CN106521961A - Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent - Google Patents
Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent Download PDFInfo
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- CN106521961A CN106521961A CN201610964040.7A CN201610964040A CN106521961A CN 106521961 A CN106521961 A CN 106521961A CN 201610964040 A CN201610964040 A CN 201610964040A CN 106521961 A CN106521961 A CN 106521961A
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- mass parts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention relates to a waterborne light-curing oil treating agent for synthetic leather and a preparation method of the waterborne light-curing oil treating agent. The waterborne light-curing oil treating agent for the synthetic leather comprises the following components: waterborne resin, a defoamer, a wetting agent, a Deqian thickening agent, BCS and water. Various components of the waterborne light-curing oil treating agent for the synthetic leather cooperate with one another and interact, and after being treated, the synthetic leather feels unique, and does not crack after being baked at high temperature. Meanwhile, a prepared spraying dilute solution has good storage stability, pigment cannot settle easily, and the leather manufactured by using the treating agent is natural in gloss, clear in color and luster, good in color developing and good in comprehensive effect.
Description
Technical field
The present invention relates to a kind of high solid light oil-treatment agent of use for synthetic leather aqueouss, is more particularly to applied to synthetic leather rear section technique
The high solid light oil-treatment agent of use for synthetic leather aqueouss, while the invention also discloses the use for synthetic leather aqueouss high solid light oil-treatment agent
Preparation method.
Background technology
At present, after the high solid light oil-treatment agent of existing use for synthetic leather aqueouss is processed, feel is poor, ftractures when toasting at high temperature,
The spraying dilute solution poor storage stability allotted simultaneously, pigment are easily settled.Using the high solid light oil-treatment agent of such aqueouss
Synthetic leather, its gloss and color and luster it is poor, color development is also not fully up to expectations.Accordingly, it would be desirable to a kind of high Gu Guangyouchu of improved aqueouss
Reason agent.
The content of the invention
It is an object of the invention to provide a kind of high solid light oil-treatment agent of use for synthetic leather aqueouss.
The high solid light oil-treatment agent of the use for synthetic leather aqueouss of the present invention is achieved through the following technical solutions：
The high solid light oil-treatment agent of use for synthetic leather aqueouss disclosed in this invention, comprising following components：Water-base resin, froth breaking
Agent, wetting agent, the modest thickening agent of moral, BCS and water.
On the basis of the gross weight of water-base resin, each group of the high solid light oil-treatment agent of use for synthetic leather aqueouss that the present invention is provided
Point proportioning can be：75～80 mass parts of water-base resin, 0.02～0.05 mass parts of defoamer, 0.2～0.3 mass of wetting agent
Part, modest 0.2～0.4 mass parts of thickening agent of moral, 1.5～2 mass parts of BCS, 20～25 mass parts of water.
In one embodiment of the invention, the proportioning of each component of the high solid light oil-treatment agent of use for synthetic leather aqueouss is as follows：
75 mass parts of water-base resin, 0.05 mass parts of defoamer, 0.3 mass parts of wetting agent, modest 0.4 mass parts of thickening agent of moral, 2 matter of BCS
Amount part, 22.25 mass parts of water.
In another embodiment of the invention, the proportioning of each component of the high solid light oil-treatment agent of use for synthetic leather aqueouss is as follows：
78 mass parts of water-base resin, 0.03 mass parts of defoamer, 0.3 mass parts of wetting agent, modest 0.27 mass parts of thickening agent of moral, BCS
1.4 mass parts, 20 mass parts of water.
In another embodiment of the invention, the proportioning of each component of the high solid light oil-treatment agent of use for synthetic leather aqueouss is as follows：
75 mass parts of water-base resin, 0.02 mass parts of defoamer, 0.2 mass parts of wetting agent, modest 0.28 mass parts of thickening agent of moral, BCS
1.5 mass parts, 23 mass parts of water.
The present invention also provides a kind of preparation method of the high solid light oil-treatment agent of use for synthetic leather aqueouss, comprises the steps of：
By the water-base resin in formula, defoamer, wetting agent, the modest thickening agent of moral, BCS and water uniform stirring.
The proportioning of each component in the preparation method of the high solid light oil-treatment agent of the use for synthetic leather aqueouss of the present invention can be as follows：
75～80 mass parts of water-base resin, 0.02～0.05 mass parts of defoamer, 0.2～0.3 mass parts of wetting agent, the modest thickening agent of moral
0.2～0.4 mass parts, 1.5～2 mass parts of BCS, 20～25 mass parts of water.
