WO2017065013A1 - Granular agrochemical composition and method for manufacturing same - Google Patents

Granular agrochemical composition and method for manufacturing same Download PDF

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Publication number
WO2017065013A1
WO2017065013A1 PCT/JP2016/078869 JP2016078869W WO2017065013A1 WO 2017065013 A1 WO2017065013 A1 WO 2017065013A1 JP 2016078869 W JP2016078869 W JP 2016078869W WO 2017065013 A1 WO2017065013 A1 WO 2017065013A1
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WIPO (PCT)
Prior art keywords
parts
expanded plastic
particle size
agrochemical composition
plastic microballoon
Prior art date
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PCT/JP2016/078869
Other languages
French (fr)
Japanese (ja)
Inventor
聡信 山崎
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クミアイ化学工業株式会社
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Filing date
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Application filed by クミアイ化学工業株式会社 filed Critical クミアイ化学工業株式会社
Priority to JP2017545141A priority Critical patent/JP6732772B2/en
Priority to KR1020187004785A priority patent/KR20180067500A/en
Priority to CN201680050110.6A priority patent/CN107920508B/en
Publication of WO2017065013A1 publication Critical patent/WO2017065013A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • the present invention relates to a water surface-floating large granular pesticide composition, and more specifically, for example, water surface floatability capable of uniformly dispersing a pesticide active ingredient by spraying a small amount directly on the water surface of, for example, a paddy field.
  • the present invention relates to a large granular agrochemical composition and a method for producing the same.
  • agrochemical compositions used in paddy fields and the like are generally granules, powders, emulsions, wettable powders, and flowables.
  • granules and powders have been sprayed directly without diluting 1-4 kg of water per 10a, but in recent years there has been a call for labor saving in spraying pesticides. Therefore, it is possible to reduce the spraying amount as a pesticide composition by increasing the content of the pesticide active ingredient in the pesticide composition, or to spray it by simply throwing it from the shore without entering the paddy field. Things are sought.
  • Patent Document 1 contains an agrochemical active ingredient
  • a water surface-floating large granular agrochemical composition characterized by having a particle size distribution of 80% or more of particles having a particle size of 3 mm or more and a property of floating on the water surface, and disintegrating on the water surface within 30 minutes.
  • the agrochemical composition has a high self-diffusibility, and by spraying a small amount of the agrochemical composition of about 250-500 g per 10 a paddy field, the agrochemical active ingredient is uniformly distributed throughout the paddy field. It can be thrown in and can be said to be an ideal pesticide composition for labor saving application.
  • the granular agrochemical composition described in Patent Document 1 is composed of a self-diffusion design by disintegrating while floating on the water surface when treated in a paddy field, and as a premise for exhibiting such performance, the composition Is required to float in the water.
  • the literature includes perlite made of pearlite and obsidian, foamed shirasu made of shirasu, phyllite fired in an aluminosilicate system, sodium silicate or borax.
  • a method of containing a floating carrier having one or a plurality of independent air chambers, such as fly ash produced as time ash, a method of containing a water-repellent substance such as stearic acid and salts thereof, and hydrophobic white carbon It is disclosed.
  • a hollow microballoon having a thermoplastic polymer wall membrane (hereinafter sometimes referred to as “plastic microballoon” in the present specification) imparts sufficient buoyancy to a granular agrochemical composition with a small amount of blending.
  • Patent Document 2 shows that when a granular agrochemical composition is produced by extrusion granulation, the weight of the granulated product per unit time, that is, the granulation property is also improved. It is described in. Therefore, when it is going to manufacture the granular agrochemical composition of patent document 1 with an extrusion granulation method, a plastic microballoon is a floating carrier to want to employ
  • the plastic micro-balloon is usually a very light powder having a true specific gravity of about 0.02-0.04.
  • the true specific gravity of solid carriers generally used in solid agrochemical compositions such as clay, calcium carbonate, diatomaceous earth, and white carbon is around 2-3, and the true specific gravity of agrochemical active ingredients and surfactants is usually also normal. No less than 1.
  • the raw material containing the agrochemical active ingredient, the surfactant, the plastic microballoon, and the solid carrier is mixed before the granulation step.
  • the plastic microballoons are difficult to proceed with other raw materials due to the difference in true specific gravity.
  • the main object of the present invention is to provide a water surface-floating large-sized granular agricultural chemical composition that employs a plastic microballoon as a floating carrier, a method for producing a water surface-floating large-sized granular agricultural chemical composition that is quickly and stably good in quality, and
  • An object of the present invention is to provide a water surface-floating large-sized granular agricultural chemical composition produced by the method.
  • the present invention has the following contents.
  • a pesticidal active ingredient, a surfactant, a hollow body, and a solid carrier, a particle size distribution with a particle size of 3 mm or more being 80% or more, floating on the water surface, and 30 minutes A method for producing a granular agrochemical composition having a property of collapsing on the water surface within the surface, the surface of an expanded plastic microballoon having an average particle diameter of 1 to 100 ⁇ m as a hollow body, using a thermoplastic polymer as a wall material, Mineral fine powder coated pre-expanded plastic microballoon coated with mineral fine powder having an average particle size of 0.1-15 ⁇ m and 1/2 or less of the pre-expanded plastic microballoon A balloon is mixed with an agrochemical active ingredient, a surfactant and a solid carrier, and then a predetermined amount of water is added to the mixture and kneaded, and the kneaded product is screened with a pore diameter of 3 mm or more.
  • thermoplastic polymer is polyacrylonitrile or a polyacrylonitrile-based copolymer containing acrylonitrile as a monomer unit.
  • the weight of the expanded plastic microballoon obtained by removing mineral fine powder from the surface of the mineral powder coated expanded plastic microballoon is 5-20 mass%.
  • the agrochemical active ingredient, the surfactant, and the thermoplastic polymer produced by the production method according to any one of (1) to (5) above are used as wall materials, and the average particle size is 1 to 100 ⁇ m.
  • a granular agrochemical composition comprising a solid carrier and having a particle size distribution of 80% or more having a particle size of 3 mm or more, and a property of floating on the water surface and disintegrating on the water surface within 30 minutes.
  • the surface of an already expanded plastic microballoon having an average particle size of 1 to 100 ⁇ m and an average particle size of 0.1 to 15 ⁇ m.
  • a granular agrochemical composition characterized by being a mineral fine powder-covered expanded plastic microballoon coated with a mineral fine powder that is 1/2 or less of an already expanded plastic microballoon.
  • a pesticidal active ingredient, a surfactant, a hollow body, and a solid carrier, a particle size distribution having a particle size of 3 mm or more is 80% or more, floating on the water surface, and 30 minutes
  • the surface of an already expanded plastic microballoon having an average particle diameter of 1 to 100 ⁇ m as a hollow body and a thermoplastic polymer as a wall material has an average particle diameter Mineral fine powder coated pre-expanded plastic microballoon coated with mineral fine powder having a particle size of 0.1-15 ⁇ m and 1/2 or less of the pre-expanded plastic microballoon.
  • a method for improving disintegration of a granular agrochemical composition comprising extruding and granulating the resulting granulated product to remove moisture.
  • the hollow body is uniformly dispersed in the raw material mixture of the agricultural chemical granular composition by mixing in a very short time, an agricultural chemical granular composition having excellent water surface floatability can be obtained efficiently. It becomes possible. Furthermore, since the disintegration time on the water surface is shortened, the agrochemical granular composition produced by the method of the present invention is not easily affected by wind blowing around the field at the time of spraying, and phytotoxicity due to uneven distribution of components in the field. It becomes an agrochemical granular composition excellent in disintegration without fear of occurrence.
  • short diameter means the length of a short part in the shape of the granule
  • particle size It means the particle size obtained by a sieving method using a sieve with a predetermined opening
  • ⁇ particle size distribution '' means the cumulative weight percentage of the predetermined particle size range obtained by the sieving method.
  • average particle size means the volume average diameter determined by the laser diffraction method
  • particle size distribution is a predetermined value determined by the laser diffraction method. It means the cumulative volume percentage of the particle size range (measured by wet method; SK Laser Micron Sizer LMS-2000e (manufactured by Seishin Enterprise)).
  • composition is an extruded granulated product comprising an agrochemical active ingredient, a surfactant, a hollow body, and a solid carrier.
  • a granular agrochemical composition having a particle size distribution of 3% or more having a particle size distribution of 80% or more, a property of floating on the water surface, and a disintegration time of 30 minutes or less.
  • Such a granular agrochemical composition is first mixed with raw materials constituting the granular agrochemical composition, added with a predetermined amount of water, kneaded, extruded from a screen having a pore diameter of 3 mm or more, granulated, dried, for example, It can be obtained by taking out granules having a desired particle size using two sieves having different openings.
  • the agrochemical active ingredient that can be used in the granular agrochemical composition of the present invention is not particularly limited, and may be solid or liquid at room temperature. Although the agrochemical active ingredient which can be used for this invention is listed below, it is not limited to these.
  • [Insecticide active ingredient] Acrinathrin, Azadirachtin, Azamethiphos, Azinophos-ethyl, Azeinosylacetin, Acequinocetyl (Acephate), azocyclotin, abamectin, afidopyropen, amidoflumet, amitraz, alanib, alicalb, aldib Aldoxycarb, allethrin [including d-cis-trans-form and d-trans-form], isazophos, isamifofos, isocarbophos, isoxathion methyl, isoxathion methyl, isoxathion (Isofenphos-methyl), isoprocarb, ivermectin, imicyafos, imidacloprid, imiprothrin, indoxacarb, indoxacarb offencarb, ethifotin, etemoforthos,
  • Islaelensis Bacillus thuringiensis subsp. Kurstakis, B. burs. thuringiensis subsp. , DDT (1,1 1-trichloro-2,2-bis (4-chlorophenyl) ethane), DEP (dimethyl-2,2,2-trichloro-1-hydroxyethylphosphonate), DNOC (4,6-dinitro-o-cresol), DSP (O, O-diethyl-O- [4- (dimethylsulfamoyl) phenyl] -phosphorothionate), EPN (O-ethyl-O-4- (nitrophenyl) phenylphosphonothioate, nuclear polyhedrosis) Virus embedded body, NA-85 (code number), NA-89 (code number), NC-515 (code number), RU15525 (code number), ZDI-2501 (code number), XMC (XMC), Z- 13-Icosen-10-one, ZXI89
  • pesticidal active ingredients azimusulfuron, azoxystrobin, anilophos, isoprothiolane, ipfencarbazone, imazosulfuron, imidacloprid, indanophane, etiprole, ethoxysulfuron, oxadiargyl, oxadichrome mephone, caventrolol, cartap, carfentrazone / ethyl , Quinoclamine, cumyluron, chromeprop, chlorantraniliprole, cyantraniprolol, cyclosulfamuron, cycloprotonline, dinotefuran, cyhalohop butyl, dimetamethrin, sulfoxafurol, diemron, thiobencarb, tenylchlore, tefriltrione, triafmon, tricyclazole , Triflumezopyrim, halosulfuron methyl
  • the above-mentioned pesticidal active ingredients may be used pure or as they are, or may be used in the form of a premix in which the pesticidal active ingredients are previously mixed with solid or liquid auxiliary materials. Furthermore, it can also be used in the form of a reservoir microcapsule in which an agrochemical active ingredient is coated with a wall material, or a monolithic microcapsule in which an agrochemical active ingredient is dispersed in a core matrix.
  • agrochemical active ingredients represented by the methods exemplified above, and known methods and materials may be arbitrarily used as desired.
  • the above pesticidal active ingredients can be used alone or in admixture of two or more.
  • the total blending ratio of these pesticidal active ingredients is not particularly limited, but is usually 0.1 to 65% by mass, preferably 0.5 to 60% by mass, more preferably based on the total amount of the granular pesticidal composition. 1-50 mass%.
  • a phytotoxicity reducing compound can be blended together with the above pesticidal active ingredient.
  • blended is described below, this invention is not limited to these safener compounds.
  • the above phytotoxicity reducing compounds can be used alone or in admixture of two or more. Further, when these phytotoxicity reducing compounds are blended, the total blending ratio is usually 0.1-40% by mass, preferably 0.5-30% by mass, more preferably based on the total amount of the granular agrochemical composition. 1-25% by mass.
  • a surfactant is blended in order to disintegrate the grains on the water surface and diffuse the agrochemical active ingredient into water.
  • the surfactant that can be used those generally used in agricultural chemical compositions can be used.
  • surfactants examples include polyethylene glycol higher fatty acid esters, polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene aryl phenyl ethers, sorbitan monoalkylates, acetylene alcohols and acetylenic diols and their Nonionic surfactants such as alkylene oxide adducts; alkylaryl sulfonates, dialkyl sulfonates, lignin sulfonates, naphthalene sulfonates and their condensates, alkyl sulfates, alkyl phosphates, alkylaryls Sulfate ester salt, alkylaryl phosphate ester salt, polyoxyethylene alkyl ether sulfate ester salt, polyoxyethylene alkyl aryl ether sulfate ester Anionic surfactants such as thiol salts, polyoxyethylene arylphenyl
  • the above surfactants can be used alone or in admixture of two or more.
  • the total blending ratio of these surfactants is not particularly limited, but is usually 0.1-15% by mass, preferably 0.5-12.5% by mass, more preferably based on the total amount of the granular agrochemical composition. 1-10% by mass.
  • the granular agricultural chemical composition of the present invention floats on the water surface.
  • methods for imparting water surface floatability to granular agrochemical compositions include, for example, perlite made of pearlite or obsidian, foamed shirasu made of shirasu, phylite baked in an aluminosilicate system, sodium silicate or borax.
  • the former More preferably, a method of containing a standing hollow body having one or a plurality of air chambers is used, and as the hollow body, a plastic microballoon having a thermoplastic polymer as a wall material is less than 5% by mass based on the total amount of the granular composition.
  • a plastic microballoon having a thermoplastic polymer as a wall material is less than 5% by mass based on the total amount of the granular composition.
  • This is particularly preferable in that it can ensure the water surface floatability of the granular pesticide composition from a small amount and also has a secondary effect of improving the granulation property when the raw material kneaded product is extruded and granulated.
  • thermoplastic polymer used as the wall material of the plastic microballoon examples include vinyl polymers such as hard or soft polyvinyl chloride, polyvinylidene chloride or polyvinyl alcohol; polystyrene, high density, medium density or low density polyethylene, Polystyrene polymers such as ethylene / vinyl acetate copolymers; non-modified polypropylene; polyacetal polymers of homopolymers or copolymers; acrylic polymers such as polymethyl methacrylate and methacryl / styrene copolymers; acetic acid Cellulose; Polycarbonate; Polyester polymer such as polyethylene terephthalate; Polyamide polymer such as nylon 6 and nylon 66; Thermoplastic polyurethane; Ethylene trifluoride, tetrafluoroethylene, tetrafluoroethylene / hexafluoropropylene Polymer Fluoropolymers such as tetrafluoroethylene / perfluoroal
  • examples of the monomer copolymerizable with acrylonitrile include (meth) acrylic acid, (meth) acrylic acid ester, styrene, vinyl acetate, vinylidene chloride and the like.
  • styrene / Acrylonitrile copolymer styrene / butadiene / acrylonitrile copolymer, vinylidene chloride / methyl methacrylate / acrylonitrile copolymer, methyl methacrylate / acrylonitrile / methacrylonitrile copolymer, methyl methacrylate / acrylonitrile copolymer, acrylonitrile / Methacrylonitrile / itaconic acid copolymer.
  • a methyl methacrylate / acrylonitrile copolymer is preferable in that it is hardly affected by organic substances such as agrochemical active ingredients.
  • plastic micro-balloons contain a gas source such as low-boiling hydrocarbons in a thermoplastic polymer film material, soften the film material by heat treatment, and at the same time expand the gas source so that the inside of the film material is hollow. It is a hollow body having a structure. Therefore, as an aspect of the plastic microballoon raw material, there is an unexpanded plastic microballoon that is assumed to be inflated by heat treatment in the manufacturing process of the final product, but the plastic microballoon raw material used in the manufacturing method of the present invention Since the surface is used by coating the surface with mineral fine powder, a heat-treated already expanded plastic microballoon is suitable.
  • a gas source such as low-boiling hydrocarbons in a thermoplastic polymer film material
  • the preferable average particle size of the plastic microballoon used in the production method of the present invention is 1-100 ⁇ m, more preferable average particle size is 10-70 ⁇ m, and particularly preferable average particle size is 20-60 ⁇ m. If the average particle size of the plastic microballoon is too small, it becomes difficult to coat the surface of the plastic microballoon with an appropriate amount of mineral fine powder described later, while the average particle size of the plastic microballoon is excessive. In addition, the strength of the membrane material is insufficient, and during the production process of the granular agrochemical composition, the load applied during kneading or granulation cannot be withstood, and the hollow structure may be damaged.
  • the production method of the present invention is characterized in that a mineral fine powder-coated expanded plastic microballoon in which the surface of the aforementioned expanded plastic microballoon is coated with a mineral powder is used as the hollow body.
  • a mineral fine powder that can be used for coating the surface of the plastic microballoon includes, for example, calcium carbonate, titanium oxide, talc and the like.
  • a fine mineral powder having an average particle size of 0.1-15 ⁇ m and 1 ⁇ 2 or less of the average particle size of the plastic microballoon is preferable, and in particular, an average particle size of 1-12 ⁇ m and an average particle of the plastic microballoon Mineral fine powder having a diameter of 2/5 or less is preferred.
  • the previously expanded plastic microballoons coated with mineral fine powder as described above are rapidly mixed with powders of agrochemical active ingredients, surfactants, solid carriers, etc., despite their extremely small true specific gravity. To do. Therefore, according to the production method of the present invention, since a homogeneous raw material mixture can be obtained in a short mixing step, the production efficiency of the granular agricultural chemical composition is remarkably improved, and the quality that is surely floating on the water surface is good. Can be produced stably. In turn, the granular agrochemical composition produced by the production method of the present invention reliably floats on the water surface and has good quality.
  • the raw material mixture can be homogenized by mixing for a long time at the expense of production efficiency. Compared to the present invention, it takes a long time to collapse on the water surface during application.
  • the granular agrochemical composition of the present invention has improved disintegration compared to that using a plastic microballoon that is not coated with mineral fine powder.
  • the disintegration time on the water surface is 10% or more, more preferably 20 %, And is less susceptible to wind blows around the field when sprayed, and is less likely to cause phytotoxicity due to uneven distribution of components in the field.
  • pre-expanded plastic microballoon coated with mineral fine powder commercially available products such as Matsumoto Microsphere MFL series (made by Matsumoto Yushi) may be used as they are, or the pre-expanded plastic microballoon not covered with mineral fine powder and mineral By mixing the fine powder, an already expanded plastic microballoon covered with the fine mineral powder can be obtained.
  • an expanded plastic microballoon covered with mineral fine powder can be obtained according to the above, and the unexpanded plastic Microballoon raw material and mineral fine powder are mixed, and the resulting mixture is heated to expand the unexpanded plastic microballoon raw material, and the fine powder is attached to the outer surface of the obtained expanded plastic microballoon. It can also be made.
  • this coating step is carried out by itself, it is preferable to perform the coating process in a system in which only the unexpanded plastic microballoon raw material or the already expanded plastic microballoon and the mineral fine powder exist.
  • the expanded plastic microballoon not covered with the mineral fine powder, the mineral fine powder, and all the other raw materials constituting the granular pesticide composition are mixed.
  • the mineral fine powder does not selectively adhere to the surface of the plastic microballoon and is dispersed in the raw material mixture, the effect of the present invention is not exhibited.
  • “coating” means a state in which mineral fine powder is adhered to all or a part of the surface of an already expanded plastic microballoon.
  • the coating amount of the mineral fine powder on the plastic microballoon is not particularly limited, but the weight of the plastic microballoon obtained by removing the mineral fine powder from the surface of the plastic microballoon is 5 on the basis of the total amount of the mineral fine powder-coated inflated plastic microballoon. It is preferably ⁇ 20% by mass.
  • the mineral fine powder-covered pre-expanded plastic microballoon is dispersed in water and only the mineral fine powder is utilized by utilizing the difference in specific gravity. Examples of the means for removing the moisture after settling and removing the water can be exemplified.
  • Mineral fine powder-coated expanded plastic microballoons used in the production method of the present invention may contain a small amount of moisture, but excess moisture is a binder that aggregates mineral fine powder-coated expanded plastic microballoons. In the mixing step with other raw materials, it may interfere with the rapid mixing of the mineral fine powder-coated expanded plastic microballoons.
  • the water content of the mineral fine powder-coated expanded plastic microballoon is preferably 5% by mass or less, and particularly preferably 3% by mass or less.
  • the production method of the present invention is used in combination with a mineral fine powder-coated expanded plastic microballoon, and is a hollow body other than a plastic microballoon or plastic microballoon that is not coated with a mineral fine powder (hereinafter collectively referred to as other hollow bodies).
  • a mineral fine powder-coated expanded plastic microballoon is a hollow body other than a plastic microballoon or plastic microballoon that is not coated with a mineral fine powder (hereinafter collectively referred to as other hollow bodies).
  • other hollow bodies are not excluded at the same time, and such a production method and the granular agrochemical composition thus obtained are also included in the present invention.
  • most of the hollow bodies are preferably made of mineral fine powder-coated expanded plastic microballoons.
  • the mineral fine powder-coated expanded plastic microballoon is 50% by mass or more, preferably 70% by mass or more, more preferably It is good to set it as 90 mass% or more.
  • the amount of these hollow bodies to be blended is not particularly limited as long as the total amount of the hollow body is such that the granular agrochemical composition obtains water surface floatability. Since it may be unfavorable, for example, it may be crushed during transportation or use, or the amount of dust generated during production may be increased, it is desirable to add the minimum amount necessary. For this reason, the upper limit of the blending amount of the hollow body is generally up to about 30% by mass, preferably 15% by mass or less, more preferably 5% by mass or less, based on the total amount of the granular agricultural chemical composition.
  • the composition can obtain water surface floatability even with a blending amount of 5% by mass or less as the plastic microballoon body.
  • a minimum is 0.3 mass%, and it is preferable that it is 0.5 mass% or more. If the blending ratio is less than 0.3% by mass, the composition may not exhibit water surface floatability.
  • the granular agrochemical composition of the present invention it is desirable to contain a trace amount of water in the composition in order to enhance the effect of the hollow body.
  • the water content is not particularly limited, but is usually about 0.3 to 3% by mass, preferably about 0.3 to 1.5% by mass, based on the total amount of the granular agrochemical composition.
  • water is 0.3% by mass or less, the structure allows water to easily enter the composition. Therefore, when the composition is poured into water, it floats once on the surface of the water, but then the air inside the composition In some cases, it may fall out and settle, and the above-mentioned floating carrier must be contained more than necessary, which may be undesirable.
  • the water content is 3% by mass or more, it may be unfavorable because the particles may adhere to each other, making it difficult to disperse and making the composition brittle and generating fine powder during application. is there.
  • the granular agrochemical composition of the present invention as a method of containing a predetermined amount of water, there is also a method of adding the composition by spraying after completely drying the composition, but usually while measuring the water content What is necessary is just to complete
  • the water content in the granular agrochemical composition of the present invention can be measured using, for example, a Karl Fischer moisture measuring device or an infrared moisture measuring device.
  • a solid carrier is blended.
  • a water-soluble carrier or a water-insoluble carrier can be used, and these can be used in combination.
  • Water-soluble carriers include, for example, organic or inorganic acid salts such as ammonium sulfate, ammonium bicarbonate, ammonium nitrate, ammonium chloride, potassium chloride, sodium sulfate, magnesium sulfate, sodium citrate, sodium carbonate, sodium bicarbonate, citric acid, succinic acid Organic acids such as sucrose, saccharides such as lactose, urea and the like.
  • Mineral fine powder is generally used as the water-insoluble carrier, and examples thereof include clays, calcium carbonate, bentonite, talc, diatomaceous earth, calcium stearate, and white carbon.
  • the solid carriers can be used alone or in admixture of two or more.
  • the total blending ratio of these solid carriers is not particularly limited, but is usually 0.1-99.2% by mass, preferably 10-70% by mass, based on the total amount of the granular agricultural chemical composition.
  • an auxiliary agent is blended as necessary as other components.
  • the auxiliary agent which is an optional component include a binder, a disintegrant, and an agrochemical active ingredient decomposition inhibitor.
  • binder examples include carboxymethylcellulose sodium salt, dextrin, water-soluble starch, xanthan gum, guar seed gum, sucrose, polyvinylpyrrolidone, polyvinyl alcohol, polyacrylic acid sodium salt, polyoxyethylene having an average molecular weight of 6,000 to 5 million, and the like. Can be mentioned.
  • disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylate copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene -Maleic anhydride copolymer, starch-polyacrylonitrile graft copolymer, etc. can be mentioned.
  • the decomposition inhibitor include desiccants such as zeolite, quicklime and magnesium oxide, antioxidants such as phenol compounds, amine compounds, sulfur compounds and phosphate compounds, UV absorption of salicylic acid compounds and benzophenone compounds. Agents and the like.
  • the adjuvants can be used alone or in admixture of two or more. When these adjuvants are blended, the total blending ratio of the adjuvants is usually 0.01-10% by mass, preferably 0.1-6% by mass, based on the total amount of the granular agrochemical composition.
  • an organic solvent may be used when the agrochemical active ingredient is dissolved or dispersed.
  • the organic solvent include dioctyl phthalate, methyl naphthalene, alkyl pyrrolidone, phenyl xylyl ethane, glycerin, alkylene glycol, machine oil, methane series hydrocarbon, fatty acid ester, polybasic acid, coconut oil, soybean oil, rapeseed oil. Silicone oil or the like can be used, but a high boiling point solvent is preferable.
  • the organic solvents can be used alone or in admixture of two or more. When these organic solvents are blended, the total blending ratio of the organic solvents is usually 10 to 200 parts by weight with respect to 100 parts by weight of the pesticidal active ingredient.
  • the granular agrochemical composition of the present invention is usually a granular composition that floats on the water surface containing the components described above, but each of the aforementioned components and blending amounts is a composition having a particle size of 3 mm or more.
  • the disintegration time is adjusted to be within 30 minutes, preferably within 20 minutes. When the disintegration time exceeds 30 minutes, the composition is blown by the wind, which is not preferable.
  • each of the above components is such that when the composition floats on the water surface, the portion exposed on the water surface is 40% or less, preferably 20% or less of the entire composition. It is desirable to adjust the blending amount.
  • the manufacturing process itself of the granular agrochemical composition of the present invention is in accordance with a publicly known method except that a mineral fine powder-coated expanded plastic microballoon is employed as a hollow body. That is, (A) mixing all the raw materials constituting the granular agrochemical composition to obtain a mixture; (B) adding a predetermined amount of water to the mixture obtained in the step (a) and kneading the mixture; (C) discharging and granulating the kneaded product obtained in the step (b) from a screen having a pore diameter of 3 mm or more using an extrusion granulator; (D) drying the granulated product obtained in the step (c);
  • the granular agrochemical composition of this invention can be obtained by passing through.
  • step (a) all raw materials constituting the granular agrochemical composition including the agrochemical active ingredient, surfactant, mineral fine powder-coated expanded plastic microballoon and solid carrier are mixed.
  • a known mixer such as a Nauta mixer or a vertical mixer can be used.
  • the time required for this mixing is usually about 30 seconds to 3 minutes, depending on the performance of the mixer and the batch scale.
  • step (b) water is added to the mixture obtained as described above and kneaded (step (b)).
  • a known kneader such as a kneader, a ribbon mixer, or a vertical mixer can be used.
  • the amount of water to be added is not particularly limited, but about 10-15% by mass is usually added to the mixture in an external ratio.
  • This mixture is kneaded in the kneader for a predetermined time to obtain a kneaded product.
  • This kneaded product is discharged from a screen having a pore diameter of 3 mm or more, preferably 3-10 mm, using an extrusion granulator and granulated (step (c)), and then the obtained granulated product is dried (step (c) d)). Further, the drying temperature when the granulated product is dried is not particularly limited, but is about 40 to 95 ° C.
  • composition of the granular agrochemical composition of the present invention include, for example, an active ingredient having a water surface application effect as a component, and its particle size is 3-8 mm and the specific gravity is 0.3-1. Examples include those that disintegrate in 5-20 minutes after spraying.
  • the granular agrochemical composition of the present invention is required to contain more particles having a particle size of 3 mm or more, that is, to have a particle size distribution in which particles having a particle size of 3 mm or more are 80% or more. More preferably, the particle size of ⁇ 10 mm is 80% or more, and in particular, the particle size of 3-8 mm is 80% or more.
  • a method for spraying the granular agrochemical composition of the present invention described above on the surface of water such as paddy fields.
  • a method of holding and throwing the composition with a hand wearing vinyl gloves, using a power spreader A method of continuously discharging and spraying from the nozzle, or a method of intermittently discharging and spraying by opening and closing the shutter lever, a method of throwing using a handle, and a method of throwing and throwing a cylindrical container , A method using a hand-pulverized granulator, and a method of spraying in a streak-like manner or a spot using a radio control helicopter.
  • a predetermined amount of the obtained granular agricultural chemical composition may be packaged with a water-soluble film such as polyvinyl alcohol, and the packaged body may be put into a paddy field or the like as a so-called jumbo agent.
  • the labor-saving spraying composition on which local spraying is a premise was a composition sprayed when rice plants are small.
  • the granular pesticide composition of the present invention has good diffusion of the pesticide active ingredient in the paddy field where algae is generated, or in the paddy field where rice plants have grown to some extent, and the desired pesticide effect can be obtained. It can be said that it is a water-floating granular pesticide composition, and by spraying this to a specific position in a paddy field and within a specific area, it is possible to achieve a uniform pesticide active ingredient with almost no hindrance to labor saving when spraying pesticides. It can be spread. That is, the diffusible granular pesticide composition having a particle size of 3 mm or more according to the present invention is 80% or more, floats on the water surface, and disintegrates on the water surface within 30 minutes. By spraying over the above distance, preferably at a distance of 2 m or more from the shore, 5-50% of the total paddy area, preferably 10-50%, it is uniformly distributed in the paddy field. Can be sprayed.
  • the granular pesticide composition of the present invention is sprayed over 50% or more of the total paddy field area, it is meaningless for the purpose of labor-saving pesticide spraying, and sprayed over an area of 50% or less. Is desirable. Furthermore, naturally, even in a paddy field free from algae, a paddy field before transplanting, or a paddy field with a small rice stock, the diffusion of the pesticidal active ingredient by the granular pesticide composition of the present invention is good, and An effect is obtained.
