WO2018150165A1 - Textile résistant au feu - Google Patents

Textile résistant au feu Download PDF

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Publication number
WO2018150165A1
WO2018150165A1 PCT/GB2018/050376 GB2018050376W WO2018150165A1 WO 2018150165 A1 WO2018150165 A1 WO 2018150165A1 GB 2018050376 W GB2018050376 W GB 2018050376W WO 2018150165 A1 WO2018150165 A1 WO 2018150165A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
woven layer
around
fibres
aramid
Prior art date
Application number
PCT/GB2018/050376
Other languages
English (en)
Inventor
Robert Wesley BEADLE
Original Assignee
Arville Textiles Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arville Textiles Limited filed Critical Arville Textiles Limited
Priority to EP18705485.3A priority Critical patent/EP3582859B1/fr
Priority to ES18705485T priority patent/ES2857824T3/es
Priority to AU2018220789A priority patent/AU2018220789B2/en
Publication of WO2018150165A1 publication Critical patent/WO2018150165A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B17/00—Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00—Double or multi-ply fabrics not otherwise provided for
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • A41D31/085—Heat resistant; Fire retardant using layered materials
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments

Definitions

  • the present invention relates to fire resistant textile materials and to garments manufactured from such materials.
  • the present invention relates to articles of fire resistant clothing for use by fire fighters, military personnel and police officers, or the like, and to textiles for manufacturing such clothing.
  • the assembled garments which typically include a pair of trousers/salopettes and a jacket, must protect the wearer from radiant and thermal exposure, and unexpected f!ashover conditions, whilst still maintaining an adequate level of dexterity and comfort.
  • WO2015/008030 it is known to reduce second and third degree burns to a wearer by ensuring the barrier of protective clothing located between the heat source and the wearer's skin remains intact during exposure to heat and flame whilst ensuring an air gap exists between the skin and the heat source. It is also known to provide a single woven layer of fire resistant textile materia!
  • a fire resistant textile material comprising:
  • an outer woven layer comprising polyparaphenylene isophthalamide (meta- aramid) fibres or a blend of meta-aramid with polyparaphenylene terephthalamide (para-aramid) fibres;
  • an inner woven layer comprising polyparaphenylene terephthalamide (para- aramide) fibres; and an intermediate woven layer disposed between the outer and the inner woven layers and comprising a blend of wool fibres and cellulose fibres.
  • the intermediate woven layer comprises a twill weave defining an open structure.
  • the twill weave comprises a 2 x 2 twill weave.
  • the wool fibres have a thickness of around 15.5 ⁇ to around 29.5 ⁇ .
  • the wool fibres are shrink resistant wool fibres.
  • the blend of wool fibres and cellulose fibres comprises by weight from around 25% wool and 75% cellulose to around 75% wool and 25% cellulose.
  • the blend of wool fibres and cellulose fibres comprises by weight around 55% wool and around 45% cellulose.
  • the cellulose fibres comprise a fire retardant viscose fibre.
  • the outer woven layer comprises a twill weave defining an open structure in normal use.
  • the twill weave comprises a 2 x 2 twill weave.
  • the inner woven layer comprises a twill weave defining an open structure.
  • the twill weave comprises a 2 x 2 twill weave.
  • the outer woven layer comprises a yarn count of from around 40/2 Nm to around 100/2 Nm.
  • the yarn count of the outer woven layer is around 72/2 Nm.
  • the inner woven layer comprises a yarn count of from around 50/1 Nm to around 100/2 Nm.
  • the yarn count of the inner woven layer is around 100/2 Nm.
  • the intermediate woven layer comprises a yarn count of from around 20/2 Nm to around 100/2 Nm.
  • the yarn count of the intermediate woven layer is around 60/2 Nm.
  • the outer woven layer comprises around 93% meta-aramid, around 5% para-aramid, and around 2% antistatic fibre.
  • the outer woven layer comprises NomexTM.
  • the inner woven layer comprises 100% para-aramid.
  • the inner woven layer comprises KevlarTM.
  • the inner woven layer is connected to the intermediate woven layer and the outer woven layer.
  • warp ends from the inner woven layer weave into the outer woven layer and the intermediate woven layer respectively by crossing over individual picks thereof.
  • the warp ends of the inner layer interact with the picks of the outer layer and intermediate layer as illustrated in Figure 2.
  • the material has a weight of around 250gsm.
  • a fire resistant textile material in accordance with the first aspect of the present invention to protect a human's or animal's skin from burning.
