WO2017140125A1 - Procédé de fabrication d'un panneau de tabatière non métallique anticorrosion constitué d'un élément pré-tissé pourvu d'une couche de dérivation - Google Patents

Procédé de fabrication d'un panneau de tabatière non métallique anticorrosion constitué d'un élément pré-tissé pourvu d'une couche de dérivation Download PDF

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Publication number
WO2017140125A1
WO2017140125A1 PCT/CN2016/103794 CN2016103794W WO2017140125A1 WO 2017140125 A1 WO2017140125 A1 WO 2017140125A1 CN 2016103794 W CN2016103794 W CN 2016103794W WO 2017140125 A1 WO2017140125 A1 WO 2017140125A1
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WO
WIPO (PCT)
Prior art keywords
manufacturing
glass fiber
anticorrosive
metallic
lighting panel
Prior art date
Application number
PCT/CN2016/103794
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English (en)
Chinese (zh)
Inventor
梅天诚
Original Assignee
苏州振瑞昌材料科技有限公司
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Publication of WO2017140125A1 publication Critical patent/WO2017140125A1/fr

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Classifications

    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/35—Roofing slabs or stiff sheets comprising two or more layers, e.g. for insulation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10779—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B43/00—Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
    • B32B43/003—Cutting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/043—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres

Definitions

  • the present invention relates to the field of anticorrosive lighting panels, and more particularly to a non-metal made of a pre-woven fabric with a flow guiding layer.
  • anti-corrosion lighting panels have been widely used in more and more construction fields and have become one of the necessary building materials.
  • the use of anti-corrosion and lighting panels can not only achieve corrosion protection, but also save energy.
  • the role but also has a neat, beautiful, environmentally friendly role.
  • anti-corrosion lighting panels were mainly made of metal plates such as color steel plates, etc. These products have excellent light transmission properties and thermal insulation properties.
  • metal plates such as color steel plates, etc.
  • These products have excellent light transmission properties and thermal insulation properties.
  • organic material its flame retardancy, weather resistance and the like limit its application in lighting panels.
  • the non-metallic anticorrosive plate with a thickness of 2 mm or more has a problem of broken nails caused by tensile force and severe aging of nail hole wear after installation on a circular arc roof, and higher requirements are imposed on the current anticorrosive plate.
  • the present invention provides a method of manufacturing a non-metallic anticorrosive lighting panel made of a pre-woven fabric with a flow guiding layer, which can be applied to a dome structure having a large curvature to solve problems such as fracture, corrosion, flammability and aging.
  • a method for manufacturing a non-metallic anticorrosive lighting panel with a drainage layer comprises the following three steps:
  • the hybrid resin system prepared by the step 2) is transported by a transfer pump onto the PET lower film and the same as that obtained by the step 1)
  • the glass fiber felt pre-weave is soaked, completely penetrated into the calendering zone, and pressed onto the PET film; then enters the bending mold of the heating forming zone to perform high-temperature pultrusion; and then pulls the formed composite material through the tractor And cooling, and finally cutting as required to obtain the non-metallic anticorrosive lighting panel.
  • step 2) the curing agent and the accelerator are added by a proportional pump. Further, in step 2), the surface treated aluminum hydroxide flame retardant is dissolved in ethanol by interfacial coupling agent KH550, and then the aluminum hydroxide flame retardant is dissolved in the interface coupling agent solution. In the middle, after stirring uniformly, the ethanol solvent is distilled off to obtain.
  • the tractor is a top-and-down coupled rubber roller tractor.
  • a fan circulation duct for cooling the lighting panel is further provided at the upper and lower positions of the tractor.
  • step 3 the cutting is completed by a cutting zone, the cutting zone comprising a cutter, a measuring system, a dust recovery system, and a control system simultaneously connected to the tool and the measuring system .
  • the beneficial effects of the invention are as follows: a fiber cloth having a reinforcing effect is used as a flow guiding layer, and the fiber mat can be uniformly impregnated during the resin impregnation process, so that the obtained composite material has stable performance; Structural design, using carbon fiber interpenetration in the inter-fiber structure, the composite material non-metallic anti-corrosion board product can increase the longitudinal strength and impact strength by at least 50%; combined with aluminum hydroxide high-efficiency flame retardant and unsaturated polyester Resin Inorganic/organic hybrid technology, prepared composite non-metallic anti-corrosion board products have first-grade flame retardancy
  • FIG. 1 is a structural view showing a fiber pre-woven member of a bakelite board in the present invention.
  • the invention discloses a novel structure reinforced non-metal anti-corrosion board lighting board preparation method, comprising the following steps:
  • Step 1 Glass fiber pre-woven parts manufacturing
  • the glass fiber mat 1 is first layered, and then the baffle fiber cloth 2 is added to the intermediate layer of the layered glass fiber mat 2, and then the layer is laid by high-strength continuous carbon fiber yarn 3 by sewing technique.
