may become 2 weight ppm or more. In this case, since the composition of the present invention can impart flavor more effectively, it is added so that the concentration of (C) in the food (condiment etc.) is 30000 ppm by weight or less. It is more preferable that it is added so that it becomes 3000 ppm by weight or less, and it is particularly preferable that it is added so that it becomes 200 ppm by weight or less.
 本発明の組成物は、スパイス含有食品又はその加工品等に添加される場合、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(A)の濃度が、0.00002重量ppm以上となるように添加されることが好ましく、0.002重量ppm以上となるように添加されることがより好ましく、0.2重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(A)の濃度が、500重量ppm以下となるように添加されることが好ましく、100重量ppm以下となるように添加されることがより好ましく、10重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention is added to a spice-containing food or processed product thereof, it can impart a more effective flavor. The concentration is preferably added to be 0.00002 ppm by weight or more, more preferably added to be 0.002 ppm by weight or more, and added to be 0.2 ppm by weight or more. It is particularly preferable. In this case, since the composition of the present invention can impart flavor more effectively, the concentration of (A) in the food (such as a spice-containing food or a processed product thereof) is 500 ppm by weight or less. It is preferably added so that it is 100 ppm by weight or less, more preferably 10 ppm by weight or less.
 本発明の組成物が(B1)を含有し、スパイス含有食品又はその加工品等に添加される場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(B1)の濃度が、0.00001重量ppm以上となるように添加されることが好ましく、0.002重量ppm以上となるように添加されることがより好ましく、0.2重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(B1)の濃度が、100重量ppm以下となるように添加されることが好ましく、50重量ppm以下となるように添加されることがより好ましく、10重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention contains (B1) and is added to a spice-containing food or a processed product thereof, the composition of the present invention can impart flavor more effectively. The content of (B1) in the contained food or processed product thereof is preferably 0.00001 ppm by weight or more, more preferably 0.002 ppm by weight or more. It is particularly preferable to add such that it becomes 0.2 ppm by weight or more. In this case, since the composition of the present invention can impart flavor more effectively, the concentration of (B1) in the food (such as a spice-containing food or a processed product thereof) is 100 ppm by weight or less. It is preferably added so that it is 50 ppm by weight or less, more preferably 10 ppm by weight or less.
 本発明の組成物が(B2)を含有し、スパイス含有食品又はその加工品等に添加される場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(B2)の濃度が、0.00005重量ppm以上となるように添加されることが好ましく、0.005重量ppm以上となるように添加されることがより好ましく、0.5重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(B2)の濃度が、200重量ppm以下となるように添加されることが好ましく、100重量ppm以下となるように添加されることがより好ましく、20重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention contains (B2) and is added to a spice-containing food or a processed product thereof, the composition of the present invention can impart flavor more effectively. The content of (B2) in the contained food or processed product thereof is preferably 0.00005 ppm by weight or more, more preferably 0.005 ppm by weight or more. It is particularly preferable to add such that it becomes 0.5 ppm by weight or more. In this case, since the composition of the present invention can impart flavor more effectively, the concentration of (B2) in the food (such as spice-containing food or processed product thereof) is 200 ppm by weight or less. It is preferable to add so that it may become 100 weight ppm or less, It is more preferable to add so that it may become 20 weight ppm or less.
 本発明の組成物は、スパイス含有食品又はその加工品等に添加される場合、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(C)の濃度が、0.000001重量ppm以上となるように添加されることが好ましく、0.0002重量ppm以上となるように添加されることがより好ましく、0.02重量ppm以上となるように添加されることが特に好ましい。また、この場合、本発明の組成物は、より効果的に風味を付与し得ることから、当該食品(スパイス含有食品又はその加工品等)における(C)の濃度が、300重量ppm以下となるように添加されることが好ましく、30重量ppm以下となるように添加されることがより好ましく、2重量ppm以下となるように添加されることが特に好ましい。 When the composition of the present invention is added to a spice-containing food or a processed product thereof, the flavor can be imparted more effectively, so that (C) in the food (a spice-containing food or a processed product thereof) is concerned. The concentration is preferably added to be 0.000001 ppm by weight or more, more preferably added to be 0.0002 ppm by weight or more, and added to be 0.02 ppm by weight or more. It is particularly preferable. In this case, since the composition of the present invention can impart flavor more effectively, the concentration of (C) in the food (such as a spice-containing food or a processed product thereof) is 300 ppm by weight or less. Preferably, it is added so that it may become 30 weight ppm or less, It is especially preferable to add so that it may become 2 weight ppm or less.
 本発明によれば、本発明の組成物を含有する食品(本明細書中、単に「本発明の食品」と称する場合がある)も提供される。
 本発明の食品における本発明の組成物の含有量は、本発明の食品における(A)、成分グループB及び(C)の各濃度が、上述の範囲内となるように適宜調整すればよく、特に制限されない。
 本発明の食品の種類は特に制限されないが、加熱調理香が付与されることを所望されるもの、不快臭がマスキングされることを所望されるもの、スパイス感が増強されることを所望されるもの、甘味が増強されることを所望されるものが好ましく、例えば、本発明の組成物を添加し得る食品として例示したものと同様のものが挙げられる。
According to the present invention, a food containing the composition of the present invention (sometimes referred to simply as “the food of the present invention” in the present specification) is also provided.
The content of the composition of the present invention in the food of the present invention may be appropriately adjusted so that the concentrations of (A), component groups B and (C) in the food of the present invention are within the above-mentioned ranges, There is no particular limitation.
The type of the food of the present invention is not particularly limited, but it is desired that a cooked incense is given, that an unpleasant odor is desired to be masked, and that a feeling of spice is enhanced. And those in which sweetness is desired to be enhanced are preferable, and examples thereof include those exemplified as foods to which the composition of the present invention can be added.
(本発明の製造方法)
 本発明は、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することを含む、食品の製造方法(本明細書中、単に「本発明の製造方法」と称する場合がある)も提供する。
(Production method of the present invention)
The present invention relates to a method for producing a food comprising adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It may also be referred to as “the manufacturing method of the present invention”).
 本発明の製造方法は、成分グループBとして、(B1)及び(B2)からなる群より選択される少なくとも一つを添加すればよいが、(B1)及び(B2)を共に添加することが好ましい。 In the production method of the present invention, at least one selected from the group consisting of (B1) and (B2) may be added as component group B, but it is preferable to add both (B1) and (B2). .
 好適な本発明の製造方法の一態様は、(A)、(B1)、(B2)及び(C)を添加することを含む、食品の製造方法である。 A preferred embodiment of the production method of the present invention is a food production method including adding (A), (B1), (B2) and (C).
 本発明の製造方法によって製造される食品は特に制限されないが、加熱調理香が付与されることを所望されるもの、不快臭がマスキングされることを所望されるもの、スパイス感が増強されることを所望されるもの、甘味が増強されることを所望されるものが好ましく、例えば、本発明の組成物を添加し得る食品として例示したものと同様のものが挙げられる。 The food produced by the production method of the present invention is not particularly limited, but those that are desired to be provided with cooked incense, those that are desired to mask unpleasant odor, and that the feeling of spice is enhanced. Are desirable, and those whose sweetness is desired to be enhanced are preferable, and examples thereof include those exemplified as foods to which the composition of the present invention can be added.
