WO2016086656A1 - Method for steaming during changing of softwood into hardwood - Google Patents

Method for steaming during changing of softwood into hardwood Download PDF

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Publication number
WO2016086656A1
WO2016086656A1 PCT/CN2015/083153 CN2015083153W WO2016086656A1 WO 2016086656 A1 WO2016086656 A1 WO 2016086656A1 CN 2015083153 W CN2015083153 W CN 2015083153W WO 2016086656 A1 WO2016086656 A1 WO 2016086656A1
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Prior art keywords
pressure treatment
steam
temperature
cork
continuous
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PCT/CN2015/083153
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French (fr)
Chinese (zh)
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王凯
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王凯
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Priority to JP2017510901A priority Critical patent/JP6383097B2/en
Publication of WO2016086656A1 publication Critical patent/WO2016086656A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/007Treating of wood not provided for in groups B27K1/00, B27K3/00 using pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/08Impregnating by pressure, e.g. vacuum impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00

Definitions

  • the invention relates to a steaming method, in particular to a method for introducing steam when softwood is compacted into hardwood.
  • Hardwood is hard and fine, with beautiful color and fine texture. It is a good material for furniture and wood products. However, due to its slow growth and fine wooden structure, it is very expensive. Cork is composed of many flat cells with radiation arrangement. The cell cavity often contains resin and tannin compounds. The cells are filled with air and are generally used for furniture and wood products or core materials. Because cork is soft and soft, with low strength and flexible defects, wood products manufacturers almost do not use cork to produce products such as furniture and wood products, and can only act as a supporting role for hardwood; but cork has a short growth cycle and its price ratio Hardwood is much cheaper and more affordable. Based on this, how to remove the air, resin and tannin compounds inside the cork, and change the soft wood softness, low density and low hardness are the technical problems that researchers need to solve urgently.
  • the present invention studies an improvement of the softness of the softwood, and excludes the resin and the tannin compound in the softwood, so that it becomes a hardwood with high hardness, high wear resistance and high strength.
  • the method is mainly a steaming method when the cork is compacted into a hardwood.
  • the invention provides a steaming method for softwood compaction into hardwood, the method comprising the following steps:
  • High temperature and high pressure treatment applying a certain pressure to the cork at a certain temperature, and performing high temperature and high pressure treatment under the condition of intermittent or continuous steam introduction;
  • Continuous pressure treatment The cork after high temperature and high pressure treatment is applied with a certain pressure at a certain temperature, and the continuous pressure treatment is carried out under the condition of intermittent or continuous steam introduction.
  • the method of introducing steam into the hardwood when the cork is compacted comprises the following steps:
  • High temperature and high pressure treatment the cork is applied at a temperature of 120-150 ° C, a pressure of 15-35 kg / cm 2 , and high temperature and high pressure treatment under the condition of continuous or continuous steam, high temperature and high pressure treatment time is 3 -10min, the time of steaming is not greater than the time of high temperature and high pressure treatment;
  • Continuous pressure treatment the cork after high temperature and high pressure treatment is applied at a temperature of 160-190 ° C, a pressure of 15-35 kg / cm 2 , and continuous pressure treatment under the condition of continuous or continuous steaming,
  • the time for the continuous pressure treatment is 4-10 min, and the time for introducing steam is not more than the time for the continuous pressure treatment.
  • the softwood referred to in the present invention is a softwood material such as pine, fir, eucalyptus, nanmu and eucalyptus.
  • the invention provides a steaming method by compacting softwood into hardwood.
  • the method is simple in operation.
  • the steaming method provided by the invention adopts two steam inlets, and the first is in the high temperature and high pressure processing process.
  • the steam can be injected into the inner nest cells of the cork step by step without causing the cells in the cork to quickly dry and break, but the original air, resin and tannin compounds in the internal structure are uniformly discharged. Out; this ensures that the hardwood made is more uniform; the second steaming is in the process of continuous pressure, which ensures that the air and existing impurities in the cell tissue inside the cork are completely discharged; and the cork cell structure is affected.
  • the external strong pressure and steam double factors make it into a linear strip shape; the high temperature steam is introduced while the pressure is applied, so that the cork is wetted while being wetted, and the pollutants are completely eliminated; the texture can be obtained by the above operation.
  • Soft, low-strength, low-density and low-hardness cork becomes a hard material with high strength and wear resistance and hardwood.
  • the cork is subjected to a high temperature and high pressure treatment after being subjected to steam preheating and pressure treatment
  • the steam preheating and pressure curing treatment is a steam that is introduced into a space of the cork for a certain time and temperature.
  • the steam temperature is 120-200 ° C and the time is 2-10 min.
  • the cork observed under the microscope is composed of thousands of dead cells like a honeycomb, the cells are filled with air, forming a closed airbag.
  • the intracellular pressure is increased and the pressure is increased.
  • the cork texture the cork is preheated and pressurized with steam before steam is introduced.
  • the steam is introduced for a period of 3 to 10 minutes, and preferably, the temperature of the steam is 140 to 170 °C.
  • the steam is introduced for 4-10 minutes, and the steam is introduced at a temperature of 100-150 °C.
  • the pressurization speed is 50-80 mm/min.
  • the prepared hardwood has high hardness and good specific gravity and bearing capacity.
  • the method comprises the following steps:
  • steam preheating pressure treatment steam into the space where the cork is located, 150 ° C steam, the access time is 3 min;
  • High temperature and high pressure treatment the cork subjected to steam preheating and pressure treatment is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure.
  • the treatment time is 4 min
  • the steaming time is 4 min
  • the steaming temperature is 150 ° C;
  • the uniformity of the wood is controlled, and the speed of the steam is 30-50 kg/min during the high temperature and high pressure treatment; the speed of the steam is introduced during the continuous pressure treatment It is 75-100 kg/min.
  • oxygen is introduced into the steam during high temperature and high pressure treatment, and the oxygen gas is introduced at a rate of 1-3 kg/min.
  • the high temperature and high pressure treatment and the continuous pressure treatment step also include introducing steam of different colors and/or steam of different odors.
  • the invention can change the surface of the wood into various colors during the process of changing the cork into hardwood by introducing steam with different colors and odors, or the wood can emit various aromas; for example; Special flavors such as rosewood, rosewood and various redwoods.
  • the inner cells of the cork can be turned into a flat structure state, so that the treated cork has the characteristics and stability of the hardwood;
  • the hardwood when steam is introduced, the hardwood can be changed into a variety of colors, patterns and smells of wood.
  • Example 1 Method for introducing steam when cork compaction is changed into hardwood
  • the method comprises the following steps:
  • High temperature and high pressure treatment applying a certain pressure to the cork at a certain temperature, and performing high temperature and high pressure treatment under the condition that steam is introduced at intervals;
  • Continuous pressure treatment the cork after high temperature and high pressure treatment is applied with a certain pressure at a certain temperature, and the continuous pressure treatment is carried out under the condition that steam is introduced at intervals.
  • the method comprises the following steps:
  • the method comprises the following steps:
  • High temperature and high pressure treatment the cork is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 , and high temperature and high pressure treatment under continuous steaming conditions, high temperature and high pressure treatment time is 4 min, steaming time 4min;
  • Continuous pressure treatment the cork after high temperature and high pressure treatment is subjected to a pressure of 30 kg/cm 2 at a temperature of 170 ° C, and the continuous pressure treatment is carried out under continuous steaming, and the time of the continuous pressure treatment is 5 min, the steaming time was 5 min.
