WO2017169940A1 - 薄鋼板およびめっき鋼板、並びに、熱延鋼板の製造方法、冷延フルハード鋼板の製造方法、熱処理板の製造方法、薄鋼板の製造方法およびめっき鋼板の製造方法 - Google Patents
薄鋼板およびめっき鋼板、並びに、熱延鋼板の製造方法、冷延フルハード鋼板の製造方法、熱処理板の製造方法、薄鋼板の製造方法およびめっき鋼板の製造方法 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
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- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
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- C21D2211/00—Microstructure comprising significant phases
- C21D2211/004—Dispersions; Precipitations
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- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
Definitions
- the present invention relates to a thin steel plate and a plated steel plate, a hot rolled steel plate manufacturing method, a cold rolled full hard steel plate manufacturing method, a heat treated plate manufacturing method, a thin steel plate manufacturing method, and a plated steel plate manufacturing method.
- Patent Document 1 discloses a method for producing a hot-dip galvanized steel sheet of 590 MPa or higher, which is precipitation strengthened by adding Nb.
- high-strength hot-dip galvanized steel sheets used for automobile structural members and reinforcing members are assembled mainly by spot welding after pressing.
- a nugget diameter by adding a high heat input to the vicinity of the occurrence of dust
- Cu and Zn melt at the interface between the electrode and the steel plate, and cracks occur in the steel plate (for example, Non-patent document 1). If such surface cracks exist, there is a high possibility of stress concentration at the time of a vehicle collision, and even if the collision absorption energy characteristic is obtained with a high yield ratio, the absorbed collision energy is reduced.
- an object of the present invention is to provide a plated steel sheet having high strength, high yield ratio, high strength, and a method for producing the same, which solves the above-mentioned problems of the prior art and has excellent elongation, hole expansibility and spot weldability. And providing a thin steel sheet necessary for obtaining the plated steel sheet, a method for producing a hot-rolled steel sheet necessary for obtaining the plated steel sheet, a method for producing a cold-rolled full hard steel sheet, and a heat treatment plate Another object is to provide a manufacturing method and a manufacturing method of a thin steel plate.
- the present inventors have controlled the volume ratio of each phase in the steel structure in order to improve elongation, hole expansibility and spot weldability while ensuring a high yield ratio.
- the present inventors have found that it is necessary to finely disperse ferrite and martensite and to finely disperse precipitates.
- the present invention is based on the above findings.
- Nb is added, and the cooling conditions during hot rolling are controlled to form Nb-based precipitates having an average particle size of 0.10 ⁇ m or less after annealing.
- the inventors have found that the crystal grain size of ferrite and martensite becomes finer.
- the present invention provides the following.
- the composition is composed of unavoidable impurities, and contains, by volume, 75 to 95% ferrite, 3 to 15% martensite, 0.5 to 10% pearlite, 10% or less non-recrystallized ferrite, It consists of a low temperature generation phase, the average crystal grain size of the ferrite is 6 ⁇ m or less, the average crystal grain size of the martensite is 3 ⁇ m or less, the average aspect ratio is 4.0 or less, and the average grain size is 0.10 ⁇ m or less.
- the component composition further includes, in mass%, Cr: 0.50% or less, Mo: 0.50% or less, Cu: 0.50% or less, Ni: 0.50% or less, B: 0.00.
- a plated steel sheet comprising a plated layer on the surface of the thin steel sheet according to any one of [1] to [3].
- the steel material having the composition according to any one of [1] to [3] has a reduction rate of 12% or more in the final pass of finish rolling, and a reduction rate of 15% in the pass before the final pass.
- the hot rolling is performed under the condition that the finish rolling finish temperature is 850 to 950 ° C.
- the first average cooling rate to the cooling stop temperature is 75 ° C./s or more
- the cooling stop temperature is 700 ° C. or less.
- the secondary cooling is performed under the condition that the second average cooling rate up to the coiling temperature is 5 ° C./s or more and less than 75 ° C./s, and the coiling temperature is 450 to 650 ° C.
- a method for producing a hot-rolled steel sheet wherein the method is wound up by a roll.
- [7] A method for producing a cold-rolled full hard steel plate, characterized by pickling and cold rolling the hot-rolled steel plate obtained by the production method according to [6].
- the cold-rolled full hard steel sheet obtained by the production method according to [7] is heated under conditions where the dew point in the temperature range of 600 ° C or higher is -40 ° C or lower and the maximum temperature is 730 to 900 ° C. And holding at the maximum temperature for 15 to 600 s, and after the holding, cooling is performed under the condition that the average cooling rate to the cooling stop temperature is 3 to 30 ° C./s and the cooling stop temperature is 600 ° C. or less.
- a method for producing a heat-treated plate characterized in that the cold-rolled full hard steel plate obtained by the production method according to [7] is heated and cooled under conditions of a heating temperature of 700 to 900 ° C.
- the heat-treated plate obtained by the production method according to [9] is heated under conditions where the dew point in the temperature range of 600 ° C. or higher is ⁇ 40 ° C. or lower and the maximum temperature is 730 to 900 ° C.
- Production of a thin steel sheet characterized by holding at an ultimate temperature for 15 to 600 s, and after that holding, cooling at an average cooling rate of 3 to 30 ° C./s until the cooling stop temperature and a cooling stop temperature of 600 ° C. or less Method.
- a method for producing a plated steel sheet comprising a plating step of plating the surface of the thin steel sheet obtained by the production method according to [8] or [10].
- the plated steel sheet obtained by the present invention has a high yield ratio, high tensile strength, high elongation, excellent hole expandability, and excellent spot weldability.
- a high yield ratio means that the yield ratio is 70% or more
- a high tensile strength means that the tensile strength is 590 MPa or more
- a high elongation means that the elongation is 28% or more.
- Excellent hole expansibility means that the hole expansion ratio is 60% or more, and excellent spot weldability is obtained when spot welding is performed at a current value reduced by 0.1 kA from the current value of dust generation. This means that surface cracks do not occur.
- the tensile strength is preferably less than 780 MPa, more preferably 700 MPa or less.
- the thin steel plate of this invention the manufacturing method of a hot-rolled steel plate, the manufacturing method of a cold-rolled full hard steel plate, the manufacturing method of a heat processing board, and the manufacturing method of a thin steel plate are intermediate
- a manufacturing method of a product or an intermediate product it contributes to the above-described improvement in properties of the plated steel sheet.
- the present invention is a thin steel plate and a plated steel plate, a method for producing a hot-rolled steel plate, a method for producing a cold-rolled full hard steel plate, a method for producing a heat-treated plate, a method for producing a thin steel plate, and a method for producing a plated steel plate.
- the thin steel plate of the present invention is an intermediate product for obtaining the plated steel plate of the present invention.
- a plated steel sheet is obtained through a manufacturing process of forming a hot-rolled steel sheet, a cold-rolled full hard steel sheet, and a thin steel sheet.
- a plated steel sheet is obtained through a manufacturing process of forming a hot-rolled steel sheet, a cold-rolled full hard steel sheet, a heat-treated sheet, and a thin steel sheet.
- the thin steel plate of the present invention is a thin steel plate in the above process.
- the manufacturing method of the hot-rolled steel sheet of the present invention is a manufacturing method until obtaining the hot-rolled steel sheet in the above process.
- the method for producing a cold-rolled full hard steel plate according to the present invention is a method for obtaining a cold-rolled full hard steel plate from a hot-rolled steel plate in the above process.
- the method for producing a heat-treated plate according to the present invention is a method for obtaining a heat-treated plate from a cold-rolled full hard steel plate in the above process in the case of the two-time method.
- the manufacturing method of the thin steel plate of the present invention is a manufacturing method until obtaining a thin steel plate from a cold-rolled full hard steel plate in the case of the one-time process, and until obtaining a thin steel plate from a heat-treated plate in the case of the two-time method. It is a manufacturing method.
