WO2017180453A1 - Composition de fragrance - Google Patents

Composition de fragrance Download PDF

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Publication number
WO2017180453A1
WO2017180453A1 PCT/US2017/026489 US2017026489W WO2017180453A1 WO 2017180453 A1 WO2017180453 A1 WO 2017180453A1 US 2017026489 W US2017026489 W US 2017026489W WO 2017180453 A1 WO2017180453 A1 WO 2017180453A1
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WIPO (PCT)
Prior art keywords
alkyl
ethanol
water
fragrance
fragrance composition
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Application number
PCT/US2017/026489
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English (en)
Inventor
Florin Iosif VLAD
Stephanie Voorhees HAKES
Matthew MEEHAN
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Ungerer And Company
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Publication date
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Publication of WO2017180453A1 publication Critical patent/WO2017180453A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/347—Phenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00—Formulations or additives for perfume preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients

Definitions

  • the invention is directed to an ethanol-free fragrance composition.
  • the composition can be in concentrated and ready-to-use (RTU) forms.
  • Fragrance compositions typically use an alcohol, such as ethanol, as a solvent because the fragrance component, such as an essential oil, dissolve well in alcohol.
  • ethanol is a harsh chemical and classified as a volatile organic compound ("VOC”); a compound defined, for example, by the Environmental Protection Agency, or by EC Directive 1999/13/EC (Solvent Emissions Directive) as an organic compound having a vapour pressure of 0.01 kPa or more at 293.15 K (20°C), or having a corresponding volatility under particular conditions of use.
  • VOC volatile organic compound
  • ethanol is an ideal solvent for perfumery ingredients, e.g. it evaporates rapidly and does not hedonically interfere with the odor of the perfume in applications.
  • Another key characteristic of ethanol is its wetting power, which allows good spreadability of the perfume on the skin and in turn controls the diffusion of the perfume at a later step.
  • the fast evaporation of ethanol also adds a somewhat refreshing aspect to the formulation; a characteristic that is highly appreciated by the customer.
  • Water-based fragrance formulations are an alternative to ethanol-based compositions. But water-based formulations also suffer from a number of disadvantages. These disadvantages include, for example, restrictions in fragrance creation due to water solubility issues of perfuming ingredients; limitations on the amount of fragrance that can be employed due to fragrance solubility or solubilization issues; the need of large amounts of solubilizers and surfactants that raise safety, environmental and regulatory issues; undesirable skin feel such as tackiness and oilyness; unacceptable fragrance performance such as spray atomization or diffusion through delivery devices such as wicks or reeds; and surface staining upon application.
  • disadvantages include, for example, restrictions in fragrance creation due to water solubility issues of perfuming ingredients; limitations on the amount of fragrance that can be employed due to fragrance solubility or solubilization issues; the need of large amounts of solubilizers and surfactants that raise safety, environmental and regulatory issues; undesirable skin feel such as tackiness and oilyness; unacceptable fragrance performance such as spray atomization or diffusion through
  • the present invention is directed to an ethanol-free fragrance composition, comprising:
  • fragrance selected from the group consisting of fragrance ingredients, flavor ingredients, essential oils, natural extracts, or a mixture thereof, and optionally fragrance miscible or partial miscible cosmetic ingredients selected from the group consisting of emollients, humectants, cooling agents, vitamins, antioxidants, dyes, pigments, preservatives, UV-blockers and specialty ingredients selected from the group consisting of malodor counteracting ingredients or insect repelling agents;
  • phase transfer carrier at a weight ratio of 1 :9 to 1 : 1 versus total amount of fragrance and capable of self-segregating in water into organized clusters
  • an ethanol-free water modulator at a weight concentration of 5-95% of said fragrance composition comprising: (i) an interfacial modulator at weight ratio 1 :5 to 10: 1 versus total amount of fragrance, comprised of a miscible or partial miscible antimicrobial composition or a mixture thereof, and (ii) a water disrupting solvent at a weight concentration 10-90%o versus total amount of water modulator, comprised of one or more water miscible, or partial miscible, hydrotropic or hydrophilic solvent, or mixture of such solvents, having surface tension values less than 60 mN/m measured at 20-25°C and atmospheric pressure 760 mm Hg; and
  • the invention is also directed to consumer articles or products comprising the ethanol- free fragrance composition and methods of using the composition.
