GB2516317A - Fire resistant textile material - Google Patents

Fire resistant textile material Download PDF

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Publication number
GB2516317A
GB2516317A GB1312981.2A GB201312981A GB2516317A GB 2516317 A GB2516317 A GB 2516317A GB 201312981 A GB201312981 A GB 201312981A GB 2516317 A GB2516317 A GB 2516317A
Authority
GB
United Kingdom
Prior art keywords
textile material
fire resistant
resistant textile
fibres
wool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB1312981.2A
Other versions
GB201312981D0 (en
Inventor
Simon Callum Burnett-Boothroyd
Robert Beadle
Derek Walker
Thomas Hainsworth
Charlotte Brandt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hainsworth AW and Sons Ltd
Original Assignee
Hainsworth AW and Sons Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hainsworth AW and Sons Ltd filed Critical Hainsworth AW and Sons Ltd
Priority to GB1312981.2A priority Critical patent/GB2516317A/en
Publication of GB201312981D0 publication Critical patent/GB201312981D0/en
Priority to EP14742293.5A priority patent/EP3022343A1/en
Priority to AU2014291849A priority patent/AU2014291849B2/en
Priority to PCT/GB2014/052051 priority patent/WO2015008030A1/en
Publication of GB2516317A publication Critical patent/GB2516317A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/02Wool
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides

Abstract

A fire resistant textile material for garments comprises a woven twill comprising polyparaphenylene isophthalamide fibres and a blend of cellulose fibres and wool fibres. The polyparaphenylene isophthalamide fibres may be a meta aramid such as Nomex and is preferably 95% Nomex 3% Kevlar and 2% antistatic (P 140) fibres. The cellulose fibres may be manufactured from wood pulp treated with a fire retardant such as Lenzing. The wool fibres may be shrink resistant. The fabric may have a weight of 200-300g/m2. The preferred weaving plan is shown in Figure 1.