  • the method comprises the following steps:
  • High temperature and high pressure treatment the cork is applied at a temperature of 140 ° C, a pressure of 20 kg / cm 2 , and high temperature and high pressure treatment under continuous steaming conditions, high temperature and high pressure treatment time is 5 min, steaming time 5 min, the temperature of steaming is 140 ° C;
  • Continuous pressure treatment the cork after high temperature and high pressure treatment is subjected to a pressure of 15 kg/cm 2 at a temperature of 190 ° C, and the continuous pressure treatment is carried out under continuous steaming, and the time of the continuous pressure treatment is At 6 min, the steaming time was 6 min, and the steaming temperature was 140 °C.
  • the method comprises the following steps:
  • High temperature and high pressure treatment the cork is applied at a temperature of 140 ° C, a pressure of 35 kg / cm 2 , and high temperature and high pressure treatment under continuous steaming conditions, high temperature and high pressure treatment time is 3 min, steaming time 3 min, the temperature of steaming is 140 ° C;
  • Continuous pressure treatment the cork subjected to high temperature and high pressure treatment is subjected to a pressure of 20 kg/cm 2 at a temperature of 180 ° C, a pressurization speed of 80 mm/min, and a continuous pressure under continuous steaming conditions.
  • the method comprises the following steps:
  • steam preheating pressure treatment steam into the space where the cork is located, 150 ° C steam, the access time is 3 min;
  • High temperature and high pressure treatment the cork subjected to steam preheating and pressure treatment is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure.
  • the treatment time is 4 min
  • the steaming time is 4 min
  • the steaming temperature is 150 ° C;
  • Example 7 Method for introducing steam when cork compaction is changed into hardwood
  • the method comprises the following steps:
  • High temperature and high pressure treatment the cork subjected to steam preheating and pressure treatment is applied at a temperature of 120 ° C, a pressure of 30 kg / cm 2 is applied, and continuous flow of yellow steam and rosewood odor steam is carried out.
  • High temperature and high pressure treatment, high temperature and high pressure treatment time is 5min, steaming time is 5min, steaming temperature is 170 °C;
  • Example 8 Method for introducing steam when cork compaction is changed into hardwood
  • the method comprises the following steps:
  • steam preheating pressure treatment steam into the space where the cork is located, 200 ° C steam, the access time is 4 min;
  • High temperature and high pressure treatment the cork after steam preheating and pressure treatment is applied at a temperature of 150 ° C, a pressure of 15 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure.
  • the treatment time is 7 min, the steaming time is 6 min, and the steaming temperature is 160 ° C;
  • Example 9 Method for introducing steam when cork compaction is changed into hardwood
  • the method comprises the following steps:
  • High temperature and high pressure treatment the cork subjected to steam preheating and pressure treatment is applied at a temperature of 125 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure.
  • the treatment time is 10 min
  • the steaming time is 10 min
  • the steaming temperature is 150 ° C;
  • the time of high temperature and high pressure treatment was designed to be 0 min, 2 min, 3 min, 6 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9.
  • the prepared hardwood specific gravity and the cellular state structure were investigated. The results are shown in Table 1;
  • the temperature of the high temperature and high pressure treatment was designed to be 10 levels of 110 ° C, 120 ° C, 135 ° C, 150 ° C and 160 ° C, and the remaining steps were prepared according to the method of Example 9, and the prepared hardwood specific gravity and the cellular state structure content were determined. Inspection, the results of the inspection are shown in Table 1;
  • the high temperature and high pressure treatment pressure was designed to be 10 kg/cm 2 , 15 kg/cm 2 , 25 kg/cm 2 , 35 kg/cm 2 and 45 kg/cm 2 , 5 levels, and the remaining steps were as follows according to the method of Example 9. Preparation, the specific gravity of the prepared hardwood and the cellular structure of the honeycomb structure were investigated, and the results are shown in Table 1;
  • the steaming time during the high temperature and high pressure treatment was designed to be 0 min, 2 min, 3 min, 6 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9, and the resin in the internal structure of the prepared hardwood and The content of tannin compounds was investigated, and the results are shown in Table 2;
  • the temperature of the steam entering during the high temperature and high pressure treatment was designed to be 5 levels of 130 ° C, 140 ° C, 150 ° C, 170 ° C and 180 ° C, and the remaining steps were prepared according to the method of Example 9, and the internal structure of the prepared hardwood was prepared.
  • the content of resin and tannin compound was investigated, and the results are shown in Table 2;
  • the time of the continuous pressure treatment was designed to be 0 min, 3 min, 4 min, 7 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9.
  • the prepared hardwood specific gravity and the cellular state structure content were investigated. The results are shown in Table 3;
  • the temperature of the continuous pressure treatment was designed to be 150 ° C, 160 ° C, 175 ° C, 190 ° C and 200 ° C, 5 levels, and the remaining steps were prepared according to the method of Example 9, and the prepared hardwood specific gravity and the cellular state structure content were determined. Inspection, the results of the investigation are shown in Table 3;
  • the pressure of the continuous pressure treatment was designed to be 10 kg/cm 2 , 15 kg/cm 2 , 25 kg/cm 2 , 35 kg/cm 2 and 45 kg/cm 2 , 5 levels, and the remaining steps were as follows according to the method of Example 9. Preparation, the specific gravity of the prepared hardwood and the cellular structure of the honeycomb structure were investigated, and the results are shown in Table 3;
  • the time, temperature and pressure of the continuous pressure treatment have a significant influence on the specific gravity of the prepared hardwood and the content of the cellular structure. Only when the time is controlled within 10 minutes, the temperature is controlled within 190 °C, and the pressure is controlled. In the range of 35 kg/cm 2 , the specific gravity of hardwood can be provided at low cost and low consumption, most impurities in hardwood can be excluded, and the honeycomb structure can be largely changed into a linear strip structure; Temperature, pressure and processing time continue to rise, and inputs and outputs are not directly proportional.
  • the steaming time during the continuous pressure treatment was designed to be 0 min, 3 min, 4 min, 7 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9, and the resin in the prepared hardwood internal structure and The content of tannin compounds was investigated, and the results of the investigation are shown in Table 4;
  • the temperature of the steam introduced during the continuous pressure treatment was designed to be 90 ° C, 100 ° C, 120 ° C, 150 ° C and 160 ° C, 5 levels, and the remaining steps were prepared according to the method of Example 9, for the internal structure of the prepared hardwood.
  • the content of resin and tannin compound was investigated, and the results are shown in Table 4;
  • the entire continuous pressure process can eliminate a very small amount of resin and tannin compound.
  • the steam can be introduced into the high-temperature and high-pressure treatment process.
  • the remaining resin and tannin compound are excluded; the more the time is removed and the temperature of the steam increases, but when the time increases to 10 min or the steam temperature rises to 150 ° C, the content of the resin and tannin compound does not pass.
  • it has been reduced by more than 90%.
  • the input and output are not proportional. Therefore, the steaming time during the continuous pressure treatment is controlled at 4-10min, and the steam temperature is controlled. 100-150 ° C.