- the method for producing a plated steel sheet according to the present invention is a process for obtaining a plated steel sheet from a thin steel sheet in the above process.
- the component compositions of hot-rolled steel sheet, cold-rolled full hard steel sheet, heat-treated sheet, thin steel sheet and plated steel sheet are common, and the steel structures of thin steel sheet and plated steel sheet are common.
- a thin steel plate, a plated steel plate, and a manufacturing method are common.
- the plated steel sheet or the like of the present invention is, in mass%, C: 0.05 to 0.11%, Si: 0.60% or less, Mn: 1.50 to 2.10%, P: 0.05% or less, S: 0.005% or less, Al: 0.01 to 0.10%, N: 0.010% or less, Ti: 0.005 to 0.07%, Nb: 0.01 to 0.10% And the remainder has a component composition consisting of Fe and inevitable impurities.
- the above component composition may further contain V: 0.10% or less in terms of mass%.
- the above component composition is further mass%, Cr: 0.50% or less, Mo: 0.50% or less, Cu: 0.50% or less, Ni: 0.50% or less, B: 0.01% or less And a total of Ca and / or REM: one or more selected from 0.005% or less may be contained.
- % representing the content of a component means “mass%”.
- C 0.05 to 0.11%
- C is an element effective for increasing the strength of the steel sheet and contributes to the formation of martensite and pearlite in the present invention. If the C content is less than 0.05%, it is difficult to ensure the required volume ratio of martensite. A preferable C content is 0.06% or more. On the other hand, when C is added excessively to more than 0.11%, the hardness difference between ferrite and martensite becomes large, so that the hole expandability is deteriorated and the toughness of the HAZ part at the time of spot welding is also deteriorated. Cracking occurs.
- a preferable C content is 0.10% or less.
- Si 0.60% or less Si solidifies and strengthens ferrite. For this reason, there exists a tendency for a hole expansion rate to increase in order to reduce the hardness difference with a hard phase by Si containing.
- Si is concentrated on the steel sheet surface as an oxide during annealing, so that the plating property is deteriorated.
- the toughness at the time of high temperature will also deteriorate, Therefore It becomes easy to produce
- the preferred Si content is 0.50% or less, more preferably less than 0.50, even more preferably 0.45% or less, and most preferably 0.30% or less. Although there is no particular lower limit, the Si content is preferably 0.005% or more from the viewpoint of the above hole expansion rate. In addition, even if Si content is less than 0.005%, since a hole expansion rate can be improved, a minimum is not specifically limited.
- Mn 1.50-2.10% Since Mn is useful for forming a second phase (phase other than ferrite) such as solid solution strengthening and martensite, it contributes to an increase in strength. Therefore, the Mn content needs to be 1.50% or more. On the other hand, when Mn is contained excessively, the martensitic transformation point (Ms point) of the HAZ part at the time of spot welding is lowered, so that the hardness of the HAZ part becomes high and surface cracks at the time of spot welding are likely to be generated. Therefore, the content is made 2.10% or less. Preferably it is 2.00% or less.
- P 0.05% or less P contributes to high strength by solid solution strengthening. Moreover, since the alloying speed can be controlled by alloying the hot-dip galvanized steel sheet with P, the plating property can be improved by adjusting the P content. In order to obtain the effect, the P content is preferably 0.001% or more. However, when P is contained excessively, it segregates at the grain boundary during spot welding, which promotes surface cracking during spot welding. Therefore, the P content is set to 0.05% or less. A preferable P content is 0.04% or less.
- S 0.005% or less
- a large amount of sulfide such as MnS is generated, and MnS is the starting point at the time of punching, and voids are generated. Therefore, the upper limit of the content is made 0.005%.
- a preferable S content is 0.004% or less. Although there is no lower limit in particular, extremely low S increases the steelmaking cost, so the S content is preferably 0.0003% or more.
- Al 0.01 to 0.10%
- Al is an element necessary for deoxidation, and in order to obtain this effect, it is necessary to contain 0.01% or more of Al. On the other hand, even if the Al content exceeds 0.10%, the effect is saturated, so the content is made 0.10% or less.
- a preferable Al content is 0.05% or less.
- N 0.010% or less Since N forms coarse Ti nitride or coarse Nb nitride and deteriorates the hole expanding property, it is necessary to suppress the content. If the N content exceeds 0.010%, this tendency becomes significant, so the N content is set to 0.010% or less. A preferable N content is 0.008% or less. In addition, about the preferable minimum of N content, it is 0.0005% or more from the surface of the cost on melting.
- Ti 0.005 to 0.07%
- Ti forms fine Ti-based precipitates (meaning Ti carbide, nitride, carbonitride. At least one of carbide, nitride, and carbonitride precipitates), and thus nucleates during annealing. Therefore, it contributes to refinement of the steel structure and further increases in strength.
- the Ti content is set to 0.005% or more.
- a preferable Ti content is 0.010% or more.
- the Ti content is set to 0.07% or less.
- it is 0.04% or less.
- the average particle size of the Ti-based precipitate is usually 0.01 to 0.10 ⁇ m under the component composition and steel structure of the present invention.
- Nb 0.01 to 0.10% Nb also forms fine precipitates (meaning Nb carbides, nitrides, carbonitrides. At least one of carbides, nitrides, and carbonitrides precipitates) in the same manner as Ti. Contributes to the refinement of the organization. In order to obtain the effect, the Nb content is 0.01% or more. A preferable Nb content is 0.015% or more. On the other hand, when a large amount of Nb is added, the elongation is remarkably lowered, so the content is made 0.10% or less. A preferable Nb content is 0.06% or less.
- the following components may contain one kind or two or more kinds.
- V 0.10% or less V, like Ti, contributes to the refinement of the steel structure by forming fine precipitates, and can be added as necessary. From the viewpoint of obtaining this effect, the V content is preferably 0.01% or more. However, when a large amount of V is contained, the elongation is remarkably lowered. Therefore, the V content is preferably 0.10% or less.
- Cr 0.50% or less Cr is an element that contributes to increasing the strength by generating martensite, and can be added as necessary. From the viewpoint of obtaining this effect, the Cr content is preferably 0.01% or more. However, if the Cr content exceeds 0.50%, not only excessive martensite is generated, but also Cr oxide is generated on the surface of the steel sheet during annealing, so the plating property is lowered and plating unevenness is likely to be generated. . Therefore, the Cr content is preferably 0.50% or less.
- Mo 0.50% or less Mo, like Cr, is an element that generates martensite and further generates some carbides to contribute to high strength. From the viewpoint of obtaining this effect, the Mo content is preferably 0.005% or more. However, when the Mo content exceeds 0.50%, the martensite is excessively generated, so that the hole expandability is deteriorated. Therefore, the content is preferably 0.50% or less.
- Cu 0.50% or less
- Cu is an element that contributes to increasing the strength by contributing to the promotion of formation of the second phase such as solid solution strengthening and martensite phase, and can be added as necessary.
- the Cu content is preferably 0.01% or more.
- the Cu content is preferably 0.50% or less.
- Ni 0.50% or less
- Ni is an element that contributes to increasing the strength by contributing to the promotion of formation of second phase such as solid solution strengthening and martensite phase, and may be added as necessary. it can.
- the Ni content is preferably 0.01% or more.
- the content is preferably 0.50% or less.
- B 0.01% or less B is an element that improves the hardenability and promotes the formation of the second phase and contributes to an increase in strength, and can be added as necessary.
- the B content is preferably 0.0002% or more.
- the content is preferably 0.01% or less.
- Total of Ca and / or REM are elements that contribute to the improvement of the negative effect of sulfide on spheroidizing and expanding the hole shape, if necessary. Can do. In order to exhibit these effects, it is preferable that the total content (the content of one when only one is included) is 0.0005% or more. On the other hand, since the effect is saturated even if the total content exceeds 0.005%, the total content is preferably 0.005% or less.