  • the invention provides for an ethanol-free, clear or translucent, temperature stable, fragrance composition, alternative referred to herein as the "composition,” “formulation” or the "functional fragrance.”
  • the functional fragrance (alternatively referred to herein as “fragrance,” “parfume” or “perfume”) in the composition self- transfers into water, either by direct dilution or by dispersion, through a dual solvency- solubilization mechanism without the need of applying external forces such as high shear mixing, high pressure, or PIT.
  • the functional fragrance comprises (i) 0.1 to 95% by weight fragrance, also referred in the invention as perfume or perfumee, which fragrance contains at least 0.1% by weight one or more fragrance ingredients, flavor ingredients, essential oils, natural extracts, or a mixture thereof, and optionally fragrance miscible cosmetic ingredients such as emollients, humectants, cooling agents, antioxidants, antibacterial agents, dyes, UV- blockers, or specialty ingredients such as malodor neutralizing, counteracting ingredients or insect repelling agents, (ii) a phase transfer carrier at a weight ratio 1 :9 to 1 :1 versus total amount of fragrance, (iii) an ethanol-free, water modulator at the weight concentration 5-95% versus fragrance composition, and (iv) optionally, up to 20% by weight water.
  • fragrance also referred in the invention as perfume or perfumee
  • fragrance contains at least 0.1% by weight one or more fragrance ingredients, flavor ingredients, essential oils, natural extracts, or a mixture thereof, and optionally fragrance miscible cosmetic ingredients such as emolli
  • the aforementioned phase transfer carrier can include, for example, at least one, or more, associative ionic, non-ionic amphiphilic molecules, or a mixture thereof.
  • the phase transfer carrier is capable of self-segregating in water into organized clusters or aggregates such as micelles or to self-structure into water-dispersible lamellar, cubical, or hexagonal crystal liquid morphologies.
  • the ethanol-free water modulator of the invention can be, for example, of two parts: (i) an interfacial modulator at a weight ratio 1 :5 to 10: 1 versus total amount of fragrance, which is a fragrance miscible or partial miscible antimicrobial composition, and (ii) a water disrupting solvent at a weight concentration of 1-95% versus total amount of water modulator, which is comprised of at least one or more, water miscible, or partial miscible, hydrotropic or hydrophilic solvent, or mixture of such solvents, having surface tension values less than 60 mN/m while, surface tension values measured under normal conditions, where herein normal conditions mean room temperature 20-25°C and atmospheric pressure 760 mm Hg.
  • the water-based products or articles created by the incorporation of the functional fragrance of the invention also alternatively referred to herein as the "perfuming compositions", benefit from the presence of the interfacial modulator for at least two reasons: (i) unexpectedly, and surprisingly, the interfacial modulator allows for the lowering of the amount of the phase transfer carrier, while also allowing for the customization of the using level of fragrance into perfuming composition; and (ii) the perfuming compositions containing this interfacial modulator self-preserve in water, with no need to add extra antimicrobial agents.
  • Embodiments of the invention include, for example, any article or product associated with the functional fragrance, obtained by direct use of the said functional fragrance, or simply by dilution with water or dispersion in water.
  • Other embodiments of the invention include methods of manufacturing such an article or product.
  • the functional fragrance of this invention can be directly diluted with water, or can be dispersed in water by gentle mixing, with no need to apply any external mixing force such as high pressure, high shear, or temperature phase inversion (PIT), to form a low viscosity, sprayable, or capillary wicking product or article.
  • PIT temperature phase inversion
  • the ethanol-free, self-water-transfer fragrance composition of the invention can be formulated under no restriction rules into skin, hair, home care and environmentally-safe products or articles, and allows the customization of the fragrance level in products or articles.