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  • Life Sciences & Earth Sciences (AREA)
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  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
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Abstract

The present invention relates to a method for steaming during changing of a softwood into a hardwood; the method comprises: at a certain temperature, a certain pressure is applied to a softwood, and while steaming at intervals or continuously, high-temperature high-pressure treatment is performed; at a certain temperature, a certain pressure is applied to the high-temperature high-pressure treated softwood, and while steaming at intervals or continuously, continued pressure treatment is performed; by means of the above operation, the pit-shaped cells inside the softwood are changed so that they have a flattened structure; air, resin, tannin compounds, and other impurities are removed from the cells of the softwood at the same time, such that the processed softwood has the robust texture of a hardwood.

Description

软木压密变为硬木时通入蒸汽方法 Steaming method when cork compaction becomes hardwood 技术领域Technical field
本发明涉及一种通入蒸汽方法,特别涉及一种软木压密变为硬木时通入蒸汽方法。 The invention relates to a steaming method, in particular to a method for introducing steam when softwood is compacted into hardwood.
背景技术Background technique
硬木由于木材坚硬细密,色泽华丽,花纹优美细腻,是做家具和木制品的上乘材料,但由于其生长缓慢,木质结构细密紧致,所以价格非常昂贵;软木是由许多辐射排列的扁平细胞组成,细胞腔内往往含有树脂和单宁化合物,细胞内充满空气,一般用来做家具和木制品辅料或者芯材来使用。由于软木存在得质地轻软,承受力度小,富有弹性的缺陷,木制品制造商几乎不采用软木来生产家具和木制品等产品,只能充当硬木的配角;但软木生长周期短,其价格比硬木要低廉实惠得多,基于这一点,如何除去软木内部的空气、树脂和单宁化合物,改变软木质地柔软,密度低及硬度低的缺陷,是目前科研人员急需解决的技术问题。 Hardwood is hard and fine, with beautiful color and fine texture. It is a good material for furniture and wood products. However, due to its slow growth and fine wooden structure, it is very expensive. Cork is composed of many flat cells with radiation arrangement. The cell cavity often contains resin and tannin compounds. The cells are filled with air and are generally used for furniture and wood products or core materials. Because cork is soft and soft, with low strength and flexible defects, wood products manufacturers almost do not use cork to produce products such as furniture and wood products, and can only act as a supporting role for hardwood; but cork has a short growth cycle and its price ratio Hardwood is much cheaper and more affordable. Based on this, how to remove the air, resin and tannin compounds inside the cork, and change the soft wood softness, low density and low hardness are the technical problems that researchers need to solve urgently.
发明内容Summary of the invention
为了解决上述技术问题,对软木的充分利用,本发明研究一种改善软木质地柔软,排除软木内的树脂和单宁化合物,使其变成材质硬朗、强度高耐磨及承受力度大的硬木的方法,该方法主要为软木压密变为硬木时通入蒸汽方法。 In order to solve the above technical problems and fully utilize the cork, the present invention studies an improvement of the softness of the softwood, and excludes the resin and the tannin compound in the softwood, so that it becomes a hardwood with high hardness, high wear resistance and high strength. In the method, the method is mainly a steaming method when the cork is compacted into a hardwood.
技术解决方案Technical solution
本发明具体技术方案如下:The specific technical solutions of the present invention are as follows:
本发明提供一种软木压密变为硬木时通入蒸汽方法,该方法包括如下步骤: The invention provides a steaming method for softwood compaction into hardwood, the method comprising the following steps:
a.高温高压处理:将软木在一定温度下,施加一定的压力,并且在间隔或连续通入蒸汽的条件下进行高温高压处理;a. High temperature and high pressure treatment: applying a certain pressure to the cork at a certain temperature, and performing high temperature and high pressure treatment under the condition of intermittent or continuous steam introduction;
b.续压处理:将经过高温高压处理后的软木,在一定温度下,施加一定压力,并且在间隔或连续通入蒸汽的条件下进行续压处理。b. Continuous pressure treatment: The cork after high temperature and high pressure treatment is applied with a certain pressure at a certain temperature, and the continuous pressure treatment is carried out under the condition of intermittent or continuous steam introduction.
进一步改进的方案中,所述软木压密变为硬木时通入蒸汽方法,包括以下步骤:In a further improved solution, the method of introducing steam into the hardwood when the cork is compacted comprises the following steps:
a.高温高压处理:将软木在温度为120-150℃下,施加15-35 kg/cm2 的压力,并且在间隔或连续通入蒸汽的条件下进行高温高压处理,高温高压处理时间为3-10min,通入蒸汽的时间不大于高温高压处理的时间;a. High temperature and high pressure treatment: the cork is applied at a temperature of 120-150 ° C, a pressure of 15-35 kg / cm 2 , and high temperature and high pressure treatment under the condition of continuous or continuous steam, high temperature and high pressure treatment time is 3 -10min, the time of steaming is not greater than the time of high temperature and high pressure treatment;
b.续压处理:将经过高温高压处理后的软木,在温度为160-190℃下,施加15-35 kg/cm2 压力,并且在间隔或连续通入蒸汽的条件下进行续压处理,续压处理的时间为4-10min,通入蒸汽的时间不大于续压处理的时间。b. Continuous pressure treatment: the cork after high temperature and high pressure treatment is applied at a temperature of 160-190 ° C, a pressure of 15-35 kg / cm 2 , and continuous pressure treatment under the condition of continuous or continuous steaming, The time for the continuous pressure treatment is 4-10 min, and the time for introducing steam is not more than the time for the continuous pressure treatment.
本发明所指的软木为针叶材,例如松木、杉木、榉木、楠木和樟木等。The softwood referred to in the present invention is a softwood material such as pine, fir, eucalyptus, nanmu and eucalyptus.
本发明通过将软木压密变为硬木时,提供一种通入蒸汽方法,该方法操作简单,本发明提供的通入蒸汽方法采用了两次通入蒸汽,第一次是在高温高压处理过程中,通过压力可循序渐进地将蒸汽注入到软木的内部窝状细胞里,不会导致软木内的细胞迅速干裂破损,而是使其内部结构中原有的空气、树脂和单宁化合物等均匀的排放出来;这样保证制成的硬木更加均匀;第二次通入蒸汽是在续压处理过程中,保证了将软木内部细胞组织里的空气和已有的杂质排出完全;并且软木细胞组织结构受到了外部的强压和蒸汽双重因素,使其变成了线状条形的状态;一边加压一边通入高温蒸汽是让软木吸湿的同时放湿,并彻底排除污染物;通过以上的操作能够将质地柔软,承受力度小,密度低及硬度低的软木变成材质硬朗,强度高耐磨及承受力度大的硬木。The invention provides a steaming method by compacting softwood into hardwood. The method is simple in operation. The steaming method provided by the invention adopts two steam inlets, and the first is in the high temperature and high pressure processing process. In the process, the steam can be injected into the inner nest cells of the cork step by step without causing the cells in the cork to quickly dry and break, but the original air, resin and tannin compounds in the internal structure are uniformly discharged. Out; this ensures that the hardwood made is more uniform; the second steaming is in the process of continuous pressure, which ensures that the air and existing impurities in the cell tissue inside the cork are completely discharged; and the cork cell structure is affected. The external strong pressure and steam double factors make it into a linear strip shape; the high temperature steam is introduced while the pressure is applied, so that the cork is wetted while being wetted, and the pollutants are completely eliminated; the texture can be obtained by the above operation. Soft, low-strength, low-density and low-hardness cork becomes a hard material with high strength and wear resistance and hardwood.