  • Example 1 Caffeanthrol 3 parts, benzobicyclone 8 parts, bensulfuron methyl 3 parts, dialkylaryl sulfonate 3.5 parts, anhydrous sodium sulfate 1.5 parts, polyoxyalkylene alkynyl glycol ether 2 parts, modified dextrin 2 parts, average 13 parts of an already inflated plastic microballoon having an average particle diameter of 41 ⁇ m using a vinylidene chloride / acrylonitrile copolymer surface-coated with calcium carbonate having a particle diameter of 11 ⁇ m as a wall material (1.95 parts as a plastic microballoon and 11.95 as calcium carbonate).
  • Example 2 Pyriminobac methyl 1.2 parts, pyrazosulfuron ethyl 0.84 parts, bromobutide 36 parts, polyoxyethylene arylphenyl ether sulfate 1 part, polyoxyethylene alkyl ether 1 part, alkylaryl sulfonate formalin condensate 5 parts, Alkyl aryl sulfonate 5 parts, polyoxyalkylene alkynyl glycol ether 1.5 parts, vinylidene chloride / acrylonitrile copolymer coated on the surface with calcium carbonate having an average particle diameter of 11 ⁇ m as a wall material having an average particle diameter of 41 ⁇ m 10 parts of plastic microballoons (1.5 parts as plastic microballoons, 8.5 parts as calcium carbonate), pre-expanded plastic microballs having an average particle diameter of 41 ⁇ m using vinylidene chloride / acrylonitrile copolymer as a wall material 10 parts of water containing 85% water (1.5 parts
  • Example 3 2 parts of pyrimylsulfan, 6 parts of pyraclonyl, 6 parts of phenoxasulfone, 1.65 parts of dialkylaryl sulfonate, 0.7 parts of anhydrous sodium sulfate, 4 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphate-crosslinked starch 5 parts, 1 part of polyoxyalkylene alkynyl glycol ether, 2 parts of polypropylene glycol, pre-expanded plastic microballoon with an average particle diameter of 41 ⁇ m using vinylidene chloride / acrylonitrile polymer coated on the surface with calcium carbonate having an average particle diameter of 11 ⁇ m as a wall material 13 parts (1.95 parts as a plastic microballoon, 11.05 parts as calcium carbonate), 15 parts of diatomaceous earth, 5 parts of bentonite and 37.65 parts of clay were weighed and mixed for 60 seconds with a vertical mixer.
  • Example 4 2 parts of pyrimisulphan, 12 parts of benzobicyclone, 8 parts of phenoxasulfone, 2.1 parts of dialkylaryl sulfonate, 0.9 parts of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphoric acid 5 parts of cross-linked starch, 1.5 parts of polyoxyalkylene alkynyl glycol ether, 3 parts of polypropylene glycol, and an average particle diameter of 28 ⁇ m having a wall material of methyl methacrylate / acrylonitrile polymer coated with calcium carbonate having an average particle diameter of 10 ⁇ m 9 parts of pre-expanded plastic microballoon (1.8 parts as plastic microballoon, 7.2 parts as calcium carbonate), 15 parts of diatomaceous earth, 5 parts of bentonite and 33.5 parts of clay were weighed and mixed for 60 seconds with a vertical mixer.
  • Example 5 2 parts of pyrimylsulfan, 40 parts of mefenacet, 2.1 parts of dialkylaryl sulfonate, 0.9 part of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, 5 parts of phosphate cross-linked starch, polyoxyalkylene 1 part alkynyl glycol ether, 2 parts polypropylene glycol, 11.25 parts of an inflated plastic microballoon having an average particle diameter of 56 ⁇ m with a wall material of methyl methacrylate / acrylonitrile polymer coated with calcium carbonate having an average particle diameter of 8 ⁇ m ( 1.8 parts as a plastic microballoon and 9.45 parts as calcium carbonate), 15 parts of diatomaceous earth, 5 parts of bentonite, and 12.75 parts of calcium carbonate having an average particle diameter of 30 ⁇ m were weighed and mixed for 60 seconds with a vertical mixer.
  • Example 6 Surface coating with 48 parts of pyroxylone, 10 parts of alkyl aryl sulfonate, 1 part of polyoxyethylene aryl phenyl ether sulfate, 1 part of polyoxyethylene alkyl ether, 2 parts of polyoxyalkylene alkynyl glycol ether, calcium carbonate with an average particle size of 8 ⁇ m 10 parts of an expanded plastic microballoon having an average particle size of 56 ⁇ m using 1.6 methyl methacrylate / acrylonitrile polymer as a wall material (1.6 parts as a plastic microballoon, 8.4 parts as calcium carbonate), 3 parts bentonite, urea One part and 24 parts of calcium carbonate having an average particle diameter of 8 ⁇ m were weighed and mixed with a vertical mixer for 60 seconds.
  • Example 7 2 parts of pyrimisulphan, 12 parts of benzobicyclone, 8 parts of phenoxasulfone, 2.1 parts of dialkylaryl sulfonate, 0.9 parts of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphoric acid 5 parts of cross-linked starch, 1.5 parts of polyoxyalkylene alkynyl glycol ether, 3 parts of polypropylene glycol, an existing particle having an average particle diameter of 28 ⁇ m using a methyl methacrylate / acrylonitrile polymer coated with talc having an average particle diameter of 10 ⁇ m as a wall material.
  • Comparative Example 2B Except for mixing time of 5 minutes, in the same manner as Comparative Example 2A, a granular agrochemical with a short diameter of 5 mm containing 1.2% by mass of pyriminobac-methyl, 0.84% by mass of pyrazosulfuron / ethyl and 36% by mass of bromobutide A composition was obtained.
  • Comparative Example 3B A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of pyrimislphan, 6% by mass of pyraclonyl and 6% by mass of phenoxasulfone was obtained in the same manner as in Comparative Example 3A except that the mixing time was changed to 5 minutes. It was.
  • Comparative Example 4B Except for mixing time of 5 minutes, in the same manner as in Comparative Example 4A, a granular agrochemical composition having a short diameter of 5 mm containing 2% by mass of pyrimulsulfan, 12% by mass of benzobicyclone, and 8% by mass of phenoxasulfone. Got.
  • Comparative Example 5B A granular agrochemical composition with a short diameter of 5 mm containing 2% by mass of pyrimylsulfan and 40% by mass of mefenacet was obtained in the same manner as in Comparative Example 5A except that the mixing time was 5 minutes.
  • Comparative Example 6B A granular agrochemical composition having a minor axis of 5 mm containing 48% by mass of pyroxylone was obtained in the same manner as in Comparative Example 6A except that the mixing time was 5 minutes.
  • Comparative Example 7B A granular agrochemical composition having a minor axis of 5 mm containing 48% by mass of pyroxylone was obtained in the same manner as in Comparative Example 7A except that the mixing time was 5 minutes.
  • Test Example 1 100 grains of the agrochemical granular composition obtained in Examples and Comparative Examples were put into a water tank filled with industrial water at room temperature, and the number of settled grains was measured. The results are shown in Table 1.
  • Test Example 2 One pesticide granular composition obtained in Examples 2-4, 6 and 7 and Comparative Examples 2B-4B, 6B and 7B was put into a water tank filled with room-temperature industrial water and floated on the water surface. The time required for the object to collapse was measured. The results are shown in Table 2.
  • the hollow body is uniformly dispersed in the raw material mixture of the agricultural chemical granular composition by mixing in a very short time, an agricultural chemical granular composition having excellent water surface floatability can be obtained efficiently. It becomes possible. Furthermore, since the disintegration time on the water surface is shortened, the agrochemical granular composition produced by the method of the present invention is not easily affected by wind blowing around the field at the time of spraying, and phytotoxicity due to uneven distribution of components in the field. It becomes an agrochemical granular composition excellent in disintegration without fear of occurrence.

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Abstract

The present invention addresses the problem of providing: a method for quickly and stably manufacturing a high-quality water-surface-floating large-grain agrochemical composition in which plastic microballoons are adopted as a floating carrier; and a high-quality water-surface-floating large-grain agrochemical composition manufactured using the method. The method for manufacturing a granular agrochemical composition by which the aforesaid problem is overcome: contains an agrochemical active component, a surfactant, hollow bodies, and a solid carrier; has a particle size distribution in which particles measuring 3 mm or more in diameter account for 80% or more; and has the property of floating on a water surface and disintegrating on the water surface within 30 minutes, wherein the method is characterized in that: in the hollow bodies, a thermoplastic polymer is used as a wall member; mineral-substance-micropowder-coated expanded plastic microballoons are used, said microballoons being obtained by covering the surface of expanded plastic microballoons having an average particle size of 1-100 µm with a mineral-substance micropowder in which the average particle size is 0.1-15 µm and is no more than 1/2 of the expanded plastic microballoons; the mineral-substance-micropowder-coated expanded plastic microballoons are blended with the agrochemical active component, the surfactant, and the solid carrier, whereupon a prescribed amount of water is added to the mixture and the mixture is kneaded; and the mixture is extruded through a screen having a hole diameter of 3 mm or more and granulated, whereupon the obtained granules are dried and moisture is removed.

Description

粒状農薬組成物及びその製造方法Granular agrochemical composition and method for producing the same
　本発明は、水面浮遊性大型粒状農薬組成物に関し、更に詳細には、例えば水田などの水面に部分的に少量を直接散布することで、農薬活性成分を均一に拡散することのできる水面浮遊性大型粒状農薬組成物及びその製造方法に関する。 The present invention relates to a water surface-floating large granular pesticide composition, and more specifically, for example, water surface floatability capable of uniformly dispersing a pesticide active ingredient by spraying a small amount directly on the water surface of, for example, a paddy field. The present invention relates to a large granular agrochemical composition and a method for producing the same.
　従来、水田などで用いられる農薬組成物は、粒剤、粉剤、乳剤、水和剤、及びフロアブル剤が一般的である。これらの農薬組成物のなかで粒剤及び粉剤は、通常１０ａ当たり１－４ｋｇを水に希釈しないで直接散布されてきたが、近年、農薬散布の省力化が叫ばれており、これに対応するために、農薬組成物中の農薬活性成分含有量を高めて農薬組成物としての散布量を低減することや、あるいは水田に入らずに畦畔から投げ込むだけで散布可能な、省力散布対応農薬組成物が求められている。 Conventionally, agrochemical compositions used in paddy fields and the like are generally granules, powders, emulsions, wettable powders, and flowables. Of these agrochemical compositions, granules and powders have been sprayed directly without diluting 1-4 kg of water per 10a, but in recent years there has been a call for labor saving in spraying pesticides. Therefore, it is possible to reduce the spraying amount as a pesticide composition by increasing the content of the pesticide active ingredient in the pesticide composition, or to spray it by simply throwing it from the shore without entering the paddy field. Things are sought.
　このような要求に対して種々の省力化された農薬組成物が検討され、その技術が公開されているが、特に有効なものとして、例えば、特許文献１には、農薬活性成分を含有し、粒径３ｍｍ以上のものが８０％以上である粒度分布と水面に浮遊する性質を有し、かつ３０分以内に水面で崩壊することを特徴とする水面浮遊性大型粒状農薬組成物が開示されている。前記農薬組成物は高い自己拡散性を具備しており、水田１０ａ当たり２５０－５００ｇ程度と少量の農薬組成物を直接散布することで水田全体に農薬活性成分が均一に行き渡るため、畦畔からの投げ込み散布が可能であり、理想的な省力散布対応農薬組成物といえる。 Various labor-saving pesticide compositions have been studied for such demands, and the technology has been disclosed. However, for example, Patent Document 1 contains an agrochemical active ingredient, Disclosed is a water surface-floating large granular agrochemical composition characterized by having a particle size distribution of 80% or more of particles having a particle size of 3 mm or more and a property of floating on the water surface, and disintegrating on the water surface within 30 minutes. Yes. The agrochemical composition has a high self-diffusibility, and by spraying a small amount of the agrochemical composition of about 250-500 g per 10 a paddy field, the agrochemical active ingredient is uniformly distributed throughout the paddy field. It can be thrown in and can be said to be an ideal pesticide composition for labor saving application.
　前記特許文献１に記載の粒状農薬組成物は、水田に処理した際に水面を浮遊しながら崩壊することにより自己拡散する設計により成り立っており、かかる性能を発揮するための前提として、該組成物は水に浮くことが要求される。粒状農薬組成物に浮力を付与する方法として、同文献には、真珠岩や黒曜石よりなるパーライト、シラスよりなる発泡シラス、アルミノシリケート系で焼成してなるフィライト、珪酸ソーダあるいは硼砂を発泡させたマイクロバルーン、軽石、粒状珪藻土、粒状活性炭、木粉、コルク粉、ケナフ片、フェノール樹脂よりなるフェノールマイクロバルーン、エポキシ樹脂よりなるエコスフェアー、ポリウレタンよりなるポリウレタンフォーム、ポリアクリロニトリルよりなるマイクロスフェアー、火力発電時の灰として産出するフライアッシュ等、独立した１個又は複数個の気室を有する浮遊性担体を含有させる方法、ステアリン酸及びその塩、疎水性ホワイトカーボン等の撥水性物質を含有させる方法が開示されている。 The granular agrochemical composition described in Patent Document 1 is composed of a self-diffusion design by disintegrating while floating on the water surface when treated in a paddy field, and as a premise for exhibiting such performance, the composition Is required to float in the water. As a method for imparting buoyancy to a granular agrochemical composition, the literature includes perlite made of pearlite and obsidian, foamed shirasu made of shirasu, phyllite fired in an aluminosilicate system, sodium silicate or borax. Balloon, pumice, granular diatomaceous earth, granular activated carbon, wood powder, cork powder, kenaf pieces, phenol microballoon made of phenol resin, ecosphere made of epoxy resin, polyurethane foam made of polyurethane, microsphere made of polyacrylonitrile, thermal power generation A method of containing a floating carrier having one or a plurality of independent air chambers, such as fly ash produced as time ash, a method of containing a water-repellent substance such as stearic acid and salts thereof, and hydrophobic white carbon It is disclosed.
　また、熱可塑性重合体の壁膜を有する中空マイクロバルーン（以下、本明細書では「プラスチックマイクロバルーン」と称することがある）は、少量の配合で粒状農薬組成物に十分な浮力を付与することができる有力な浮遊性担体であり、しかも、押し出し造粒で粒状農薬組成物を製造する場合は、単位時間あたりの造粒物重量、すなわち造粒性を向上させる効果も奏することが特許文献２に記載されている。したがって、押し出し造粒法で特許文献１に記載の粒状農薬組成物を製造しようとする場合、プラスチックマイクロバルーンは積極的に採用したい浮遊性担体である。 Further, a hollow microballoon having a thermoplastic polymer wall membrane (hereinafter sometimes referred to as “plastic microballoon” in the present specification) imparts sufficient buoyancy to a granular agrochemical composition with a small amount of blending. Patent Document 2 shows that when a granular agrochemical composition is produced by extrusion granulation, the weight of the granulated product per unit time, that is, the granulation property is also improved. It is described in. Therefore, when it is going to manufacture the granular agrochemical composition of patent document 1 with an extrusion granulation method, a plastic microballoon is a floating carrier to want to employ | adopt actively.
　ところで、前記プラスチックマイクロバルーンは、通常０．０２－０．０４程度の真比重を有する極めて軽い粉体である。一方、クレー、炭酸カルシウム、珪藻土、ホワイトカーボンなどの、固体農薬組成物において一般的に使用される固体担体の真比重は２－３前後であり、農薬活性成分や界面活性剤の真比重も通常１を下回ることはない。押し出し造粒法で特許文献１に記載の粒状農薬組成物を製造するためには、造粒工程の前に、まず、農薬活性成分と界面活性剤とプラスチックマイクロバルーンと固体担体を含む原料を混合し、均質化した原料混合物を得る工程が必要となるが、前記真比重の違いにより、プラスチックマイクロバルーンはその他の原料との混合が進みにくいところがあった。 By the way, the plastic micro-balloon is usually a very light powder having a true specific gravity of about 0.02-0.04. On the other hand, the true specific gravity of solid carriers generally used in solid agrochemical compositions such as clay, calcium carbonate, diatomaceous earth, and white carbon is around 2-3, and the true specific gravity of agrochemical active ingredients and surfactants is usually also normal. No less than 1. In order to produce the granular agrochemical composition described in Patent Document 1 by the extrusion granulation method, first, the raw material containing the agrochemical active ingredient, the surfactant, the plastic microballoon, and the solid carrier is mixed before the granulation step. However, although a step of obtaining a homogenized raw material mixture is required, the plastic microballoons are difficult to proceed with other raw materials due to the difference in true specific gravity.
　原料の混合が不十分であると、原料混合物中のプラスチックマイクロバルーン含量に濃淡を生じ、プラスチックマイクロバルーンの少ない部分が造粒された粒状農薬組成物は浮力が不足し、水に投入すると沈降するため、所期の自己拡散性を発揮できない不良粒となる。この不良粒は、水に投入するまでは水に浮く正常粒と区別することが困難であるため、造粒工程後の品質検査で抜き取った標本からそのような不良粒が散見されるロットについては、正常粒も含めて全量廃棄する他なく、経済的な損失が甚大となる。したがって、プラスチックマイクロバルーンを含む均質な原料混合物を得るためには、十分な時間をかけて丁寧に混合を行う必要があった。 If the mixing of raw materials is insufficient, the content of plastic microballoons in the raw material mixture will become light and dark, and the granular agrochemical composition in which a small portion of plastic microballoons has been granulated will have insufficient buoyancy and will settle when poured into water. Therefore, it becomes a defective grain that cannot exhibit the desired self-diffusion. This defective grain is difficult to distinguish from normal grains floating in water until it is put into water, so for lots where such defective grains are found in samples extracted by quality inspection after the granulation process. In addition to discarding the entire amount including normal grains, the economic loss is enormous. Therefore, in order to obtain a homogeneous raw material mixture containing plastic microballoons, it has been necessary to carefully mix for a sufficient time.
特開２００２－１７９５０７号公報JP 2002-179507 A 特開平１０－２４５３０３号公報JP-A-10-245303
　本発明の主たる目的は、浮遊性担体としてプラスチックマイクロバルーンを採用する水面浮遊性大型粒状農薬組成物において、迅速にかつ安定的に品質良好な水面浮遊性大型粒状農薬組成物を製造する方法、並びに該方法により製造された品質良好な水面浮遊性大型粒状農薬組成物を提供することである。 The main object of the present invention is to provide a water surface-floating large-sized granular agricultural chemical composition that employs a plastic microballoon as a floating carrier, a method for producing a water surface-floating large-sized granular agricultural chemical composition that is quickly and stably good in quality, and An object of the present invention is to provide a water surface-floating large-sized granular agricultural chemical composition produced by the method.
　本発明者らは、鋭意研究した結果、表面が特定の粒径を有する鉱物質微粉で被覆されている既膨張プラスチックマイクロバルーンの採用が上記課題を解決し得ることを見出し、本発明を完成するに至った。 As a result of diligent research, the present inventors have found that the use of an already expanded plastic microballoon whose surface is coated with mineral fine powder having a specific particle size can solve the above-mentioned problems, and completes the present invention. It came to.
　すなわち本発明は、以下の内容のものである。 That is, the present invention has the following contents.
（１）農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有する粒状農薬組成物の製造方法であって、中空体として、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーン用い、該鉱物質微粉被覆既膨張プラスチックマイクロバルーンを、農薬活性成分、界面活性剤及び固体担体と混合し、次いで該混合物に所定量の水を加えて混練し、該混練物を孔径３ｍｍ以上のスクリーンから押し出し造粒した後、得られた造粒物を乾燥して水分を除去することを特徴とする粒状農薬組成物の製造方法。 (1) A pesticidal active ingredient, a surfactant, a hollow body, and a solid carrier, a particle size distribution with a particle size of 3 mm or more being 80% or more, floating on the water surface, and 30 minutes A method for producing a granular agrochemical composition having a property of collapsing on the water surface within the surface, the surface of an expanded plastic microballoon having an average particle diameter of 1 to 100 μm as a hollow body, using a thermoplastic polymer as a wall material, Mineral fine powder coated pre-expanded plastic microballoon coated with mineral fine powder having an average particle size of 0.1-15 μm and 1/2 or less of the pre-expanded plastic microballoon A balloon is mixed with an agrochemical active ingredient, a surfactant and a solid carrier, and then a predetermined amount of water is added to the mixture and kneaded, and the kneaded product is screened with a pore diameter of 3 mm or more. A method for producing a granular agrochemical composition, comprising extruding and granulating the product and then drying the resulting granulated product to remove moisture.
（２）熱可塑性高分子がモノマー単位としてアクリロニトリルを含有するポリアクリロニトリル又はポリアクリロニトリル系共重合体である、前記（１）に記載の粒状農薬組成物の製造方法。 (2) The method for producing a granular agrochemical composition according to (1), wherein the thermoplastic polymer is polyacrylonitrile or a polyacrylonitrile-based copolymer containing acrylonitrile as a monomer unit.
（３）既膨張プラスチックマイクロバルーンを被覆する鉱物質微粉が炭酸カルシウム、酸化チタン又はタルクである、前記（１）又は（２）に記載の粒状農薬組成物の製造方法。 (3) The manufacturing method of the granular agrochemical composition as described in said (1) or (2) whose mineral substance fine powder which coats an already expanded plastic microballoon is a calcium carbonate, a titanium oxide, or a talc.
（４）鉱物質微粉被覆既膨張プラスチックマイクロバルーンの全量基準で、鉱物質微粉被覆既膨張プラスチックマイクロバルーンの表面から鉱物質微粉を除いた既膨張プラスチックマイクロバルーンの重量が５－２０質量％である、前記（１）－（３）のいずれかに記載の粒状農薬組成物の製造方法。 (4) Based on the total amount of mineral fine powder coated expanded plastic microballoon, the weight of the expanded plastic microballoon obtained by removing mineral fine powder from the surface of the mineral powder coated expanded plastic microballoon is 5-20 mass%. The method for producing a granular agrochemical composition according to any one of (1) to (3).
（５）鉱物質微粉被覆既膨張プラスチックマイクロバルーンの水分含量が５質量％以下であることを更なる特徴とする、前記（１）－（４）のいずれかに記載の粒状農薬組成物の製造方法。 (5) The production of the granular agrochemical composition according to any one of (1) to (4), further characterized in that the water content of the expanded mineral micropowder-coated expanded plastic microballoon is 5% by mass or less. Method.
（６）前記（１）－（５）のいずれかに記載の製造方法により製造された、農薬活性成分と、界面活性剤と、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンと、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有する粒状農薬組成物。 (6) The agrochemical active ingredient, the surfactant, and the thermoplastic polymer produced by the production method according to any one of (1) to (5) above are used as wall materials, and the average particle size is 1 to 100 μm. A mineral fine powder-coated expanded plastic microballoon in which the surface of a certain expanded plastic microballoon is coated with a mineral fine powder having an average particle size of 0.1-15 μm and 1/2 or less of the expanded plastic microballoon; A granular agrochemical composition comprising a solid carrier and having a particle size distribution of 80% or more having a particle size of 3 mm or more, and a property of floating on the water surface and disintegrating on the water surface within 30 minutes.
（７）農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有し、中空体が、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンであることを特徴とする粒状農薬組成物。 (7) A pesticidal active ingredient, a surfactant, a hollow body, and a solid carrier, a particle size distribution in which particles having a particle size of 3 mm or more are 80% or more, floating on the water surface, and 30 minutes The surface of an already expanded plastic microballoon having an average particle size of 1 to 100 μm and an average particle size of 0.1 to 15 μm. A granular agrochemical composition characterized by being a mineral fine powder-covered expanded plastic microballoon coated with a mineral fine powder that is 1/2 or less of an already expanded plastic microballoon.
（８）農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有する粒状農薬組成物の製造において、中空体として、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンを用い、該鉱物質微粉被覆既膨張プラスチックマイクロバルーンを、農薬活性成分、界面活性剤及び固体担体と混合し、次いで該混合物に所定量の水を加えて混練し、該混練物を孔径３ｍｍ以上のスクリーンから押し出し造粒した後、得られた造粒物を乾燥して水分を除去することを特徴とする粒状農薬組成物の崩壊性向上方法。 (8) A pesticidal active ingredient, a surfactant, a hollow body, and a solid carrier, a particle size distribution having a particle size of 3 mm or more is 80% or more, floating on the water surface, and 30 minutes In the production of a granular agricultural chemical composition having a property of collapsing on the water surface within, the surface of an already expanded plastic microballoon having an average particle diameter of 1 to 100 μm as a hollow body and a thermoplastic polymer as a wall material has an average particle diameter Mineral fine powder coated pre-expanded plastic microballoon coated with mineral fine powder having a particle size of 0.1-15 μm and 1/2 or less of the pre-expanded plastic microballoon. , Mixed with an agrochemical active ingredient, a surfactant and a solid carrier, and then kneaded the mixture with a predetermined amount of water. A method for improving disintegration of a granular agrochemical composition, comprising extruding and granulating the resulting granulated product to remove moisture.
　本発明の製造方法によれば、ごく短時間の混合で農薬粒状組成物の原料混合物中に中空体を均一に分散するため、水面浮遊性に優れた農薬粒状組成物を効率的に得ることが可能となる。更に、本発明の方法により製造された農薬粒状組成物は、水面上における崩壊時間が短縮されるため、散布時に圃場周辺の風による吹き寄せ等の影響を受けにくく、圃場中での成分偏在による薬害発生の懸念がない、崩壊性に優れた農薬粒状組成物となる。 According to the production method of the present invention, since the hollow body is uniformly dispersed in the raw material mixture of the agricultural chemical granular composition by mixing in a very short time, an agricultural chemical granular composition having excellent water surface floatability can be obtained efficiently. It becomes possible. Furthermore, since the disintegration time on the water surface is shortened, the agrochemical granular composition produced by the method of the present invention is not easily affected by wind blowing around the field at the time of spraying, and phytotoxicity due to uneven distribution of components in the field. It becomes an agrochemical granular composition excellent in disintegration without fear of occurrence.
　本明細書中において、水面浮遊性大型粒状農薬組成物の粒径や粒度分布を取り扱う場合、「短径」は粒剤の形状において短い部分の長さのことを意味し、「粒径」は所定の目開きの篩を用いて篩分け法により求めた粒径を意味し、「粒度分布」は篩分け法により求めた所定の粒径範囲の積算重量百分率を意味するが、農薬活性成分をはじめとする個々の構成要素の粒子径や粒度分布を取り扱う場合、「平均粒子径」はそれぞれレーザー回折法により求めた体積平均径を意味し、「粒度分布」はレーザー回折法により求めた所定の粒径範囲の積算体積百分率を意味する（湿式法にて測定；ＳＫレーザーマイクロンサイザーＬＭＳ－２０００ｅ（セイシン企業製））。 In the present specification, when dealing with the particle size and particle size distribution of the water-floating large-sized granular agricultural chemical composition, “short diameter” means the length of a short part in the shape of the granule, and “particle diameter” It means the particle size obtained by a sieving method using a sieve with a predetermined opening, and `` particle size distribution '' means the cumulative weight percentage of the predetermined particle size range obtained by the sieving method. When dealing with the particle size and particle size distribution of individual components such as the first, “average particle size” means the volume average diameter determined by the laser diffraction method, and “particle size distribution” is a predetermined value determined by the laser diffraction method. It means the cumulative volume percentage of the particle size range (measured by wet method; SK Laser Micron Sizer LMS-2000e (manufactured by Seishin Enterprise)).
　本発明の粒状農薬組成物（以下、単に「組成物」ということがある）は、農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなる、押し出し造粒された粒状農薬組成物であって、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊する性質を有し、崩壊時間が３０分以内であることを特徴とする。このような粒状農薬組成物は、まず該粒状農薬組成物を構成する原料を混合し、所定量の水を加えて混練し、孔径３ｍｍ以上のスクリーンから押し出し造粒し、乾燥して、例えば、目開きの異なる２つの篩を用いて所望の粒度の粒状物を取り出すことで得られる。 The granular agrochemical composition of the present invention (hereinafter sometimes simply referred to as “composition”) is an extruded granulated product comprising an agrochemical active ingredient, a surfactant, a hollow body, and a solid carrier. A granular agrochemical composition having a particle size distribution of 3% or more having a particle size distribution of 80% or more, a property of floating on the water surface, and a disintegration time of 30 minutes or less. Such a granular agrochemical composition is first mixed with raw materials constituting the granular agrochemical composition, added with a predetermined amount of water, kneaded, extruded from a screen having a pore diameter of 3 mm or more, granulated, dried, for example, It can be obtained by taking out granules having a desired particle size using two sieves having different openings.
　本発明の粒状農薬組成物に使用できる農薬活性成分は特に限定されず、常温で固体であっても液体であってもよい。本発明に使用できる農薬活性成分を以下に列記するが、これらに限定されるものではない。 The agrochemical active ingredient that can be used in the granular agrochemical composition of the present invention is not particularly limited, and may be solid or liquid at room temperature. Although the agrochemical active ingredient which can be used for this invention is listed below, it is not limited to these.