- Inevitable impurities include, for example, Sb, Sn, Zn, Co and the like.
- the allowable ranges of these contents are Sb: 0.01% or less, Sn: 0.10% or less, Zn: 0.0. 10% or less, Co: 0.10% or less.
- Sb 0.01% or less
- Sn 0.10% or less
- Zn 0.0. 10% or less
- Co 0.10% or less.
- this invention even if it contains Ta, Mg, and Zr within the range of a normal steel composition, the effect will not be lost.
- the steel structure of the plated steel sheet of the present invention has a volume ratio of 75 to 95% for ferrite, 3 to 15% for martensite, 0.5 to 10% for pearlite, and 10% or less for non-recrystallized ferrite (0%).
- the balance is composed of a low-temperature generation phase, the average crystal grain size of ferrite is 6 ⁇ m or less, the average crystal grain size of martensite is 3 ⁇ m or less, the average aspect ratio is 4.0 or less, and the average grain size is Contains Nb-based precipitates of 0.10 ⁇ m or less.
- the volume ratio described here is the volume ratio with respect to the entire steel sheet, and the same applies hereinafter.
- a volume ratio, an average particle diameter, etc. mean the value obtained by the method as described in an Example.
- the volume fraction of ferrite 75-95%
- the volume fraction of ferrite is less than 75%, it is a hard second phase (phase other than ferrite phase, specifically martensite, pearlite, non-recrystallized ferrite, bainite, retained austenite, spherical cementite, and the like. )
- the volume ratio of the ferrite phase is 75% or more.
- the volume fraction of ferrite exceeds 95%, it is difficult to ensure the tensile strength because there are few hard second phases. Therefore, the upper limit of the volume fraction of ferrite is 95%.
- the volume fraction of the ferrite phase is preferably 92% or less, more preferably less than 90%.
- Average crystal grain size of ferrite 6 ⁇ m or less
- the average grain size of ferrite exceeds 6 ⁇ m, voids are easy to connect when expanding holes, and good hole expansion properties cannot be obtained.
- the crystal grain size of the HAZ part on the surface of the steel sheet becomes coarse, and it becomes difficult to suppress the important surface cracks of the present invention.
- the average crystal grain size of ferrite is set to 6 ⁇ m or less. Preferably it is 5 micrometers or less.
- the preferable minimum of the average crystal grain diameter of a ferrite is 0.3 micrometer or more from the cost surface on manufacture.
- the volume ratio of martensite is 3% or more.
- a preferred martensite volume fraction is 5% or more.
- the volume ratio may be less than 15%.
- the volume ratio is preferably 13% or less, more preferably 11% or less, more preferably less than 10%, and most preferably 9% or less.
- the present invention may contain a small amount of bainite, the sum of martensite and bainite is often less than 15%, more generally 13% or less.
- Average grain size of martensite 3 ⁇ m or less and average aspect ratio: 4.0 or less
- the average aspect ratio of martensite exceeds 4.0, the HAZ part of the steel sheet surface during spot welding becomes high temperature by resistance welding.
- the hardness distribution in the steel structure of the HAZ part is biased, and surface cracks are likely to be generated during spot welding. Therefore, in order to suppress surface cracks during spot welding, martensite is preferably close to a sphere. Therefore, the average aspect ratio of martensite is 4.0 or less. Preferably it is 3.5 or less.
- the average aspect ratio is preferably 0.25 or more from the viewpoint that a spherical shape is preferable.
- the aspect ratio is a value (long side / short side) obtained by dividing the long side by the short side when converted to an ellipse equivalent.
- the upper limit is 3 ⁇ m.
- a preferable average crystal grain size is 2 ⁇ m or less.
- the preferable minimum of the average crystal grain diameter of a martensite is 0.3 micrometer or more from a manufacturing cost side.
- Perlite 0.5-10%
- Non-recrystallized ferrite 10% or less (including 0%)
- the volume ratio of non-recrystallized ferrite is set to 10% or less.
- the preferred volume ratio is 8% or less, more preferably less than 5%.
- the other phase steel structures may include structures other than the above-described ferrite, martensite, pearlite, and non-recrystallized ferrite.
- the remaining structure may be one of low-temperature generation phases selected from bainite, retained austenite, spherical cementite, or the like, or a mixed structure in which two or more are combined. It is preferable from the viewpoint of formability (elongation) that the balance other than the ferrite, martensite, pearlite, and non-recrystallized ferrite is less than 5.0% in total in volume ratio. Therefore, the remaining structure may be 0% in volume ratio.
- the retained austenite is less than 4% or 3% or less, and the content thereof is not large.
- Nb-based precipitates having an average particle size of 0.10 ⁇ m or less
- the steel structure needs to contain Nb-based precipitates having an average particle size of 0.10 ⁇ m or less. If the average grain size of Nb-based precipitates exceeds 0.10 ⁇ m, the yield strength due to precipitation strengthening of the steel sheet cannot be increased, and in addition to the decrease in yield ratio, it becomes difficult to refine ferrite and martensite. The hole expandability and spot weldability are reduced. This preferable average particle diameter is 0.08 ⁇ m or less.
- the Nb-based precipitate means Nb carbide, nitride, or carbonitride, and it is sufficient that at least one of them is included.
- ⁇ Thin steel plate> The component composition and steel structure of the thin steel sheet are as described above. Moreover, although the thickness of a thin steel plate is not specifically limited, Usually, it is 0.4 mm or more and 3.2 mm or less.
- the plated steel sheet of the present invention is a plated steel sheet provided with a plating layer on the thin steel sheet of the present invention.
- the kind of plating layer is not specifically limited, For example, either a hot dipping layer and an electroplating layer may be sufficient.
- the plating layer may be an alloyed plating layer.
- the plated layer is preferably a galvanized layer.
- the galvanized layer may contain Al or Mg. Further, hot dip zinc-aluminum-magnesium alloy plating (Zn—Al—Mg plating layer) is also preferable.
- the Al content is 1% by mass or more and 22% by mass or less
- the Mg content is 0.1% by mass or more and 10% by mass or less
- the balance is Zn.
- the Zn—Al—Mg plating layer in addition to Zn, Al, and Mg, one or more selected from Si, Ni, Ce, and La may be contained in a total amount of 1% by mass or less.
- a plating metal is not specifically limited, Al plating etc. may be sufficient besides the above Zn plating.
- Al plating etc. may be sufficient besides Zn plating.
- the composition of the plating layer is not particularly limited and may be a general one.
- a hot-dip galvanized layer or an alloyed hot-dip galvanized layer generally, Fe: 20% by mass or less, Al: 0.001% by mass to 1.0% by mass, and further, Pb, One or more selected from Sb, Si, Sn, Mg, Mn, Ni, Cr, Co, Ca, Cu, Li, Ti, Be, Bi, and REM in total 0 to 3.5% by mass It is contained below, and the balance is composed of Zn and inevitable impurities.
- a hot dip galvanized layer having a plating adhesion amount of 20 to 120 g / m 2 on one side, and an alloyed hot dip galvanized layer obtained by alloying it. This is because if it is less than 20 g / m 2 , it may be difficult to ensure corrosion resistance. On the other hand, if it exceeds 120 g / m 2 , the plating peel resistance may deteriorate.
- the plated layer is a hot dip galvanized layer, the Fe content in the plated layer is less than 7% by mass.
- the plated layer is an alloyed hot dip galvanized layer, the Fe content in the plated layer is 7%. ⁇ 20% by weight.