进一步的改进,所述软木经过蒸汽预热养压处理后,再进行高温高压处理,所述蒸汽预热养压处理是向软木所在空间内通入一定时间和温度的蒸汽。According to a further improvement, the cork is subjected to a high temperature and high pressure treatment after being subjected to steam preheating and pressure treatment, and the steam preheating and pressure curing treatment is a steam that is introduced into a space of the cork for a certain time and temperature.
优选地,所述蒸汽预热养压处理过程中,通入蒸汽温度为120-200℃,时间为2-10min。Preferably, during the steam preheating pressure treatment process, the steam temperature is 120-200 ° C and the time is 2-10 min.
由于在显微镜下观察的软木是由成千上万个犹如蜂窝状的死细胞组成,细胞内充满了空气,形成了一个一个的密闭气囊,为了使细胞收缩变小,提高细胞内的压力,提高软木的质地,在通入蒸汽前,要用蒸汽对软木进行预热养压的处理。Since the cork observed under the microscope is composed of thousands of dead cells like a honeycomb, the cells are filled with air, forming a closed airbag. In order to reduce the contraction of the cells, the intracellular pressure is increased and the pressure is increased. For the cork texture, the cork is preheated and pressurized with steam before steam is introduced.
进一步的改进,所述高温高压处理过程中,通入蒸汽的时间为3-10min,优选地,通入蒸汽的温度为140-170℃。In a further improvement, during the high temperature and high pressure treatment, the steam is introduced for a period of 3 to 10 minutes, and preferably, the temperature of the steam is 140 to 170 °C.
所述续压处理过程中,通入蒸汽的时间为4-10min,通入蒸汽的温度为100-150℃。During the continuous pressure treatment, the steam is introduced for 4-10 minutes, and the steam is introduced at a temperature of 100-150 °C.
所述续压处理过程中,加压速度为50-80mm/min。During the continuous pressure treatment, the pressurization speed is 50-80 mm/min.
通过对软木压密变为硬木时通入蒸汽方法各参数的限定,使得制备的硬木具有很高的硬度,并且具有很好的比重和承受力。By defining the parameters of the steaming method when the softwood is compacted into hardwood, the prepared hardwood has high hardness and good specific gravity and bearing capacity.
进一步的改进,所述方法包括如下步骤: In a further improvement, the method comprises the following steps:
(1)蒸汽预热养压处理:向软木所在空间内通入150℃的蒸汽,通入时间为3min;(1) steam preheating pressure treatment: steam into the space where the cork is located, 150 ° C steam, the access time is 3 min;
(2)高温高压处理:将经过蒸汽预热养压处理后的软木在温度为130℃下,施加30 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理的时间为4min,通入蒸汽的时间为4min,通入蒸汽的温度为150℃;(2) High temperature and high pressure treatment: the cork subjected to steam preheating and pressure treatment is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure. The treatment time is 4 min, the steaming time is 4 min, and the steaming temperature is 150 ° C;
(3)续压处理:将经过所述高温高压处理后的软木,在温度为175℃下,施加30 kg/cm2 压力,加压速度为65mm/min,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为5min,通入蒸汽的时间为5min,通入蒸汽的温度为120℃。(3) Continuous pressure treatment: the cork subjected to the high temperature and high pressure treatment is subjected to a pressure of 30 kg/cm 2 at a temperature of 175 ° C, a pressurization speed of 65 mm/min, and under continuous steaming conditions. The continuous pressure treatment was carried out, the time of the continuous pressure treatment was 5 min, the time of steam introduction was 5 min, and the temperature of steam introduction was 120 °C.
为了调节各步骤蒸汽的通入速度,控制好木质的均匀性,所述高温高压处理过程中,通入蒸汽的速度为30-50kg/min;所述续压处理过程中,通入蒸汽的速度为75-100kg/min。In order to adjust the inlet speed of the steam in each step, the uniformity of the wood is controlled, and the speed of the steam is 30-50 kg/min during the high temperature and high pressure treatment; the speed of the steam is introduced during the continuous pressure treatment It is 75-100 kg/min.
为了防止细胞快速干裂破损,高温高压处理过程中,通入蒸汽的同时还通入氧气,所述氧气的通入速度为1-3kg/min。In order to prevent rapid cell breakage and breakage, oxygen is introduced into the steam during high temperature and high pressure treatment, and the oxygen gas is introduced at a rate of 1-3 kg/min.
所述高温高压处理和续压处理步骤还包括通入不同颜色的蒸汽和/或不同气味的蒸汽。The high temperature and high pressure treatment and the continuous pressure treatment step also include introducing steam of different colors and/or steam of different odors.
本发明通过在通入蒸汽同时通入不同颜色和气味的蒸汽,可在软木压密变为硬木过程中,将木材表面变化出各式各样的颜色,也可以木材散发出各种香气;例如紫檀木、花梨木及各种红木等特有味道。The invention can change the surface of the wood into various colors during the process of changing the cork into hardwood by introducing steam with different colors and odors, or the wood can emit various aromas; for example; Special flavors such as rosewood, rosewood and various redwoods.
有益效果 Beneficial effect
本发明的有益效果如下:The beneficial effects of the present invention are as follows:
1.经过上述通入蒸汽方法,可将软木内部窝状细胞变成扁平结构状态,使得经过处理的软木具有硬木的特性及稳定性;1. After the above steaming method, the inner cells of the cork can be turned into a flat structure state, so that the treated cork has the characteristics and stability of the hardwood;
2.经过上述通入蒸汽方法,可排除软木细胞内的空气、树脂、单宁化合物和其他杂质,使得经过处理的软木具有硬木的质地硬朗的特性;2. After the above steaming method, air, resin, tannin compounds and other impurities in the cork cells can be excluded, so that the treated cork has the tough property of hardwood;
3.同时在通入蒸汽时,可将硬木变化出各种各样的颜色、图案和气味的木材。3. At the same time, when steam is introduced, the hardwood can be changed into a variety of colors, patterns and smells of wood.
本发明的实施方式 Embodiments of the invention
实施例1软木压密变为硬木时通入蒸汽方法Example 1 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
a.高温高压处理:将软木在一定温度下,施加一定的压力,并且在间隔通入蒸汽的条件下进行高温高压处理;a. High temperature and high pressure treatment: applying a certain pressure to the cork at a certain temperature, and performing high temperature and high pressure treatment under the condition that steam is introduced at intervals;
b.续压处理:将经过高温高压处理后的软木,在一定温度下,施加一定压力,并且在间隔通入蒸汽的条件下进行续压处理。b. Continuous pressure treatment: the cork after high temperature and high pressure treatment is applied with a certain pressure at a certain temperature, and the continuous pressure treatment is carried out under the condition that steam is introduced at intervals.
实施例2软木压密变为硬木时通入蒸汽方法Example 2 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
(1)蒸汽预热养压处理:向软木所在空间内通入一定时间和温度的蒸汽;(1) Steam preheating and pressure treatment: steam entering a certain time and temperature into the space where the cork is located;
(2)高温高压处理:将软木在一定温度下,施加一定的压力,并且在连续通入蒸汽的条件下进行高温高压处理;(2) High temperature and high pressure treatment: applying a certain pressure to the cork at a certain temperature, and performing high temperature and high pressure treatment under continuous steaming conditions;
(3)续压处理:将经过高温高压处理后的软木,在一定温度下,施加一定压力,并且在连续通入蒸汽的条件下进行续压处理。(3) Continuous pressure treatment: The cork subjected to high temperature and high pressure treatment is subjected to a certain pressure at a certain temperature, and subjected to a continuous pressure treatment under continuous steaming.
