WO2018062724A1 - Composition cosmétique de maquillage du type huile dans l'eau - Google Patents

Composition cosmétique de maquillage du type huile dans l'eau Download PDF

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Publication number
WO2018062724A1
WO2018062724A1 PCT/KR2017/010037 KR2017010037W WO2018062724A1 WO 2018062724 A1 WO2018062724 A1 WO 2018062724A1 KR 2017010037 W KR2017010037 W KR 2017010037W WO 2018062724 A1 WO2018062724 A1 WO 2018062724A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
cosmetic composition
makeup cosmetic
water
weight
Prior art date
Application number
PCT/KR2017/010037
Other languages
English (en)
Korean (ko)
Inventor
강유진
김경남
Original Assignee
주식회사 아모레퍼시픽
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 아모레퍼시픽 filed Critical 주식회사 아모레퍼시픽
Publication of WO2018062724A1 publication Critical patent/WO2018062724A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/62—Coated
    • A61K2800/622—Coated by organic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/62—Coated
    • A61K2800/623—Coating mediated by organosilicone compounds

Definitions

  • the present invention relates to an oil-in-water makeup cosmetic composition.
  • the present invention seeks to provide a makeup cosmetic in a stable formulation, using polyurethane as a thickener, without the need for additional emulsifiers or surfactants, having a high volume of oil content.
  • the present invention provides an oil-in-water makeup cosmetic composition comprising an aqueous phase and an oil phase, wherein the aqueous phase provides an oil-in-water makeup cosmetic composition comprising an inorganic powder and a polyurethane coated with a hydrophilic coating agent.
  • the oil-in-water makeup cosmetic composition according to the present invention contains a polyurethane as a thickener in the water phase, and does not require an additional emulsifier or a surfactant, and has a high volume of oil content, thereby providing excellent initial moisture and good applicability.
  • the finish is not dry but excellent in durability, and the oil can enhance the shine and moisture.
  • the phase separation due to the colorant does not occur, the stability of the formulation is excellent.
  • oil-in-water makeup cosmetic composition according to the present invention will be described in detail.
  • the oil in water (O / W) type means an emulsion formulation in which the continuous phase is an aqueous phase and the dispersed phase is an oil phase.
  • an emulsion formulation refers to a formulation in which a dispersed phase including one or more liquid phases in a continuous phase including one or more liquid phases is dispersed in the form of droplets.
  • the water phase comprises water and the water phase comprises a hydrophilic substance dissolved in water.
  • the aqueous phase according to the present invention comprises an inorganic powder coated with a hydrophilic coating agent.
  • the hydrophilic coating agent is one containing at least one of silica and cellulose.
  • the content of the hydrophilic coating agent is 2 to 15% by weight based on the total weight of the inorganic powder. If less than 2% by weight, the coating of the hydrophilic coating agent on the inorganic powder is not uniform as a whole, the effect of the hydrophilic coating is inadequate, when more than 15% by weight, the coloring effect of the inorganic powder is lowered to a greater There is a drawback that inorganic powders are required.
  • the content of the inorganic powder coated with the hydrophilic coating agent is 0.01 wt% to 10 wt% with respect to the total weight of the composition.
  • the content of the inorganic powder coated with the hydrophilic coating agent is less than 0.01% by weight, the color development effect is insufficient to function as a makeup cosmetic, when more than 10% by weight, the stability of the formulation is lowered.
  • the inorganic powder coated with the hydrophilic coating agent can be prepared by a method known in the art, the method is not particularly limited.
  • precursors capable of forming a hydrophilic coating layer after dispersing the inorganic powder for example, in the case of a silica layer, are added with tetraethoxysilane and heat-treated for 1 to 6 hours at a temperature of 50 to 400 ° C.
  • the inorganic pigment surface can be treated with silica.
  • the inorganic powder is not particularly limited as long as it can implement color development as a colorant.
  • the inorganic powder may be titanium oxide, yellow iron oxide, red iron oxide or black iron oxide.
  • the inorganic powder it is preferable to use a mixture of titanium oxide and yellow, red or black iron oxide.
  • the average particle diameter of the inorganic powder is 200 nm to 600 nm.
  • the average particle diameter of the inorganic powder is less than 200 nm, the color development effect is insignificant, and when the average particle diameter is more than 600 nm, the feeling of grain becomes rough and the feeling of use deteriorates.
  • the water phase according to the invention comprises a polyurethane.
  • the polyurethane is an ethoxylate-based urethane.
  • the ethoxylate-based urethane is an isophorone diisocyanate (IPDI) -based compound.
  • IPDI isophorone diisocyanate
  • the isophorone diisocyanate compound is a compound represented by the following formula (1).
  • n is 50 to 120, preferably 75 to 100, more preferably 75 or 100
  • R is independently an alkyl group having 12 to 24 carbon atoms or an alke having 12 to 24 carbon atoms. It is a nil group, Preferably it is a C12-C24 alkyl group, More preferably, it is a C18 alkyl group.
  • the isophorone diisocyanate compound is disteares-75 IPDI or disteares-100 IPDI.
  • the polyurethane is 0.1% by weight to 10% by weight relative to the total weight of the composition. If it is less than 0.1% by weight, the effect as a thickener does not appear, and if it is more than 10% by weight, the hardness of the formulation of the composition is increased, resulting in deterioration of the usability, such as flowability and dullness.
  • the oil phase comprises an oil
