WO2017056325A1 - 排水処理システム及び排水処理方法 - Google Patents
排水処理システム及び排水処理方法 Download PDFInfo
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- WO2017056325A1 WO2017056325A1 PCT/JP2015/078117 JP2015078117W WO2017056325A1 WO 2017056325 A1 WO2017056325 A1 WO 2017056325A1 JP 2015078117 W JP2015078117 W JP 2015078117W WO 2017056325 A1 WO2017056325 A1 WO 2017056325A1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1205—Particular type of activated sludge processes
- C02F3/1221—Particular type of activated sludge processes comprising treatment of the recirculated sludge
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1205—Particular type of activated sludge processes
- C02F3/121—Multistep treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1236—Particular type of activated sludge installations
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/005—Processes using a programmable logic controller [PLC]
- C02F2209/006—Processes using a programmable logic controller [PLC] comprising a software program or a logic diagram
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/08—Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/20—Total organic carbon [TOC]
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/21—Dissolved organic carbon [DOC]
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/40—Liquid flow rate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/04—Flow arrangements
- C02F2301/046—Recirculation with an external loop
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Definitions
- the present invention relates to a wastewater treatment system having an ozone treatment device and a wastewater treatment method.
- Patent Document 1 describes a wastewater treatment system including a biological treatment tank that performs biological treatment with aerobic microorganisms and a precipitation tank that separates wastewater after biological treatment into a precipitate and a supernatant. .
- the wastewater is mixed with activated sludge and aeration air to be aerobically biologically treated.
- the sedimentation tank the biologically treated waste water and activated sludge flow from the biological treatment tank, the activated sludge is settled and separated, and the supernatant liquid is discharged as treated water.
- the present invention has been made to solve such a problem, and a wastewater treatment system and a wastewater treatment method capable of suppressing the generation of waste such as excess sludge and reducing the waste disposal cost.
- the purpose is to provide.
- the wastewater treatment system according to the present invention is stored in a wastewater storage tank that stores wastewater containing organic matter, an ozone treatment device that reduces the organic matter contained in the wastewater by ozone treatment, and the wastewater storage tank.
- the aerobic microorganisms are brought into contact with the drainage recirculation mechanism that feeds the wastewater to the ozone treatment device and circulates the ozone-treated wastewater to the wastewater storage tank, and the wastewater that contains the ozone-treated wastewater and is sent from the wastewater storage tank.
- a biological treatment tank that reduces organic matter contained in the waste water.
- the drainage recirculation mechanism is provided between the wastewater storage tank and the ozone treatment apparatus, and is supplied with ozone treatment for feeding the wastewater stored in the wastewater storage tank to the ozone treatment apparatus.
- An ozone treatment recirculation pipe provided between the water pipe, the waste water storage tank and the ozone treatment device for circulating the ozone treated waste water to the waste water storage tank, and the waste water stored in the waste water storage tank to the ozone treatment device. It is preferable to provide an ozone treatment water pump for feeding water.
- the suspended matter or solid matter contained in the wastewater is separated, and the wastewater from which the suspended matter or solid matter is separated, It is preferable to further have a separation device for feeding water from the waste water storage tank to the biological treatment tank.
- the wastewater treatment system further includes a froth recirculation pipe for circulating the suspended matter separated in the separation device to the wastewater storage tank.
- the separation device is preferably a pressurized flotation device or a coagulation sedimentation device.
- the ozone treatment device includes a nozzle for ejecting ozone gas, and a swirling jet that stirs ozone gas and drainage by generating a swirling phenomenon of the jet by the ozone gas ejected from the nozzle. It is preferable that it is a type
- the ozone treatment device is preferably an ejector-type ozone mixing device or an ozone diffuser.
- the drainage storage tank includes a measuring instrument that measures the amount of organic matter in the wastewater stored in the wastewater storage tank, and the amount of organic matter in the wastewater stored in the wastewater storage tank is equal to or greater than a predetermined threshold value. If the amount of organic matter in the waste water is less than a predetermined threshold, the control device for sending the waste water stored in the waste water storage tank to the biological treatment tank. It is preferable to have.
- the wastewater treatment system further includes a sedimentation tank that separates the wastewater into a precipitate and a supernatant, and the sedimentation tank recirculates the sediment that has settled in the sedimentation tank to the wastewater storage tank. It is preferable to provide.
- the wastewater treatment method includes a step of storing wastewater containing organic matter in a wastewater storage tank, a step of causing the drainage recirculation mechanism to send the wastewater stored in the wastewater storage tank to the ozone treatment device, and an ozone treatment device. , The step of reducing the molecular weight of organic matter contained in the wastewater by ozone treatment of the discharged wastewater, the step of circulating the wastewater recirculation mechanism to the wastewater storage tank, the biological treatment tank A step of bringing aerobic microorganisms into contact with the wastewater containing the treated wastewater and fed from the wastewater storage tank to reduce organic matter contained in the wastewater.
- the wastewater treatment system and wastewater treatment method according to the present invention can suppress the generation of waste such as excess sludge and reduce waste disposal costs.
- the wastewater treatment system and the wastewater treatment method according to the present invention can improve the purification effect of biological treatment, and can sufficiently remove substances that cause pollution from wastewater.
- FIG. 3 is a flowchart illustrating an example of wastewater treatment by the wastewater treatment system 1.