实施例3软木压密变为硬木时通入蒸汽方法Example 3 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
a.高温高压处理:将软木在温度为130℃下,施加30 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理时间为4min,通入蒸汽的时间为4min;a. High temperature and high pressure treatment: the cork is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 , and high temperature and high pressure treatment under continuous steaming conditions, high temperature and high pressure treatment time is 4 min, steaming time 4min;
b.续压处理:将经过高温高压处理后的软木,在温度为170℃下,施加30 kg/cm2 压力,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为5min,通入蒸汽的时间为5min。b. Continuous pressure treatment: the cork after high temperature and high pressure treatment is subjected to a pressure of 30 kg/cm 2 at a temperature of 170 ° C, and the continuous pressure treatment is carried out under continuous steaming, and the time of the continuous pressure treatment is 5 min, the steaming time was 5 min.
实施例4软木压密变为硬木时通入蒸汽方法Example 4 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
a.高温高压处理:将软木在温度为140℃下,施加20 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理时间为5min,通入蒸汽的时间为5min,通入蒸汽的温度为140℃;a. High temperature and high pressure treatment: the cork is applied at a temperature of 140 ° C, a pressure of 20 kg / cm 2 , and high temperature and high pressure treatment under continuous steaming conditions, high temperature and high pressure treatment time is 5 min, steaming time 5 min, the temperature of steaming is 140 ° C;
b.续压处理:将经过高温高压处理后的软木,在温度为190℃下,施加15 kg/cm2 压力,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为6min,通入蒸汽的时间为6min,通入蒸汽的温度为140℃。b. Continuous pressure treatment: the cork after high temperature and high pressure treatment is subjected to a pressure of 15 kg/cm 2 at a temperature of 190 ° C, and the continuous pressure treatment is carried out under continuous steaming, and the time of the continuous pressure treatment is At 6 min, the steaming time was 6 min, and the steaming temperature was 140 °C.
实施例5软木压密变为硬木时通入蒸汽方法Example 5 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
a.高温高压处理:将软木在温度为140℃下,施加35 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理时间为3min,通入蒸汽的时间为3min,通入蒸汽的温度为140℃;a. High temperature and high pressure treatment: the cork is applied at a temperature of 140 ° C, a pressure of 35 kg / cm 2 , and high temperature and high pressure treatment under continuous steaming conditions, high temperature and high pressure treatment time is 3 min, steaming time 3 min, the temperature of steaming is 140 ° C;
b.续压处理:将经过高温高压处理后的软木,在温度为180℃下,施加20 kg/cm2 压力,加压速度为80mm/min,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为8min,通入蒸汽的时间为8min,通入蒸汽的温度为100℃。b. Continuous pressure treatment: the cork subjected to high temperature and high pressure treatment is subjected to a pressure of 20 kg/cm 2 at a temperature of 180 ° C, a pressurization speed of 80 mm/min, and a continuous pressure under continuous steaming conditions. The treatment, the time of the continuous pressure treatment was 8 min, the time of steam introduction was 8 min, and the temperature of steam introduction was 100 °C.
实施例6软木压密变为硬木时通入蒸汽方法Example 6 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
(1)蒸汽预热养压处理:向软木所在空间内通入150℃的蒸汽,通入时间为3min;(1) steam preheating pressure treatment: steam into the space where the cork is located, 150 ° C steam, the access time is 3 min;
(2)高温高压处理:将经过蒸汽预热养压处理后的软木在温度为130℃下,施加30 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理的时间为4min,通入蒸汽的时间为4min,通入蒸汽的温度为150℃;(2) High temperature and high pressure treatment: the cork subjected to steam preheating and pressure treatment is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure. The treatment time is 4 min, the steaming time is 4 min, and the steaming temperature is 150 ° C;
(3)续压处理:将经过所述高温高压处理后的软木,在温度为175℃下,施加30 kg/cm2 压力,加压速度为65mm/min,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为5min,通入蒸汽的时间为5min,通入蒸汽的温度为120℃。(3) Continuous pressure treatment: the cork subjected to the high temperature and high pressure treatment is subjected to a pressure of 30 kg/cm 2 at a temperature of 175 ° C, a pressurization speed of 65 mm/min, and under continuous steaming conditions. The continuous pressure treatment was carried out, the time of the continuous pressure treatment was 5 min, the time of steam introduction was 5 min, and the temperature of steam introduction was 120 °C.
实施例7软木压密变为硬木时通入蒸汽方法Example 7 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
(1)蒸汽预热养压处理:向软木所在空间内通入170℃的蒸汽,通入时间为6min;(1) Steam preheating and pressure treatment: 170 ° C steam is introduced into the space where the cork is located, and the access time is 6 min;
(2)高温高压处理:将经过蒸汽预热养压处理后的软木在温度为120℃下,施加30 kg/cm2 的压力,并且在连续通入黄色蒸汽和紫檀木气味蒸汽的条件下进行高温高压处理,高温高压处理的时间为5min,通入蒸汽的时间为5min,通入蒸汽的温度为170℃;(2) High temperature and high pressure treatment: the cork subjected to steam preheating and pressure treatment is applied at a temperature of 120 ° C, a pressure of 30 kg / cm 2 is applied, and continuous flow of yellow steam and rosewood odor steam is carried out. High temperature and high pressure treatment, high temperature and high pressure treatment time is 5min, steaming time is 5min, steaming temperature is 170 °C;
(3)续压处理:将经过所述高温高压处理后的软木,在温度为170℃下,施加20 kg/cm2 压力,加压速度为60mm/min,并且在连续通入黄色蒸汽和紫檀木气味蒸汽的条件下进行续压处理,续压处理的时间为6min,通入蒸汽的时间为6min,通入蒸汽的温度为130℃。(3) Continuous pressure treatment: the cork subjected to the high temperature and high pressure treatment is subjected to a pressure of 20 kg/cm 2 at a temperature of 170 ° C, a pressurization speed of 60 mm/min, and continuous passage of yellow steam and red sandalwood The continuous pressure treatment was carried out under the condition of wood odor steam, the time of the continuous pressure treatment was 6 min, the time of steam introduction was 6 min, and the temperature of steam introduction was 130 °C.
实施例8软木压密变为硬木时通入蒸汽方法Example 8 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
(1)蒸汽预热养压处理:向软木所在空间内通入200℃的蒸汽,通入时间为4min;(1) steam preheating pressure treatment: steam into the space where the cork is located, 200 ° C steam, the access time is 4 min;
(2)高温高压处理:将经过蒸汽预热养压处理后的软木在温度为150℃下,施加15 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理的时间为7min,通入蒸汽的时间为6min,通入蒸汽的温度为160℃;(2) High temperature and high pressure treatment: the cork after steam preheating and pressure treatment is applied at a temperature of 150 ° C, a pressure of 15 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure. The treatment time is 7 min, the steaming time is 6 min, and the steaming temperature is 160 ° C;
(3)续压处理:将经过所述高温高压处理后的软木,在温度为160℃下,施加25 kg/cm2 压力,加压速度为80mm/min,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为4min,通入蒸汽的时间为4min,通入蒸汽的温度为150℃。(3) Continuous pressure treatment: the cork subjected to the high temperature and high pressure treatment is subjected to a pressure of 25 kg/cm 2 at a temperature of 160 ° C, a pressurization speed of 80 mm/min, and under continuous steaming conditions. The continuous pressure treatment was carried out, the time of the continuous pressure treatment was 4 minutes, the steaming time was 4 minutes, and the temperature of the steam was 150 °C.
