CN106521960A - Water-based burning brightening agent used for synthetic leather, and preparation method thereof - Google Patents

Water-based burning brightening agent used for synthetic leather, and preparation method thereof Download PDF

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Publication number
CN106521960A
CN106521960A CN201610964038.XA CN201610964038A CN106521960A CN 106521960 A CN106521960 A CN 106521960A CN 201610964038 A CN201610964038 A CN 201610964038A CN 106521960 A CN106521960 A CN 106521960A
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CN
China
Prior art keywords
mass parts
water
agent
synthetic leather
aqueouss
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Pending
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CN201610964038.XA
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Chinese (zh)
Inventor
陈勇刚
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Jiangsu Baoze Polymer Materials Co Ltd
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Jiangsu Baoze Polymer Materials Co Ltd
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Publication date
Application filed by Jiangsu Baoze Polymer Materials Co Ltd filed Critical Jiangsu Baoze Polymer Materials Co Ltd
Priority to CN201610964038.XA priority Critical patent/CN106521960A/en
Publication of CN106521960A publication Critical patent/CN106521960A/en
Priority to PCT/CN2017/107315 priority patent/WO2018077136A1/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them

Abstract

The invention relates to a water-based burning brightening agent used for synthetic leather, and a preparation method thereof. The water-based burning brightening agent used for synthetic leather comprises following ingredients: a water-based resin, a water-based thickening agent, a defoaming agent, a smooth hand feeling agent, a levelling agent, BCS, and water. Intercoordination of the ingredients of the water-based burning brightening agent is realized, combined action is achieved, handfeel is unique after treatment, the synthetic leather obtained via processing with the water-based burning brightening agent is natural in gloss, clear in colour and luster, and excellent in comprehensive effect; a spraying dilute solution prepared from the water-based burning brightening agent possesses excellent storage stability, and pigment sedimentation is not easily caused.

