WO2016081148A1 - Improved catalytic fast pyrolysis process - Google Patents

Improved catalytic fast pyrolysis process Download PDF

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Publication number
WO2016081148A1
WO2016081148A1 PCT/US2015/056946 US2015056946W WO2016081148A1 WO 2016081148 A1 WO2016081148 A1 WO 2016081148A1 US 2015056946 W US2015056946 W US 2015056946W WO 2016081148 A1 WO2016081148 A1 WO 2016081148A1
Authority
WO
WIPO (PCT)
Prior art keywords
zsm
toluene
feeding
stream
combinations
Prior art date
Application number
PCT/US2015/056946
Other languages
English (en)
French (fr)
Inventor
Charles Sorensen
Original Assignee
Anellotech, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anellotech, Inc. filed Critical Anellotech, Inc.
Priority to EP15860567.5A priority Critical patent/EP3221425A4/en
Priority to CN201580061202.XA priority patent/CN107207968A/zh
Priority to AU2015350437A priority patent/AU2015350437A1/en
Priority to BR112017010285A priority patent/BR112017010285A2/pt
Priority to MX2017006108A priority patent/MX2017006108A/es
Priority to JP2017527291A priority patent/JP2018504465A/ja
Priority to KR1020177016788A priority patent/KR20170102237A/ko
Priority to CA2964268A priority patent/CA2964268A1/en
Publication of WO2016081148A1 publication Critical patent/WO2016081148A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Definitions

  • the toluene can be converted to an equilibrium mixture of benzene and xylenes by disproportionation in a fixed bed reactor operating at elevated pressure and in the presence of added hydrogen gas.
  • disproportionation process is disclosed in U. S. Patents No.
  • Biomass is conventionally defined as the living or recently dead biological material that can be converted for use as fuel or for industrial production.
  • the criterion as biomass is that the material should be recently participating in the carbon cycle so that the release of carbon in the combustion process results in no net increase averaged over a reasonably short period of time (for this reason, fossil fuels such as peat, lignite and coal are not considered biomass by this definition as they contain carbon that has not participated in the carbon cycle for a long time so that their combustion results in a net increase in atmospheric carbon dioxide).
  • biomass refers to plant matter grown for use as biofuel, but it also includes plant or animal matter used for production of fibers, chemicals or heat.
  • the catalyst composition required in the CFP process fluidized bed reactor of the present invention comprises a crystalline molecular sieve characterized by an SAR greater than 12 and a Constraint Index from 1 to 12.
  • these crystalline molecular sieves are those having the structure of ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-50 or combinations thereof.
  • the catalyst composition comprises a crystalline molecular sieve characterized by an SAR from greater than 12 to 240 and a Constraint Index from 5 to 10, such as, for example, molecular sieves having the structure of ZSM-5, ZSM-11, ZSM-22, ZSM-23 or combinations thereof.
  • the relative proportion of suitable crystalline molecular sieve of the total catalyst composition may vary widely with the molecular sieve content ranging from 30 to 90 percent by weight and more usually in the range of 40 to 70 percent by weight of the composition.
  • the catalyst composition may be in the form of an extrudate, beads or f!uidizab!e microspheres.
  • a portion of the stream may be taken as a purge of, for example, from 5 to 50 , via line 17 in order to prevent the buildup of inert materials in the system.
  • the stream of line 10 is passed to product recovery system 150 for recovery of benzene, toluene, xylenes and other aromatics.
  • product recovery system 150 From product recovery system 150 is obtained benzene via line 11, xylenes via line 12, toluene via line 14, and other aromatics via line 13.
  • At least a portion, such as from 5 to 99 , for example from 10 to 95 , such as from 30 to 50 , of the contents of line 14 is passed to CFP reactor 110 via line 3 as recycle.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
PCT/US2015/056946 2014-11-20 2015-10-22 Improved catalytic fast pyrolysis process WO2016081148A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP15860567.5A EP3221425A4 (en) 2014-11-20 2015-10-22 Improved catalytic fast pyrolysis process
CN201580061202.XA CN107207968A (zh) 2014-11-20 2015-10-22 改进的催化快速热解工艺
AU2015350437A AU2015350437A1 (en) 2014-11-20 2015-10-22 Improved catalytic fast pyrolysis process
BR112017010285A BR112017010285A2 (pt) 2014-11-20 2015-10-22 processo aprimorado de pirólise catalítica rápida
MX2017006108A MX2017006108A (es) 2014-11-20 2015-10-22 Proceso de pirolisis rapida catalitica mejorada.
JP2017527291A JP2018504465A (ja) 2014-11-20 2015-10-22 改良された触媒急速熱分解方法
KR1020177016788A KR20170102237A (ko) 2014-11-20 2015-10-22 개선된 촉매성 급속 열분해 방법
CA2964268A CA2964268A1 (en) 2014-11-20 2015-10-22 Improved catalytic fast pyrolysis process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462082419P 2014-11-20 2014-11-20
US62/082,419 2014-11-20