 本発明の製造方法において(A)、成分グループB及び(C)の添加は、食品が炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品又はそれらの加工品等である場合、当該食品(炒め物、焼き物、揚げ物、魚介含有食品、野菜含有食品又はそれらの加工品等)における(A)、成分グループB及び(C)の各濃度が、本発明の組成物が当該食品に添加される場合の当該食品における(A)、成分グループB及び(C)の各濃度(上述)と同様となるように行い得る。 In the production method of the present invention, (A), the addition of component groups B and (C) is performed when the food is a fried food, a grilled food, a fried food, a seafood-containing food, a vegetable-containing food, or a processed product thereof. (A), component groups B and (C) in the fried food, grilled food, fried food, seafood-containing food, vegetable-containing food or processed food thereof, etc.) are added to the food of the present invention. In this case, the concentration may be the same as that of each of the food groups (A), component groups B and (C) (described above).
 本発明の製造方法において(A)、成分グループB及び(C)の添加は、食品が調味料等である場合、当該食品(調味料等)における(A)、成分グループB及び(C)の各濃度が、本発明の組成物が当該食品に添加される場合の当該食品における(A)、成分グループB及び(C)の各濃度(上述)と同様となるように行い得る。 In the production method of the present invention, the addition of (A), component groups B and (C) is the same as that of (A), component groups B and (C) in the food (condiment etc.) when the food is a seasoning etc. Each concentration can be performed so as to be the same as the respective concentrations (above) of (A), component groups B and (C) in the food when the composition of the present invention is added to the food.
 本発明の製造方法において(A)の添加量と、成分グループB及び(C)の各成分の添加量の重量比は、本発明の組成物における(A)の含有量と成分グループB及び(C)の各成分の含有量の重量比(上述)と同様に設定し得る。 In the production method of the present invention, the weight ratio of the added amount of (A) and the added amount of each component of component groups B and (C) is the same as the content of (A) and the component groups B and ( It can be set in the same manner as the weight ratio (described above) of the content of each component of C).
 本発明の製造方法は、(A)、成分グループB及び(C)を個別に添加してよいが、(A)、成分グループB及び(C)を添加前に予め混合し、得られた混合物を添加してもよい。(A)、成分グループB及び(C)の添加は、本発明の組成物を使用して行われてもよい。
 (A)、成分グループB及び(C)を個別に添加する場合、添加の順序及び間隔は特に制限されず、例えば(A)、成分グループB及び(C)の順序、あるいはその逆の順序等で添加してよい。また(A)、成分グループB及び(C)を同時に添加してもよい。
In the production method of the present invention, (A), component groups B and (C) may be added individually, but (A), component groups B and (C) are mixed in advance before addition, and the resulting mixture May be added. Addition of (A), component groups B and (C) may be performed using the composition of the present invention.
When (A), component groups B and (C) are added individually, the order and interval of addition are not particularly limited. For example, the order of (A), component groups B and (C), or the reverse order thereof. May be added. In addition, (A), component groups B and (C) may be added simultaneously.
 本発明の製造方法は、上述の(A)、成分グループB及び(C)の添加に加えて、食品の製造において慣用の処理工程、調理工程を、製造する食品の種類等に応じて適宜含んでよい。 The production method of the present invention appropriately includes, in addition to the addition of (A), component groups B and (C) described above, conventional processing steps and cooking steps in the production of food depending on the type of food to be produced. It's okay.
 本発明の製造方法によれば、炭様の刺激的な風味が付与された食品を製造できる。また炭様の刺激的な風味を食品に付与することによって、加熱調理香を付与できるため、本発明の製造方法によれば、加熱調理香が付与された食品(例、焼成感が付与された食品、油調感が付与された食品等)を製造できる。
 本発明の製造方法によれば、スパイス感及び甘味からなる群より選択される少なくとも一つが増強された食品、不快臭がマスキングされた食品を製造できる。
According to the production method of the present invention, a food with a charcoal-like stimulating flavor can be produced. Moreover, since a cooking fragrance can be imparted by imparting a charcoal-like stimulating flavor to food, according to the production method of the present invention, a food with a cooking fragrance (e.g., a feeling of baking is imparted). Food, food with an oily feel, etc.) can be produced.
According to the production method of the present invention, a food product in which at least one selected from the group consisting of a spice feeling and sweetness is enhanced, and a food product in which an unpleasant odor is masked can be produced.
(本発明の付与方法)
 本発明は、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することを含む、炭様の刺激的な風味の付与方法(本明細書中、単に「本発明の付与方法」と称する場合がある)も提供する。
 本発明の付与方法は、特に断りのない限り、本発明の製造方法と同様に実施し得、好ましい態様も同様である。
(Granting method of the present invention)
The present invention provides a method for imparting a charcoal-like stimulating flavor comprising adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). In the specification, it may be simply referred to as “the method of applying the present invention”).
The application method of the present invention can be carried out in the same manner as the production method of the present invention unless otherwise specified, and preferred embodiments are also the same.
 本発明の付与方法において、(A)、成分グループB及び(C)を添加する方法及び条件は特に限定されず、(A)、成分グループB及び(C)を添加する食品の種類等に応じて適宜設定できる。(A)、成分グループB及び(C)を食品に添加する時期は特に限定されず、いかなる時点で添加してもよいが、例えば、食品の製造中及び食品の完成後(例、食品の喫食直前、食品の喫食中等)等が挙げられる。食品を製造する前の食品原料に(A)、成分グループB及び(C)を添加してもよい。 In the imparting method of the present invention, the method and conditions for adding (A), ingredient group B and (C) are not particularly limited, depending on the type of food to which (A), ingredient group B and (C) are added. Can be set as appropriate. The time when (A), ingredient group B and (C) are added to the food is not particularly limited, and may be added at any time. For example, during production of the food and after completion of the food (eg, food consumption) Immediately before, during food consumption, etc.). You may add (A), ingredient group B, and (C) to the foodstuff raw material before manufacturing a foodstuff.
 本発明の付与方法によれば、食品に炭様の刺激的な風味を付与することができる。また炭様の刺激的な風味を食品に付与することによって、加熱調理香を付与できるため、本発明の付与方法によれば、食品に加熱調理香を付与することができる。従って、本発明の付与方法は、加熱調理香の付与方法(例、焼成感の付与方法、油調感の付与方法等)であってよい。 According to the imparting method of the present invention, a charcoal-like stimulating flavor can be imparted to food. Moreover, since a heat cooking incense can be provided by giving a charcoal-like exciting flavor to food, according to the provision method of this invention, heat cooking incense can be provided to food. Therefore, the application method of the present invention may be a method for applying a cooked incense (e.g., a method for giving a burning feeling, a method for giving an oily feeling, etc.).
 本発明の付与方法によって炭様の刺激的な風味が付与され得る食品は特に制限されないが、加熱調理香が付与されることを所望されるものが好ましく、例えば、本発明の組成物を添加し得る食品として例示したものと同様のものが挙げられる。 The food to which a charcoal-like stimulating flavor can be imparted by the imparting method of the present invention is not particularly limited, but those that are desired to be provided with a cooked incense are preferred. For example, the composition of the present invention is added. The thing similar to what was illustrated as a foodstuff to obtain is mentioned.