  • a further feature of the present invention is that the herein protected functional fragrance has a high flash point, which makes it safe in handling and transportation; low viscosity; and excellent clarity and stability over wide temperature ranges.
  • the functional fragrance of the invention can accept certain amounts of functionalized oil- or water-soluble cosmetic ingredients, such as antioxidants, moisturizers, emollients, vitamins, UV stabilizers, dyes, or specialty ingredients such as malodor counteracting ingredients or insect or animal repelling agents.
  • the perfuming products created based on the functional fragrance of this invention are safer, greener and have better performance characteristics than most petrochemical solvent based similar products or articles such as perfumes, cosmetic formulations, air fresheners, household products, I&I products.
  • the instant invention is distinguishable over other formulations in the art because of at least two aspects: a formulation aspect and a processing aspect.
  • the formulation aspect is related to the fragrance formulation strategy, which is a novel, two-part fragrance formulation strategy to build a self-water-transferable functional fragrance.
  • the first part includes, for example, a fragrance oil and "phase transfer carrier", while the second part is comprised of a "water modulator". When the two parts are mixed together, the result is the functional fragrance.
  • This fragrance formulation strategy leads to an unexpected dual solvency-solubilization mechanism which allows for the direct transfer of functional fragrance into water, to form a single-phase, isotropic, clear or translucent, temperature stable perfuming product or article, without the need to apply external mixing forces, such as high shear, high pressure or PIT.
  • the processing aspect relates to the processing of the functional fragrance by direct dilution with water or by dispersion in water by gentle mixing with no need to apply external forces such as high shear, high pressure, and phase inversion temperature.
  • a key element of the invention is the antimicrobial interfacial modulator.
  • the antimicrobial modulator of the invention functions to: (i) formulate fragrances with unusual and unexpected properties when are transferred in water, and (ii) transfers fragrances in water, or to handle the fragrances and water mixing process in unusual and unexpected ways.
  • the inventors were able to: (i) handle the fragrance as a fragrance "concentrate”, referred to herein as a functional fragrance, which self-disperses in water or is a self-water dilutable fragrance; (ii) dilute the functional fragrance or disperse the functional fragrance in water to form a RTU clear or translucent, single- phase, temperature stable perfuming products or articles that display unusual low viscosity, sprayable, spreadable, skin feeling, skin benefits, hair deposition or capillary wicking properties with no need to apply external mixing forces such as high shear, high pressure or PIT; and (iii) reduce the level of phase transfer carrier needed to transfer the fragrance in water at desired and customized levels, with no ingredient restrictions in fragrance creation and limited restrictions in selection of optional fragrance miscible ingredients; (iv) formulate stable perfuming products or articles with no need to add extra antimicrobial agents.
  • the functional fragrance has three parts.
  • the first part, named fragrance comprises 0.1-95% w/w of the entire fragrance formula.
  • the fragrance can include, for example, fragrance ingredients typically used in the art, flavor ingredients, essential oils, natural extracts or a combination of them, and optionally fragrance miscible or partial miscible cosmetic ingredients such as emollients, humectants, cooling agents, vitamins, dyes, pigments, antioxidants, preservatives, UV-blockers, or specialty ingredients such as malodor counteracting ingredients or insect or animal repelling agent.
  • fragrance ingredients is defined as fragrance components commonly employed in the art in an appropriate combination, such as ketones, aldehydes, esters, alcohols, ethers, terpenes, natural essential oils, and synthetic musk.
  • fragrance ingredients that can be used in the invention are not limited in kind and include those usually used in various products, such as preparations for external application (e.g., cosmetics and pharmaceuticals), cleansers for human body, clothes, and hard surfaces, bleachers, and softeners.
  • Useful fragranced ingredients include, for example, synthetic ones and natural ones of animal or plant origin.