Description

FIRE RESISTANT TEXTILE MATERIAL
This invention relates to fire resistant textile materials and garments made from these materials. The invention relates particularly but not exclusively to articles of clothing for use by fire fighters and for textiles for manufacture of such clothing.
European legislation requires employers to provide gannents which protect their employees against hazards to which they may be exposed. Clothing for protection against heat and flame must pass minimum perfonnance requirements for flame, radiant heat, heat resistance, tensile and tear strength, abrasion resistance and penetration by water and liquid chemicals. The assembled garments must achieve levels of resistance to heat transfer by both flame and radiant heat.
One of the most effective ways to reduce second and third degree burns is to make sure that the barrier of protective clothing between the heat source and the skin remains intact during exposure. This is referred to as the break open resistance or non-break open protection.
US 6699802 discloses a fire resistant textile material comprising a woven face fabric composed of meta-aramid fibres including a woven mesh of low thermal shrinkage fibres, for example para-aramid fibres.
An object of the present invention is to provide a fire resistant textile material with reduced weight, increased drape and improved comfort in use.
According to the present invention a fire resistant textile material is composed of a woven twill comprising: polyparaphenylene isophthalamide fibres; and a blend of cellulose fibres and wool fibres.
The cellulose/wool blend is predominantly located on the back surface or back area of the fabric.
A preferred polyparaphenylene isophthalamide (meta-aramid) is Nomex (Registered Trade Mark). A particularly preferred fibre comprises 95% Nomex, 3% Keviar and 2% antistatic (P 140) fibres.
A preferred meta-aramid fibre may comprise polyparaphenylene isophthalamide eg Nomex (Registered Trade Mark). Alternative meta-aramid fibres may comprise polybenzimidazole (PBI), polybenzobisoxazole (PBO) or blends thereof A preferred cellulose fibre is a fire retardant cellulose fibre. These may be manufactured from wood pulp treated with a fire retardant, for example Lenzing FR.
2.2 Decitex fibres are preferred.
Preferred wool fibres are 20.8 m shrink resistant wool fibres. The blend may comprise from 25% wool and 75% cellulose to 75% wool and 25% cellulose, preferably about 50% wool and 50% cellulose.
A fabric may comprise a 2 x 1 ripstop twill having a warp comprising meta-aramid eg Nomex eg Nomex Ill with a warp count of Nm 60/2.
In a preferred fabric the weft may comprise a wool-cellulose blend with a weft count of Nm 60/2 and Nm 40/2/2 Nomex, with maximum weft mixing.
Use of a 2 x 1 twill allows an excess of Nomex warp to be provided on the fabric face. A ripstop is provided in the warp & well combination.
Double twisted yarns may be employed. The warp may have a yarn count in the range of Nm 20/2 to 100/2, preferably Nm 30/2 to 80/2, more preferably Nm 40/2 to 60/2, especially Nm 60/2. When using Nm 60/2 the number of warp ends may be 4500 to 5600, typically 5168.
A preferred fabric weight may be 200 to 300, typically 240g/m2.
A weaving plan is shown in Figure 1, A fabric in accordance with the present invention confers several advantages.
The water absorbing properties of wool combined with excellent working properties of the cellulose fibres ensures transfer of moisture away from a wearer's skin. The moisture is retained by the buffering effect of the wool before evaporation to maintain cool and dry wearing conditions of use of Lenzing (FR) and wool affords excellent thermal protection with break open protection provided by the meta-aramid fibres.
Wool also provides inherent antimicrobial and antistatic properties to make the garment comfortable even after prolonged wearing.
Thermal regulation is improved in warm thy conditions due to the unique blend of wool / Lenzing and para-aramid fibres. The natural hydrophilic properties of wool facilitate vapour or moisture desorption in low relative humidity climates The hydrophilic properties of Lenzing fibres serves to push moisture away. The fabric therefore acts as a heat exchanger and regulator.
The unique blend of the fibres and yarns gives the fabric a breathable buffer and a thermal barrier properties which assist in keeping the wearer comfortable and avoids a liability to suffer from heat fatigue.
The primary use of the fabric is a moisture management system coupled with a barrier to both radiant and convective heat extreme, for example during wildland fire fighting.
Tear Strength is increased due to the unique network of meta aramid fibres (which may be referred to as "tram lines") acting as strengthening support beams in the fabric structure and making it more durable.
When the face of the fabric is exposed to extreme heat and a consolidation occurs due to the nature of the aromatic fibres the heavier weft yarns (tram lines) act as a support to the fabric not only in providing dimensional stability but assists in the crimping effect of the structure thus getting volume into the structure. This property creates an increase in the thermal barrier protection by absorbing some of the energy on exposure and has less surface contact with the wearer.
During thermal decomposition of a surface layer water is released.
F This may be dissolved by the underlying wool fibres. Evaporation of this moisture may enhance thermal protection of a user's skin.

Claims (9)