实施例9软木压密变为硬木时通入蒸汽方法Example 9 Method for introducing steam when cork compaction is changed into hardwood
该方法包括如下步骤:The method comprises the following steps:
(1)蒸汽预热养压处理:向软木所在空间内通入130℃的蒸汽,通入时间为10min;(1) Steam preheating and pressure treatment: steam of 130 ° C is introduced into the space where the cork is located, and the access time is 10 min;
(2)高温高压处理:将经过蒸汽预热养压处理后的软木在温度为125℃下,施加30 kg/cm2 的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理的时间为10min,通入蒸汽的时间为10min,通入蒸汽的温度为150℃;(2) High temperature and high pressure treatment: the cork subjected to steam preheating and pressure treatment is applied at a temperature of 125 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure. The treatment time is 10 min, the steaming time is 10 min, and the steaming temperature is 150 ° C;
(3)续压处理:将经过所述高温高压处理后的软木,在温度为170℃下,施加30 kg/cm2 压力,加压速度为70mm/min,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为10min,通入蒸汽的时间为10min,通入蒸汽的温度为120℃。(3) Continuous pressure treatment: the cork subjected to the high temperature and high pressure treatment is subjected to a pressure of 30 kg/cm 2 at a temperature of 170 ° C, a pressurization speed of 70 mm/min, and under continuous steaming conditions. The continuous pressure treatment was carried out, the time of the continuous pressure treatment was 10 minutes, the time of steam introduction was 10 minutes, and the temperature of steam introduction was 120 °C.
实验例1高温高压处理各参数的考察 Experimental Example 1 Investigation of various parameters of high temperature and high pressure treatment
将高温高压处理的时间设计成0min、2min、3min、6min、10min和12min,6个水平,其余步骤按照实施例9的方法制备,对制备后的硬木比重和蜂窝状态组织结构含量进行考察,考察结果见表1;The time of high temperature and high pressure treatment was designed to be 0 min, 2 min, 3 min, 6 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9. The prepared hardwood specific gravity and the cellular state structure were investigated. The results are shown in Table 1;
将高温高压处理的温度设计成110℃、120℃、135℃、150℃和160℃,5个水平,其余步骤按照实施例9的方法制备,对制备后的硬木比重和蜂窝状态组织结构含量进行考察,考察结果见表1;The temperature of the high temperature and high pressure treatment was designed to be 10 levels of 110 ° C, 120 ° C, 135 ° C, 150 ° C and 160 ° C, and the remaining steps were prepared according to the method of Example 9, and the prepared hardwood specific gravity and the cellular state structure content were determined. Inspection, the results of the inspection are shown in Table 1;
将高温高压处理的压力设计成10 kg/cm2 、15 kg/cm2 、25 kg/cm2 、35 kg/cm2 和45 kg/cm2 ,5个水平,其余步骤按照实施例9的方法制备,对制备后的硬木比重和蜂窝状态组织结构含量进行考察,考察结果见表1;The high temperature and high pressure treatment pressure was designed to be 10 kg/cm 2 , 15 kg/cm 2 , 25 kg/cm 2 , 35 kg/cm 2 and 45 kg/cm 2 , 5 levels, and the remaining steps were as follows according to the method of Example 9. Preparation, the specific gravity of the prepared hardwood and the cellular structure of the honeycomb structure were investigated, and the results are shown in Table 1;
表1 高温高压处理 各 参数的考察结果 Table 1 High temperature and high pressure treatment
考察指标 Survey indicator 硬木比重( kg/m Hardwood specific gravity (kg/m 33  ) 蜂窝状态组织结构含量(%) Cellular state tissue structure content (%)
时间( min ) Time ( min ) 0 0 70 70 98 98
2 2 360 360 87 87
3 3 400 400 71 71
6 6 423 423 63 63
10 10 450 450 53 53
12 12 455 455 51 51
温度( ℃ ) Temperature ( °C ) 110 110 340 340 83 83
120 120 415 415 72 72
135 135 433 433 62 62
150 150 460 460 50 50
160 160 462 462 50 50
压力(kg/cm2Pressure (kg/cm 2 ) 10 10 356 356 85 85
15 15 415 415 74 74
25 25 437 437 65 65
35 35 472 472 54 54
45 45 480 480 52 52
从表1中可以看出高温高压处理过程中的时间、温度、和压力及对硬木比重和蜂窝状态组织结构含量具有显著的影响,只有当时间控制在10min内,温度控制在150℃,压力控制在35 kg/cm2 , 才能够低成本、低消耗地将木材的比重提高到450 kg/m3 左右,并且能将原料软木中50%左右的蜂窝状态组织结构变成实芯线状组织结构;当温度、压力和处理时间继续升高,投入和产出不成正比。It can be seen from Table 1 that the time, temperature, and pressure during the high temperature and high pressure treatment have a significant effect on the specific gravity of the hardwood and the cellular structure. Only when the time is controlled within 10 minutes, the temperature is controlled at 150 °C, and the pressure is controlled. At 35 kg/cm 2 , the specific gravity of the wood can be increased to about 450 kg/m 3 at low cost and low consumption, and about 50% of the honeycomb structure in the raw material cork can be converted into a solid core structure. When temperature, pressure, and processing time continue to rise, inputs and outputs are not directly proportional.
实验例2高温高压处理过程中通入蒸汽时间和蒸汽温度的考察Experimental Example 2 Investigation of steaming time and steam temperature during high temperature and high pressure treatment
将高温高压处理过程中通入蒸汽的时间设计成0min、2min、3min、6min、10min和12min,6个水平,其余步骤按照实施例9的方法制备,对制备后的硬木内部结构中的树脂和单宁化合物的含量进行考察,考察结果见表2;The steaming time during the high temperature and high pressure treatment was designed to be 0 min, 2 min, 3 min, 6 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9, and the resin in the internal structure of the prepared hardwood and The content of tannin compounds was investigated, and the results are shown in Table 2;
将高温高压处理过程中的通入蒸汽的温度设计成130℃、140℃、150℃、170℃和180℃,5个水平,其余步骤按照实施例9的方法制备,对制备后的硬木内部结构中的树脂和单宁化合物的含量进行考察,考察结果见表2;The temperature of the steam entering during the high temperature and high pressure treatment was designed to be 5 levels of 130 ° C, 140 ° C, 150 ° C, 170 ° C and 180 ° C, and the remaining steps were prepared according to the method of Example 9, and the internal structure of the prepared hardwood was prepared. The content of resin and tannin compound was investigated, and the results are shown in Table 2;
表2高温高压处理过程中通入蒸汽时间和蒸汽温度的考察结果 Table 2 Investigation results of steaming time and steam temperature during high temperature and high pressure treatment
考察指标 Survey indicator 树脂含量( % ) Resin content (%) 单宁化合物含量( % ) Tannin compound content (%)
时间( min ) Time ( min ) 0 0 2.03 2.03 10.2 10.2
2 2 1.73 1.73 8.8 8.8
3 3 1.57 1.57 7.9 7.9
6 6 1.13 1.13 6.2 6.2
10 10 0.78 0.78 4.1 4.1
12 12 0.75 0.75 4.0 4.0
130 130 1.59 1.59 8.1 8.1
140 140 1.41 1.41 6.7 6.7
温度( ℃ ) Temperature ( °C ) 150 150 1.19 1.19 5.8 5.8
170 170 0.76 0.76 4.0 4.0
180 180 0.75 0.75 3.9 3.9
从表中可以看出,在高温高压处理过程中,如果不通入蒸汽,不能排除软木中的树脂和单宁化合物;随着通入蒸汽时间和蒸汽温度的增加,树脂和单宁化合物的含量显著降低,当通入蒸汽时间达到10min或温度达到170℃时,树脂和单宁化合物的含量已降低了60%左右,继续通入蒸汽或提高温度,对树脂和单宁化合物的含量影响不大,投入和产出不成正比;所以高温高压处理过程中通入蒸汽的时间控制在3-10min内,蒸汽温度应控制在140-170℃内。It can be seen from the table that in the process of high temperature and high pressure treatment, the resin and tannin compounds in the softwood cannot be excluded if steam is not introduced; the content of resin and tannin compound is remarkable as the steaming time and steam temperature increase. Decrease, when the steaming time reaches 10min or the temperature reaches 170°C, the content of resin and tannin compound has been reduced by about 60%. Continue to steam or increase the temperature has little effect on the content of resin and tannin compound. The input and output are not proportional; therefore, the time for steam introduction during high temperature and high pressure treatment is controlled within 3-10min, and the steam temperature should be controlled within 140-170 °C.