  • a garment comprising a fire resistant textile material in accordance with the first aspect of the present invention.
  • a face surface of the outer layer defines an outer surface of the garment and a back face of the inner layer is contactable with a wearer's skin or an inner membrane layer of the garment.
  • the fire resistant textile material has a weaving plan substantially as shown in Figure 3.
  • a fire resistant textile material comprising:
  • an outer woven layer comprising polyparaphenylene isophthalamide (meta-aramid) fibres or a blend of meta-aramid with polyparaphenylene
  • intermediate woven layer is disposed between the outer and the inner woven layers.
  • the outer and inner woven layers define opposed face and back surfaces of the material respectively.
  • the method further comprises connecting yarns of the inner woven layer with yarns of the intermediate woven layer and the outer woven layer.
  • connecting comprises interweaving warp ends from the inner layer into the outer layer and the intermediate layer respectively by crossing over individual picks thereof.
  • the method further comprises interacting the warp ends of the inner layer with the picks of the outer layer and intermediate layer as illustrated in Figure 2.
  • the intermediate woven layer and the inner woven layer each comprise a twill weave to define a substantially open structure.
  • the outer woven layer comprises a twill weave defining a substantially open structure in normal use.
  • Figure 1 a illustrates an isometric view from the back side of a portion of a textile material in accordance with certain embodiments of the present invention
  • Figure 1 b illustrates a plan view from the face side of the textile material of Figure 1 a
  • Figure 1 c illustrates a sectional view through the textile material of Figures 1 a and 1 b;
  • Figure 2 illustrates a lifting plan for manufacturing a textile according to certain embodiments of the present invention
  • Figure 3 illustrates a weaving plan for manufacturing a textile according to certain embodiments of the present invention
  • Figures 4a and 4b illustrate how the outer layer of the textile according to certain embodiments of the present invention reacts in a high temperature environment.
  • a fire resistant textile material 100 includes three woven layers 102,104,106 which are distinct from each other and adapted to perform a particular technical function.
  • the outer woven layer 102 which aptly provides a face surface of the textile material 100 comprises a meta-aramid yarn.
  • the meta-aramid yarn is a poly- paraphenylene isophthalamide (meta-aramid) yarn, such as NomexTM.
  • the yarn optionally includes around 50-100% meta-aramid and around 0-50% para-aramid, and aptly comprises 93% meta-aramid (e.g. NomexTM), around 5% para-aramid (e.g.
  • KevlarTM and around 2% antistatic fibres (e.g. carbon fibres).
  • Alternative fibres for the outer woven layer 102 may comprise para-aramids, polybenzimidazole (PBI), poly (paraphenylenbenzobisoxazole) (PBO), or blends thereof.
  • the outer layer 102 is a 2x2 twill weave but other suitable weave patterns may be used such as a plain weave, 3x1 , 4x1 or 2x2 twill weaves, ripstop or hopsack weaves, satin, or sateen weaves, or the like.
  • a 2x2 twill weave is desirable in the outer layer to hide the stitching points of the lower layers.
  • a twill weave also desirably provides a tighter, denser construction which enhances the dimensional stability and increases durability after multiple washing.
  • NomexTM yarn is typically available in three types based on the linear mass density (2.2 dtex, 1 .7dtex and 1 .4dtex). Aptly, a 1 .4dtex NomexTM yarn is used as it offers desirable comfort and flexibility in view of its fineness.
  • a yarn count of the outer layer 102 is from around 40/2 Nm to around 100/2 Nm, and aptly around 72/2 Nm.
  • the intermediate woven layer 104 comprises a blended yarn of wool and cellulose- based (e.g. LenzingTM) fibres.
  • the blended yarn optionally comprises by weight from around 25% wool and 75% cellulose to around 75% wool and 25% cellulose fibres, and aptly around 55% wool to around 45% cellulose fibres for optimum moisture management as described further below.
  • the wool fibres have a thickness of between around 15.5-29.5 ⁇ , and aptly around 20.8 ⁇ which has been found to be optimum in terms of efficient and effective transportation of moisture from the skin and across adjacent fibres.
  • the lenzing fibre has a linear mass density of around 2.2 dtex.
  • the wool fibres are treated to be shrink resistant and the cellulose fibres comprise a fire retardant viscose fibre.
  • the intermediate woven layer 104 is a 2x2 twill weave and defines an open grid structure wherein the warp (Wpint) and weft (Wtint) yarns are approximately aligned with every other respective yarn (Wp 0 ut and W ) of the outer layer, i.e. there are approximately half the number of
  • a yarn count of the intermediate layer is from around 20/2 Nm to around 100/2 Nm, and aptly around 60/2 Nm.
