CN113249988A - Leather printed product and preparation method thereof - Google Patents
Leather printed product and preparation method thereof Download PDFInfo
- Publication number
- CN113249988A CN113249988A CN202110569060.5A CN202110569060A CN113249988A CN 113249988 A CN113249988 A CN 113249988A CN 202110569060 A CN202110569060 A CN 202110569060A CN 113249988 A CN113249988 A CN 113249988A
- Authority
- CN
- China
- Prior art keywords
- leather
- printed
- printing
- preparing
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
- C14C11/006—Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
Abstract
The invention relates to a genuine leather printed product and a preparation method thereof. The preparation method comprises the following steps: (1) selecting finished leather (cow leather, sheep leather, pigskin or horse leather) of genuine leather for surface pretreatment to obtain pretreated leather; (2) preparing water-based color paste, and printing the water-based color paste on the surface of the pretreated leather to obtain printed leather; (3) and drying the printed leather, and fixing the color to obtain the leather printed product. The preparation method solves the existing problems that the printing of the genuine leather is faded, the dry and wet rubbing resistance is poor, the printing material is not environment-friendly, the hand feeling of the printing finished product is poor, the air permeability of the genuine leather is influenced, the cost of the printing material is high, and the printing paste is easy to crack after long-term use. The quality of the leather printing finished product can be effectively improved, and the leather product has more colorful colors and more fashionable design.
Description
Technical Field
The invention belongs to the field of leather, and particularly relates to a leather printed product and a preparation method thereof.
Background
The dermis is composed mainly of connective tissues such as collagen fibers, elastic fibers, reticular fibers, amorphous matrix and the like. Therefore, the leather has the characteristics of natural and smooth surface, comfortable air permeability, fine and plump texture, soft and moist hand feeling and high elasticity. This is also an advantage compared to artificial leather. In recent years, with the improvement of living standard of people, the requirements on quality and individuality of substances are higher and higher, and the existing genuine leather products are limited by single color and insufficient innovation and are gradually far away from the field of vision of the public. Although various methods for printing leather have been developed, most of the printing methods have various drawbacks and problems due to the characteristics of the leather, and even some techniques cannot be applied to printing of leather products.
Specifically, the thermal transfer leather printing is to prepare ink by hot melt adhesive, print the ink on paper or a film, and transfer the ink to the surface of leather under the condition of hot pressing, but the thermal transfer leather printing has the defects that the thermal transfer leather printing is not easy to be used on leather, the leather is shrunk, deformed and hardened at the high temperature of the hot pressing, the hand feeling of the leather and the specific air permeability of the leather are influenced, and meanwhile, the material of the sol ink is not environment-friendly; the UV digital ink-jet leather printing is to process patterns by a computer and print patterns on leather by a professional printer and a professional color paste, but the printing speed of the technology is low, the cost of the machine and the special color paste is too high, the color accuracy is not high, a film is still coated and primed before printing, the specific air permeability of leather is influenced, and the problem of drying crack of the printing color paste is caused after long-time use and storage; the leather dye printing is similar to the textile printing method, but the leather dye printing has the problems of no high temperature steaming resistance and no high temperature washing resistance on the surface of the leather.
Therefore, the technical scheme of the invention is provided.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a genuine leather printed product and a preparation method thereof. The preparation method solves the existing problems that the printing of the genuine leather is faded, the dry and wet rubbing resistance is poor, the printing material is not environment-friendly, the hand feeling of the printing finished product is poor, the air permeability of the genuine leather is influenced, the cost of the printing material is high, and the printing paste is easy to crack after long-term use. The quality of the leather printing finished product can be effectively improved, and the leather product has more colorful colors and more fashionable design.
The invention aims to provide a preparation method of a genuine leather printed product, which comprises the following steps:
(1) selecting finished leather of genuine leather to carry out surface pretreatment to obtain pretreated leather;
(2) preparing water-based color paste, and printing the water-based color paste on the surface of the pretreated leather to obtain printed leather;
(3) and drying the printed leather, and fixing the color to obtain the leather printed product.
In particular, in summary, the steps include: selecting leather, surface treatment, preparing color paste, making patterns, printing leather surface, cleaning printing plates, naturally airing (or drying), and fixing color to obtain a finished product.
