WO2018077134A1 - Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent - Google Patents

Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent Download PDF

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Publication number
WO2018077134A1
WO2018077134A1 PCT/CN2017/107305 CN2017107305W WO2018077134A1 WO 2018077134 A1 WO2018077134 A1 WO 2018077134A1 CN 2017107305 W CN2017107305 W CN 2017107305W WO 2018077134 A1 WO2018077134 A1 WO 2018077134A1
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mass
parts
water
agent
treatment agent
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PCT/CN2017/107305
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French (fr)
Chinese (zh)
Inventor
陈勇刚
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江苏宝泽高分子材料股份有限公司
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Publication of WO2018077134A1 publication Critical patent/WO2018077134A1/en

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Definitions

  • the invention relates to a water-based high-fixing oil treatment agent for synthetic leather, in particular to a water-based high-fixing oil treatment agent for synthetic leather used in the process of synthetic leather, and the invention also discloses that the synthetic leather is highly water-based.
  • a method of preparing a varnish treatment agent is also disclosed.
  • the existing synthetic water-based high-fixing varnish treatment agent has poor hand feeling, and cracks when baked at a high temperature, and the sprayed diluted solution prepared is poor in storage stability, and the pigment is easily settled.
  • the synthetic leather using such a water-based high-fixing oil treatment agent has poor gloss and color, and the color development is not satisfactory. Therefore, there is a need for an improved aqueous high fixation oil treatment agent.
  • the synthetic leather aqueous high-solid varnish treatment agent disclosed in the invention comprises the following components: an aqueous resin, an antifoaming agent, a wetting agent, a Deqian thickener, BCS and water.
  • the ratio of each component of the aqueous high-solid fixing oil treatment agent for synthetic leather provided by the present invention may be 75 to 80 parts by mass of the aqueous resin and 0.02 to 0.05 parts by mass of the antifoaming agent, based on the total weight of the aqueous resin.
  • the components of the synthetic leather aqueous high-solid varnish treatment agent are as follows: 75 parts by mass of the aqueous resin, 0.05 parts by mass of the antifoaming agent, 0.3 parts by mass of the wetting agent, Deqian 0.4 parts by mass of the thickener, 2 parts by mass of BCS, and 22.25 parts by mass of water.

Abstract

The present invention relates to a water-based high gloss-setting oil treatment agent for synthetic leather and a preparation method for the agent. The water-based high gloss-setting oil treatment agent for synthetic leather comprises the following components: a water-based resin, a defoamer, a moisturizer, a Deuchem thickener, BCS, and water. The components of the water-based high gloss-setting oil treatment agent for synthetic leather of the present invention are coordinated with each other and provide joint effects, a unique post-treatment touch is provided, the advantage is not being prone to cracking when baked at a high temperature, at the same time, a diluted spraying solution prepared as such has great storage stability, dyes are not prone to settlement, and leather made with the present treatment agent has natural gloss, clear colors, great color development and general effects.

