WO2016102499A1 - Liquid sulfonylurea-containing herbicidal compositions - Google Patents

Liquid sulfonylurea-containing herbicidal compositions Download PDF

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Publication number
WO2016102499A1
WO2016102499A1 PCT/EP2015/080844 EP2015080844W WO2016102499A1 WO 2016102499 A1 WO2016102499 A1 WO 2016102499A1 EP 2015080844 W EP2015080844 W EP 2015080844W WO 2016102499 A1 WO2016102499 A1 WO 2016102499A1
Authority
WO
WIPO (PCT)
Prior art keywords
methyl
ethyl
sulfonylurea
tribenuron
metsulfuron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2015/080844
Other languages
English (en)
French (fr)
Inventor
Oliver Egan
Andrew Goldsmith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle UK Ltd
Mitsui AgriScience International NV SA
Original Assignee
Battelle UK Ltd
Mitsui AgriScience International NV SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BR112017013448-9A priority Critical patent/BR112017013448B1/pt
Priority to EP18203057.7A priority patent/EP3456199A1/en
Priority to MX2017008371A priority patent/MX379333B/es
Priority to PL15813079T priority patent/PL3236749T3/pl
Priority to PL18170343T priority patent/PL3387904T3/pl
Priority to AU2015371074A priority patent/AU2015371074B2/en
Priority to DK15813079.9T priority patent/DK3236749T3/da
Priority to KR1020177020666A priority patent/KR102291873B1/ko
Priority to UAA201707444A priority patent/UA122330C2/uk
Priority to CN201580073346.7A priority patent/CN107427010B/zh
Priority to JP2017534742A priority patent/JP6736560B6/ja
Priority to CA2971795A priority patent/CA2971795C/en
Priority to ES15813079T priority patent/ES2739540T3/es
Priority to EP15813079.9A priority patent/EP3236749B1/en
Priority to EA201791345A priority patent/EA038316B1/ru
Priority to US15/538,158 priority patent/US11071296B2/en
Application filed by Battelle UK Ltd, Mitsui AgriScience International NV SA filed Critical Battelle UK Ltd
Priority to EP18170343.0A priority patent/EP3387904B1/en
Publication of WO2016102499A1 publication Critical patent/WO2016102499A1/en
Anticipated expiration legal-status Critical
Priority to CONC2017/0006981A priority patent/CO2017006981A2/es
Priority to US17/132,116 priority patent/US12268209B2/en
Priority to US19/078,167 priority patent/US20250241298A1/en
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/04—Carbon disulfide; Carbon monoxide; Carbon dioxide
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/26—Phosphorus; Compounds thereof

Definitions

  • Y is selected from the group H, C1-C4 alkyl, C 1 -C4 alkoxy, C r C 4 haloalkoxy, C 1 -C4 alkylthio, C 1 -C4 haloalkylthio, C2-C5 alkoxyalkyi, C 2 -C5 alkoxyalkoxy, amino, C 1 -C3 alkylammo, di(Ci-C 3 alkyl)amino, C3-C4 alkenyloxy, C3-C4 alkynyloxy.
  • alkoxyalkoxy denotes alkoxy substitution on alkoxy
  • alkylthio includes branched or straight- chain alkylthio moieties such as methylthio. ethylthio, and the different propylthio isomers;
  • esters for the purpose of this invention are the alkyl esters, in particular the Ci-Cjo-alkyl esters, such as methyl and ethyl esters.
  • the sulfonylurea has a particle size (D50) of at least 100 nm or more, at least 200 nm or more, at least 500 nm or more, at least 1 ⁇ or more, at least 2 ⁇ or more, or at least 3 ⁇ or more as a particle size less than this can generate excess heat during milling and possibly degrade the sulfonylurea.
  • D50 particle size
  • trisodium phosphate and tripotassium phosphate provide for a sulfonylurea with superior chemical stability than many of the other salts mentioned herein, particularly with respect to those sulfonylureas that are more prone to hydrolysis in liquid compositions.
  • tribcnuron-methyl was found to have excellent chemical stability in the presence of trisodium phosphate.
  • trisodium phosphate in its anhydrous or hydrated forms is particularly preferred as the inorganic salt of the invention.
  • the total amount of sulfonylurea compounds is 2 to 20 wt.%
  • the total amount of inorganic salt selected from the metal carbonates and metal phosphates is 1 to 20 wt.%
  • the weight ratio of inorganic salt to sulfonylurea is in the range of from 0.1 to 5.
  • the amounts described herein refer to the sum amount of all of the non-sulfonylurea herbicides present in the composition.
  • one or more of the non-sulfonylurea herbicides may be partially or wholly encapsulated (e.g. microcapsules) such as is described in WO 2008/061721 A2 (GAT Microencapsulation AG).
  • the wt.% amounts that are described herein refer to the weight of the non-sulfonylurea herbicides without the encapsulating material.
  • the liquid composition of the invention may comprise any of the sulfonylureas described herein with any of the non-sulfonylurea herbicides described herein.
  • Exemplary combinations of sulfonylurea and safener include: iodosulfuron-methyl (optionally as the sodium salt) and mefenpyr-diethyl: mesosulfuron (and or as the methyl ester) and mefenpyr-di-ethyl; mesosulfuron (and/or as the methyl ester) and propoxycarbazone (e.g. sodium salt) and mefenpyr-di-ethyl.
  • An emulsifiable concentrate comprising at least one sulfonylurea and K 3 PO 4 in a nonaqueous solvent system, wherein the at least one sulfonylurea is selected from tribenuron-methyl, nicosulfuron and metsulfuron methyl,