(本発明の増強方法)
 本発明は、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することを含む、スパイス感及び甘味からなる群より選択される少なくとも一つの増強方法(本明細書中、単に「本発明の増強方法」と称する場合がある)も提供する。
 本発明の増強方法は、特に断りのない限り、本発明の製造方法、本発明の付与方法と同様に実施し得、好ましい態様も同様である。
 本発明の増強方法によってスパイス感及び甘味からなる群より選択される少なくとも一つが増強され得る食品は特に制限されないが、スパイス感が増強されることを所望されるもの、甘味が増強されることを所望されるものが好ましく、例えば、本発明の組成物を添加し得る食品として例示したものと同様のものが挙げられる。
(Enhancement method of the present invention)
The present invention includes (A), at least one selected from the group consisting of (B1) and (B2), and (C), and at least selected from the group consisting of spice feeling and sweetness An enhancement method (sometimes referred to herein simply as “the enhancement method of the present invention”) is also provided.
Unless otherwise specified, the enhancement method of the present invention can be carried out in the same manner as the production method of the present invention and the application method of the present invention, and preferred embodiments are also the same.
The food that can enhance at least one selected from the group consisting of a spice feeling and sweetness by the enhancing method of the present invention is not particularly limited, but it is desired that the spice feeling is enhanced, and that the sweetness is enhanced. What is desired is preferable, and examples thereof include those exemplified as foods to which the composition of the present invention can be added.
(本発明のマスキング方法)
 本発明は、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することを含む、不快臭のマスキング方法(本明細書中、単に「本発明のマスキング方法」と称する場合がある)も提供する。
 本発明のマスキング方法は、特に断りのない限り、本発明の製造方法、本発明の付与方法と同様に実施し得、好ましい態様も同様である。
 本発明のマスキング方法によって不快臭がマスキングされ得る食品は特に制限されないが、不快臭がマスキングされることを所望されるものが好ましく、例えば、本発明の組成物を添加し得る食品として例示したものと同様のものが挙げられる。
(Masking method of the present invention)
The present invention relates to a method for masking unpleasant odors, which comprises adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). Also referred to as “masking method of the present invention”).
The masking method of the present invention can be carried out in the same manner as the production method of the present invention and the application method of the present invention unless otherwise specified, and preferred embodiments are also the same.
The food that can mask the unpleasant odor by the masking method of the present invention is not particularly limited, but it is preferable that the unpleasant odor is desired to be masked. The same thing is mentioned.
 以下の実施例において本発明を更に具体的に説明するが、本発明はこれらの例によってなんら限定されるものではない。尚、本明細書において「%」、「ppm」と記載されている場合は、特に断りのない限り「重量%」、「重量ppm」を意味する。 The present invention will be described more specifically in the following examples, but the present invention is not limited to these examples. In this specification, “%” and “ppm” mean “% by weight” and “ppm by weight” unless otherwise specified.
1.添加溶液の調製
 所定量の2-アセチルフラン、6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン、フルフリルアルコール及びフルフリルメチルジスルフィドをそれぞれエタノール(販売元:日本アルコール産業、商品名:特定アルコール トレーサブル95 1級)に溶解して、当該各成分の0.0001重量%~10重量%溶液(添加溶液)を調製した。使用した各成分の販売元は、表1に示す通りである。
1. Preparation of Additive Solution Predetermined amounts of 2-acetylfuran, 6,7-dihydro-5-methyl-5H-cyclopentapyrazine, furfuryl alcohol and furfuryl methyl disulfide were each ethanol (distributor: Japan Alcohol Industry, trade name: A specific alcohol traceable 95 grade 1) was dissolved to prepare a 0.0001 wt% to 10 wt% solution (addition solution) of each component. The vendors of the components used are as shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
2.炭様の刺激的な風味の付与効果の評価
 市販の回鍋肉の素(製品名:CookDo(登録商標)「回鍋肉」、販売元:味の素株式会社)の調味液を、水で5倍希釈した後、当該希釈液に上記1.において調製した各成分の添加溶液を添加して全量を100gとし、十分に攪拌して混合することにより、評価サンプル(実施例1~30、比較例1~6)を調製した。使用した添加溶液中の各成分の濃度、添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表2~9の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
2. Evaluation of charcoal-like stimulating flavor imparting effect After diluting the seasoning liquid of commercially available nabe-no-meme (product name: CookDo (registered trademark) “Kainnabe”, distributor: Ajinomoto Co., Inc.) 5 times with water, In the diluted solution, the above 1. Evaluation samples (Examples 1 to 30 and Comparative Examples 1 to 6) were prepared by adding the addition solutions of the respective components prepared in Step 1 to a total amount of 100 g, and sufficiently stirring and mixing. The concentration of each component in the used addition solution, the addition amount of the addition solution, and the concentration of each component in the evaluation sample are “addition solution concentration (%)”, “addition amount (mg)” in Tables 2 to 9 below, And “Concentration in sample (ppm)”.
 炭様の刺激的な風味の付与効果の評価は、3名の専門パネルにより、各評価サンプルを無添加品(添加溶液を添加していない上記希釈液そのもの)と比較して、炭様の刺激的な風味を付与する効果の有無や程度を確認し、下記の評価基準で行った。
[評価基準]
 ±:炭様の刺激的な風味を付与する効果がない
 +:炭様の刺激的な風味を付与する効果がわずかにある
 ++:炭様の刺激的な風味を付与する効果がややある
 +++:炭様の刺激的な風味を付与する効果が適度にある
 ++++:炭様の刺激的な風味を付与する効果がかなりある
 +++++:炭様の刺激的な風味を付与する効果が非常にある
The evaluation of the charcoal-like stimulating flavor was evaluated by a panel of three people, comparing each evaluation sample with the additive-free product (the diluted solution without any added solution). The presence / absence and extent of the effect of imparting a typical flavor were confirmed, and the following evaluation criteria were used.
[Evaluation criteria]
±: There is no effect of imparting a charcoal-like stimulating flavor +: There is a slight effect of imparting a charcoal-like stimulating flavor ++: There is a slight effect of imparting a charcoal-like stimulating flavor ++++: The effect of imparting a charcoal-like stimulating flavor is moderate. +++++: The effect of imparting a charcoal-like stimulating flavor is considerable. +++++: The effect of imparting a charcoal-like stimulating flavor is very high.
 結果を下記表2~9に示す。 The results are shown in Tables 2 to 9 below.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
 表2及び表4~9に示される結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、炭様の刺激的な風味を付与し得ることが確認された。
 一方、表3に示される結果から明らかなように、(A)、成分グループB及び(C)のいずれかを単独で添加した場合(比較例1~3)には、炭様の刺激的な風味を付与できなかった。また、(A)及び成分グループBのみ添加し、(C)は添加しなかった場合(比較例4)、(A)及び(C)のみ添加し、成分グループBは添加しなかった場合(比較例5)、成分グループB及び(C)のみ添加し、(A)は添加しなかった場合(比較例6)にも、炭様の刺激的な風味を付与できなかった。
From the results shown in Table 2 and Tables 4 to 9, by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C), charcoal-like irritation It was confirmed that a typical flavor could be imparted.