Preferably, the proportioning of each component is as follows：75 mass parts of water-base resin, 0.05 mass parts of defoamer, 0.3 matter of wetting agent
Amount part, modest 0.4 mass parts of thickening agent of moral, 2 mass parts of BCS, 22.25 mass parts of water.
It is highly preferred that the proportioning of each component is as follows：78 mass parts of water-base resin, 0.03 mass parts of defoamer, wetting agent 0.3
Mass parts, modest 0.27 mass parts of thickening agent of moral, 1.4 mass parts of BCS, 20 mass parts of water.
It is highly preferred that the proportioning of each component is as follows：75 mass parts of water-base resin, 0.02 mass parts of defoamer, wetting agent 0.2
Mass parts, modest 0.28 mass parts of thickening agent of moral, 1.5 mass parts of BCS, 23 mass parts of water.
As using above technical scheme, the present invention is had the advantage that compared with prior art：
1. each component of the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention is mutually coordinated, collective effect, place
After reason, feel is unique, the advantages of cracking when toasting at high temperature, while the spraying dilute solution allotted has storage well steady
Qualitative, pigment does not allow free settling, and the leather gloss nature made with this kind of inorganic agent, color clarification, color development are good, resultant effect；
2. the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention replaces organic solvent as disperse medium using water
New polyurethane system, as aqueous polyurethane is with water compositing dispersion medium, the course of processing without the need for organic solvent, therefore to environment
Pollution-free, to operator without health hazard, and aqueous polyurethane abnormal smells from the patient is little, nonflammable, and the course of processing is safe and reliable.Water
Property polyurethane with water as solvent, pollution-free, safe and reliable, good mechanical performance, the compatibility be good, it is easily modified the advantages of；
3. without poisonous in the aqueous polyurethane system of the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention
NCO group, as aqueous polyurethane is without toxic organic solvents, therefore remains without toxic solvent in product, product safety, environmental protection,
No way out is limited；
4. the moisture-inhibiting steam permeability of the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention will be far better than similar
Solvent borne polyurethane product, because the hydrophilic of aqueous polyurethane is strong, it is strong with the binding ability of water, so its product has
Good moisture-inhibiting steam permeability；
5. the water of the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention makees continuous phase so that aqueous polyurethane body
It is that viscosity is unrelated with polyurethane resin molecular weight, and it is lower than solid content identical solvent borne polyurethane solution viscosity, it is easy to process,
It is easy to operate；
6. the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention is blended with other water-based emulsions or copolymerizing and blending,
Reduces cost or the more diversified polyaminoester emulsion of performance can be obtained, therefore style and the synthetic leather of different properties can be brought to produce
Product, meet all kinds of consumer demands；Also, due to solvent price in recent years is surging and environmental administration to organic solvent using and
The strict restriction of waste discharge, makes aqueous polyurethane replace solvent borne polyurethane to become an important development direction；
7. use for synthetic leather aqueouss of the present invention are high consolidates light oil-treatment agent good hand feeling, and soft texture, comfortably, with not
Combustion, it is nontoxic, pollution-free the advantages of.By the oxygen flow gas of finished leather, poisture-penetrability, low-temperature flex resistance, Bearable dry and wet wipe, resistance to ag(e)ing
Deng, with solvent borne polyurethane cover with paint, lacquer, colour wash, etc. after synthetic leather carried out comparative study.Traditional solvent-borne type is substituted using aqueous polyurethane
It is excellent that polyurethane completes the performances such as the Final finishing of synthetic leather, the breathability of finished leather, poisture-penetrability, low-temperature flex resistance, Bearable dry and wet wipe
In the former, whole technical process does not have solvent discharge, environmental friendliness；
8. the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention can carry out secondary research and development according to demand, with good
Good market using value；
9. the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention is applied on existing synthetic leather production line, technique
Simply, be back segment process a kind of new material, need not change production equipment increase cost；
10. the preparation method of the high solid light oil-treatment agent of use for synthetic leather aqueouss of the present invention is simple, need not be using complexity
Mechanical treatment, saved production cost, be suitable to industrialized production.
Specific embodiment
Below by embodiment, technical solution of the present invention is described in detail, but protection scope of the present invention not office
It is limited to the embodiment.
Embodiment 1
The high solid light oil-treatment agent of use for synthetic leather aqueouss includes 75 mass parts water-base resins, 0.05 mass parts defoamer, 0.3 matter
Amount part wetting agent, the modest thickening agent of 0.4 mass parts moral, 2 mass parts BCS, 22.25 mass parts water.