Description

一种合成革用水性高固光油处理剂及其制备方法Water-based high-fixing oil treatment agent for synthetic leather and preparation method thereof 技术领域Technical field
本发明涉及一种合成革用水性高固光油处理剂,特别涉及应用于合成革后段工艺的合成革用水性高固光油处理剂,同时本发明还公开了该合成革用水性高固光油处理剂的制备方法。The invention relates to a water-based high-fixing oil treatment agent for synthetic leather, in particular to a water-based high-fixing oil treatment agent for synthetic leather used in the process of synthetic leather, and the invention also discloses that the synthetic leather is highly water-based. A method of preparing a varnish treatment agent.
背景技术Background technique
目前,现有的合成革用水性高固光油处理剂处理后手感差,在高温下烘烤时开裂,同时配出的喷涂稀释溶液储存稳定性差,颜料容易沉降。应用这样的水性高固光油处理剂的合成革,其光泽和色泽较差,展色也不尽如人意。因此,需要一种改进的水性高固光油处理剂。At present, the existing synthetic water-based high-fixing varnish treatment agent has poor hand feeling, and cracks when baked at a high temperature, and the sprayed diluted solution prepared is poor in storage stability, and the pigment is easily settled. The synthetic leather using such a water-based high-fixing oil treatment agent has poor gloss and color, and the color development is not satisfactory. Therefore, there is a need for an improved aqueous high fixation oil treatment agent.
发明内容Summary of the invention
本发明的目的是提供一种合成革用水性高固光油处理剂。It is an object of the present invention to provide an aqueous high-solid varnish treatment agent for synthetic leather.
本发明的合成革用水性高固光油处理剂通过以下技术方案实现:The water-based high-fixing oil treatment agent for synthetic leather of the invention is realized by the following technical solutions:
本发明所公开的合成革用水性高固光油处理剂,包含以下组分:水性树脂、消泡剂、润湿剂、德谦增稠剂、BCS及水。The synthetic leather aqueous high-solid varnish treatment agent disclosed in the invention comprises the following components: an aqueous resin, an antifoaming agent, a wetting agent, a Deqian thickener, BCS and water.
以水性树脂的总重量为基准,本发明提供的合成革用水性高固光油处理剂的各组分的配比可以为:水性树脂75~80质量份,消泡剂0.02~0.05质量份,润湿剂0.2~0.3质量份,德谦增稠剂0.2~0.4质量份,BCS 1.5~2质量份,水20~25质量份。The ratio of each component of the aqueous high-solid fixing oil treatment agent for synthetic leather provided by the present invention may be 75 to 80 parts by mass of the aqueous resin and 0.02 to 0.05 parts by mass of the antifoaming agent, based on the total weight of the aqueous resin. 0.2 to 0.3 parts by mass of the wetting agent, 0.2 to 0.4 parts by mass of Deqian thickener, 1.5 to 2 parts by mass of BCS, and 20 to 25 parts by mass of water.
在本发明的一个实施例中,合成革用水性高固光油处理剂的各组分的配比如下:水性树脂75质量份,消泡剂0.05质量份,润湿剂0.3质量份,德谦增稠剂0.4质量份,BCS 2质量份,水22.25质量份。 In one embodiment of the present invention, the components of the synthetic leather aqueous high-solid varnish treatment agent are as follows: 75 parts by mass of the aqueous resin, 0.05 parts by mass of the antifoaming agent, 0.3 parts by mass of the wetting agent, Deqian 0.4 parts by mass of the thickener, 2 parts by mass of BCS, and 22.25 parts by mass of water.

Claims (1)

  1. 在本发明的另一实施例中,合成革用水性高固光油处理剂的各组分的配比如下:水性树脂78质量份,消泡剂0.03质量份,润湿剂0.3质量份,德谦增稠剂0.27质量份,BCS 1.4质量份,水20质量份。In another embodiment of the present invention, the components of the synthetic water-based high-solid varnish treatment agent are as follows: 78 parts by mass of the aqueous resin, 0.03 parts by mass of the antifoaming agent, 0.3 parts by mass of the wetting agent, 0.27 parts by mass of thick thickener, 1.4 parts by mass of BCS, and 20 parts by mass of water.
    在本发明的另一实施例中,合成革用水性高固光油处理剂的各组分的配比如下:水性树脂75质量份,消泡剂0.02质量份,润湿剂0.2质量份,德谦增稠剂0.28质量份,BCS 1.5质量份,水23质量份。In another embodiment of the present invention, the components of the synthetic water-based high-fixing varnish treatment agent are as follows: 75 parts by mass of the aqueous resin, 0.02 parts by mass of the antifoaming agent, 0.2 parts by mass of the wetting agent, 0.28 parts by mass of thick thickener, 1.5 parts by mass of BCS, and 23 parts by mass of water.
    本发明还提供一种合成革用水性高固光油处理剂的制备方法,包含以下步骤:The invention also provides a preparation method of an aqueous high-solid fixing oil treatment agent for synthetic leather, comprising the following steps:
    将配方中的水性树脂、消泡剂、润湿剂、德谦增稠剂、BCS及水均匀搅拌。The aqueous resin, defoamer, wetting agent, Deqian thickener, BCS and water in the formulation were uniformly stirred.
    本发明的合成革用水性高固光油处理剂的制备方法中的各组分的配比可以如下:水性树脂75~80质量份,消泡剂0.02~0.05质量份,润湿剂0.2~0.3质量份,德谦增稠剂0.2~0.4质量份,BCS 1.5~2质量份,水20~25质量份。The ratio of each component in the preparation method of the aqueous high-solid varnish treatment agent for synthetic leather of the present invention may be as follows: 75 to 80 parts by mass of the aqueous resin, 0.02 to 0.05 parts by mass of the antifoaming agent, and 0.2 to 0.3 of the wetting agent. The mass fraction is 0.2 to 0.4 parts by mass of the Deqian thickener, 1.5 to 2 parts by mass of BCS, and 20 to 25 parts by mass of water.
    优选地,各组分的配比如下:水性树脂75质量份,消泡剂0.05质量份,润湿剂0.3质量份,德谦增稠剂0.4质量份,BCS 2质量份,水22.25质量份。Preferably, the components are formulated as follows: 75 parts by mass of the aqueous resin, 0.05 parts by mass of the antifoaming agent, 0.3 parts by mass of the wetting agent, 0.4 parts by mass of the Deqian thickener, 2 parts by mass of the BCS, and 22.25 parts by mass of the water.
    更优选地,各组分的配比如下:水性树脂78质量份,消泡剂0.03质量份,润湿剂0.3质量份,德谦增稠剂0.27质量份,BCS 1.4质量份,水20质量份。More preferably, the components are as follows: 78 parts by mass of the aqueous resin, 0.03 parts by mass of the antifoaming agent, 0.3 parts by mass of the wetting agent, 0.27 parts by mass of the Deqian thickener, 1.4 parts by mass of the BCS, and 20 parts by mass of the water. .
    更优选地,各组分的配比如下:水性树脂75质量份,消泡剂0.02质量份,润湿剂0.2质量份,德谦增稠剂0.28质量份,BCS 1.5质量份,水23质量份。More preferably, the components are as follows: 75 parts by mass of the aqueous resin, 0.02 parts by mass of the antifoaming agent, 0.2 parts by mass of the wetting agent, 0.28 parts by mass of the Deqian thickener, 1.5 parts by mass of the BCS, and 23 parts by mass of the water. .
    由于采用以上技术方案,本发明与现有技术相比具有如下优点:Due to the above technical solution, the present invention has the following advantages compared with the prior art:
    1.本发明所述的合成革用水性高固光油处理剂的各组分相互协调、共同作用,处理后手感独特,在高温下烘烤时不开裂等优点,同时配出的喷涂稀释溶液有很好的储存稳定性,颜料不容易沉降,用此种处理剂做出的 1. The components of the water-based high-fixing varnish treatment agent for synthetic leather according to the present invention are mutually coordinated and act together, and have a unique hand feeling after treatment, and are not cracked when baked at a high temperature, and the sprayed diluted solution is prepared at the same time. Good storage stability, pigments are not easy to settle, made with this treatment
PCT/CN2017/107305 2016-10-28 2017-10-23 Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent WO2018077134A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610964040.7A CN106521961A (en) 2016-10-28 2016-10-28 Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent
CN201610964040.7 2016-10-28