  1. SCLAIMS1. A fire resistant textile material comprising a woven twill comprising: polyparaphenylene isophthalamide fibres; and a blend of cellulose fibres and wool fibres.
  2. 2. A fire resistant textile material as claimed in claim 1, wherein the cellulose/wool blend is predominantly located on a back surface of the fabric.
  3. 3. A fire resistant textile material as claimed in claim 1 or 2, wherein the polyparaphenylene isophthalamide fibres comprise meta aramid fibres selected from the group consisting of Nomex, polybenzimidazole (PBI) or polybenzobisoxazole (PBO) or blends thereof
  4. 4. A fire resistant textile material as claimed in any preceding claim, wherein the cellulose fibre is a fire retardant cellulose fibre.
  5. 5. A fire resistant textile material as claimed in claim 4, wherein the cellulose fibre manufactured from wood pulp treated with a fire retardant.
  6. 6. A fire resistant textile material as claimed in any preceding claim, wherein the wool fibres are 20.8 jim shrink resistant wool fibres.
  7. 7. A fire resistant textile material as claimed in any preceding claim wherein the blend of cellulose fibres and wool fibres comprises by weight, from 25% wool and 75% cellulose to 75% wool and 25% cellulose.
  8. 8. A fire resistant textile material as claimed in claim 7, wherein the blend comprises about 50% wool and about 50% cellulose.
  9. 9. A fire resistant textile material as claimed in any preceding claim comprising a 2 x 1 ripstop twill having a warp comprising meta aramid with a warp count of Nm 60/2. r10. A fire resistant textile material as claimed in any preceding claim wherein the weft comprises a wool-cellulose blend with a weft count of Nm 60/2 and Nm 40/2/2 meta aramid.11. A fire resistant textile material as claimed in any preceding claim comprising double twisted yams.12. A fire resistant textile material as claimed in claim 11, wherein the warp has a yarn count in the range of Nm 20/2 to 100/2.13. A fire resistant textile material as claimed in claim 12, wherein the warp has a yarn count in the range of Nm 30/2 to 80/2.14. A fire resistant textile material as claimed in claim 13, wherein the warp has a yarn count in the range of Nm 40/2 to 60/2.15. A fire resistant textile material as claimed in claim 14, wherein the warp has a yarn count is Nm 60/2.16. A fire resistant textile material as claimed in claim 15, wherein the number of warp ends is 4500 to 5600.17. A fire resistant textile material as claimed in any preceding claim, wherein the fabric weight is 200 to 300g/m2.18. A fire resistant textile material having a weaving plan as shown in Figure 1.19. A fire resistant textile material substantially as hereinbefore described. ij
GB1312981.2A 2013-07-19 2013-07-19 Fire resistant textile material Withdrawn GB2516317A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB1312981.2A GB2516317A (en) 2013-07-19 2013-07-19 Fire resistant textile material
EP14742293.5A EP3022343A1 (en) 2013-07-19 2014-07-04 Fire resistant textile material
AU2014291849A AU2014291849B2 (en) 2013-07-19 2014-07-04 Fire resistant textile material
PCT/GB2014/052051 WO2015008030A1 (en) 2013-07-19 2014-07-04 Fire resistant textile material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1312981.2A GB2516317A (en) 2013-07-19 2013-07-19 Fire resistant textile material

Publications (2)

Publication Number Publication Date
GB201312981D0 GB201312981D0 (en) 2013-09-04
GB2516317A true GB2516317A (en) 2015-01-21

Family

ID=49119017

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1312981.2A Withdrawn GB2516317A (en) 2013-07-19 2013-07-19 Fire resistant textile material

Country Status (1)

Country Link
GB (1) GB2516317A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4868041A (en) * 1987-02-09 1989-09-19 Toyo Boseki Kabushiki Kaisha Cloth for protection against flames
US4927698A (en) * 1989-03-15 1990-05-22 Springs Industries, Inc. Pucker and shrink resistant flame retardant fabric formed of corespun yarns
US20040152378A1 (en) * 2002-06-07 2004-08-05 Stanhope Michael T. Flame resistant fabrics having increased strength
JP2005154974A (en) * 2003-11-28 2005-06-16 Abbott Mind Kk Reinforced fabric
WO2008075505A1 (en) * 2006-12-18 2008-06-26 Hayashi Yarn Twisting Co., Ltd. Heat-resistant bound double woven fabric and garment and heat-resistant glove comprising the same
WO2011050257A2 (en) * 2009-10-23 2011-04-28 Invista Technologies S.A R.L. Blended fiber yarns and fabrics including oxidized polymeric fibers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4868041A (en) * 1987-02-09 1989-09-19 Toyo Boseki Kabushiki Kaisha Cloth for protection against flames
US4927698A (en) * 1989-03-15 1990-05-22 Springs Industries, Inc. Pucker and shrink resistant flame retardant fabric formed of corespun yarns
US20040152378A1 (en) * 2002-06-07 2004-08-05 Stanhope Michael T. Flame resistant fabrics having increased strength
JP2005154974A (en) * 2003-11-28 2005-06-16 Abbott Mind Kk Reinforced fabric
WO2008075505A1 (en) * 2006-12-18 2008-06-26 Hayashi Yarn Twisting Co., Ltd. Heat-resistant bound double woven fabric and garment and heat-resistant glove comprising the same
WO2011050257A2 (en) * 2009-10-23 2011-04-28 Invista Technologies S.A R.L. Blended fiber yarns and fabrics including oxidized polymeric fibers

Also Published As

Publication number Publication date
GB201312981D0 (en) 2013-09-04

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)