The preparation method of the high solid light oil-treatment agent of above-mentioned use for synthetic leather aqueouss is：By 75 mass parts aqueouss trees in formula
Fat, 0.05 mass parts defoamer, 0.3 mass parts wetting agent, the modest thickening agent of 0.4 mass parts moral, 2 mass parts BCS, 22.25 mass
The high solid light oil-treatment agent of described use for synthetic leather aqueouss is obtained final product after part water uniform stirring.The high solid light of resulting use for synthetic leather aqueouss
The performance indications of oil-treatment agent are shown in Table 1.
The methods such as the stirring employed in above-mentioned preparation process are customary way in the art.
Embodiment 2
The high solid light oil-treatment agent of use for synthetic leather aqueouss includes 78 mass parts water-base resins, 0.03 mass parts defoamer, 0.3 matter
Amount part wetting agent, the modest thickening agent of 0.27 mass parts moral, 1.4 mass parts BCS, 20 mass parts water.
The preparation method of the high solid light oil-treatment agent of above-mentioned use for synthetic leather aqueouss is：By 78 mass parts aqueouss trees in formula
Fat, 0.03 mass parts defoamer, 0.3 mass parts wetting agent, the modest thickening agent of 0.27 mass parts moral, 1.4 mass parts BCS, 20 mass
The high solid light oil-treatment agent of described use for synthetic leather aqueouss is obtained final product after part water uniform stirring.The high solid light of resulting use for synthetic leather aqueouss
The performance indications of oil-treatment agent are shown in Table 1.
The methods such as the stirring employed in above-mentioned preparation process are customary way in the art.
Embodiment 3
The high solid light oil-treatment agent of use for synthetic leather aqueouss includes 75 mass parts water-base resins, 0.02 mass parts defoamer, 0.2 matter
Amount part wetting agent, the modest thickening agent of 0.28 mass parts moral, 1.5 mass parts BCS, 23 mass parts water.
The preparation method of the high solid light oil-treatment agent of above-mentioned use for synthetic leather aqueouss is：By 75 mass parts aqueouss trees in formula
Fat, 0.02 mass parts defoamer, 0.2 mass parts wetting agent, the modest thickening agent of 0.28 mass parts moral, 1.5 mass parts BCS, 23 mass
The high solid light oil-treatment agent of described use for synthetic leather aqueouss is obtained final product after part water uniform stirring.The high solid light of resulting use for synthetic leather aqueouss
The performance indications of oil-treatment agent are shown in Table 1.
The methods such as the stirring employed in above-mentioned preparation process are customary way in the art.
Table 1
The foregoing is only presently preferred embodiments of the present invention, not for limit the present invention practical range；If do not taken off
From the spirit and scope of the present invention, the present invention is modified or equivalent, all should be covered in the claims in the present invention
In the middle of protection domain.
Claims (10)
1. a kind of use for synthetic leather aqueouss are high consolidates light oil-treatment agent, it is characterised in that comprising following components：Water-base resin, defoamer,
The modest thickening agent of wetting agent, moral, BCS and water.
2. the high solid light oil-treatment agent of use for synthetic leather aqueouss according to claim 1, it is characterised in that each component is matched somebody with somebody
Than as follows：75～80 mass parts of water-base resin, 0.02～0.05 mass parts of defoamer, 0.2～0.3 mass parts of wetting agent, moral are modest
0.2～0.4 mass parts of thickening agent, 1.5～2 mass parts of BCS, 20～25 mass parts of water.
3. the high solid light oil-treatment agent of use for synthetic leather aqueouss according to claim 2, it is characterised in that each component is matched somebody with somebody
Than as follows：75 mass parts of water-base resin, 0.05 mass parts of defoamer, 0.3 mass parts of wetting agent, modest 0.4 mass parts of thickening agent of moral,
2 mass parts of BCS, 22.25 mass parts of water.
4. the high solid light oil-treatment agent of use for synthetic leather aqueouss according to claim 2, it is characterised in that each component is matched somebody with somebody
Than as follows：78 mass parts of water-base resin, 0.03 mass parts of defoamer, 0.3 mass parts of wetting agent, modest 0.27 mass of thickening agent of moral
Part, 1.4 mass parts of BCS, 20 mass parts of water.
5. the high solid light oil-treatment agent of use for synthetic leather aqueouss according to claim 2, it is characterised in that each component is matched somebody with somebody
Than as follows：75 mass parts of water-base resin, 0.02 mass parts of defoamer, 0.2 mass parts of wetting agent, modest 0.28 mass of thickening agent of moral
Part, 1.5 mass parts of BCS, 23 mass parts of water.