Preferably, in the step (1), the finished leather product is cow leather, sheep leather, pig leather or horse leather;
preferably, in the step (1), the pretreatment is a surface finishing treatment of finished leather.
Preferably, in the step (2), the aqueous color paste is specially-made aqueous color paste special for printing.
Preferably, the aqueous color paste comprises the following raw materials in parts by weight: 20 parts of pigment, 1-3 parts of wetting dispersant, 1-2 parts of anti-settling agent defoamer, 20 parts of resin and 55 parts of deionized water.
Preferably, in the step (2), the printing method is screen printing.
Preferably, in the step (3), the drying is natural drying or drying by drying.
Preferably, in step (3), the fixation is surface-treated with a fixing agent.
Preferably, in the step (3), the fixing temperature is natural drying or drying below 80 ℃.
Based on the same technical concept, the invention provides the leather printed product prepared by the method.
The invention has the beneficial effects that:
the preparation method of the genuine leather printed product comprises the steps of selecting genuine leather, pretreating the genuine leather, manufacturing printed patterns into a silk screen printing plate, selecting water-based color paste, performing silk screen printing on the surface of the genuine leather, drying the genuine leather at normal temperature, and finally fixing the color by heating at medium and low temperatures to prepare the finished product. The leather is treated before and after, so that the problem that the coating is not dry-wet-wiping resistant is solved, the quality of a finished product is greatly improved, the coating of the water-based color paste keeps the attribute of the original real leather, and the hand feeling and the air permeability are not damaged; in addition, the water-based color paste solves the problem that solvent-based ink is not environment-friendly, is beneficial to the health of operators, and can meet the individual requirements of different audience groups due to the flexibility of screen printing.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
Example 1
The embodiment provides a preparation method of a genuine leather printed product, which comprises the following steps:
(1) selecting a real cowhide finished product for surface pretreatment, and specifically: firstly, carrying out the damage treatment on a cowhide blank to ensure that the surface of the cowhide blank is smooth; secondly, coating the processed leather blank, wherein the main coating materials are pigment paste, acrylic resin and polyurethane resin, and the coating auxiliary agent and water are uniformly stirred according to the conventional proportion and sprayed for 2 times; thirdly, drying and ironing the coated cowhide; obtaining pretreated leather;
(2) according to the pattern requirements, preparing water-based color pastes with different colors, wherein the water-based color pastes comprise the following components in percentage by weight: 20g of pigment, 1g of wetting dispersant, 1g of anti-precipitation defoaming agent, 20g of resin and 55g of deionized water;
(3) making a pattern to be printed into a board, and treating the pretreated leather by using water-based color paste according to a screen printing process to obtain printed leather;
(4) cleaning a printing plate in time, drying the printed leather, and fixing color under a natural drying condition; and obtaining a finished product of the genuine leather printing.
Example 2
The embodiment provides a preparation method of a genuine leather printed product, which comprises the following steps:
(1) selecting a real sheepskin finished product for surface pretreatment, and specifically comprising the following steps: firstly, carrying out the damage treatment on a cowhide blank to ensure that the surface of the cowhide blank is smooth; secondly, coating the processed leather blank, wherein the main coating materials are pigment paste, acrylic resin and polyurethane resin, and the coating auxiliary agent and water are uniformly stirred according to the conventional proportion and sprayed for 3 times; thirdly, drying and ironing the coated sheepskin; obtaining pretreated leather;
(2) according to the pattern requirements, preparing water-based color pastes with different colors, wherein the water-based color pastes comprise the following components in percentage by weight: 20g of pigment, 3g of wetting dispersant, 2g of anti-precipitation defoaming agent, 20g of resin and 55g of deionized water;
(3) making a pattern to be printed into a board, and treating the pretreated leather by using water-based color paste according to a screen printing process to obtain printed leather;
(4) cleaning a printing plate in time, drying the printed leather, and fixing color at 60 ℃; and obtaining a finished product of the genuine leather printing.