  • the inner woven layer 106 which aptly provides a back surface of the textile material 100 comprises a para-aramid, e.g. KevlarTM, yarn.
  • the inner layer is made up of 100% para-aramid fibres.
  • a yarn count of the inner layer is from around 50/1 Nm to around 100/2 Nm, and aptly 100/2 Nm.
  • the inner layer is a 2x2 twill weave, or the like, that defines an open grid structure of the same or similar density in terms of warp and weft spacing to that of the intermediate layer.
  • the warp (Wpinn) and weft (Wtinn) yarns of the inner layer 106 are each located at least approximately between adjacent and respective yarns (Wpint and Wtint) of the intermediate layer 104.
  • the weft yarns (Wtinn) of the inner layer 106 are located between adjacent weft yarns (Wtint) of the intermediate layer 104 and in the same plane.
  • the warp yarns (Wpinn) of the inner layer 106 are aligned between the respective warp yarns (Wpint) of the intermediate layer 104 whilst being predominantly in a different plane to the warp yarns of the intermediate layer 104.
  • the warp yarns (Wpinn) of the inner layer 106 occasionally interact with the weft yarns (Wtint) of the intermediate layer 104 and the weft yarns (WW) of the outer layer 102 to thereby hold the textile material 100 together.
  • Alternate warp ends (Wpinn) from the Kevlar inner layer 106 weave into the Nomex outer layer 102 and the wool/Lenzing intermediate layer 104 respectively to provide stitching points (as illustrated by the four dark blocks in the lifting plan of Figure 2).
  • the weave structure repeats after every sixteen warp ends and every sixteen picks. The warp and weft repeat within that structure repeats after four ends (warp) and four picks (weft).
  • the yarn sequence is NomexTM, Wool/LenzingTM, NomexTM, KevlarTM for both warp and weft. Therefore, there are four repeats of the yarn sequence within the weave structure repeat.
  • the binding (stitching) point (first dark block from left to right in Figure 2) of the first Kevlar warp end is onto the fifth pick of the weft repeat which is a Nomex pick.
  • This warp end is the fourth of the sixteen end warp repeat.
  • the binding point (second dark block from left to right in Figure 2) of the second Kevlar warp end is onto the tenth pick of the repeat which is a
  • This warp end is the eighth pick of the sixteen end warp repeat.
  • the binding point (third dark block from left to right in Figure 2) of the third Kevlar warp end is onto the thirteenth pick of the repeat which is a Nomex pick.
  • This warp end is the twelfth of the sixteen end warp repeat.
  • the binding point (fourth dark block from left to right in Figure 2) of the fourth Kevlar warp end is onto the second pick of the repeat which is a wool/Lenzing pick.
  • This warp end is the sixteenth of the sixteen end warp repeat.
  • the weave structure as illustrated in Figures 1 a to 1 c for example has a ratio of 2/1 /1 , i.e. a weave structure of 2 outer picks (i.e.
  • each of the three woven layers 1 02,1 04,1 06 allows air to flow between the yarns through the textile 1 00 and allows the same to 'breath' which in turn helps to dissipate moisture from a wearer's skin through the textile/garment, e.g. a fire-fighter's jacket.
  • the meta-aramid yarns of the outer layer 1 02 which have a relatively dense arrangement of yarns compared to the intermediate and inner layers 1 04,1 06, provide excellent strength, thermal resistance, UV stability, wearability and abrasion resistant properties to the textile 100, whilst also protecting the underlying layers to such environmental conditions, i.e. UV, abrasion and the like, in normal use.
  • the Wool/LenzingTM blended yarn of the intermediate layer 104 provides comfort and moisture management in that the blended yarn is adapted for moisture absorption and dissipation.
  • the natural wicking properties of LenzingTM and moisture absorption properties of wool ensures efficient moisture transport from the inner layer 106 of the textile 100 when the same interfaces with a membrane layer of a garment and/or the skin of the wearer depending on the technical application for the textile 100.
  • Wool is hygroscopic, meaning it can hold up to one third of its own weight in moisture without feeling wet, thereby enhancing comfort.
  • the hygroscopic properties of wool help regulate temperature and humidity, creating a buffer area, thereby also enhancing comfort.
  • the chemical building blocks of wool - amino acids - are hydrophilic (water-liking), meaning that they attract and absorb water molecules into the chemical structure of the fibre.
  • wool Water binds within the wool's structure through the action of hydrogen bonds in a process known as absorption.
  • wool is inherently antimicrobial and antistatic, enhancing comfort and protection.
  • wool has a helical configuration in the centre of the fibre which acts like a shock-absorbing spring under compression, further enhancing comfort for the end user.
