WO2017101770A1 - 一种双重硬度复合钢板及其制造方法 - Google Patents
一种双重硬度复合钢板及其制造方法 Download PDFInfo
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- WO2017101770A1 WO2017101770A1 PCT/CN2016/109781 CN2016109781W WO2017101770A1 WO 2017101770 A1 WO2017101770 A1 WO 2017101770A1 CN 2016109781 W CN2016109781 W CN 2016109781W WO 2017101770 A1 WO2017101770 A1 WO 2017101770A1
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- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
- B21B2001/386—Plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2251/00—Treating composite or clad material
- C21D2251/02—Clad material
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
- F41H5/02—Plate construction
- F41H5/04—Plate construction composed of more than one layer
- F41H5/0442—Layered armour containing metal
- F41H5/045—Layered armour containing metal all the layers being metal layers
Definitions
- the present invention relates to a steel sheet and a method of manufacturing the same, and more particularly to a composite steel sheet and a method of manufacturing the same.
- an increase in the thickness and hardness of the steel plate is beneficial to improve the protection of the armored vehicle.
- the increase in the thickness of the steel plate is not conducive to the weight loss of the vehicle, which affects the tactical mobility of the vehicle.
- after the hardness of the steel plate exceeds a certain range it will cause a collapse after being exposed to the bullets or shells. These fragments will directly endanger the personal safety and the normal operation of the equipment.
- the announcement number is CN202750372U, and the publication date is February 20, 2013.
- the Chinese patent document entitled "A New Bulletproof Cabinet” discloses a cabinet body having a bulletproof function.
- the cabinet is provided with bulletproof armor.
- the bulletproof armor is made of 616 armor plate and Kevlar composite plate.
- the 616 armor plate is the outer layer of bulletproof armor.
- the Kevlar composite plate is the inner layer of bulletproof armor.
- the outer layer 616 armor plate is made of 8 mm thick steel plate, and the inner Kevlar composite plate is 7 mm thick steel plate.
- the Chinese patent literature does not cover the product characteristics and comprehensive properties of the relevant steel sheets.
- One of the surfaces of the double-hardness composite steel sheet has an ultra-high hardness, and has a relatively low hardness and a high low-temperature toughness with respect to the other surface of the surface.
- the double hardness composite steel plate of the present invention achieves a combination of high, low hardness and high toughness.
- the double hardness composite steel sheet according to the present invention has good machinability and excellent ballistic performance.
- the present invention provides a double-hardness composite steel plate having a high hardness layer on one surface and a low hardness layer on the other surface, and a rolling composite between the high hardness layer and the low hardness layer.
- Atomic bonding is achieved in which the low hardness layer is Mn13 steel and the high hardness layer has a Brinell hardness of more than 600.
- the low hardness layer means that it has a lower hardness with respect to the high hardness layer.
- its Brinell hardness is generally less than 250.
- Mn13 steel refers to a steel in which the Mn content is controlled within a range of 10% ⁇ Mn ⁇ 20%, and the microstructure of such steel is substantially a single austenite structure.
- the balance is Fe and unavoidable impurities.
- C It can act as a solid solution strengthening in steel, which is a strengthening element that contributes the most to the strength of steel and has the lowest cost.
- the steel contains a high content of C.
- the C content in the high hardness layer of the double hardness composite steel sheet according to the present invention should be controlled to be 0.35 to 0.45%.
- Si is a deoxidizing element.
- Si can be dissolved in ferrite to act as a solid solution strengthening, which is second only to carbon, nitrogen, and phosphorus and exceeds other alloying elements. Therefore, Si can significantly increase the strength and hardness of steel. If it is necessary to utilize Si solid solution strengthening, the amount thereof is usually not less than 0.6%. In the above high hardness layer, the Si content needs to be controlled between 0.8 and 1.6% to achieve solid solution strengthening.
- Mn can reduce the critical cooling rate of steel, thereby greatly improving the hardenability and solid solution strengthening effect on steel.
- the martensite transformation temperature will decrease too much, resulting in an increase in residual austenite at room temperature, which is not conducive to the increase of the strength of the steel; in the center segregation part of the slab
- the formation of coarse MnS reduces the toughness of the center of the plate.
- the Mn content in the above high hardness layer should be controlled to be 0.3 to 1.0%.
