WO2017204361A1 - 化粧材 - Google Patents
化粧材 Download PDFInfo
- Publication number
- WO2017204361A1 WO2017204361A1 PCT/JP2017/019815 JP2017019815W WO2017204361A1 WO 2017204361 A1 WO2017204361 A1 WO 2017204361A1 JP 2017019815 W JP2017019815 W JP 2017019815W WO 2017204361 A1 WO2017204361 A1 WO 2017204361A1
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- WO
- WIPO (PCT)
- Prior art keywords
- gloss
- layer
- adjustment layer
- matting agent
- pattern
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D5/00—Surface treatment to obtain special artistic surface effects or finishes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/02—Superimposing layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F7/00—Designs imitating three-dimensional effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/42—Gloss-reducing agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/263—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer having non-uniform thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
- Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
Definitions
- the present invention relates to a cosmetic material for use in surface makeup of a building interior / exterior, joinery, furniture, and the like. More specifically, the present invention relates to a decorative material that expresses unevenness three-dimensionally due to the difference in surface gloss.
- a desired pattern such as a wood grain pattern or a stone grain pattern is usually applied to a cosmetic material used for surface makeup of a building interior / exterior, joinery, furniture, or the like.
- a decorative material that expresses the unevenness of the surface of natural wood and stone materials in a three-dimensional manner is desirable. It is widely used mainly for applications.
- the surface of the formed synthetic paint layer A glossy transparent or translucent synthetic coating layer is formed on the portion excluding the portion corresponding to the dent pattern.
- the formation of synthetic paint layers with different luster can be performed by conventional printing methods such as gravure printing methods following the formation of pattern patterns (pattern ink layers), so no special equipment is required and production efficiency is high. Synchronization with the pattern is easy.
- the thickness of the synthetic paint layer is much thinner than the height difference of the unevenness to be expressed, so the amount of resin used can be reduced, and it is advantageous in terms of flexibility, and has excellent bending processability. It is easy to realize a decorative material. Moreover, since there is no large unevenness
- a method of adding a gloss adjusting agent (matting agent) to a transparent resin as a binder is general.
- the gloss adjusting agent fine particles of inorganic material or organic material are mainly used.
- fine particles of inorganic material especially silica fine particles
- the gloss adjusting agent imparts unevenness to the surface of the gloss adjusting layer, and the unevenness scatters light to provide a matting effect.
- the type and amount of the gloss adjusting agent the required gloss can be freely created.
- the unevenness provided by the gloss adjusting agent is small relative to the thickness of the gloss adjusting layer, and is very small compared to the unevenness provided by the mechanical embossing method. For this reason, even when the surface of the decorative material is observed from the front, even if the unevenness due to the sufficient difference in gloss is obtained, the glossiness of the relatively low gloss portion increases in the oblique observation, The problem is that the unevenness obtained by the difference in gloss is reduced.
- cosmetic materials are actually used for building interiors and exteriors, furniture, furniture, etc., the user observes the surface of the cosmetic material from various angles. As a result, there is a problem that the luxury feeling of the cosmetic material is greatly impaired.
- the present invention has an object to provide a cosmetic material in which the unevenness obtained by the difference in gloss is hardly changed even when observed from an oblique direction.
- the inventors have adjusted the gloss when observed obliquely by setting the layer thickness of the gloss adjustment layer having a relatively low gloss and the particle size of the matting agent to be added to the optimum range. It was found that the glossiness of the layer could be suppressed and that the unevenness due to the difference in glossiness was not impaired even when observed from all angles.
- a decorative material includes a first gloss adjustment layer provided on a base material, and a first gloss adjustment layer partially provided on the first gloss adjustment layer.
- a second gloss adjustment layer having a gloss different from that of the adjustment layer, and the particle size of the first gloss adjustment layer and the second gloss adjustment layer is relatively low.
- a matting agent having a layer thickness of 1.0 times or more is added.
- the layer thickness of the gloss adjustment layer having a low gloss and the particle size of the matting agent to be added are in an optimal range, so that the gloss adjustment layer when observed from an oblique direction is used. Gloss rise can be suppressed, and even when observed obliquely, it is possible to provide a cosmetic material in which the unevenness obtained by the difference in gloss is hardly changed.
- a decorative material 1 according to an embodiment of the present invention will be described with reference to the drawings.
- the drawings are schematic, and the relationship between the thickness and the planar dimensions, the ratio of the thickness of each layer, and the like are different from the actual ones.
- the embodiment described below exemplifies a configuration for embodying the technical idea of the present invention, and the technical idea of the present invention describes the material, shape, structure, and the like of component parts as follows. It is not something specific.
- the technical idea of the present invention can be variously modified within the technical scope defined by the claims described in the claims.
- the decorative material 1 of the present embodiment is provided with a first gloss adjustment layer 5 provided on a base material 2 and a part of the first gloss adjustment layer 5. And a second gloss adjusting layer 6 having a gloss different from the gloss of the gloss adjusting layer 5. And among these 1st, 2nd glossiness adjustment layers 5 and 6, in a glossiness adjustment layer with comparatively low glossiness, a particle size is 1.0 times or more of layer thickness, More preferably, 1.1 times or more It is important that a matting agent is added. Thereby, since sufficient unevenness
- the base ink layer 3 may be a layer formed by, for example, applying solid ink to the base material 2.
- the layer thickness is the thickness of the resin portion that fills between the matting agents when observing the cross section of the gloss adjustment layer having a relatively low gloss.
- the particle size of the matting agent is 1.1 times or more of the layer thickness, the matting agent is not buried in the gloss adjusting layer, and is partially exposed from the surface. It has become. Therefore, the measurement of the layer thickness can be obtained by measuring a plurality of resin portions between the matting agents and averaging the obtained values.
- the particle size when the particle shape is not spherical, the cross section of the particle may be elliptical and the average value of the major axis and minor axis may be used as the particle size. That is, in this embodiment, the particle size is an average particle size when the cross-sectional shape of the particles is assumed to be circular or elliptical.