- the method for producing a hot-rolled steel sheet comprises a steel material having the above-described composition, wherein the rolling reduction of the final pass of finish rolling is 12% or more, the rolling reduction of the pass before the final pass is 15% or more, and the finish rolling end temperature is Hot rolling under conditions of 850 to 950 ° C., and after the hot rolling, the first average cooling rate to the cooling stop temperature is 75 ° C./s or more, and the primary cooling is performed at a cooling stop temperature of 700 ° C. or less.
- the secondary cooling is performed under the condition that the second average cooling rate up to the coiling temperature is 5 ° C./s or more and less than 75 ° C./s after the primary cooling, and the coil is wound at the coiling temperature of 450 to 650 ° C.
- the temperature is the steel sheet surface temperature unless otherwise specified.
- the steel sheet surface temperature can be measured using a radiation thermometer or the like.
- the steel slab (steel material) to be used is preferably manufactured by a continuous casting method in order to prevent macro segregation of components.
- the steel material can also be produced by an ingot-making method or a thin slab casting method.
- hot rolling after steel slab is cast, hot rolling can be started at 1150 to 1270 ° C. without reheating, or hot rolling can be started after reheating to 1150 to 1270 ° C. preferable.
- the preferred conditions for hot rolling are first to hot-roll a steel slab at a hot rolling start temperature of 1150 to 1270 ° C.
- after manufacturing the steel slab in addition to the conventional method of once cooling to room temperature and then reheating, it was charged into a heating furnace as it was without cooling, or heat was retained. Energy saving processes such as direct feed rolling and direct rolling in which rolling is performed immediately after casting or rolling after casting can be applied without any problem.
- the rolling reduction of the final pass of finish rolling is 12% or more.
- the rolling reduction of the pass before the final pass is 15% or more.
- Setting the rolling reduction of the final pass of finish rolling to 12% or more introduces many shear bands in the austenite grains. However, this is necessary from the viewpoint of increasing the number of nucleation sites of the ferrite transformation after hot rolling and miniaturizing the hot-rolled sheet. Preferably it is 13% or more.
- an upper limit is not specifically limited, 30% or less is preferable for the reason that the plate
- the reduction ratio of the pass before the final pass increases the strain accumulation effect, introduces many shear bands in the austenite grains, further increases the nucleation sites of ferrite transformation, and This is necessary from the viewpoint of making the structure finer. Preferably it is 15% or more.
- an upper limit is not specifically limited, 30% or less is preferable for the reason that the plate
- Finishing rolling finish temperature 850-950 ° C
- the finish rolling end temperature is set to 850 ° C. or higher.
- the finish rolling end temperature exceeds 950 ° C., the hot rolled structure becomes coarse and the properties after annealing deteriorate, so the finish rolling end temperature is set to 850 to 950 ° C.
- Primary cooling As primary cooling, cooling is performed such that the first average cooling rate up to the cooling stop temperature is 75 ° C./s or more and the cooling stop temperature is 700 ° C. or less.
- the cooling conditions are adjusted in order to control the precipitation state of Nb fine precipitates after annealing (heating after cold rolling, cooling treatment) described later.
- This control also has the effect of refining ferrite and martensite in the final steel structure. If the average cooling rate to the cooling stop temperature of the primary cooling is less than 75 ° C./s, the formation of a large amount of Nb precipitates is accelerated and the precipitates are coarsened, so that it is difficult to contribute to the refinement of the steel sheet. Become. As a result, the hole expandability and spot weldability after annealing deteriorate.
- the cooling stop temperature of primary cooling exceeds 700 ° C., excessive pearlite is generated in the hot-rolled steel sheet, the steel structure of the hot-rolled steel sheet becomes inhomogeneous, and the hole expandability and spot weldability after annealing deteriorate.
- the cooling stop temperature may be set to an arbitrary temperature of 700 ° C. or lower, but 600 ° C. or higher is preferable. However, the cooling stop temperature is set to a temperature exceeding the coiling temperature.
- Secondary cooling As the secondary cooling, cooling is performed under the condition that the second average cooling rate up to the coiling temperature is 5 ° C./s or more and less than 75 ° C./s after the primary cooling.
- the average cooling rate is less than 5 ° C./s, Nb-based precipitates are coarsened, so that it is difficult to refine the steel structure after annealing.
- the Ti and Nb-based precipitates are coarsened, so that it is difficult to refine the steel sheet structure after annealing.
- the average cooling rate is 75 ° C./s or more, Ti and Nb-based precipitates that are solid-dissolved after winding remain, so that it is difficult to refine the steel sheet structure after annealing. Therefore, the average cooling rate up to the coiling temperature of 650 ° C. or less is controlled.
- the cooling stop temperature (corresponding to the coiling temperature) is less than 450 ° C.
- the amount of Nb-based precipitation is small, the amount of solid solution in the steel sheet increases, and it becomes difficult to refine the steel sheet structure after final annealing. Therefore, the cooling stop temperature is set to 450 ° C. or higher.
- Winding temperature 450-650 ° C
- the upper limit is 650 ° C.
- the coiling temperature is less than 450 ° C., the amount of Ti and Nb in the steel sheet increases, and it becomes difficult to refine the steel structure. Therefore, the lower limit of the coiling temperature is 450 ° C.
- the steel sheet After the winding, the steel sheet is cooled by air cooling or the like, and used for manufacturing the following cold-rolled full hard steel sheet.
- a hot-rolled steel plate becomes a transaction object as an intermediate product, it is normally a transaction object in a cooled state after winding.
- the manufacturing method of the cold-rolled full hard steel plate (the steel plate as cold-rolled) of this invention is a manufacturing method of the cold-rolled full hard steel plate which cold-rolls the hot-rolled steel plate obtained by the said manufacturing method.
- Cold rolling conditions are appropriately set from the viewpoint of, for example, a desired thickness.
- the rolling reduction of cold rolling is 95% or less.
- ⁇ Manufacturing method of thin steel plate> There are two methods for producing a thin steel plate: a method of heating and cooling a cold-rolled full hard steel plate to produce a thin steel plate (one-time method), and heating and cooling the cold-rolled full hard steel plate to form a heat treated plate. There is a method (twice method) of manufacturing a thin steel sheet by heating and cooling. First, the one-time method will be described.
- Maximum temperature reached 730-900 ° C When the maximum temperature reached is less than 730 ° C., the recrystallization of ferrite does not proceed sufficiently, and excessive unrecrystallized ferrite exists in the steel structure, and the formability deteriorates. In addition, it is difficult to form the second phase necessary for the present invention. On the other hand, when the maximum reached temperature exceeds 900 ° C., the precipitates become coarse, making it difficult to refine the steel structure, and a desired average crystal grain size cannot be obtained for ferrite and martensite.
- the heating conditions for heating up to the maximum temperature are not particularly limited, but the average heating rate is preferably in the range of 2 to 50 ° C./s. This is because when the average heating rate is less than 2 ° C./s, the Nb-based precipitates are coarsened during heating, and it may be difficult to refine the steel structure. In addition, when the average heating rate exceeds 50 ° C./s, there may be a temperature range for ⁇ formation without sufficiently proceeding with recrystallization, so that unrecrystallized ferrite may remain excessively.
- Retention (holding) time of maximum temperature reached 15 to 600s
- the residence time is less than 15 s, the recrystallization of ferrite does not proceed sufficiently, and excess unrecrystallized ferrite exists in the steel structure, thereby degrading the formability.
- the residence time exceeds 600 s, the ferrite becomes coarse and the hole expansion property deteriorates, so the residence time is set to 600 s or less.
- the average cooling rate up to the cooling stop temperature is 3-30 ° C / s Cooling stop temperature is 600 ° C. or less After the above heating, it is necessary to cool at an average cooling rate to the cooling stop temperature of 3 to 30 ° C./s. If the average cooling rate is less than 3 ° C./s, ferrite transformation proceeds during cooling, and the volume fraction of martensite decreases, so that it is difficult to ensure strength. On the other hand, when the average cooling rate exceeds 30 ° C./s, martensite is excessively generated, and it is difficult to ensure the hole expandability.