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
PCT/EP2015/080844 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions Ceased WO2016102499A1 (en)

Priority Applications (20)

Application Number Priority Date Filing Date Title
JP2017534742A JP6736560B6 (ja) 2014-12-22 2015-12-21 液体のスルホニル尿素含有除草組成物
MX2017008371A MX379333B (es) 2014-12-22 2015-12-21 Composiciones herbicidas liquidas que contienen sulfonilurea.
PL15813079T PL3236749T3 (pl) 2014-12-22 2015-12-21 Ciekłe kompozycje chwastobójcze zawierające tribenuron
PL18170343T PL3387904T3 (pl) 2014-12-22 2015-12-21 Ciekłe kompozycje chwastobójcze zawierające sulfonylomocznik
AU2015371074A AU2015371074B2 (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions
EP18203057.7A EP3456199A1 (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions
KR1020177020666A KR102291873B1 (ko) 2014-12-22 2015-12-21 액체 설포닐우레아-함유 제초제 조성물
UAA201707444A UA122330C2 (uk) 2014-12-22 2015-12-21 Рідкі гербіцидні композиції, які містять похідні сульфонілсечовини
CN201580073346.7A CN107427010B (zh) 2014-12-22 2015-12-21 液态含磺酰脲的除草性组合物
CA2971795A CA2971795C (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions
DK15813079.9T DK3236749T3 (da) 2014-12-22 2015-12-21 Flydende tribenuron-holdige herbicidsammensætninger
BR112017013448-9A BR112017013448B1 (pt) 2014-12-22 2015-12-21 Composições líquidas de herbicidas contendo sulfonilureia
EP15813079.9A EP3236749B1 (en) 2014-12-22 2015-12-21 Liquid tribenuron-containing herbicidal compositions
EA201791345A EA038316B1 (ru) 2014-12-22 2015-12-21 Жидкие гербицидные композиции, содержащие производные сульфонилмочевины
US15/538,158 US11071296B2 (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions
ES15813079T ES2739540T3 (es) 2014-12-22 2015-12-21 Composiciones herbicidas que contienen tribenurón líquido
EP18170343.0A EP3387904B1 (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions
CONC2017/0006981A CO2017006981A2 (es) 2014-12-22 2017-07-12 Composiciones herbicidas líquidas que contienen sulfonilurea
US17/132,116 US12268209B2 (en) 2014-12-22 2020-12-23 Liquid sulfonylurea-containing herbicidal compositions
US19/078,167 US20250241298A1 (en) 2014-12-22 2025-03-12 Liquid Sulfonylurea-Containing Herbicidal Compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14199867 2014-12-22
EP14199867.4 2014-12-22

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US15/538,158 A-371-Of-International US11071296B2 (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions
US17/132,116 Continuation US12268209B2 (en) 2014-12-22 2020-12-23 Liquid sulfonylurea-containing herbicidal compositions

Publications (1)

Publication Number Publication Date
WO2016102499A1 true WO2016102499A1 (en) 2016-06-30

Family

ID=52134029

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2015/080844 Ceased WO2016102499A1 (en) 2014-12-22 2015-12-21 Liquid sulfonylurea-containing herbicidal compositions