  • intermediate layer 104 in accordance with certain embodiments of the present invention also ensures moisture in liquid/vapour form is dissipated from the breathable membrane normally associated with Firefighters PPE, allowing a better moisture flow through the textile/garment 100 and reducing the level of moisture next to the skin, therefore reducing the possibility of scald/steam burn injuries.
  • the arrangement of the intermediate layer 104 and inner layer 106 allows a portion of each of the wool/LenzingTM warp yarns (Wpint) to occasionally extend between the KevlarTM warp yarns (Wpinn) of the inner layer 106 to engage with an inner membrane of a Firefighters PPE or directly with a wearer's skin to thereby provide comfort to a wearer whilst efficiently wicking away any moisture in the form of sweat from the skin.
  • the inner layer 106 is aptly a KevlarTM yarn to provide the textile with strength and stability particularly during heat exposure.
  • the warp yarns (Wpinn) of the inner layer 106 occasionally extend over predetermined ones of the weft yarns (Wtint) of the intermediate layer 104 and at different locations predetermined ones of the weft yarns (WW) of the outer layer 102 to thereby stitch up to these layers to connect the three woven layers 102,104,106 together as a three-layer, single woven fabric/textile to offer optimised bulk with improved thermal protection.
  • this construction also ensures the para-aramid KevlarTM fibres of the inner layer 106 are protected by the outer layer 102 and in turn from environmental conditions, particularly UV exposure in view of its relatively low stability in UV light.
  • the unique construction of the textile in accordance with certain embodiments of the present invention also provides excellent durability, dimensional stability, and tear strength as the three layers 102,104,106 support one another during a tearing motion.
  • the arrangement and configuration of the intermediate layer 104 ensures any moisture created at the inner layer 106, e.g. sweat, is efficiently dissipated away from the skin and the efficient air flow through the textile provided by the substantially open structure of each layer in normal use ensures the dissipated moisture is efficiently evaporated to atmosphere to further reduce the risk of any moisture at the skin converting to steam and causing scalding.
  • the meta-aramid yarns of the outer layer 102 consolidating, the para-aramid yarns of the inner layer 106 become locked into the structure to add additional strength and stability to the textile/garment 100 whilst being protected from
  • a fabric/textile material 100 according to certain embodiments of the present invention is further described by way of the following non-limiting examples:
  • the fabric includes three warp layers consisting of warp A having 93% Meta-Aramid (Nomex), 5% Para-Aramid (Kevlar) and 2% Antistatic fibre (P140), warp B having 55% wool and 45% cellulose FR (Lenzing), and warp C having 100% para-aramid.
  • This fabric is woven with two warp A ends to one warp B and one warp C. This is also the same ratio for the weft.
  • the fabric incudes three warp layers consisting of warp A having a PBI/para-aramid blend yarn, warp B having 55% Wool and 45% cellulose FR (Lenzing), and warp C having 100% para-aramid.
  • This fabric is woven with two warp A ends to one warp B and one warp C. This is also the same ratio for the weft.
  • Certain embodiments of the present invention therefore provide a light weight, comfortable fabric/textile, which is suitable for and provides improved performance in a PPE application, and which uses an open, breathable construction that reacts to its environment to increase thermal protection.
  • the open structure of the textile allows air to circulate through the garment whilst ensuring the efficient dissipation of moisture to reduce discomfort and the effects of heat stress and exhaustion.
  • the configuration of the textile further ensures the risk of scald burns are significantly reduced in the event of a high temperature event.
  • the end user of a garment made from a textile according to certain embodiments of the present invention will feel cooler and dryer with a reduced wear burden.
  • the textile/fabric meets the requirements of EN 469, BS7971 -10, AS/NZ4967, NFPA 1971 , EN1 1612 and other FR PPE standards, and also has a weight of less than 500 gsm when combined with a moisture barrier and inner liner for a firefighting garment.
  • the textile according to certain embodiments of the present invention may be used in garments for use in many technical applications, such as wild land fire garments, structural fire garments, electric arc garment, petrochemical garment, urban search and rescue garments, forestry garments, police violent situation garments (e.g. riot), and garments for military use, or the like.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Woven Fabrics (AREA)