  • hydrocarbons such as aliphatic hydrocarbons, terpene hydrocarbons, and aromatic hydrocarbons
  • alcohols such as aliphatic alcohols, terpene alcohols, and aromatic alcohols
  • ethers such as aliphatic ethers and aromatic ethers
  • oxides such as aliphatic oxides and terpene oxides
  • aldehydes such as aliphatic aldehydes, terpene aldehydes, hydrogenated aromatic aldehydes, thioaldehydes, and aromatic aldehydes
  • ketones such as aliphatic ketones, terpene ketones, hydrogenated aromatic ketones, cyclic ketones, and aromatic ketones
  • acids such as fatty acids, hydrogenated aromatic carboxylic acids, and aromatic carboxylic acids
  • lactones such as aliphatic lactones, macrocyclic lactones, terpene lac
  • fragranced ingredients useful in the invention are listed as follows: C 6 -C 12 Aldehydes, anisaldehyde, acetal R, acetophenone, acetylcedrene, adoxal, allylamyl glycolate, allyl cyclohexanepropionate, a-damascone, ⁇ -damascone, ⁇ -damascone, ambrettolide, ambroxan, amylcinnamic aldehyde, amylcinnamic aldehyde dimethylacetal, amyl valerianate, amyl salicylate, isoamyl acetate, isoamyl salicylate, aurantiol, acetyl eugenol, bacdanol, benzyl acetate, benzyl alcohol, benzyl salicylate, bergamyl acetate, bornyl acetate, butyl butyrate,
  • the second part of the functional fragrance is a phase transfer carrier at a weight ratio 1 :9 to 1 : 1 versus entire fragrance formula.
  • the phase transfer carrier is comprised of one or more associative ionic, non-ionic amphiphilic molecules, or mixture of them, capable to self-structure in water presence into organized clusters or aggregates such as micelles, or to self-segregate into lamellar, or cubical, or hexagonal crystal liquid morphologies.
  • the phase transfer carrier can include, for example, ionic or non-ionic surfactants, humectants, solubilizers, or mixture thereof, is selected from the group consisting of: C 8-18 alkyl sarcosinates, C 8 .
  • alkyl taurates C 10 .i8 alkyl and di-alkyl sulfosuccinates, C 10 .i8 alkyl sulfones, C 10 . 18 alkyl phosphates, C 8-18 alkyl sulfates and alkyl ether sulfates, C 8-1 6 sulphated alcanolamides, Cio-is alkyl, alkyl aryl and alkyl ether sulphonates, C 8 .i8 alkyl and alky ether carboxylates, C 8 .i6 alkyl amino-oxides, C 8-18 ethoxylated alcohols, C 8 . 18 ethoxylated sorbitols, C 8 -i6 ethoxylated polyglycols, C 8-16 polyglucosides, alkyl quaternary amino acids and C 8- 25 alkyl betaines.