- 1 is a schematic diagram for explaining an outline of a wastewater treatment system 10.
- FIG. 1 is a schematic diagram for demonstrating an example of the waste_water
- 1 is a schematic diagram for explaining an outline of a wastewater treatment system 100.
- FIG. 3 is a flowchart illustrating an example of wastewater treatment by the wastewater treatment system 100.
- Drawing 1 is a mimetic diagram for explaining an outline of waste water treatment system 1 of a 1st embodiment.
- the wastewater treatment system 1 of the first embodiment has a function of removing substances that cause pollution from wastewater discharged from wastewater generation sources such as factories or homes, and includes at least a wastewater storage tank 2 and an ozone treatment device 3.
- the biological treatment tank 4 and the sedimentation tank 5 are provided.
- the substance causing the contamination is, for example, an organic substance.
- the organic substance may be simply referred to as an organic substance.
- the waste water storage tank 2 is, for example, a flow rate adjusting tank, stores the waste water flowing in from the waste water generation source, and has a function of sending water to the ozone treatment apparatus 3 and the biological treatment tank 4 for performing post-treatment, and the ozone treatment apparatus 3. It has a function to store the drained water circulated from
- drain which flows in from a waste_water
- the drainage storage tank 2 includes an ozone treatment water pump 21 and a biological treatment water pump 22.
- the ozone treatment water pump 21 feeds the waste water stored in the waste water storage tank 2 to the ozone treatment device 3.
- the biological treatment water pump 22 feeds the wastewater stored in the wastewater storage tank 2 to the biological treatment tank 4 when a predetermined time has elapsed since the wastewater stored in the wastewater storage tank 2 was supplied to the ozone treatment device 3. To do.
- the ozone treatment device 3 mixes the wastewater sent from the wastewater storage tank 2 with ozone gas, performs ozone treatment, and circulates the wastewater after ozone treatment to the wastewater storage tank 2.
- the ozone treatment device 3 blows out ozone gas into the wastewater sent into the ozone treatment device 3, thereby causing organic substances contained in the wastewater to react with the ozone gas and decompose.
- the low-degradability polymer contained in the wastewater is reduced in molecular weight by reacting with ozone gas, which increases the amount of aerobic microorganisms that can be adsorbed to pollutants in the subsequent biological treatment, and the pollutant removal efficiency. Will increase.
- the ozone treatment device 3 performs a so-called swirling jet ozone treatment using, for example, a stirring device described in Japanese Patent No. 4195782.
- a device that performs a swirling jet ozone treatment may be referred to as a swirling jet ozone processing device.
- a known ozone mixer or the like may be used as the ozone treatment device 3.
- the ozone treatment device 3 is not limited to the swirling jet type ozone treatment device and the ozone mixer described above, and any device may be used as long as the waste water and ozone are mixed.
- the biological treatment tank 4 biologically treats the wastewater sent from the wastewater storage tank 2 with activated sludge.
- the activated sludge is a mud aggregate of aerobic microorganisms that oxidatively decompose organic substances contained in wastewater, and the aerobic microorganisms are bacteria, protozoa, metazoan bacteria, and the like.
- aerobic microorganisms are fed from the wastewater storage tank 2 and adsorbed to pollutants in the wastewater containing organic matter, and by consuming oxygen, the organic matter is oxidatively decomposed or absorbed and separated. Purify wastewater.
- the waste water purified by the biological treatment tank 4 flows into the sedimentation tank 5.
- the wastewater sent from the wastewater storage tank 2 may be biologically treated by a biofilm method.
- a biofilm filter medium to which aerobic microorganisms are attached is placed in the biological treatment tank 4, and the aerobic microorganisms attached to the biofilm filter medium come into contact with pollutants including organic matter in the waste water.
- the organic matter is oxidatively decomposed or absorbed and separated, and the waste water containing the organic matter is purified.
- the biological treatment in the biological treatment tank 4 is not limited to the activated sludge method and the biofilm method described above, but may be a method of contacting aerobic microorganisms with organic matter in the wastewater, such as a sprinkling filter bed method and a rotating plate contact method. Any method may be used.
- the waste water flowing from the biological treatment tank 4 settles and separates into a sediment and a supernatant liquid.
- Precipitates are activated sludge and pollutants in the waste water flowing from the biological treatment tank 4 and settle due to the difference in specific gravity with water.
- the supernatant liquid separated and settled was treated as wastewater from the precipitation tank 5, a sewage treatment facility such as an industrial park, a community plant such as an apartment house, a sewer , Discharged into rivers or sea areas.
- the wastewater treatment system 1 can reduce the organic molecules contained in the wastewater by the ozone treatment device 3 before biologically treating the wastewater flowing in from the wastewater generation source in the biological treatment tank 4, purification of biological treatment The effect can be improved. Therefore, the wastewater treatment system 1 can sufficiently remove substances that cause sludge from the wastewater. Moreover, since the wastewater treatment system 1 can reduce the amount of sludge discarded, the amount of industrial waste treated can be reduced, and the waste disposal cost can be reduced.
- FIG. 2 is a schematic diagram for explaining an example of waste water treatment by the waste water storage tank 2 and the ozone treatment device 3.