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WO2018077134A1 true WO2018077134A1 (en) 2018-05-03

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106521961A (en) * 2016-10-28 2017-03-22 江苏宝泽高分子材料股份有限公司 Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040011989A1 (en) * 2002-07-08 2004-01-22 China Textile Institute Fabric coating composition with latent heat effect and a method for fabricating the same
CN101649547A (en) * 2009-08-25 2010-02-17 江苏宝泽高分子材料股份有限公司 Waterborne PU fixing gloss oil for synthetic leather
CN102535171A (en) * 2011-12-08 2012-07-04 浙江深蓝轻纺科技有限公司 Waterborne polyurethane finishing agent for matting type synthetic leather and preparation method thereof
CN105316947A (en) * 2015-11-27 2016-02-10 江苏宝泽高分子材料股份有限公司 Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof
CN105442323A (en) * 2015-11-27 2016-03-30 江苏宝泽高分子材料股份有限公司 Water-based polishing treatment agent for synthetic leather and preparation method of agent
CN106521961A (en) * 2016-10-28 2017-03-22 江苏宝泽高分子材料股份有限公司 Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040011989A1 (en) * 2002-07-08 2004-01-22 China Textile Institute Fabric coating composition with latent heat effect and a method for fabricating the same
CN101649547A (en) * 2009-08-25 2010-02-17 江苏宝泽高分子材料股份有限公司 Waterborne PU fixing gloss oil for synthetic leather
CN102535171A (en) * 2011-12-08 2012-07-04 浙江深蓝轻纺科技有限公司 Waterborne polyurethane finishing agent for matting type synthetic leather and preparation method thereof
CN105316947A (en) * 2015-11-27 2016-02-10 江苏宝泽高分子材料股份有限公司 Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof
CN105442323A (en) * 2015-11-27 2016-03-30 江苏宝泽高分子材料股份有限公司 Water-based polishing treatment agent for synthetic leather and preparation method of agent
CN106521961A (en) * 2016-10-28 2017-03-22 江苏宝泽高分子材料股份有限公司 Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent

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