- Al is also a deoxidizing element. At the same time, Al can form fine and insoluble AlN particles with nitrogen, refine the microstructure of the steel, and inhibit the formation of BN, so that B exists in a solid solution state, thereby ensuring the hardenability of the steel. Once the Al content exceeds 0.06%, coarse alumina inclusions are formed in the steel. Therefore, the Al content in the high hardness layer is controlled to 0.02 to 0.06%.
- Ni is only soluble in the matrix phase ferrite and austenite in steel, and does not form carbides, and the austenite stabilization effect is very strong.
- Ni is a main element for ensuring high toughness of steel, and the Ni content in the high hardness layer is set to 0.3 to 1.2% in consideration of the strengthening effect of Ni and the cost of addition thereof.
- Cr is an element that reduces the austenite phase region, which is also a medium-strong carbide element. Cr is also soluble in ferrite. Cr can increase the stability of austenite, shifting the C curve to the right, thereby lowering the critical cooling rate to improve the hardenability of the steel.
- the Cr content in the above high hardness layer needs to be controlled to be 0.3 to 1.0%.
- Mo Since Mo can exist in both the solid solution phase and the carbide phase in steel, Mo has both solid solution strengthening and carbide dispersion strengthening effect on steel, thereby significantly increasing the hardness and strength of steel. . For this reason, the Mo content in the above high hardness layer needs to be controlled to be 0.20 to 0.80%.
- Cu:Cu exists mainly in the solid solution state and the elemental phase precipitation in steel, and the solid solution Cu can act as a solid solution strengthening. Since the solid solubility of Cu in ferrite rapidly decreases with decreasing temperature, Cu which is supersaturated with solid solution precipitates as a simple substance at a relatively low temperature, thereby exhibiting precipitation strengthening. The addition of 0.2 to 0.6% of Cu to the above high hardness layer can remarkably improve the resistance of the steel to atmospheric corrosion.
- Ti:Ti can form titanium carbide, titanium nitride or titanium carbonitride with C and N in the steel, so as to refine the austenite grains during the heating and rolling stage of the billet, thereby increasing the strength of the steel and toughness.
- an excessively high Ti content causes more coarse titanium nitride to form in the steel, which adversely affects the strength and toughness of the steel.
- the Ti content in the above high hardness layer should be controlled within a range of 0.01 to 0.05%.
- B When B is added in a small amount, the hardenability of the steel can be remarkably improved, and the martensite structure can be easily obtained in the steel. However, it is not advisable to add too much B because the strong binding force between B and the grain boundary is easy to be segregated to the grain boundary, thereby affecting the overall performance of the steel. For this reason, the B content in the above high hardness layer needs to be controlled in the range of 0.001 to 0.003%.
- the unavoidable impurities in the high hardness layer of the double hardness composite steel sheet according to the present invention are mainly P and S.
- microstructure of the above high hardness layer is martensite and a small amount of retained austenite.
- the comparative example of the above retained austenite is less than 1%.
- the reason why the microstructure of the high hardness layer is controlled to martensite and a small amount of retained austenite is that the retained austenite is not in the phase transition of the supercooled austenite after quenching. Avoiding the structure, strict control of retained austenite is beneficial to ensure the performance of the steel, while the martensite is solid solution strengthening due to the carbon dissolved in the ⁇ phase and the strengthening effect caused by the presence of high density dislocation substructure In order to make the martensite have a high hardness characteristic, in order to ensure the hardness of the high hardness layer, it is necessary to control the microstructure to almost all of the martensite structure.
- the balance is Fe and other unavoidable impurities.
- C is an element that stabilizes austenite, and keeps the austenite structure to room temperature when it is rapidly cooled.
- the increase in carbon content enhances the solid solution strengthening of steel, which increases the strength and hardness of Mn13 steel. If the carbon content is too high, the carbides in the steel will dissolve into the austenite during solution treatment. Because of the large difference in specific volume between carbide and austenite, the high-manganese steel after solid solution has pore defects. This leads to a decrease in density, which has an effect on the properties of high-manganese steel. If water-toughened, the carbides may be distributed along the grain boundaries, resulting in a significant decrease in the toughness of the steel.
- Si is added as a deoxidizing element, and also has a function of strengthening the solid solution and increasing the yield strength.