- the drainage storage tank 2 stores the wastewater flowing in from the drainage source through the storage tank inflow pipe 60 in the drainage storage tank 2.
- the ozone treatment water pump 21 feeds the waste water stored in the waste water storage tank 2 to the ozone treatment device 3 through the ozone treatment water supply pipe 61.
- the ozone treatment device 3 performs ozone treatment by mixing the waste water sent from the waste water storage tank 2 with ozone gas.
- ozone gas supplied into the ozone treatment device 3 is generated by an ozone generator (not shown).
- the ozone generator for example, compresses air with an air compressor, generates concentrated oxygen gas from the compressed air by a PSA (Pressure Swing Adsorption) method, and further applies high voltage using a discharge unit or the like from the concentrated oxygen gas. Ozone gas is generated.
- the ozone treatment device 3 includes a cylindrical container 31 that stores wastewater to be treated, and an ozone gas ejection nozzle 32 that is disposed so as to protrude upward from the bottom surface of the cylindrical container 31. .
- the inner diameter of the cylindrical container 31 is D
- the depth from the drainage liquid surface to the tip of the ozone ejection port 33 of the ozone ejection nozzle 32 is H1.
- the waste water stored in the waste water storage tank 2 is appropriately supplied through the ozone treatment water supply pipe 61 so that the height of the liquid level in the cylindrical container 31 is kept constant.
- the ratio (H1 / D) of the depth H1 of the ozone outlet 33 to the inner diameter D of the cylindrical container 31 is in the range of about 0.3 to about 1.0.
- ⁇ is the density of drainage and ⁇ is the surface tension of the drainage.
- drain above the ozone jet nozzle 33 turns in the arrow A direction, the waste water below the ozone jet nozzle 33 will rotate in the arrow B direction of a reverse direction by the angular momentum conservation law.
- the swirling phenomenon of the jet flow occurs by ejecting ozone gas.
- the waste water in the cylindrical container 31 is agitated without using a mechanical drive source such as a propeller.
- the ozone treatment device 3 is thus more efficient than the method of simply injecting ozone gas from the bottom surface of the cylindrical container 31 by stirring the waste water in the cylindrical container 31 and dispersing the ozone gas as fine bubbles in the waste water. It reacts with ozone and waste water. Then, due to the strong oxidizing power of ozone, high molecular organic substances such as oil in the wastewater are reduced in molecular weight.
- the ejection and ejection time of ozone gas from the ozone generator are controlled by an ozone control unit (not shown) so that the amount of organic matter in the wastewater is equal to or less than a predetermined threshold.
- the amount of organic substances is TOC (Total Organic Carbon) and COD.
- the swirling jet type ozone treatment in which the ozone gas is ejected to generate a swirling jet and the ozone gas and the waste water react with each other, the amount of aerobic microorganisms that can be adsorbed to the pollutant in the biological treatment in the subsequent stage is large. Thus, it becomes possible to increase the removal efficiency of pollutants.
- the swirling jet type ozone treatment has various advantages such as low sludge generation and excellent deodorizing and decoloring effects in addition to the effect of reducing the molecular weight of high molecular organic substances such as oil. .
- the swirl jet ozone treatment has been described as a treatment for reacting ozone gas and wastewater.
- the ozone gas is dissolved in the wastewater by an ejector-type ozone mixing device or an ozone diffuser. May be.
- an ejector-type ozone mixing device inhales ozone gas using the vacuum action caused by the negative pressure generated when the wastewater is ejected as a contracted flow, and ejects ozone gas as bubbles into the wastewater, thereby generating ozone gas and wastewater. Is a device for mixing.
- the drainage storage tank 2 and the ozone treatment device 3 are connected via an overflow pipe 62. That is, when the water level of drainage in the ozone treatment apparatus 3 (in the cylindrical container 31) rises to the height (H2) or more of the lower end position of the connection port of the overflow pipe 62 in the cylindrical container 31, it is equal to or higher than the connection position.
- the waste water flows back to the waste water storage tank 2. Therefore, the ozone treatment water pump 21 feeds the waste water in the waste water storage tank 2 through the ozone treatment water supply pipe 61 to the ozone treatment device 3, and the ozone treatment device 3 performs ozone treatment on the sent waste water.
- the wastewater after the ozone treatment flows back to the wastewater storage tank 2 through the overflow pipe 62, the wastewater in the wastewater storage tank 2 and the wastewater after the ozone treatment are mixed, and the mixed wastewater in the wastewater storage tank 2 is treated with ozone. Water is sent to the device 3.
- the waste water from the waste water storage tank 2 and the waste water from the ozone treatment device 3 are circulated by the ozone treatment water pump 21, the ozone treatment water feed pipe 61, and the overflow pipe 62. Then, after the drainage circulates for a predetermined time, the wastewater in the drainage storage tank 2 is fed by the biological treatment water pump 22 through the storage tank outflow pipe 63.
- the overflow pipe 62 is an example of an ozone treatment circulation pipe, and the ozone treatment water pump 21, the ozone treatment water supply pipe 61, and the overflow pipe 62 are examples of the drainage circulation mechanism 7.
- ozone treatment water supply pump 21 between the waste water storage tank 2 and the ozone treatment apparatus 3, or in the ozone treatment apparatus 3 instead of in the waste water storage tank 2.