　［除草活性成分］
　アイオキシニル（ｉｏｘｙｎｉｌ）、アクロニフェン（ａｃｌｏｎｉｆｅｎ）、アクロレイン（ａｃｒｏｌｅｉｎ）、アザフェニジン（ａｚａｆｅｎｉｄｉｎ）、アシフルオルフェン（ａｃｉｆｌｕｏｒｆｅｎ）（ナトリウムなどとの塩を含む）、アジムスルフロン（ａｚｉｍｓｕｌｆｕｒｏｎ）、アシュラム（ａｓｕｌａｍ）、アセトクロ－ル（ａｃｅｔｏｃｈｌｏｒ）、アトラジン（ａｔｒａｚｉｎｅ）、アニロホス（ａｎｉｌｏｆｏｓ）、アミカルバゾン（ａｍｉｃａｒｂａｚｏｎｅ）、アミドスルフロン（ａｍｉｄｏｓｕｌｆｕｒｏｎ）、アミトロール（ａｍｉｔｒｏｌｅ）、アミノシクロピラクロル（ａｍｉｎｏｃｙｃｌｏｐｙｒａｃｈｌｏｒ）、アミノピラリド（ａｍｉｎｏｐｙｒａｌｉｄ）、アミプロホス・メチル（ａｍｉｐｒｏｆｏｓ－ｍｅｔｈｙｌ）、アメトリン（ａｍｅｔｒｙｎ）、アラクロール（ａｌａｃｈｌｏｒ）、アロキシジム（ａｌｌｏｘｙｄｉｍ）、イソウロン（ｉｓｏｕｒｏｎ）、イソキサクロルトール（ｉｓｏｘａｃｈｌｏｒｔｏｌｅ）、イソキサフルトール（ｉｓｏｘａｆｌｕｔｏｌｅ）、イソキサベン（ｉｓｏｘａｂｅｎ）、イソプロツロン（ｉｓｏｐｒｏｔｕｒｏｎ）、イプフェンカルバゾン（ｉｐｆｅｎｃａｒｂａｚｏｎｅ）、イマザキン（ｉｍａｚａｑｕｉｎ）、イマザピク（ｉｍａｚａｐｉｃ）（アミンなどとの塩を含む）、イマザピル（ｉｍａｚａｐｙｒ）（イソプロピルアミンなどの塩を含む）、イマザメタベンズ・メチル（ｉｍａｚａｍｅｔｈａｂｅｎｚ－ｍｅｔｈｙｌ）、イマザモックス（ｉｍａｚａｍｏｘ）、イマゼタピル（ｉｍａｚｅｔｈａｐｙｒ）、イマゾスルフロン（ｉｍａｚｏｓｕｌｆｕｒｏｎ）、インダジフラム（ｉｎｄａｚｉｆｌａｍ）、インダノファン（ｉｎｄａｎｏｆａｎ）、エグリナジン・エチル（ｅｇｌｉｎａｚｉｎｅ－ｅｔｈｙｌ）、エスプロカルブ（ｅｓｐｒｏｃａｒｂ）、エタメトスルフロン・メチル（ｅｔｈａｍｅｔｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、エタルフルラリン（ｅｔｈａｌｆｌｕｒａｌｉｎ）、エチジムロン（ｅｔｈｉｄｉｍｕｒｏｎ）、エトキシスルフロン（ｅｔｈｏｘｙｓｕｌｆｕｒｏｎ）、エトキシフェン・エチル（ｅｔｈｏｘｙｆｅｎ－ｅｔｈｙｌ）、エトフメセート（ｅｔｈｏｆｕｍｅｓａｔｅ）、エトベンザニド（ｅｔｏｂｅｎｚａｎｉｄ）、エンドタール二ナトリウム塩（ｅｎｄｏｔｈａｌ－ｄｉｓｏｄｉｕｍ）、オキサジアゾン（ｏｘａｄｉａｚｏｎ）、オキサジアルギル（ｏｘａｄｉａｒｇｙｌ）、オキサジクロメホン（ｏｘａｚｉｃｌｏｍｅｆｏｎｅ）、オキシフルオルフェン（ｏｘｙｆｌｕｏｒｆｅｎ）、オリザリン（ｏｒｙｚａｌｉｎ）、オルトスルファムロン（ｏｒｔｈｏｓｕｌｆａｍｕｒｏｎ）、オルベンカルブ（ｏｒｂｅｎｃａｒｂ）、カフェンストロール（ｃａｆｅｎｓｔｒｏｌｅ）、カルフェントラゾン・エチル（ｃａｒｆｅｎｔｒａｚｏｎｅ－ｅｔｈｙｌ）、カルブチレート（ｋａｒｂｕｔｉｌａｔｅ）、カルベタミド（ｃａｒｂｅｔａｍｉｄｅ）、キザロホップ（ｑｕｉｚａｌｏｆｏｐ－ｅｔｈｙｌ）、キザロホップ・Ｐ・エチル（ｑｕｉｚａｌｏｆｏｐ－Ｐ－ｅｔｈｙｌ）、キザロホップ・Ｐ・テフリル（ｑｕｉｚａｌｏｆｏｐ－Ｐ－ｔｅｆｕｒｙｌ）、キノクラミン（ｑｕｉｎｏｃｌａｍｉｎｅ）、キンクロラック（ｑｕｉｎｃｌｏｒａｃ）、キンメラック（ｑｕｉｎｍｅｒａｃ）、クミルロン（ｃｕｍｙｌｕｒｏｎ）、クラシホス（ｃｌａｃｙｆｏｓ）、グリホサート（ｇｌｙｐｈｏｓａｔｅ）（ナトリウム、カリウム、アンモニウム、アミン、プロピルアミン、イソプロピルアミン、ジメチルアミン又はトリメシウムなどの塩を含む）、グルホシネート（ｇｌｕｆｏｓｉｎａｔｅ）（アミン又はナトリウムなどの塩を含む）、グルホシネート・Ｐ・ナトリウム塩（ｇｌｕｆｏｓｉｎａｔｅ－Ｐ－ｓｏｄｉｕｍ）、クレトジム（ｃｌｅｔｈｏｄｉｍ）、クロジナホップ・プロパルギル（ｃｌｏｄｉｎａｆｏｐ－ｐｒｏｐａｒｇｙｌ）、クロピラリド（ｃｌｏｐｙｒａｌｉｄ）、クロマゾン（ｃｌｏｍａｚｏｎｅ）、クロメトキシフェン（ｃｈｌｏｍｅｔｈｏｘｙｆｅｎ）、クロメプロップ（ｃｌｏｍｅｐｒｏｐ）、クロランスラム・メチル（ｃｌｏｒａｎｓｕｌａｍ－ｍｅｔｈｙｉ）、クロランベン（ｃｈｌｏｒａｍｂｅｎ）、クロリダゾン（ｃｈｌｏｒｉｄａｚｏｎ）、クロリムロン・エチル（ｃｈｌｏｒｉｍｕｒｏｎ－ｅｔｈｙｌ）、クロルスルフロン（ｃｈｌｏｒｓｕｌｆｕｒｏｎ）、クロルタル・ジメチル（ｃｈｌｏｒｔｈａｌ－ｄｉｍｅｔｈｙｌ）、クロルチアミド（ｃｈｌｏｒｔｈｉａｍｉｄ）、クロルフタリム（ｃｈｌｏｒｐｈｔｈａｌｉｍ）、クロルフルレノール・メチル（ｃｈｌｏｒｆｌｕｒｅｎｏｌ－ｍｅｔｈｙｌ）、クロルプロファム（ｃｈｌｏｒｐｒｏｐｈａｍ）、クロルブロムロン（ｃｈｌｏｒｂｒｏｍｕｒｏｎ）、クロロクスロン（ｃｈｌｏｒｏｘｕｒｏｎ）、クロロトルロン（ｃｈｌｏｒｏｔｏｌｕｒｏｎ）、サフルフェナシル（ｓａｆｌｕｆｅｎａｃｉｌ）、シアナジン（ｃｙａｎａｚｉｎｅ）、シアナミド（ｃｙａｎａｍｉｄｅ）、ジウロン（ｄｉｕｒｏｎ）、ジエタチル・エチル（ｄｉｅｔｈａｔｙｌ－ｅｔｈｙｌ）、ジカンバ（ｄｉｃａｍｂａ）（アミン、ジエチルアミン、イソプロピルアミン、ジグリコールアミン、ナトリウム又はリチウムなどの塩を含む）、シクロエート（ｃｙｃｌｏａｔｅ）、シクロキシジム（ｃｙｃｌｏｘｙｄｉｍ）、ジクロスラム（ｄｉｃｌｏｓｕｌａｍ）、シクロスルファムロン（ｃｙｃｌｏｓｕｌｆａｍｕｒｏｎ）、シクロピリモレート（ｃｙｃｌｏｐｙｒｉｍｏｒａｔｅ）、ジクロベニル（ｄｉｃｈｌｏｂｅｎｉｌ）、ジクロホップ・Ｐ・メチル（ｄｉｃｌｏｆｏｐ－Ｐ－ｍｅｔｈｙｌ）、ジクロホップ・メチル（ｄｉｃｌｏｆｏｐ－ｍｅｔｈｙｌ）、ジクロルプロップ（ｄｉｃｈｌｏｒｐｒｏｐ）、ジクロルプロップ－Ｐ（ｄｉｃｈｌｏｒｐｒｏｐ－Ｐ）、ジクワット（ｄｉｑｕａｔ）、ジチオピル（ｄｉｔｈｉｏｐｙｒ）、シデュロン（ｓｉｄｕｒｏｎ）、ジニトラミン（ｄｉｎｉｔｒａｍｉｎｅ）、シニドン・エチル（ｃｉｎｉｄｏｎ－ｅｔｈｙｌ）、シノスルフロン（ｃｉｎｏｓｕｌｆｕｒｏｎ）、ジノテルブ（ｄｉｎｏｔｅｒｂ）、シハロホップ・ブチル（ｃｙｈａｌｏｆｏｐ－ｂｕｔｙｌ）、ジフェナミド（ｄｉｐｈｅｎａｍｉｄ）、ジフェンゾコート（ｄｉｆｅｎｚｏｑｕａｔ）、ジフルフェニカン（ｄｉｆｌｕｆｅｎｉｃａｎ）、ジフルフェンゾピル（ｄｉｆｌｕｆｅｎｚｏｐｙｒ）、シマジン（ｓｉｍａｚｉｎｅ）、ジメタクロール（ｄｉｍｅｔｈａｃｈｌｏｒ）、ジメタメトリン（ｄｉｍｅｔｈａｍｅｔｒｙｎ）、ジメテナミド（ｄｉｍｅｔｈｅｎａｍｉｄ）、ジメテナミド・Ｐ（ｄｉｍｅｔｈｅｎａｍｉｄ－Ｐ）、シメトリン（ｓｉｍｅｔｒｙｎ）、ジメピペレート（ｄｉｍｅｐｉｐｅｒａｔｅ）、ジメフロン（ｄｉｍｅｆｕｒｏｎ）、シンメチリン（ｃｉｎｍｅｔｈｙｌｉｎ）、スエップ（ｓｗｅｐ）、スルコトリオン（ｓｕｌｃｏｔｒｉｏｎｅ）、スルフェントラゾン（ｓｕｌｆｅｎｔｒａｚｏｎｅ）、セトキシジム（ｓｅｔｈｏｘｙｄｉｍ）、ターバシル（ｔｅｒｂａｃｉｌ）、ダイムロン（ｄａｉｍｕｒｏｎ）、ダラポン（ｄａｌａｐｏｎ）、チアゾピル（ｔｈｉａｚｏｐｙｒ）、チアフェナシル（ｔｉａｆｅｎａｃｉｌ）、チエンカルバゾン（ｔｈｉｅｎｃａｒｂａｚｏｎｅ）（ナトリウム塩、メチルエステルなどを含む）、チオカルバジル（ｔｉｏｃａｒｂａｚｉｌ）、チオベンカルブ（ｔｈｉｏｂｅｎｃａｒｂ）、チジアジミン（ｔｈｉｄｉａｚｉｍｉｎ）、チフェンスルフロン・メチル（ｔｈｉｆｅｎｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、デスメディファム（ｄｅｓｍｅｄｉｐｈａｍ）、デスメトリン（ｄｅｓｍｅｔｒｙｎｅ）、テニルクロール（ｔｈｅｎｙｌｃｈｌｏｒ）、テブタム（ｔｅｂｕｔａｍ）、テブチウロン（ｔｅｂｕｔｈｉｕｒｏｎ）、テプラロキシジム（ｔｅｐｒａｌｏｘｙｄｉｍ）、テフリルトリオン（ｔｅｆｕｒｙｌｔｒｉｏｎｅ）、テムボトリオン（ｔｅｍｂｏｔｒｉｏｎｅ）、テルブチラジン（ｔｅｒｂｕｔｈｙｌａｚｉｎｅ）、テルブトリン（ｔｅｒｂｕｔｒｙｎ）、テルブメトン（ｔｅｒｂｕｍｅｔｏｎ）、トプラメゾン（ｔｏｐｒａｍｅｚｏｎｅ）、トラルコキシジム（ｔｒａｌｋｏｘｙｄｉｍ）、トリアジフラム（ｔｒｉａｚｉｆｌａｍ）、トリアスルフロン（ｔｒｉａｓｕｌｆｕｒｏｎ）、トリアファモン（ｔｒｉａｆａｍｏｎｅ）、トリアレート（ｔｒｉ－ａｌｌａｔｅ）、トリエタジン（ｔｒｉｅｔａｚｉｎｅ）、トリクロピル（ｔｒｉｃｌｏｐｙｒ）、トリクロピル－ブトティル（ｔｒｉｃｌｏｐｙｒ－ｂｕｔｏｔｙｌ）、トリフルジムオキサジン（ｔｒｉｆｌｕｄｉｍｏｘａｚｉｎ）、トリトスルフロン（ｔｒｉｔｏｓｕｌｆｕｒｏｎ）、トリフルスルフロン・メチル（ｔｒｉｆｌｕｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、トリフルラリン（ｔｒｉｆｌｕｒａｌｉｎ）、トリフロキシスルフロンナトリウム塩（ｔｒｉｆｌｏｘｙｓｕｌｆｕｒｏｎ－ｓｏｄｉｕｍ）、トリベニュロン・メチル（ｔｒｉｂｅｎｕｒｏｎ－ｍｅｔｈｙｌ）、トルピラレート（ｔｏｌｐｙｒａｌａｔｅ）、ナプタラム（ｎａｐｔａｌａｍ）（ナトリウムなどとの塩を含む）、ナプロアニリド（ｎａｐｒｏａｎｉｌｉｄｅ）、ナプロパミド（ｎａｐｒｏｐａｍｉｄｅ）、ナプロパミド－Ｍ（ｎａｐｒｏｐａｍｉｄｅ－Ｍ）、ネブロン（ｎｅｂｕｒｏｎ）、ノルフルラゾン（ｎｏｒｆｌｕｒａｚｏｎ）、バーナレート（ｖｅｒｎｏｌａｔｅ）、パラコート（ｐａｒａｑｕａｔ）、ハルキシフェン－メチル（ｈａｌａｕｘｉｆｅｎ－ｍｅｔｈｙｌ）、ハロキシホップ（ｈａｌｏｘｙｆｏｐ）、ハロキシホップ・Ｐ（ｈａｌｏｘｙｆｏｐ－Ｐ）、ハロキシホップ－エトティル（ｈａｌｏｘｙｆｏｐ－ｅｔｏｔｙｌ）、ハロスルフロン・メチル（ｈａｌｏｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、ピクロラム（ｐｉｃｌｏｒａｍ）、ピコリナフェン（ｐｉｃｏｌｉｎａｆｅｎ）、ビシクロピロン（ｂｉｃｙｃｌｏｐｙｒｏｎｅ）、ビスピリバック・ナトリウム塩（ｂｉｓｐｙｒｉｂａｃ－ｓｏｄｉｕｍ）、ピノキサデン（ｐｉｎｏｘａｄｅｎ）、ビフェノックス（ｂｉｆｅｎｏｘ）、ピペロホス（ｐｉｐｅｒｏｐｈｏｓ）、ピラクロニル（ｐｙｒａｃｌｏｎｉｌ）、ピラスルホトール（ｐｙｒａｓｕｌｆｏｔｏｌｅ）、ピラゾキシフェン（ｐｙｒａｚｏｘｙｆｅｎ）、ピラゾスルフロン・エチル（ｐｙｒａｚｏｓｕｌｆｕｒｏｎ－ｅｔｈｙｌ）、ピラゾリネート（ｐｙｒａｚｏｌｙｎａｔｅ）、ビラナホス（ｂｉｌａｎａｆｏｓ）、ピラフルフェン・エチル（ｐｙｒａｆｌｕｆｅｎ－ｅｔｈｙｌ）、ピリダフォル（ｐｙｒｉｄａｆｏｌ）、ピリチオバック・ナトリウム塩（ｐｙｒｉｔｈｉｏｂａｃ－ｓｏｄｉｕｍ）、ピリデート（ｐｙｒｉｄａｔｅ）、ピリフタリド（ｐｙｒｉｆｔａｌｉｄ）、ピリブチカルブ（ｐｙｒｉｂｕｔｉｃａｒｂ）、ピリベンゾキシム（ｐｙｒｉｂｅｎｚｏｘｉｍ）、ピリミスルファン（ｐｙｒｉｍｉｓｕｌｆａｎ）、ピリミノバック・メチル（ｐｙｒｉｍｉｎｏｂａｃ－ｍｅｔｈｙｌ）、ピロキサスルホン（ｐｙｒｏｘａｓｕｌｆｏｎｅ）、ピロクススラム（ｐｙｒｏｘｓｕｌａｍ）、フェニソファム（ｐｈｅｎｉｓｏｐｈａｍ）、フェニュロン（ｆｅｎｕｒｏｎ）、フェノキサスルホン（ｆｅｎｏｘａｓｕｌｆｏｎｅ）、フェノキサプロップ・Ｐ・エチル（ｆｅｎｏｘａｐｒｏｐ－Ｐ－ｅｔｈｙｌ）、フェンキノトリオン（ｆｅｎｑｕｉｎｏｔｒｉｏｎｅ）、フェンチアプロップ・エチル（ｆｅｎｔｈｉａｐｒｏｐ－ｅｔｈｙｌ）、フェントラザミド（ｆｅｎｔｒａｚａｍｉｄｅ）、フェンメディファム（ｐｈｅｎｍｅｄｉｐｈａｍ）、フォラムスルフロン（ｆｏｒａｍｓｕｌｆｕｒｏｎ）、ブタクロール（ｂｕｔａｃｈｌｏｒ）、ブタフェナシル（ｂｕｔａｆｅｎａｃｉｌ）、ブタミホス（ｂｕｔａｍｉｆｏｓ）、ブチレート（ｂｕｔｙｌａｔｅ）、ブテナクロール（ｂｕｔｅｎａｃｈｌｏｒ）、ブトラリン（ｂｕｔｒａｌｉｎ）、ブトロキシジム（ｂｕｔｒｏｘｙｄｉｍ）、フラザスルフロン（ｆｌａｚａｓｕｌｆｕｒｏｎ）、フラムプロップ（ｆｌａｍｐｒｏｐ）（メチル、エチル、イソプロピルエステルを含む）
、フラムプロップ・Ｍ（ｆｌａｍｐｒｏｐ－Ｍ）（メチル、エチル、イソプロピルエステルを含む）、フルアジホップ・ブチル（ｆｌｕａｚｉｆｏｐ－ｂｕｔｙｌ）、フルアジホップ・Ｐ・ブチル（ｆｌｕａｚｉｆｏｐ－Ｐ－ｂｕｔｙｌ）、フルアゾレート（ｆｌｕａｚｏｌａｔｅ）、フルオメツロン（ｆｌｕｏｍｅｔｕｒｏｎ）、フルオログリコフェン（ｆｌｕｏｒｏｇｌｙｃｏｆｅｎ－ｅｔｈｙｌ）、フルカルバゾン・ナトリウム塩（ｆｌｕｃａｒｂａｚｏｎｅ－ｓｏｄｉｕｍ）、フルクロラリン（ｆｌｕｃｈｌｏｒａｌｉｎ）、フルセトスルフロン（ｆｌｕｃｅｔｏｓｕｌｆｕｒｏｎ）、フルチアセット・メチル（ｆｌｕｔｈｉａｃｅｔ－ｍｅｔｈｙｌ）、フルピルスルフロン・メチル・ナトリウム塩（ｆｌｕｐｙｒｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ－ｓｏｄｉｕｍ）、フルフェナセット（ｆｌｕｆｅｎａｃｅｔ）、フルフェンピル・エチル（ｆｌｕｆｅｎｐｙｒ－ｅｔｈｙｌ）、フルプロパネート（ｆｌｕｐｒｏｐａｎａｔｅ）、フルポキサム（ｆｌｕｐｏｘａｍｅ）、フルミオキサジン（ｆｌｕｍｉｏｘａｚｉｎ）、フルミクロラック・ペンチル（ｆｌｕｍｉｃｌｏｒａｃ－ｐｅｎｔｙｌ）、フルメツラム（ｆｌｕｍｅｔｓｕｌａｍ）、フルリドン（ｆｌｕｒｉｄｏｎｅ）、フルルタモン（ｆｌｕｒｔａｍｏｎｅ）、フルロキシピル（ｆｌｕｒｏｘｙｐｙｒ）、フルロクロリドン（ｆｌｕｒｏｃｈｌｏｒｉｄｏｎｅ）、プレチラクロール（ｐｒｅｔｉｌａｃｈｌｏｒ）、プロカルバゾン・ナトリウム塩（ｐｒｏｃａｒｂａｚｏｎｅ－ｓｏｄｉｕｍ）、プロジアミン（ｐｒｏｄｉａｍｉｎｅ）、プロスルホカルブ（ｐｒｏｓｕｌｆｏｃａｒｂ）、プロパキザホップ（ｐｒｏｐａｑｕｉｚａｆｏｐ）、プロパクロール（ｐｒｏｐａｃｈｌｏｒ）、プロパジン（ｐｒｏｐａｚｉｎｅ）、プロパニル（ｐｒｏｐａｎｉｌ）、プロピザミド（ｐｒｏｐｙｚａｍｉｄｅ）、プロピソクロール（ｐｒｏｐｉｓｏｃｈｌｏｒ）、プロピリスルフロン（ｐｒｏｐｙｒｉｓｕｌｆｕｒｏｎ）、プロファム（ｐｒｏｐｈａｍ）、プロフルアゾール（ｐｒｏｆｌｕａｚｏｌ）、プロポキシカルバゾン・ナトリウム塩（ｐｒｏｐｏｘｙｃａｒｂａｚｏｎｅ－ｓｏｄｉｕｍ）、プロホキシジム（ｐｒｏｆｏｘｙｄｉｍ）、ブロマシル（ｂｒｏｍａｃｉｌ）、ブロムピラゾン（ｂｒｏｍｐｙｒａｚｏｎ）、プロメトリン（ｐｒｏｍｅｔｒｙｎ）、プロメトン（ｐｒｏｍｅｔｏｎ）、ブロモキシニル（ｂｒｏｍｏｘｙｎｉｌ）（酪酸、オクタン酸又はヘプタン酸などのエステル体を含む）、ブロモフェノキシム（ｂｒｏｍｏｆｅｎｏｘｉｍ）、ブロモブチド（ｂｒｏｍｏｂｕｔｉｄｅ）、フロラスラム（ｆｌｏｒａｓｕｌａｍ）、ペトキサミド（ｐｅｔｈｏｘａｍｉｄ）、ベナゾリン（ｂｅｎａｚｏｌｉｎ）、ペノキススラム（ｐｅｎｏｘｓｕｌａｍ）、ヘプタマロキシログルカン（ｈｅｐｔａｍａｌｏｘｙｌｏｇｌｕｃａｎ）、ベフルブタミド（ｂｅｆｌｕｂｕｔａｍｉｄ）、ペブレート（ｐｅｂｕｌａｔｅ）、ベンカルバゾン（ｂｅｎｃａｒｂａｚｏｎｅ）、ペンジメタリン（ｐｅｎｄｉｍｅｔｈａｌｉｎ）、ベンズフェンジゾン（ｂｅｎｚｆｅｎｄｉｚｏｎｅ）、ベンスリド（ｂｅｎｓｕｌｉｄｅ）、ベンスルフロン・メチル（ｂｅｎｓｕｌｆｕｒｏｎ－　ｍｅｔｈｙｌ）、ベンゾビシクロン（ｂｅｎｚｏｂｉｃｙｃｌｏｎ）、ベンゾフェナップ（ｂｅｎｚｏｆｅｎａｐ）、ベンタゾン（ｂｅｎｔａｚｏｎｅ）、ペンタノクロール（ｐｅｎｔａｎｏｃｈｌｏｒ）、ペントキサゾン（ｐｅｎｔｏｘａｚｏｎｅ）、ベンフルラリン（ｂｅｎｆｌｕｒａｌｉｎ）、ベンフレセート（ｂｅｎｆｕｒｅｓａｔｅ）、ホサミン（ｆｏｓａｍｉｎｅ）、ホメサフェン（ｆｏｍｅｓａｆｅｎ）、メコプロップ（ｍｅｃｏｐｒｏｐ）（ナトリウム、カリウム、イソプロピルアミン、トリエタノールアミン、ジメチルアミンなどの塩を含む）、メコプロップ・Ｐ・カリウム塩（ｍｅｃｏｐｒｏｐ－Ｐ－ｐｏｔａｓｓｉｕｍ）、メソスフロン・メチル（ｍｅｓｏｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、メソトリオン（ｍｅｓｏｔｒｉｏｎｅ）、メタザクロール（ｍｅｔａｚａｃｈｌｏｒ）、メタゾスルフロン（ｍｅｔａｚｏｓｕｌｆｕｒｏｎ）、メタベンズチアズロン（ｍｅｔｈａｂｅｎｚｔｈｉａｚｕｒｏｎ）、メタミトロン（ｍｅｔａｍｉｔｒｏｎ）、メタミホップ（ｍｅｔａｍｉｆｏｐ）、メチオゾリン（ｍｅｔｈｉｏｚｏｌｉｎ）、メチルダイムロン（ｍｅｔｈｙｌｄｙｍｕｒｏｎ）、メトキスロン（ｍｅｔｏｘｕｒｏｎ）、メトスラム（ｍｅｔｏｓｕｌａｍ）、メトブロムロン（ｍｅｔｏｂｒｏｍｕｒｏｎ）、メトベンズロン（ｍｅｔｏｂｅｎｚｕｒｏｎ）、メトラクロール（ｍｅｔｏｌａｃｈｌｏｒ）、メトリブジン（ｍｅｔｒｉｂｕｚｉｎ）、メフェナセット（ｍｅｆｅｎａｃｅｔ）、モノリニュロン（ｍｏｎｏｌｉｎｕｒｏｎ）、モリネート（ｍｏｌｉｎａｔｅ）、ヨードスルフロン（ｉｏｄｏｓｕｌｆｕｒｏｎ）、ヨードスルフロンメチルナトリウム塩（ｉｏｄｏｓｕｌｆｕｌｏｎ－ｍｅｔｈｙｌ－ｓｏｄｉｕｍ）、ヨーフェンスルフロン（ｉｏｆｅｎｓｕｌｆｕｒｏｎ）、ヨーフェンスルフロン・ナトリウム塩（ｉｏｆｅｎｓｕｌｆｕｒｏｎ－ｓｏｄｉｕｍ）、ラクトフェン（ｌａｃｔｏｆｅｎ）、リニュロン（ｌｉｎｕｒｏｎ）、レナシル（ｌｅｎａｃｉｌ）、２，３，６－ＴＢＡ（２，３，６－トリクロロ安息香酸）、２，４，５－Ｔ（２，４，５－トリクロロフェノキシ酢酸）、２，４－Ｄ（２，４－ジクロロフェノキシ酢酸）（アミン、ジエチルアミン、トリエタノールアミン、イソプロピルアミン、ナトリウムまたはリチウム等の塩を含む）、２，４－ＤＢ（４－（２，４－ジクロロフェノキシ）酪酸）、ＡＥ－Ｆ‐１５０９４４（コード番号）、ＤＮＯＣ（４，６－ジニトロ－ｏ－クレゾール）（アミンまたはナトリウムなどの塩を含む）、ＥＰＴＣ（Ｓ－エチルジプロピルチオカーバメート）、ＭＣＰＡ（２－メチル－４－クロロフェノキシ酢酸）、ＭＣＰＡ・チオエチル（ＭＣＰＡ－ｔｈｉｏｅｔｈｙｌ）、ＭＣＰＢ（２－メチル－４－クロロフェノキシ酪酸）（ナトリウム塩、エチルエステル等を含む）、ＳＹＰ－２９８（コード番号）、ＳＹＰ－３００（コード番号）、Ｓ－メトラクロール（Ｓ－ｍｅｔｏｌａｃｈｌｏｒ）、ＴＣＡ（２，２，２－トリクロロ酢酸）（ナトリウム、カルシウムまたはアンモニアなどの塩を含む）。 [Herbicidal active ingredient]
Ioxynil, aclonifen, acrolein, azafenidin, acifluorfen (including salts with sodium, etc.), azimsulfuron, acelam, acelam- (Acetochlor), atrazine, anilofos, amicarbazone, amidosulfuron, amitrole, aminocyclopyrachlor (methyl), aminopyrachlor ofos-methyl, amethrin, alachlor, alloxydim, isouron, isoxachlortole, isoxaflutole, isopablon ), Ipfencarbazone, imazaquin, imazapic (including salts with amines, etc.), imazapyr (including salts such as isopropylamine), imazametabenz methyz-methyl (imabine) ), Imazamox, imazeta Imazethapyr, imazosulfuron, indaziflam, indanophan, erinazine-ur, etrincarb, esprocarb. ), Etidimuron, ethoxysulfuron, ethoxyphen-ethyl, etofumesate, etobenzanid, endothal disodium salt (endothal-is) dium), oxadiazon, oxadiaargyl, oxadichromefone, oxyfluorfen, oryzalin, entrabole, fensulfone, ensulfaurone Carbethylate-carbylate, carbbutilate, carbetamide, quizalofop-ethyl, quizalofop-p-ethylp alfop-P-tefuryl, quinoclamamine, quinclorac, quinmerac, cumyluron, clacyfos, glyphosate (sodium, amine, potassium, amine) Including salts such as isopropylamine, dimethylamine or trimesium), glufosinate (including salts such as amine or sodium), glufosinate-P-sodium, cletodim, clodinahop Propargyl (clodinafop-propargyl), clopyralid Clopyralid, Chromazone, Chloromphen, Chloridaur, Chloridazon, Chloridazon, Chloridazon, Chloridazon, Chloridazon, Chloridazon, Chloridazon Chlorsulfuron, chlorthal-dimethyl, chlorthiamid, chlorphthalim, chlorflulenol-methyl, chlorprophum , Chlorobromuron, chloroxuron, chlorotoluron, saflufenacil, cyanazine, cyanamide, dithrone, dithyl, dithrone, dithulone ) (Including salts such as amine, diethylamine, isopropylamine, diglycolamine, sodium or lithium), cycloate, cycloxydim, diclosulam, cyclosulfamuron, cyclopyrimoleate (Cyclopy imorate, diclobenil, diclohop-P-methyl, diclohop-methyl, dichlorprop, dichlorprop-P, dichlorprop-P diquat, dithiopyr, siduron, dinitramine, cinidon-ethyl, cinosulfuron, dinoterb, cyhalohop butyl (midhlo butyl) , Difenzoquat , Diflufenican, diflufenzopyr, simazine, dimethachlor, dimetamethrin, dimethenamide, dimethenamide (dimethenamide), dimethenamide (dimethenamide) dimipeperate, dimethylfuron, cinmethylin, swep, sulcotrione, sulfentrazone, cetoxydim, terbacil (terbacil) ron), dalapon, thiazopyr, thiafenacil, thiencarbazone (including sodium salt, methyl ester, etc.), thiocarbazil, thiobencarbizine, thiobencarbizine Ruflon-methyl, desmedifam, desmetrine, tenylchlor, tebutam, tebuthiuron, tepralophyl u yttrione, tembotrione, terbuthylazine, terbutriain, terbumeton, terbumeton, terbutiton, terbutiton, terbutiton, terbutiton Tri-allate, trietazine, triclopyr, triclopyr-butotyl, trifludimoxazine, tritosulfuron (trisulflon) ron), triflusulfuron-methyl, trifluralin, trifloxysulfuron-sodium, tribenuron-methylol, tylpyralate. (Including salts with sodium, etc.), naproanilide, napropamide, napropamide-M, neburon, norflurazon, vernarate, u Halxifen-Me Chill (haluxifen-methyl), haloxyhop (haloxyhop), haloxyhop-ethyl, halosulfuron-methyl, halosulfone-methyl, halosulfo-methyl Bicyclopyrone, Bispyribac-sodium, Pinoxaden, Bifenox, Piperophos, Pyraclonil, Pirasulfitol, Pirasulfitol xyfen), pyrazosulfuron-ethyl, pyrazolynate, bianafos, pyraflufen-ethyl, pyridafol-pyrium salt , Pyriftalid, pyributicalcarb, pyribenzoxim, pyrimisulfan, pyriminobac-methyl, pyroxasulfone, pyramsulphone roxsuram, phenisopham, fenuron, fenoxasulfone, fenoxaprop-P-ethyl, fenquinotrione, fentiapro-ethyl ethyl), fentrazamide, fenmedifam, foramsulfuron, butachlor, butafenacil, butamifos, butyrate, butyrate, butyrate Tralarin, butroxydim, flazasulfuron, flampprop (including methyl, ethyl, isopropyl ester)