- Mn is the main alloying element in high manganese steel, which has the function of expanding the austenite phase region, stabilizing austenite and lowering the Ms point. Manganese can maintain the austenite structure to room temperature. In addition to solid solution in the austenite, manganese is also present in the steel (Mn, Fe) C type carbide. If the manganese content is increased, the strength and toughness of the high-manganese steel will increase because manganese has an effect of increasing intergranular bonding force; if the manganese content is too high, the thermal conductivity of the steel increases, and thus the transgranular structure is easily generated, and the influence is high. Mechanical properties of manganese steel. In order to obtain stable mechanical properties, when the carbon content is 0.9-1.5%, the manganese content is generally controlled at 11-19%.
- Al is also a deoxidizing element. At the same time, Al can form fine and insoluble AlN particles with nitrogen to refine the microstructure of the steel, and inhibit the formation of BN, so that B exists in a solid solution state, thereby ensuring the hardenability of the steel. Once the Al content exceeds 0.06%, coarse alumina inclusions are formed in the steel. Therefore, the Al content in the low hardness layer is controlled to 0.02 to 0.06%.
- Mo may be further added in the low hardness layer: 0.90 to 1.80%.
- the reason why the alloying element Mo is further added to the low hardness layer is that the binding force of Mo and iron is relatively strong, and the size of the molybdenum atom is large, and it is difficult to diffuse, so the precipitation amount of carbide in the as-cast high manganese steel to which Mo is added is higher. It is small and does not have a network distribution on the austenite grain boundaries. After water toughening treatment, molybdenum is dissolved in austenite, delaying the decomposition of austenite, which is beneficial to the strength and toughness of high manganese steel.
- the double hardness composite steel sheet according to the present invention has an impact energy at 40 ° C of not less than 50 J.
- the thickness ratio of the high hardness layer to the low hardness layer is (0.43 to 3):1.
- Another object of the present invention is to provide a method for producing a double hardness composite steel sheet.
- the manufacturing method is capable of obtaining a composite steel sheet having two surfaces having different hardness characteristics, one of which has an ultra-high hardness and the other of which has a relatively low hardness and a high low-temperature toughness.
- the combination of high, low hardness and high toughness in the same steel sheet is achieved by this manufacturing method.
- the double-hardness composite steel sheet obtained by the production method has good machinability and excellent ballistic performance.
- a method for manufacturing a double-hardness composite steel sheet according to the present invention includes the steps of:
- Heat treatment heat treatment heating temperature is 1050 ⁇ 1100 ° C, heating time is 2 ⁇ 3min / mm ⁇ plate thickness, the heated composite plate is water-cooled, the water temperature is less than 40 ° C, wherein the unit thickness is mm.
- the key to the manufacturing method of the double-hardness composite steel sheet according to the present invention is that the slab atoms having different hardness characteristics are bonded together by composite rolling.
- Another key point of this manufacturing method is The heating temperature in the heat treatment step is set to 1050 to 1100 ° C to obtain a single uniform austenite microstructure in the low hardness layer slab.
- the purpose of cooling the heated composite sheet with water having a temperature of less than 40 ° C is to perform a water toughening treatment on the low hardness layer slab of the composite sheet to obtain a single austenite microstructure.
- the heat treatment step is quenched for the high hardness layer slab of the composite sheet to obtain a martensite microstructure.
- the heating temperature is 1130 to 1250 ° C, and the heating time is 120 to 180 min.
- step (3) the heating temperature is controlled to be 1130 to 1250 ° C, and the controlled heating time is 120 to 180 min to ensure uniform alloy composition in the composite slab to obtain a complete austenite phase in the low hardness layer. , thereby reducing the yield stress of the slab, thereby reducing the deformation resistance of the finished composite steel sheet.
- the finishing rolling temperature is controlled to be 850 to 1000 °C.
- the final rolling temperature is set to ⁇ 950 ° C in the step (4) in order to reduce the deformation resistance of the composite slab during the rolling stage.
- the alloy composition in the technical solution of the present invention is simple and easy to control, and is mainly composed of medium carbon low alloying elements, and fully utilizes solid solution strengthening effects of alloying elements such as C, Si, Mn, Cr, Ni, Cu, and B, and microalloys.
- the role of fine Ti (C, N) particles formed by the elements Ti and C and N elements refines the austenite grains, and obtains different hardness characteristics through process steps such as rolling and heat treatment in the manufacturing process. Double hardness composite steel plate.