  • phase transfer carrier ingredients from the above mentioned classes are as follows:
  • anionic amphiphilic molecules include, for example, fatty acid soaps, such as soap bases, sodium laurate, and sodium palmitate; higher alkylsulfuric ester salts, such as sodium laurylsulfate and potassium lauryl sulfate; alkyl ether sulfuric ester salts, such as triethanolamine POE laurylsulfate and sodium POE laurylsulfate; N-acylsarcosinic acids, such as sodium lauroylsarconinate, higher fatty acid amidosulfonates, such as sodium N- myristoyl-N-methyltaurine, sodium palm oil fatty acid methyltauride, and sodium laurylmethyltauride; phosphoric ester salts, such as sodium POE oleyl ether phosphate and POE stearyl ether phosphate; sulfosuccinates, such as sodium di-2- ethylhexylsulfosuccinate, sodium POE monol
  • cationic amphiphilic molecules include, for example, alkyltrimethylammonium salts, such as stearyltrimethylammonium chloride and lauryltrimethylammonium chloride; dialkyldimethylammonium salts, such as distearyldimethylammonium chloride, alkylpyridinium salts, such as poly-N,N'-dimethyl-3,5-methylenepiperidinium chloride; alkyl quaternary ammonium salts, alkyldimethylbenzylammonium salts, alkylisoquinolinium salts, dialkylmorpholinium salts, POE alkylamines, alkylamine salts, polyamine fatty acid derivatives, amyl alcohol fatty acid derivatives, benzalkonium chloride, and benzethonium chloride;
  • alkyltrimethylammonium salts such as stearyltrimethylammonium chloride and lauryltrimethylammonium chloride
  • amphoteric amphiphilic molecules include, for example, imidazoline surfactants, such as sodium 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline and disodium 2-cocoyl-2-imidazolinium hydroxide-l-carboxyethyloxy; and betaines, such as 2- heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, alkyl betaines, amide betaines, and sulfobetaines;
  • imidazoline surfactants such as sodium 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline and disodium 2-cocoyl-2-imidazolinium hydroxide-l-carboxyethyloxy
  • betaines such as 2- heptadecyl-N-carboxymethyl-N-hydroxyethylimidazo
  • lipophilic nonionic amphiphilic molecules include, for example, sorbitan fatty acid esters, such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, and diglycerol sorbitan tetra-2-ethylhexylate; glycerol or polyglycerol fatty acids esters, such as glycerol mono-cotton seed oil fatty acid ester, glycerol monoerucate, glycerol sesquioleate, glycerol monostearate, glycerol ⁇ , ⁇ '-oleate pyroglutamate, and glycerol monostearate maleate; propylene glycol fatty acid esters, such as propy
  • hydrophilic nonionic amphiphilics include, for example, POE sorbitan fatty acid esters, such as POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monooleate, and POE sorbitan tetraoleate; POE sorbitol fatty acid esters, such as POE sorbitol monolaurate, POE sorbitol monooleate, POE sorbitol pentaoleate, and POE sorbitol monostearate; POE glycerol fatty acid esters, such as POE glycerol monostearate, POE glycerol monoisostearate, and POE glycerol triisostearate; POE fatty acid esters, such as POE monooleate, POE distearate, POE monodioleate, and ethylene glycol distearate; POE alkyl ethers, such as POE
  • the third part of the functional fragrance of the invention is an ethanol-free water modulator that represents 5% to 95% by weight of the entire functional fragrance.
  • the water modulator can comprise (i) water miscible, or partial miscible interfacial modulator at weight ratio 1 :5 to 10: 1 versus total amount of fragrance, selected from antimicrobial molecules such as phenoxyethanol, glycols, geminal diols, dialkyl-alkyl diols, alkyl or dialkyl-salicylates or combination of those, and (ii) a water disrupting solvent, at weight concentration 10-90% versus total amount of water modulator, which is a linear, branched, cyclic, or aromatic mono-, di- or poly-alcohols, ethoxylated alcohols, alcohol derivatives with at least one hydroxyl group, poly- glycol-ethers, or any combination of those, and optionally hydrotropic organic salts such as benzoates, hydroxyl benzoates, carboxyl amino pyrrolidon
  • Non-limiting examples of suitable solvents from the above mentioned classes are as follows: ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3- butylene glycol, tetram ethylene glycol, 2,3-butylene glycol, pentam ethylene glycol, 2-butene- 1,4-diol, hexylene glycol, and octylene glycol; trihydric alcohols, such as glycerol, trimethylolpropane, and 1,2,6-heanetriol; tetrahydric alcohols, such as pentaerythritol; pentahydric alcohols, such as xylitol, hexahydric alcohols, such as sorbitol and mannitol; polyhydric alcohols, such as diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerol, polyethylene glycol, trig