- an ozone treatment recirculation pump (not shown) is provided in the waste water storage tank 2, between the waste water storage tank 2 and the ozone treatment apparatus 3, or in the ozone treatment apparatus 3. It may be.
- an ozone treatment recirculation pump is connected to the overflow pipe 62.
- the biological treatment water pump 22 may be provided outside the drainage storage tank 2.
- the ozone treatment water pump 21 and the biological treatment water pump 22 may be a single discharge pump.
- a valve is provided in each of the ozone treatment water supply pipe 61 and the storage tank outflow pipe 63.
- the valve of the ozone treatment water supply pipe 61 is opened and the valve of the storage tank outflow pipe 63 is closed.
- the reservoir tank outflow pipe 63 is opened and the ozone treatment water supply pipe 61 is closed.
- a three-way valve may be provided between one discharge pump and the ozone treatment water supply pipe 61 and the storage tank outflow pipe 63.
- the wastewater sent from the wastewater storage tank 2 is efficiently reacted with ozone by the ozone treatment device 3, and the wastewater after the ozone treatment flows back to the wastewater storage tank 2 and is sent to the ozone treatment device 3. Is repeated.
- the ozone treatment device 3 that performs ozone treatment exclusively, compared with a method of simply injecting ozone gas into the wastewater in the wastewater storage tank 2, high-molecular organic substances such as oil in the wastewater are high. Low molecular weight with efficiency.
- FIG. 3 is a schematic diagram for explaining an example of waste water treatment by the biological treatment tank 4.
- the biological treatment tank 4 has activated sludge and an air pipe 42.
- the air pipe 42 is connected to a blower 41 that supplies air.
- the wastewater in the wastewater storage tank 2 is fed through the storage tank outflow pipe 63.
- drain storage tank 2 contains the organic substance by which the molecular weight was reduced by ozone treatment.
- the air pipe 42 has a plurality of small-diameter air outlets 43 for ejecting the air supplied from the blower 41 into the waste water containing organic matter.
- air is ejected into the biological treatment tank 4 from the air outlet 43 of the air pipe 42, aerobic microorganisms contained in the activated sludge are aerated, and pollutants contained in the wastewater containing organic matter are biodegraded (oxidative decomposition). Or waste water containing organic matter is purified. Then, the waste water purified by the biological treatment tank 4 flows into the sedimentation tank 5 through the sedimentation tank inflow pipe 64.
- the air pipe 42 Since the air pipe 42 is disposed at the bottom of the biological treatment tank 4, the efficiency of adsorbing the aerobic microorganisms to the pollutant is obtained by stirring the waste water and activated sludge by the air ejected from the air ejection port 43. improves.
- FIG. 4 is a schematic diagram for explaining an example of waste water treatment by the settling tank 5.
- the sedimentation tank 5 includes a sediment discharge pump 51 and a sediment circulation pipe 66.
- the wastewater that has flowed from the biological treatment tank 4 through the sedimentation tank inflow pipe 64 is settled and separated into a precipitate and a supernatant.
- the sediment discharge pump 51 discharges the sediment settled in the sedimentation tank 5 to the outside of the sedimentation tank 5 through the sediment circulation pipe 66 after a predetermined time has passed since the wastewater was introduced from the biological treatment tank 4.
- the sediment discharge pump 51 is installed at a position below a predetermined height from the bottom surface of the sedimentation tank 5 in order to discharge the sediment.
- the supernatant liquid settled and separated is discharged from the settling tank 5 through the treated drainage discharge pipe 65 as treated wastewater to a sewage treatment facility such as an industrial park, a community plant such as an apartment house, a sewer, a river or a sea area.
- the sediment discharge pump 51 may be provided outside the sedimentation tank 5. Moreover, you may provide the discharge port for discharging
- FIG. 5 is a flowchart showing an example of wastewater treatment by the wastewater treatment system 1.
- wastewater discharged from a wastewater generation source such as a factory or home flows into the wastewater storage tank 2 (step S101).
- step S102 the drained wastewater is stored in the drainage storage tank 2 (step S102).
- step S103 it is determined whether or not the wastewater stored in the wastewater storage tank 2 is sent to the biological treatment tank 4 (step S103). For example, when a predetermined time has elapsed since the wastewater stored in the wastewater storage tank 2 is supplied to the ozone treatment device 3, it is determined that the wastewater stored in the wastewater storage tank 2 is supplied to the biological treatment tank 4. The In addition, when the organic substance amount measuring device which measures the amount of organic substances is provided in the waste water storage tank 2 and it is determined that the organic substance quantity has become a predetermined threshold value or less, the waste water stored in the waste water storage tank 2 is the biological treatment tank. 4 may be sent to water.
- a control device that determines whether or not the wastewater stored in the wastewater storage tank 2 is sent to the biological treatment tank 4 and controls the operations of the ozone treatment water supply pump 21 and the biological treatment water supply pump 22 is provided. It may be provided, or an administrator of the wastewater treatment system 1 may perform the determination and operation control of the pump.
- step S103-Yes when it is determined that the wastewater stored in the wastewater storage tank 2 is sent to the biological treatment tank 4 (step S103-Yes), the process proceeds to step S106. If it is determined that the wastewater stored in the wastewater storage tank 2 is not sent to the biological treatment tank 4 (No at Step S103), the wastewater stored in the wastewater storage tank 2 is sent to the ozone treatment device 3. (Step S104).