Publications (1)

Publication Number Publication Date
WO2016081148A1 true WO2016081148A1 (en) 2016-05-26

Family

ID=56009558

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2015/056946 WO2016081148A1 (en) 2014-11-20 2015-10-22 Improved catalytic fast pyrolysis process

Country Status (10)

Country Link
US (1) US20160145496A1 (es)
EP (1) EP3221425A4 (es)
JP (1) JP2018504465A (es)
KR (1) KR20170102237A (es)
CN (1) CN107207968A (es)
AU (1) AU2015350437A1 (es)
BR (1) BR112017010285A2 (es)
CA (1) CA2964268A1 (es)
MX (1) MX2017006108A (es)
WO (1) WO2016081148A1 (es)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106244184A (zh) * 2016-08-22 2016-12-21 华北电力大学 一种生物质热解气催化裂解制备btx的方法
CN106244185A (zh) * 2016-08-22 2016-12-21 华北电力大学 一种生物质催化热解制备btx的方法

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI125978B (fi) * 2013-02-22 2016-05-13 Endev Oy Kiertomassakuivuri ja menetelmä märän lietteen kuivaamiseksi
CN105814009B (zh) * 2013-12-20 2021-11-12 埃克森美孚研究工程公司 用于将含氧化合物选择性转化成芳香族化合物的催化剂
CN107663002A (zh) * 2016-07-28 2018-02-06 华云新能源科技（深圳）有限公司 一种污泥裂解处理方法及设备
US10364322B2 (en) 2017-01-25 2019-07-30 Alliance For Sustainable Energy, Llc Naphthalene-containing polymers and methods of making the same
AR118764A1 (es) * 2019-04-25 2021-10-27 Tubis Eng Gmbh Proceso continuo para producir hidrocarburos a partir de productos orgánicos naturales o sintéticos
US12043801B2 (en) 2021-06-30 2024-07-23 E2 Technologies, Llc Apparatus and processes for pyrolysis of plastic feeds

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851604A (en) * 1987-09-02 1989-07-25 Mobil Oil Corp. Toluene disproportionation
US20130023706A1 (en) * 2008-03-04 2013-01-24 University Of Massachusetts Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds
US20140027265A1 (en) * 2012-07-27 2014-01-30 Anellotech, Inc. Fast catalytic pyrolysis with recycle of side products
US20140238835A1 (en) * 2013-02-26 2014-08-28 The United States Of America, As Represented By The Secretary Of Agriculture Methods For Producing Bio-oil

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JPH08119882A (ja) * 1994-10-07 1996-05-14 Chevron Usa Inc 不純トルエンの芳香族化及び選択的不均化の併用による高純度ベンゼン及びパラに富むキシレンの製造法
JP5917532B2 (ja) * 2010-10-22 2016-05-18 エスケー イノベーション カンパニー リミテッド 石油、石炭または木に由来する炭化水素留分から高付加芳香族製品および軽質パラフィン製品を製造する方法
US8754275B2 (en) * 2011-07-26 2014-06-17 Uop Llc Methods and apparatuses for producing aromatic hydrocarbon-rich effluent from lignocellulosic material
WO2013169464A1 (en) * 2012-05-07 2013-11-14 Exxonmobil Chemical Patents Inc. Process for the production of xylenes and light olefins
US8921633B2 (en) * 2012-05-07 2014-12-30 Exxonmobil Chemical Patents Inc. Process for the production of xylenes and light olefins

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851604A (en) * 1987-09-02 1989-07-25 Mobil Oil Corp. Toluene disproportionation
US20130023706A1 (en) * 2008-03-04 2013-01-24 University Of Massachusetts Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds
US20140027265A1 (en) * 2012-07-27 2014-01-30 Anellotech, Inc. Fast catalytic pyrolysis with recycle of side products
US20140238835A1 (en) * 2013-02-26 2014-08-28 The United States Of America, As Represented By The Secretary Of Agriculture Methods For Producing Bio-oil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3221425A4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106244184A (zh) * 2016-08-22 2016-12-21 华北电力大学 一种生物质热解气催化裂解制备btx的方法
CN106244185A (zh) * 2016-08-22 2016-12-21 华北电力大学 一种生物质催化热解制备btx的方法

Also Published As

Publication number Publication date
AU2015350437A1 (en) 2017-04-27
KR20170102237A (ko) 2017-09-08
EP3221425A1 (en) 2017-09-27
BR112017010285A2 (pt) 2018-02-14
MX2017006108A (es) 2017-10-11
US20160145496A1 (en) 2016-05-26
CA2964268A1 (en) 2016-05-26
JP2018504465A (ja) 2018-02-15
EP3221425A4 (en) 2018-06-20
CN107207968A (zh) 2017-09-26

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