  • an ethanol-free fragrance composition comprising:
  • fragrance selected from the group consisting of fragrance ingredients, flavor ingredients, essential oils, natural extracts, or a mixture thereof, and optionally fragrance miscible or partial miscible cosmetic ingredients selected from the group consisting of emollients, humectants, cooling agents, vitamins, antioxidants, dyes, pigments, preservatives, UV-blockers and specialty ingredients selected from the group consisting of malodor counteracting ingredients or insect repelling agents;
  • phase transfer carrier at a weight ratio of 1 :9 to 1 : 1 versus total amount of fragrance and capable of self-segregating in water into organized clusters
  • an ethanol-free water modulator at a weight concentration of 5-95% of said fragrance composition comprising: (i) an interfacial modulator at weight ratio 1 :5 to 10: 1 versus total amount of fragrance, comprised of a miscible or partial miscible antimicrobial composition or a mixture thereof, and (ii) a water disrupting solvent at a weight concentration 10-90%) versus total amount of disrupting water modulator, comprised of one or more water miscible, or partial miscible, hydrotropic or hydrophilic solvent, or mixture of such solvents, having surface tension values less than 60 mN/m measured at 20-25°C and atmospheric pressure 760 mm Hg; and
  • an ethanol-free fragrance composition wherein said phase transfer carrier comprises ionic or non-ionic surfactants, humectants, solubilizers, or mixture thereof, selected from the group consisting of: C 8 .i 8 alkyl sarcosinates, Cs-is alkyl taurates, C 10 .i8 alkyl and di-alkyl sulfosuccinates, w.n alkyl sulfones, Cio-18 alkyl phosphates, C 8-18 alkyl sulfates and alkyl ether sulfates, C 8-16 sulphated alcanolamides, C 10 -i8 alkyl, alkyl aryl and alkyl ether sulphonates, C 8- i 8 alkyl and alky ether carboxylates, C 8-16 alkyl amino-oxides, C
  • an ethanol-free fragrance composition wherein said water modulator comprises a water disrupting solvent that contains at least one water miscible or partial miscible solvent, or mixture of solvents, which solvents have surface tension values less than 60 mN/m at 20-25°C and atmospheric pressure of 760 mmHg.
  • an ethanol-free fragrance composition wherein said interfacial modulator comprises an antimicrobial agent, an antimicrobial organic salt or a combination thereof.
  • an ethanol-free fragrance composition wherein said antimicrobial agent is phenoxyethanol, geminal diols, alkyl- or dialkyl-diols, alkyl or dialkyl-salicylates, or a mixture thereof.
  • an ethanol-free fragrance composition wherein said antimicrobial organic salt is a benzoate, hydroxyl benzoate, carboxyl amino pyrrolidone, taurate, or combinations thereof.
  • an ethanol-free fragrance composition wherein said interfacial modulator is 2-phenoxyethanol, 3-(2- ethylhexyloxypropane-1,2 diol, 1,2 hexanediol, 2-methyl-2,4-pentanediol or combinations thereof.
  • an ethanol-free fragrance composition wherein the interfacial modulator and water disrupting solvent are at a weight ratio 1 : 1 to 1 :5.
  • an ethanol-free fragrance composition wherein said optional water is deionized water further comprising functionalized water soluble ingredients selected from the group consisting of pH buffers, antioxidant agents, antimicrobial agents, dyes, preservatives, organic and inorganic salts and combinations thereof.
  • an ethanol-free fragrance composition wherein said composition has a low viscosity, is sprayable, spreadable, or capillary- wicking.
  • an ethanol-free fragrance composition wherein said optional water is least 10 % w/w relative to the total weight of the composition.
  • a consumer article comprising the ethanol-free fragrance composition of the invention.
  • the consumer article can be in the form of air freshener, textile freshener, all-purpose cleaner, perfume, hair or skin formulation.
  • a method of conferring, enhancing or modifying the odor properties of a surface selected from the group consisting of glass, tiles, textiles, wood, a kitchen or bathroom comprising the step of applying to such surfaces an olfactive amount of the ethanol-free fragrance composition of the invention.
  • the surface is glass, tiles, textiles or wood.
  • an ethanol-free fragrance composition wherein said composition is in concentrated form.
  • an ethanol-free fragrance composition wherein said composition is in ready-to-use form.