  • the glass fiber mat 1 and the baffle fiber cloth 2 are sewn together to produce the glass fiber mat pre-woven reinforced between carbon fiber layers.
  • the baffle fiber cloth can be made of a polyolefin fiber unidirectional cloth, such as a polypropylene fiber unidirectional cloth or a polyethylene fiber unidirectional cloth.
  • the fiber has a smooth surface rod-like structure, is light and high in strength, and has good wear resistance. Polypropylene fiber unidirectional cloth is preferred.
  • the baffle fiber cloth may also be a carbon fiber unidirectional cloth which has a large amount of carbon fiber filaments in one direction (usually warp direction) and a small amount and usually fine carbon fiber filaments in the other direction.
  • the baffle fiber cloth can also employ extruded high molecular weight polyolefin mesh cloth having high permeability, which facilitates the flow and penetration of the resin.
  • Step 2 Preparation of organic-inorganic hybrid resin system
  • the aluminum hydroxide flame retardant is surface-treated with an interface coupling agent to enhance the adhesion of the organic-inorganic interface.
  • a surface-treated aluminum hydroxide flame retardant, an ultraviolet absorber, a pigment paste, or the like is added to the unsaturated resin, and the mixture is uniformly stirred.
  • the curing agent and the accelerator are added to the second pump by a proportional pump, and the organic/inorganic hybrid resin system is prepared by mixing uniformly.
  • Step 3 Preparation of non-metallic anti-corrosion board for composite materials
  • the mixed organic/inorganic hybrid resin is transported to the PET stretched film (lower film) by a transfer pump to be impregnated with the glass fiber chopped strand mat (high-strength carbon fiber yarn is contained between the two layers of glass fiber mat), and is completely impregnated and then enters.
  • the PET film (upper film) is pressed, and then enters the heating forming zone, and the reverse molding die of about 10 meters is set in the heating forming zone (for effecting the natural bending curvature after the lighting plate is formed),
  • An upper and lower coupling type rubber roller tractor is arranged at the outlet of the heating forming zone. The upper and lower positions of the tractor are provided with a fan circulation pipe for cooling the lighting plate.
  • the cutting area includes: a tool, a measuring system, a dust recovery system (a cutting tool and a plate length, and a thickness measuring system are simultaneously connected to the control system).
  • An automatic lighting panel storage unit (two sets of alternate use) is provided after the cutting area.
  • the process of exhibiting natural bending curvature after forming the non-metallic anti-corrosion lighting plate is realized, overcoming the non-metal of 2 mm and above thickness in the prior art.
  • the anti-corrosion plate is seriously deteriorated due to the tensile force caused by the tensile force and the nail hole wear after the installation of the arc-shaped roof.
  • the resin system formula can be adjusted to increase the viscosity of the resin, and the purpose of reducing the fluidity to ensure the uniformity of the product after molding is achieved.
  • the interface coupling agent KH550 (5 kg) was dissolved in 1000 L of ethanol, and then an aluminum hydroxide flame retardant (500 kg) was dissolved in the interface coupling agent solution. After stirring evenly, the ethanol solvent is distilled off. A surface treated aluminum hydroxide flame retardant is prepared.
  • This resin system is used in the manufacture of composite lighting panels for a period of no more than one hour.
  • the prepared resin system is conveyed to the PET stretched film (lower film) by a transfer pump to be impregnated with the glass fiber pre-woven fabric, completely penetrated into the calendering zone, and pressed to the PET film (upper film);
  • the bending die of the zone is subjected to high temperature pultrusion;
  • the composite composite lighting plate is pulled out at the exit through the upper and lower coupling rubber roller tractor, and is cooled by the cooling fan circulation pipe passing the upper and lower positions of the tractor;
  • the length of the lighting board is cut according to requirements, so that a new reinforced composite anti-corrosion lighting board is obtained.
  • the pre-woven member of the non-metallic anti-corrosion board of the present invention adopts a reinforcing fiber cloth as a flow guiding layer, and can uniformly permeate the fiber mat during the resin impregnation process to stabilize the obtained composite material.
  • the interlayer strengthening method is used to longitudinally strengthen the high-performance carbon fiber in the two-dimensional glass fiber interlayer structure, and the longitudinal strength and the impact strength are improved by 50% compared with the existing non-metallic anticorrosive board products.
  • the non-metal anti-corrosion board lighting board of the invention has the first-class flame-retardant function, and the oxygen index of the anti-corrosion board manufactured by the invention reaches 35.4, and the inorganic/organic hybridization of the high-efficiency flame retardant and the unsaturated polyester resin by combining the aluminum hydroxide is combined. , on the basis of achieving the first-grade flame retardant, still has excellent mechanical properties.
  • the non-metallic anticorrosive plate lighting plate of the invention has excellent chemical corrosion resistance, oxidation resistance, acid alkali resistance and weather resistance. When replacing steel sheets, a large amount of waste of steel resources due to corrosion of steel is avoided.