- the control temperature range of the cooling rate exceeds 600 ° C., pearlite is excessively generated, so that a predetermined volume ratio cannot be obtained for each phase in the steel structure, and ductility (formability) and hole expandability are obtained. descend. Further, the cooling stop temperature needs to be 600 ° C. or lower as described above.
- the dew point in the temperature range of 600 ° C or higher is set to -40 ° C or lower.
- the decarburization from the steel plate surface during annealing can be suppressed, and the tensile strength of 590 MPa defined in the present invention can be stably realized.
- the dew point in the temperature range exceeds ⁇ 40 ° C., the steel sheet may have a tensile strength of less than 590 MPa due to the decarburization. Therefore, the dew point in the above temperature range was set to ⁇ 40 ° C. or lower.
- the lower limit of the dew point of the atmosphere is not particularly specified, but if it is less than ⁇ 80 ° C., the effect is saturated and disadvantageous in terms of cost, it is preferably ⁇ 80 ° C. or higher.
- the temperature in the above temperature range is based on the steel sheet surface temperature. That is, when the steel sheet surface temperature is in the above temperature range, the dew point is adjusted to the above range.
- a thin steel plate when a thin steel plate becomes a transaction object, it is cooled to room temperature after the above cooling or temper rolling described later, and becomes a transaction object.
- the manufacturing method for obtaining the heat treated plate is the method for producing the heat treated plate of the present invention.
- the heating for obtaining the heat treatment plate is heating under the condition that the heating temperature is 700 to 900 ° C.
- the heating temperature is set to 700 to 900 ° C. If it is less than 700 degreeC, said effect will not fully be acquired. If the temperature exceeds 900 ° C., the precipitates become coarse, and it is difficult to refine the steel structure by heating the heat treatment plate to be performed next.
- the cooling conditions are not particularly limited. Usually, the average cooling rate is 1 to 30 ° C./s.
- the heating method of the said heating is not specifically limited, It is preferable to carry out by a continuous annealing line (CAL) or batch annealing (BAF).
- CAL continuous annealing line
- BAF batch annealing
- the heat-treated plate is further heated and cooled.
- the heating and cooling conditions maximum reached temperature, dew point, holding time, average cooling rate, cooling stop temperature
- maximum reached temperature, dew point, holding time, average cooling rate, cooling stop temperature are the same as those applied to the cold-rolled full hard steel plate by a one-time method, and thus the description thereof is omitted.
- the thin steel plate obtained by the above method may be subjected to temper rolling, and the temper rolled thin steel plate may be regarded as the thin steel plate of the present invention.
- a preferable range of the elongation rate is 0.05 to 2.0%.
- the method for producing a plated steel sheet according to the present invention is a method for producing a plated steel sheet, in which the thin steel sheet obtained above is plated.
- examples of the plating process include a hot dip galvanizing process and a process of alloying after hot dip galvanizing. Moreover, you may perform annealing and galvanization continuously by 1 line.
- a plating layer may be formed by electroplating such as Zn—Ni electroalloy plating, or hot dip zinc-aluminum-magnesium alloy plating may be performed.
- the kind of metal plating such as Zn plating and Al plating, is not specifically limited.
- the plating process includes a plating process in the case where annealing and plating are continuously performed in a plating line.
- the steel plate temperature at which the thin steel plate is immersed in the plating bath is preferably (hot dip galvanizing bath temperature ⁇ 40) ° C. to (hot dip galvanizing bath temperature +50) ° C. If the temperature of the steel sheet immersed in the plating bath is below (hot dip galvanizing bath temperature ⁇ 40) ° C., when the steel plate is immersed in the plating bath, a part of the molten zinc solidifies and deteriorates the plating appearance. Therefore, the preferable lower limit is set to (hot dip galvanizing bath temperature ⁇ 40) ° C.
- the preferable upper limit is (hot dip galvanizing bath temperature +50) ° C.
- alloying treatment may be performed in a temperature range of 450 to 600 ° C.
- the Fe concentration during plating becomes 7 to 15%, and adhesion of plating and corrosion resistance after coating are improved.
- the alloying temperature is less than 450 ° C., alloying does not proceed sufficiently, leading to a decrease in sacrificial anticorrosive action and a decrease in slidability.
- the alloying temperature is higher than 600 ° C., the progress of alloying becomes remarkable and the powdering property is lowered.
- a series of processes such as annealing (heating and cooling for cold-rolled full hard steel sheet and the like), hot dipping treatment, and alloying treatment are performed in a continuous hot dip galvanizing line (CGL).
- CGL hot dip galvanizing line
- Zn plating is preferable, but plating treatment using other metals such as Al plating may be used.
- the obtained hot-rolled sheet was pickled and then cold-rolled to produce a cold-rolled sheet (sheet thickness: 1.4 mm) (this cold-rolled sheet corresponds to a cold-rolled full hard steel sheet).
- the obtained cold-rolled sheet is subjected to heating and cooling treatment (annealing) according to the production conditions shown in Table 2 in a continuous hot-dip galvanizing line, and after hot-dip galvanizing treatment, further alloying treatment at the temperature shown in Table 2 And an alloyed hot-dip galvanized steel sheet was obtained.
- annealing heating and cooling treatment according to the production conditions shown in Table 2 in a continuous hot-dip galvanizing line
- further alloying treatment at the temperature shown in Table 2
- an alloyed hot-dip galvanized steel sheet was obtained.
- Table 2 about some steel plates, after cold rolling, 1st heat processing was implemented at the temperature shown in Table 2 with a continuous annealing line, and it plated with the continuous hot-dip galvanizing line.
- the plating treatment is performed by galvanizing bath temperature: 460 ° C.
- galvanizing bath Al concentration 0.14 mass% (when alloying treatment is performed), 0.18 mass% (when alloying treatment is not performed), one side
- the per-plating adhesion amount was 45 g / m 2 (double-sided plating).
- JIS No. 5 tensile test piece was taken from the direction perpendicular to the rolling direction to the longitudinal direction (tensile direction), and by tensile test (JIS Z2241 (1998)), tensile strength (TS), total elongation (EL ), Yield strength (YS) was measured. Moreover, the yield ratio (YR) was calculated.
- the pair of electrode tips used was an alumina-dispersed copper DR type electrode having a radius of curvature R40 at the tip and a tip diameter of 6 mm.
- the welding conditions were as follows: first, the applied pressure was 3500 N, the energization time was 18 cycles, and the hold time was 1 cycle. In each hot-dip galvanized steel sheet, the current value at which dust was generated was obtained, and then 0.1 kA from the current value.
- a retest was conducted with the reduced current value, and it was confirmed with a microscope whether cracks had occurred on the surface.
- Surface cracking is defined as surface cracking when a crack is generated within a diameter of 7 mm with the center of the nugget at the center of the circle. Here, a crack is defined as 100 ⁇ m or more in length.
- the hot-dip galvanized steel sheet in which the galvanized steel sheet was present was designated as “x”, and the hot-dip galvanized steel sheet that did not exist was designated as “ ⁇ ”.
- the volume ratio of ferrite, martensite, pearlite, and non-recrystallized ferrite in the steel sheet was 2000% using a SEM (scanning electron microscope) after corroding the plate thickness section parallel to the rolling direction of the steel sheet and then corroding with 3% nital. A 1/4 thickness position was observed from the surface at a magnification of 5,000 times, and the area ratio was measured by a point count method (based on ASTM E562-83 (1988)), and the area ratio was taken as the volume ratio.
- the average crystal grain size of ferrite and martensite is calculated by taking the image of each ferrite and martensite crystal grain that has been identified in advance from a steel structure photograph using Image-Pro of Media Cybernetics. The circle equivalent diameter was calculated and the values were averaged.