- this embodiment demonstrated the case where the particle size of a matting agent was 1.1 times or more of layer thickness, this embodiment is not limited to this.
- the matting agent is not buried in the gloss adjusting layer and is partially exposed from the surface. This is because the surface of the matting agent to be described later may have a low “wetting property” with respect to the resin forming the gloss adjusting layer. This is to be repelled in part.
- the upper limit of the particle size of the matting agent is likely to drop off from the resin component by increasing the particle size, and the wear resistance and scratch resistance required for the cosmetic material are deteriorated. If the particle size increases, the surface irregularities increase, and the contamination resistance deteriorates due to poor wiping of contaminating components. Is preferable.
- the particle size of the matting agent is 1.0 times or more of the layer thickness, more preferably 1.1 times or more.
- the specific size may be any numerical value. For example, when the layer thickness is set to 5 ⁇ m, the particle size of the matting agent may be 5.0 ⁇ m or more, more preferably 5.5 ⁇ m or more.
- the matting agent a known matting agent that is commercially available can be used.
- examples thereof include fine particles made of an inorganic material such as silica, glass, alumina, calcium carbonate, barium sulfate, and acrylic. Since the first and second gloss adjusting layers 5 and 6 are required to have high transparency, it is desirable to use fine particles such as silica, glass, and acrylic having high transparency.
- a matting agent having a low bulk density formed by secondary aggregation of fine primary particles, not solid true spherical particles has a high matting effect with respect to the added amount. Therefore, by using such a matting agent, it is possible to form a gloss adjusting layer having a lower gloss. Thereby, the difference of the glossiness of the 1st glossiness adjustment layer 5 and the 2nd glossiness adjustment layer 6 can be enlarged, and the uneven
- the particle size of the matting agent can be selected from any numerical value, but when a known matting agent is used, it is preferably 2 ⁇ m or more and 15 ⁇ m or less. More preferably, it is 4 ⁇ m or more and 12 ⁇ m or less.
- a matting agent having a particle size of less than 2 ⁇ m has a low matting effect, so that the unevenness characteristic of the present embodiment cannot be sufficiently obtained.
- a matting agent having a particle size of more than 15 ⁇ m results in increased light scattering, leading to white turbidity of the first and second gloss adjusting layers 5 and 6 and an increase in visual feeling of particles. And the unevenness
- the resin part (resin composition) constituting the first and second gloss adjusting layers 5 and 6 examples include polyurethane, acrylic silicon, fluorine, epoxy, vinyl, polyester, melamine, amino Alkyd, urea and the like can be used.
- the form of the resin composition is not particularly limited, such as aqueous, emulsion, solvent type.
- a curing method for the resin composition for example, a one-component type, a two-component type, an ultraviolet curing method, or the like can be used.
- urethane-based materials using isocyanate as the resin composition are suitable from the viewpoints of workability, cost, cohesive strength of the resin itself, and the like.
- the isocyanate include tolylene diisocyanate (TDI), xylylene diisocyanate (XDI), hexamethylene diisocyanate (HMDI), diphenylmethane diisocyanate (MDI), lysine diisocyanate (LDI), isophorone diisocyanate (IPDI), methylhexane diisocyanate (HTDI). ), Bis (isocyanatemethyl) cyclohexane (HXDI), trimethylhexamethylene diisocyanate (TMDI) and other derivatives such as adducts, burettes and isocyanurates can be used.
- HMDI hexamethylene diisocyanate
- IPDI isophorone diisocyanate
- a resin that is cured by active energy rays such as ultraviolet rays and electron beams.
- functional additives such as antibacterial agents and fungicides may be added to the first and second gloss adjusting layers 5 and 6 in order to impart various functions.
- the ultraviolet absorber for example, benzotriazole, benzoate, benzophenone, and triazine can be used.
- group can be used as a light stabilizer.
- a release agent having a silicone skeleton can be added when anti-contamination performance and Sellotape (registered trademark) releasability are required.
- the type of the release agent is not particularly limited, but by using a silicone release agent having a terminal functional group that has reactivity with the resin composition, antifouling performance and durability of cello tape release properties can be achieved. It can be improved.
- the first and second gloss adjusting layers 5 and 6 have different gloss.
- the first gloss adjustment layer 5 covers the entire surface of the substrate 2 on the first gloss adjustment layer 5 side
- the second gloss adjustment layer 6 is on the first gloss adjustment layer 5.
- the surface on the second gloss adjusting layer 6 side is partially covered.
- the uneven shape is expressed by the difference in gloss between the first and second gloss adjusting layers 5 and 6.
- the first gloss adjustment layer 5 covers the entire surface of the substrate 2 on the first gloss adjustment layer 5 side, but other configurations may be employed. .
- the first gloss adjusting layer 5 may partially cover the surface of the base 2 on the first gloss adjusting layer 5 side.
- a matting agent is added to the gloss adjustment layer having a relatively low gloss among the first and second gloss adjustment layers 5 and 6.
- the addition amount of the matting agent is preferably 5 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of the resin composition. More preferably, it is 10 to 30 mass parts.
- the amount is less than 5 parts by mass, the matte effect is insufficient, so that the difference in gloss with the gloss adjustment layer having a relatively high gloss becomes small, and the unevenness is insufficient.
- the resin composition is relatively insufficient with respect to the matting agent, which causes the matting agent to drop off or the scratch resistance to be reduced due to the dropping. The required durability is greatly impaired.
- any matting agent can be added to the gloss adjustment layer having a relatively high gloss. These should be appropriately adjusted according to the final unevenness and design. Further, the matting agent and the resin composition used for the first and second gloss adjusting layers 5 and 6 may be the same or different. These can be freely selected from the feeling of unevenness and various required characteristics.