Description

Bright ironing brightness treating agent of a kind of use for synthetic leather aqueouss and preparation method thereof
Technical field
The present invention relates to a kind of bright ironing brightness treating agent of use for synthetic leather aqueouss, is more particularly to applied to synthetic leather rear section technique The bright ironing brightness treating agent of use for synthetic leather aqueouss, while the invention also discloses the preparation side of the bright ironing brightness treating agent of use for synthetic leather aqueouss Method.
Background technology
At present, after the bright ironing brightness treating agent of existing use for synthetic leather aqueouss is processed, feel is poor.Scald bright using such aqueouss are bright The synthetic leather of inorganic agent, its gloss and color and luster after scalding bright washing are poor, while the spraying dilute solution stable storing allotted Property is poor, and pigment is easily settled.Accordingly, it would be desirable to a kind of bright ironing brightness treating agent of improved aqueouss.
The content of the invention
It is an object of the invention to provide a kind of bright ironing brightness treating agent of use for synthetic leather aqueouss.
The bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention is achieved through the following technical solutions:
The bright ironing brightness treating agent of use for synthetic leather aqueouss disclosed in this invention, comprising following components:Water-base resin, aqueouss thickening Agent, defoamer, smooth hand feeling agent, levelling agent, BCS and water.
On the basis of the gross weight of water-base resin, each component of the bright ironing brightness treating agent of use for synthetic leather aqueouss that the present invention is provided Proportioning can be:54~60 mass parts of water-base resin, 0.5~1 mass parts of water-based thickener, 0.5~1 mass parts of defoamer, 0.5~1 mass parts of smooth hand feeling agent, 0.5~1 mass parts of levelling agent, 4~5 mass parts of BCS, 35~45 mass parts of water.
In one embodiment of the invention, the proportioning of each component of the bright ironing brightness treating agent of use for synthetic leather aqueouss is as follows:Water Property 56 mass parts of resin, 1 mass parts of water-based thickener, 1 mass parts of defoamer, 1 mass parts of smooth hand feeling agent, 1 mass of levelling agent Part, 5 mass parts of BCS, 35 mass parts of water.
In another embodiment of the invention, the proportioning of each component of the bright ironing brightness treating agent of use for synthetic leather aqueouss is as follows:Water Property 59 mass parts of resin, 0.5 mass parts of water-based thickener, 0.5 mass parts of defoamer, 0.5 mass parts of smooth hand feeling agent, levelling agent 0.5 mass parts, 4 mass parts of BCS, 35 mass parts of water.
In another embodiment of the invention, the proportioning of each component of the bright ironing brightness treating agent of use for synthetic leather aqueouss is as follows:Water Property 54.5 mass parts of resin, 0.5 mass parts of water-based thickener, 0.5 mass parts of defoamer, 0.5 mass parts of smooth hand feeling agent, levelling 0.5 mass parts of agent, 4.5 mass parts of BCS, 39 mass parts of water.
The present invention also provides a kind of preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss, comprises the steps of:
Water-base resin in formula, water-based thickener, defoamer, smooth hand feeling agent, levelling agent, BCS and water are uniformly stirred Mix.
The proportioning of each component in the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention can be as follows:Water Property 54~60 mass parts of resin, 0.5~1 mass parts of water-based thickener, 0.5~1 mass parts of defoamer, smooth hand feeling agent 0.5~1 Mass parts, 0.5~1 mass parts of levelling agent, 4~5 mass parts of BCS, 35~45 mass parts of water.
Preferably, the proportioning of each component is as follows:56 mass parts of water-base resin, 1 mass parts of water-based thickener, 1 matter of defoamer Amount part, 1 mass parts of smooth hand feeling agent, 1 mass parts of levelling agent, 5 mass parts of BCS, 35 mass parts of water.
It is highly preferred that the proportioning of each component is as follows:59 mass parts of water-base resin, 0.5 mass parts of water-based thickener, defoamer 0.5 mass parts, 0.5 mass parts of smooth hand feeling agent, 0.5 mass parts of levelling agent, 4 mass parts of BCS, 35 mass parts of water.
It is highly preferred that the proportioning of each component is as follows:54.5 mass parts of water-base resin, 0.5 mass parts of water-based thickener, froth breaking 0.5 mass parts of agent, 0.5 mass parts of smooth hand feeling agent, 0.5 mass parts of levelling agent, 4.5 mass parts of BCS, 39 mass parts of water.
As using above technical scheme, the present invention is had the advantage that compared with prior art:
1. each component of the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention is mutually coordinated, collective effect, processes Feel is unique afterwards, and the leather made with this kind of inorganic agent is good through scalding gloss nature after bright washing, color clarification, resultant effect, together When the spraying dilute solution allotted have good storage stability, pigment does not allow free settling;
2. the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention replaces organic solvent as disperse medium using water New polyurethane system, as aqueous polyurethane is with water compositing dispersion medium, the course of processing without the need for organic solvent, therefore to environment without Pollution, to operator without health hazard, and aqueous polyurethane abnormal smells from the patient is little, nonflammable, and the course of processing is safe and reliable.Aqueouss Polyurethane with water as solvent, pollution-free, safe and reliable, good mechanical performance, the compatibility be good, it is easily modified the advantages of;
3. in the aqueous polyurethane system of the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention without it is poisonous- NCO group, as aqueous polyurethane is without toxic organic solvents, therefore remains without toxic solvent in product, product safety, environmental protection, No way out is limited;
4. the moisture-penetrable ventilated property of the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention is molten far better than similar Dosage form polyurethane products, because the hydrophilic of aqueous polyurethane is strong, it is strong with the binding ability of water, so its product has very Good moisture-penetrable ventilated property;