- the ozone treatment device 3 performs ozone treatment by mixing the wastewater sent from the wastewater storage tank 2 with ozone gas (step S105).
- the waste water after the ozone treatment is circulated to the waste water storage tank 2, and the process is returned to step S102.
- Step S106 the wastewater stored in the wastewater storage tank 2 is sent to the biological treatment tank 4.
- the biological treatment tank 4 biologically treats the wastewater sent from the wastewater storage tank 2 with activated sludge. (Step S107).
- the waste water flowing from the biological treatment tank 4 is settled and separated into a precipitate and a supernatant (step S109). Then, after a predetermined time has passed since the wastewater was introduced from the biological treatment tank 4, the supernatant liquid separated and settled was treated as wastewater from the precipitation tank 5, a sewage treatment facility such as an industrial park, a community plant such as an apartment house, a sewer Then, it is discharged into a river or sea area, and the series of steps is completed.
- the waste water storage tank 2 and the ozone treatment apparatus 3 might be connected via the overflow pipe 62
- the ozone treatment apparatus 3 and the biological treatment tank 4 were connected via the overflow pipe (not shown). You may do it.
- the wastewater treatment system 1 of the first embodiment is configured so that the organic matter contained in the wastewater is reduced in molecular weight by the ozone treatment device 3 before biologically treating the wastewater in the biological treatment tank 4.
- the purification effect of the biological treatment in the treatment tank 4 can be improved.
- FIG. 6 is a schematic diagram for explaining the outline of the waste water treatment system 10 of the second embodiment.
- the waste water treatment system 10 according to the second embodiment includes a measuring tank 8 and a separation device 9 in addition to the waste water storage tank 2, the ozone treatment apparatus 3, the biological treatment tank 4, and the sedimentation tank 5 shown in FIG. Prepare.
- the drainage storage tank 2 includes an ozone treatment water pump 21 and a separation device discharge pump 23.
- the ozone treatment water pump 21 feeds the waste water stored in the waste water storage tank 2 to the ozone treatment device 3.
- the separation device discharge pump 23 feeds the wastewater stored in the wastewater storage tank 2 to the separation device 9 via the measuring tank 8.
- the measuring tank 8 has a function of adjusting the flow rate of the wastewater sent from the drainage storage tank 2.
- the inside of the measuring tank 8 is partitioned into a plurality of rooms.
- the flow rate adjusting pump controls the flow rate capability of the flow rate adjusting pump by controlling the rotational speed of the pump motor by inverter driving.
- the separation device 9 is a pressurized flotation device, a coagulation sedimentation device, or the like and has a function of separating floating substances such as floating substances and solid substances contained in the waste water from the waste water. Then, the waste water from which the suspended substances are separated by the separation device 9 flows into the biological treatment tank 4. Thus, since the wastewater treatment system 10 includes the separation device 9, the separation device 9 removes suspended solids from the wastewater, so that the purification effect of the biological treatment of wastewater in the biological treatment tank 4 at the subsequent stage is improved.
- FIG. 7 is a schematic diagram for explaining an example of waste water treatment by the separation device 9.
- the separation device 9 shown in FIG. 7 is an example of a pressure levitation device.
- a part of the waste water flowing in from the measuring tank 8 is pumped to a pressure tank (not shown) by a pressure pump (not shown) to generate pressurized waste water in which air is dissolved in the tank.
- a pressure pump not shown
- pressurized wastewater is discharged from the pressurized wastewater discharge port 91 to the floating tank 92, ultrafine bubbles are generated by the discharge of the pressurized wastewater.
- the generated ultrafine bubbles adhere to the oil and floating substances contained in the drainage and float on the upper surface of the floating tank 92.
- the ultrafine bubbles that have floated up, the oil, and the suspended matter are scraped off by the skimmer 93 and collected in the floss collecting unit 94.
- the waste water from which the oil and floating substances have been separated and removed by the separation device 9 flows out into the biological treatment tank 4 through the biological treatment tank inflow pipe 95.
- oil and floating substances contained in the wastewater may be levitated by a pressurized levitation tank to separate floating substances such as suspended solids and solid matter contained in the wastewater from the wastewater.
- the amount of the hardly decomposable polymer is reduced. Therefore, in the biological treatment tank 4 in the subsequent stage, the amount of aerobic microorganisms that can be adsorbed by the low-molecular contaminants that can be biologically processed increases, and the contaminant removal efficiency increases. Moreover, since the organic substance contained in the wastewater is reduced in molecular weight by the ozone treatment device 3, the amount of suspended matter floating in the separation device 9 is increased, and the removal efficiency of suspended matter is improved.
- the oil and floating substances collected in the froth collecting section 94 are circulated to the drainage storage tank 2 through the froth circulation pipe (not shown) by a froth circulation pump (not shown) or the like, and drained again. .
- the amount of waste such as oil and suspended solids can be reduced, so that the amount of industrial waste processed can be reduced and the waste disposal cost can be reduced.
- FIG. 8 is a schematic diagram for explaining the outline of the wastewater treatment system 100 of the third embodiment.
- FIG. 8 the same components as those in the waste water treatment system 1 shown in FIG.
- FIG. 9 is a flowchart illustrating an example of wastewater treatment by the wastewater treatment system 100.