- the layer thicknesses of the first and second gloss adjusting layers 5 and 6 can be selected from arbitrary numerical values. However, as described above, the particle size of the matting agent is preferably 2 ⁇ m or more and 15 ⁇ m or less. Among them, it is more preferable that the thickness is 1.8 ⁇ m or more and 13.6 ⁇ m or less.
- the first and second gloss adjusting layers 5 and 6 are the outermost layers of the decorative material 1, and therefore wear resistance, scratch resistance, solvent resistance, stain resistance, and the like necessary for the decorative material 1. Surface properties are required. Among these, the wear resistance and scratch resistance are affected by the layer thickness, and a thicker layer is advantageous.
- a more preferable layer thickness of the first and second gloss adjusting layers 5 and 6 is 2 ⁇ m or more and 12 ⁇ m or less.
- the thickness is less than 1.8 ⁇ m, the wear resistance and scratch resistance are greatly deteriorated, and the use as the decorative material 1 may be limited.
- the workability as the decorative material 1 may deteriorate.
- the base material 2 is not particularly limited as long as it is used as a base paper for the decorative material 1.
- paper such as thin paper, resin-mixed paper, titanium paper, resin-impregnated paper, flame-retardant paper, inorganic paper, woven or non-woven fabric made of natural fiber or synthetic fiber, homo- or random polypropylene resin, polyolefin resin such as polyethylene resin Synthetic resin systems such as copolyester resins, amorphous crystalline polyester resins, polyethylene naphthalate resins, polybutylene resins, acrylic resins, polyamide resins, polycarbonate resins, polyvinyl chloride resins, polyvinylidene chloride resins, fluorine resins Substrate, wood veneer, veneer, plywood, laminated wood, particle board, medium density fiber board, etc., wood base material, gypsum board, cement board, calcium silicate board, ceramic board, inorganic base material, iron, copper , Metal base materials such as aluminum and stainless steel, or composite materials and
- a pattern ink layer 4 for adding a pattern to the decorative material 1 can be provided between the base material 2 and the first gloss adjustment layer 5.
- the pattern pattern for example, a grain pattern, a stone pattern, a grain pattern, a tiled pattern, a brickwork pattern, a cloth pattern, a leather pattern, a geometric figure, or the like can be used.
- the pattern ink layer 4 is formed immediately below the second gloss adjusting layer 6.
- the second gloss adjusting layer 6 is formed only in a portion overlapping the pattern ink layer 4.
- the pattern of the pattern ink layer 4 is synchronized with the gloss of the second gloss adjustment layer 6. Thereby, the design property by the 2nd glossiness adjustment layer 6 can be added to the design property by the pattern ink layer 4.
- FIG. therefore, it is possible to form the decorative material 1 having a high-quality design expression close to that of natural wood or natural stone.
- the second gloss adjusting layer 6 is formed only in a portion overlapping the pattern ink layer 4, that is, an example in which it is formed only in a portion immediately above the pattern ink layer 4 is shown.
- Other configurations can also be employed.
- it may be a portion that overlaps with the pattern ink layer 4, and may be formed on a portion other than the portion directly above in addition to the portion directly above the pattern ink layer 4.
- a base ink layer 3 is provided between the base material 2 and the pattern ink layer 4 so as to cover the entire surface of the base material 2 on the first gloss adjustment layer 5 side according to the required design. May be.
- the base ink layer 3 may be a multilayer of two or more layers as necessary, such as concealment.
- the pattern ink layer 4 may be formed by laminating as many as the number of color separations necessary for expressing a desired design. As described above, the pattern ink layer 4 and the base ink layer 3 are variously combined depending on a required design, that is, a design to be expressed, but are not particularly limited.
- the constituent materials of the base ink layer 3 and the pattern ink layer 4 are not particularly limited.
- a printing ink or coating agent in which a matrix and a colorant such as a dye or pigment are dissolved and dispersed in a solvent can be used.
- the matrix include oil-based nitrified cotton resin, two-component urethane resin, acrylic resin, styrene resin, polyester resin, urethane resin, polyvinyl resin, alkyd resin, epoxy resin, melamine resin, and fluorine resin.
- Various synthetic resins such as resins, silicone resins and rubber resins, or a mixture or copolymer thereof can be used.
- the colorant examples include inorganic pigments such as carbon black, titanium white, zinc white, petal, yellow lead, bitumen, cadmium red, azo pigments, lake pigments, anthraquinone pigments, phthalocyanine pigments, isoindolinone pigments.
- Organic pigments such as dioxazine pigments, or mixtures thereof can be used.
- the solvent for example, toluene, xylene, ethyl acetate, butyl acetate, methyl alcohol, ethyl alcohol, isopropyl alcohol, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, water, or a mixture thereof can be used.
- Functional additives such as a curing accelerator and a curing retarder may be added.
- Each of the base ink layer 3, the pattern ink layer 4, and the first and second gloss adjustment layers 5 and 6 is, for example, a gravure printing method, an offset printing method, a screen printing method, an electrostatic printing method, an inkjet printing method, or the like. It can be formed by various printing methods. In addition, since the base ink layer 3 and the first gloss adjustment layer 5 cover the entire surface of the substrate 2 on the first gloss adjustment layer 5 side, for example, a roll coating method, a knife coating method, a micro coating method, and the like. It can also be formed by various coating methods such as a gravure coating method and a die coating method. These printing methods and coating methods may be selected separately depending on the layer to be formed, or the same method may be selected and collectively processed.
- the coating amount may be adjusted in the above-described printing method and coating method.
- the coating amount can be calculated from the difference in mass between various printing methods and coating methods in which the gloss adjusting layer is formed on the base material 2 and not.
- the relationship between the coating amount and the layer thickness can be obtained by cross-sectional observation.
- a transparent resin layer (not shown) can be provided between the pattern ink layer 4 and the first gloss adjusting layer 5.
- the transparent resin layer for example, it is preferable to use a resin composition containing an olefin resin as a main component.
