CN105316947A - Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof - Google Patents
Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof Download PDFInfo
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- CN105316947A CN105316947A CN201510845509.0A CN201510845509A CN105316947A CN 105316947 A CN105316947 A CN 105316947A CN 201510845509 A CN201510845509 A CN 201510845509A CN 105316947 A CN105316947 A CN 105316947A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
Abstract
The invention relates to a water-based super-fogging super-blackening treating agent for synthetic leather, and the water-based super-fogging super-blackening treating agent is applied to a later period technology of the synthetic leather. The water-based super-fogging super-blackening treating agent is prepared from water-based resin, a water-based dispersing agent, a defoaming agent, silicon dioxide matting powder, a wetting agent, a Deuchem thickening agent and water. The invention further relates to a preparation method of the water-based super-fogging super-blackening treating agent for the synthetic leather. According to the water-based super-fogging super-blackening treating agent, all the components cooperate with one another and interact with one another, the synthetic leather is unique in handfeel after being treated, and the synthetic leather treated by the treating agent is natural in gloss, clear in color and luster, better in color developing and excellent in comprehensive effect, meanwhile, a prepared spraying dilute solution has the very good storage stability, and pigments are not prone to sedimentation. The water-based super-fogging super-blackening treating agent for the synthetic leather is a novel material in later period treatment and can be applied to an existing synthetic leather production line, the technology is simple, production equipment does not need to be changed, and the production cost cannot be increased.
Description
Technical field
The present invention relates to use for synthetic leather surface conditioning agent field, particularly, relate to a kind of goth black finishing agent of the special mist of use for synthetic leather water-based for the synthesis of leather last part technology, the present invention relates to the preparation method of the goth black finishing agent of the special mist of this use for synthetic leather water-based simultaneously.
Background technology
Synthetic leather surface conditioning agent can carry out top finishing according to the classification of product, and it can improve the brightness of synthetic leather, color and luster and feel.But, along with consumer requires more and more higher to the color and luster of leather surface and feel, not only to increase the sense of touch of synthetic leather, also will ensure the brightness on synthetic leather surface and color etc.And existing surface conditioning agent can not meet the requirement that consumer increases day by day to the brightness of synthetic leather and feel, be therefore badly in need of one and can have improved synthetic leather sense of touch, the feel of synthetic leather can have been improved again, the finishing agent of the resultant effect such as brightness, gloss.
Summary of the invention
In order to solve the problem and defect, the object of this invention is to provide the goth black finishing agent of the special mist of a kind of use for synthetic leather water-based.The present invention also provides the preparation method of the goth black finishing agent of the special mist of this use for synthetic leather water-based.
The goth black finishing agent of the special mist of use for synthetic leather water-based of the present invention is achieved through the following technical solutions:
The goth black finishing agent of the special mist of a kind of use for synthetic leather water-based, it, for the synthesis of the last part technology of leather, comprises following component: water-base resin, aqueous dispersion, defoamer, silica flatting silica, wetting agent, the modest thickener of moral, water.
Further, the proportioning of described each component is as follows: water-base resin 26-30 weight portion, aqueous dispersion 0.2-1 weight portion, defoamer 0.2-1 weight portion, silica flatting silica 4-8 weight portion, wetting agent 0.2-1 weight portion, moral modest thickener 1-2 weight portion, water 55-60 weight portion.
Further, the proportioning of described each component is as follows: water-base resin 28-30 weight portion, aqueous dispersion 0.5-1 weight portion, defoamer 0.5-1 weight portion, silica flatting silica 6-8 weight portion, wetting agent 0.5-1 weight portion, moral modest thickener 1-2 weight portion, water 58-60 weight portion.
Further, the proportioning of described each component is as follows: water-base resin 30 weight portion, aqueous dispersion 1 weight portion, defoamer 0.5 weight portion, silica flatting silica 6 weight portion, wetting agent 0.5 weight portion, moral modest thickener 2 weight portion, water 60 weight portion.
The present invention also provides the preparation method of the goth black finishing agent of the special mist of a kind of use for synthetic leather water-based, comprises following steps:
1) take each component materials by weight ratio, by water-base resin, aqueous dispersion, defoamer, silica flatting silica, wetting agent, the modest thickener of moral and water mixing, stir, and obtains the goth black finishing agent of the special mist of described use for synthetic leather water-based.