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

L'invention concerne un procédé de fabrication d'un panneau de tabatière non métallique anticorrosion constitué d'un élément pré-tissé pourvu d'une couche de dérivation, comprenant les trois étapes suivantes consistant à: fabriquer un élément pré-tissé en feutre de fibre de verre, préparer un système de résine hybride, et préparer le moulage du panneau de tabatière non métallique anticorrosion. Le panneau de tabatière non métallique anticorrosion comprend l'élément pré-tissé en feutre de fibre de verre et le système de résine hybride, l'élément pré-tissé en feutre de fibre de verre comprenant des feutres de fibre de verre en couches, un tissu de fibres de couche de dérivation, et des fibres continues de couche intermédiaire, le tissu de fibres de couche de dérivation est disposé au niveau de la position médiane des feutres de fibre de verre en couches, et les feutres de fibres de verre en couches sont cousus avec le tissu de fibres de la couche de dérivation au moyen des fibres continues de la couche intermédiaire.
PCT/CN2016/103794 2016-02-19 2016-10-28 Procédé de fabrication d'un panneau de tabatière non métallique anticorrosion constitué d'un élément pré-tissé pourvu d'une couche de dérivation WO2017140125A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610093774.2A CN105711199B (zh) 2016-02-19 2016-02-19 一种由带导流层的预织件制成的非金属防腐采光板的制造方法
CN201610093774.2 2016-02-19

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WO2017140125A1 true WO2017140125A1 (fr) 2017-08-24

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CN105711199B (zh) * 2016-02-19 2017-10-27 苏州振瑞昌材料科技有限公司 一种由带导流层的预织件制成的非金属防腐采光板的制造方法
CN105711214A (zh) * 2016-02-19 2016-06-29 苏州振瑞昌材料科技有限公司 一种带导流层的层间增强纤维复合材料及其制造方法
CN106393846A (zh) * 2016-08-30 2017-02-15 苏州振瑞昌材料科技有限公司 一种阻燃高韧性酚醛树脂防腐采光板及其制备方法
CN114249038B (zh) * 2021-12-07 2023-05-05 南通中集翌科新材料开发有限公司 一种复合材料地板中梁和集装箱

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