- olefin resin examples include, in addition to polypropylene, polyethylene, polybutene and the like, ⁇ -olefin (eg, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1 -Decene, 1-undecene, 1-dodecene, tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene, 1-eicosene, 3-methyl-1-butene, 3 -Methyl-1-pentene, 3-ethyl-1-pentene, 4-methyl-1-pentene, 4-methyl-1-hexene, 4,4-dimethyl-1-pentene, 4-ethyl-1-hexene, 3 -Ethyl-1-hexene
- additives such as a heat stabilizer, an ultraviolet absorber, a light stabilizer, an antiblocking agent, a catalyst scavenger and a colorant may be added to the transparent resin layer.
- additives can be appropriately selected from known ones and used.
- the transparent resin layer can be formed by various lamination methods such as a method using hot pressure, an extrusion laminating method, and a dry laminating method.
- the particle size of the first gloss adjustment layer 5 and the second gloss adjustment layer 6 is relatively low.
- the decorative material 1 of this embodiment since the pattern of the pattern ink layer 4 and the gloss of the 2nd gloss adjustment layer 6 synchronize, it is 2nd in the design property by the pattern ink layer 4. Thus, the decorative material 1 having a high-quality design expression close to that of natural wood or natural stone can be formed.
- a matting agent made of an inorganic material having a high matting effect is used. Therefore, the gloss of the added gloss adjusting layer can be greatly reduced. Therefore, the difference between the gloss of the first gloss adjustment layer 5 and the gloss of the second gloss adjustment layer 6 can be increased, and the resulting unevenness can be increased. Thereby, a deeper and excellent design expression becomes possible.
- the matting agent is in a range of 5 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of the resin composition constituting the gloss adjustment layer having a relatively low gloss. It was made to add in. Therefore, since sufficient unevenness can be reliably imparted to the surface of the gloss adjusting layer, the glossiness does not increase even when observed obliquely, and low gloss can be reliably maintained. Therefore, even when observed from an oblique direction, it is possible to reliably provide the cosmetic material 1 in which the uneven feeling obtained due to the difference in gloss hardly changes.
- a matting agent is also added to the gloss adjustment layer having a relatively high gloss. Even in such a form, since sufficient unevenness can be imparted to the surface of the gloss adjusting layer, the glossiness does not increase even when observed obliquely, and low gloss can be maintained. Therefore, even when observed obliquely, it is possible to provide the decorative material 1 in which the unevenness obtained by the difference in gloss is difficult to change.
- the particle size of the matting agent is set in the range of 2 ⁇ m or more and 15 ⁇ m or less. Therefore, the unevenness on the surface of the gloss adjusting layer can be sufficiently obtained.
- the particle size of the matting agent is set to be 3.0 times or less the layer thickness of the gloss adjusting layer having a relatively low gloss. Therefore, since the fall of the matting agent can be reduced, it is possible to provide the cosmetic material 1 that is excellent in wear resistance and scratch resistance and excellent in wiping off of contaminating components.
- the second gloss adjustment layer 6 is formed in a portion overlapping the pattern ink layer 4, and the pattern pattern of the pattern ink layer 4 and the gloss of the second gloss adjustment layer 6 are synchronized.
- the second gloss adjustment layer 6 is formed in a portion other than directly above the pattern ink layer 4, and the pattern pattern of the pattern ink layer 4 and the gloss of the first gloss adjustment layer 5 are synchronized. You may do it. Thereby, the glossiness of the exposed first gloss adjustment layer 5 is imparted to the pattern of the pattern ink layer 4, and the design properties of the first gloss adjustment layer 5 can be added to the design properties of the pattern ink layer 4. . Therefore, it is possible to form the decorative material 1 having a high-quality design expression close to that of natural wood or natural stone.
- Example 1 the impregnated paper having a basis weight 50g / m 2 (GFR-506 : Kohjin Ltd. Co.) was used as the base material 2. Then, on one surface of the base material 2, using the oil-based nitrified cotton resin-based gravure printing ink (PCNT (PCRNT), each color: manufactured by Toyo Ink Co., Ltd.), the base ink layer 3 and the pattern ink layer 4 are provided. They were formed in this order. The pattern of the pattern ink layer 4 was a wood grain pattern.
- PCNT oil-based nitrified cotton resin-based gravure printing ink
- an ink for the first gloss adjustment layer 5 is applied on the base 2 on which the pattern ink layer 4 is formed so as to cover the entire surface of one side of the base 2, and the first gloss adjustment layer 5 was formed.
- Ink is 100 parts by weight of acrylic polyol (6KW-700: manufactured by Taisei Fine Chemical Co., Ltd.), 8 parts by weight of silica matting agent (Mizukasil 310P: manufactured by Fuji Silysia Chemical Co., Ltd.), polyisocyanate (cured by UR190B) Agent: Toyo Ink Co., Ltd.) 10 parts by mass.
- the amount of ink applied was 2.5 g / m 2 .
- the layer thickness was 2.1 ⁇ m as a result of cross-sectional observation.
- the average particle size of the silica-based matting agent was 2.7 ⁇ m.
- the second gloss adjusting layer 6 was formed by applying the ink for the second gloss adjusting layer 6 to a portion of the first gloss adjusting layer 5 immediately above the pattern ink layer 4.
- Ink is 100 parts by mass of acrylic polyol (6KW-700: manufactured by Taisei Fine Chemical Co., Ltd.), 3 parts by mass of silica-based matting agent (Mizukasil 310P: manufactured by Fuji Silysia Chemical Co., Ltd.), polyisocyanate (cured by UR190B) Agent: Toyo Ink Co., Ltd.) 10 parts by mass.
- the average particle size of the silica-based matting agent was 2.7 ⁇ m.
- Example 2 the ink for the first gloss adjusting layer 5 is applied on the base 2 on which the pattern ink layer 4 is formed so as to cover the entire surface of one side of the base 2, and the first gloss The adjustment layer 5 was formed.