Further, the proportioning of each component is as follows: water-base resin 26-30 weight portion, aqueous dispersion 0.2-1 weight portion, defoamer 0.2-1 weight portion, silica flatting silica 4-8 weight portion, wetting agent 0.2-1 weight portion, moral modest thickener 1-2 weight portion, water 55-60 weight portion.
Further, carry out all at normal temperatures and pressures in steps.
Owing to adopting above technical scheme, the present invention compared with prior art has following Advantageous Effects:
(1) the goth black finishing agent of the special mist of water-based of the present invention is the new polyurethane system using water to replace organic solvent as decentralized medium, because aqueous polyurethane is with water compositing dispersion medium, process is without the need to organic solvent, therefore environmentally safe, to operating personnel without health hazard, and aqueous polyurethane smell is little, nonflammable, and process is safe and reliable.Aqueous polyurethane take water as solvent, pollution-free, safe and reliable, good mechanical performance, compatibility are good, be easy to the advantages such as modification;
(2) each component of the goth black finishing agent of the special mist of water-based of the present invention mutually coordinate, acting in conjunction, after process, feel is unique, the leather gloss nature made with this kind of finishing agent, color clarification, color development is good, resultant effect is excellent, and the spraying dilute solution simultaneously allotted has good storage stability, and pigment is not easy sedimentation;
(3) the goth black finishing agent of the special mist of water-based of the present invention is high temperature resistant, and can be used for pre-treatment, applied widely, resultant effect is good;
(4) do not contain poisonous-NCO group in aqueous polyurethane system, because aqueous polyurethane is without toxic organic solvents, therefore remain without toxic solvent in product, product safety, environmental protection, No way out limits;
(5) the moisture-inhibiting steam permeability of aqueous polyurethane product will be better than similar solvent borne polyurethane product far away, because the hydrophily of aqueous polyurethane is strong, therefore strong with the binding ability of water, so its product has good moisture-inhibiting steam permeability;
(6) water makes continuous phase, and aqueous polyurethane system viscosity and polyurethane resin molecular weight are had nothing to do, and the solvent borne polyurethane solution viscosity more identical than solid content is low, easy to process, easy to operate;
(7) water-based system of aqueous polyurethane can blended or copolymerizing and blending or copolymerization with other water-based emulsion, can reduce costs or obtain the more diversified polyaminoester emulsion of performance, therefore can bring the synthetic leather product of style and different properties, meet all kinds of consumer demand; Further, because solvent price is in recent years surging and environmental administration uses organic solvent and the strict restriction of waste discharge, making aqueous polyurethane replace solvent borne polyurethane becomes an important development direction;
(8) use the finished product good hand feeling that the goth black finishing agent of the special mist of water-based of the present invention is made, quality is soft, comfortable, has advantages such as not firing, nontoxic, pollution-free.By the oxygen flow gas, poisture-penetrability, low-temperature flex resistance, Bearable dry and wet wipe, resistance to ag(e)ing etc. of finished leather, the synthetic leather after covering with paint, lacquer, colour wash, etc. with solvent borne polyurethane has carried out comparative study.Adopt aqueous polyurethane to substitute the Final finishing that traditional solvent borne polyurethane completes synthetic leather, the performance such as gas permeability, poisture-penetrability, low-temperature flex resistance, Bearable dry and wet wipe of finished leather is all better than the former, and whole technical process does not have solvent discharge, environmental friendliness;
(9) the goth black finishing agent of the special mist of use for synthetic leather water-based of the present invention is a kind of new material of back segment process, can be used in existing synthetic leather production line, and technique is simple, without the need to changing production equipment, can not increase production cost.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
embodiment 1
The goth black finishing agent of the special mist of use for synthetic leather water-based is made up of the component of following proportioning: water-base resin 26 weight portion, aqueous dispersion 0.2 weight portion, defoamer 0.2 weight portion, silica flatting silica 4 weight portion, wetting agent 0.2 weight portion, moral modest thickener 1 weight portion, water 55 weight portion.