On the other hand, as is clear from the results shown in Table 3, when any one of (A), component groups B and (C) was added alone (Comparative Examples 1 to 3), the charcoal-like stimulant The flavor could not be imparted. Moreover, only (A) and component group B are added, (C) is not added (Comparative Example 4), only (A) and (C) are added, and component group B is not added (Comparison) Even when only Example Group 5), component groups B and (C) were added, and (A) was not added (Comparative Example 6), a charcoal-like stimulating flavor could not be imparted.
3.香料組成物の調製
 2-アセチルフラン、6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン、フルフリルアルコール及びフルフリルメチルジスルフィドを、表10に示す割合で混合し、香料組成物を調製した。
3. Preparation of perfume composition 2-acetylfuran, 6,7-dihydro-5-methyl-5H-cyclopentapyrazine, furfuryl alcohol and furfurylmethyl disulfide were mixed in the proportions shown in Table 10 to prepare a perfume composition. did.
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
4.加熱調理香の付与効果の評価
(1)炊飯米(350g)、チャーシュー(70g)、長ねぎ(40g)及び卵(2個)を用いて常法により作製した炒飯に、上記3.において調製した香料組成物を、当該炒飯における香料組成物の喫食時濃度が21.89重量ppmとなるように添加した後、3名の専門パネルにより、加熱調理香の有無や程度を確認した。その結果、当該炒飯に加熱調理香(詳細には、高温で加熱した様な風味)が付与されたことが確認された。
(2)市販の中華丼の具(冷凍食品、販売元:味の素冷凍食品株式会社)に、上記3.において調製した香料組成物を、当該中華丼の具における香料組成物の喫食時濃度が21.89重量ppmとなるように添加した後、3名の専門パネルにより、加熱調理香の有無や程度を確認した。その結果、当該中華丼の具に加熱調理香(詳細には、高温で加熱した様な風味)が付与されたことが確認された。
(3)市販の焼き鳥丼の具(冷凍食品、販売元:味の素冷凍食品株式会社)に、上記3.において調製した香料組成物を、当該中華丼の具における香料組成物の喫食時濃度が41.04重量ppmとなるように添加した後、3名の専門パネルにより、加熱調理香の有無や程度を確認した。その結果、当該焼き鳥丼の具に加熱調理香(詳細には、炭火で焼いた様な風味)が付与されたことが確認された。
 上記(1)~(3)の結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、食品に加熱調理香を付与できることが確認された。
4). Evaluation of heating cooking incense imparting effect (1) Fried rice prepared by a conventional method using cooked rice (350 g), char siu (70 g), long onion (40 g), and eggs (2 pieces). After adding the fragrance composition prepared in step 1 so that the concentration of the fragrance composition in the fried rice at the time of eating was 21.89 ppm by weight, the presence or absence and degree of cooked incense were confirmed by three specialized panels. As a result, it was confirmed that cooked incense (specifically, a flavor as if heated at high temperature) was imparted to the fried rice.
(2) In the above-mentioned 3. After adding the fragrance composition prepared in step 2 so that the concentration of the fragrance composition at the time of eating in the Chinese rice bowl is 21.89 ppm by weight, the presence and degree of cooked incense is determined by three specialized panels. confirmed. As a result, it was confirmed that the cooked incense (specifically, a flavor as if heated at a high temperature) was imparted to the Chinese rice bowl.
(3) The above-mentioned 3. is added to a commercially available yakitori bowl ingredient (frozen food, distributor: Ajinomoto Frozen Food Co., Ltd.). After adding the fragrance composition prepared in step 1 so that the concentration of the fragrance composition in the Chinese rice bowl at the time of eating was 41.04 ppm by weight, the presence or absence and degree of cooked incense were determined by three specialized panels. confirmed. As a result, it was confirmed that heat-cooked incense (specifically, a flavor baked over charcoal) was added to the yakitori bowl.
From the results of the above (1) to (3), by adding at least one selected from the group consisting of (A), (B1) and (B2), and (C), the cooked incense is added to the food. It was confirmed that can be imparted.
5.焼成感の付与効果の評価
 評価サンプルとして、下記1)~6)の手順でクッキーを作製した(実施例31)。使用した添加溶液中の各成分の濃度、添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表11の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
[クッキーの作製方法]
1)フードプロセッサーに、薄力粉25g、強力粉25g、砂糖15g及び食塩0.26gを入れて混合した(2000rpm、10秒間×2回)。
2)上記1)で得られた混合物に、発酵バター3.1g及びショートニング22.5gを加えて混合した(2000rpm、10秒間×4回)。
3)上記2)で得られた混合物に、卵8g及び上記1.において調製した各成分の添加溶液を添加し、更に水を加えて全量を100gとした後、均一になるまで混合した(2000rpm、10秒間×2回)。
4)上記3)で得られた混合物をチャック付ポリ袋に入れ、麺棒で平ら(厚さ5mm程度)に伸ばした。
5)上記4)で得られたクッキー生地を-20℃で30分間、冷凍保存した。
6)冷凍保存後のクッキー生地を所定の形状に型ぬきした後、オーブンにて180℃で12分間焼成した。
5). As a sample for evaluation and evaluation of the effect of imparting a burning sensation , a cookie was prepared according to the following procedures 1) to 6) (Example 31). The concentration of each component in the used addition solution, the addition amount of the addition solution, and the concentration of each component in the evaluation sample are “addition solution concentration (%)”, “addition amount (mg)”, and “ As shown in “Concentration in sample (ppm)”.
[Cookie making method]
1) In a food processor, 25 g of weak flour, 25 g of strong flour, 15 g of sugar and 0.26 g of salt were mixed and mixed (2000 rpm, 10 seconds × twice).
2) To the mixture obtained in 1) above, 3.1 g of fermentation butter and 22.5 g of shortening were added and mixed (2000 rpm, 10 seconds × 4 times).
3) Into the mixture obtained in the above 2), 8 g of the egg and 1. The addition solution of each component prepared in (1) was added, water was further added to make the total amount 100 g, and then mixed until uniform (2000 rpm, 10 seconds × 2 times).
4) The mixture obtained in 3) above was put in a plastic bag with a chuck and stretched flat (about 5 mm thick) with a rolling pin.
5) The cookie dough obtained in 4) above was stored frozen at −20 ° C. for 30 minutes.
6) The frozen cookie dough was cut into a predetermined shape and then baked in an oven at 180 ° C. for 12 minutes.
 焼成感の付与効果の評価は、3名の専門パネルにより、評価サンプルを無添加品(添加溶液に代えて同量の水を使用したこと以外は実施例31と同様に作製したクッキー)と比較して、焼成感の有無や程度を確認し、下記の評価基準で行った。
[評価基準]
 -:無添加品よりも焼成感が弱い
 ±:無添加品と焼成感に差がない
 +:無添加品よりもわずかに焼成感が上昇している
 ++:無添加品よりもやや焼成感が上昇している
 +++:無添加品よりも適度に焼成感が上昇している
 ++++:無添加品よりもかなり焼成感が上昇している
 +++++:無添加品よりも非常に焼成感が上昇している
The evaluation of the effect of imparting a burning feeling was compared with an additive-free product (cookie prepared in the same manner as in Example 31 except that the same amount of water was used instead of the additive solution) by a panel of three experts. Then, the presence or absence and degree of firing feeling were confirmed, and the following evaluation criteria were used.