- the sedimentation tank 5 includes a sediment discharge pump 51 and a sediment reflux pipe 66, and also includes a supernatant liquid reflux pump 52 and a supernatant liquid discharge pipe 67.
- the sediment discharge pump 51 circulates the sediment settled in the sedimentation tank 5 to the drainage storage tank 2 through the sediment circulation pipe 66 (S201), and again drains it. Thereby, it becomes possible to reduce the disposal cost of waste by reducing the amount of disposal of activated sludge and pollutants.
- the supernatant liquid recirculation pump 52 discharges the supernatant liquid in the sedimentation tank 5 to the drainage storage tank 2 through the supernatant liquid discharge pipe 67 (S202).
- the supernatant liquid recirculation pump 52 is installed at a position higher than a predetermined height from the bottom surface of the settling tank 5 in order to discharge the supernatant liquid.
- an organic substance amount measuring device 53 for measuring the organic substance amount of the supernatant liquid is installed at the same height as the position where the supernatant liquid reflux pump 52 is installed.
- the amount of organic substances is TOC and COD.
- the supernatant liquid discharged by the supernatant liquid circulation pump 52 is stored in a storage section in the drainage branching device 54.
- the drainage control unit of the drainage branching device 54 determines whether or not the organic matter amount of the supernatant measured by the organic matter amount measuring instrument 53 is equal to or greater than the first threshold (step S203).
- the drainage control unit of the drainage branching device 54 discharges the supernatant liquid to the drainage storage tank 2 through the first supernatant liquid circulation pipe 68 when the amount of the organic matter in the supernatant liquid is equal to or larger than the first threshold (step S203—Yes). Step S204).
- the drainage control unit of the drainage branching device 54 determines whether or not the amount of organic matter in the supernatant liquid is greater than or equal to the second threshold value. Determination is made (step S205).
- the drainage control unit of the drainage branching device 54 discharges the supernatant liquid to the biological treatment tank 4 through the second supernatant liquid circulation pipe 69 when the amount of the organic matter in the supernatant liquid is equal to or greater than the second threshold (step S205—Yes). Step S206). Note that the second threshold value is smaller than the first threshold value.
- the drainage control unit of the drainage branching device 54 stops the discharge by the supernatant liquid recirculation pump 52 when the organic matter amount of the supernatant measured by the organic matter amount measuring device 53 is less than the second threshold (No in step S205). Then, the supernatant liquid is discharged from the settling tank 5 as treated wastewater to a sewage treatment facility such as an industrial park, a community plant such as an apartment house, a sewer, a river or a sea area, and the series of steps is completed.
- a sewage treatment facility such as an industrial park, a community plant such as an apartment house, a sewer, a river or a sea area
- a supernatant liquid recirculation pump 52 may be provided outside the precipitation tank 5. Moreover, you may provide the discharge port for discharging
- FIG. 1 A supernatant liquid recirculation pump 52 may be provided outside the precipitation tank 5. Moreover, you may provide the discharge port for discharging
- a second organic substance measuring instrument 531 (not shown) is provided on the bottom surface of the sedimentation tank 5, and a second drainage branching device 541 (not shown) is provided. May be provided.
- the second drainage control unit of the second drainage branching device 541 is configured to remove the sediment from the first sediment circulation pipe 681 when the amount of organic matter in the sediment settled in the sedimentation tank 5 is equal to or greater than the third threshold. It discharges to the drainage storage tank 2 through (not shown).
- drain branching apparatus 541 determines whether the organic matter content of a sediment is more than a 4th threshold value, when the organic matter content of a sediment is less than a 3rd threshold value. .
- the second drainage control unit of the second drainage branching device 541 uses the biological treatment tank 4 to pass the sediment through the second sediment circulation pipe 691 (not shown) when the amount of organic matter in the sediment is equal to or greater than the fourth threshold. To discharge. Note that the fourth threshold value is smaller than the third threshold value.
- the second drainage control unit of the second drainage branching apparatus 541 stops the discharge by the sediment discharge pump 51 when the organic matter amount of the precipitate measured by the second organic matter amount measuring instrument 531 is less than the fourth threshold value. . Thereby, since the amount of deposits of sludge substances etc. can be reduced, the amount of industrial waste treated can be reduced, and the waste disposal cost can be reduced.
- the BOD of the waste water before the ozone treatment is 690 mg / L, whereas the BOL of the waste water after the ozone treatment is reduced to 470 mg / L.
- the normal hexane extract substance content of the waste water before ozone treatment is 140 mg / L, whereas the normal hexane extract substance content of the waste water after ozone treatment is reduced to 50 mg / L.
- the wastewater treatment systems 1, 10, and 100 can reduce the molecular weight of organic matter in the wastewater by the ozone treatment device before the wastewater flows into the biological treatment tank, the biological treatment purification effect. Can be improved. Therefore, the wastewater treatment systems 1, 10, and 100 can sufficiently remove substances that cause sludge from the wastewater.
- the wastewater treatment systems 1, 10, 100 do not include the sedimentation tank 5, but treat the wastewater purified by the biological treatment tank 4 as treated wastewater, treat sewage treatment facilities such as industrial parks, community plants such as apartment houses, It may be discharged into sewers, rivers or sea areas.