- the aspect ratio of martensite was obtained by obtaining the aspect ratio of each grain based on the above photograph and averaging them.
- the average particle diameter of the Nb-based precipitates was measured by observing 10 thin-films prepared from a position of 1 ⁇ 4 thickness from the surface of the obtained steel sheet with a transmission electron microscope (TEM) (photo enlargement and magnification) : 500000 times), and the average particle size of the precipitate was determined.
- the particle diameter of each precipitate is the diameter when the precipitate is spherical, and when the precipitate is elliptical, the major axis a of the precipitate and the direction perpendicular to the major axis
- the minor axis was measured, and the square root of the product a ⁇ b of the major axis a and the minor axis b was defined as the particle size.
- the particle size of each precipitate observed in 10 fields of view was added, and the value divided by the number of precipitates was taken as the average particle size of the carbide.
- Table 3 shows the measured tensile properties, hole expansion ratio, spot weldability, and steel structure measurement results.
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Abstract
Description
本発明のめっき鋼板等は、質量%で、C:0.05~0.11%、Si:0.60%以下、Mn:1.50~2.10%、P:0.05%以下、S:0.005%以下、Al:0.01~0.10%、N:0.010%以下、Ti:0.005~0.07%、Nb:0.01~0.10%を含有し、残部がFeおよび不可避的不純物からなる成分組成を有する。
Cは鋼板の高強度化に有効な元素であり、本発明におけるマルテンサイト、パーライトの形成に寄与する。C含有量が0.05%未満では、必要なマルテンサイトの体積率の確保が困難である。好ましいC含有量は0.06%以上である。一方、Cを0.11%超まで過剰に添加するとフェライトとマルテンサイトの硬度差が大きくなるため穴広げ性が低下する上に、スポット溶接時のHAZ部の靭性も劣化するためスポット溶接時に表面割れが起こる。好ましいC含有量は0.10%以下である。
Siはフェライトを固溶強化する。このため、Si含有により、硬質相との硬度差を低下させるため穴広げ率が増加する傾向がある。しかし、Siの多量な含有により、焼鈍時に酸化物としてSiが鋼板表面に濃縮するため、めっき性が劣化する。さらに、Si含有量が多過ぎると、高温時の靭性も劣化することから、スポット溶接時の表面割れを生成しやすくなる。そこで、Si含有量を0.60%以下とする。Si含有量は0.60%未満であってもよい。好ましいSi含有量は0.50%以下であり、より好ましくは0.50未満であり、さらに好ましくは0.45%以下であり、最も好ましくは0.30%以下である。特に下限は無いが、上記の穴広げ率の観点からSi含有量は0.005%以上が好ましい。なお、Si含有量が0.005%未満であっても穴広げ率を改善可能であることから下限は特に限定しない。
Mnは固溶強化やマルテンサイト等の第二相(フェライト以外の相)の形成に役立つため、高強度化に寄与する。そこで、Mn含有量は1.50%以上にすることが必要である。一方、Mnを過剰に含有した場合、スポット溶接時のHAZ部のマルテンサイト変態点(Ms点)を低下させるため、HAZ部の硬度が高くなり、スポット溶接時の表面割れが生成しやすくなる。そのため、その含有量は2.10%以下とする。好ましくは2.00%以下である。
Pは固溶強化により高強度化に寄与する。また、Pにより、溶融亜鉛めっき鋼板を合金化する際に合金化速度を制御可能なため、P含有量の調整によりめっき性を向上させることができる。その効果を得るためには、P含有量は0.001%以上が好ましい。しかし、Pを過剰に含有すると、スポット溶接時に粒界に偏析するためスポット溶接時の表面割れを助長する。そこで、P含有量を0.05%以下とする。好ましいP含有量は0.04%以下である。
Sの含有量が多い場合には、MnSなどの硫化物が多く生成して、打ち抜き加工時にMnSが起点となりボイドが生成するため、穴広げ性が劣化する。そのため、含有量の上限を0.005%とする。好ましいS含有量は、0.004%以下である。特に下限は無いが、極低S化は製鋼コストが上昇するため、S含有量は0.0003%以上が好ましい。
Alは脱酸に必要な元素であり、この効果を得るためにはAlを0.01%以上含有することが必要である。一方、Al含有量が0.10%を超えても効果が飽和するため、0.10%以下とする。好ましいAl含有量は0.05%以下である。
Nは粗大なTi窒化物や粗大なNb窒化物を形成して穴広げ性を劣化させることから、含有量を抑える必要がある。N含有量が0.010%超では、この傾向が顕著となることからNの含有量は0.010%以下とする。好ましいN含有量は0.008%以下である。なお、N含有量の好ましい下限については、溶製上のコスト面より、0.0005%以上である。
Tiは微細なTi系析出物(Tiの炭化物、窒化物、炭窒化物を意味する。炭化物、窒化物および炭窒化物の少なくとも1種が析出する。)を形成することで、焼鈍時に核成長を抑制する効果があるため、鋼組織の微細化を担い、さらに強度上昇に寄与する。このような効果を発揮させるためには、Ti含有量は0.005%以上とする。好ましいTi含有量は0.010%以上である。一方、多量にTiを含有すると、未再結晶フェライトが過剰に生成して伸びが著しく低下する。そこで、Ti含有量は0.07%以下とする。好ましく0.04%以下である。なお、Ti系析出物の平均粒径は、本発明の成分組成や鋼組織等のもとでは通常0.01~0.10μmである。
NbもTiと同様に、微細な析出物(Nbの炭化物、窒化物、炭窒化物を意味する。炭化物、窒化物および炭窒化物の少なくとも1種が析出する。)を形成することで、鋼組織の微細化に寄与する。その効果を得るためには、Nb含有量は0.01%以上とする。好ましいNb含有量は0.015%以上である。一方、多量にNbを添加すると伸びが著しく低下するため、その含有量は0.10%以下とする。好ましいNb含有量は0.06%以下である。
VもTiと同様に、微細な析出物を形成することで、鋼組織の微細化に寄与するため、必要に応じて添加することができる。この効果を得る観点からV含有量は0.01%以上が好ましい。ただし、多量にVを含有すると伸びが著しく低下する。そこで、V含有量は0.10%以下が好ましい。
Crはマルテンサイトを生成することで高強度化に寄与する元素であり、必要に応じて添加することができる。この効果を得る観点からCr含有量は0.01%以上が好ましい。ただし、Cr含有量が0.50%超えると、過剰にマルテンサイトが生成するだけでなく、焼鈍時にCr酸化物が鋼板表面に生成するためにめっき性が低下して、めっきムラが生成しやすい。そのため、Cr含有量は0.50%以下が好ましい。