6. the preparation method of the high solid light oil-treatment agent of use for synthetic leather aqueouss described in claim 1, it is characterised in that comprising following
Step：
By the water-base resin in formula, defoamer, wetting agent, the modest thickening agent of moral, BCS and water uniform stirring.
7. use for synthetic leather aqueouss height according to claim 6 consolidates the preparation method of light oil-treatment agent, it is characterised in that each group
The proportioning divided is as follows：75～80 mass parts of water-base resin, 0.02～0.05 mass parts of defoamer, 0.2～0.3 mass of wetting agent
Part, modest 0.2～0.4 mass parts of thickening agent of moral, 1.5～2 mass parts of BCS, 20～25 mass parts of water.
8. use for synthetic leather aqueouss height according to claim 7 consolidates the preparation method of light oil-treatment agent, it is characterised in that each group
The proportioning divided is as follows：75 mass parts of water-base resin, 0.05 mass parts of defoamer, 0.3 mass parts of wetting agent, the modest thickening agent of moral 0.4
Mass parts, 2 mass parts of BCS, 22.25 mass parts of water.
9. use for synthetic leather aqueouss height according to claim 7 consolidates the preparation method of light oil-treatment agent, it is characterised in that each group
The proportioning divided is as follows：78 mass parts of water-base resin, 0.03 mass parts of defoamer, 0.3 mass parts of wetting agent, the modest thickening agent of moral 0.27
Mass parts, 1.4 mass parts of BCS, 20 mass parts of water.
10. use for synthetic leather aqueouss height according to claim 7 consolidates the preparation method of light oil-treatment agent, it is characterised in that each
The proportioning of component is as follows：75 mass parts of water-base resin, 0.02 mass parts of defoamer, 0.2 mass parts of wetting agent, the modest thickening agent of moral
0.28 mass parts, 1.5 mass parts of BCS, 23 mass parts of water.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610964040.7A CN106521961A (en) | 2016-10-28 | 2016-10-28 | Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent |
| PCT/CN2017/107305 WO2018077134A1 (en) | 2016-10-28 | 2017-10-23 | Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610964040.7A CN106521961A (en) | 2016-10-28 | 2016-10-28 | Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent |
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| CN106521961A true CN106521961A (en) | 2017-03-22 |
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| CN201610964040.7A Pending CN106521961A (en) | 2016-10-28 | 2016-10-28 | Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent |
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| CN (1) | CN106521961A (en) |
| WO (1) | WO2018077134A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018077134A1 (en) * | 2016-10-28 | 2018-05-03 | 江苏宝泽高分子材料股份有限公司 | Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649547A (en) * | 2009-08-25 | 2010-02-17 | 江苏宝泽高分子材料股份有限公司 | Waterborne PU fixing gloss oil for synthetic leather |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6814882B2 (en) * | 2002-07-08 | 2004-11-09 | China Textile Institute | Fabric coating composition with latent heat effect and a method for fabricating the same |
| CN102535171A (en) * | 2011-12-08 | 2012-07-04 | 浙江深蓝轻纺科技有限公司 | Waterborne polyurethane finishing agent for matting type synthetic leather and preparation method thereof |
| CN105442323A (en) * | 2015-11-27 | 2016-03-30 | 江苏宝泽高分子材料股份有限公司 | Water-based polishing treatment agent for synthetic leather and preparation method of agent |
| CN105316947A (en) * | 2015-11-27 | 2016-02-10 | 江苏宝泽高分子材料股份有限公司 | Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof |
| CN106521961A (en) * | 2016-10-28 | 2017-03-22 | 江苏宝泽高分子材料股份有限公司 | Waterborne light-curing oil treating agent for synthetic leather and preparation method of waterborne light-curing oil treating agent |
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2016
- 2016-10-28 CN CN201610964040.7A patent/CN106521961A/en active Pending
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- 2017-10-23 WO PCT/CN2017/107305 patent/WO2018077134A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649547A (en) * | 2009-08-25 | 2010-02-17 | 江苏宝泽高分子材料股份有限公司 | Waterborne PU fixing gloss oil for synthetic leather |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018077134A1 (en) * | 2016-10-28 | 2018-05-03 | 江苏宝泽高分子材料股份有限公司 | Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent |
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| WO2018077134A1 (en) | 2018-05-03 |
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Application publication date: 20170322 |