[Evaluation criteria]
-: Baking feeling is weaker than additive-free products ±: There is no difference in baking feeling from additive-free products +: Slightly higher burning feeling than additive-free products ++: Slightly burning feeling than additive-free products +++: The firing feeling is moderately higher than the additive-free product. +++++: The firing feeling is considerably higher than the additive-free product. +++++: The firing feeling is much higher than the additive-free product. Have
 結果を下記表11に示す。 The results are shown in Table 11 below.
Figure JPOXMLDOC01-appb-T000011
Figure JPOXMLDOC01-appb-T000011
 表11に示される結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、焼成感を付与し得ることが確認された。また実施例31の評価サンプルは、高温で焦がした風味、コーヒー様の香ばしい風味が付与されていた。 From the results shown in Table 11, it was confirmed that a feeling of firing can be imparted by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It was done. In addition, the evaluation sample of Example 31 was given a flavor burnt at high temperature and a coffee-like fragrant flavor.
6.油調感の付与効果の評価
 一口大にカットした鶏もも肉90gに、市販のから揚げ粉(製品名:から揚げ粉 揚げない調理タイプ、販売元:日清製粉株式会社)10gをまぶした後、電子レンジにて加熱(600W、2分50秒間)し、から揚げを作製した。当該から揚げ(100g)に、上記1.において調製した各成分の添加溶液を添加して、評価サンプル(実施例32)を調製した。使用した添加溶液中の各成分の濃度、添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表12の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
6). Evaluation of the effect of imparting oil feel After 90 g of chicken thigh cut into a bite size was sprinkled with 10 g of commercially available fried flour (product name: non-fried cooking type, distributor: Nisshin Flour Milling Co., Ltd.) It was heated in a microwave oven (600 W, 2 minutes and 50 seconds) to prepare fried chicken. To the fried chicken (100 g), the above 1. An addition sample of each component prepared in step 1 was added to prepare an evaluation sample (Example 32). The concentration of each component in the used addition solution, the addition amount of the addition solution, and the concentration of each component in the evaluation sample are “addition solution concentration (%)”, “addition amount (mg)”, and “ As shown in “Concentration in sample (ppm)”.
 油調感の付与効果の評価は、3名の専門パネルにより、評価サンプルを無添加品(添加溶液を添加していないから揚げ)と比較して、油調感の有無や程度を確認し、下記の評価基準で行った。
[評価基準]
 -:無添加品よりも油調感が弱い
 ±:無添加品と油調感に差がない
 +:無添加品よりもわずかに油調感が上昇している
 ++:無添加品よりもやや油調感が上昇している
 +++:無添加品よりも適度に油調感が上昇している
 ++++:無添加品よりもかなり油調感が上昇している
 +++++:無添加品よりも非常に油調感が上昇している
The evaluation of the effect of imparting oil feel was confirmed by comparing the evaluation sample with the additive-free product (fried because no additive solution was added), and the presence and extent of oil feel, The following evaluation criteria were used.
[Evaluation criteria]
-: Oil feel is weaker than additive-free products ±: No difference between oil feel and additive-free products +: Oil feel slightly higher than additive-free products ++: Slightly higher than additive-free products Oil tone is rising +++: Oil tone feels moderately higher than additive-free products +++++: Oil tone feels considerably higher than additive-free products +++++: Much higher than additive-free products Oil tone is rising
 結果を下記表12に示す。 The results are shown in Table 12 below.
Figure JPOXMLDOC01-appb-T000012
Figure JPOXMLDOC01-appb-T000012
 表12に示される結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、油調感を付与し得ることが確認された。また実施例32の評価サンプルは、香ばしい風味が付与されていた。 From the results shown in Table 12, by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C), it is possible to impart an oily feel. confirmed. In addition, the evaluation sample of Example 32 was given a fragrant flavor.
7.不快臭のマスキング効果の評価
 一口大に切った小松菜120g及び市販の調味料(製品名:CookDo(登録商標)鶏ガラ、ネギ油、こがしにんにくの油香味ペースト、販売元:味の素株式会社)3gに、水10gを加え、よく混合した後、電子レンジにて加熱(600W、2分間)し、野菜炒めを作製した。当該野菜炒め100gに対し、上記1.において調製した各成分の添加溶液を添加して、評価サンプル(実施例33~35)を調製した。使用した添加溶液中の各成分の濃度、添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表13の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
7). Evaluation of masking effect of unpleasant odor To 120 g of Komatsuna cut into bite size and commercially available seasoning (Product name: CookDo (registered trademark) chicken garage, leek oil, oil garlic flavor paste, distributor: Ajinomoto Co., Inc.) After adding 10 g of water and mixing well, it was heated in a microwave (600 W, 2 minutes) to prepare a stir-fried vegetable. For 100 g of the stir-fried vegetables, the above 1. Samples for evaluation (Examples 33 to 35) were prepared by adding the additive solution of each component prepared in (1). The concentration of each component in the used additive solution, the added amount of the added solution, and the concentration of each component in the evaluation sample are “added solution concentration (%)”, “added amount (mg)”, and “ As shown in “Concentration in sample (ppm)”.
 不快臭のマスキング効果の評価は、3名の専門パネルにより、評価サンプルを無添加品(添加溶液を添加していない野菜炒め)と比較して、不快臭(具体的には、小松菜に起因する青臭さ)のマスキング強度の有無や程度を確認し、下記の評価基準で行った。
[評価基準]
 -:無添加品よりもマスキング強度が弱い
 ±:無添加品とマスキング強度に差がない
 +:無添加品よりもわずかにマスキング強度が上昇している
 ++:無添加品よりもやや塩味強度が上昇している
 +++:無添加品よりも適度にマスキング強度が上昇している
 ++++:無添加品よりもかなりマスキング強度が上昇している
 +++++:無添加品よりも非常にマスキング強度が上昇している
The evaluation of the masking effect of unpleasant odor is caused by three specialized panels, comparing the evaluation sample with an additive-free product (fried vegetables without added solution), and unpleasant odor (specifically, due to Komatsuna) The presence / absence and degree of masking strength of (blue odor) were confirmed, and the following evaluation criteria were used.
[Evaluation criteria]
-: Masking strength is weaker than additive-free products ±: No difference in masking strength from additive-free products +: Masking strength is slightly higher than additive-free products ++: Slightly salty strength than additive-free products ++++: Masking strength is moderately higher than additive-free products. +++: Masking strength is considerably higher than additive-free products. +++++: Masking strength is much higher than additive-free products. Have
 結果を下記表13に示す。 The results are shown in Table 13 below.
Figure JPOXMLDOC01-appb-T000013
Figure JPOXMLDOC01-appb-T000013
 表13に示される結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、不快臭をマスキングし得ることが確認された。 From the results shown in Table 13, it was confirmed that an unpleasant odor can be masked by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It was done.
8.甘味増強効果の評価
 市販のみたらしだんご(製品名:焦がし醤油風味の串団子、販売元:山崎製パン株式会社)に、上記1.において調製した各成分の添加溶液を添加して、評価サンプル(実施例36~39)を調製した。使用した添加溶液中の各成分の濃度、みたらしだんご100g当たりの添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表14の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
8). Evaluation of sweetness-enhancing effect Commercially available Mitarashi Dango (product name: burnt soy sauce-flavored skewers, distributor: Yamazaki Baking Co., Ltd.) The evaluation samples (Examples 36 to 39) were prepared by adding the additive solution of each component prepared in (1). The concentration of each component in the used addition solution, the addition amount of the addition solution per 100 g of Mitarashi dango, and the concentration of each component in the evaluation sample are “addition solution concentration (%)” and “addition amount (mg) in Table 14 below. ) ”And“ Concentration in sample (ppm) ”.