实验例3续压处理各参数的考察 Experimental Example 3 Investigation of various parameters of continuous pressure treatment
将续压处理的时间设计成0min、3min、4min、7min、10min和12min,6个水平,其余步骤按照实施例9的方法制备,对制备后的硬木比重和蜂窝状态组织结构含量进行考察,考察结果见表3; The time of the continuous pressure treatment was designed to be 0 min, 3 min, 4 min, 7 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9. The prepared hardwood specific gravity and the cellular state structure content were investigated. The results are shown in Table 3;
将续压处理的温度设计成150℃,160℃、175℃、190℃和200℃,5个水平,其余步骤按照实施例9的方法制备,对制备后的硬木比重和蜂窝状态组织结构含量进行考察,考察结果见表3; The temperature of the continuous pressure treatment was designed to be 150 ° C, 160 ° C, 175 ° C, 190 ° C and 200 ° C, 5 levels, and the remaining steps were prepared according to the method of Example 9, and the prepared hardwood specific gravity and the cellular state structure content were determined. Inspection, the results of the investigation are shown in Table 3;
将续压处理的压力设计成10 kg/cm2 、15 kg/cm2 、25 kg/cm2 、35 kg/cm2 和45 kg/cm2 ,5个水平,其余步骤按照实施例9的方法制备,对制备后的硬木比重和蜂窝状态组织结构含量进行考察,考察结果见表3;The pressure of the continuous pressure treatment was designed to be 10 kg/cm 2 , 15 kg/cm 2 , 25 kg/cm 2 , 35 kg/cm 2 and 45 kg/cm 2 , 5 levels, and the remaining steps were as follows according to the method of Example 9. Preparation, the specific gravity of the prepared hardwood and the cellular structure of the honeycomb structure were investigated, and the results are shown in Table 3;
表3续压处理 各 参数的考察结果 Table 3 Continued Pressure Treatment Results of each parameter
考察指标 Survey indicator 硬木比重( kg/m Hardwood specific gravity (kg/m 33  ) 蜂窝状态组织结构含量( % ) Cellular state structure content (%)
时间(min) Time (min) 0 0 450 450 50 50
3 3 520 520 45 45
4 4 600 600 33 33
7 7 640 640 24 twenty four
10 10 700 700 13 13
12 12 710 710 11 11
温度( ℃ ) Temperature ( °C ) 150 150 550 550 44 44
160 160 620 620 32 32
175 175 680 680 20 20
190 190 720 720 9 9
200 200 725 725 8 8
压力(kg/cm2Pressure (kg/cm 2 ) 10 10 560 560 38 38
15 15 610 610 29 29
25 25 660 660 14 14
35 35 710 710 5 5
45 45 720 720 4 4
从表中可以看出,续压处理的时间、温度和压力对制备的硬木比重和及蜂窝状态组织结构含量含量存在显著影响,只有当时间控制在10min内,温度控制在190℃内,压力控制在35 kg/cm2 的范围内,才能够低成本、低消耗地提供硬木的比重,排除硬木中大部分杂质,并且才能将蜂窝状组织结构大部分地变成线状条形组织结构;当温度、压力和处理时间继续升高,投入和产出不成正比。It can be seen from the table that the time, temperature and pressure of the continuous pressure treatment have a significant influence on the specific gravity of the prepared hardwood and the content of the cellular structure. Only when the time is controlled within 10 minutes, the temperature is controlled within 190 °C, and the pressure is controlled. In the range of 35 kg/cm 2 , the specific gravity of hardwood can be provided at low cost and low consumption, most impurities in hardwood can be excluded, and the honeycomb structure can be largely changed into a linear strip structure; Temperature, pressure and processing time continue to rise, and inputs and outputs are not directly proportional.
实验例4续压处理过程中通入蒸汽温度和时间的考察 Experimental Example 4 Investigation of steam temperature and time during continuous pressure treatment
将续压处理过程中通入蒸汽的时间设计成0min、3min、4min、7min、10min和12min,6个水平,其余步骤按照实施例9的方法制备,对制备后的硬木内部结构中的树脂和单宁化合物的含量进行考察,考察结果见表4;The steaming time during the continuous pressure treatment was designed to be 0 min, 3 min, 4 min, 7 min, 10 min and 12 min, 6 levels, and the remaining steps were prepared according to the method of Example 9, and the resin in the prepared hardwood internal structure and The content of tannin compounds was investigated, and the results of the investigation are shown in Table 4;
将续压处理过程中通入蒸汽的温度设计成90℃,100℃、120℃、150℃和160℃,5个水平,其余步骤按照实施例9的方法制备,对制备后的硬木内部结构中的树脂和单宁化合物的含量进行考察,考察结果见表4;The temperature of the steam introduced during the continuous pressure treatment was designed to be 90 ° C, 100 ° C, 120 ° C, 150 ° C and 160 ° C, 5 levels, and the remaining steps were prepared according to the method of Example 9, for the internal structure of the prepared hardwood. The content of resin and tannin compound was investigated, and the results are shown in Table 4;
表4续压处理过程中通入蒸汽时间和温度的考察结果 Table 4 Investigation results of steaming time and temperature during continuous pressure treatment
考察指标 Survey indicator 树脂含量( % ) Resin content (%) 单宁化合物含量( % ) Tannin compound content (%)
时间(min) Time (min) 0 0 0.73 0.73 3.9 3.9
3 3 0.62 0.62 2.7 2.7
4 4 0.51 0.51 2.1 2.1
7 7 0.37 0.37 1.6 1.6
10 10 0.25 0.25 0.9 0.9
12 12 0.23 0.23 0.8 0.8
温度( ℃ ) Temperature ( °C ) 90 90 0.65 0.65 3.6 3.6
100 100 0.52 0.52 2.4 2.4
120 120 0.36 0.36 1.7 1.7
150 150 0.26 0.26 0.9 0.9
160 160 0.25 0.25 0.9 0.9
从表中可以看出,当续压过程中不通入蒸汽,整个续压过程可以排除极少量的树脂和单宁化合物,当再次通入蒸汽后,可将高温高压处理过程中通入蒸汽后,剩余的树脂和单宁化合物排除;随着时间和蒸汽温度的升高,排除的越多,但当时间增加到10min或蒸汽温度升高到150℃,树脂和单宁化合物的含量与未通入蒸汽时相比,已降低90%多,继续增加通入蒸汽时间和蒸汽温度后,投入和产出不成正比,所以将续压处理过程中通入蒸汽时间控制在4-10min,蒸汽温度控制在100-150℃。It can be seen from the table that when steam is not introduced during the continuous pressure process, the entire continuous pressure process can eliminate a very small amount of resin and tannin compound. When the steam is re-introduced, the steam can be introduced into the high-temperature and high-pressure treatment process. The remaining resin and tannin compound are excluded; the more the time is removed and the temperature of the steam increases, but when the time increases to 10 min or the steam temperature rises to 150 ° C, the content of the resin and tannin compound does not pass. Compared with steam, it has been reduced by more than 90%. After increasing the steaming time and steam temperature, the input and output are not proportional. Therefore, the steaming time during the continuous pressure treatment is controlled at 4-10min, and the steam temperature is controlled. 100-150 ° C.