MoもCrと同様、マルテンサイトを生成して、さらに一部炭化物を生成して高強度化に寄与する元素である。この効果を得る観点からMo含有量は0.005%以上が好ましい。ただし、Mo含有量が0.50%を超えると、過剰にマルテンサイトが生成するため穴広げ性が低下する。そこで、その含有量は0.50%以下が好ましい。
Cuは固溶強化、マルテンサイト相等の第2相の生成促進に寄与することで高強度化に寄与する元素であり、必要に応じて添加することができる。これら効果を発揮するためにはCu含有量は0.01%以上が好ましい。しかし、Cu含有量が0.50%を超えると効果が飽和し、またCuに起因する表面欠陥が発生しやすくなる。そこで、Cu含有量は0.50%以下が好ましい。
NiもCuと同様、固溶強化、マルテンサイト相等の第2相の生成促進に寄与することで高強度化に寄与する元素であり、必要に応じて添加することができる。これら効果を発揮させるためにはNi含有量は0.01%以上が好ましい。また、Cuと同時に、添加すると、Cu起因の表面欠陥を抑制する効果があるため、Cu添加時にNi添加することが有効である。一方、Ni含有量が0.50%を超えても効果が飽和するため、その含有量を0.50%以下が好ましい。
Bは焼入れ性を向上させ、第2相の生成を促進して高強度化に寄与する元素であり、必要に応じて添加することができる。この効果を発揮するためには、B含有量は0.0002%以上が好ましい。一方、B含有量が0.01%を超えても効果が飽和するため、その含有量は0.01%以下が好ましい。
CaおよびREMは、硫化物の形状を球状化し穴広げ性への硫化物の悪影響を改善に寄与する元素であり、必要に応じて添加することができる。これらの効果を発揮するためには合計含有量(一方しか含まない場合には一方の含有量)が0.0005%以上であることが好ましい。一方、合計含有量が0.005%を超えても効果が飽和するため、その合計含有量は0.005%以下が好ましい。
本発明のめっき鋼板等の鋼組織は、体積率で、フェライトを75~95%、マルテンサイトを3~15%、パーライトを0.5~10%、未再結晶フェライトを10%以下(0%含む)含み、残部が低温生成相からなり、フェライトの平均結晶粒径が6μm以下であり、マルテンサイトの平均結晶粒径が3μm以下かつ平均アスペクト比が4.0以下であり、平均粒径が0.10μm以下のNb系析出物を含有する。ここで述べる体積率は鋼板の全体に対する体積率であり、以下同様である。また、体積率や平均粒径等は実施例に記載の方法で得られる値を意味する。
フェライトの体積率が75%未満の形成では、硬質な第2相(フェライト相以外の相、具体的には、マルテンサイト、パーライト、未再結晶フェライト、ベイナイト、残留オーステナイトおよび球状セメンタイト等である。)が多くなるため、軟質なフェライト相と硬質第2相との硬度差が大きい箇所が多く存在し、穴広げ性が低下する。そのためフェライト相の体積率は75%以上とする。好ましくは82%以上である。フェライトの体積率が95%超では硬質な第2相が少ないため、引張強度の確保が困難である。そこで、フェライトの体積率の上限は95%とする。好ましいフェライト相の体積率は92%以下であり、さらに好ましくは90%未満である。
フェライトの平均粒径(平均結晶粒径)が6μm超では、穴広げ時にボイドが連結しやすくなり、良好な穴広げ性が得られないばかりか、スポット溶接時の鋼板表面のHAZ部の結晶粒径も粗大となってしまい、本発明の重要な表面割れを抑制することが困難となる。このため、フェライトの平均結晶粒径は6μm以下とする。好ましくは5μm以下である。なお、フェライトの平均結晶粒径の好ましい下限は、製造上のコスト面から0.3μm以上である。
所望の引張強度および降伏比を確保するために、マルテンサイトの体積率は3%以上とする。好ましいマルテンサイトの体積率は5%以上である。硬質なマルテンサイトの体積率が15%を超えると降伏比が低下するため、その体積率は15%以下とする。その体積率を15%未満としてもよい。好ましい上記体積率は13%以下であり、さらに好ましくは11%以下であり、より好ましくは10%未満、最も好ましくは9%以下である。
マルテンサイトの平均アスペクト比が4.0超では、スポット溶接時の鋼板表面のHAZ部において、抵抗溶接により高温となった際、マルテンサイトに濃化していたCやMnが均質にオーステナイト中に分散しないため、HAZ部の鋼組織中の硬度分布に偏りが起きてスポット溶接時に表面割れを生成しやすい。よって、スポット溶接時の表面割れを抑制するにはマルテンサイトは球状に近い方が好ましい。そこで、マルテンサイトの平均アスペクト比は4.0以下とする。好ましくは3.5以下とする。また、球状に近い方が好ましい観点から平均アスペクト比は0.25以上が好ましい。なお、ここでいうアスペクト比とは、楕円相当に換算した際に長辺を短辺で除した値(長辺/短辺)のことである。
鋼組織にパーライトを含有することで引張強度を確保しつつ高降伏比を得ることが可能である。体積率で0.5%未満の場合は高い降伏比を得ることが困難であるため、パーライトの体積率は0.5%以上とする。また、パーライトの体積率が10%超では穴広げ性が低下するため、その上限は10%とする。好ましいパーライトの体積率は8%以下である。
鋼組織に未再結晶フェライトを含有することで引張強度を確保しつつ高降伏比を得ることが可能である。しかし、未再結晶フェライトの体積率が10%を超える場合、延性が低下する他に、高い転位密度を保有しているため靭性に乏しく、スポット溶接時の表面割れが起こりやすい。そのため、未再結晶フェライトの体積率は10%以下とする。好ましい体積率は8%以下であり、さらに好ましくは5%未満である。
鋼組織は、上記した、フェライト、マルテンサイト、パーライトおよび未再結晶フェライト以外の組織を含んでいてもよい。その場合の残部組織は、ベイナイト、残留オーステナイトおよび球状セメンタイト等から選択される低温生成相の1種であるか、或いは2種以上を組み合わせた混合組織としてもよい。このフェライト、マルテンサイト、パーライトおよび未再結晶フェライト以外の残部は、体積率で合計5.0%未満とすることが、成形性(伸び)の点から好ましい。従って、上記残部組織は体積率で0%でもよい。なお、通常、残留オーステナイトは4%未満や3%以下であり、その含有量は多くはない。
鋼組織は、平均粒径が0.10μm以下のNb系析出物を含有する必要がある。Nb系析出物の平均粒径が0.10μm超では鋼板の析出強化による降伏強度を高めることが出来ず、降伏比が低下することに加え、フェライトやマルテンサイトの微細化が困難となり、焼鈍後の穴広げ性やスポット溶接性が低下する。このましい平均粒径は0.08μm以下である。なお、Nb系析出物とは、Nbの炭化物、窒化物、炭窒化物を意味し、これらのうち少なくとも1つが含まれていればよい。
薄鋼板の成分組成および鋼組織は上記の通りである。また、薄鋼板の厚みは特に限定されないが、通常、0.4mm以上3.2mm以下である。
本発明のめっき鋼板は、本発明の薄鋼板上にめっき層を備えるめっき鋼板である。めっき層の種類は特に限定されず、例えば、溶融めっき層、電気めっき層のいずれでもよい。また、めっき層は合金化されためっき層でもよい。めっき層は亜鉛めっき層が好ましい。亜鉛めっき層はAlやMgを含有してもよい。また、溶融亜鉛-アルミニウム-マグネシウム合金めっき(Zn-Al-Mgめっき層)も好ましい。この場合、Al含有量を1質量%以上22質量%以下、Mg含有量を0.1質量%以上10質量%以下とし残部はZnとすることが好ましい。また、Zn-Al-Mgめっき層の場合、Zn、Al、Mg以外に、Si、Ni、Ce及びLaから選ばれる一種以上を合計で1質量%以下含有してもよい。なお、めっき金属は特に限定されないため、上記のようなZnめっき以外に、Alめっき等でもよい。なお、めっき金属は特に限定されないため、Znめっき以外に、Alめっき等でもよい。