 甘味増強効果の評価は、3名の専門パネルにより、評価サンプルを無添加品(添加溶液を添加していないみたらしだんご)と比較して、甘味の強度を確認し、下記の評価基準で行った。
[評価基準]
 -:無添加品よりも甘味強度が弱い
 ±:無添加品と甘味強度に差がない
 +:無添加品よりもわずかに甘味強度が上昇している
 ++:無添加品よりもやや甘味強度が上昇している
 +++:無添加品よりも適度に甘味強度が上昇している
 ++++:無添加品よりもかなり甘味強度が上昇している
 +++++:無添加品よりも非常に甘味強度が上昇している
The evaluation of the sweetness enhancement effect was carried out by three specialist panels, comparing the evaluation sample with the additive-free product (Mitarashi dango without added solution), confirming the intensity of sweetness, and performing the following evaluation criteria. .
[Evaluation criteria]
-: The sweetness intensity is weaker than the additive-free product ±: There is no difference in sweetness intensity from the additive-free product +: The sweetness intensity is slightly higher than the additive-free product ++: The sweetness intensity is slightly higher than the additive-free product +++: Sweetness intensity is moderately higher than additive-free products +++: Sweetness intensity is considerably higher than additive-free products +++++: Sweetness intensity is much higher than additive-free products Have
 結果を下記表14に示す。 The results are shown in Table 14 below.
Figure JPOXMLDOC01-appb-T000014
Figure JPOXMLDOC01-appb-T000014
 表14に示される結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、甘味を増強し得ることが確認された。 From the results shown in Table 14, it was confirmed that sweetness could be enhanced by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It was.
9.スパイス感増強効果の評価
 市販のコショー(製品名:GABAN(登録商標)「コショー」、販売元:ハウス食品株式会社)0.1gを水100gに加え、コショー水溶液を調製した。当該コショー水溶液(100g)に、上記1.において調製した各成分の添加溶液を添加して、評価サンプル(実施例40~44)を調製した。使用した添加溶液中の各成分の濃度、添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表15の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
9. Evaluation of Spice Sense Enhancement Effect 0.1 g of commercially available cosho (product name: GABAN (registered trademark) “Cosho”, distributor: House Foods Co., Ltd.) was added to 100 g of water to prepare an aqueous solution of cosho. To the aqueous solution (100 g), the above 1. The evaluation samples (Examples 40 to 44) were prepared by adding the additive solution of each component prepared in (1). The concentration of each component in the used addition solution, the addition amount of the addition solution, and the concentration of each component in the evaluation sample are “addition solution concentration (%)”, “addition amount (mg)”, and “ As shown in “Concentration in sample (ppm)”.
 スパイス感増強効果の評価は、3名の専門パネルにより、評価サンプルを無添加品(添加溶液に代えて同量の水のみを添加したコショー水溶液)と比較して、スパイス強度を確認し、下記の評価基準で行った。
[評価基準]
 -:無添加品よりもスパイス強度が弱い
 ±:無添加品とスパイス強度に差がない
 +:無添加品よりもわずかにスパイス強度が上昇している
 ++:無添加品よりもややスパイス強度が上昇している
 +++:無添加品よりも適度にスパイス強度が上昇している
 ++++:無添加品よりもかなりスパイス強度が上昇している
 +++++:無添加品よりも非常にスパイス強度が上昇している
Evaluation of the effect of enhancing the spice feeling was confirmed by comparing the evaluation sample with an additive-free product (an aqueous solution of Kosho with the same amount of water added instead of the added solution), and the spice strength was confirmed. The evaluation criteria were used.
[Evaluation criteria]
-: Spice strength is weaker than additive-free products ±: No difference in spice strength from additive-free products +: Spice strength is slightly higher than additive-free products ++: Spice strength is slightly higher than additive-free products ++++: Spice strength is moderately higher than additive-free products +++: Spice strength is significantly higher than additive-free products +++++: Spice strength is much higher than additive-free products Have
 結果を下記表15に示す。 The results are shown in Table 15 below.
Figure JPOXMLDOC01-appb-T000015
Figure JPOXMLDOC01-appb-T000015
 表15に示される結果から、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、スパイス感を増強し得ることが確認された。 From the results shown in Table 15, it was confirmed that the feeling of spice can be enhanced by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C). It was done.
10.各種食品における効果の評価
 各種食品に、(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加し、スパイス感増強効果、不快臭のマスキング効果、甘味増強効果の評価を行った。
 下記表18に示す各種食品に、上記1.において調製した各成分の添加溶液を添加して、評価サンプル(実施例45~48)を調製した。使用した添加溶液中の各成分の濃度、食品100g当たりの添加溶液の添加量、各成分の評価サンプル中の濃度は、下記表18の「添加溶液濃度(%)」、「添加量(mg)」、及び「サンプル中濃度(ppm)」に示す通りである。
 評価サンプルの調製に使用した各種食品は、それぞれ下記の手順で作製、準備した。
(から揚げ)
 一口大にカットした鶏もも肉に、市販のから揚げ粉(製品名:Sajiku(登録商標)、販売元:インドネシア味の素社)をまぶし、常法によりから揚げを作製した。
(大豆ハンバーグ)
 下記表16に示す材料を用い、特許第6160131号公報に記載の方法に従って、大豆ハンバーグを作製した。
(ぶり大根)
 下記表17に示す材料を用い、特許第6160131号公報に記載の方法に従って、ぶり大根を作製した。ぶり大根の作製は、具体的には下記1)~4)の手順で行った。
[ぶり大根の作製方法]
1)ぶりを一口大に切り、酒及び生姜に1分間漬けた。
2)大根を1cm幅に輪切りした後、4等分にいちょう切りしたものを容器に入れ、市販の風味調味料(製品名:ほんだし(登録商標)煮物上手(登録商標)、販売元:味の素株式会社)及び水を加え、電子レンジで加熱した(600W、3分間)。
3)上記2)の加熱後の大根に、上記1)のぶり切り身を加え、電子レンジで加熱した(600W、3分30秒間)。
4)加熱したぶり大根を、電子レンジから出し、5分間以上蒸らした。
(プリン)
 市販のプリン(製品名:プッチンプリン、販売元:グリコ乳業株式会社)をそのまま使用した。
10. Evaluation of effects in various foods To each food, (A), at least one selected from the group consisting of (B1) and (B2), and (C) are added to enhance the spice feeling and mask unpleasant odor. The effect and sweetness enhancing effect were evaluated.
In the various foods shown in Table 18 below, Evaluation samples (Examples 45 to 48) were prepared by adding the additive solution of each component prepared in (1). The concentration of each component in the added solution used, the added amount of the added solution per 100 g of food, and the concentration of each component in the evaluation sample are shown in Table 18 below as “added solution concentration (%)” and “added amount (mg)”. And “concentration in sample (ppm)”.
Various foods used for preparing the evaluation samples were prepared and prepared by the following procedures.