  • Such products include air freshener products with customized level of fragrance, which can be released into a surrounding environment through wicks, reeds, or any natural or synthetic porous materials over customized periods of time (Examples 1 and 2); an antimicrobial air freshener spray (Example 3); an antimicrobial surface cleaner that leaves no residual on application (Example 4); an ethanol-free, body mist with high level of natural fragrance (essential oil) and water (Example 5); an ethanol- free high fragrance load cologne (Example 6); and an ethanol-free, high fragrance load reed diffuser solution (Example 7).
  • air freshener products with customized level of fragrance which can be released into a surrounding environment through wicks, reeds, or any natural or synthetic porous materials over customized periods of time
  • an antimicrobial air freshener spray Example 3
  • an antimicrobial surface cleaner that leaves no residual on application Example 4
  • Aerosol OT-75 is sodium di-2-ethylhexylsulfosuccinate from Cytec, Inc.
  • Aerosol OT-75 is sodium di-2-ethylhexylsulfosuccinate from Cytec, Inc.
  • Aerosol OT-75 is sodium di-2-ethylhexylsulfosuccinate from Cytec, Inc.
  • Butyl Carbitol is Ethanol, 2-(2-butoxy-ethoxy) from Dow Chemical
  • Crodasinc CS-30 LQ sodium cocoyl sarcosinate from Croda
  • Aerosol OT75PG sodium dioctyl sulfosuccinate(and)pg from Solvay
  • fragrance oil free of any solvent from Ungerer and Company
  • Aerosol OT75PG sodium dioctyl sulfosuccinate(and)pg from Solvay *** Dowanol PM, methoxy isopropanol from Dow

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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Abstract

La présente invention concerne une composition de fragrance sans éthanol se présentant à la fois sous des formes concentrée et prête à l'emploi.
PCT/US2017/026489 2016-04-11 2017-04-07 Composition de fragrance WO2017180453A1 (fr)

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US201662320753P 2016-04-11 2016-04-11
US62/320,753 2016-04-11

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3669859A1 (fr) * 2018-12-20 2020-06-24 Chanel Inc. Parfums aqueux
WO2023018673A1 (fr) * 2021-08-08 2023-02-16 Elc Management Llc Compositions de parfum
US11806448B2 (en) 2018-07-31 2023-11-07 Arylessence, Inc. Freshening compositions comprising controlled release modulators

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1617914B1 (fr) * 2003-04-21 2008-10-15 Firmenich Sa Microemulsions exemptes de composes organiques volatils
US20120097754A1 (en) * 2010-10-22 2012-04-26 Florin-Joseph Vlad Water-based air freshener compositions, systems, and methods of use thereof
US8513180B2 (en) * 2010-10-25 2013-08-20 Symrise Ag Ethanol-free perfume oil microemulsion
US20150322374A1 (en) * 2012-12-13 2015-11-12 Firmenich Sa Ethanol-free microemulsion perfuming compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1617914B1 (fr) * 2003-04-21 2008-10-15 Firmenich Sa Microemulsions exemptes de composes organiques volatils
US20120097754A1 (en) * 2010-10-22 2012-04-26 Florin-Joseph Vlad Water-based air freshener compositions, systems, and methods of use thereof
US8513180B2 (en) * 2010-10-25 2013-08-20 Symrise Ag Ethanol-free perfume oil microemulsion
US20150322374A1 (en) * 2012-12-13 2015-11-12 Firmenich Sa Ethanol-free microemulsion perfuming compositions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11806448B2 (en) 2018-07-31 2023-11-07 Arylessence, Inc. Freshening compositions comprising controlled release modulators
EP3669859A1 (fr) * 2018-12-20 2020-06-24 Chanel Inc. Parfums aqueux
EP3839023A1 (fr) * 2018-12-20 2021-06-23 Chanel Inc Parfums aqueux
WO2023018673A1 (fr) * 2021-08-08 2023-02-16 Elc Management Llc Compositions de parfum

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