- Ink is 100 parts by mass of acrylic polyol (6KW-700: manufactured by Taisei Fine Chemical Co., Ltd.), 8 parts by mass of silica-based matting agent (ACEMATT OK900: manufactured by Evonik), polyisocyanate (UR190B curing agent: Toyo Ink) It was composed of 10 parts by mass.
- the average particle size of the silica-based matting agent was 7.5 ⁇ m.
- the amount of ink applied was 7 g / m 2 .
- the layer thickness was 6.5 ⁇ m.
- the ink for the second gloss adjustment layer 6 is applied only to the portion on the first gloss adjustment layer 5 that is directly above the pattern ink layer 4, so that the second gloss adjustment layer 6 is applied.
- Ink is 100 parts by weight of acrylic polyol (6KW-700: manufactured by Taisei Fine Chemical Co., Ltd.), 3 parts by weight of a silica matting agent (ACEMATT OK900: manufactured by Evonik) with an average particle size of 7.5 ⁇ m, polyisocyanate (UR190B curing agent: manufactured by Toyo Ink Co., Ltd.) 10 parts by mass. Otherwise, the configuration was the same as in Example 1.
- Example 3 the ink for the first gloss adjusting layer 5 is applied on the base 2 on which the pattern ink layer 4 is formed so as to cover the entire surface of one side of the base 2, and the first gloss The adjustment layer 5 was formed.
- Ink is 100 parts by weight of acrylic polyol (6KW-700: manufactured by Taisei Fine Chemical Co., Ltd.), 8 parts by weight of silica-based matting agent (ACEMATT 810: manufactured by Evonik), polyisocyanate (UR190B curing agent: Toyo Ink) It was composed of 10 parts by mass.
- the average particle size of the silica-based matting agent was 10.5 ⁇ m.
- the amount of ink applied was 9.5 g / m 2 .
- the layer thickness was 9.3 ⁇ m.
- the ink for the second gloss adjustment layer 6 is applied only to the portion on the first gloss adjustment layer 5 that is directly above the pattern ink layer 4, so that the second gloss adjustment layer 6 is applied. 6 was formed.
- Ink is 100 parts by weight of acrylic polyol (6KW-700: manufactured by Taisei Fine Chemical Co., Ltd.), 3 parts by weight of a silica matting agent (ACEMATT 810: manufactured by Evonik) with an average particle size of 10.5 ⁇ m, polyisocyanate (UR190B curing agent: manufactured by Toyo Ink Co., Ltd.) 10 parts by mass. Otherwise, the configuration was the same as in Example 1.
- Comparative Example 1 In Comparative Example 1, the base material 2 having the pattern ink layer 4 formed thereon was coated with the ink for the first gloss adjusting layer 5 having the same composition as that of Example 1 so that the coating amount was 3.5 g / m 2. It applied so that the whole surface of one side of 2 might be covered. Other than that, the 1st glossiness adjustment layer 5 and the 2nd glossiness adjustment layer 6 were formed similarly to Example 1, and the decorative material 1 was obtained. In addition, the layer thickness of the 1st glossiness adjustment layer 5 at this time was 3.3 micrometers as a result of cross-sectional observation.
- Comparative example 2 In Comparative Example 2, the base material 2 having the pattern ink layer 4 formed thereon was coated with the ink for the first gloss adjusting layer 5 having the same composition as that of Example 2 so that the application amount was 8.5 g / m 2. It applied so that the whole surface of one side of 2 might be covered. Other than that, the 1st glossiness adjustment layer 5 and the 2nd glossiness adjustment layer 6 were formed similarly to Example 2, and the decorative material 1 was obtained. In addition, the layer thickness of the 1st glossiness adjustment layer 5 at this time was 8.4 micrometers as a result of cross-sectional observation.