5. the water of the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention makees continuous phase so that aqueous polyurethane system Viscosity is unrelated with polyurethane resin molecular weight, and lower than solid content identical solvent borne polyurethane solution viscosity, easy to process, easily Operation;
6. in the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention, the water-based system of aqueous polyurethane can be with which Its water-based emulsion is blended or copolymerizing and blending, it is possible to decrease cost obtains the more diversified polyaminoester emulsion of performance, therefore can band Carry out the synthetic leather product of style and different properties, meet all kinds of consumer demands;Also, as solvent price is surging in recent years With environmental administration to organic solvent use and the strict restriction of waste discharge, aqueous polyurethane is made to replace solvent borne polyurethane to become One important development direction;
7. the bright ironing brightness treating agent good hand feeling of use for synthetic leather aqueouss of the present invention, soft texture, comfortably, with not Combustion, it is nontoxic, pollution-free the advantages of.By the oxygen flow gas of finished leather, poisture-penetrability, low-temperature flex resistance, Bearable dry and wet wipe, resistance to ag(e)ing Deng, with solvent borne polyurethane cover with paint, lacquer, colour wash, etc. after synthetic leather carried out comparative study.Traditional solvent-borne type is substituted using aqueous polyurethane It is excellent that polyurethane completes the performances such as the Final finishing of synthetic leather, the breathability of finished leather, poisture-penetrability, low-temperature flex resistance, Bearable dry and wet wipe In the former, whole technical process does not have solvent discharge, environmental friendliness;
8. the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention can carry out secondary research and development according to demand, with good Market using value;
9. the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention is applied on existing synthetic leather production line, technique letter It is single, it is a kind of new material of back segment process, need not change production equipment increases cost.
10. the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss of the present invention is simple, need not be using complexity Mechanical treatment, has saved production cost, is suitable to industrialized production.
Specific embodiment
Below by embodiment, technical solution of the present invention is described in detail, but protection scope of the present invention not office It is limited to the embodiment.
Embodiment 1
The bright ironing brightness treating agent of use for synthetic leather aqueouss includes 56 mass parts water-base resins, 1 mass parts water-based thickener, 1 mass Part defoamer, the smooth hand feeling agent of 1 mass parts, 1 mass parts levelling agent, 5 mass parts BCS, 35 mass parts water.
The preparation method of the bright ironing brightness treating agent of above-mentioned use for synthetic leather aqueouss is:By 56 mass parts water-base resins in formula, 1 Mass parts water-based thickener, 1 mass parts defoamer, the smooth hand feeling agent of 1 mass parts, 1 mass parts levelling agent, 5 mass parts BCS, 35 Mass parts water is sequentially added into, and obtains final product the described bright ironing brightness treating agent of use for synthetic leather aqueouss after uniform stirring.Resulting synthesis The performance indications of the bright ironing brightness treating agent of leather aqueouss are shown in Table 1.
The methods such as the stirring employed in above-mentioned preparation process are customary way in the art.
Embodiment 2
The bright ironing brightness treating agent of use for synthetic leather aqueouss includes 59 mass parts water-base resins, and 0.5 mass parts water-based thickener disappears 0.5 mass parts infusion, the smooth hand feeling agent of 0.5 mass parts, 0.5 mass parts levelling agent, 4 mass parts BCS, 35 mass parts water.
The preparation method of the bright ironing brightness treating agent of above-mentioned use for synthetic leather aqueouss is:By 59 mass parts water-base resins in formula, 0.5 mass parts water-based thickener, disappear 0.5 mass parts infusion, the smooth hand feeling agent of 0.5 mass parts, 0.5 mass parts levelling agent, 4 mass Part BCS, 35 mass parts water are sequentially added into, and obtain final product the described bright ironing brightness treating agent of use for synthetic leather aqueouss after uniform stirring.Gained To the performance indications of the bright ironing brightness treating agent of use for synthetic leather aqueouss be shown in Table 1.
The methods such as the stirring employed in above-mentioned preparation process are customary way in the art.
Embodiment 3
The bright ironing brightness treating agent of use for synthetic leather aqueouss include 54.5 mass parts water-base resins, 0.5 mass parts water-based thickener, 0.5 mass parts defoamer, 0.5 mass parts, smooth hand feeling agent, 0.5 mass parts levelling agent, 4.5 mass parts BCS, 39 mass parts water.
The preparation method of the bright ironing brightness treating agent of above-mentioned use for synthetic leather aqueouss is:By 54.5 mass parts aqueouss trees in formula Fat, 0.5 mass parts water-based thickener, 0.5 mass parts defoamer, 0.5 mass parts, smooth hand feeling agent, 0.5 mass parts levelling agent, 4.5 mass parts BCS, 39 mass parts water are sequentially added into, and obtain final product the bright boiling hot bright process of described use for synthetic leather aqueouss after uniform stirring Agent.The performance indications of the resulting bright ironing brightness treating agent of use for synthetic leather aqueouss are shown in Table 1.
The methods such as the stirring employed in above-mentioned preparation process are customary way in the art.
Table 1
The foregoing is only presently preferred embodiments of the present invention, not for limit the present invention practical range;If do not taken off From the spirit and scope of the present invention, the present invention is modified or equivalent, all should be covered in the claims in the present invention In the middle of protection domain.