Example 3
The embodiment provides a preparation method of a genuine leather printed product, which comprises the following steps:
(1) selecting a real pigskin finished product for surface pretreatment, and specifically comprising the following steps: firstly, carrying out the damage treatment on a cowhide blank to ensure that the surface of the cowhide blank is smooth; secondly, coating the processed leather blank, wherein the main coating materials are pigment paste, acrylic resin and polyurethane resin, and the coating auxiliary agent and water are uniformly stirred according to the conventional proportion and sprayed for 3 times; thirdly, drying and ironing the coated pigskin; obtaining pretreated leather;
(2) according to the pattern requirements, preparing water-based color pastes with different colors, wherein the water-based color pastes comprise the following components in percentage by weight: 20g of pigment, 3g of wetting dispersant, 2g of anti-precipitation defoaming agent, 20g of resin and 55g of deionized water;
(3) making a pattern to be printed into a board, and treating the pretreated leather by using water-based color paste according to a screen printing process to obtain printed leather;
(4) cleaning a printing plate in time, drying the printed leather, and fixing color at 80 ℃; and obtaining a finished product of the genuine leather printing.
In order to verify the color fastness and the hand feeling performance of the genuine leather printed product, the same type of products (comparative examples) sold in the market are selected for comprehensive verification.
Wherein the color fastness comprises light fastness, washing fastness and rubbing fastness; hand properties include softness and smoothness properties.
The test of the light fastness adopts an SZl500 type xenon arc lamp as a radiation source, the range of visible light emitted by the xenon arc lamp is 380-750 nm, the range of ultraviolet light is 300-380 nm, the xenon arc lamp is very similar to sunlight, and the radiation source is equivalent to the result of sunlight measurement.
The washing fastness is tested by a Gelloven double-cylinder washing color fastness tester.
The crockfastness was measured using a Y571FA crockfastness apparatus manufactured by Square and round instruments.
Hand feel properties (softness and smoothness properties) were tested using an intelligent stylizer, Nucybertek Phabrometer.
The results are shown in Table 1.
TABLE 1 test results
| Detecting items | Example 1 | Example 2 | Example 3 | Comparative example |
| Light fastness/grade | 7.0 | 7.5 | 7.5 | 5.5 |
| Washing fastness/grade | 4.5 | 4.0 | 4.5 | 3.5 |
| Crockfastness/grade | 4.5 | 4.5 | 4.0 | 3.0 |
| Softness | 9.887 | 9.741 | 9.603 | 8.014 |
| Smoothing | 10.758 | 10.327 | 10.116 | 8.756 |
The detection result shows that the leather printed product obtained by the invention is superior to the similar products sold in the aspects of light fastness, washing fastness, rubbing fastness, softness and smoothness, and reaches a better level.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (10)
1. The preparation method of the genuine leather printed product is characterized by comprising the following steps:
(1) selecting finished leather of genuine leather to carry out surface pretreatment to obtain pretreated leather;
(2) preparing water-based color paste, and printing the water-based color paste on the surface of the pretreated leather to obtain printed leather;
(3) and drying the printed leather, and fixing the color to obtain the leather printed product.
2. The method for preparing a dermal printed product according to claim 1, wherein in the step (1), the finished leather is cow leather, sheep leather, pig leather or horse leather.
3. A method for preparing a printed leather product according to claim 1, wherein the pretreatment in step (1) is a finishing treatment of the surface of finished leather.
4. The method for preparing a dermal printed product according to claim 1, wherein in the step (2), the aqueous color paste is a printing-dedicated aqueous color paste.
5. The preparation method of the dermal printed matter of claim 4, wherein the aqueous color paste comprises the following raw materials in parts by weight: 20 parts of pigment, 1-3 parts of wetting dispersant, 1-2 parts of anti-settling agent defoamer, 20 parts of resin and 55 parts of deionized water.
6. A method for preparing a dermal printed product according to claim 1, wherein the printing method in the step (2) is screen printing.
7. A method for preparing a printed leather product according to claim 1, wherein the drying in step (3) is natural drying or oven drying.
8. A method for preparing a printed leather as defined in claim 1, wherein in the step (3), the fixing is performed by surface treatment with a fixing agent.
9. A method for preparing a printed leather product according to claim 1, wherein in the step (3), the fixing temperature is natural drying or drying below 80 ℃.