熱延鋼板の製造方法は、上記成分組成を有する鋼素材を、仕上げ圧延の最終パスの圧下率が12%以上、該最終パスの前のパスの圧下率が15%以上、仕上げ圧延終了温度が850~950℃の条件の熱間圧延し、該熱間圧延後、冷却停止温度までの第1平均冷却速度が75℃/s以上、冷却停止温度が700℃以下の1次冷却をし、該1次冷却後、巻取温度までの第2平均冷却速度が5℃/s以上75℃/s未満の条件で2次冷却をし、450~650℃の巻取温度で巻き取る方法である。なお、以下の説明において、温度は特に断らない限り鋼板表面温度とする。鋼板表面温度は放射温度計等を用いて測定し得る。
最終パスの前のパスの圧下率が15%以上
仕上げ圧延の最終パスの圧下率を12%以上にすることはオーステナイト粒内にせん断帯を多数導入し、熱間圧延後のフェライト変態の核生成サイトを増大して熱延板の微細化を図るという観点から必要である。好ましくは13%以上である。また、上限は特に限定されないが熱延負荷荷重が増大することで、板の幅方向での板厚変動が大きくなり、材質均一性が変化するという理由で30%以下が好ましい。
熱間圧延では、鋼板内の組織均一化、材質の異方性低減により、焼鈍後の伸びおよび穴広げ性を向上させるため、オーステナイト単相域にて終了する必要がある。そこで、仕上げ圧延終了温度は850℃以上とする。一方、仕上げ圧延終了温度が950℃超えでは、熱延組織が粗大になり、焼鈍後の特性が低下するため、仕上げ圧延終了温度は850~950℃とする。
1次冷却として、冷却停止温度までの第1平均冷却速度が75℃/s以上、冷却停止温度が700℃以下の冷却を行う。
2次冷却として、該1次冷却後、巻取温度までの第2平均冷却速度が5℃/s以上75℃/s未満の条件で冷却を行う。
上記2次冷却後の巻取りにおける、巻取温度が650℃超では、パーライトが過剰に生成して鋼組織が不均質となり、TiおよびNb系の析出部が粗大化するため、巻取温度の上限は650℃とする。好ましくは630℃以下である。巻取温度が450℃未満では、TiおよびNbの鋼板内の固溶量が増加するため、鋼組織の微細化が困難となるため、巻取温度の下限は450℃とする。
本発明の冷延フルハード鋼板(冷延ままの鋼板)の製造方法は、上記製造方法で得られた熱延鋼板を冷間圧延する冷延フルハード鋼板の製造方法である。
薄鋼板の製造方法には、冷延フルハード鋼板を加熱し冷却して薄鋼板を製造する方法(1回法)と、冷延フルハード鋼板を加熱し冷却して熱処理板とし該熱処理板を加熱し冷却して薄鋼板を製造する方法(2回法)とがある。先ず1回法を説明する。
最高到達温度が730℃未満の場合には、フェライトの再結晶が十分に進行せず、過剰な未再結晶フェライトが鋼組織に存在してしまい、成形性が劣化する。また、本発明に必要な第2相の形成も困難となる。一方、最高到達温度が900℃を超える場合は、析出物が粗大化し、鋼組織の微細化が困難となり、フェライトやマルテンサイトについて所望の平均結晶粒径を得られない。
滞留時間が15s未満の場合には、フェライトの再結晶が十分に進行せず、過剰な未再結晶フェライトが鋼組織に存在してしまい、成形性が劣化する。また、本発明に必要な第2相の形成も困難となる。また、滞留時間が600s超となると、フェライトが粗大化し、穴広げ性が劣化するため、滞留時間は600s以下とする。
冷却停止温度が600℃以下
上記の加熱後は、冷却停止温度までの平均冷却速度が3~30℃/sの条件で冷却する必要がある。平均冷却速度が3℃/s未満では、冷却中にフェライト変態が進行して、マルテンサイトの体積率が減少するため、強度確保が困難である。一方、平均冷却速度が30℃/sを超える場合には、マルテンサイトが過剰に生成するため、穴広げ性の確保が困難である。また、冷却速度の制御温度域が600℃を超える場合には、パーライトが過剰に生成するため、鋼組織における各相について所定の体積率を得られず、延性(成形性)および穴広げ性が低下する。また、冷却停止温度は上記の通り600℃以下にする必要がある。
本発明のめっき鋼板の製造方法は、上記で得られた薄鋼板にめっきを施す、めっき鋼板の製造方法である。
Claims (12)
- 質量%で、
C:0.05~0.11%、
Si:0.60%以下、
Mn:1.50~2.10%、
P:0.05%以下、
S:0.005%以下、
Al:0.01~0.10%、
N:0.010%以下、
Ti:0.005~0.07%、
Nb:0.01~0.10%を含有し、残部がFeおよび不可避的不純物からなる成分組成と、
体積率で、フェライトを75~95%、マルテンサイトを3~15%、パーライトを0.5~10%、未再結晶フェライトを10%以下含み、残部が低温生成相からなり、前記フェライトの平均結晶粒径が6μm以下であり、前記マルテンサイトの平均結晶粒径が3μm以下かつ平均アスペクト比が4.0以下であり、平均粒径が0.10μm以下のNb系析出物を含有する鋼組織と、を有し、
引張強さが590MPa以上であることを特徴とする薄鋼板。 - 前記成分組成は、さらに、質量%で、V:0.10%以下を含有することを特徴とする請求項1に記載の薄鋼板。
- 前記成分組成は、さらに、質量%で、
Cr:0.50%以下、
Mo:0.50%以下、
Cu:0.50%以下、
Ni:0.50%以下、
B:0.01%以下、
並びにCa及び/又はREMの合計:0.005%以下から選択される一種以上を含有することを特徴とする請求項1または2に記載の薄鋼板。 - 請求項1~3のいずれかに記載の薄鋼板の表面にめっき層を有することを特徴とするめっき鋼板。
- 前記めっき層が溶融亜鉛めっき層又は合金化溶融亜鉛めっき層であることを特徴とする請求項4に記載のめっき鋼板。
- 請求項1~3のいずれかに記載の成分組成を有する鋼素材を、仕上げ圧延の最終パスの圧下率が12%以上、該最終パスの前のパスの圧下率が15%以上、仕上げ圧延終了温度が850~950℃の条件で熱間圧延し、該熱間圧延後、冷却停止温度までの第1平均冷却速度が75℃/s以上、冷却停止温度が700℃以下の1次冷却をし、該1次冷却後、巻取温度までの第2平均冷却速度が5℃/s以上75℃/s未満の条件で2次冷却をし、450~650℃の巻取温度で巻き取ることを特徴とする熱延鋼板の製造方法。
- 請求項6に記載の製造方法で得られた熱延鋼板を酸洗し、冷間圧延することを特徴とする冷延フルハード鋼板の製造方法。
- 請求項7に記載の製造方法で得られた冷延フルハード鋼板を、600℃以上の温度域の露点を-40℃以下とし、最高到達温度が730~900℃の条件で加熱し、該最高到達温度で15~600s保持し、該保持後、冷却停止温度までの平均冷却速度が3~30℃/s、冷却停止温度が600℃以下の条件で冷却することを特徴とする薄鋼板の製造方法。
- 請求項7に記載の製造方法で得られた冷延フルハード鋼板を、加熱温度が700~900℃の条件で加熱し、冷却することを特徴とする熱処理板の製造方法。
- 請求項9に記載の製造方法で得られた熱処理板を、600℃以上の温度域の露点を-40℃以下とし、最高到達温度が730~900℃の条件で加熱し、該最高到達温度で15~600s保持し、該保持後、冷却停止温度までの平均冷却速度が3~30℃/s、冷却停止温度が600℃以下の条件で冷却することを特徴とする薄鋼板の製造方法。
- 請求項8又は10に記載の製造方法で得られた薄鋼板の表面にめっき処理を施すめっき工程を備えることを特徴とするめっき鋼板の製造方法。
- 前記めっき処理は、溶融亜鉛めっきし、450~600℃で合金化する処理であることを特徴とする請求項11に記載のめっき鋼板の製造方法。
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MX2018011688A (es) | 2016-03-31 | 2019-02-18 | Jfe Steel Corp | Lamina de acero y lamina de acero enchapada, metodo para producir lamina de acero laminada en caliente, metodo para producir lamina de acero de dureza completa laminada en frio, metodo para producir lamina termicamente tratada, metodo para producir lamina de acero, y metodo para producir lamina de acero enchapada. |
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