, Flampprop-M (including methyl, ethyl, isopropyl ester), fluazifop-butyl, fluazifop-P-butyl, fluazolate, fluometuron ( fluomethuron, fluoroglycofen-ethyl, flucarbazone sodium salt, fluchloralin, flucetosulfuron, fluthiacet-methyl, fluthiaset-methyl Sodium salt (flupyrsulfuron) methyl-sodium, flufenacet, flufenpyr-ethyl, flupropanate, flupoxame, flumioxazin, flumicro pentyl, flumicroc pentyl Flumetsuram, fluridone, flurtamone, fluroxypyr, flurochloridone, pretilaclor di-pro-clavone sodium salt diamine, prosulfocarb, propaquizahop, propachlor, propazin, propanil, propiamide, propiamide, propiamide, propiamide, propiamide ), Propham, profluazole, propoxycarbazone sodium salt (propoxycarbazone-sodium), propoxydim, bromacil, brompyrazon, brompyrazin Prometon, bromoxynil (including esters such as butyric acid, octanoic acid or heptanoic acid), bromophenoxime, bromobutide, floraslamm, petoxamide (pexamide) ), Penoxslam, heptamamaloxyloglucan, beflubutamide, pebrate, bencarbene, pendimethalin (pendimethenzine). sulide), bensulfuron-methyl, benzobicyclon, benzofenap, bentazone, pentanochlor, pentobenzole, pentobenzone (Benfurateate), fosamine, fomesafen, mecoprop (including salts such as sodium, potassium, isopropylamine, triethanolamine, dimethylamine), mecoprop-P-potassium salt (mecoprop-P- Potassium), Meso Suflon Mechi (Mesosulfuron-methyl), mesotrione (methazolurone), metazosulfuron (metazothururon), metamethothion (methithiouron), metamitron (meta), metamitron (metamethyl) ), Metoxuron, Metoslam, Metobromuron, Metobenzuron, Metolachlor, Metribuzin, Mefenaset (mefenaset) et), monolinuron, molinate, iodosulfuron, iodosulfuron methyl sodium salt (iodosulfuron-methyl-sodium), iofensulfuron, iofensulfuron ulfuron sodium), lactofen, linuron, lenacyl, 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,4,5-T (2,4,5) -Trichlorophenoxyacetic acid), 2,4-D (2,4-dichlorophenoxyacetic acid) (amine, diethylamine, triethanolamine, isopropylamine, Including salts such as sodium or lithium), 2,4-DB (4- (2,4-dichlorophenoxy) butyric acid), AE-F-150944 (code number), DNOC (4,6-dinitro-o-cresol) ) (Including salts such as amine or sodium), EPTC (S-ethyldipropylthiocarbamate), MCPA (2-methyl-4-chlorophenoxyacetic acid), MCPA-thioethyl (MCPA-thioethyl), MCPB (2-methyl) -4-chlorophenoxybutyric acid) (including sodium salts, ethyl esters, etc.), SYP-298 (code number), SYP-300 (code number), S-metolachlor, TCA (2,2, 2-trichloroacetic acid) (including salts such as sodium, calcium or ammonia)
　［殺虫活性成分］
　アクリナトリン（ａｃｒｉｎａｔｈｒｉｎ）、アザジラクチン（ａｚａｄｉｒａｃｈｔｉｎ）、アザメチホス（ａｚａｍｅｔｈｉｐｈｏｓ）、アジンホス・エチル（ａｚｉｎｐｈｏｓ－ｅｔｈｙｌ）、アジンホス・メチル（ａｚｉｎｐｈｏｓ－ｍｅｔｈｙｌ）、アセキノシル（ａｃｅｑｕｉｎｏｃｙｌ）、アセタミプリド（ａｃｅｔａｍｉｐｒｉｄ）、アセトプロール（ａｃｅｔｏｐｒｏｌｅ）、アセフェート（ａｃｅｐｈａｔｅ）、アゾシクロチン（ａｚｏｃｙｃｌｏｔｉｎ）、アバメクチン（ａｂａｍｅｃｔｉｎ）、アフィドピロペン（ａｆｉｄｏｐｙｒｏｐｅｎ）、アミドフルメット（ａｍｉｄｏｆｌｕｍｅｔ）、アミトラズ（ａｍｉｔｒａｚ）、アラニカルブ（ａｌａｎｙｃａｒｂ）、アルジカルブ（ａｌｄｉｃａｒｂ）、アルドキシカルブ（ａｌｄｏｘｙｃａｒｂ）、アレスリン（ａｌｌｅｔｈｒｉｎ）［ｄ－ｃｉｓ－ｔｒａｎｓ－体、ｄ－ｔｒａｎｓ－体を含む］、イサゾホス（ｉｓａｚｏｐｈｏｓ）、イサミドホス（ｉｓａｍｉｄｏｆｏｓ）、イソカルボホス（ｉｓｏｃａｒｂｏｐｈｏｓ）、イソキサチオン（ｉｓｏｘａｔｈｉｏｎ）、イソフェンホス・メチル（ｉｓｏｆｅｎｐｈｏｓ－ｍｅｔｈｙｌ）、イソプロカルブ（ｉｓｏｐｒｏｃａｒｂ）、イベルメクチン（ｉｖｅｒｍｅｃｔｉｎ）、イミシアホス（ｉｍｉｃｙａｆｏｓ）、イミダクロプリド（ｉｍｉｄａｃｌｏｐｒｉｄ）、イミプロトリン（ｉｍｉｐｒｏｔｈｒｉｎ）、インドキサカルブ（ｉｎｄｏｘａｃａｒｂ）、エスフェンバレレート（ｅｓｆｅｎｖａｌｅｒａｔｅ）、エチオフェンカルブ（ｅｔｈｉｏｆｅｎｃａｒｂ）、エチオン（ｅｔｈｉｏｎ）、エチプロール（ｅｔｈｉｐｒｏｌｅ）、エチレンジブロミド（ｅｔｈｙｌｅｎｅ　ｄｉｂｒｏｍｉｄｅ）、エトキサゾール（ｅｔｏｘａｚｏｌｅ）、エトフェンプロックス（ｅｔｏｆｅｎｐｒｏｘ）、エトプロホス（ｅｔｈｏｐｒｏｐｈｏｓ）、エトリムホス（ｅｔｒｉｍｆｏｓ）、エマメクチンベンゾエート（ｅｍａｍｅｃｔｉｎ　ｂｅｎｚｏａｔｅ）、エンドスルファン（ｅｎｄｏｓｕｌｆａｎ）、エンペントリン（ｅｍｐｅｎｔｈｒｉｎ）、オキサミル（ｏｘａｍｙｌ）、オキシジメトン・メチル（ｏｘｙｄｅｍｅｔｏｎ－ｍｅｔｈｙｌ）、オキシデプロホス（ｏｘｙｄｅｐｒｏｆｏｓ）、オメトエート（ｏｍｅｔｈｏａｔｅ）、カズサホス（ｃａｄｕｓａｆｏｓ）、カッパ-テフルトリン（ｋａｐｐａ－ｔｅｆｌｕｔｈｒｉｎ）、カッパ-ビフェントリン（ｋａｐｐａ－ｂｉｆｅｎｔｈｒｉｎ）、カランジン（ｋａｒａｎｊｉｎ）、カルタップ（ｃａｒｔａｐ）、カルバリル（ｃａｒｂａｒｙｌ）、カルボスルファン（ｃａｒｂｏｓｕｌｆａｎ）、カルボフラン（ｃａｒｂｏｆｕｒａｎ）、ガンマ－ＢＨＣ（ｇａｍｍａ－ＢＨＣ）、キシリルカルブ（ｘｙｌｙｌｃａｒｂ）、キナルホス（ｑｕｉｎａｌｐｈｏｓ）、キノプレン（ｋｉｎｏｐｒｅｎｅ）、キノメチオネート（ｃｈｉｎｏｍｅｔｈｉｏｎａｔ）、クマホス（ｃｏｕｍａｐｈｏｓ）、クリオライト（ｃｒｙｏｌｉｔｅ）、クロチアニジン（ｃｌｏｔｈｉａｎｉｄｉｎ）、クロフェンテジン（ｃｌｏｆｅｎｔｅｚｉｎｅ）、クロマフェノジド（ｃｈｒｏｍａｆｅｎｏｚｉｄｅ）、クロラントラニリプロール（ｃｈｌｏｒａｎｔｒａｎｉｌｉｐｒｏｌｅ）、クロルエトキシホス（ｃｈｌｏｒｅｔｈｏｘｙｆｏｓ）、クロルデン（ｃｈｌｏｒｄａｎｅ）、クロルピクリン（ｃｈｌｏｒｏｐｉｃｒｉｎ）、クロルピリホス（ｃｈｌｏｒｐｙｒｉｆｏｓ）、クロルピリホス・メチル（ｃｈｌｏｒｐｙｒｉｆｏｓ－ｍｅｔｈｙｌ）、クロルフェナピル（ｃｈｌｏｒｆｅｎａｐｙｒ）、クロルフェンビンホス（ｃｈｌｏｒｆｅｎｖｉｎｐｈｏｓ）、クロルフルアズロン（ｃｈｌｏｒｆｌｕａｚｕｒｏｎ）、クロルメホス（ｃｈｌｏｒｍｅｐｈｏｓ）、シアノホス（ｃｙａｎｏｐｈｏｓ）、ジアフェンチウロン（ｄｉａｆｅｎｔｈｉｕｒｏｎ）、ジアミダホス（ｄｉａｍｉｄａｆｏｓ）、シアントラニリプロール（ｃｙａｎｔｒａｎｉｌｉｐｒｏｌｅ）、ジエノクロル（ｄｉｅｎｏｃｈｌｏｒ）、シエノピラフェン（ｃｙｅｎｏｐｙｒａｆｅｎ）、ジオキサベンゾホス（ｄｉｏｘａｂｅｎｚｏｆｏｓ）、ジオフェノラン（ｄｉｏｆｅｎｏｌａｎ）、シクラニリプロール（ｃｙｃｌａｎｉｌｉｐｒｏｌｅ）、ジクロトホス（ｄｉｃｒｏｔｏｐｈｏｓ）、ジクロフェンチオン（ｄｉｃｈｌｏｆｅｎｔｈｉｏｎ）、シクロプロトリン（ｃｙｃｌｏｐｒｏｔｈｒｉｎ）、ジクロルボス（ｄｉｃｈｌｏｒｖｏｓ）、ジクロロメゾチアッツ（ｄｉｃｌｏｒｏｍｅｚｏｔｉａｚ）、１，３‐ジクロロプロペン（１，３－ｄｉｃｈｌｏｒｏｐｒｏｐｅｎｅ）、ジコホル（ｄｉｃｏｆｏｌ）、ジシクラニル（ｄｉｃｙｃｌａｎｉｌ）、ジスルホトン（ｄｉｓｕｌｆｏｔｏｎ）、ジノテフラン（ｄｉｎｏｔｅｆｕｒａｎ）、ジノブトン（ｄｉｎｏｂｕｔｏｎ）、シハロトリン（ｃｙｈａｌｏｔｈｒｉｎ）［ｇａｍｍａ－体，ｌａｍｂｄａ－体を含む］、シフェノトリン（ｃｙｐｈｅｎｏｔｈｒｉｎ）［（１Ｒ）－ｔｒａｎｓ－体を含む］、シフルトリン（ｃｙｆｌｕｔｈｒｉｎ）［ｂｅｔａ－体を含む］、ジフルベンズロン（ｄｉｆｌｕｂｅｎｚｕｒｏｎ）、シフルメトフェン（ｃｙｆｌｕｍｅｔｏｆｅｎ）、ジフロビダジン（ｄｉｆｌｏｖｉｄａｚｉｎ）、シヘキサチン（ｃｙｈｅｘａｔｉｎ）、シペルメトリン（ｃｙｐｅｒｍｅｔｈｒｉｎ）［ａｌｐｈａ－体，ｂｅｔａ－体，ｔｈｅｔａ－体，ｚｅｔａ－体を含む］、ジメチルビンホス（ｄｉｍｅｔｈｙｌｖｉｎｐｈｏｓ）、ジメフルスリン（ｄｉｍｅｆｌｕｔｈｒｉｎ）、ジメトエート（ｄｉｍｅｔｈｏａｔｅ）、シラフルオフェン（ｓｉｌａｆｌｕｏｆｅｎ）、シロマジン（ｃｙｒｏｍａｚｉｎｅ）、スピネトラム（ｓｐｉｎｅｔｏｒａｍ）、スピノサド（ｓｐｉｎｏｓａｄ）、スピロジクロフェン（ｓｐｉｒｏｄｉｃｌｏｆｅｎ）、スピロテトラマト（ｓｐｉｒｏｔｅｔｒａｍａｔ）、スピロメシフェン（ｓｐｉｒｏｍｅｓｉｆｅｎ）、スルコフロン・ナトリウム塩（ｓｕｌｃｏｆｕｒｏｎ－ｓｏｄｉｕｍ）、スルフルラミド（ｓｕｌｆｌｕｒａｍｉｄ）、スルホキサフロル（ｓｕｌｆｏｘａｆｌｏｒ）、スルホテップ（ｓｕｌｆｏｔｅｐ）、ダイアジノン（ｄｉａｚｉｎｏｎ）、チアクロプリド（ｔｈｉａｃｌｏｐｒｉｄ）、チアメトキサム（ｔｈｉａｍｅｔｈｏｘａｍ）、チオキサザフェン（ｔｉｏｘａｚａｆｅｎ）、チオジカルブ（ｔｈｉｏｄｉｃａｒｂ）、チオシクラム（ｔｈｉｏｃｙｃｌａｍ）、チオスルタップ（ｔｈｉｏｓｕｌｔａｐ）、チオナジン（ｔｈｉｏｎａｚｉｎ）、チオファノックス（ｔｈｉｏｆａｎｏｘ）、チオメトン（ｔｈｉｏｍｅｔｏｎ）、テトラクロルビンホス（ｔｅｔｒａｃｈｌｏｒｖｉｎｐｈｏｓ）、テトラジホン（ｔｅｔｒａｄｉｆｏｎ）、テトラニリプロール（ｔｅｔｒａｎｉｌｉｐｒｏｌｅ）、テトラメチルフルスリン（ｔｅｔｒａｍｅｔｈｙｌｆｌｕｔｈｒｉｎ）、テトラメトリン（ｔｅｔｒａｍｅｔｈｒｉｎ）、テブピリムホス（ｔｅｂｕｐｉｒｉｍｆｏｓ）、テブフェノジド（ｔｅｂｕｆｅｎｏｚｉｄｅ）、テブフェンピラド（ｔｅｂｕｆｅｎｐｙｒａｄ）、テフルトリン（ｔｅｆｌｕｔｈｒｉｎ）、テフルベンズロン（ｔｅｆｌｕｂｅｎｚｕｒｏｎ）、デメトン・Ｓ・メチル（ｄｅｍｅｔｏｎ－Ｓ－ｍｅｔｈｙｌ）、テメホス（ｔｅｍｅｐｈｏｓ）、デルタメトリン（ｄｅｌｔａｍｅｔｈｒｉｎ）、テルブホス（ｔｅｒｂｕｆｏｓ）、トラロメトリン（ｔｒａｌｏｍｅｔｈｒｉｎ）、トランスフルトリン（ｔｒａｎｓｆｌｕｔｈｒｉｎ）、トリアザメート（ｔｒｉａｚａｍａｔｅ）、トリアゾホス（ｔｒｉａｚｏｐｈｏｓ）、トリクロルホン（ｔｒｉｃｈｌｏｒｆｏｎ）、トリフルムロン（ｔｒｉｆｌｕｍｕｒｏｎ）、トリフルメゾピリム（ｔｒｉｆｌｕｍｅｚｏｐｙｒｉｍ）、トリメタカルブ（ｔｒｉｍｅｔｈａｃａｒｂ）、トルフェンピラド（ｔｏｌｆｅｎｐｙｒａｄ）、ナレッド（ｎａｌｅｄ）、ニテンピラム（ｎｉｔｅｎｐｙｒａｍ）、ノバルロン（ｎｏｖａｌｕｒｏｎ）、ノビフルムロン（ｎｏｖｉｆｌｕｍｕｒｏｎ）、バーティシリウム　レカニ（Ｖｅｒｔｉｃｉｌｌｉｕｍ　ｌｅｃａｎｉｉ）、ハイドロプレン（ｈｙｄｒｏｐｒｅｎｅ）、パスツーリアペネトランス胞子（Ｐａｓｔｅｕｒｉａｐｅｎｅｔｒａｎｓ）、バミドチオン（ｖａｍｉｄｏｔｈｉｏｎ）、パラチオン（ｐａｒａｔｈｉｏｎ）、パラチオン・メチル（ｐａｒａｔｈｉｏｎ－ｍｅｔｈｙｌ）、ハルフェンプロックス（ｈａｌｆｅｎｐｒｏｘ）、ハロフェノジド（ｈａｌｏｆｅｎｏｚｉｄｅ）、ビオアレスリン（ｂｉｏａｌｌｅｔｈｒｉｎ）、ビオアレスリンＳ‐シクロペンテニル（ｂｉｏａｌｌｅｔｈｒｉｎ　Ｓ－ｃｙｃｌｏｐｅｎｔｅｎｙｌ）、ビオレスメトリン（ｂｉｏｒｅｓｍｅｔｈｒｉｎ）、ビストリフルロン（ｂｉｓｔｒｉｆｌｕｒｏｎ）、ヒドラメチルノン（ｈｙｄｒａｍｅｔｈｙｌｎｏｎ）、ビフェナゼート（ｂｉｆｅｎａｚａｔｅ）、ビフェントリン（ｂｉｆｅｎｔｈｒｉｎ）、ピフルブミド（ｐｙｆｌｕｂｕｍｉｄｅ）、ピペロニルブトキシド（ｐｉｐｅｒｏｎｙｌ　ｂｕｔｏｘｉｄｅ）、ピメトロジン（ｐｙｍｅｔｒｏｚｉｎｅ）、ピラクロホス（ｐｙｒａｃｌｏｆｏｓ）、ピラフルプロール（ｐｙｒａｆｌｕｐｒｏｌｅ）、ピリダフェンチオン（ｐｙｒｉｄａｐｈｅｎｔｈｉｏｎ）、ピリダベン（ｐｙｒｉｄａｂｅｎ）、ピリダリル（ｐｙｒｉｄａｌｙｌ）、ピリフルキナゾン（ｐｙｒｉｆｌｕｑｕｉｎａｚｏｎ）、ピリプロール（ｐｙｒｉｐｒｏｌｅ）、ピリプロキシフェン（ｐｙｒｉｐｒｏｘｙｆｅｎ）、ピリミカルブ（ｐｉｒｉｍｉｃａｒｂ）、ピリミジフェン（ｐｙｒｉｍｉｄｉｆｅｎ）、ピリミノストロビン（ｐｙｒｉｍｉｎｏｓｔｒｏｂｉｎ）、ピリミホス・メチル（ｐｉｒｉｍｉｐｈｏｓ－ｍｅｔｈｙｌ）、ピレトリン（ｐｙｒｅｔｈｒｉｎｅ）、ファムフル（ｆａｍｐｈｕｒ）、フィプロニル（ｆｉｐｒｏｎｉｌ）、フェナザキン（ｆｅｎａｚａｑｕｉｎ）、フェナミホス（ｆｅｎａｍｉｐｈｏｓ）、フェニトロチオン（ｆｅｎｉｔｒｏｔｈｉｏｎ）、フェノキシカルブ（ｆｅｎｏｘｙｃａｒｂ）、フェノチオカルブ（ｆｅｎｏｔｈｉｏｃａｒｂ）、フェノトリン（ｐｈｅｎｏｔｈｒｉｎ）［（１Ｒ）－ｔｒａｎｓ－体を含む］、フェノブカルブ（ｆｅｎｏｂｕｃａｒｂ）、フェンチオン（ｆｅｎｔｈｉｏｎ）、フェントエート（ｐｈｅｎｔｈｏａｔｅ）、フェンバレレート（ｆｅｎｖａｌｅｒａｔｅ）、フェンピロキシメート（ｆｅｎｐｙｒｏｘｉｍａｔｅ）、フェンブタンチン・オキシド（ｆｅｎｂｕｔａｔｉｎ　ｏｘｉｄｅ）、フェンプロパトリン（ｆｅｎｐｒｏｐａｔｈｒｉｎ）、フォノホス（ｆｏｎｏｆｏｓ）、フッ化スルフリル（ｓｕｌｆｕｒｙｌ　ｆｌｕｏｒｉｄｅ）、ブトカルボキシム（ｂｕｔｏｃａｒｂｏｘｉｍ）、ブトキシカルボキシム（ｂｕｔｏｘｙｃａｒｂｏｘｉｍ）、ブプロフェジン（ｂｕｐｒｏｆｅｚｉｎ）、フラチオカルブ（ｆｕｒａｔｈｉｏｃａｒｂ）、プラレトリン（ｐｒａｌｌｅｔｈｒｉｎ）、フルアクリピリム（ｆｌｕａｃｒｙｐｙｒｉｍ）、フルアズロン（ｆｌｕａｚｕｒｏｎ）、フルエンスルホン（ｆｌｕｅｎｓｕｌｆｏｎｅ）、フルオロ酢酸ナトリウム塩（ｓｏｄｉｕｍ　ｆｌｕｏｒｏａｃｅｔａｔｅ）、フルシクロクスロン（ｆｌｕｃｙｃｌｏｘｕｒｏｎ）、フルシトリネート（ｆｌｕｃｙｔｈｒｉｎａｔｅ）、フルスルファミド（ｆｌｕｓｕｌｆａｍｉｄｅ）、フルバリネート（ｆｌｕｖａｌｉｎａｔｅ）　［ｔａｕ－体を含む］、フルピラジフロン（ｆｌｕｐｙｒａｄｉｆｕｒｏｎｅ）、フルピラゾホス（ｆｌｕｐｙｒａｚｏｆｏｓ）、フルフィプロール（ｆｌｕｆｉｐｒｏｌｅ）、フルフェネリム（ｆｌｕｆｅｎｅｒｉｍ）、フルフェノキシストロビン（ｆｌｕｆｅｎｏｘｙｓｔｒｏｂｉｎ）、フルフェノクスロン（ｆｌｕｆｅｎｏｘｕｒｏｎ）、フルヘキサフォン（ｆｌｕｈｅｘａｆｏｎ）、フルベンジアミド（ｆｌｕｂｅｎｄｉａｍｉｄｅ）、フルメトリン（ｆｌｕｍｅｔｈｒｉｎ）、プロトリフェンブト（ｐｒｏｔｒｉｆｅｎｂｕｔｅ）、プロチオホス（ｐｒｏｔｈｉｏｆｏｓ）、フロニカミド（ｆｌｏｎｉｃａｍｉｄ）、プロパホス（ｐｒｏｐａｐｈｏｓ）、プロパ
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Acrinathrin, Azadirachtin, Azamethiphos, Azinophos-ethyl, Azeinosylacetin, Acequinocetyl (Acephate), azocyclotin, abamectin, afidopyropen, amidoflumet, amitraz, alanib, alicalb, aldib Aldoxycarb, allethrin [including d-cis-trans-form and d-trans-form], isazophos, isamifofos, isocarbophos, isoxathion methyl, isoxathion methyl, isoxathion (Isofenphos-methyl), isoprocarb, ivermectin, imicyafos, imidacloprid, imiprothrin, indoxacarb, indoxacarb offencarb, ethifotin, etemoforthos, etemoforthos, etemoforthos Endosulfan, empentrin, oxamyl, oxydimethon-methyl, oxydeprofos, omethoate, cadsafoth, cadpasatoflus (Kappa-tefluthrin), kappa-bifenthrin, caranjin, cartap, carbaryl, carbosulfan, carbofuran (HC) ), Xylylcarb, quinalphos, quinoprene, quinomethionate, coumafos, cryolite, rothianzine, rothenidin, clotianidin de), chlorantraniliprole, chlorethoxyphos, chlordane, chloropicrin, chlorpyrifos, chlorpyrifos, chlorpyrifos methyl. Vinfenfos, chlorfluazuron, chlormefos, cyanophos, diafenthiuron, diamidafos, cyantraniprolol aniliprole, dienochlor, cenopyrafen, dioxabenfos, diphenolan, cyclaniloprole, dicrotophos, dicrotophos , Dichlorovos, dichloromezothiaz, 1,3-dichloropropene, dicofol, dicyclanil, disulfoton, dinotef Dinotefuran, dinobuton, cyhalothrin (including gamma-form and lambda-form), cyphenothrin [including (1R) -trans-form], cyfluthrin- (cyfluthrin-) Diflubenzuron, cyflumetofen, diflovidazin, cyhexatin, cypermethrin [alpha-, beta-, beta-, beta-, beta-, beta-, beta-, beta, Dimethylvinphos, dimethylfluthrin, Dimethoate, silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, spirotetramethylene salt, spirotetramethylene salt, spirotetramethylene salt (Sulcofuron-sodium), sulfluramide, sulfoxafluor, sulfotep, diazinon, thiacloprid, thiamethoxam, thiamethoxam afen), thiodicarb, thiocyclam, thiosultap, thiozazine, thiophanox, thiomethonte, dichlortetraphos, tetrachlorvinphos (tetrachlordiphos) Tetroliliprole, tetramethylfluthrin, tetramethrin, tebupyrimfos, tebufenozide, tebufenpyrthful , Teflubenzuron, demethon-S-methyl, temephos, deltamethrin, terbufos, tralomethrin, trafluthrin (t), transfluthrin (t) , Triazophos, trichlorfon, triflumuron, triflumezopyrim, trimetacarb, tolfenpyrad, tolfenpyrad am), novaluron, noviflumuron, verticillium lecanii, hydroprene, pasteuria tranion, pastathione, bamidion Methyl (parathion-methyl), Halfenprox, Halofenozide, Bioallethrin, Bioarethrin S-cyclopentenylthylene (biethylenethrin), Biolethrin S-cyclopentenyl Bistrifluron, hydramethylnon, bifenazate, bifenthrin, piflubumide, piperonyl pyroxide, piperonyl pyroxide pyrafluprole, pyridafenthion, pyridaben, pyridalyl, pyrifluquinazone, pyriprole, pyriprofen, pyriprox Carbim, pyrimidifen, pyriminostrobin, pyrimiphos-methyl, pyrethrin, famkin, fepronil, fepronil, fepronil, fepronil ), Fenitrothion, phenoxycarb, phenothiocarb, phenothrin [including (1R) -trans-form], fenobucarb, phenthion, fention, fention thiovalate, fenvalerate, fenpyroximate, fenbutatin oxide, fenpropatrinin, fofofos, carboxysulfuryl fluoride , Butoxycarboxim, buprofezin, furathiocarb, praretrin, fluacrylpyrim, fluazuluon, fluazuron Sodium acetoacetate (sodium fluoroacetate), flucycloxuron, flucitrinate, flusulfamide, fluvalinate [including tau-form], flupiradifluon, flupyrazurafone ), Flufiprole, flufenerim, fluphenoxystrobin, flufenoxuron, fluhexafon, flubenamidef, flubenamide f umethrin, protrifenbute, prothiofos, flonicamid, propopas, propargite, profenofos, rofluprodo, proflufos. , Propoxur, flometoquin, bromopropyrate, hexathiazox, hexaflumuron, pequilomyces teneupes uipes), Pecilomyces fumosoroseus, heptafluthrin, heptenophos (permethrinb), permethrin (benmethothib), benclothiaz (benmethothib) ), Benfuracarb, beauveria tenella, beauberia bassiana, beauberia bronnia (ph), salon, x phosalone, phosthiazate, phosthietan, phosphamidone, phosmet, polynactin complex, formatenate, ect, m Mecarbam, mesulfenfos, methomyl, methaflumizone, methamidophos, methamofion, methicarb, methithion Methyl isothiocyanate, methyl bromide, methoxychlor, methoxyphenozide, methotrine, methofrine, methofrine, Meperfluthrin, monacrosporium phymatopagum, monocrotophos, monofluorophosphine, momfluorothrin, little a re-A), Little A B (Little-B), Aluminum Phosphide, Zinc Phosphide, Hydrogen Phosphine, Lufenuron, Rescalure, Resmethrin , Lepimectin, rotenone, fenbutatin oxide, calcium cyanide, nicotine-sulfate, (Z) -11 tetradecenyl acetate, (Z) -11 hexade (Z) -11-hexadecenyl acetate, (Z) -9,12-tetradecadienyl acetate (Z) -9-tetradecen-1-ol, (Z, E) -9,11-tetradecadienyl acetate, (Z, E) -9,12-tetradecadienyl acetate, bacillus・ Popillier (Bacillus popilliae), Bacillus subtilis, Bacillus sphaericus (Bacillus sphaericus), Bacillus thuringiensis, subspecies ・ Izawaii Aizawai), Bacillus thuringiensis subsp. Islaelensis, Bacillus thuringiensis subsp. Kurstakis, B. burs. thuringiensis subsp. , DDT (1,1 1-trichloro-2,2-bis (4-chlorophenyl) ethane), DEP (dimethyl-2,2,2-trichloro-1-hydroxyethylphosphonate), DNOC (4,6-dinitro-o-cresol), DSP (O, O-diethyl-O- [4- (dimethylsulfamoyl) phenyl] -phosphorothionate), EPN (O-ethyl-O-4- (nitrophenyl) phenylphosphonothioate, nuclear polyhedrosis) Virus embedded body, NA-85 (code number), NA-89 (code number), NC-515 (code number), RU15525 (code number), ZDI-2501 (code number), XMC (XMC), Z- 13-Icosen-10-one, ZXI8901 (code number), ME5382.