- the microstructure of the high hardness layer in the double hardness composite steel sheet according to the present invention is martensite and a small amount of retained austenite
- the microstructure of the low hardness layer in the double hardness composite steel sheet according to the present invention is a single Austenite.
- the thickness ratio of the high hardness layer and the low hardness layer is adjusted, and then the composite composite is processed to obtain a double composite steel plate having both high and low hardness.
- the manufacturing method of the double hardness composite steel plate according to the present invention achieves the water toughening treatment of the low hardness layer in the composite steel plate by the same heat treatment process step, and also completes the quenching treatment of the high hardness layer in the composite steel plate. .
- the double hardness composite steel plate of the invention has different surface hardness, wherein one surface has a Brinell hardness of >600 and the other surface has a Brinell hardness of ⁇ 250, and has excellent anti-elasticity, which can meet the requirements of domestic armored vehicles for steel plates. Bulletproof requirements.
- the double hardness composite steel sheet according to the present invention has excellent low temperature toughness, and its -40 ° C summer
- the longitudinal impact energy of the V-type is not less than 50J.
- the double-hardness composite steel plate according to the present invention also has good machinability, and is suitable for manufacturing and obtaining a vehicle having bulletproof requirements and structural components thereof.
- the method for producing a double-hardness composite steel sheet according to the present invention can obtain a composite steel sheet having different surface hardness characteristics, and the steel sheet has excellent low-temperature toughness, excellent ballistic performance, and good machinability.
- the manufacturing method of the double-hardness composite steel plate according to the present invention is simple and easy, and is suitable for stable production on medium and heavy plate production lines.
- Fig. 1 is a photograph showing the metallographic structure of the double-hardness composite steel plate of Example A4.
- Example 2 is a microstructure diagram of a high hardness layer in the double hardness composite steel plate of Example A4.
- the thickness of the blank is determined according to the thickness of the finished double hardness composite steel plate and the thickness ratio of the high hardness layer and the low hardness layer;
- heating temperature is 1130 ⁇ 1250 ° C, heating time is 120 ⁇ 180min;
- Heat treatment heat treatment heating temperature is 1050 ⁇ 1100 ° C, heating time is 2 ⁇ 3min / mm ⁇ plate thickness, the heated composite board is water-cooled in the roller or pool, the water temperature is less than 40 °C.
- Table 1 lists the mass distribution ratios of the respective chemical elements in the high hardness layer and the low hardness layer of the double hardness composite steel sheets of Examples A1 to A6.
- I indicates a high hardness layer and II indicates a low hardness layer.
- Table 2 lists the specific process parameters of the manufacturing method of the double hardness composite steel sheets of Examples A1 to A6.
- Table 3 lists the relevant mechanical property parameters of the double hardness composite steel sheets of Examples A1 to A4.
- the impact specimen size of the test plates in A1 and A2 is 5 ⁇ 10 ⁇ 55mm; the impact specimen size of the test plates in A3 ⁇ A6 is 10 ⁇ 10 ⁇ 55mm.
- the position of the impact sample in the thickness direction of the test plate is: sampling on the side of the low hardness layer of the steel plate, and after removing the surface layer of the steel plate by 1 mm, the longitudinal impact sample is processed.
- HB10/3000 indicates the Brinell hardness value measured under a load of 3000 kg using a head having a diameter of 10 mm.
- the high hardness layer of the double hardness composite steel sheets of Examples A1 to A6 has a Brinell hardness of ⁇ 613 HB, and the Brinell hardness of the low hardness layer is ⁇ 250 HB, thereby explaining the composite steel sheet of this embodiment.
- the hardness of the two surfaces is different, and the composite steel sheet has two different hardness characteristics.
- the impact hardness KV2 (-40 ° C) of the double-hardness composite steel sheets of Examples A1 to A6 was all >50 J, thereby demonstrating that the composite steel sheets of the above examples have excellent low temperature toughness.
- Table 4 lists the firing test results for the double hardness composite steels of Examples A1 - A4.
- Examples A1-A6 have excellent ballistic performance, and their anti-elastic properties are in accordance with the FB5 standard in EN.1063.
- Figure 1 shows the metallographic structure of the double hardness composite steel plate of Example A4.