(fried)
Chicken thighs cut into bite-sized pieces were sprinkled with commercially available fried flour (product name: Sajiku (registered trademark), distributor: Indonesian Ajinomoto Co., Inc.), and then fried in a conventional manner.
(Soy hamburger)
Using the materials shown in Table 16 below, soybean hamburgers were produced according to the method described in Japanese Patent No. 6160131.
(Buri Daikon)
According to the method described in Japanese Patent No. 6160131, a radish was produced using the materials shown in Table 17 below. Specifically, the radish was produced by the following procedures 1) to 4).
[How to make radish]
1) Cut the bite into bite-sized pieces and immerse in sake and ginger for 1 minute.
2) After cutting the radish into 1cm width, put it into four equal portions, put it in a container, and put a commercially available flavor seasoning (product name: Hondashi (registered trademark) boiled well (registered trademark), distributor: Ajinomoto Co., Inc. Company) and water were added and heated in a microwave (600 W, 3 minutes).
3) To the radish heated in 2) above, the sliced fillet of 1) above was added and heated in a microwave oven (600 W, 3 minutes 30 seconds).
4) The heated radish was taken out of the microwave and steamed for 5 minutes or more.
(Pudding)
A commercially available pudding (product name: Putin pudding, distributor: Glico Dairy Co., Ltd.) was used as it was.
Figure JPOXMLDOC01-appb-T000016
Figure JPOXMLDOC01-appb-T000016
Figure JPOXMLDOC01-appb-T000017
Figure JPOXMLDOC01-appb-T000017
 スパイス感増強効果、不快臭のマスキング効果、甘味増強効果の評価は、3名の専門パネルにより、評価サンプルを無添加品(添加溶液を添加していない食品)と比較して、上記7.~9.と同様の評価基準で行った。
 実施例45(から揚げ)の評価サンプルは、スパイス感増強効果の評価を、実施例46(大豆ハンバーグ)及び実施例47(ぶり大根)の各評価サンプルは、不快臭(具体的には、大豆に起因する青臭さ、ぶりに起因する生臭さ)のマスキング効果の評価を、実施例48(プリン)の評価サンプルは、甘味増強効果の評価を、それぞれ行った。
 結果を下記表18に示す。
The evaluation of spice sensation enhancing effect, unpleasant odor masking effect, and sweet taste enhancing effect was performed by comparing the evaluation sample with the additive-free product (food without added solution) by the above three specialist panels. ~ 9. The same evaluation criteria were used.
The evaluation sample of Example 45 (fried fried) evaluated the effect of enhancing the spice feeling, and each evaluation sample of Example 46 (soybean hamburger) and Example 47 (buri radish) was an unpleasant odor (specifically, soybean The evaluation of the masking effect of the blue odor caused by the odor and the raw odor caused by the taste was performed, and the evaluation sample of Example 48 (purine) was evaluated for the sweetness enhancing effect.
The results are shown in Table 18 below.
Figure JPOXMLDOC01-appb-T000018
Figure JPOXMLDOC01-appb-T000018
 表18に示される結果から、各種食品に(A)と、(B1)及び(B2)からなる群より選択される少なくとも一つと、(C)とを添加することによって、スパイス感増強効果、不快臭のマスキング効果、甘味増強効果を奏し得ることが確認された。 From the results shown in Table 18, by adding (A), at least one selected from the group consisting of (B1) and (B2), and (C) to various foods, the spice feeling enhancement effect, unpleasantness It was confirmed that odor masking effect and sweetness enhancing effect can be achieved.
 本発明によれば、炭様の刺激的な風味を付与できる組成物を提供できる。
 本発明によれば、炭様の刺激的な風味が付与された食品の製造方法、並びに炭様の刺激的な風味の付与方法を提供できる。
 また本発明によれば、炭様の刺激的な風味を食品に付与できるため、加熱調理により発現する風味(加熱調理香)を効果的に付与された食品を提供できる。
 本発明によれば、焼成感及び油調感からなる群より選択される少なくとも一つが付与された食品を提供できる。
 本発明によれば、スパイス感及び甘味からなる群より選択される少なくとも一つが増強された食品、不快臭がマスキングされた食品を提供できる。
 本発明の組成物は、特定の化合物を混合することにより得られるため、当業者において一般に利用されている装置で製造でき、その製造条件も容易に制御できる。
 さらに、本発明の組成物は特定の化合物を含有するものであり、食品の種類に応じて組成を調整する必要はないため、様々な食品に広く利用できる。 
ADVANTAGE OF THE INVENTION According to this invention, the composition which can provide a charcoal-like exciting flavor can be provided.
ADVANTAGE OF THE INVENTION According to this invention, the manufacturing method of the foodstuff provided with the charcoal-like stimulating flavor and the imparting method of charcoal-like stimulating flavor can be provided.
Moreover, according to this invention, since the charcoal-like exciting flavor can be provided to food, the food which was effectively provided with the flavor (cooking incense) expressed by heat cooking can be provided.
According to the present invention, a food provided with at least one selected from the group consisting of a burning feeling and an oily feeling can be provided.
ADVANTAGE OF THE INVENTION According to this invention, the foodstuff in which at least one selected from the group which consists of a spice feeling and sweet taste was strengthened, and the foodstuff by which the unpleasant odor was masked can be provided.
Since the composition of the present invention is obtained by mixing a specific compound, it can be produced by an apparatus generally used by those skilled in the art, and the production conditions can be easily controlled.
Furthermore, since the composition of the present invention contains a specific compound and it is not necessary to adjust the composition according to the type of food, it can be widely used for various foods.
 本出願は、日本で出願された特願2017-066150(出願日:2017年3月29日)を基礎としており、その内容は本明細書に包含されるものである。 This application is based on Japanese Patent Application No. 2017-066150 filed in Japan (filing date: March 29, 2017), the contents of which are included in this specification.

Claims (27)

  1.  (A)2-アセチルフランと、
     (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
     (C)フルフリルメチルジスルフィドと
    を含有する組成物。
    (A) 2-acetylfuran;
    (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
    (C) A composition containing furfurylmethyl disulfide.
  2.  食品における(A)の濃度が0.0002~500重量ppmとなるように食品に添加される、請求項1記載の組成物。 The composition according to claim 1, which is added to the food so that the concentration of (A) in the food is 0.0002 to 500 ppm by weight.
  3.  食品における(C)の濃度が0.00001~300重量ppmとなるように食品に添加される、請求項1又は2記載の組成物。 The composition according to claim 1 or 2, which is added to the food so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
  4.  (A)の含有量と(C)の含有量の重量比(A:C)が、1:0.000005~1000である、請求項1~3のいずれか一項に記載の組成物。 The composition according to any one of claims 1 to 3, wherein a weight ratio (A: C) of the content of (A) to the content of (C) is 1: 0.000005 to 1000.
  5.  炭様の刺激的な風味付与用である、請求項1~4のいずれか一項に記載の組成物。 The composition according to any one of claims 1 to 4, which is for imparting a charcoal-like stimulating flavor.
  6.  加熱調理香付与用である、請求項1~4のいずれか一項に記載の組成物。 The composition according to any one of claims 1 to 4, which is used for imparting a cooking incense.
  7.  加熱調理香付与が、焼成感及び油調感からなる群より選択される少なくとも一つの付与である、請求項6記載の組成物。 The composition according to claim 6, wherein the heat cooking incense application is at least one application selected from the group consisting of a burning feeling and an oily feeling.