　［殺菌活性成分］
　アザコナゾール（ａｚａｃｏｎａｚｏｌｅ）、アシベンゾラル・Ｓ・メチル（ａｃｉｂｅｎｚｏｌａｒ－Ｓ－ｍｅｔｈｙｌ）、アゾキシストロビン（ａｚｏｘｙｓｔｒｏｂｉｎ）、アニラジン（ａｎｉｌａｚｉｎｅ）、アミスルブロム（ａｍｉｓｕｌｂｒｏｍ）、アメトクトラジン（ａｍｅｔｏｃｔｒａｄｉｎ）、アルジモルフ（ａｌｄｉｍｏｒｐｈ）、イソチアニル（ｉｓｏｔｉａｎｉｌ）、イソピラザム（ｉｓｏｐｙｒａｚａｍ）、イソフェタミド（ｉｓｏｆｅｔａｍｉｄ）、イソプロチオラン（ｉｓｏｐｒｏｔｈｉｏｌａｎｅ）、イプコナゾール（ｉｐｃｏｎａｚｏｌｅ）、イプロジオン（ｉｐｒｏｄｉｏｎｅ）、イプロバリカルブ（ｉｐｒｏｖａｌｉｃａｒｂ）、イプロベンホス（ｉｐｒｏｂｅｎｆｏｓ）、イマザリル（ｉｍａｚａｌｉｌ）、イミノクタジン・アルベシル酸塩（ｉｍｉｎｏｃｔａｄｉｎｅ－ａｌｂｅｓｉｌａｔｅ）、イミノクタジン酢酸塩（ｉｍｉｎｏｃｔａｄｉｎｅ－　ｔｒｉａｃｅｔａｔｅ）、イミベンコナゾール（ｉｍｉｂｅｎｃｏｎａｚｏｌｅ）、エジフェンホス（ｅｄｉｆｅｎｐｈｏｓ）、エタコナゾ－ル（ｅｔａｃｏｎａｚｏｌｅ）、エタボキサム（ｅｔｈａｂｏｘａｍ）、エチリモル（ｅｔｈｉｒｉｍｏｌ）、エトキシキン（ｅｔｈｏｘｙｑｕｉｎ）、エトリジアゾール（ｅｔｒｉｄｉａｚｏｌｅ）、エネストロブリン（ｅｎｅｓｔｒｏｂｕｒｉｎ）、エノキサストロビン（ｅｎｏｘａｓｔｒｏｂｉｎ）、エポキシコナゾール（ｅｐｏｘｉｃｏｎａｚｏｌｅ）、オーガニックオイル（ｏｒｇａｎｉｃ　ｏｉｌｓ）、オキサジキシル（ｏｘａｄｉｘｙｌ）、オキサジニラゾール（ｏｘａｚｉｎｙｌａｚｏｌｅ）、オキサチアピプロリン（ｏｘａｔｈｉａｐｉｐｒｏｌｉｎ）、オキシカルボキシン（ｏｘｙｃａｒｂｏｘｉｎ）、オキシキノリン銅（ｏｘｉｎｅ－ｃｏｐｐｅｒ）、オキシテトラサイクリン（ｏｘｙｔｅｔｒａｃｙｃｌｉｎｅ）、オキスポコナゾールフマル酸塩（ｏｘｐｏｃｏｎａｚｏｌｅ－ｆｕｍａｒａｔｅ）、オキソリニック酸（ｏｘｏｌｉｎｉｃ　ａｃｉｄ）、オクタン酸銅（ｃｏｐｐｅｒ　ｄｉｏｃｔａｎｏａｔｅ）、オクチリノン（ｏｃｔｈｉｌｉｎｏｎｅ）、オフラセ（ｏｆｕｒａｃｅ）、オリサストロビン（ｏｒｙｓａｓｔｒｏｂｉｎ）、オルソフェニルフェノール（ｏ－ｐｈｅｎｙｌｐｈｅｎｏｌ）、カスガマイシン（ｋａｓｕｇａｍｙｃｉｎ）、カプタホール（ｃａｐｔａｆｏｌ）、カルプロパミド（ｃａｒｐｒｏｐａｍｉｄ）、カルベンダジム（ｃａｒｂｅｎｄａｚｉｍ）、カルボキシン（ｃａｒｂｏｘｉｎ）、カルボネ（ｃａｒｖｏｎｅ）、キノキシフェン（ｑｕｉｎｏｘｙｆｅｎ）、キノメチオネート（ｃｈｉｎｏｍｅｔｈｉｏｎａｔ）、キャプタン（ｃａｐｔａｎ）、キンコナゾール（ｑｕｉｎｃｏｎａｚｏｌｅ）、キントゼン（ｑｕｉｎｔｏｚｅｎｅ）、グアザチン（ｇｕａｚａｔｉｎｅ）、クフラネブ（ｃｕｆｒａｎｅｂ）、クモキシストロビン（ｃｏｕｍｏｘｙｓｔｒｏｂｉｎ）、クレソキシム・メチル（ｋｒｅｓｏｘｉｍ－ｍｅｔｈｙｌ）、クロジラコン（ｃｌｏｚｙｌａｃｏｎ）、クロゾリネート（ｃｈｌｏｚｏｌｉｎａｔｅ）、クロロタロニル（ｃｈｌｏｒｏｔｈａｌｏｎｉｌ）、クロロネブ（ｃｈｌｏｒｏｎｅｂ）、シアゾファミド（ｃｙａｚｏｆａｍｉｄ）、ジエトフェンカルブ（ｄｉｅｔｈｏｆｅｎｃａｒｂ）、ジクロシメット（ｄｉｃｌｏｃｙｍｅｔ）、ジクロフルアニド（ｄｉｃｈｌｏｆｌｕａｎｉｄ）、ジクロメジン（ｄｉｃｌｏｍｅｚｉｎｅ）、ジクロラン（ｄｉｃｌｏｒａｎ）、ジクロロフェン（ｄｉｃｈｌｏｒｏｐｈｅｎ）、ジチアノン（ｄｉｔｈｉａｎｏｎ）、ジニコナゾール（ｄｉｎｉｃｏｎａｚｏｌｅ）、ジニコナゾール・Ｍ（ｄｉｎｉｃｏｎａｚｏｌｅ－Ｍ）、ジネブ（ｚｉｎｅｂ）、ジノカップ（ｄｉｎｏｃａｐ）、ジピメチトロン（ｄｉｐｙｍｅｔｉｔｒｏｎｅ）、ジフェニルアミン（ｄｉｐｈｅｎｙｌａｍｉｎｅ）、ジフェノコナゾール（ｄｉｆｅｎｏｃｏｎａｚｏｌｅ）、シフルフェナミド（ｃｙｆｌｕｆｅｎａｍｉｄ）、ジフルメトリム（ｄｉｆｌｕｍｅｔｏｒｉｍ）、シプロコナゾール（ｃｙｐｒｏｃｏｎａｚｏｌｅ）、シプロジニル（ｃｙｐｒｏｄｉｎｉｌ）、シメコナゾール（ｓｉｍｅｃｏｎａｚｏｌｅ）、ジメチリモル（ｄｉｍｅｔｈｉｒｉｍｏｌ）、ジメチルジスルフィド（ｄｉｍｅｔｈｙｌ　ｄｉｓｕｌｆｉｄｅ）、ジメトモルフ（ｄｉｍｅｔｈｏｍｏｒｐｈ）、シモキサニル（ｃｙｍｏｘａｎｉｌ）、ジモキシストロビン（ｄｉｍｏｘｙｓｔｒｏｂｉｎ）、ジラム（ｚｉｒａｍ）、シルチオファム（ｓｉｌｔｈｉｏｆａｍ）、ストレプトマイシン（ｓｔｒｅｐｔｏｍｙｃｉｎ）、スピロキサミン（ｓｐｉｒｏｘａｍｉｎｅ）、セダキサン（ｓｅｄａｘａｎｅ）、ゾキサミド（ｚｏｘａｍｉｄｅ）、ダゾメット（ｄａｚｏｍｅｔ）、チアジニル（ｔｉａｄｉｎｉｌ）、チアベンダゾール（ｔｈｉａｂｅｎｄａｚｏｌｅ）、チウラム（ｔｈｉｒａｍ）、チオファネート（ｔｈｉｏｐｈａｎａｔｅ）、チオファネート・メチル（ｔｈｉｏｐｈａｎａｔｅ－ｍｅｔｈｙｌ）、チフルザミド（ｔｈｉｆｌｕｚａｍｉｄｅ）、テクナゼン（ｔｅｃｎａｚｅｎｅ）、テクロフタラム（ｔｅｃｌｏｆｔａｌａｍ）、テトラコナゾール（ｔｅｔｒａｃｏｎａｚｏｌｅ）、デバカルブ（ｄｅｂａｃａｒｂ）、テブコナゾール（ｔｅｂｕｃｏｎａｚｏｌｅ）、テブフロキン（ｔｅｂｕｆｌｏｑｕｉｎ）、テルビナフィン（ｔｅｒｂｉｎａｆｉｎｅ）、ドジン（ｄｏｄｉｎｅ）、ドデモルフ（ｄｏｄｅｍｏｒｐｈ）、トリアジメノール（ｔｒｉａｄｉｍｅｎｏｌ）、トリアジメホン（ｔｒｉａｄｉｍｅｆｏｎ）、トリアゾキシド（ｔｒｉａｚｏｘｉｄｅ）、トリクラミド（ｔｒｉｃｈｌａｍｉｄｅ）、トリクロピリカルブ（ｔｒｉｃｌｏｐｙｒｉｃａｒｂ）、トリシクラゾール（ｔｒｉｃｙｃｌａｚｏｌｅ）、トリチコナゾール（ｔｒｉｔｉｃｏｎａｚｏｌｅ）、トリデモルフ（ｔｒｉｄｅｍｏｒｐｈ）、トリフルミゾール（ｔｒｉｆｌｕｍｉｚｏｌｅ）、トリフロキシストロビン（ｔｒｉｆｌｏｘｙｓｔｒｏｂｉｎ）、トリホリン（ｔｒｉｆｏｒｉｎｅ）、トリルフルアニド（ｔｏｌｙｌｆｌｕａｎｉｄ）、トルクロホス・メチル（ｔｏｌｃｌｏｆｏｓ－ｍｅｔｈｙｌ）、トルニファニド（ｔｏｌｎｉｆａｎｉｄｅ）、トルプロカルブ（ｔｏｌｐｒｏｃａｒｂ）、ナーバム（ｎａｂａｍ）、ナタマイシン（ｎａｔａｍｙｃｉｎ）、ナフティフィン（ｎａｆｔｉｆｉｎｅ）、ニトラピリン（ｎｉｔｒａｐｙｒｉｎ）、ニトロタル・イソプロピル（ｎｉｔｒｏｔｈａｌ－ｉｓｏｐｒｏｐｙｌ）、ヌアリモル（ｎｕａｒｉｍｏｌ）、ノニルフェノールスルホン酸銅（ｃｏｐｐｅｒ　ｎｏｎｙｌ　ｐｈｅｎｏｌ　ｓｕｌｐｈｏｎａｔｅ）、バチルス・ズブチリス（Ｂａｃｉｌｌｕｓ　ｓｕｂｔｉｌｉｓ）（ｓｔｒａｉｎ：ＱＳＴ　７１３）、バリダマイシン（ｖａｌｉｄａｍｙｃｉｎ）、バリフェナレート（ｖａｌｉｆｅｎａｌａｔｅ）、ピカルブトラゾックス（ｐｉｃａｒｂｕｔｒａｚｏｘ）、ビキサフェン（ｂｉｘａｆｅｎ）、ピコキシストロビン（ｐｉｃｏｘｙｓｔｒｏｂｉｎ）、ビテルタノール（ｂｉｔｅｒｔａｎｏｌ）、ビナパクリル（ｂｉｎａｐａｃｒｙｌ）、ビフェニル（ｂｉｐｈｅｎｙｌ）、ピペラリン（ｐｉｐｅｒａｌｉｎ）、ヒメキサゾール（ｈｙｍｅｘａｚｏｌ）、ピラオキシストロビン（ｐｙｒａｏｘｙｓｔｒｏｂｉｎ）、ピラクロストロビン（ｐｙｒａｃｌｏｓｔｒｏｂｉｎ）、ピラジフルミド（ｐｙｒａｚｉｆｌｕｍｉｄ）、ピラゾホス（ｐｙｒａｚｏｐｈｏｓ）、ピラメトストロビン（ｐｙｒａｍｅｔｏｓｔｒｏｂｉｎ）、ピリオフェノン（ｐｙｒｉｏｆｅｎｏｎｅ）、ピリソキサゾール（ｐｙｒｉｓｏｘａｚｏｌｅ）、ピリフェノックス（ｐｙｒｉｆｅｎｏｘ）、ピリブチカルブ（ｐｙｒｉｂｕｔｉｃａｒｂ）、ピリベンカルブ（ｐｙｒｉｂｅｎｃａｒｂ）、ピリメタニル（ｐｙｒｉｍｅｔｈａｎｉｌ）、ピロキロン（ｐｙｒｏｑｕｉｌｏｎ）、ビンクロゾリン（ｖｉｎｃｌｏｚｏｌｉｎ）、ファーバム（ｆｅｒｂａｍ）、ファモキサドン（ｆａｍｏｘａｄｏｎｅ）、フェナジンオキシド（ｐｈｅｎａｚｉｎｅ　ｏｘｉｄｅ）、フェナミドン（ｆｅｎａｍｉｄｏｎｅ）、フェナミンストロビン（ｆｅｎａｍｉｎｓｔｒｏｂｉｎ）、フェナリモル（ｆｅｎａｒｉｍｏｌ）、フェノキサニル（ｆｅｎｏｘａｎｉｌ）、フェリムゾン（ｆｅｒｉｍｚｏｎｅ）、フェンピクロニル（ｆｅｎｐｉｃｌｏｎｉｌ）、フェンピラザミン（ｆｅｎｐｙｒａｚａｍｉｎｅ）、フェンブコナゾール（ｆｅｎｂｕｃｏｎａｚｏｌｅ）、フェンフラム（ｆｅｎｆｕｒａｍ）、フェンプロピジン（ｆｅｎｐｒｏｐｉｄｉｎ）、フェンプロピモルフ（ｆｅｎｐｒｏｐｉｍｏｒｐｈ）、フェンヘキサミド（ｆｅｎｈｅｘａｍｉｄ）、フォルペット（ｆｏｌｐｅｔ）、フサライド（ｐｈｔｈａｌｉｄｅ）、ブピリメート（ｂｕｐｉｒｉｍａｔｅ）、フベリダゾール（ｆｕｂｅｒｉｄａｚｏｌｅ）、ブラストサイジン－Ｓ（ｂｌａｓｔｉｃｉｄｉｎ－Ｓ）、フラメトピル（ｆｕｒａｍｅｔｐｙｒ）、フララキシル（ｆｕｒａｌａｘｙｌ）、フランカルボン酸（ｆｕｒａｎｃａｒｂｏｘｙｌｉｃ　ａｃｉｄ）、フルアジナム（ｆｌｕａｚｉｎａｍ）、フルオキサストロビン（ｆｌｕｏｘａｓｔｒｏｂｉｎ）、フルオピコリド（ｆｌｕｏｐｉｃｏｌｉｄｅ）、フルオピラム（ｆｌｕｏｐｙｒａｍ）、フルオルイミド（ｆｌｕｏｒｏｉｍｉｄｅ）、フルキサピロキサド（ｆｌｕｘａｐｙｒｏｘａｄ）、フルキンコナゾール（ｆｌｕｑｕｉｎｃｏｎａｚｏｌｅ）、フルコナゾール（ｆｕｒｃｏｎａｚｏｌｅ）、フルコナゾール・シス（ｆｕｒｃｏｎａｚｏｌｅ　－ｃｉｓ）、フルジオキソニル（ｆｌｕｄｉｏｘｏｎｉｌ）、フルシラゾール（ｆｌｕｓｉｌａｚｏｌｅ）、フルスルファミド（ｆｌｕｓｕｌｆａｍｉｄｅ）、フルチアニル（ｆｌｕｔｉａｎｉｌ）、フルトラニル（ｆｌｕｔｏｌａｎｉｌ）、フルトリアホール（ｆｌｕｔｒｉａｆｏｌ）、フルフェノキシストロビン（ｆｌｕｆｅｎｏｘｙｓｔｒｏｂｉｎ）、フルメトベル（ｆｌｕｍｅｔｏｖｅｒ）、フルモルフ（ｆｌｕｍｏｒｐｈ）、プロキナジド（ｐｒｏｑｕｉｎａｚｉｄ）、プロクロラズ（ｐｒｏｃｈｌｏｒａｚ）、プロシミドン（ｐｒｏｃｙｍｉｄｏｎｅ）、プロチオカルブ（ｐｒｏｔｈｉｏｃａｒｂ）、プロチオコナゾール（ｐｒｏｔｈｉｏｃｏｎａｚｏｌｅ）、ブロノポール（ｂｒｏｎｏｐｏｌ）、プロパモカルブ塩酸塩（ｐｒｏｐａｍｏｃａｒｂ－ｈｙｄｒｏｃｈｌｏｒｉｄｅ）、プロピコナゾール（ｐｒｏｐｉｃｏｎａｚｏｌｅ）、プロピネブ（ｐｒｏｐｉｎｅｂ）、プロベナゾール（ｐｒｏｂｅｎａｚｏｌｅ）、ブロムコナゾール（ｂｒｏｍｕｃｏｎａｚｏｌｅ）、ヘキサコナゾール（ｈｅｘａｃｏｎａｚｏｌｅ）、ベナラキシル（ｂｅｎａｌａｘｙｌ）、ベナラキシル・Ｍ（ｂｅｎａｌａｘｙｌ－Ｍ）、ベノダニル（ｂｅｎｏｄａｎｉｌ）、ベノミル（ｂｅｎｏｍｙｌ）、ペフラゾエート（ｐｅｆｕｒａｚｏａｔｅ）、ペンコナゾール（ｐｅｎｃｏｎａｚｏｌｅ）、ペンシクロン（ｐｅｎｃｙｃｕｒｏｎ）、ベンゾビンジフルピル（ｂｅｎｚｏｖｉｎｄｉｆｌｕｐｙｒ）、ベンチアゾール（ｂｅｎｔｈｉａｚｏｌｅ）、ベンチアバリカルブ・イソプロピル（ｂｅｎｔｈｉａｖａｌｉｃａｒｂ－ｉｓｏｐｒｏｐｙｌ）、ペンチオピラド（ｐｅｎｔｈｉｏｐｙｒａｄ）、ペンフルフェン（ｐｅｎｆｌｕｆｅｎ）、ボスカリド（ｂｏｓｃａｌｉｄ）、ホセチル（ｆｏｓｅｔｙｌ）（ａｌｍｉｎｉｕｍ，　ｃａｌｃｉｕｍ，　ｓｏｄｉｕｍ）、ポリオキシン（ｐｏｌｙｏｘｉｎ）、ポリカーバメート（ｐｏｌｙｃａｒｂａｍａｔｅ）、ボルドー液（Ｂｏｒｄｅａｕｘ　ｍｉｘｔｕｒｅ）、マンコゼブ（ｍａｎｃｏｚｅｂ）、マンジプロパミド（ｍａｎｄｉｐｒｏｐａｍｉｄ）、マンデストロビン（ｍａｎｄｅｓｔｒｏｂｉｎ）、マンネブ（ｍａｎｅｂ）、ミクロブタニル（ｍｙｃｌｏｂｕｔａｎｉｌ）、ミネラルオイル（ｍｉｎｅｒａｌ　ｏｉｌｓ）、ミルディオマイシン（ｍｉｌｄｉｏｍｙｃｉｎ）、
メタスルホカルブ（ｍｅｔｈａｓｕｌｆｏｃａｒｂ）、メタム（ｍｅｔａｍ）、メタラキシル（ｍｅｔａｌａｘｙｌ）、メタラキシル・Ｍ（ｍｅｔａｌａｘｙｌ－Ｍ）、メチラム（ｍｅｔｉｒａｍ）、メトコナゾール（ｍｅｔｃｏｎａｚｏｌｅ）、メトミノストロビン（ｍｅｔｏｍｉｎｏｓｔｒｏｂｉｎ）、メトラフェノン（ｍｅｔｒａｆｅｎｏｎｅ）、メパニピリム（ｍｅｐａｎｉｐｙｒｉｍ）、メプチルジノカップ（ｍｅｐｔｙｌｄｉｎｏｃａｐ）、メプロニル（ｍｅｐｒｏｎｉｌ）、ヨードカルブ（ｉｏｄｏｃａｒｂ）、ラミナリン（ｌａｍｉｎａｒｉｎ）、亜リン酸及び塩（ｐｈｏｓｐｈｏｒｏｕｓ　ａｃｉｄ　ａｎｄ　ｓａｌｔｓ）、塩基性塩化銅（ｃｏｐｐｅｒ　ｏｘｙｃｈｌｏｒｉｄｅ）、銀（ｓｉｌｖｅｒ）、酸化第一銅（ｃｕｐｒｏｕｓ　ｏｘｉｄｅ）、水酸化第二銅（ｃｏｐｐｅｒ　ｈｙｄｒｏｘｉｄｅ）、炭酸水素カリウム（ｐｏｔａｓｓｉｕｍ　ｂｉｃａｒｂｏｎａｔｅ）、炭酸水素ナトリウム（ｓｏｄｉｕｍ　ｂｉｃａｒｂｏｎａｔｅ）、硫黄（ｓｕｌｆｕｒ）、硫酸オキシキノリン（ｏｘｙｑｕｉｎｏｌｉｎｅ　ｓｕｌｆａｔｅ）、硫酸銅（ｃｏｐｐｅｒ　ｓｕｌｆａｔｅ）、（３，４－ジクロロイソチアゾール－５－イル）メチル　４－（ｔｅｒｔ－ブチル）安息香酸エステル（化学名、ＣＡＳ登録番号：１２３１２１４－２３－５）、３－（（３，４－ジクロロイソチアゾール－５－イル）メトキシ）ベンゾ［ｄ］イソチアゾール－１，１－ジオキシド（化学名、ＣＡＳ登録番号：９５７１４４－７７－３）、ＢＡＦ－０４５（コード番号）、ＢＡＧ－０１０（コード番号）、ＤＢＥＤＣ（ドデシルベンゼンスルホン酸ビスエチレンジアミン銅錯塩［ＩＩ］）、ＭＩＦ－１００２（コード番号）、ＴＰＴＡ（酢酸トリフェニルスズ）、ＴＰＴＣ（トリフェニルチンクロライド）、ＴＰＴＨ（水酸化トリフェニルスズ）、非病原性エルビニア・カロトボーラ。 [Bactericidal active ingredient]
Azaconazole, acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbisoyl, amethoctrazine , Isopyrazam, isofetamid, isoprothiolane, ipconazole, iprodione, iprovalicas, iprobenizar, iprobenfos il), iminoctadine-albesylate, iminoctadate acetate, imibenconazole, ethifenphos, etaconazol, etaconazol, etaconazol. ), Ethoxyquin, etridiazole, enestroburin, enoxastrobin, epoxiconazole, organic oils, oxazixyl xyl), oxazinylazole, oxathiapiproline, oxycarboxin, oxyquinoline copper, oxytetracycline olpoline oxalcoline oxalconol zole -Fumarate, oxolinic acid, copper dioctanoate, octilinone, offrace, oryastrobine, uga phenylphenol, o-phenylphenol, g-finger, gacin (Captafol), carpropamide, carbendazim, carboxin, carbonone, quinoxyphen, quinomethionate, captamine c ), Guazatine, cufraneb, cuoxystrobin, cresoxime-methyl, clozilacon, chlorothalinate, chlorothalinate ), Chloroneb, cyazofamid, diethofencarb, diclocimet, diclofluanid, diclomandine, dichroane, dichlorane. Diniconazole, Diniconazole-M, Dineb, Dinocap, Dipymetitrone, Diphenylamine, Diphenoconazole (difenoconazole) Cyamide, diflumetrim, diprometazole, cyprodinil, dimethimol, dimethyldisulfide Xylostrobin, ziram, silthiofam, streptomycin, spiroxamine, sedaxane, zoxamide, dazomede Dazomet, thiadinil, thiabendazole, thiram, thiophanate, thiophanate-methyl, tifluzamide, tenazene, technazate Conazole, debacarb, tebuconazole, tebufloquin, terbinafine, dodine, diol, diol, tormeol Dimephone, triazoxide, trichlamide, triclopyricarb, tricyclazole, trifluonazole, trifluconazole, triticonazole, tritriconezole (Trifloxystrobin), triforine, tolylfluanid, tolclofos-methyl, tolnifanide, tolprocarbna, navamnab tamcin, naphthifine, nitrapyrine, nitrotal-isopropyl, nuarimol, copper nonylphenol sulphonate, stilphenate 713), validamycin, varifenalate, picarbutrazox, bixafen, picoxystrobin, bittertanol, binaparol l), biphenyl, piperalin, hymezazole, pyraoxystrobin, pyracrostrobin, pyraziflumid, pirazotopyro Pyriophenone, pyrisoxazole, pyrifenox, pyributicalcarb, pyribencarb, pyrimenil (pyriqanthil), piromethanil (pirimethanil), piromethanil (pirimethanil) lozolin, ferbam, famoxadone, phenazine oxide, phenamidone, phenamine, fenoximol, fenoxilone, fenoxilone, ), Fenpyrazamine, Fenbuconazole, Fenfuram, Fenpropidin, Fenpropimorph, Fenhexamide, Folpetamide folpet, fthalide, bupirimate, fuberidazole, blasticidin-S, furametopyr, furaxyl, furaxyl, furaxyl ), Fluoxastrobine, fluopicolide, fluopyram, fluorimide, fluxapyroxad, fluquinconolazole, fluquinconazole fluquinconazole e), fluconazole-cis, fludioxonil, flusilazole, flusulfamide, fluthianil, flutolanil, flutriahole (flu) ), Flumetover, fluromorph, proquinazid, prochloraz, procymidone, prothiocarb, prothioconazole, prothioconazole Bronopol, propamocarb-hydrochloride, propiconazole, propineb, probenazole, bromoconazole, bromuconazole, bromuconazole, bromuconazole, bromuconazole Benalaxyl-M, benodanyl, benomyl, pefurazoate, penconazole, pencyclon, benzobindiflupyr (benzyl) zole), Benchavaricarb-isopropyl, pentiopyrad, penflufen, boscalid, fosetyl, oxidium, calcium, oxium polycarbamate), Bordeaux mixture, mancozeb, mandipropamide, mandestrobin, manneb, microbutanil, myclobulin mineral Neomycin (mildiomycin),
Metasulfocarb, metham, metalaxyl, metalaxyl-M, metyram, metconazole, metminostrofenine, metminostrofenine mepyrimim, meptyldinocap, mepronil, iodocarb, laminarin, phosphorous acid and salt (phosphorus acid and salt), basic copper chloride ), Cuprous oxide (cup) rous oxide, copper hydroxide, potassium bicarbonate, sodium bicarbonate, sulfur, oxyquinoline sulfate, copper sulfate, copper sulfate, sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate, copper sulfate sulfate (3,4-Dichloroisothiazol-5-yl) methyl 4- (tert-butyl) benzoate (Chemical name, CAS registry number: 1231214-23-5), 3-((3,4-Dichloroisothiazole) -5-yl) methoxy) benzo [d] isothiazole-1,1-dioxide (chemical name, CAS registry number: 957144-77-3), BAF-045 (code number), BAG-010 (co DBEDC (dodecylbenzenesulfonic acid bisethylenediamine copper complex salt [II]), MIF-1002 (code number), TPTA (triphenyltin acetate), TPTC (triphenyltin chloride), TPTH (triphenyl hydroxide) Tin), non-pathogenic Erwinia carotobola.