- Fig. 2 shows the microstructure of the high hardness layer in the double hardness composite steel plate of Example A4.
- the double-hardness composite steel plate has a high hardness layer and a low hardness layer, wherein the upper layer is a high hardness layer, the microstructure is martensite and a small amount of retained austenite, and the lower layer is a low hardness layer, The microstructure is a single austenite. It can be seen from Fig. 2 that the microstructure of the high hardness layer is substantially all martensite, and the ratio of retained austenite is less than 1%.
Abstract
Description
Claims (11)
- 一种双重硬度复合钢板,其特征在于:其一个表面为高硬度层,其另一个表面为低硬度层,所述高硬度层与低硬度层之间通过轧制复合实现原子结合,其中低硬度层为Mn13钢,所述高硬度层的布氏硬度大于600。
- 如权利要求1所述的双重硬度复合钢板,其特征在于,所述高硬度层的化学元素质量百分比为:C:0.35~0.45%、Si:0.80~1.60%、Mn:0.3~1.0%、Al:0.02~0.06%、Ni:0.3~1.2%、Cr:0.30~1.00%、Mo:0.20~0.80%、Cu:0.20~0.60%、Ti:0.01~0.05%、B:0.001~0.003%,余量为Fe和不可避免的杂质。
- 如权利要求2所述的双重硬度复合钢板,其特征在于,所述高硬度层的微观组织为马氏体和少量残余奥氏体。
- 如权利要求3所述的双重硬度复合钢板,其特征在于,所述残余奥氏体的相比例低于1%。
- 如权利要求1所述的双重硬度复合钢板,其特征在于,所述低硬度层的化学元素质量百分比为:C:1.00~1.35%、Si:0.30~0.90%、Mn:11.0~19.0%、Al:0.02~0.06%,余量为Fe和其他不可避免的杂质。
- 如权利要求5所述的双重硬度复合钢板,其特征在于,所述低硬度层还具有化学元素Mo:0.90~1.80%。
- 如权利要求1所述的双重硬度复合钢板,其特征在于,其-40℃下的冲击功不低于50J。
- 如权利要求1所述的双重硬度复合钢板,其特征在于,所述高硬度层与低硬度层的厚度比为(0.43~3):1。
- 如权利要求1-8中任意一项所述的双重硬度复合钢板的制造方法,其特征在于,包括步骤:(1)分别制备高硬度层板坯和低硬度层板坯;(2)组坯:对板坯结合面进行预处理,并对板坯贴合面进行四周焊接密封,对焊接密封后的复合坯进行抽真空处理;(3)加热;(4)复合轧制;(5)冷却;(6)热处理:热处理加热温度为1050~1100℃,加热时间为2~3min/mm×板厚,对加热后的复合板进行水冷,水温小于40℃,其中板厚的单位为mm。
- 如权利要求9所述的双重硬度复合钢板的制造方法,其特征在于,在所述步骤(3)中,加热温度为1130~1250℃,加热时间为120~180min。
- 如权利要求10所述的双重硬度复合钢板的制造方法,其特征在于,在所述步骤(4)中,控制终轧温度为850~1000℃。
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JP2018549386A JP6644163B2 (ja) | 2015-12-14 | 2016-12-14 | 二重硬度合わせ鋼板及びその製造方法 |
EP16874827.5A EP3392600B1 (en) | 2015-12-14 | 2016-12-14 | Dual-hardness clad steel plate and production method thereof |
US16/061,189 US10851435B2 (en) | 2015-12-14 | 2016-12-14 | Dual-hardness clad steel plate and production method thereof |
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CN114891989B (zh) * | 2022-06-20 | 2023-05-02 | 河北普阳钢铁有限公司 | 一种耐磨耐蚀复合钢板的轧制工艺 |
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EP3392600B1 (en) | 2021-03-24 |
KR20180097176A (ko) | 2018-08-30 |
JP6644163B2 (ja) | 2020-02-12 |
EP3392600A4 (en) | 2019-05-15 |
EP3392600A1 (en) | 2018-10-24 |
US20180363093A1 (en) | 2018-12-20 |
CN105499269A (zh) | 2016-04-20 |
KR102138313B1 (ko) | 2020-08-14 |
US10851435B2 (en) | 2020-12-01 |
JP2019505687A (ja) | 2019-02-28 |
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