10. A printed dermal product produced by the method according to any one of claims 1 to 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110569060.5A CN113249988A (en) | 2021-05-25 | 2021-05-25 | Leather printed product and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110569060.5A CN113249988A (en) | 2021-05-25 | 2021-05-25 | Leather printed product and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113249988A true CN113249988A (en) | 2021-08-13 |
Family
ID=77184157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110569060.5A Pending CN113249988A (en) | 2021-05-25 | 2021-05-25 | Leather printed product and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113249988A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| WO2017088085A1 (en) * | 2015-11-27 | 2017-06-01 | 江苏宝泽高分子材料股份有限公司 | Aqueous ultra-misty ultra-black treatment agent for synthetic leather and preparation method for same |
| CN107903718A (en) * | 2017-12-01 | 2018-04-13 | 常德金德新材料科技股份有限公司 | A kind of aqueous color paste and preparation method thereof |
| CN108997832A (en) * | 2018-09-25 | 2018-12-14 | 惠州市彩森环保涂料有限公司 | Environmentally friendly leather silk screen water-based ink and its preparation process |
| CN110983830A (en) * | 2019-11-27 | 2020-04-10 | 岳西县天恩皮具有限公司 | Leather printing method |
-
2021
- 2021-05-25 CN CN202110569060.5A patent/CN113249988A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| WO2017088085A1 (en) * | 2015-11-27 | 2017-06-01 | 江苏宝泽高分子材料股份有限公司 | Aqueous ultra-misty ultra-black treatment agent for synthetic leather and preparation method for same |
| CN107903718A (en) * | 2017-12-01 | 2018-04-13 | 常德金德新材料科技股份有限公司 | A kind of aqueous color paste and preparation method thereof |
| CN108997832A (en) * | 2018-09-25 | 2018-12-14 | 惠州市彩森环保涂料有限公司 | Environmentally friendly leather silk screen water-based ink and its preparation process |
| CN110983830A (en) * | 2019-11-27 | 2020-04-10 | 岳西县天恩皮具有限公司 | Leather printing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105002762B (en) | A kind of digital ink-jet printed method of silk | |
| CN105019277B (en) | A kind of method of Silk reactive printing | |
| US3567548A (en) | Production of permanently sculptured pile fabrics | |
| CN107503197A (en) | A kind of chalk pretreatment fluid and preparation method thereof, direct-injection digital printing process | |
| CN110438822B (en) | Steaming-washing-free printing process for disperse dye | |
| CN113512906A (en) | Coating composition for pyrograph transfer paper, pyrograph transfer paper and preparation method thereof | |
| CN104746351B (en) | A kind of preparation method for emulating crystallization skin | |
| CN103898778A (en) | Sublimation transfer printing process for natural fabrics or rayon | |
| CN113249988A (en) | Leather printed product and preparation method thereof | |
| CN108239889B (en) | Wet low-temperature thermal transfer printing method | |
| CN105235436B (en) | A kind of skin is drawn | |
| CN105421112A (en) | Wax-painting process for vegetable-tanned leather | |
| CN110593006B (en) | Daming currency precious bank note repair process | |
| CN112030581A (en) | Environment-friendly silver-ironing-imitating printing process and application thereof | |
| CN105603781B (en) | A kind of preparation method of modified acrylate emulsion and the application in pigment printing | |
| CN111041701A (en) | Preparation process of fox fur-imitated fabric | |
| CN112063767B (en) | Process for coating elastic leather product gum dyeing and finishing | |
| CN111040515A (en) | Digital ink jet printing after-finishing ink and application thereof | |
| CN1150197A (en) | Leather colour printing and dyeing method | |
| CN115323808A (en) | Digital three-dimensional 3D printing process for coating | |
| CN107385970A (en) | Hankow road goat skin imitates rare deerskin printing technology | |
| KR100624396B1 (en) | Preparation method of fabrics for ink-jet printing using chitosan | |
| CN107190509A (en) | A kind of preparation technology of soft pro-skin mercerized cloth | |
| CN104452339A (en) | Production method for pigment ink-jet printing fabric | |
| CN109944097A (en) | Instrument synthetic fibre PRINTED FABRIC and its printing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210813 |