　［植物生育調節活性成分］
　１－メチルシクロプロペン（１－ｍｅｔｈｙｌｃｙｃｌｏｐｒｏｐｅｎｅ）、１－ナフチルアセトアミド（１－ｎａｐｈｔｈｙｌａｃｅｔａｍｉｄｅ）、２，６－ジイソプロピルナフタレン（２，６－ｄｉｉｓｏｐｒｏｐｙｌｎａｐｈｔｈａｌｅｎｅ）、４－クロロフェノキシ酢酸（４－ＣＰＡ）、ベンジルアミノプリン（ｂｅｎｚｙｌａｍｉｎｏｐｕｒｉｎｅ）、アンシミドール（ａｎｃｙｍｉｄｏｌ）、アビグリシン（ａｖｉｇｌｙｃｉｎｅ）、カルボネ（ｃａｒｖｏｎｅ）、クロルメコート（ｃｈｌｏｒｍｅｑｕａｔ）、クロプロップ（ｃｌｏｐｒｏｐ）、クロキシホナック（ｃｌｏｘｙｆｏｎａｃ）、クロキシホナック・カリウム塩（ｃｌｏｘｙｆｏｎａｃ－ｐｏｔａｓｓｉｕｍ）、シクラニリド（ｃｙｃｌａｎｉｌｉｄｅ）、サイトカイニン（ｃｙｔｏｋｉｎｉｎｓ）、ダミノジット（ｄａｍｉｎｏｚｉｄｅ）、ジケグラック（ｄｉｋｅｇｕｌａｃ）、ジメチピン（ｄｉｍｅｔｈｉｐｉｎ）、エテホン（ｅｔｈｅｐｈｏｎ）、エポコレオン（ｅｐｏｃｈｏｌｅｏｎｅ）、エチクロゼート（ｅｔｈｙｃｈｌｏｚａｔｅ）、フルメトラリン（ｆｌｕｍｅｔｒａｌｉｎ）、フルレノール（ｆｌｕｒｅｎｏｌ）、フルルプリミドール（ｆｌｕｒｐｒｉｍｉｄｏｌ）、ホルクロルフェニュロン（ｆｏｒｃｈｌｏｒｆｅｎｕｒｏｎ）、ジベレリン（ｇｉｂｂｅｒｅｌｌｉｎ）、イナベンフィド（ｉｎａｂｅｎｆｉｄｅ）、インドール酢酸（ｉｎｄｏｌｅ　ａｃｅｔｉｃ　ａｃｉｄ）、インドール酪酸（ｉｎｄｏｌｅ　ｂｕｔｙｒｉｃ　ａｃｉｄ）、マレイン酸ヒドラジド（ｍａｌｅｉｃ　ｈｙｄｒａｚｉｄｅ）、メフルイジド（ｍｅｆｌｕｉｄｉｄｅ）、メピコート・クロリド（ｍｅｐｉｑｕａｔ　ｃｈｌｏｒｉｄｅ）、ｎ－デシルアルコール（ｎ－ｄｅｃａｎｏｌ）、パクロブトラゾール（ｐａｃｌｏｂｕｔｒａｚｏｌ）、プロヘキサジオン・カルシウム塩（ｐｒｏｈｅｘａｄｉｏｎｅ－ｃａｌｃｉｕｍ）、プロヒドロジャスモン（ｐｒｏｈｙｄｒｏｊａｓｍｏｎ）、シントフェン（ｓｉｎｔｏｆｅｎ）、チジアズロン（ｔｈｉｄｉａｚｕｒｏｎ）、トリアコンタノール（ｔｒｉａｃｏｎｔａｎｏｌ）、トリネキサパック・エチル（ｔｒｉｎｅｘａｐａｃ－ｅｔｈｙｌ）、ウニコナゾール（ｕｎｉｃｏｎａｚｏｌｅ）、ウニコナゾール－Ｐ（ｕｎｉｃｏｎａｚｏｌｅ－Ｐ）又は４－オキソ－４－（２－フェニルエチル）アミノ酪酸（化学名、ＣＡＳ登録番号：１０８３－５５－２）、過酸化カルシウム。 [Plant growth regulating active ingredient]
1-methylcyclopropene, 1-naphthylacetamide, 2,6-diisopropylnaphthalene, 4-chlorophenoxyacetic acid (4-CPA), benzylaminopurine (1) benzylaminopurine, ancymidol, aviglycine, carbonone, chlormequat, cloprop, xoxyphonac, cloxyphonac, cloxyphonac Cyclanilide, rhinoceros Cytokinins, daminozide, dikegluc, dimethipin, etephone, epocholone, ethichlorol, luflurinate, luflurinate ), Forchlorfenuron, gibberellin, inabenfide, indole acetic acid, indole butyric acid, maleic hydrazide (maleic acid) drazide, mefluideide, mepiquat chloride, n-decyl alcohol, paclobutrazol, prohexadione calcium salt (prohexadione-calcium), prohexadione-calcium prohydrojasmon, sintofen, thidiazuron, triacontanol, trinexapac-ethyl, uniconazole, uniconazole-Pol or uniconazole-Pol -(2-Phenylethyl) aminobutyric acid ( Chemical name, CAS registration number: 1083-55-2), calcium peroxide.
　上記の農薬活性成分の中でもアジムスルフロン、アゾキシストロビン、アニロホス、イソプロチオラン、イプフェンカルバゾン、イマゾスルフロン、イミダクロプリド、インダノファン、エチプロール、エトキシスルフロン、オキサジアルギル、オキサジクロメホン、カフェンストロール、カルタップ、カルフェントラゾン・エチル、キノクラミン、クミルロン、クロメプロップ、クロラントラニリプロール、シアントラニリプロール、シクロスルファムロン、シクロプロトリン、ジノテフラン、シハロホップ・ブチル、ジメタメトリン、スルホキサフロル、ダイムロン、チオベンカルブ、テニルクロール、テフリルトリオン、トリアファモン、トリシクラゾール、トリフルメゾピリム、ハロスルフロン・メチル、ピラクロニル、ピラゾキシフェン、ピラゾスルフロン・エチル、ピラゾレート、ピリフタリド、ピリブチカルブ、ピリミスルファン、ピリミノバック・メチル、ピロキロン、フェノキサスルホン、フェンキノトリオン、フェントラザミド、ブタクロール、フルセトスルフロン、プレチラクロール、プロピリスルフロン、プロベナゾール、ブロモブチド、ベンスルタップ、ベンスルフロン・メチル、ベンゾビシクロン、ベンゾフェナップ、ペントキサゾン、メタゾスルフロン、メトミノストロビン及びメフェナセットは、水面浮遊型自己拡散性農薬組成物として検討又は既に実用化された実績があり、本発明の如き粒状農薬組成物への使用適性が特に高く、好適に使用できる。 Among the above pesticidal active ingredients, azimusulfuron, azoxystrobin, anilophos, isoprothiolane, ipfencarbazone, imazosulfuron, imidacloprid, indanophane, etiprole, ethoxysulfuron, oxadiargyl, oxadichrome mephone, caventrolol, cartap, carfentrazone / ethyl , Quinoclamine, cumyluron, chromeprop, chlorantraniliprole, cyantraniprolol, cyclosulfamuron, cycloprotonline, dinotefuran, cyhalohop butyl, dimetamethrin, sulfoxafurol, diemron, thiobencarb, tenylchlore, tefriltrione, triafmon, tricyclazole , Triflumezopyrim, halosulfuron methyl, pyraclonyl, pyrazoki Fen, pyrazosulfuron ethyl, pyrazolate, pyriftalide, pyributycarb, pyrimylsulfan, pyriminobac methyl, pyroxylone, phenoxasulfone, fenquinotrione, fentolazamide, butachlor, flucetsulfuron, pretilachlor, propyrisulfuron, probenazole, bromobutide, bensultap, Bensulfuron methyl, benzobicyclon, benzophenap, pentoxazone, metazosulfuron, metminostrobin and mefenacet have been studied or already put into practical use as water-floating self-diffusing pesticide compositions. The suitability for use in an agrochemical composition is particularly high and can be suitably used.
　上記の農薬活性成分は、純品又は原体をそのまま用いてもよいし、予め農薬活性成分を固体又は液体の副原料と混合したプレミックスの形態で用いてもよい。更には、農薬活性成分を壁材で被覆したリザーバー型マイクロカプセルや、農薬活性成分を芯材のマトリクス中に分散したモノリシック型マイクロカプセルの形態で用いることもできる。以上例示した方法に代表される農薬活性成分の製剤化前処理技術の適用については特に限定されず、所望により公知の方法及び資材を任意に使用してよい。 The above-mentioned pesticidal active ingredients may be used pure or as they are, or may be used in the form of a premix in which the pesticidal active ingredients are previously mixed with solid or liquid auxiliary materials. Furthermore, it can also be used in the form of a reservoir microcapsule in which an agrochemical active ingredient is coated with a wall material, or a monolithic microcapsule in which an agrochemical active ingredient is dispersed in a core matrix. There is no particular limitation on the application of the pre-formulation pretreatment technology for agrochemical active ingredients represented by the methods exemplified above, and known methods and materials may be arbitrarily used as desired.
　上記の農薬活性成分は、単独で又は２種以上を混合して用いることができる。また、これらの農薬活性成分の配合割合の合計は特に限定されないが、粒状農薬組成物全量基準で、通常０．１－６５質量％、好ましくは０．５－６０質量％であり、より好ましくは１－５０質量％である。 The above pesticidal active ingredients can be used alone or in admixture of two or more. The total blending ratio of these pesticidal active ingredients is not particularly limited, but is usually 0.1 to 65% by mass, preferably 0.5 to 60% by mass, more preferably based on the total amount of the granular pesticidal composition. 1-50 mass%.
　更に、本発明の粒状農薬組成物においては、上記の農薬活性成分と併せて、薬害軽減化合物を配合することもできる。配合可能な薬害軽減化合物の例を以下に記載するが、本発明はこれらの薬害軽減化合物に限定されるものではない。 Furthermore, in the granular agrochemical composition of the present invention, a phytotoxicity reducing compound can be blended together with the above pesticidal active ingredient. Although the example of the safener compound which can be mix | blended is described below, this invention is not limited to these safener compounds.
　［薬害軽減化合物］
　ベノキサコル（ｂｅｎｏｘａｃｏｒ）、フリラゾール（ｆｕｒｉｌａｚｏｌｅ）、ジクロルミド（ｄｉｃｈｌｏｒｍｉｄ）、ジシクロノン（ｄｉｃｙｃｌｏｎｏｎｅ）、ＤＫＡ－２４（Ｎ１，Ｎ２－ジアリル－Ｎ２－ジクロロアセチルグリシンアミド）、ＡＤ－６７（４－ジクロロアセチル－１－オキサ－４－アザスピロ［４．５］デカン）、ＰＰＧ－１２９２（２，２－ジクロロ－Ｎ－（１，３－ジオキサン－２－イルメチル）－Ｎ－（２－プロペニル）アセトアミド）、Ｒ－２９１４８（３－ジクロロアセチル－２，２，５－トリメチル－１，３－オキサゾリジン）、クロキントセット－メキシル（ｃｌｏｑｕｉｎｔｃｅｔ－ｍｅｘｙｌ）、ナフタル酸無水物（１，８－Ｎａｐｈｔｈａｌｉｃ　Ａｎｈｙｄｒｉｄｅ）、メフェンピル－ジエチル（ｍｅｆｅｎｐｙｒ－ｄｉｅｔｈｙｌ）、メフェンピル（ｍｅｆｅｎｐｙｒ）、メフェンピルエチル（ｍｅｆｅｎｐｙｒ－ｅｔｈｙｌ）、フェンクロラゾール－エチル（ｆｅｎｃｈｌｏｒａｚｏｌｅ－Ｏ－ｅｔｈｙｌ）、フェンクロリム（ｆｅｎｃｌｏｒｉｍ）、ＭＧ－１９１（２－ジクロロメチル－２－メチル－１，３－ジオキサン）、シオメトリニル（ｃｙｏｍｅｔｒｉｎｉｌ）、フルラゾール（ｆｌｕｒａｚｏｌｅ）、フルキソフェニム（ｆｌｕｘｏｆｅｎｉｍ）、イソキサジフェン（ｉｓｏｘａｄｉｆｅｎ）、イソキサジフェン－エチル（ｉｓｏｘａｄｉｆｅｎ－ｅｔｈｙｌ）、ＭＯＮ４６６０（コード番号）、オキサベトリニル（ｏｘａｂｅｔｒｉｎｉｌ）、シプロスルファミド（ｃｙｐｒｏｓｕｌｆａｍｉｄｅ）、低級アルキル置換安息香酸、ＴＩ－３５（コード番号）又はＮ－（２－メトキシベンゾイル）－４－［（メチルアミノカルボニル）アミノ］ベンゼンスルホンアミド（化学名、ＣＡＳ登録番号：１２９５３１－１２－０）。 [Drug-damaging compounds]
Benoxacor, furilazole, dichlormid, dicyclonone, DKA-24 (N1, N2-diallyl-N2-dichloroacetylglycinamide), AD-67 (4-dichloroacetyl-1-oxa) -4-azaspiro [4.5] decane), PPG-1292 (2,2-dichloro-N- (1,3-dioxan-2-ylmethyl) -N- (2-propenyl) acetamide), R-29148 ( 3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine), croquint set-mexyl, naphthalic anhydride (1,8-naphthalic anhydride), mefenpyr-die Chill (mefenpyr-diethyl), mefenpyr (mefenpyr), mefenpyr-ethyl, fenchlorazole-O-ethyl, fenchlorim, MG-191 (2-dichloromethyl-2) -Methyl-1,3-dioxane), Ciomethrinil, flurazole, fluxofenim, isoxadifen, isoxadifen-ethyl (isoxadifen-ethyl), MON4660 (cord number, ox4660) Cyprosulfamide, lower al -Substituted benzoic acid, TI-35 (code number), or N-(2-methoxy) -4 - [(methylaminocarbonyl) amino] benzenesulfonamide (chemical name, CAS Registry Number: 129531-12-0).
　上記の薬害軽減化合物は、単独で又は２種以上を混合して用いることができる。また、これら薬害軽減化合物を配合する場合、その配合割合の合計は、粒状農薬組成物全量基準で、通常０．１－４０質量％、好ましくは０．５－３０質量％であり、より好ましくは１－２５質量％である。 The above phytotoxicity reducing compounds can be used alone or in admixture of two or more. Further, when these phytotoxicity reducing compounds are blended, the total blending ratio is usually 0.1-40% by mass, preferably 0.5-30% by mass, more preferably based on the total amount of the granular agrochemical composition. 1-25% by mass.
　また、本発明の粒状農薬組成物においては、水面で粒を崩壊させ、農薬活性成分を水中に拡散させるために、界面活性剤が配合される。用いることのできる界面活性剤としては、農薬組成物に一般的に用いられるものを使用することができる。 Also, in the granular agrochemical composition of the present invention, a surfactant is blended in order to disintegrate the grains on the water surface and diffuse the agrochemical active ingredient into water. As the surfactant that can be used, those generally used in agricultural chemical compositions can be used.
　具体的な界面活性剤の例としては、ポリエチレングリコール高級脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンアリールフェニルエーテル、ソルビタンモノアルキレート、アセチレンアルコール及びアセチレンジオール並びにそれらのアルキレンオキシド付加物などのノニオン性界面活性剤；アルキルアリールスルホン酸塩、ジアルキルスルホン酸塩、リグニンスルホン酸塩、ナフタレンスルホン酸塩及びその縮合物、アルキル硫酸エステル塩、アルキルリン酸エステル塩、アルキルアリール硫酸エステル塩、アルキルアリールリン酸エステル塩、ポリオキシエチレンアルキルエーテル硫酸エステル塩、ポリオキシエチレンアルキルアリールエーテル硫酸エステル塩、ポリオキシエチレンアリールフェニルエーテル硫酸エステル塩、ポリカルボン酸型高分子活性剤などのアニオン性界面活性剤；テトラアルキルアンモニウム塩、アルキルアミン、アルキルピリミジニウム塩などのカチオン性界面活性剤；アルキルベタイン、アルキルアミンオキシド、アルキルイミダゾリニウムベタイン、アミノ酸などの両性界面活性剤；更にはシリコーン系界面活性剤、フッ素系界面活性剤などを挙げることができる。なお、常温で液体の界面活性剤は、ホワイトカーボンや珪藻土などの固体担体に吸着して用いてもよい。 Examples of specific surfactants include polyethylene glycol higher fatty acid esters, polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene aryl phenyl ethers, sorbitan monoalkylates, acetylene alcohols and acetylenic diols and their Nonionic surfactants such as alkylene oxide adducts; alkylaryl sulfonates, dialkyl sulfonates, lignin sulfonates, naphthalene sulfonates and their condensates, alkyl sulfates, alkyl phosphates, alkylaryls Sulfate ester salt, alkylaryl phosphate ester salt, polyoxyethylene alkyl ether sulfate ester salt, polyoxyethylene alkyl aryl ether sulfate ester Anionic surfactants such as thiol salts, polyoxyethylene arylphenyl ether sulfates, polycarboxylic acid type polymer surfactants; cationic surfactants such as tetraalkylammonium salts, alkylamines, alkylpyrimidinium salts; Examples include amphoteric surfactants such as alkyl betaines, alkyl amine oxides, alkyl imidazolinium betaines, and amino acids; and silicone surfactants and fluorine surfactants. The surfactant that is liquid at room temperature may be adsorbed on a solid carrier such as white carbon or diatomaceous earth.
　上記の界面活性剤は単独で又は２種以上を混合して用いることができる。また、これらの界面活性剤の配合割合の合計は特に限定されないが、粒状農薬組成物全量基準で、通常０．１－１５質量％、好ましくは０．５－１２．５質量％、更に好ましくは１－１０質量％である。 The above surfactants can be used alone or in admixture of two or more. The total blending ratio of these surfactants is not particularly limited, but is usually 0.1-15% by mass, preferably 0.5-12.5% by mass, more preferably based on the total amount of the granular agrochemical composition. 1-10% by mass.
　本発明の粒状農薬組成物は、水面に浮遊することが必須である。粒状農薬組成物に水面浮遊性を付与する方法としては、例えば、真珠岩や黒曜石よりなるパーライト、シラスよりなる発泡シラス、アルミノシリケート系で焼成してなるフィライト、珪酸ソーダあるいは硼砂を発泡させたマイクロバルーン、軽石、粒状珪藻土、粒状活性炭、木粉、コルク粉、ケナフ片、フェノール樹脂よりなるフェノールマイクロバルーン、エポキシ樹脂よりなるエコスフェアー、ポリウレタン系樹脂よりなるポリウレタンフォーム、ポリアクリロニトリル系樹脂よりなるマイクロバルーン、火力発電時の灰として産出するフライアッシュなど、独立した１個又は複数個の気室を有する中空体を含有させる方法、ステアリン酸及びその塩、疎水性ホワイトカーボンなどの撥水性物質を含有させる方法が挙げられるが、前者の独立した１個又は複数個の気室を有する中空体を含有させる方法がより好ましく、該中空体としては熱可塑性高分子を壁材とするプラスチックマイクロバルーンが粒状組成物全量基準で５質量％未満の少量から粒状農薬組成物の水面浮遊性を担保でき、かつ、原料混練物を押し出し造粒する際の造粒性を改善する副次的効果も奏するという点で特に好ましい。 It is essential that the granular agricultural chemical composition of the present invention floats on the water surface. Examples of methods for imparting water surface floatability to granular agrochemical compositions include, for example, perlite made of pearlite or obsidian, foamed shirasu made of shirasu, phylite baked in an aluminosilicate system, sodium silicate or borax. Balloon, pumice, granular diatomaceous earth, granular activated carbon, wood powder, cork powder, kenaf pieces, phenol microballoon made of phenol resin, ecosphere made of epoxy resin, polyurethane foam made of polyurethane resin, microballoon made of polyacrylonitrile resin , A method of containing a hollow body having one or more independent air chambers, such as fly ash produced as ash during thermal power generation, and a water-repellent substance such as stearic acid and salts thereof, hydrophobic white carbon, etc. There is a method, but the former More preferably, a method of containing a standing hollow body having one or a plurality of air chambers is used, and as the hollow body, a plastic microballoon having a thermoplastic polymer as a wall material is less than 5% by mass based on the total amount of the granular composition. This is particularly preferable in that it can ensure the water surface floatability of the granular pesticide composition from a small amount and also has a secondary effect of improving the granulation property when the raw material kneaded product is extruded and granulated.
　前記プラスチックマイクロバルーンの壁材となる熱可塑性高分子としては、硬質又は軟質のポリ塩化ビニル、ポリ塩化ビニリデン又はポリビニルアルコールなどのビニル系高分子；ポリスチレン、高密度、中密度又は低密度のポリエチレン、エチレン／酢酸ビニル共重合体などのポリスチレン系高分子；非変性のポリプロピレン；単重合体又は共重合体のポリアセタール系高分子；ポリメチルメタクリレート、メタクリル／スチレン共重合体などのアクリル系高分子；酢酸セルロース；ポリカーボネート；ポリエチレンテレフタレートなどのポリエステル系高分子；ナイロン６、ナイロン６６などのポリアミド系高分子；熱可塑性ポリウレタン；三フッ化塩化エチレン、四フッ化エチレン、四フッ化エチレン／六フッ化プロピレン共重合体、四フッ化エチレン／パーフルオロアルコキシエチレン共重合体、四フッ化エチレン／エチレン共重合体、フッ化ビニリデンなどのフッ素系高分子なども挙げることができるが、モノマー単位としてアクリロニトリルを含有するポリアクリロニトリル又はポリアクリロニトリル系共重合体が好ましい。ポリアクリロニトリル系共重合体において、アクリルニトリルと共重合可能なモノマーとしては、（メタ）アクリル酸、（メタ）アクリル酸エステル、スチレン、酢酸ビニル、塩化ビニリデン等が例示でき、具体的には、スチレン／アクリロニトリル共重合体、スチレン／ブタジエン／アクリロニトリル共重合体、塩化ビニリデン／メタクリル酸メチル／アクリロニトリル共重合体、メタクリル酸メチル／アクリロニトリル／メタクリロニトリル共重合体、メタクリル酸メチル／アクリロニトリル共重合体、アクリロニトリル／メタクリロニトリル／イタコン酸共重合体等が挙げられる。これらのうち、農薬活性成分等の有機物に侵されにくいという点でメタクリル酸メチル／アクリロニトリル共重合体が好適である。 Examples of the thermoplastic polymer used as the wall material of the plastic microballoon include vinyl polymers such as hard or soft polyvinyl chloride, polyvinylidene chloride or polyvinyl alcohol; polystyrene, high density, medium density or low density polyethylene, Polystyrene polymers such as ethylene / vinyl acetate copolymers; non-modified polypropylene; polyacetal polymers of homopolymers or copolymers; acrylic polymers such as polymethyl methacrylate and methacryl / styrene copolymers; acetic acid Cellulose; Polycarbonate; Polyester polymer such as polyethylene terephthalate; Polyamide polymer such as nylon 6 and nylon 66; Thermoplastic polyurethane; Ethylene trifluoride, tetrafluoroethylene, tetrafluoroethylene / hexafluoropropylene Polymer Fluoropolymers such as tetrafluoroethylene / perfluoroalkoxyethylene copolymer, tetrafluoroethylene / ethylene copolymer, and vinylidene fluoride can also be mentioned, but polyacrylonitrile containing acrylonitrile as a monomer unit or Polyacrylonitrile copolymers are preferred. In the polyacrylonitrile copolymer, examples of the monomer copolymerizable with acrylonitrile include (meth) acrylic acid, (meth) acrylic acid ester, styrene, vinyl acetate, vinylidene chloride and the like. Specifically, styrene / Acrylonitrile copolymer, styrene / butadiene / acrylonitrile copolymer, vinylidene chloride / methyl methacrylate / acrylonitrile copolymer, methyl methacrylate / acrylonitrile / methacrylonitrile copolymer, methyl methacrylate / acrylonitrile copolymer, acrylonitrile / Methacrylonitrile / itaconic acid copolymer. Among these, a methyl methacrylate / acrylonitrile copolymer is preferable in that it is hardly affected by organic substances such as agrochemical active ingredients.
　ところで、プラスチックマイクロバルーンとは、熱可塑性高分子の膜材に低沸点炭化水素などの気体原を内包し、加熱処理により膜材を軟化させると同時に前記気体原を膨張させ、膜材内部を中空構造とした中空体である。したがって、プラスチックマイクロバルーン原料の態様としては、最終製品の製造工程中で加熱処理を行い膨張させることを想定した未膨張プラスチックマイクロバルーンも存在するが、本発明の製造方法に用いられるプラスチックマイクロバルーン原料は、その表面に鉱物質微粉を被覆して使用するものであるから、加熱処理済の既膨張プラスチックマイクロバルーンが適する。本発明の製造方法に用いられるプラスチックマイクロバルーンの好ましい平均粒子径は１－１００μｍであり、さらに好ましい平均粒子径は１０－７０μｍ、格別好ましい平均粒子径は２０－６０μｍである。プラスチックマイクロバルーンの平均粒子径が過小であると、プラスチックマイクロバルーンの表面を後記する適切な量の鉱物質微粉で被覆することが困難となり、一方で、プラスチックマイクロバルーンの平均粒子径が過大であると、膜材の強度が不足し、粒状農薬組成物の製造工程中において混練時や造粒時にかかる負荷に耐えられず、中空構造が破損する場合がある。 By the way, plastic micro-balloons contain a gas source such as low-boiling hydrocarbons in a thermoplastic polymer film material, soften the film material by heat treatment, and at the same time expand the gas source so that the inside of the film material is hollow. It is a hollow body having a structure. Therefore, as an aspect of the plastic microballoon raw material, there is an unexpanded plastic microballoon that is assumed to be inflated by heat treatment in the manufacturing process of the final product, but the plastic microballoon raw material used in the manufacturing method of the present invention Since the surface is used by coating the surface with mineral fine powder, a heat-treated already expanded plastic microballoon is suitable. The preferable average particle size of the plastic microballoon used in the production method of the present invention is 1-100 μm, more preferable average particle size is 10-70 μm, and particularly preferable average particle size is 20-60 μm. If the average particle size of the plastic microballoon is too small, it becomes difficult to coat the surface of the plastic microballoon with an appropriate amount of mineral fine powder described later, while the average particle size of the plastic microballoon is excessive. In addition, the strength of the membrane material is insufficient, and during the production process of the granular agrochemical composition, the load applied during kneading or granulation cannot be withstood, and the hollow structure may be damaged.
　本発明の製造方法では、中空体として、前記既膨張プラスチックマイクロバルーンの表面に鉱物質微粉が被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンを用いることを特徴とする。プラスチックマイクロバルーン表面の被覆に用いることができる好ましい鉱物質微粉としては、例えば、炭酸カルシウム、酸化チタン、タルクなどを挙げることができる。また、平均粒子径が０．１－１５μｍかつ前記プラスチックマイクロバルーンの平均粒子径の１／２以下である鉱物質微粉が好ましく、特に、平均粒子径が１－１２μｍかつ前記プラスチックマイクロバルーンの平均粒子径の２／５以下である鉱物質微粉が好ましい。 The production method of the present invention is characterized in that a mineral fine powder-coated expanded plastic microballoon in which the surface of the aforementioned expanded plastic microballoon is coated with a mineral powder is used as the hollow body. Preferable mineral fine powder that can be used for coating the surface of the plastic microballoon includes, for example, calcium carbonate, titanium oxide, talc and the like. Further, a fine mineral powder having an average particle size of 0.1-15 μm and ½ or less of the average particle size of the plastic microballoon is preferable, and in particular, an average particle size of 1-12 μm and an average particle of the plastic microballoon Mineral fine powder having a diameter of 2/5 or less is preferred.
　驚くべきことに、上記の如く鉱物質微粉で被覆された既膨張プラスチックマイクロバルーンは、その極めて小さな真比重にも拘らず、農薬活性成分、界面活性剤、固体担体などの粉体と速やかに混和する。したがって、本発明の製造方法によれば、短時間の混合工程で均質な原料混合物を得ることができるため、粒状農薬組成物の製造効率が顕著に向上するうえ、確実に水面に浮遊する品質良好な粒状農薬組成物を安定して製造することができる。転じて、本発明の製造方法によって製造された粒状農薬組成物は、確実に水面に浮遊する、品質良好なものとなる。また、鉱物質微粉で被覆されていないプラスチックマイクロバルーンを用いた場合においても、製造効率を犠牲にして長時間混合すれば原料混合物の均質化を図ることができるが、得られた粒状農薬組成物は、本発明のものと比べて、施用時に水面上で崩壊するまでに長時間要するものとなってしまう。本発明の粒状農薬組成物は、鉱物質微粉で被覆されていないプラスチックマイクロバルーンを用いたものと比較して崩壊性が向上し、例えば水面上での崩壊時間が１０％以上、より好ましくは２０％以上短縮され、散布時に圃場周辺の風による吹き寄せ等の影響を受けにくく、圃場中での成分偏在による薬害発生が生じにくいものである。 Surprisingly, the previously expanded plastic microballoons coated with mineral fine powder as described above are rapidly mixed with powders of agrochemical active ingredients, surfactants, solid carriers, etc., despite their extremely small true specific gravity. To do. Therefore, according to the production method of the present invention, since a homogeneous raw material mixture can be obtained in a short mixing step, the production efficiency of the granular agricultural chemical composition is remarkably improved, and the quality that is surely floating on the water surface is good. Can be produced stably. In turn, the granular agrochemical composition produced by the production method of the present invention reliably floats on the water surface and has good quality. Even when plastic microballoons not coated with mineral fine powder are used, the raw material mixture can be homogenized by mixing for a long time at the expense of production efficiency. Compared to the present invention, it takes a long time to collapse on the water surface during application. The granular agrochemical composition of the present invention has improved disintegration compared to that using a plastic microballoon that is not coated with mineral fine powder. For example, the disintegration time on the water surface is 10% or more, more preferably 20 %, And is less susceptible to wind blows around the field when sprayed, and is less likely to cause phytotoxicity due to uneven distribution of components in the field.
　鉱物質微粉被覆既膨張プラスチックマイクロバルーンは、マツモトマイクロスフェアーＭＦＬシリーズ（松本油脂製）などの市販品をそのまま用いてもよいし、鉱物質微粉で被覆されていない既膨張プラスチックマイクロバルーンと鉱物質微粉を混合することにより、鉱物質微粉で被覆された既膨張プラスチッマイクロクバルーンとすることもできる。又は、未膨張のプラスチックマイクロバルーン原料を加熱処理して既膨張プラスチックマイクロバルーンとした後、上記に準じて、鉱物質微粉で被覆された既膨張プラスチックマイクロバルーンを得ることもでき、未膨張のプラスチックマイクロバルーン原料と鉱物質微粉を混合し、得られた混合物を加熱処理して、前記未膨張のプラスチックマイクロバルーン原料を膨張させるとともに、得られる既膨張プラスチックマイクロバルーンの外表面に鉱物質微粉を付着させることもできる。いずれも、この被覆工程を自ら実施する場合は、未膨張のプラスチックマイクロバルーン原料または既膨張プラスチックマイクロバルーンと鉱物質微粉のみが存在する系で被覆処理を行うのがよい。これに反して、例えば、粒状農薬組成物の製造工程中で、鉱物質微粉で被覆されていない既膨張プラスチックマイクロバルーンと、鉱物質微粉と、その他粒状農薬組成物を構成する全原料を混合しても、鉱物質微粉がプラスチックマイクロバルーンの表面に選択的に付着することはなく、原料混合物中に分散してしまうため、本発明の効果を奏することはない。
　なお、本発明において、「被覆」とは、既膨張プラスチックマイクロバルーン表面の全部または一部に鉱物質微粉が付着した状態を意味する。 As the pre-expanded plastic microballoon coated with mineral fine powder, commercially available products such as Matsumoto Microsphere MFL series (made by Matsumoto Yushi) may be used as they are, or the pre-expanded plastic microballoon not covered with mineral fine powder and mineral By mixing the fine powder, an already expanded plastic microballoon covered with the fine mineral powder can be obtained. Alternatively, after heat-treating an unexpanded plastic microballoon raw material into an expanded plastic microballoon, an expanded plastic microballoon covered with mineral fine powder can be obtained according to the above, and the unexpanded plastic Microballoon raw material and mineral fine powder are mixed, and the resulting mixture is heated to expand the unexpanded plastic microballoon raw material, and the fine powder is attached to the outer surface of the obtained expanded plastic microballoon. It can also be made. In any case, when this coating step is carried out by itself, it is preferable to perform the coating process in a system in which only the unexpanded plastic microballoon raw material or the already expanded plastic microballoon and the mineral fine powder exist. On the other hand, for example, in the manufacturing process of the granular pesticide composition, the expanded plastic microballoon not covered with the mineral fine powder, the mineral fine powder, and all the other raw materials constituting the granular pesticide composition are mixed. However, since the mineral fine powder does not selectively adhere to the surface of the plastic microballoon and is dispersed in the raw material mixture, the effect of the present invention is not exhibited.