- the cosmetic materials of Examples 1 to 3 are cosmetic materials 1 having an excellent design with a uniform uneven feeling obtained by the difference in gloss even when observed from all angles.
- the cosmetic material of this invention is not limited to said embodiment and Example, A various change is possible in the range which does not impair the characteristic of invention.
Abstract
Description
ここで、図面は模式的なものであり、厚みと平面寸法との関係、各層の厚みの比率等は現実のものとは異なる。また、以下に示す実施形態は、本発明の技術的思想を具体化するための構成を例示するものであって、本発明の技術的思想は、構成部品の材質、形状および構造等を下記のものに特定するものでない。本発明の技術的思想は、特許請求の範囲に記載された請求項が規定する技術的範囲内において、種々の変更を加えることができる。
図1に示すように、本実施形態の化粧材1は、基材2上に設けられた第1の艶調整層5と、第1の艶調整層5上に部分的に設けられ、第1の艶調整層5の艶と異なる艶を有する第2の艶調整層6とを備えている。そして、これら第1、第2の艶調整層5、6のうち、相対的に艶の低い艶調整層に、粒径が層厚の1.0倍以上、より好ましくは1.1倍以上の艶消し剤が添加されていることが重要である。これにより、艶調整層の表面に十分な凹凸を付与することができるため、斜めからの観察において光沢度が上昇せず、低光沢を維持することができる。
なお、基材2と第1の艶調整層5との間には、後述するように下地インキ層3、柄インキ層4および透明樹脂層(不図示)等、他の層を配置する構成としてもよい。また、下地インキ層3は、例えば、基材2上にインキをベタ塗りして形成した層であってもよい。
なお、層厚と艶消し剤の粒径との関係としては、艶消し剤の粒径が層厚の1.0倍以上、より好ましくは1.1倍以上であることが重要であるが、具体的な大きさについては任意の数値として構わない。例えば、層厚を5μmに設定した場合、艶消し剤の粒径は5.0μm以上、より好ましくは5.5μm以上とすればよい。
なお、本実施形態では、第1の艶調整層5が、基材2の第1の艶調整層5側の面の全面を被覆する例を示したが、他の構成を採用することもできる。例えば、第1の艶調整層5が、基材2の第1の艶調整層5側の面を部分的に被覆する構成としてもよい。
なお、相対的に艶の高い艶調整層においても、任意の艶消し剤を添加することが可能である。これらは最終的な凹凸感や意匠性に応じて適宜調整されるべきものである。また、第1、第2の艶調整層5、6に用いられる艶消し剤および樹脂組成物は、同じでも異なっていてもよい。これらは凹凸感および各種要求特性から自由に選択することができる。
さらに、基材2と柄インキ層4との間には、求められる意匠に応じて、基材2の第1の艶調整層5側の面の全面を被覆する下地インキ層3を設けるようにしてもよい。また、下地インキ層3は、隠蔽性等、必要に応じて2層以上の多層としてもよい。さらに、柄インキ層4は、求められる意匠を表現するために必要な分版の数だけ積層して形成してもよい。このように、柄インキ層4と下地インキ層3とは、求められる意匠、つまり、表現したい意匠に応じて様々な組み合わせとなるが、特に限定されるものではない。
また、下地インキ層3および柄インキ層4には、各種機能を付与するために、例えば、体質顔料、可塑剤、分散剤、界面活性剤、粘着付与剤、接着助剤、乾燥剤、硬化剤、硬化促進剤および硬化遅延剤等の機能性添加剤を添加してもよい。
(1)以上のように、本実施形態の化粧材1では、第1の艶調整層5と第2の艶調整層6とのうち、相対的に艶の低い艶調整層に、粒径がその層厚の1.0倍以上、より好ましくは1.1倍以上の艶消し剤を添加するようにした。それゆえ、艶調整層の表面に十分な凹凸を付与することができるため、斜めからの観察においても光沢度が上昇せず、低光沢を維持することができる。そのため、斜めから観察しても、艶の差により得られる凹凸感が変化し難い化粧材1を提供できる。
なお、本実施形態では、第2の艶調整層6が柄インキ層4と重なる部分に形成され、柄インキ層4の柄模様と第2の艶調整層6の艶とが同調している例を示したが、他の構成を採用することもできる。例えば、図2に示すように、第2の艶調整層6が柄インキ層4の直上以外の部分に形成され、柄インキ層4の柄模様と第1の艶調整層5の艶とが同調していてもよい。これにより、柄インキ層4の柄模様に、露出している第1の艶調整層5の艶が付与され、柄インキ層4による意匠性に第1の艶調整層5による意匠性を付加できる。それゆえ、天然木や天然石に近い高級感のある意匠表現を有した化粧材1を形成できる。
<実施例1>
実施例1では、坪量50g/m2の含浸紙(GFR-506:興人(株)製)を基材2として用いた。そして、基材2の一方の面に、油性硝化綿樹脂系グラビア印刷インキ(PCNT(PCRNT)各色:東洋インキ(株)製)を使用して、下地インキ層3と、柄インキ層4とをこの順に形成した。柄インキ層4の柄模様は、木目柄とした。
実施例2では、柄インキ層4を形成した基材2上に、第1の艶調整層5用のインキを基材2の一方の面の全面を被覆するように塗布し、第1の艶調整層5を形成した。インキは、アクリルポリオール(6KW-700:大成ファインケミカル(株)製)100質量部に対して、シリカ系艶消し剤(ACEMATT OK900:エボニック社製)8質量部、ポリイソシアネート(UR190B硬化剤:東洋インキ(株)製)10質量部から構成した。シリカ系艶消し剤の平均粒径は7.5μmとした。また、インキの塗布量は7g/m2とした。層厚は断面観察の結果、6.5μmであった。次に、第2の艶調整層6用のインキを、第1の艶調整層5上であって、柄インキ層4の直上となる部分にのみ塗布することで、第2の艶調整層6を形成した。インキは、アクリルポリオール(6KW-700:大成ファインケミカル(株)製)100質量部に対して、平均粒径7.5μmのシリカ系艶消し剤(ACEMATT OK900:エボニック社製)3質量部、ポリイソシアネート(UR190B硬化剤:東洋インキ(株)製)10質量部から構成した。それ以外は実施例1と同様の構成とした。
実施例3では、柄インキ層4を形成した基材2上に、第1の艶調整層5用のインキを基材2の一方の面の全面を被覆するように塗布し、第1の艶調整層5を形成した。インキは、アクリルポリオール(6KW-700:大成ファインケミカル(株)製)100質量部に対して、シリカ系艶消し剤(ACEMATT 810:エボニック社製)8質量部、ポリイソシアネート(UR190B硬化剤:東洋インキ(株)製)10質量部から構成した。シリカ系艶消し剤の平均粒径は10.5μmとした。また、インキの塗布量は9.5g/m2とした。層厚は断面観察の結果、9.3μmであった。次に、第2の艶調整層6用のインキを、第1の艶調整層5上であって、柄インキ層4の直上となる部分にのみに塗布することで、第2の艶調整層6を形成した。インキは、アクリルポリオール(6KW-700:大成ファインケミカル(株)製)100質量部に対して、平均粒径10.5μmのシリカ系艶消し剤(ACEMATT 810:エボニック社製)3質量部、ポリイソシアネート(UR190B硬化剤:東洋インキ(株)製)10質量部から構成した。それ以外は実施例1と同様の構成とした。
比較例1では、柄インキ層4を形成した基材2上に、実施例1と同じ組成の第1の艶調整層5用のインキを塗布量3.5g/m2となるように基材2の一方の面の全面を被覆するように塗布した。それ以外は実施例1と同様に第1の艶調整層5および第2の艶調整層6を形成し、化粧材1を得た。なお、このときの第1の艶調整層5の層厚は、断面観察の結果、3.3μmであった。
比較例2では、柄インキ層4を形成した基材2上に、実施例2と同じ組成の第1の艶調整層5用のインキを塗布量8.5g/m2となるように基材2の一方の面の全面を被覆するように塗布した。それ以外は実施例2と同様に第1の艶調整層5および第2の艶調整層6を形成し、化粧材1を得た。なお、このときの第1の艶調整層5の層厚は、断面観察の結果、8.4μmであった。