Claims (9)

  1. 一种软木压密变为硬木时通入蒸汽方法,其特征在于,所述方法包括如下步骤: A steaming method for cork compaction into hardwood, characterized in that the method comprises the following steps:
    a.高温高压处理:将软木在一定温度下,施加一定的压力,并且在间隔或连续通入蒸汽的条件下进行高温高压处理;a. High temperature and high pressure treatment: applying a certain pressure to the cork at a certain temperature, and performing high temperature and high pressure treatment under the condition of intermittent or continuous steam introduction;
    b.续压处理:将经过高温高压处理后的软木,在一定温度下,施加一定压力,并且在间隔或连续通入蒸汽的条件下进行续压处理。b. Continuous pressure treatment: The cork after high temperature and high pressure treatment is applied with a certain pressure at a certain temperature, and the continuous pressure treatment is carried out under the condition of intermittent or continuous steam introduction.
  2. 如权利要求1所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述方法包括如下步骤: The method of steaming a softwood compacted into a hardwood according to claim 1, wherein the method comprises the steps of:
    a.高温高压处理:将软木在温度为120-150℃下,施加15-35kg/cm2 的压力,并且在间隔或连续通入蒸汽的条件下进行高温高压处理,高温高压处理时间为3-10min,通入蒸汽的时间不大于高温高压处理的时间;a. High temperature and high pressure treatment: the cork is applied at a temperature of 120-150 ° C, a pressure of 15-35 kg / cm 2 , and high temperature and high pressure treatment under the condition of continuous or continuous steam, high temperature and high pressure treatment time is 3- 10 minutes, the time of steaming is not greater than the time of high temperature and high pressure treatment;
    b.续压处理:将经过高温高压处理后的软木,在温度为160-190℃下,施加15-35kg/cm2 压力,并且在间隔或连续通入蒸汽的条件下进行续压处理,续压处理的时间为4-10min,通入蒸汽的时间不大于续压处理的时间。b. Continuous pressure treatment: the cork after high temperature and high pressure treatment is applied at a temperature of 160-190 ° C, a pressure of 15-35 kg / cm 2 is applied, and the continuous pressure treatment is carried out under the condition of continuous or continuous steaming, continued The time for the pressure treatment is 4-10 min, and the time for introducing steam is not more than the time for the continuous pressure treatment.
  3. 如权利要求1-2任一所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述软木经过蒸汽预热养压处理后,再进行高温高压处理,所述蒸汽预热养压处理是向软木所在空间内通入一定时间和温度的蒸汽。 The method for introducing steam into a hardwood when the cork is compacted into a hardwood according to any one of claims 1 to 2, wherein the cork is subjected to a high temperature and high pressure treatment after being subjected to steam preheating and pressure treatment, and the steam is preheated. The pressure-raising treatment is steam that is introduced into the space where the cork is located for a certain period of time and temperature.
  4. 如权利要求3所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述蒸汽预热养压处理过程中,通入蒸汽温度为120-200℃,时间为2-10min。 The steaming method for cork compaction into hardwood according to claim 3, wherein during the steam preheating pressure treatment, the steam temperature is 120-200 ° C and the time is 2-10 min.
  5. 如权利要求2所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述高温高压处理过程中,通入蒸汽的时间为3-10min,优选地,通入蒸汽的温度为140-170℃。 The steaming method for cork compaction into hardwood according to claim 2, wherein during the high temperature and high pressure treatment, the steam is introduced for 3-10 minutes, preferably, the temperature of the steam is 140-170 ° C.
  6. 如权利要求2所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述续压处理过程中,通入蒸汽的时间为4-10min,通入蒸汽的温度为100-150℃。The steaming method for cork compaction into hardwood according to claim 2, wherein during the continuous pressure treatment, steam is introduced for 4-10 minutes, and steam is introduced at a temperature of 100-150. °C.
  7. 如权利要求2所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述续压处理过程中,加压速度为50-80mm/min。 The method of introducing steam when softwood compaction is changed into hardwood according to claim 2, wherein the pressurization speed is 50-80 mm/min during the continuous pressure treatment.
  8. 如权利要求3所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述方法包括如下步骤: The method of steaming a softwood compacted into a hardwood according to claim 3, wherein the method comprises the steps of:
    (1)蒸汽预热养压处理:向软木所在空间内通入150℃的蒸汽,通入时间为3min;(1) steam preheating pressure treatment: steam into the space where the cork is located, 150 ° C steam, the access time is 3 min;
    (2)高温高压处理:将经过蒸汽预热养压处理后的软木在温度为130℃下,施加30kg/cm2的压力,并且在连续通入蒸汽的条件下进行高温高压处理,高温高压处理的时间为4min,通入蒸汽的时间为4min,通入蒸汽的温度为150℃;(2) High temperature and high pressure treatment: the cork after steam preheating and pressure treatment is applied at a temperature of 130 ° C, a pressure of 30 kg / cm 2 is applied, and high temperature and high pressure treatment is carried out under continuous steaming conditions, high temperature and high pressure treatment. The time is 4 min, the steaming time is 4 min, and the steaming temperature is 150 ° C;
    (3)续压处理:将经过所述高温高压处理后的软木,在温度为175℃下,施加30kg/cm2压力,加压速度为65mm/min,并且在连续通入蒸汽的条件下进行续压处理,续压处理的时间为5min,通入蒸汽的时间为5min,通入蒸汽的温度为120℃。(3) Continuous pressure treatment: the cork subjected to the high-temperature and high-pressure treatment is subjected to a pressure of 30 kg/cm 2 at a temperature of 175 ° C, a pressurization speed of 65 mm/min, and under continuous steaming. The continuous pressure treatment, the time of the continuous pressure treatment is 5 min, the time of steam introduction is 5 min, and the temperature of steam introduction is 120 °C.
  9. 如权利要求2所述的软木压密变为硬木时通入蒸汽方法,其特征在于,所述高温高压处理和续压处理步骤还包括通入不同颜色的蒸汽和/或不同气味的蒸汽。The steaming method for cork compaction into hardwood according to claim 2, wherein said high temperature and high pressure treatment and said continuous pressure treatment step further comprises introducing steam of different colors and/or steam of different odors.
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