- the wastewater treatment systems 1, 10, and 100 may not be provided with the sedimentation tank 5, but may solid-liquid separate the wastewater in the biological treatment tank 4 by membrane separation activated sludge method (Membrane Bioreactor, MBR).
- MBR membrane separation activated sludge method
- a submerged membrane separation module is provided in the biological treatment tank 4, and treated water in the membrane separation module is discharged out of the membrane separation module by a suction pump.
- the membrane separation module includes a membrane element for solid-liquid separation of the wastewater in the biological treatment tank 4 into treated water and activated sludge, and the membrane element is constituted by, for example, a hollow fiber membrane, a flat membrane, or a monolith membrane Is done.
- the activated sludge amount (Mixed liquorMsuspended solid, MLSS) of the wastewater in the biological treatment tank 4 may be measured, and if the MLSS is a predetermined threshold value or more, the wastewater may be recirculated to the wastewater storage tank 2.
- the biological treatment tank 4 removes the treated water in the membrane separation module from the wastewater treatment systems 1, 10, 100 (sewage treatment facilities such as industrial parks, community plants such as housing complexes, sewers, rivers, sea areas, etc.)
- a return pump for supplying the wastewater in the biological treatment tank 4 to the drainage storage tank 2 is provided.
- an MLSS measuring device is provided, and the waste water treatment systems 1, 10, and 100 are provided with a control device (not shown) that continuously monitors the MLSS measured by the MLSS measuring device. .
- the control device controls the return pump so that the drainage is fed to the drainage storage tank 2, and when the measured MLSS is less than the predetermined threshold, the drainage is drained.
- the suction pump is controlled so as to be discharged out of the treatment system 1, 10, 100 (sewage treatment facilities such as industrial parks, community plants such as apartment buildings, sewers, rivers or sea areas).
- wastewater such as excess sludge is suppressed by circulating the wastewater to the wastewater storage tank 2 and performing wastewater treatment again. It becomes possible to reduce the disposal cost.
- the administrator of the wastewater treatment system 1, 10, 100 may monitor the MLSS measured by the MLSS measuring instrument and control the suction pump and the return pump. Further, even when a biological treatment other than the membrane separation activated sludge method is adopted, if the MLSS of the wastewater in the biological treatment tank 4 is equal to or greater than a predetermined threshold, the wastewater in the biological treatment tank 4 is recirculated to the wastewater storage tank 2. You may do it.
- the wastewater treatment systems 1, 10, 100 may be provided with two biological treatment tanks 400, 410.
- the biological treatment tanks 400 and 410 have the same function as the biological treatment tank 4 described above.
- the drainage storage tank 2 sends the wastewater to either the ozone treatment device 3 or the first biological treatment tank 400.
- the first biological treatment tank 400 supplies wastewater to the ozone treatment apparatus 3, and the ozone treatment apparatus 3 circulates the wastewater to either the wastewater storage tank 2 or the first biological treatment tank 400.
- the first biological treatment tank 400 supplies the wastewater to the second biological treatment tank 410, and the second biological treatment tank 410 sends the wastewater to the precipitation tank 5.
- the organic substance amount measuring device which measures the amount of organic substances in the first biological treatment tank 400
- the biological treatment tank for feeding the waste water in the first biological treatment tank 400 to the second biological treatment tank 410.
- a pump may be provided, and when it is determined that the amount of organic substances has become a predetermined threshold value or less, the wastewater stored in the first biological treatment tank 400 may be sent to the second biological treatment tank 410.
- a controller is provided that determines whether or not the wastewater stored in the first biological treatment tank 400 is sent to the second biological treatment tank 410 and controls the operation of the inter-biological treatment tank pump.
- an administrator of the wastewater treatment system 1, 10, 100 may perform the determination and control of the operation of the biological treatment tank pump.
- two or more second biological treatment tanks 410 may be provided in series. For example, when two second biological treatment tanks 410 are provided, the wastewater stored in the first biological treatment tank 400 is sent to the first tank of the second biological treatment tank 410, The wastewater stored in the first tank of the second biological treatment tank 410 is sent to the second tank of the second biological treatment tank 410 and stored in the second tank of the second biological treatment tank 410. The discharged waste water is sent to the settling tank 5.