Claims (10)

1. the bright ironing brightness treating agent of a kind of use for synthetic leather aqueouss, it is characterised in that comprising following components:Water-base resin, aqueouss thickening Agent, defoamer, smooth hand feeling agent, levelling agent, BCS and water.
2. the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 1, it is characterised in that the proportioning of each component It is as follows:54~60 mass parts of water-base resin, 0.5~1 mass parts of water-based thickener, 0.5~1 mass parts of defoamer, smooth feel 0.5~1 mass parts of agent, 0.5~1 mass parts of levelling agent, BCS4~5 mass parts, 35~45 mass parts of water.
3. the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 2, it is characterised in that the proportioning of each component It is as follows:56 mass parts of water-base resin, 1 mass parts of water-based thickener, 1 mass parts of defoamer, 1 mass parts of smooth hand feeling agent, levelling 1 mass parts of agent, 5 mass parts of BCS, 35 mass parts of water.
4. the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 2, it is characterised in that the proportioning of each component It is as follows:59 mass parts of water-base resin, 0.5 mass parts of water-based thickener, 0.5 mass parts of defoamer, 0.5 mass of smooth hand feeling agent Part, 0.5 mass parts of levelling agent, 4 mass parts of BCS, 35 mass parts of water.
5. the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 2, it is characterised in that the proportioning of each component It is as follows:54.5 mass parts of water-base resin, 0.5 mass parts of water-based thickener, 0.5 mass parts of defoamer, 0.5 mass of smooth hand feeling agent Part, 0.5 mass parts of levelling agent, 4.5 mass parts of BCS, 39 mass parts of water.
6. the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss described in claim 1, it is characterised in that comprising following step Suddenly:
By the water-base resin in formula, water-based thickener, defoamer, smooth hand feeling agent, levelling agent, BCS and water uniform stirring.
7. the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 6, it is characterised in that each component Proportioning it is as follows:54~60 mass parts of water-base resin, 0.5~1 mass parts of water-based thickener, 0.5~1 mass parts of defoamer are sliding 0.5~1 mass parts of refreshing hand feeling agent, 0.5~1 mass parts of levelling agent, 4~5 mass parts of BCS, 35~45 mass parts of water.
8. the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 7, it is characterised in that each component Proportioning it is as follows:56 mass parts of water-base resin, 1 mass parts of water-based thickener, 1 mass parts of defoamer, 1 mass of smooth hand feeling agent Part, 1 mass parts of levelling agent, 5 mass parts of BCS, 35 mass parts of water.
9. the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 7, it is characterised in that each component Proportioning it is as follows:59 mass parts of water-base resin, 0.5 mass parts of water-based thickener, 0.5 mass parts of defoamer, smooth hand feeling agent 0.5 Mass parts, 0.5 mass parts of levelling agent, BCS4 mass parts, 35 mass parts of water.
10. the preparation method of the bright ironing brightness treating agent of use for synthetic leather aqueouss according to claim 7, it is characterised in that each group The proportioning divided is as follows:54.5 mass parts of water-base resin, 0.5 mass parts of water-based thickener, 0.5 mass parts of defoamer, smooth feel 0.5 mass parts of agent, 0.5 mass parts of levelling agent, 4.5 mass parts of BCS, 39 mass parts of water.
CN201610964038.XA 2016-10-28 2016-10-28 Water-based burning brightening agent used for synthetic leather, and preparation method thereof Pending CN106521960A (en)

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PCT/CN2017/107315 WO2018077136A1 (en) 2016-10-28 2017-10-23 Aqueous bright lustering treatment agent for synthetic leather and preparation method for same

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Publication number Priority date Publication date Assignee Title
WO2018077136A1 (en) * 2016-10-28 2018-05-03 江苏宝泽高分子材料股份有限公司 Aqueous bright lustering treatment agent for synthetic leather and preparation method for same

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