In the present invention, “coating” means a state in which mineral fine powder is adhered to all or a part of the surface of an already expanded plastic microballoon.
　前記鉱物質微粉のプラスチックマイクロバルーンに対する被覆量は特に限定されないが、鉱物質微粉被覆既膨張プラスチックマイクロバルーンの全量基準で、プラスチックマイクロバルーンの表面から鉱物質微粉を除いたプラスチックマイクロバルーンの重量が５－２０質量％であるのが好ましい。前記鉱物質微粉被覆既膨張プラスチックマイクロバルーンの表面から鉱物質微粉を取り除く方法としては、例えば、鉱物質微粉被覆既膨張プラスチックマイクロバルーンを水に分散し、比重の違いを利用して鉱物質微粉だけを沈降させて取り除いた後、乾燥して水分を除去する手段を例示することができる。 The coating amount of the mineral fine powder on the plastic microballoon is not particularly limited, but the weight of the plastic microballoon obtained by removing the mineral fine powder from the surface of the plastic microballoon is 5 on the basis of the total amount of the mineral fine powder-coated inflated plastic microballoon. It is preferably −20% by mass. As a method for removing mineral fine powder from the surface of the mineral powder-covered pre-expanded plastic microballoon, for example, the mineral fine powder-covered pre-expanded plastic microballoon is dispersed in water and only the mineral fine powder is utilized by utilizing the difference in specific gravity. Examples of the means for removing the moisture after settling and removing the water can be exemplified.
　本発明の製造方法に用いられる鉱物質微粉被覆既膨張プラスチックマイクロバルーンは、微量の水分を含有してもよいが、過剰の水分は鉱物質微粉被覆既膨張プラスチックマイクロバルーン同士を凝集させる粘結剤として機能してしまい、他の原料との混合工程において鉱物質微粉被覆既膨張プラスチックマイクロバルーンの速やかな混和を妨げる場合がある。前記鉱物質微粉被覆既膨張プラスチックマイクロバルーンの好ましい水分含量は５質量％以下、特に好ましい水分含量は３質量％以下である。 Mineral fine powder-coated expanded plastic microballoons used in the production method of the present invention may contain a small amount of moisture, but excess moisture is a binder that aggregates mineral fine powder-coated expanded plastic microballoons. In the mixing step with other raw materials, it may interfere with the rapid mixing of the mineral fine powder-coated expanded plastic microballoons. The water content of the mineral fine powder-coated expanded plastic microballoon is preferably 5% by mass or less, and particularly preferably 3% by mass or less.
　本発明の製造方法は、鉱物質微粉被覆既膨張プラスチックマイクロバルーンと併用して、鉱物質微粉で被覆されていないプラスチックマイクロバルーンやプラスチックマイクロバルーン以外の中空体（以下、総称してその他の中空体という）を同時に配合することを排除するものではなく、かような製造方法、及び、そのようにして得られた粒状農薬組成物も本発明に包含される。但し、その他の中空体を併用する場合であっても、大半の中空体は鉱物質微粉被覆既膨張プラスチックマイクロバルーンとするのが好ましい。具体的には、鉱物質微粉やその他の添加物を除いた中空体本体としての全量基準で、鉱物質微粉被覆既膨張プラスチックマイクロバルーンが５０質量％以上、好ましくは７０質量％以上、さらに好ましくは９０質量％以上とするのがよい。 The production method of the present invention is used in combination with a mineral fine powder-coated expanded plastic microballoon, and is a hollow body other than a plastic microballoon or plastic microballoon that is not coated with a mineral fine powder (hereinafter collectively referred to as other hollow bodies). Are not excluded at the same time, and such a production method and the granular agrochemical composition thus obtained are also included in the present invention. However, even when other hollow bodies are used in combination, most of the hollow bodies are preferably made of mineral fine powder-coated expanded plastic microballoons. Specifically, based on the total amount of the hollow body main body excluding mineral fine powder and other additives, the mineral fine powder-coated expanded plastic microballoon is 50% by mass or more, preferably 70% by mass or more, more preferably It is good to set it as 90 mass% or more.
　また、これらの中空体の配合量は、中空体本体の総量として粒状農薬組成物が水面浮遊性を得る量であるならば特に限定はされないが、必要以上に配合すると脆い粒となり、保管中や輸送時又は使用時に潰れたり、製造時の粉塵発生量が多くなるなど好ましくない場合があるため、必要最少量を配合するのが望ましい。このため、中空体本体の配合量の上限は、粒状農薬組成物全量基準で一般に３０質量％程度までであり、好ましくは１５質量％以下、更に好ましくは５質量％以下とするのがよい。中空体がプラスチックマイクロバルーンである場合、プラスチックマイクロバルーン本体として５質量％以下の配合量でも組成物は水面浮遊性を得ることができる。また、下限は０．３質量％であり、０．５質量％以上であることが好ましい。０．３質量％未満の配合割合では組成物が水面浮遊性を示さない場合がある。 The amount of these hollow bodies to be blended is not particularly limited as long as the total amount of the hollow body is such that the granular agrochemical composition obtains water surface floatability. Since it may be unfavorable, for example, it may be crushed during transportation or use, or the amount of dust generated during production may be increased, it is desirable to add the minimum amount necessary. For this reason, the upper limit of the blending amount of the hollow body is generally up to about 30% by mass, preferably 15% by mass or less, more preferably 5% by mass or less, based on the total amount of the granular agricultural chemical composition. When the hollow body is a plastic microballoon, the composition can obtain water surface floatability even with a blending amount of 5% by mass or less as the plastic microballoon body. Moreover, a minimum is 0.3 mass%, and it is preferable that it is 0.5 mass% or more. If the blending ratio is less than 0.3% by mass, the composition may not exhibit water surface floatability.
　また、本発明の粒状農薬組成物において、前記の中空体の効果を高めるために、組成物中に微量の水を含有することが望ましい。この水の含有量は特に制限されるものではないが、粒状農薬組成物全量基準で、通常０．３－３質量％程度、好ましくは０．３－１．５質量％程度である。水が０．３質量％以下の場合には、組成物内部に水が浸入しやすい構造となるため、水に組成物を投入すると、一旦は水面に浮遊するが、その後組成物内部の空気が抜けて沈降する場合があり、必要以上に前出の浮遊性担体を含有させなければならず、好ましくない場合がある。また、水が３質量％以上の場合、粒状物同士が癒着してばらまき散布を困難にしたり、組成物が脆くなり散布時に微粉が発生するなどの問題を生じることがあるため、好ましくない場合がある。 Moreover, in the granular agrochemical composition of the present invention, it is desirable to contain a trace amount of water in the composition in order to enhance the effect of the hollow body. The water content is not particularly limited, but is usually about 0.3 to 3% by mass, preferably about 0.3 to 1.5% by mass, based on the total amount of the granular agrochemical composition. When water is 0.3% by mass or less, the structure allows water to easily enter the composition. Therefore, when the composition is poured into water, it floats once on the surface of the water, but then the air inside the composition In some cases, it may fall out and settle, and the above-mentioned floating carrier must be contained more than necessary, which may be undesirable. In addition, when the water content is 3% by mass or more, it may be unfavorable because the particles may adhere to each other, making it difficult to disperse and making the composition brittle and generating fine powder during application. is there.
　本発明の粒状農薬組成物において、所定量の水を含有させる方法としては、一旦組成物を完全に乾燥させた後、噴霧して加える方法もあるが、通常は、水分含有量を測定しながら乾燥し、所定量の水分含有量となった時点で乾燥を終了させればよい。なお、本発明の粒状農薬組成物中の水の含有量は、例えばカールフィッシャー方式の水分測定装置や赤外線水分測定装置などを用いて測定することができる。 In the granular agrochemical composition of the present invention, as a method of containing a predetermined amount of water, there is also a method of adding the composition by spraying after completely drying the composition, but usually while measuring the water content What is necessary is just to complete | finish drying when it dries and it becomes moisture content of a predetermined amount. The water content in the granular agrochemical composition of the present invention can be measured using, for example, a Karl Fischer moisture measuring device or an infrared moisture measuring device.
　更に、本発明の粒状農薬組成物においては、固体担体が配合される。固体担体としては、水溶性担体あるいは非水溶性担体を用いることができ、これらを組み合わせて用いることもできる。水溶性担体は、例えば、硫酸アンモニウム、重炭酸アンモニウム、硝酸アンモニウム、塩化アンモニウム、塩化カリウム、硫酸ナトリウム、硫酸マグネシウム、クエン酸ナトリウム、炭酸ナトリウム、炭酸水素ナトリウムなどの有機又は無機酸塩類、クエン酸、コハク酸などの有機酸類、蔗糖、ラクトースなどの糖類、尿素などを挙げることができる。また、非水溶性担体は一般的には鉱物質微粉が用いられ、例えば、クレー類、炭酸カルシウム、ベントナイト、タルク、珪藻土、ステアリン酸カルシウム、ホワイトカーボンなどを挙げることができる。 Furthermore, in the granular agrochemical composition of the present invention, a solid carrier is blended. As the solid carrier, a water-soluble carrier or a water-insoluble carrier can be used, and these can be used in combination. Water-soluble carriers include, for example, organic or inorganic acid salts such as ammonium sulfate, ammonium bicarbonate, ammonium nitrate, ammonium chloride, potassium chloride, sodium sulfate, magnesium sulfate, sodium citrate, sodium carbonate, sodium bicarbonate, citric acid, succinic acid Organic acids such as sucrose, saccharides such as lactose, urea and the like. Mineral fine powder is generally used as the water-insoluble carrier, and examples thereof include clays, calcium carbonate, bentonite, talc, diatomaceous earth, calcium stearate, and white carbon.
　前記固体担体は単独で又は２種以上を混合して用いることができる。また、これらの固体担体の配合割合の合計は特に限定されないが、粒状農薬組成物全量基準で、通常０．１－９９．２質量％、好ましくは１０－７０質量％である。 The solid carriers can be used alone or in admixture of two or more. The total blending ratio of these solid carriers is not particularly limited, but is usually 0.1-99.2% by mass, preferably 10-70% by mass, based on the total amount of the granular agricultural chemical composition.
　本発明の粒状農薬組成物においては、その他の成分として、必要により補助剤が配合される。この任意成分である補助剤の例としては、結合剤、崩壊剤、農薬活性成分の分解防止剤などを挙げることができる。 In the granular agrochemical composition of the present invention, an auxiliary agent is blended as necessary as other components. Examples of the auxiliary agent which is an optional component include a binder, a disintegrant, and an agrochemical active ingredient decomposition inhibitor.
　結合剤の具体的な例としては、カルボキシメチルセルロースナトリウム塩、デキストリン、水溶性デンプン、キサンタンガム、グアシードガム、蔗糖、ポリビニルピロリドン、ポリビニルアルコール、ポリアクリル酸ナトリウム塩、平均分子量６０００－５００万のポリオキシエチレンなどを挙げることができる。 Specific examples of the binder include carboxymethylcellulose sodium salt, dextrin, water-soluble starch, xanthan gum, guar seed gum, sucrose, polyvinylpyrrolidone, polyvinyl alcohol, polyacrylic acid sodium salt, polyoxyethylene having an average molecular weight of 6,000 to 5 million, and the like. Can be mentioned.
　崩壊剤の具体的な例としては、トリポリリン酸ナトリウム、ヘキサメタリン酸ナトリウム、ステアリン酸金属塩、セルロース粉末、デキストリン、メタクリル酸エステル系共重合体、ポリビニルピロリドン、ポリアミノカルボン酸キレート化合物、スルホン化スチレン・イソブチレン・無水マレイン酸共重合体、デンプン・ポリアクリロニトリルグラフト共重合体などを挙げることができる。 Specific examples of disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylate copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene -Maleic anhydride copolymer, starch-polyacrylonitrile graft copolymer, etc. can be mentioned.
　分解防止剤の具体的な例としては、ゼオライト、生石灰、酸化マグネシウムのような乾燥剤、フェノール化合物、アミン化合物、硫黄化合物、リン酸化合物等の酸化防止剤、サリチル酸化合物、ベンゾフェノン化合物等の紫外線吸収剤等が挙げられる。 Specific examples of the decomposition inhibitor include desiccants such as zeolite, quicklime and magnesium oxide, antioxidants such as phenol compounds, amine compounds, sulfur compounds and phosphate compounds, UV absorption of salicylic acid compounds and benzophenone compounds. Agents and the like.
　前記補助剤は単独で又は２種以上を混合して用いることができる。また、これらの補助剤を配合する場合、補助剤の配合割合の合計は、粒状農薬組成物全量基準で、通常０．０１－１０質量％、好ましくは０．１－６質量％である。 The adjuvants can be used alone or in admixture of two or more. When these adjuvants are blended, the total blending ratio of the adjuvants is usually 0.01-10% by mass, preferably 0.1-6% by mass, based on the total amount of the granular agrochemical composition.
　更にまた、本発明の粒状農薬組成物においては、農薬活性成分を溶解あるいは分散する場合に有機溶剤を用いてもよい。この有機溶剤としては、例えば、ジオクチルフタレート、メチルナフタレン、アルキルピロリドン、フェニルキシリルエタン、グリセリン、アルキレングリコール、マシン油、メタン列炭化水素、脂肪酸エステル、多塩基酸、ヤシ油、大豆油、ナタネ油、シリコーンオイルなどを用いることができるが、高沸点溶剤が好ましい。 Furthermore, in the granular agrochemical composition of the present invention, an organic solvent may be used when the agrochemical active ingredient is dissolved or dispersed. Examples of the organic solvent include dioctyl phthalate, methyl naphthalene, alkyl pyrrolidone, phenyl xylyl ethane, glycerin, alkylene glycol, machine oil, methane series hydrocarbon, fatty acid ester, polybasic acid, coconut oil, soybean oil, rapeseed oil. Silicone oil or the like can be used, but a high boiling point solvent is preferable.
　前記有機溶剤は単独で又は２種以上を混合して用いることができる。これら有機溶剤を配合する場合、有機溶剤の配合割合の合計は、農薬活性成分１００重量部に対して、通常１０－２００重量部である。 The organic solvents can be used alone or in admixture of two or more. When these organic solvents are blended, the total blending ratio of the organic solvents is usually 10 to 200 parts by weight with respect to 100 parts by weight of the pesticidal active ingredient.
　本発明の粒状農薬組成物は、通常、以上説明してきた成分を含有して成る水面に浮遊する粒状組成物であるが、前述の各成分及び配合量は、粒径を３ｍｍ以上の組成物とした際、崩壊時間が３０分以内に、好ましくは２０分以内になるように調整される。崩壊時間が３０分を越える場合、風で組成物が吹き寄せられるため好ましくない。更に吹き寄せの影響を小さくするためには、組成物が水面に浮遊した際、水面上に露出した部分が、組成物全体の４０％以下、望ましくは２０％以下となる様に、上記の各成分の配合量を調整するのが望ましい。 The granular agrochemical composition of the present invention is usually a granular composition that floats on the water surface containing the components described above, but each of the aforementioned components and blending amounts is a composition having a particle size of 3 mm or more. The disintegration time is adjusted to be within 30 minutes, preferably within 20 minutes. When the disintegration time exceeds 30 minutes, the composition is blown by the wind, which is not preferable. In order to further reduce the influence of blowing, each of the above components is such that when the composition floats on the water surface, the portion exposed on the water surface is 40% or less, preferably 20% or less of the entire composition. It is desirable to adjust the blending amount.
　鉱物質微粉被覆既膨張プラスチックマイクロバルーンを中空体として採用する点を除けば、本発明の粒状農薬組成物の製造工程そのものは、公知の方法に従う。すなわち、
（ａ）粒状農薬組成物を構成する全原料を混合し混合物を得るステップと；
（ｂ）前記（ａ）のステップで得られた混合物に所定量の水を加えて混合物を混練するステップと；
（ｃ）前記（ｂ）のステップで得られた混練物を、押し出し造粒機を用いて孔径３ｍｍ以上のスクリーンから排出して造粒するステップと；
（ｄ）前記（ｃ）のステップで得られた造粒物を乾燥するステップ；
を経ることにより、本発明の粒状農薬組成物を得ることができる。 The manufacturing process itself of the granular agrochemical composition of the present invention is in accordance with a publicly known method except that a mineral fine powder-coated expanded plastic microballoon is employed as a hollow body. That is,
(A) mixing all the raw materials constituting the granular agrochemical composition to obtain a mixture;
(B) adding a predetermined amount of water to the mixture obtained in the step (a) and kneading the mixture;
(C) discharging and granulating the kneaded product obtained in the step (b) from a screen having a pore diameter of 3 mm or more using an extrusion granulator;
(D) drying the granulated product obtained in the step (c);
The granular agrochemical composition of this invention can be obtained by passing through.
　ステップ（ａ）では、農薬活性成分、界面活性剤、鉱物質微粉被覆既膨張プラスチックマイクロバルーン及び固体担体を含む、粒状農薬組成物を構成する全原料を混合する。混合にあたっては、ナウタミキサー、バーチカルミキサーなど公知の混合機を用いることができる。この混合に要する時間は、混合機の性能やバッチスケールにもよるが、通常３０秒－３分間程度である。 In step (a), all raw materials constituting the granular agrochemical composition including the agrochemical active ingredient, surfactant, mineral fine powder-coated expanded plastic microballoon and solid carrier are mixed. For mixing, a known mixer such as a Nauta mixer or a vertical mixer can be used. The time required for this mixing is usually about 30 seconds to 3 minutes, depending on the performance of the mixer and the batch scale.
　次に、前記により得られた混合物に、水を加えて混練する（ステップ（ｂ））。混練にあたっては、ニーダー、リボンミキサー、バーチカルミキサーなど公知の混練機を用いることができる。添加する水の量は特に限定されるものではないが、混合物中に、通常１０－１５質量％程度を外割で添加すればよい。この混合物を前記混練機中で所定時間混練することにより混練物を得る。 Next, water is added to the mixture obtained as described above and kneaded (step (b)). In kneading, a known kneader such as a kneader, a ribbon mixer, or a vertical mixer can be used. The amount of water to be added is not particularly limited, but about 10-15% by mass is usually added to the mixture in an external ratio. This mixture is kneaded in the kneader for a predetermined time to obtain a kneaded product.
　この混練物を、押し出し造粒機を用いて孔径３ｍｍ以上、好ましくは３－１０ｍｍのスクリーンから排出して造粒し（ステップ（ｃ））、次いで得られた造粒物を乾燥する（ステップ（ｄ））。また、造粒物を乾燥する際の乾燥温度は、特に限定されるものではないが、４０－９５℃程度である。 This kneaded product is discharged from a screen having a pore diameter of 3 mm or more, preferably 3-10 mm, using an extrusion granulator and granulated (step (c)), and then the obtained granulated product is dried (step (c) d)). Further, the drying temperature when the granulated product is dried is not particularly limited, but is about 40 to 95 ° C.
　本発明の粒状農薬組成物の好ましい組成物例としては、例えば、成分として水面施用効果のある有効成分を含有し、その粒径が３－８ｍｍ、比重が０．３－１であり、水面に散布した後、５－２０分で崩壊するものが挙げられる。 Preferred examples of the composition of the granular agrochemical composition of the present invention include, for example, an active ingredient having a water surface application effect as a component, and its particle size is 3-8 mm and the specific gravity is 0.3-1. Examples include those that disintegrate in 5-20 minutes after spraying.
　本発明の粒状農薬組成物は、粒径が３ｍｍ以上のものをより多く含むこと、すなわち粒径３ｍｍ以上の粒子が８０％以上である粒度分布を有することが必須要件であり、更に粒径３－１０ｍｍの粒子が８０％以上であること、特に３－８ｍｍの粒子が８０％以上であることがより好ましい。製剤を上記の粒度分布とすることで、畦畔から散布した場合でも、畦畔から１ｍ以上の距離に、全水田面積の５－５０％の散布面積を容易に得ることが可能となる。なお、粒径を３ｍｍ以上とする副次的な効果としては、通常粒径０．８ｍｍ前後の粒子を多く含む水稲育苗箱施用粒剤と容易に判別ができるため、誤用を防止することが可能である点を挙げることができる。もし仮に水稲育苗箱に処理した後、誤用に気付いた場合でも、育苗箱ごと水につけることで本発明の製剤のみ水面に浮上するため、誤用の被害を最小限とすることも可能である。 The granular agrochemical composition of the present invention is required to contain more particles having a particle size of 3 mm or more, that is, to have a particle size distribution in which particles having a particle size of 3 mm or more are 80% or more. More preferably, the particle size of −10 mm is 80% or more, and in particular, the particle size of 3-8 mm is 80% or more. By making the preparation have the above particle size distribution, even when sprayed from the shore, it is possible to easily obtain a spray area of 5-50% of the total paddy area at a distance of 1 m or more from the shore. As a secondary effect of making the particle size 3 mm or more, misuse can be prevented because it can be easily discriminated from the granule for paddy rice seedling box containing many particles having a particle size of usually about 0.8 mm. Can be mentioned. Even if a misuse is noticed after treating the paddy rice seedling box, only the preparation of the present invention floats on the surface of the water by putting the whole seedling box in water, so that the damage of misuse can be minimized.
　以上説明した本発明の粒状農薬組成物を、水田などの水面に散布する方法としては特に制約はないが、例えば、ビニール手袋を着用した手で組成物を握って投げる方法、動力散布機を用い、連続的に噴頭から吐出させて散布する方法、あるいはシャッターレバーを瞬間的に開閉し、断続的に吐出させて散布する方法、柄杓を用いて投込む方法、筒状の容器を振って投げ入れる方法、手回し式散粒機を用いる方法、更にはラジコンヘリを用いて筋状に、あるいはスポット的に散布する方法が挙げられる。あるいは、得られた粒状農薬組成物の所定量をポリビニルアルコールなどの水溶性フィルムで包装し、いわゆるジャンボ剤の形態として、該包装体ごと水田などに投入してもよい。 There are no particular restrictions on the method for spraying the granular agrochemical composition of the present invention described above on the surface of water such as paddy fields.For example, a method of holding and throwing the composition with a hand wearing vinyl gloves, using a power spreader , A method of continuously discharging and spraying from the nozzle, or a method of intermittently discharging and spraying by opening and closing the shutter lever, a method of throwing using a handle, and a method of throwing and throwing a cylindrical container , A method using a hand-pulverized granulator, and a method of spraying in a streak-like manner or a spot using a radio control helicopter. Alternatively, a predetermined amount of the obtained granular agricultural chemical composition may be packaged with a water-soluble film such as polyvinyl alcohol, and the packaged body may be put into a paddy field or the like as a so-called jumbo agent.
　従来、水田における稲作において、移植時期が早い所謂早期栽培の場合は、移植後１－２週間の期間内に水面浮遊性の粒状農薬組成物を局所的に散布しても、水田に藻類の発生はほとんどなく、農薬活性成分の拡散性は良好であり、所期の効果が得られる。しかし、移植時期が５月以降となる所謂普通期栽培においては、水温が上昇し、農薬散布の適期には藻類が発生することが一般的であり、この藻類が農薬活性成分の拡散を著しく阻害するため、所期の農薬の効果が得られないことが多い。特に、藻類が風で吹き寄せられた水田に、水面浮遊性の粒状農薬組成物を局所的に散布した場合、藻類が吹き寄せられた部分は、ほとんど農薬の効果が得られないのが実情である。また、移植数週間後、水稲の生育が進み、株が大きくなった後に水面浮遊性の農薬組成物を局所的に散布した場合においても、農薬活性成分の拡散が妨げられてしまう。このように、局所的散布が前提となる省力散布組成物は、稲株が小さな時に散布される組成物であった。 Conventionally, in rice cultivation in paddy fields, in the case of so-called early cultivation, algae is generated in paddy fields even if the surface floating granular agricultural chemical composition is locally sprayed within 1-2 weeks after transplanting. There is almost no diffusibility of the pesticidal active ingredient, and the desired effect can be obtained. However, in so-called normal season cultivation after May, the water temperature rises and algae are generally generated at the appropriate time for spraying pesticides. This algae significantly inhibits the spread of pesticide active ingredients. Therefore, the desired effect of agricultural chemicals is often not obtained. In particular, when a water-floating granular pesticide composition is locally sprayed on a paddy field where algae are blown by wind, the portion where the algae is blown hardly obtains the effect of the pesticide. In addition, even when a rice-floating pesticide composition is locally sprayed after several weeks after transplantation, the growth of paddy rice progresses and the strain grows, diffusion of the pesticide active ingredient is hindered. Thus, the labor-saving spraying composition on which local spraying is a premise was a composition sprayed when rice plants are small.
　これに対し、本発明の粒状農薬組成物は、藻類が発生した水田において、あるいは、ある程度稲株が成育した水田においても、農薬活性成分の拡散が良好で、所期の農薬の効果が得られる水面浮遊性の粒状農薬組成物ということができ、このものを水田の特定の位置に、且つ特定の面積内に散布することで、農薬散布時の省力性をほとんど妨げることなく農薬活性成分の均一散布を可能とすることができるものである。即ち、本発明の粒径が３ｍｍ以上のものが８０％以上で、水面に浮遊し、かつ３０分以内に水面で崩壊する拡散性粒状農薬組成物は、湛水下の水田の畦畔から１ｍ以上の距離に、好ましくは畦畔から２ｍ以上の距離に、全水田面積の５－５０％の面積、好ましくは１０－５０％にばら撒いて散布することにより、水田中に均一に農薬活性成分を散布することができる。 On the other hand, the granular pesticide composition of the present invention has good diffusion of the pesticide active ingredient in the paddy field where algae is generated, or in the paddy field where rice plants have grown to some extent, and the desired pesticide effect can be obtained. It can be said that it is a water-floating granular pesticide composition, and by spraying this to a specific position in a paddy field and within a specific area, it is possible to achieve a uniform pesticide active ingredient with almost no hindrance to labor saving when spraying pesticides. It can be spread. That is, the diffusible granular pesticide composition having a particle size of 3 mm or more according to the present invention is 80% or more, floats on the water surface, and disintegrates on the water surface within 30 minutes. By spraying over the above distance, preferably at a distance of 2 m or more from the shore, 5-50% of the total paddy area, preferably 10-50%, it is uniformly distributed in the paddy field. Can be sprayed.
　なお、本発明の粒状農薬組成物を全水田面積の５０％以上に散布しても何ら問題はないが、省力的な農薬散布という目的からは無意味であり、５０％以下の面積に散布するのが望ましい。更に、当然のことながら、藻類の発生がない水田、移植前の水田、稲株が小さな水田においても、本発明の粒状農薬組成物による農薬活性成分の拡散は良好であり、所期の農薬の効果が得られるものである。 In addition, although there is no problem even if the granular pesticide composition of the present invention is sprayed over 50% or more of the total paddy field area, it is meaningless for the purpose of labor-saving pesticide spraying, and sprayed over an area of 50% or less. Is desirable. Furthermore, naturally, even in a paddy field free from algae, a paddy field before transplanting, or a paddy field with a small rice stock, the diffusion of the pesticidal active ingredient by the granular pesticide composition of the present invention is good, and An effect is obtained.
　以下、本発明を実施例にて詳細に説明するが、本発明はこれら実施例に何ら制約されるものではない。なお、以下の実施例において、部は重量部を表す。 Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples. In the following examples, parts represent parts by weight.
［実施例１］
　カフェンストロール３部、ベンゾビシクロン８部、ベンスルフロン・メチル３部、ジアルキルアリールスルホン酸塩３．５部、無水硫酸ナトリウム１．５部、ポリオキシアルキレンアルキニルグリコールエーテル２部、変性デキストリン２部、平均粒子径１１μｍの炭酸カルシウムで表面被覆した塩化ビニリデン／アクリロニトリル系共重合体を壁材とする平均粒子径４１μｍの既膨張プラスチックマイクロバルーン１３部（プラスチックマイクロバルーンとして１．９５部、炭酸カルシウムとして１１．０５部）、珪藻土３部、尿素２０部及び平均粒子径３０μｍの炭酸カルシウム４１部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、カフェンストロールを３質量％、ベンゾビシクロンを８質量％、ベンスルフロン・メチルを３質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 1]
Caffeanthrol 3 parts, benzobicyclone 8 parts, bensulfuron methyl 3 parts, dialkylaryl sulfonate 3.5 parts, anhydrous sodium sulfate 1.5 parts, polyoxyalkylene alkynyl glycol ether 2 parts, modified dextrin 2 parts, average 13 parts of an already inflated plastic microballoon having an average particle diameter of 41 μm using a vinylidene chloride / acrylonitrile copolymer surface-coated with calcium carbonate having a particle diameter of 11 μm as a wall material (1.95 parts as a plastic microballoon and 11.95 as calcium carbonate). 05 parts), 3 parts of diatomaceous earth, 20 parts of urea and 41 parts of calcium carbonate having an average particle diameter of 30 μm were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 3% by mass, 8% by mass of benzobicyclone and 3% by mass of bensulfuron methyl was obtained.
［実施例２］
　ピリミノバック・メチル１．２部、ピラゾスルフロン・エチル０．８４部、ブロモブチド３６部、ポリオキシエチレンアリールフェニルエーテル硫酸塩１部、ポリオキシエチレンアルキルエーテル１部、アルキルアリールスルホン酸塩ホルマリン縮合物５部、アルキルアリールスルホン酸塩５部、ポリオキシアルキレンアルキニルグリコールエーテル１．５部、平均粒子径１１μｍの炭酸カルシウムで表面被覆した塩化ビニリデン／アクリロニトリル系共重合体を壁材とする平均粒子径４１μｍの既膨張プラスチックマイクロバルーン１０部（プラスチックマイクロバルーンとして１．５部、炭酸カルシウムとして８．５部）、塩化ビニリデン／アクリロニトリル系共重合体を壁材とする平均粒子径４１μｍの既膨張プラスチックマイクロバルーンの８５％含水物１０部（プラスチックマイクロバルーンとして１．５部、水として８．５部）、尿素２０部及び平均粒子径３０μｍの炭酸カルシウム１６．９６部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６５℃で乾燥して、ピリミノバック・メチルを１．２質量％、ピラゾスルフロン・エチルを０．８４質量％、ブロモブチドを３６質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 2]
Pyriminobac methyl 1.2 parts, pyrazosulfuron ethyl 0.84 parts, bromobutide 36 parts, polyoxyethylene arylphenyl ether sulfate 1 part, polyoxyethylene alkyl ether 1 part, alkylaryl sulfonate formalin condensate 5 parts, Alkyl aryl sulfonate 5 parts, polyoxyalkylene alkynyl glycol ether 1.5 parts, vinylidene chloride / acrylonitrile copolymer coated on the surface with calcium carbonate having an average particle diameter of 11 μm as a wall material having an average particle diameter of 41 μm 10 parts of plastic microballoons (1.5 parts as plastic microballoons, 8.5 parts as calcium carbonate), pre-expanded plastic microballs having an average particle diameter of 41 μm using vinylidene chloride / acrylonitrile copolymer as a wall material 10 parts of water containing 85% water (1.5 parts as a plastic microballoon, 8.5 parts as water), 20 parts of urea and 16.96 parts of calcium carbonate with an average particle size of 30 μm were weighed, and 60 seconds with a vertical mixer. Mixed. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press granulator, and the granulated product is dried at 65 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 1.2% by mass of methyl, 0.84% by mass of pyrazosulfuron / ethyl and 36% by mass of bromobutide was obtained.