  • the oil phase comprises a lipophilic substance dissolved in oil
  • oil refers to a substance in which a phase or phase is separated from an aqueous phase in which all or a part of the oil includes water when mixed with water in a state of normal temperature and normal pressure.
  • oil is not particularly limited, but specific examples thereof will be described as follows.
  • the oil is at least one selected from the group consisting of hydrocarbon oil, ester oil, diester oil, triglyceride oil, carbonate oil, alcohol oil and silicone oil. .
  • the hydrocarbon-based oil is any selected from the group consisting of squalene, hydrogenated polyisobutene, hydrogenated poly (C6-14 olefin), hydrogenated polydecene, paraffin, ceresin and microcrystalline wax. Is more than one.
  • the ester oil is triethylhexanoin, cetylethylhexanoate, cetyloctanoate, cetylisooctanoate, octyldodecyl myristate, isopropyl palmitate, isopropyl myridine State, Butyleneglycol Dicaprylate / Dicaprate, Tocopherol Acetate, Coco-Caprylate / Caprate, Jojoba Seed Oil, Dicaprylic Carbonate, Pentaerythritol Tetraethylhexanoate and Pentaerythritol Tetraisostearate At least one selected from the group consisting of.
  • the diester oil is butylene glycol dicaprylate, dicaprate, diisostearyl malate, di-C12-13 alkyl malate, neopentyl glycol diheptanoate, tridecyl stearate At least one selected from the group consisting of latex, naerpentyl glycol dicaprylate / dicaprate, tridecyl trimellitate and dicapriryl carbonate.
  • the carbonate oil is dialkyl carbonate.
  • the triglyceride oil is selected from the group consisting of caprylic / capric triglycerides, caprylic / capric / stearic triglycerides, triethyloctanoin and tricapryline Being more than one.
  • the alcohol oil is in the group consisting of octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleyl alcohol and isostearyl alcohol One or more selected.
  • the silicone oil is dimethicone, cyclomethicone, polydimethylsiloxane, methylphenylpolysiloxane, methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, At least one selected from the group consisting of tetradecamethylhexasiloxane and octamethyltrisiloxane.
  • the amount of oil is 0.01% by weight to 50% by weight relative to the total weight of the composition. If the content of the liquid phase is less than 0.01% by weight, the moisturizing and gloss effect by the oil is inadequate, and if more than 50% by weight, the formulation is not stabilized by polyurethane alone without an additional emulsifier.
  • the formulation of the composition may be, for example, supported on a sponge.
  • the sponge may be a natural sponge or a synthetic sponge, and the natural sponge may be, for example, a sponge sponge or a natural rubber sponge.
  • the synthetic sponge is, for example, foamed urethane foam, butadiene rubber (BR), styrene-butadiene rubber (SBR), NR (Natural Rubber), chloroprene rubber (CR), isoprene-isobutylene rubber (IIR) , Isoprene rubber (IR), vulcanized ethylene-propylene rubber (EPR), polysulfide rubber, silicone rubber, fluororubber, urethane rubber, acrylic rubber ), EPDM (Ethylene propylene diene monomer) rubber, polyvinyl alcohol (PVA), nitrile rubber (Nitrile rubber) and ethylene vinyl acetate (EVA) may include one or more selected from the group consisting of.
  • composition according to the present invention may include other ingredients in addition to the above-mentioned materials within a range not impairing the main effect, preferably a synergistic effect on the main effect.
  • composition according to the present invention may further include a moisturizer, an emulsifier, a UV absorber, a preservative, a fungicide, an antioxidant, a pH adjuster, a flavoring agent, a cooling agent or a restricting agent.
  • the compounding quantity of the said component can be selected easily by a person skilled in the art within the range which does not impair the objective and effect of this invention.
  • the present invention provides the use of an oil-in-water cosmetic composition containing i) an inorganic powder coated with a hydrophilic coating agent and ii) a polyurethane as a thickener in the manufacture of a cosmetic composition or cosmetic, in particular a cosmetic composition or cosmetic for makeup. .
  • the components contained in the water phase were mixed at 70 ° C. to prepare an aqueous solution, and the colorant was mixed and dispersed in the aqueous solution.
  • step 3 The oily dispersion of step 1 was added to the aqueous solution of step 2 and stirred and mixed with a homomixer.
  • Comparative Example 1 can be confirmed that the formulation is stable while the oil content is small, but Example 1 using polyurethane as a thickener can be confirmed that the stability even when containing a high content of oil.
  • Moisture is measured by measuring the amount of moisture in the skin's epidermis using a sensor and quantifying the amount of moisture.
  • Comparative Example 1 was found to have a high water content immediately after application because the content of the water phase component is more, it can be confirmed that the water content is sharply reduced after 1 hour, the makeup cosmetic of Example 1 according to the present invention
  • the composition has a high oil content and exhibits a closing effect that prevents the applied aqueous phase component from evaporating, so that the skin moisturizing power lasts more than 8 hours.
  • Example 5 the makeup cosmetic composition of Example 1 according to the present invention exhibits excellent moisturizing and glossiness by stabilizing a high content of oil.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique de maquillage du type huile dans l'eau comprenant une phase aqueuse et une phase huileuse, la phase aqueuse comprenant du polyuréthane et de la poudre inorganique revêtue d'un agent de revêtement hydrophile.
PCT/KR2017/010037 2016-09-30 2017-09-13 Composition cosmétique de maquillage du type huile dans l'eau WO2018062724A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2016-0126692 2016-09-30
KR1020160126692A KR102598347B1 (ko) 2016-09-30 2016-09-30 수중유형 메이크업 화장료 조성물