比較例3では、柄インキ層4を形成した基材2上に、実施例3と同じ組成の第1の艶調整層5用のインキを塗布量11.5g/m2となるように基材2の一方の面の全面を被覆するように塗布した。それ以外は実施例3と同様に第1の艶調整層5および第2の艶調整層6を形成し、化粧材1を得た。なお、このときの第1の艶調整層5の層厚は、断面観察の結果、11.2μmであった。
以上の実施例1~3、比較例1~3について、意匠性と光沢度の評価を行った。
<意匠性>
正面および斜めから化粧材1の意匠性を観察した。そして、あらゆる角度から凹凸感が見られる場合を「○」、斜めからの観察で凹凸感が減少する場合を「△」、斜めからの観察で凹凸感が見られなくなる場合を「×」とした。
<光沢度>
第1の艶調整層5、つまり、相対的に艶の低い艶調整層における20°、60°、85°の光沢度を測定した。
以上の結果から、実施例1~3の化粧材は、あらゆる角度から観察しても、艶の差により得られる凹凸感が一定で、優れた意匠の化粧材1であることが明らかとなった。
なお、本発明の化粧材は、上記の実施形態および実施例に限定されるものではなく、発明の特徴を損なわない範囲において種々の変更が可能である。
2 基材
3 下地インキ層
4 柄インキ層
5 第1の艶調整層
6 第2の艶調整層
Claims (8)
- 基材上に設けられた第1の艶調整層と、前記第1の艶調整層上に部分的に設けられ、前記第1の艶調整層の艶と異なる艶を有する第2の艶調整層とを備え、
前記第1の艶調整層と前記第2の艶調整層とのうち、相対的に艶の低い艶調整層に、粒径が層厚の1.0倍以上の艶消し剤が添加されていることを特徴とする化粧材。 - 前記基材と前記第1の艶調整層との間に設けられた柄インキ層を更に備え、
前記第2の艶調整層は、前記柄インキ層と重なる部分に形成され、前記柄インキ層の柄模様と前記第2の艶調整層の艶とが同調していることを特徴とする請求項1に記載の化粧材。 - 前記基材と前記第1の艶調整層との間に設けられた柄インキ層を更に備え、
前記第1の艶調整層は、前記基材の前記第1の艶調整層側の面の全面を被覆しており、
前記第2の艶調整層は、前記柄インキ層の直上以外の部分に形成され、前記柄インキ層の柄模様と前記第1の艶調整層の艶とが同調していることを特徴とする請求項1に記載の化粧材。 - 前記艶消し剤は、無機材料からなることを特徴とする請求項1から3のいずれか1項に記載の化粧材。
- 前記艶消し剤は、前記艶消し剤が添加された前記艶調整層を構成する樹脂組成物100質量部に対して、5質量部以上40質量部以下の範囲内で添加されていることを特徴とする請求項1から4のいずれか1項に記載の化粧材。
- 前記艶消し剤は、相対的に艶の高い艶調整層にも添加されていることを特徴とする請求項1から5のいずれか1項に記載の化粧材。
- 前記艶消し剤の粒径は、2μm以上15μm以下の範囲内であることを特徴とする請求項1から6のいずれか1項に記載の化粧材。
- 前記艶消し剤の粒径は、前記艶消し剤が添加された前記艶調整層の層厚の3.0倍以下であることを特徴とする請求項1から7のいずれか1項に記載の化粧材。
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017113035A1 (de) * | 2017-06-13 | 2018-12-13 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und Vorrichtung zur Herstellung einer dekorativen Oberfläche |
WO2019135360A1 (ja) * | 2018-01-05 | 2019-07-11 | 凸版印刷株式会社 | 化粧材 |
EP3415317B1 (de) | 2017-06-13 | 2020-02-26 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und vorrichtung zur herstellung einer dekorativen oberfläche |
EP3415316B1 (de) | 2017-06-13 | 2020-04-08 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und vorrichtung zur erzeugung einer strukturierten oberfläche |
WO2022202113A1 (ja) * | 2021-03-26 | 2022-09-29 | 日清食品ホールディングス株式会社 | 発泡紙積層体 |
US11559824B2 (en) | 2019-05-03 | 2023-01-24 | Hymmen Gmbh Maschinen-Und Anlagenbau | Method for producing a structure on a surface |
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EP3466677A4 (en) * | 2016-05-26 | 2019-12-11 | Toppan Printing Co., Ltd. | DECORATIVE MATERIAL |
CN110920200B (zh) * | 2019-12-27 | 2022-11-22 | 重庆巧琢工贸发展有限公司 | 一种具有局部哑光效果的食品包装复合膜 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08300595A (ja) * | 1995-05-11 | 1996-11-19 | Nissha Printing Co Ltd | 木目柄装飾シートおよびこれを用いた木目柄ラミネート製品の製造方法 |
JP2001138470A (ja) * | 1999-11-17 | 2001-05-22 | Dainippon Printing Co Ltd | 耐摩耗性を有する化粧材 |
JP2001315286A (ja) * | 2000-05-11 | 2001-11-13 | Toppan Printing Co Ltd | 化粧材 |
JP2008087269A (ja) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | 化粧シート |
JP2014069446A (ja) * | 2012-09-28 | 2014-04-21 | Dainippon Printing Co Ltd | 加飾シート、及び加飾樹脂成型品 |
JP2017065261A (ja) * | 2015-09-28 | 2017-04-06 | 大日本印刷株式会社 | 化粧シート、化粧板及び加飾樹脂成形品 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57115717A (en) | 1981-01-09 | 1982-07-19 | Furukawa Electric Co Ltd | Method of producing metallic coated wire strand |
JP3629964B2 (ja) | 1998-07-29 | 2005-03-16 | 凸版印刷株式会社 | 化粧材 |
JP3388437B2 (ja) * | 2000-02-18 | 2003-03-24 | 大日本印刷株式会社 | 化粧シート |
JP4289548B2 (ja) * | 2003-07-28 | 2009-07-01 | 大日本印刷株式会社 | 接触適性を付与した化粧材 |
CN100528558C (zh) * | 2003-09-30 | 2009-08-19 | 大日本印刷株式会社 | 装饰材料 |
US8597793B2 (en) | 2008-06-30 | 2013-12-03 | Dai Nippon Printing Co., Ltd. | Decorative sheet, process for producing decorative resin molded product, and decorative resin molded product |
JP6171459B2 (ja) * | 2013-03-26 | 2017-08-02 | 大日本印刷株式会社 | 化粧シート |
JP6369084B2 (ja) * | 2014-03-25 | 2018-08-08 | 大日本印刷株式会社 | 化粧シート及びこれを用いた化粧板 |