［実施例３］
　ピリミスルファン２部、ピラクロニル６部、フェノキサスルホン６部、ジアルキルアリールスルホン酸塩１．６５部、無水硫酸ナトリウム０．７部、ポリアクリル酸塩４部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１部、ポリプロピレングリコール２部、平均粒子径１１μｍの炭酸カルシウムで表面被覆した塩化ビニリデン／アクリロニトリル系高分子を壁材とする平均粒子径４１μｍの既膨張プラスチックマイクロバルーン１３部（プラスチックマイクロバルーンとして１．９５部、炭酸カルシウムとして１１．０５部）、珪藻土１５部、ベントナイト５部、クレー３７．６５部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、ピラクロニルを６質量％、フェノキサスルホンを６質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 3]
2 parts of pyrimylsulfan, 6 parts of pyraclonyl, 6 parts of phenoxasulfone, 1.65 parts of dialkylaryl sulfonate, 0.7 parts of anhydrous sodium sulfate, 4 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphate-crosslinked starch 5 parts, 1 part of polyoxyalkylene alkynyl glycol ether, 2 parts of polypropylene glycol, pre-expanded plastic microballoon with an average particle diameter of 41 μm using vinylidene chloride / acrylonitrile polymer coated on the surface with calcium carbonate having an average particle diameter of 11 μm as a wall material 13 parts (1.95 parts as a plastic microballoon, 11.05 parts as calcium carbonate), 15 parts of diatomaceous earth, 5 parts of bentonite and 37.65 parts of clay were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of fan, 6% by mass of pyraclonyl and 6% by mass of phenoxasulfone was obtained.
［実施例４］
　ピリミスルファン２部、ベンゾビシクロン１２部、フェノキサスルホン８部、ジアルキルアリールスルホン酸塩２．１部、無水硫酸ナトリウム０．９部、ポリアクリル酸塩２部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１．５部、ポリプロピレングリコール３部、平均粒子径１０μｍの炭酸カルシウムで表面被覆したメタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径２８μｍの既膨張プラスチックマイクロバルーン９部（プラスチックマイクロバルーンとして１．８部、炭酸カルシウムとして７．２部）、珪藻土１５部、ベントナイト５部、クレー３３．５部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、ベンゾビシクロンを１２質量％、フェノキサスルホンを８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 4]
2 parts of pyrimisulphan, 12 parts of benzobicyclone, 8 parts of phenoxasulfone, 2.1 parts of dialkylaryl sulfonate, 0.9 parts of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphoric acid 5 parts of cross-linked starch, 1.5 parts of polyoxyalkylene alkynyl glycol ether, 3 parts of polypropylene glycol, and an average particle diameter of 28 μm having a wall material of methyl methacrylate / acrylonitrile polymer coated with calcium carbonate having an average particle diameter of 10 μm 9 parts of pre-expanded plastic microballoon (1.8 parts as plastic microballoon, 7.2 parts as calcium carbonate), 15 parts of diatomaceous earth, 5 parts of bentonite and 33.5 parts of clay were weighed and mixed for 60 seconds with a vertical mixer. . After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of a fan, 12% by mass of benzobicyclone, and 8% by mass of phenoxasulfone was obtained.
［実施例５］
　ピリミスルファン２部、メフェナセット４０部、ジアルキルアリールスルホン酸塩２．１部、無水硫酸ナトリウム０．９部、ポリアクリル酸塩２部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１部、ポリプロピレングリコール２部、平均粒子径８μｍの炭酸カルシウムで表面被覆したメタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径５６μｍの既膨張プラスチックマイクロバルーン１１．２５部（プラスチックマイクロバルーンとして１．８部、炭酸カルシウムとして９．４５部）、珪藻土１５部、ベントナイト５部、平均粒子径３０μｍの炭酸カルシウム１２．７５部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、メフェナセットを４０質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 5]
2 parts of pyrimylsulfan, 40 parts of mefenacet, 2.1 parts of dialkylaryl sulfonate, 0.9 part of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, 5 parts of phosphate cross-linked starch, polyoxyalkylene 1 part alkynyl glycol ether, 2 parts polypropylene glycol, 11.25 parts of an inflated plastic microballoon having an average particle diameter of 56 μm with a wall material of methyl methacrylate / acrylonitrile polymer coated with calcium carbonate having an average particle diameter of 8 μm ( 1.8 parts as a plastic microballoon and 9.45 parts as calcium carbonate), 15 parts of diatomaceous earth, 5 parts of bentonite, and 12.75 parts of calcium carbonate having an average particle diameter of 30 μm were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of fan and 40% by mass of mefenacet was obtained.
［実施例６］
　ピロキロン４８部、アルキルアリールスルホン酸塩１０部、ポリオキシエチレンアリールフェニルエーテル硫酸塩１部、ポリオキシエチレンアルキルエーテル１部、ポリオキシアルキレンアルキニルグリコールエーテル２部、平均粒子径８μｍの炭酸カルシウムで表面被覆したメタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径５６μｍの既膨張プラスチックマイクロバルーン１０部（プラスチックマイクロバルーンとして１．６部、炭酸カルシウムとして８．４部）、ベントナイト３部、尿素１部、平均粒子径８μｍの炭酸カルシウム２４部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を５５℃で乾燥して、ピロキロンを４８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 6]
Surface coating with 48 parts of pyroxylone, 10 parts of alkyl aryl sulfonate, 1 part of polyoxyethylene aryl phenyl ether sulfate, 1 part of polyoxyethylene alkyl ether, 2 parts of polyoxyalkylene alkynyl glycol ether, calcium carbonate with an average particle size of 8 μm 10 parts of an expanded plastic microballoon having an average particle size of 56 μm using 1.6 methyl methacrylate / acrylonitrile polymer as a wall material (1.6 parts as a plastic microballoon, 8.4 parts as calcium carbonate), 3 parts bentonite, urea One part and 24 parts of calcium carbonate having an average particle diameter of 8 μm were weighed and mixed with a vertical mixer for 60 seconds. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-end type granulator, and the granulated product is dried at 55 ° C. A granular agricultural chemical composition having a minor axis of 5 mm and containing 48% by mass was obtained.
［実施例７］
　ピリミスルファン２部、ベンゾビシクロン１２部、フェノキサスルホン８部、ジアルキルアリールスルホン酸塩２．１部、無水硫酸ナトリウム０．９部、ポリアクリル酸塩２部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１．５部、ポリプロピレングリコール３部、平均粒子径１０μｍのタルクで表面被覆したメタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径２８μｍの既膨張プラスチックマイクロバルーン９部（プラスチックマイクロバルーンとして１．８部、タルクとして７．２部）、珪藻土１５部、ベントナイト５部、クレー３３．５部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、ベンゾビシクロンを１２質量％、フェノキサスルホンを８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Example 7]
2 parts of pyrimisulphan, 12 parts of benzobicyclone, 8 parts of phenoxasulfone, 2.1 parts of dialkylaryl sulfonate, 0.9 parts of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphoric acid 5 parts of cross-linked starch, 1.5 parts of polyoxyalkylene alkynyl glycol ether, 3 parts of polypropylene glycol, an existing particle having an average particle diameter of 28 μm using a methyl methacrylate / acrylonitrile polymer coated with talc having an average particle diameter of 10 μm as a wall material. 9 parts of expanded plastic microballoon (1.8 parts as plastic microballoon, 7.2 parts as talc), 15 parts of diatomaceous earth, 5 parts of bentonite, and 33.5 parts of clay were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of a fan, 12% by mass of benzobicyclone, and 8% by mass of phenoxasulfone was obtained.
［比較例１Ａ］
　カフェンストロール３部、ベンゾビシクロン８部、ベンスルフロン・メチル３部、ジアルキルアリールスルホン酸塩３．５部、無水硫酸ナトリウム１．５部、ポリオキシアルキレンアルキニルグリコールエーテル２部、変性デキストリン２部、塩化ビニリデン／アクリロニトリル系共重合体を壁材とする平均粒子径４１μｍの既膨張プラスチックマイクロバルーンの８５％含水物１３部（プラスチックマイクロバルーンとして１．９５部、水として１１．０５部）、平均粒子径１１μｍの炭酸カルシウム１１．０５部、珪藻土３部、尿素２０部及び平均粒子径３０μｍの炭酸カルシウム４１部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、カフェンストロールを３質量％、ベンゾビシクロンを８質量％、ベンスルフロン・メチルを３質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 1A]
Caffeanthrol 3 parts, benzobicyclone 8 parts, bensulfuron methyl 3 parts, dialkylaryl sulfonate 3.5 parts, anhydrous sodium sulfate 1.5 parts, polyoxyalkylene alkynyl glycol ether 2 parts, modified dextrin 2 parts, chloride 13 parts of 85% hydrated plastic microballoon having an average particle diameter of 41 μm with vinylidene / acrylonitrile copolymer wall material (1.95 parts as plastic microballoons and 11.05 parts as water), average particle diameter 11.05 parts of 11 μm calcium carbonate, 3 parts of diatomaceous earth, 20 parts of urea and 41 parts of calcium carbonate having an average particle diameter of 30 μm were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 3% by mass, 8% by mass of benzobicyclone and 3% by mass of bensulfuron methyl was obtained.
［比較例１Ｂ］
　混合時間を５分間とした以外は比較例１Ａと同様にして、カフェンストロールを３質量％、ベンゾビシクロンを８質量％、ベンスルフロン・メチルを３質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 1B]
A granular agrochemical composition having a minor axis of 5 mm containing 3% by mass of caffentrol, 8% by mass of benzobicyclone, and 3% by mass of bensulfuron-methyl, except that the mixing time was 5 minutes. Obtained.
［比較例２Ａ］
　ピリミノバック・メチル１．２部、ピラゾスルフロン・エチル０．８４部、ブロモブチド３６部、ポリオキシエチレンアリールフェニルエーテル硫酸塩１部、ポリオキシエチレンアルキルエーテル１部、アルキルアリールスルホン酸塩ホルマリン縮合物５部、アルキルアリールスルホン酸塩５部、ポリオキシアルキレンアルキニルグリコールエーテル１．５部、塩化ビニリデン／アクリロニトリル系共重合体を壁材とする平均粒子径４１μｍの既膨張プラスチックマイクロバルーンの８５％含水物２０部（プラスチックマイクロバルーンとして３部、水として１７部）、尿素２０部及び平均粒子径３０μｍの炭酸カルシウム２５．４６部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６５℃で乾燥して、ピリミノバック・メチルを１．２質量％、ピラゾスルフロン・エチルを０．８４質量％、ブロモブチドを３６質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 2A]
Pyriminobac methyl 1.2 parts, pyrazosulfuron ethyl 0.84 parts, bromobutide 36 parts, polyoxyethylene arylphenyl ether sulfate 1 part, polyoxyethylene alkyl ether 1 part, alkylaryl sulfonate formalin condensate 5 parts, Alkyl aryl sulfonate 5 parts, polyoxyalkylene alkynyl glycol ether 1.5 parts, 20 parts of 85% hydrated plastic microballoon with an average particle size of 41 μm using vinylidene chloride / acrylonitrile copolymer as a wall material ( 3 parts as a plastic microballoon and 17 parts as water), 20 parts of urea and 25.46 parts of calcium carbonate having an average particle diameter of 30 μm were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press granulator, and the granulated product is dried at 65 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 1.2% by mass of methyl, 0.84% by mass of pyrazosulfuron / ethyl and 36% by mass of bromobutide was obtained.
［比較例２Ｂ］
　混合時間を５分間とした以外は比較例２Ａと同様にして、ピリミノバック・メチルを１．２質量％、ピラゾスルフロン・エチルを０．８４質量％、ブロモブチドを３６質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 2B]
Except for mixing time of 5 minutes, in the same manner as Comparative Example 2A, a granular agrochemical with a short diameter of 5 mm containing 1.2% by mass of pyriminobac-methyl, 0.84% by mass of pyrazosulfuron / ethyl and 36% by mass of bromobutide A composition was obtained.
［比較例３Ａ］
　ピリミスルファン２部、ピラクロニル６部、フェノキサスルホン６部、ジアルキルアリールスルホン酸塩１．６５部、無水硫酸ナトリウム０．７部、ポリアクリル酸塩４部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１部、ポリプロピレングリコール２部、メタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径５６μｍの既膨張プラスチックマイクロバルーンの８５％含水物１３部（プラスチックマイクロバルーンとして１．９５部、水として１１．０５部）、珪藻土１５部、ベントナイト５部、クレー４８．７部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、ピラクロニルを６質量％、フェノキサスルホンを６質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 3A]
2 parts of pyrimylsulfan, 6 parts of pyraclonyl, 6 parts of phenoxasulfone, 1.65 parts of dialkylaryl sulfonate, 0.7 parts of anhydrous sodium sulfate, 4 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphate-crosslinked starch 5 parts, polyoxyalkylene alkynyl glycol ether 1 part, polypropylene glycol 2 parts, 13 parts of 85% hydrated plastic microballoon with an average particle size of 56 μm using methyl methacrylate / acrylonitrile polymer as a wall material (plastic micro 1.95 parts as a balloon and 11.05 parts as water), 15 parts of diatomaceous earth, 5 parts of bentonite and 48.7 parts of clay were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of fan, 6% by mass of pyraclonyl and 6% by mass of phenoxasulfone was obtained.
［比較例３Ｂ］
　混合時間を５分間とした以外は比較例３Ａと同様にして、ピリミスルファンを２質量％、ピラクロニルを６質量％、フェノキサスルホンを６質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 3B]
A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of pyrimislphan, 6% by mass of pyraclonyl and 6% by mass of phenoxasulfone was obtained in the same manner as in Comparative Example 3A except that the mixing time was changed to 5 minutes. It was.
［比較例４Ａ］
　ピリミスルファン２部、ベンゾビシクロン１２部、フェノキサスルホン８部、ジアルキルアリールスルホン酸塩２．１部、無水硫酸ナトリウム０．９部、ポリアクリル酸塩２部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１．５部、ポリプロピレングリコール３部、メタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径２８μｍの既膨張プラスチックマイクロバルーンの８５％含水物１２部（プラスチックマイクロバルーンとして１．８部、水として１０．２部）、珪藻土１５部、ベントナイト５部、クレー４０．７部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、ベンゾビシクロンを１２質量％、フェノキサスルホンを８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 4A]
2 parts of pyrimisulphan, 12 parts of benzobicyclone, 8 parts of phenoxasulfone, 2.1 parts of dialkylaryl sulfonate, 0.9 parts of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, phosphoric acid Cross-linked starch 5 parts, polyoxyalkylene alkynyl glycol ether 1.5 parts, polypropylene glycol 3 parts, methyl methacrylate / acrylonitrile polymer as a wall material, 85% water content of expanded plastic microballoon having an average particle diameter of 28 μm 12 Parts (1.8 parts as a plastic microballoon, 10.2 parts as water), 15 parts of diatomaceous earth, 5 parts of bentonite and 40.7 parts of clay were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of a fan, 12% by mass of benzobicyclone, and 8% by mass of phenoxasulfone was obtained.
［比較例４Ｂ］
　混合時間を５分間とした以外は比較例４Ａと同様にして、ピリミスルファンを２質量％、ベンゾビシクロンを１２質量％、フェノキサスルホンを８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 4B]
Except for mixing time of 5 minutes, in the same manner as in Comparative Example 4A, a granular agrochemical composition having a short diameter of 5 mm containing 2% by mass of pyrimulsulfan, 12% by mass of benzobicyclone, and 8% by mass of phenoxasulfone. Got.
［比較例５Ａ］
　ピリミスルファン２部、メフェナセット４０部、ジアルキルアリールスルホン酸塩２．１部、無水硫酸ナトリウム０．９部、ポリアクリル酸塩２部、カルボキシメチルセルロース１部、リン酸架橋デンプン５部、ポリオキシアルキレンアルキニルグリコールエーテル１部、ポリプロピレングリコール２部、メタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径５６μｍの既膨張プラスチックマイクロバルーンの８５％含水物１２部（プラスチックマイクロバルーンとして１．８部、水として１０．２部）、珪藻土１５部、ベントナイト５部、平均粒子径３０μｍの炭酸カルシウム２２．２部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を６０℃で乾燥して、ピリミスルファンを２質量％、メフェナセットを４０質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 5A]
2 parts of pyrimylsulfan, 40 parts of mefenacet, 2.1 parts of dialkylaryl sulfonate, 0.9 part of anhydrous sodium sulfate, 2 parts of polyacrylate, 1 part of carboxymethylcellulose, 5 parts of phosphate cross-linked starch, polyoxyalkylene 1 part of alkynyl glycol ether, 2 parts of polypropylene glycol, 12 parts of 85% hydrated plastic microballoon with an average particle size of 56 μm using 1.8 parts as a plastic microballoon with a methyl methacrylate / acrylonitrile polymer as a wall material 10.2 parts as water), 15 parts of diatomaceous earth, 5 parts of bentonite and 22.2 parts of calcium carbonate having an average particle diameter of 30 μm were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-press type granulator, and the granulated product is dried at 60 ° C. A granular agrochemical composition having a minor axis of 5 mm containing 2% by mass of fan and 40% by mass of mefenacet was obtained.
［比較例５Ｂ］
　混合時間を５分間とした以外は比較例５Ａと同様にして、ピリミスルファンを２質量％、メフェナセットを４０質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 5B]
A granular agrochemical composition with a short diameter of 5 mm containing 2% by mass of pyrimylsulfan and 40% by mass of mefenacet was obtained in the same manner as in Comparative Example 5A except that the mixing time was 5 minutes.
［比較例６Ａ］
　ピロキロン４８部、アルキルアリールスルホン酸塩１０部、ポリオキシエチレンアリールフェニルエーテル硫酸塩１部、ポリオキシエチレンアルキルエーテル１部、ポリオキシアルキレンアルキニルグリコールエーテル２部、メタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径５６μｍの既膨張プラスチックマイクロバルーン１．６部、ベントナイト３部、尿素１部、平均粒子径８μｍの炭酸カルシウム３２．４部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を５５℃で乾燥して、ピロキロンを４８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 6A]
Pyroxylone 48 parts, alkylaryl sulfonate 10 parts, polyoxyethylene arylphenyl ether sulfate 1 part, polyoxyethylene alkyl ether 1 part, polyoxyalkylene alkynyl glycol ether 2 parts, methyl methacrylate / acrylonitrile polymer 1.6 parts of an expanded plastic microballoon having an average particle diameter of 56 μm, 3 parts of bentonite, 1 part of urea, and 32.4 parts of calcium carbonate having an average particle diameter of 8 μm were weighed and mixed for 60 seconds with a vertical mixer. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-end type granulator, and the granulated product is dried at 55 ° C. A granular agricultural chemical composition having a minor axis of 5 mm and containing 48% by mass was obtained.
［比較例６Ｂ］
　混合時間を５分間とした以外は比較例６Ａと同様にして、ピロキロンを４８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 6B]
A granular agrochemical composition having a minor axis of 5 mm containing 48% by mass of pyroxylone was obtained in the same manner as in Comparative Example 6A except that the mixing time was 5 minutes.
［比較例７Ａ］
　ピロキロン４８部、アルキルアリールスルホン酸塩１０部、ポリオキシエチレンアリールフェニルエーテル硫酸塩１部、ポリオキシエチレンアルキルエーテル１部、ポリオキシアルキレンアルキニルグリコールエーテル２部、平均粒子径３５μｍの炭酸カルシウムで表面被覆したメタクリル酸メチル／アクリロニトリル系高分子を壁材とする平均粒子径５６μｍの既膨張プラスチックマイクロバルーン１０部（プラスチックマイクロバルーンとして１．６部、炭酸カルシウムとして８．４部）、ベントナイト３部、尿素１部、平均粒子径８μｍの炭酸カルシウム２４部を秤量し、バーチカルミキサーで６０秒間混合した。得られた原料混合物に所定量の水を加えて混練した後、前押し型造粒機を用い目開き径５ｍｍのスクリーンより押出し造粒し、造粒物を５５℃で乾燥して、ピロキロンを４８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 7A]
Surface coating with 48 parts of pyroxylone, 10 parts of alkyl aryl sulfonate, 1 part of polyoxyethylene aryl phenyl ether sulfate, 1 part of polyoxyethylene alkyl ether, 2 parts of polyoxyalkylene alkynyl glycol ether, calcium carbonate with an average particle size of 35 μm 10 parts of an expanded plastic microballoon having an average particle size of 56 μm using 1.6 methyl methacrylate / acrylonitrile polymer as a wall material (1.6 parts as a plastic microballoon, 8.4 parts as calcium carbonate), 3 parts bentonite, urea One part and 24 parts of calcium carbonate having an average particle diameter of 8 μm were weighed and mixed with a vertical mixer for 60 seconds. After adding a predetermined amount of water to the obtained raw material mixture and kneading, it is extruded and granulated from a screen having an opening diameter of 5 mm using a front-end type granulator, and the granulated product is dried at 55 ° C. A granular agricultural chemical composition having a minor axis of 5 mm and containing 48% by mass was obtained.
［比較例７Ｂ］
　混合時間を５分間とした以外は比較例７Ａと同様にして、ピロキロンを４８質量％含有する短径５ｍｍの粒状農薬組成物を得た。 [Comparative Example 7B]
A granular agrochemical composition having a minor axis of 5 mm containing 48% by mass of pyroxylone was obtained in the same manner as in Comparative Example 7A except that the mixing time was 5 minutes.
［試験例１］
　実施例及び比較例で得られた農薬粒状組成物の１００粒を常温の工業用水を満たした水槽に投入し、沈降する粒数を計測した。結果を表１に示す。 [Test Example 1]
100 grains of the agrochemical granular composition obtained in Examples and Comparative Examples were put into a water tank filled with industrial water at room temperature, and the number of settled grains was measured. The results are shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
［試験例２］
　実施例２－４、６及び７並びに比較例２Ｂ－４Ｂ、６Ｂ及び７Ｂで得られた農薬粒状組成物の１粒を常温の工業用水を満たした水槽に投入し、水面に浮遊した農薬粒状組成物が崩壊に要する時間を計測した。結果を表２に示す。 [Test Example 2]
One pesticide granular composition obtained in Examples 2-4, 6 and 7 and Comparative Examples 2B-4B, 6B and 7B was put into a water tank filled with room-temperature industrial water and floated on the water surface. The time required for the object to collapse was measured. The results are shown in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
　本発明の製造方法によれば、ごく短時間の混合で農薬粒状組成物の原料混合物中に中空体を均一に分散するため、水面浮遊性に優れた農薬粒状組成物を効率的に得ることが可能となる。更に、本発明の方法により製造された農薬粒状組成物は、水面上における崩壊時間が短縮されるため、散布時に圃場周辺の風による吹き寄せ等の影響を受けにくく、圃場中での成分偏在による薬害発生の懸念がない、崩壊性に優れた農薬粒状組成物となる。

  According to the production method of the present invention, since the hollow body is uniformly dispersed in the raw material mixture of the agricultural chemical granular composition by mixing in a very short time, an agricultural chemical granular composition having excellent water surface floatability can be obtained efficiently. It becomes possible. Furthermore, since the disintegration time on the water surface is shortened, the agrochemical granular composition produced by the method of the present invention is not easily affected by wind blowing around the field at the time of spraying, and phytotoxicity due to uneven distribution of components in the field. It becomes an agrochemical granular composition excellent in disintegration without fear of occurrence.

Claims (8)

  1. 　農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有する粒状農薬組成物の製造方法であって、中空体として、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンを用い、該鉱物質微粉被覆既膨張プラスチックマイクロバルーンを、農薬活性成分、界面活性剤及び固体担体と混合し、次いで該混合物に所定量の水を加えて混練し、該混練物を孔径３ｍｍ以上のスクリーンから押し出し造粒した後、得られた造粒物を乾燥して水分を除去することを特徴とする粒状農薬組成物の製造方法。 It contains a pesticide active ingredient, a surfactant, a hollow body, and a solid carrier, and a particle size distribution with a particle size of 3 mm or more is 80% or more, floats on the water surface, and within 30 minutes. A method for producing a granular agrochemical composition having a property of disintegrating at a surface, wherein the surface of an already expanded plastic microballoon having an average particle diameter of 1 to 100 μm as a hollow body and a thermoplastic polymer as a wall material has an average particle diameter Mineral fine powder coated pre-expanded plastic microballoon coated with mineral fine powder having a particle size of 0.1-15 μm and 1/2 or less of the pre-expanded plastic microballoon. , Mixed with an agrochemical active ingredient, a surfactant and a solid carrier, and then kneaded the mixture with a predetermined amount of water. A method for producing a granular agrochemical composition, comprising extruding and granulating, and drying the obtained granulated product to remove moisture.
  2. 　熱可塑性高分子がモノマー単位としてアクリロニトリルを含有するポリアクリロニトリル又はポリアクリロニトリル系共重合体である、請求項１に記載の粒状農薬組成物の製造方法。 The method for producing a granular agrochemical composition according to claim 1, wherein the thermoplastic polymer is polyacrylonitrile or a polyacrylonitrile-based copolymer containing acrylonitrile as a monomer unit.
  3. 　既膨張プラスチックマイクロバルーンを被覆する鉱物質微粉が炭酸カルシウム、酸化チタン又はタルクである、請求項１又は２に記載の粒状農薬組成物の製造方法。 The method for producing a granular agrochemical composition according to claim 1 or 2, wherein the fine mineral powder covering the already expanded plastic microballoon is calcium carbonate, titanium oxide or talc.
  4. 　鉱物質微粉被覆既膨張プラスチックマイクロバルーンの全量基準で、鉱物質微粉被覆既膨張プラスチックマイクロバルーンの表面から鉱物質微粉を除いた既膨張プラスチックマイクロバルーンの重量が５－２０質量％である、請求項１－３のいずれかに記載の粒状農薬組成物の製造方法。 The weight of the pre-expanded plastic microballoon obtained by removing the mineral fine powder from the surface of the mineral fine powder-covered pre-expanded plastic microballoon is 5-20% by mass, based on the total amount of the mineral fine-powder pre-expanded plastic microballoon. The manufacturing method of the granular agrochemical composition in any one of 1-3.
  5. 　鉱物質微粉被覆既膨張プラスチックマイクロバルーンの水分含量が５質量％以下であることを更なる特徴とする、請求項１－４のいずれかに記載の粒状農薬組成物の製造方法。 The method for producing a granular agrochemical composition according to any one of claims 1 to 4, further characterized in that the mineral content fine powder-coated expanded plastic microballoon has a water content of 5% by mass or less.
  6. 　請求項１－５のいずれかに記載の製造方法により製造された、農薬活性成分と、界面活性剤と、熱可塑性高分子を壁材とし、平均粒子径１０－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンと、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有する粒状農薬組成物。 6. An expanded plastic microballoon having an average particle diameter of 10 to 100 μm, produced by the production method according to claim 1, comprising an agrochemical active ingredient, a surfactant, and a thermoplastic polymer as a wall material. Containing a mineral fine powder coated expanded plastic microballoon coated with mineral fine powder having an average particle size of 0.1-15 μm and 1/2 or less of the expanded plastic microballoon, and a solid carrier A granular agrochemical composition having a particle size distribution of 80% or more having a particle size of 3 mm or more and a property of floating on the water surface and disintegrating on the water surface within 30 minutes.
  7. 　農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有し、中空体が、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンであることを特徴とする粒状農薬組成物。 It contains a pesticide active ingredient, a surfactant, a hollow body, and a solid carrier, and a particle size distribution with a particle size of 3 mm or more is 80% or more, floats on the water surface, and within 30 minutes. The surface of an already expanded plastic microballoon having a hollow body, a thermoplastic polymer wall material, and an average particle diameter of 1-100 μm, has an average particle diameter of 0.1-15 μm and an already expanded A granular agrochemical composition characterized by being a mineral fine powder-covered pre-expanded plastic microballoon coated with a mineral fine powder that is 1/2 or less of a plastic microballoon.
  8. 　農薬活性成分と、界面活性剤と、中空体と、固体担体とを含有してなり、粒径３ｍｍ以上のものが８０％以上である粒度分布と、水面に浮遊し、かつ３０分以内に水面で崩壊する性質を有する粒状農薬組成物の製造において、中空体として、熱可塑性高分子を壁材とし、平均粒子径１－１００μｍである既膨張プラスチックマイクロバルーンの表面が、平均粒子径が０．１－１５μｍかつ既膨張プラスチックマイクロバルーンの１／２以下である鉱物質微粉で被覆されてなる鉱物質微粉被覆既膨張プラスチックマイクロバルーンを用い、該鉱物質微粉被覆既膨張プラスチックマイクロバルーンを、農薬活性成分、界面活性剤及び固体担体と混合し、次いで該混合物に所定量の水を加えて混練し、該混練物を孔径３ｍｍ以上のスクリーンから押し出し造粒した後、得られた造粒物を乾燥して水分を除去することを特徴とする粒状農薬組成物の崩壊時間の短縮方法。

          It contains a pesticide active ingredient, a surfactant, a hollow body, and a solid carrier, and a particle size distribution with a particle size of 3 mm or more is 80% or more, floats on the water surface, and within 30 minutes. In the production of a granular agrochemical composition having a property of disintegrating at a surface, the surface of an already expanded plastic microballoon having a mean particle diameter of 1 to 100 μm as a hollow body and a thermoplastic polymer as a wall material has an average particle diameter of 0.1. A mineral fine powder-covered pre-expanded plastic microballoon coated with mineral fine powder that is 1-15 μm and 1/2 or less of the pre-expanded plastic micro-balloon is used. Mix with ingredients, surfactant and solid support, then add a predetermined amount of water to the mixture and knead, and push the kneaded product through a screen with a pore diameter of 3 mm or more. A method for shortening the disintegration time of a granular agrochemical composition, wherein the granulated pesticide composition is dried and dried to remove moisture.

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JP6732772B2 (en) 2020-07-29

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