The preparation method of the goth black finishing agent of the special mist of above-mentioned use for synthetic leather water-based is: at normal temperatures and pressures, by the water-base resin of 26 weight portions, the aqueous dispersion of 0.2 weight portion, the defoamer of 0.2 weight portion, the silica flatting silica of 4 weight portions, the wetting agent of 0.2 weight portion, the modest thickener of moral of 1 weight portion, mix with the water of 55 weight portions, stir after within least 30 minutes, mixing to mixture, obtain the goth black finishing agent of the special mist of described use for synthetic leather water-based.The performance indications of the goth black finishing agent of the special mist of the use for synthetic leather water-based obtained are in table 1.
The methods such as the stirring adopted in above-mentioned preparation process are customary way in this area.
embodiment 2
The goth black finishing agent of the special mist of use for synthetic leather water-based is made up of the component of following proportioning: water-base resin 27 weight portion, aqueous dispersion 0.4 weight portion, defoamer 0.3 weight portion, silica flatting silica 5 weight portion, wetting agent 0.4 weight portion, moral modest thickener 1.5 weight portion, water 56 weight portion.
The preparation method of the goth black finishing agent of the special mist of above-mentioned use for synthetic leather water-based is: at normal temperatures and pressures, by the water-base resin of 27 weight portions, the aqueous dispersion of 0.4 weight portion, the defoamer of 0.3 weight portion, the silica flatting silica of 5 weight portions, the wetting agent of 0.4 weight portion, the modest thickener of moral of 1.5 weight portions, mix with the water of 56 weight portions, stir after within least 30 minutes, mixing to mixture, obtain the goth black finishing agent of the special mist of described use for synthetic leather water-based.The performance indications of the goth black finishing agent of the special mist of the use for synthetic leather water-based obtained are in table 1.
The methods such as the stirring adopted in above-mentioned preparation process are customary way in this area.
embodiment 3
The goth black finishing agent of the special mist of use for synthetic leather water-based is made up of the component of following proportioning: water-base resin 28 weight portion, aqueous dispersion 0.5 weight portion, defoamer 0.5 weight portion, silica flatting silica 6 weight portion, wetting agent 0.5 weight portion, moral modest thickener 1 weight portion, water 57 weight portion.
The preparation method of the goth black finishing agent of the special mist of above-mentioned use for synthetic leather water-based is: at normal temperatures and pressures, by the water-base resin of 28 weight portions, the aqueous dispersion of 0.5 weight portion, the defoamer of 0.5 weight portion, the silica flatting silica of 6 weight portions, the wetting agent of 0.5 weight portion, the modest thickener of moral of 1 weight portion, mix with the water of 57 weight portions, stir after within least 30 minutes, mixing to mixture, obtain the goth black finishing agent of the special mist of described use for synthetic leather water-based.The performance indications of the goth black finishing agent of the special mist of the use for synthetic leather water-based obtained are in table 1.
The methods such as the stirring adopted in above-mentioned preparation process are customary way in this area.
embodiment 4
The goth black finishing agent of the special mist of use for synthetic leather water-based is made up of the component of following proportioning: water-base resin 29 weight portion, aqueous dispersion 0.8 weight portion, defoamer 0.8 weight portion, silica flatting silica 7 weight portion, wetting agent 0.8 weight portion, moral modest thickener 2 weight portion, water 59 weight portion.
The preparation method of the goth black finishing agent of the special mist of above-mentioned use for synthetic leather water-based is: at normal temperatures and pressures, by the water-base resin of 29 weight portions, the aqueous dispersion of 0.8 weight portion, the defoamer of 0.8 weight portion, the silica flatting silica of 7 weight portions, the wetting agent of 0.8 weight portion, the modest thickener of moral of 2 weight portions, mix with the water of 59 weight portions, stir after within least 30 minutes, mixing to mixture, obtain the goth black finishing agent of the special mist of described use for synthetic leather water-based.The performance indications of the goth black finishing agent of the special mist of the use for synthetic leather water-based obtained are in table 1.
The methods such as the stirring adopted in above-mentioned preparation process are customary way in this area.
embodiment 5
The goth black finishing agent of the special mist of use for synthetic leather water-based is made up of the component of following proportioning: water-base resin 30 weight portion, aqueous dispersion 1 weight portion, defoamer 0.5 weight portion, silica flatting silica 6 weight portion, wetting agent 0.5 weight portion, moral modest thickener 2 weight portion, water 60 weight portion.