Abstract

La présente invention concerne un matériau textile résistant au feu (100) comprenant une couche tissée externe (102) comprenant des fibres de polyparaphénylène isophtalamide (méta-aramide) ou un mélange de méta-aramide avec des fibres de polyparaphénylène téréphtalamide (para-aramide) ; une couche tissée interne (106) comprenant des fibres de polyparaphénylène téréphtalamide (para-aramide) ; et une couche tissée intermédiaire (104) disposée entre les couches tissées externe et interne et comprenant un mélange de fibres de laine et de fibres de cellulose. La présente invention concerne également un vêtement comprenant ledit matériau et un procédé de fabrication dudit matériau.
PCT/GB2018/050376 2017-02-17 2018-02-12 Textile résistant au feu WO2018150165A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP18705485.3A EP3582859B1 (fr) 2017-02-17 2018-02-12 Textile résistant au feu
ES18705485T ES2857824T3 (es) 2017-02-17 2018-02-12 Textil resistente al fuego
AU2018220789A AU2018220789B2 (en) 2017-02-17 2018-02-12 Fire resistant textile

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1702606.3 2017-02-17
GB1702606.3A GB2559772A (en) 2017-02-17 2017-02-17 Fire resistant textile

Publications (1)

Publication Number Publication Date
WO2018150165A1 true WO2018150165A1 (fr) 2018-08-23

Family

ID=58486714

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2018/050376 WO2018150165A1 (fr) 2017-02-17 2018-02-12 Textile résistant au feu

Country Status (5)

Country Link
EP (1) EP3582859B1 (fr)
AU (1) AU2018220789B2 (fr)
ES (1) ES2857824T3 (fr)
GB (1) GB2559772A (fr)
WO (1) WO2018150165A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019133347A1 (de) * 2019-12-06 2021-06-10 DREI-PUNKT-BERUFSKLEIDUNG GmbH Personenschutzkleidung

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2111298C1 (ru) * 1996-04-26 1998-05-20 Товарищество с ограниченной ответственностью "Предприятие "Прото" Термостойкая ткань
CA2228443C (fr) * 1997-01-31 2005-10-18 Southern Mills, Inc. Vetement de pompier
DE202007014674U1 (de) * 2007-10-19 2007-12-13 Theodolf Fritsche Gmbh & Co. Kg Stoff für Flammschutzbekleidung

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2327883B1 (es) * 2006-07-18 2010-09-06 Tejidos Estambril, S.A. Tejido de proteccion termica.
US20130065470A1 (en) * 2011-03-10 2013-03-14 Mmi-Ipco, Llc Flame Resistant Fiber Blends and Flame Resistant Yarns, Fabrics, and Garments Formed Thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2111298C1 (ru) * 1996-04-26 1998-05-20 Товарищество с ограниченной ответственностью "Предприятие "Прото" Термостойкая ткань
CA2228443C (fr) * 1997-01-31 2005-10-18 Southern Mills, Inc. Vetement de pompier
DE202007014674U1 (de) * 2007-10-19 2007-12-13 Theodolf Fritsche Gmbh & Co. Kg Stoff für Flammschutzbekleidung

Also Published As

Publication number Publication date
AU2018220789A1 (en) 2019-09-19
AU2018220789B2 (en) 2019-10-31
ES2857824T3 (es) 2021-09-29
GB201702606D0 (en) 2017-04-05
EP3582859A1 (fr) 2019-12-25
GB2559772A (en) 2018-08-22
EP3582859B1 (fr) 2021-01-13

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