Publications (1)

Publication Number Publication Date
WO2018062724A1 true WO2018062724A1 (fr) 2018-04-05

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Application Number Title Priority Date Filing Date
PCT/KR2017/010037 WO2018062724A1 (fr) 2016-09-30 2017-09-13 Composition cosmétique de maquillage du type huile dans l'eau

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KR (1) KR102598347B1 (fr)
WO (1) WO2018062724A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102241417B1 (ko) * 2018-11-15 2021-04-16 주식회사 엘지생활건강 향 지속성을 향상시키는 화장료 조성물

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110017409A (ko) * 2008-06-30 2011-02-21 이엘씨 매니지먼트 엘엘씨 재도포가능한 마스카라 조성물
KR20110058238A (ko) * 2009-11-26 2011-06-01 (주)아모레퍼시픽 실리카로 표면처리된 무기안료를 포함하는 수중유형 메이크업 화장료 조성물
KR20120049078A (ko) * 2010-11-08 2012-05-16 한국콜마 주식회사 하이브리드 티타늄디옥사이드를 포함하는 파운데이션 화장료 조성물
US20120244101A1 (en) * 2009-12-17 2012-09-27 Avon Products, Inc. Self-Leveling Cosmetic
JP2016520633A (ja) * 2013-06-03 2016-07-14 ロレアル 会合性ポリウレタンと疎水コーティングされた顔料とを含む化粧用組成物

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2590064A1 (fr) * 2004-12-15 2006-06-22 Alzo International, Inc. Nouvelles emulsions cosmetiques et emulsifieur presentant des proprietaires rheologiques dilatantes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110017409A (ko) * 2008-06-30 2011-02-21 이엘씨 매니지먼트 엘엘씨 재도포가능한 마스카라 조성물
KR20110058238A (ko) * 2009-11-26 2011-06-01 (주)아모레퍼시픽 실리카로 표면처리된 무기안료를 포함하는 수중유형 메이크업 화장료 조성물
US20120244101A1 (en) * 2009-12-17 2012-09-27 Avon Products, Inc. Self-Leveling Cosmetic
KR20120049078A (ko) * 2010-11-08 2012-05-16 한국콜마 주식회사 하이브리드 티타늄디옥사이드를 포함하는 파운데이션 화장료 조성물
JP2016520633A (ja) * 2013-06-03 2016-07-14 ロレアル 会合性ポリウレタンと疎水コーティングされた顔料とを含む化粧用組成物

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Publication number Publication date
KR102598347B1 (ko) 2023-11-06
KR20180036292A (ko) 2018-04-09

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