EP3466677A4 (en) * | 2016-05-26 | 2019-12-11 | Toppan Printing Co., Ltd. | DECORATIVE MATERIAL |
WO2018084267A1 (ja) * | 2016-11-02 | 2018-05-11 | 凸版印刷株式会社 | 化粧材 |
-
2017
- 2017-05-26 EP EP17802947.6A patent/EP3466677A4/en active Pending
- 2017-05-26 JP JP2018519656A patent/JP6958550B2/ja active Active
- 2017-05-26 KR KR1020187034371A patent/KR102345151B1/ko active IP Right Grant
- 2017-05-26 WO PCT/JP2017/019815 patent/WO2017204361A1/ja unknown
- 2017-05-26 CN CN201780031766.8A patent/CN109153241B/zh active Active
-
2018
- 2018-11-19 US US16/194,602 patent/US10946610B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08300595A (ja) * | 1995-05-11 | 1996-11-19 | Nissha Printing Co Ltd | 木目柄装飾シートおよびこれを用いた木目柄ラミネート製品の製造方法 |
JP2001138470A (ja) * | 1999-11-17 | 2001-05-22 | Dainippon Printing Co Ltd | 耐摩耗性を有する化粧材 |
JP2001315286A (ja) * | 2000-05-11 | 2001-11-13 | Toppan Printing Co Ltd | 化粧材 |
JP2008087269A (ja) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | 化粧シート |
JP2014069446A (ja) * | 2012-09-28 | 2014-04-21 | Dainippon Printing Co Ltd | 加飾シート、及び加飾樹脂成型品 |
JP2017065261A (ja) * | 2015-09-28 | 2017-04-06 | 大日本印刷株式会社 | 化粧シート、化粧板及び加飾樹脂成形品 |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11141759B2 (en) | 2017-06-13 | 2021-10-12 | Hymmen GmbH Maschinen- und Anlagesbas | Method and apparatus for producing a decorative surface |
US11717850B2 (en) | 2017-06-13 | 2023-08-08 | Hymmen Gmbh Maschinen-Und Anlagenbau | Method and apparatus for producing a decorative workpiece and workpiece |
EP3415317B2 (de) † | 2017-06-13 | 2023-09-06 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und vorrichtung zur herstellung einer dekorativen oberfläche |
DE102017113035B4 (de) * | 2017-06-13 | 2019-10-31 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und Vorrichtung zur Herstellung einer dekorativen Oberfläche |
EP3415317B1 (de) | 2017-06-13 | 2020-02-26 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und vorrichtung zur herstellung einer dekorativen oberfläche |
EP3415316B1 (de) | 2017-06-13 | 2020-04-08 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und vorrichtung zur erzeugung einer strukturierten oberfläche |
EP3666525A1 (de) | 2017-06-13 | 2020-06-17 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren zur erzeugung einer strukturierten oberfläche |
DE102017113035A1 (de) * | 2017-06-13 | 2018-12-13 | Hymmen GmbH Maschinen- und Anlagenbau | Verfahren und Vorrichtung zur Herstellung einer dekorativen Oberfläche |
US11883843B2 (en) | 2017-06-13 | 2024-01-30 | Hymmen Gmbh Maschinen-Und Anlagenbau | Method for producing a structured surface |
US11717851B2 (en) | 2017-06-13 | 2023-08-08 | Hymmen GmbH Maschinen—und Anlagenbau | Method and apparatus for producing a decorative workpiece and workpiece |
US11511318B2 (en) | 2017-06-13 | 2022-11-29 | Hymmen GmbH Maschinen- und Anlagenbau | Method and apparatus for producing a decorative workpiece and workpiece |
US11420229B2 (en) | 2017-06-13 | 2022-08-23 | Hymmen GmbH Maschinen—und Anlagenbau | Method and apparatus for producing a decorative surface |
JP7003667B2 (ja) | 2018-01-05 | 2022-02-10 | 凸版印刷株式会社 | 化粧材 |
CN111556805A (zh) * | 2018-01-05 | 2020-08-18 | 凸版印刷株式会社 | 装饰材料 |
WO2019135360A1 (ja) * | 2018-01-05 | 2019-07-11 | 凸版印刷株式会社 | 化粧材 |
US11084309B2 (en) | 2018-01-05 | 2021-08-10 | Toppan Printing Co., Ltd. | Decorative material |
JP2019119138A (ja) * | 2018-01-05 | 2019-07-22 | 凸版印刷株式会社 | 化粧材 |
EP3736124A4 (en) * | 2018-01-05 | 2021-03-03 | Toppan Printing Co., Ltd. | DECORATIVE MATERIAL |
US11559824B2 (en) | 2019-05-03 | 2023-01-24 | Hymmen Gmbh Maschinen-Und Anlagenbau | Method for producing a structure on a surface |
WO2022202113A1 (ja) * | 2021-03-26 | 2022-09-29 | 日清食品ホールディングス株式会社 | 発泡紙積層体 |
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