The preparation method of the goth black finishing agent of the special mist of above-mentioned use for synthetic leather water-based is: at normal temperatures and pressures, by the water-base resin of 30 weight portions, the aqueous dispersion of 1 weight portion, the defoamer of 0.5 weight portion, the silica flatting silica of 6 weight portions, the wetting agent of 0.5 weight portion, the modest thickener of moral of 2 weight portions, mix with the water of 60 weight portions, stir after within least 30 minutes, mixing to mixture, obtain the goth black finishing agent of the special mist of described use for synthetic leather water-based.The performance indications of the goth black finishing agent of the special mist of the use for synthetic leather water-based obtained are in table 1.
The methods such as the stirring adopted in above-mentioned preparation process are customary way in this area.
Table 1
The foregoing is only preferred embodiment of the present invention, be not used for limiting practical range of the present invention; If do not depart from the spirit and scope of the present invention, the present invention is modified or equivalent to replace, in the middle of the protection domain that all should be encompassed in the claims in the present invention.
Claims (7)
1. the goth black finishing agent of the special mist of use for synthetic leather water-based, it, for the synthesis of the last part technology of leather, is characterized in that, comprise following component: water-base resin, aqueous dispersion, defoamer, silica flatting silica, wetting agent, the modest thickener of moral, water.
2. the goth black finishing agent of the special mist of use for synthetic leather water-based according to claim 1, it is characterized in that, the proportioning of described each component is as follows: water-base resin 26-30 weight portion, aqueous dispersion 0.2-1 weight portion, defoamer 0.2-1 weight portion, silica flatting silica 4-8 weight portion, wetting agent 0.2-1 weight portion, moral modest thickener 1-2 weight portion, water 55-60 weight portion.
3. the goth black finishing agent of the special mist of use for synthetic leather water-based according to claim 2, it is characterized in that, the proportioning of described each component is as follows: water-base resin 28-30 weight portion, aqueous dispersion 0.5-1 weight portion, defoamer 0.5-1 weight portion, silica flatting silica 6-8 weight portion, wetting agent 0.5-1 weight portion, moral modest thickener 1-2 weight portion, water 58-60 weight portion.
4. the goth black finishing agent of the special mist of the use for synthetic leather water-based according to Claims 2 or 3, it is characterized in that, the proportioning of described each component is as follows: water-base resin 30 weight portion, aqueous dispersion 1 weight portion, defoamer 0.5 weight portion, silica flatting silica 6 weight portion, wetting agent 0.5 weight portion, moral modest thickener 2 weight portion, water 60 weight portion.
5. a preparation method for the goth black finishing agent of the special mist of the use for synthetic leather water-based described in the claims, is characterized in that, comprise following steps:
Take each component materials by weight ratio, by water-base resin, aqueous dispersion, defoamer, silica flatting silica, wetting agent, the modest thickener of moral and water mixing, stir, and obtains the goth black finishing agent of the special mist of described use for synthetic leather water-based.
6. the preparation method of the goth black finishing agent of the special mist of use for synthetic leather water-based according to claim 5, it is characterized in that, the proportioning of each component is as follows: water-base resin 26-30 weight portion, aqueous dispersion 0.2-1 weight portion, defoamer 0.2-1 weight portion, silica flatting silica 4-8 weight portion, wetting agent 0.2-1 weight portion, moral modest thickener 1-2 weight portion, water 55-60 weight portion.