Country Status (18)

Country Link
US (3) US11071296B2 (enExample)
EP (3) EP3456199A1 (enExample)
JP (1) JP6736560B6 (enExample)
KR (1) KR102291873B1 (enExample)
CN (3) CN111713504A (enExample)
AU (1) AU2015371074B2 (enExample)
BR (1) BR112017013448B1 (enExample)
CA (1) CA2971795C (enExample)
CO (1) CO2017006981A2 (enExample)
DK (1) DK3236749T3 (enExample)
EA (1) EA038316B1 (enExample)
ES (2) ES2739540T3 (enExample)
HU (2) HUE048629T2 (enExample)
MX (1) MX379333B (enExample)
PL (2) PL3387904T3 (enExample)
TR (1) TR201910889T4 (enExample)
UA (1) UA122330C2 (enExample)
WO (1) WO2016102499A1 (enExample)

Cited By (12)

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CN107960422A (zh) * 2017-12-06 2018-04-27 江苏省农业科学院 一种一次施药防控稻茬小麦全生育期草害的除草剂减量控草方法
WO2019032990A1 (en) 2017-08-11 2019-02-14 Arysta Lifescience Inc. HERBICIDE COMPOSITION AND METHOD
RU2714736C1 (ru) * 2019-04-02 2020-02-19 Общество с ограниченной ответственностью "АХК-АГРО" Гербицидная композиция
CN111356370A (zh) * 2017-11-16 2020-06-30 株式会社Lg化学 除草组合物
US20200323206A1 (en) * 2016-06-08 2020-10-15 Clariant International Ltd. Use of n-substituted pyrrolidones to promote the penetration of agrochemical active agents
JP2021502994A (ja) * 2017-11-16 2021-02-04 エルジー・ケム・リミテッド 液状除草剤組成物
US11071296B2 (en) 2014-12-22 2021-07-27 Mitsui Agriscience International S.A./N.V. Liquid sulfonylurea-containing herbicidal compositions
WO2021152391A1 (en) 2020-01-29 2021-08-05 Fmc Agricultural Caribe Industries Ltd. Liquid sulfonylurea compositions
EP3900535A1 (en) 2020-04-24 2021-10-27 Battelle UK Limited Liquid sulfonylurea herbicide composition
RU2771039C1 (ru) * 2021-08-05 2022-04-25 ООО "Агро Эксперт Груп" Жидкая гербицидная композиция
US11464225B2 (en) 2016-06-21 2022-10-11 Battelle Uk Limited Liquid sulfonylurea- and li-salt containing herbicidal compositions
WO2023058040A1 (en) * 2021-10-08 2023-04-13 Aviral Crop Science Pvt. Ltd. Ternary herbicidal composition

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FR3046179A1 (fr) * 2015-12-23 2017-06-30 Oleon Nv Composition dispersante
TWI713933B (zh) * 2017-11-16 2020-12-21 南韓商Ｌｇ化學股份有限公司 液體除草組成物
CN108041043A (zh) * 2018-02-02 2018-05-18 陕西上格之路生物科学有限公司 一种含吡氟酰草胺的三元除草组合物
CN108308187A (zh) * 2018-02-11 2018-07-24 河北中天邦正生物科技股份公司 一种农药组合物及其应用
WO2019236738A1 (en) * 2018-06-05 2019-12-12 Monsanto Technology Llc Herbicidal compositions
CA3130265A1 (en) 2019-02-19 2020-08-27 Gowan Company, L.L.C. Stable liquid compositions and methods of using the same
WO2020234175A1 (en) 2019-05-21 2020-11-26 Syngenta Crop Protection Ag Improved herbicidal oil dispersion compositions
CN112262848A (zh) * 2020-11-24 2021-01-26 安徽苏昆化工科技有限公司 一种包含仲丁灵、吡嘧磺隆和丁草胺的除草组合物
CN112400876A (zh) * 2020-11-24 2021-02-26 安徽苏昆化工科技有限公司 一种包含仲丁灵、苄嘧磺隆和丁草胺的除草组合物
CN120379534A (zh) * 2022-12-20 2025-07-25 德州作物科学股份有限公司 油性流动性腺苷三磷酸双磷酸酶抑制剂制剂
GB202312744D0 (en) * 2023-08-21 2023-10-04 Upl Mauritius Ltd Herbicide safener composition

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