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- Hydrology & Water Resources (AREA)
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- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Activated Sludge Processes (AREA)
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Abstract
Description
図1は、第1の実施形態の排水処理システム1の概要を説明するための模式図である。第1の実施形態の排水処理システム1は、工場又は家庭等の排水の発生源から排出された排水から汚濁原因となる物質を除去する機能を有し、少なくとも排水貯留槽2、オゾン処理装置3、生物処理槽4、及び沈殿槽5を備える。汚濁原因となる物質は、例えば、有機性物質である。以下、有機性物質を、単に有機物と称する場合がある。
図6は、第2の実施形態の排水処理システム10の概要を説明するための模式図である。図6において、図1に示す排水処理システム1と同じ構成については同じ符号を付し、その説明を省略する。第2の実施形態の排水処理システム10は、図1に示した排水貯留槽2、オゾン処理装置3、生物処理槽4、及び沈殿槽5に加えて、更に、計量槽8及び分離装置9を備える。
図8は、第3の実施形態の排水処理システム100の概要を説明するための模式図である。図8において、図1に示す排水処理システム1と同じ構成については同じ符号を付し、その説明を省略する。図9は、排水処理システム100による排水処理の一例を示すフローチャートである。
2 排水貯留槽
21 オゾン処理送水ポンプ
22 生物処理送水ポンプ
23 分離装置排出ポンプ
3 オゾン処理装置
31 円筒形容器
32 オゾン噴出ノズル
33 オゾン噴出口
4 生物処理槽
41 ブロワ
42 空気配管
43 空気噴出口
5 沈殿槽
51 沈殿物排出ポンプ
52 上澄み液環流ポンプ
53 有機物量計測器
54 排水分岐装置
60 貯留槽流入管
61 オゾン処理送水管
62 オーバーフロー管
63 貯留槽流出管
64 沈殿槽流入管
65 処理済排水排出管
66 沈殿物環流管
67 上澄み液排出管
68 第1上澄み液環流管
69 第2上澄み液環流管
7 排水環流機構
8 計量槽
81 堰板
9 分離装置
91 加圧排水吐出口
92 浮上槽
93 スキマー
94 フロス収集部
95 生物処理槽流入管
Claims (10)
- 有機物を含む排水を貯留する排水貯留槽と、
排水をオゾン処理することにより排水に含まれる有機物を低分子化するオゾン処理装置と、
前記排水貯留槽に貯留された排水を前記オゾン処理装置に送水するとともに、前記オゾン処理された排水を前記排水貯留槽に環流させる排水環流機構と、
前記オゾン処理された排水を含み且つ前記排水貯留槽から送水された排水に、好気性微生物を接触させて、排水に含まれる有機物を減少させる生物処理槽と、
を備えることを特徴とする排水処理システム。 - 前記排水環流機構は、
前記排水貯留槽と前記オゾン処理装置との間に備えられ、前記排水貯留槽に貯留された排水を前記オゾン処理装置に送水させるためのオゾン処理送水管と、
前記排水貯留槽と前記オゾン処理装置との間に備えられ、前記オゾン処理された排水を前記排水貯留槽に環流させるためのオゾン処理環流管と、
前記排水貯留槽に貯留された排水を前記オゾン処理装置に送水するオゾン処理送水ポンプと、を備える、請求項1に記載の排水処理システム。 - 前記排水貯留槽と前記生物処理槽との間に備えられ、排水に含まれる浮遊物又は固形物を分離し、浮遊物又は固形物が分離された排水を、前記排水貯留槽から前記生物処理槽に送水する分離装置を更に有する、請求項1又は2に記載の排水処理システム。
- 前記分離装置において分離された浮遊物質を前記排水貯留槽に環流するフロス環流管を更に備える、請求項3に記載の排水処理システム。
- 前記分離装置は、加圧浮上装置又は凝集沈殿装置である、請求項3又は4に記載の排水処理システム。
- 前記オゾン処理装置は、オゾンガスを噴出させるノズルが配置され、前記ノズルから噴出させたオゾンガスによって噴流の旋回現象を発生させることによりオゾンガスと排水とを撹拌させる旋回噴流式オゾン処理装置である、請求項1~5の何れか1項に記載の排水処理システム。
- 前記オゾン処理装置は、エジェクター方式のオゾン混合装置又はオゾン用散気装置である、請求項1~5の何れか1項に記載の排水処理システム。
- 前記排水貯留槽は、
前記排水貯留槽に貯留された排水の有機物量を測定する計測器と、
前記排水貯留槽に貯留された排水の有機物量が所定の閾値以上である場合、前記排水貯留槽に貯留された排水を前記オゾン処理装置に送水させ、排水の有機物量が所定の閾値未満である場合、前記排水貯留槽に貯留された排水を前記生物処理槽に送水させる制御装置とを有する、請求項1~7の何れか1項に記載の排水処理システム。 - 排水を沈殿物と上澄み液に分離させる沈殿槽を更に備え、
前記沈殿槽は、沈殿槽内に沈降した沈殿物を排水貯留槽に環流させる沈殿物排出ポンプを備える、請求項1~8の何れか1項に記載の排水処理システム。 - 有機物を含む排水を排水貯留槽に貯留するステップと、
排水環流機構が、前記排水貯留槽に貯留された排水をオゾン処理装置に送水させるステップと、
前記オゾン処理装置が、前記送水された排水をオゾン処理することにより排水に含まれる有機物を低分子化するステップと、
前記排水環流機構が、前記オゾン処理された排水を前記排水貯留槽に環流させるステップと、
生物処理槽が、前記オゾン処理された排水を含み且つ前記排水貯留槽から送水された排水に、好気性微生物を接触させて、排水に含まれる有機物を減少させるステップと、
を有することを特徴とする排水処理方法。
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JP2017510704A JP6198029B2 (ja) | 2015-10-02 | 2015-10-02 | 排水処理システム及び排水処理方法 |
EP15905478.2A EP3357872A4 (en) | 2015-10-02 | 2015-10-02 | Wastewater treatment system and wastewater treatment method |
US15/765,229 US20180282187A1 (en) | 2015-10-02 | 2015-10-02 | Wastewater treatment system and wastewater treatment method |
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WO2019093283A1 (ja) * | 2017-11-07 | 2019-05-16 | 王子ホールディングス株式会社 | 混合装置、水処理装置および水処理方法 |
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