7. the preparation method of the goth black finishing agent of the special mist of use for synthetic leather water-based according to claim 5, is characterized in that, institute carries out in steps all at normal temperatures and pressures.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510845509.0A CN105316947A (en) | 2015-11-27 | 2015-11-27 | Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof |
| PCT/CN2015/000853 WO2017088085A1 (en) | 2015-11-27 | 2015-12-04 | Aqueous ultra-misty ultra-black treatment agent for synthetic leather and preparation method for same |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510845509.0A CN105316947A (en) | 2015-11-27 | 2015-11-27 | Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof |
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| CN105316947A true CN105316947A (en) | 2016-02-10 |
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| CN201510845509.0A Pending CN105316947A (en) | 2015-11-27 | 2015-11-27 | Water-based super-fogging super-blackening treating agent for synthetic leather and preparation method thereof |
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| WO (1) | WO2017088085A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106367973A (en) * | 2016-10-28 | 2017-02-01 | 江苏宝泽高分子材料股份有限公司 | Water-borne skin-touch lustering material treating agent for synthetic leather and preparing method thereof |
| CN106367972A (en) * | 2016-10-28 | 2017-02-01 | 江苏宝泽高分子材料股份有限公司 | Water-based brilliant black fog burning and brightening treatment agent for synthetic leather and preparation method thereof |
| CN106498747A (en) * | 2016-10-27 | 2017-03-15 | 江苏宝泽高分子材料股份有限公司 | Goth black inorganic agent of the special mist of a kind of use for synthetic leather and preparation method thereof |
| CN107326680A (en) * | 2017-08-18 | 2017-11-07 | 江苏宝泽高分子材料股份有限公司 | A kind of aqueous super black and misty inorganic agent of heat-resistance type and preparation method thereof |
| CN107460731A (en) * | 2017-08-18 | 2017-12-12 | 江苏宝泽高分子材料股份有限公司 | One kind is water-based to burn inorganic agent and preparation method thereof |
| CN107460730A (en) * | 2017-08-18 | 2017-12-12 | 江苏宝泽高分子材料股份有限公司 | One kind is without water-based carbon black treatment agent of colour migration and preparation method thereof |
| WO2018077134A1 (en) * | 2016-10-28 | 2018-05-03 | 江苏宝泽高分子材料股份有限公司 | Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent |
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| CN113249988A (en) * | 2021-05-25 | 2021-08-13 | 段永进 | Leather printed product and preparation method thereof |
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| CN103966854A (en) * | 2014-05-08 | 2014-08-06 | 合肥市科天化工有限公司 | Metallic fog-brightening water based treatment agent and preparation method thereof |
| CN104074056A (en) * | 2014-07-03 | 2014-10-01 | 江苏宝泽高分子材料股份有限公司 | Special mist and black treatment agent for synthetic leather and preparation method of special mist and black treatment agent |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498747A (en) * | 2016-10-27 | 2017-03-15 | 江苏宝泽高分子材料股份有限公司 | Goth black inorganic agent of the special mist of a kind of use for synthetic leather and preparation method thereof |
| CN106367973A (en) * | 2016-10-28 | 2017-02-01 | 江苏宝泽高分子材料股份有限公司 | Water-borne skin-touch lustering material treating agent for synthetic leather and preparing method thereof |
| CN106367972A (en) * | 2016-10-28 | 2017-02-01 | 江苏宝泽高分子材料股份有限公司 | Water-based brilliant black fog burning and brightening treatment agent for synthetic leather and preparation method thereof |
| WO2018077133A1 (en) * | 2016-10-28 | 2018-05-03 | 江苏宝泽高分子材料股份有限公司 | Water-based bright black matte glossing treatment agent for synthetic leather and preparation method for agent |
| WO2018077135A1 (en) * | 2016-10-28 | 2018-05-03 | 江苏宝泽高分子材料股份有限公司 | Aqueous skin-touch lustering material treating agent for synthetic leather and preparation method therefor |
| WO2018077134A1 (en) * | 2016-10-28 | 2018-05-03 | 江苏宝泽高分子材料股份有限公司 | Water-based high gloss-setting oil treatment agent for synthetic leather and preparation method for agent |
| CN107326680A (en) * | 2017-08-18 | 2017-11-07 | 江苏宝泽高分子材料股份有限公司 | A kind of aqueous super black and misty inorganic agent of heat-resistance type and preparation method thereof |
| CN107460731A (en) * | 2017-08-18 | 2017-12-12 | 江苏宝泽高分子材料股份有限公司 | One kind is water-based to burn inorganic agent and preparation method thereof |
| CN107460730A (en) * | 2017-08-18 | 2017-12-12 | 江苏宝泽高分子材料股份有限公司 | One kind is without water-based carbon black treatment agent of colour migration and preparation method thereof |
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| WO2017088085A1 (en) | 2017-06-01 |
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Application publication date: 20160210 |