  8.  スパイス感及び甘味からなる群より選択される少なくとも一つの増強用である、請求項1~4のいずれか一項に記載の組成物。 The composition according to any one of claims 1 to 4, which is used for at least one enhancement selected from the group consisting of a spice feeling and sweetness.
  9.  不快臭のマスキング用である、請求項1~4のいずれか一項に記載の組成物。 The composition according to any one of claims 1 to 4, which is used for masking unpleasant odors.
  10.  請求項1~9のいずれか一項に記載の組成物を含有する食品。 A food containing the composition according to any one of claims 1 to 9.
  11.  (A)2-アセチルフランと、
     (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
     (C)フルフリルメチルジスルフィドと
    を添加することを含む、食品の製造方法。
    (A) 2-acetylfuran;
    (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
    (C) A method for producing a food, comprising adding furfurylmethyl disulfide.
  12.  食品における(A)の濃度が0.0002~500重量ppmとなるように(A)を添加する、請求項11記載の方法。 The method according to claim 11, wherein (A) is added so that the concentration of (A) in the food is 0.0002 to 500 ppm by weight.
  13.  食品における(C)の濃度が0.00001~300重量ppmとなるように(C)を添加する、請求項11又は12記載の方法。 The method according to claim 11 or 12, wherein (C) is added so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
  14.  (A)の添加量と(C)の添加量の重量比(A:C)が、1:0.000005~1000である、請求項11~13のいずれか一項に記載の方法。 The method according to any one of claims 11 to 13, wherein a weight ratio (A: C) of the addition amount of (A) and the addition amount of (C) is 1: 0.000005 to 1000.
  15.  食品が、炭様の刺激的な風味が付与された食品である、請求項11~14のいずれか一項に記載の方法。 The method according to any one of claims 11 to 14, wherein the food is a food provided with a charcoal-like stimulating flavor.
  16.  食品が、加熱調理香が付与された食品である、請求項11~14のいずれか一項に記載の方法。 The method according to any one of claims 11 to 14, wherein the food is a food to which a cooked incense is added.
  17.  加熱調理香が付与された食品が、焼成感及び油調感からなる群より選択される少なくとも一つが付与された食品である、請求項16記載の方法。 The method according to claim 16, wherein the food provided with the cooked incense is a food provided with at least one selected from the group consisting of a burning feeling and an oily feeling.
  18.  食品が、スパイス感及び甘味からなる群より選択される少なくとも一つが増強された食品である、請求項11~14のいずれか一項に記載の方法。 The method according to any one of claims 11 to 14, wherein the food is a food in which at least one selected from the group consisting of a spice feeling and sweetness is enhanced.
  19.  食品が、不快臭がマスキングされた食品である、請求項11~14のいずれか一項に記載の方法。 The method according to any one of claims 11 to 14, wherein the food is a food with an unpleasant odor masked.
  20.  (A)2-アセチルフランと、
     (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
     (C)フルフリルメチルジスルフィドと
    を添加することを含む、炭様の刺激的な風味の付与方法。
    (A) 2-acetylfuran;
    (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
    (C) A method for imparting a charcoal-like stimulating flavor comprising adding furfurylmethyl disulfide.
  21.  (A)2-アセチルフランと、
     (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
     (C)フルフリルメチルジスルフィドと
    を添加することを含む、加熱調理香の付与方法。
    (A) 2-acetylfuran;
    (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
    (C) A method for applying a cooked incense including adding furfurylmethyl disulfide.
  22.  加熱調理香の付与が、焼成感及び油調感からなる群より選択される少なくとも一つの付与である、請求項21記載の方法。 The method according to claim 21, wherein the application of the cooked incense is at least one application selected from the group consisting of a burning feeling and an oily feeling.
  23.  (A)2-アセチルフランと、
     (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
     (C)フルフリルメチルジスルフィドと
    を添加することを含む、スパイス感及び甘味からなる群より選択される少なくとも一つの増強方法。
    (A) 2-acetylfuran;
    (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
    (C) At least one enhancement method selected from the group consisting of spice feeling and sweetness, which comprises adding furfurylmethyl disulfide.
  24.  (A)2-アセチルフランと、
     (B1)6,7-ジヒドロ-5-メチル-5H-シクロペンタピラジン及び(B2)フルフリルアルコールからなる群より選択される少なくとも一つと、
     (C)フルフリルメチルジスルフィドと
    を添加することを含む、不快臭のマスキング方法。
    (A) 2-acetylfuran;
    (B1) at least one selected from the group consisting of 6,7-dihydro-5-methyl-5H-cyclopentapyrazine and (B2) furfuryl alcohol;
    (C) An unpleasant odor masking method comprising adding furfurylmethyl disulfide.
  25.  食品における(A)の濃度が0.0002~500重量ppmとなるように(A)を食品に添加する、請求項20~24のいずれか一項に記載の方法。 The method according to any one of claims 20 to 24, wherein (A) is added to the food so that the concentration of (A) in the food is 0.0002 to 500 ppm by weight.
  26.  食品における(C)の濃度が0.00001~300重量ppmとなるように(C)を食品に添加する、請求項20~25のいずれか一項に記載の方法。 The method according to any one of claims 20 to 25, wherein (C) is added to the food so that the concentration of (C) in the food is 0.00001 to 300 ppm by weight.
  27.  (A)の添加量と(C)の添加量の重量比(A:C)が、1:0.000005~1000である、請求項20~26のいずれか一項に記載の方法。 The method according to any one of claims 20 to 26, wherein the weight ratio (A: C) of the addition amount of (A) and the addition amount of (C) is 1: 0.000005 to 1000.
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WO2022209861A1 (en) * 2021-03-29 2022-10-06 味の素株式会社 Unpleasant odor masking agent

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JP2006020526A (en) * 2004-07-06 2006-01-26 Kiyomitsu Kawasaki Coffee flavor composition, and food and drink containing the same
JP2008259472A (en) * 2007-04-13 2008-10-30 T Hasegawa Co Ltd Just-made coffee feeling imparting agent
JP2010142147A (en) * 2008-12-17 2010-07-01 Kaneka Corp Onion extract, method for producing the same, and food product using the onion extract
JP2010142148A (en) * 2008-12-17 2010-07-01 Kaneka Corp Onion extract, method for producing the same, and food product using the onion extract
JP2015053886A (en) * 2013-09-11 2015-03-23 株式会社カネカ Food flavor modifier

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Publication number Priority date Publication date Assignee Title
JP2006020526A (en) * 2004-07-06 2006-01-26 Kiyomitsu Kawasaki Coffee flavor composition, and food and drink containing the same
JP2008259472A (en) * 2007-04-13 2008-10-30 T Hasegawa Co Ltd Just-made coffee feeling imparting agent
JP2010142147A (en) * 2008-12-17 2010-07-01 Kaneka Corp Onion extract, method for producing the same, and food product using the onion extract
JP2010142148A (en) * 2008-12-17 2010-07-01 Kaneka Corp Onion extract, method for producing the same, and food product using the onion extract
JP2015053886A (en) * 2013-09-11 2015-03-23 株式会社カネカ Food flavor modifier

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022209861A1 (en) * 2021-03-29 2022-10-06 味の素株式会社 Unpleasant odor masking agent

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