WO2016053060A1 - 이차전지용 라미네이팅 장치 및 이차전지의 라미네이팅 방법 - Google Patents
이차전지용 라미네이팅 장치 및 이차전지의 라미네이팅 방법 Download PDFInfo
- Publication number
- WO2016053060A1 WO2016053060A1 PCT/KR2015/010468 KR2015010468W WO2016053060A1 WO 2016053060 A1 WO2016053060 A1 WO 2016053060A1 KR 2015010468 W KR2015010468 W KR 2015010468W WO 2016053060 A1 WO2016053060 A1 WO 2016053060A1
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- WIPO (PCT)
- Prior art keywords
- electrode
- electrode assembly
- separator
- secondary battery
- bonding
- Prior art date
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0404—Machines for assembling batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a secondary battery laminating apparatus and method, and more particularly to a secondary battery laminating apparatus and method that can be firmly bonded between the electrode assembly and the separator.
- the secondary battery is an electric vehicle (EV), a hybrid electric vehicle (HEV), a plug-in hybrid electric vehicle that has been proposed as a solution for air pollution of existing gasoline and diesel vehicles using fossil fuel. It is attracting attention as a power source such as (Plug-In HEV).
- the secondary battery is manufactured in a form in which the electrode assembly is included in the battery case together with the electrolyte.
- the electrode assembly is classified into a stack type, a folding type, and a stack-fold type according to a manufacturing method.
- the unit assembly has a structure in which the anode and the cathode are sequentially stacked with the separator interposed therebetween. In order to make such a unit assembly, a laminating process for bonding between the electrode and the separator is required.
- the laminating process is generally performed by heating the unit assembly to bond the electrode and the separator.
- a heating method for this purpose an indirect heating method by radiation and convection is mainly used. This method is for laminating the unit assembly during transportation since each manufacturing process of the secondary battery is organically connected for mass production.
- the indirect heating method by radiation and convection takes more time to raise the unit assembly to the target temperature as compared to the direct heating method which is in direct contact and conduction.
- FIG. 1 schematically illustrates an example of a conventional secondary battery laminating device
- FIG. 2 illustrates pressure applied to an electrode assembly by the conventional secondary battery laminating device of FIG. 1.
- an object of the present invention is to provide a secondary battery laminating device that can produce a secondary battery having excellent durability by applying a uniform pressure to the electrode assembly and firmly bonded to the separator by applying a uniform pressure to the electrode assembly.
- an apparatus for bonding an electrode and a separator comprising: a transfer unit for transferring the electrode assembly on the separator; It is disposed on the transfer path of the transfer portion, the contact portion for bonding the electrode assembly to the separator by applying heat to the entire surface of the electrode assembly; achieved by the secondary battery laminating device comprising a do.
- the electrode assembly may include the electrode and an electrode tab protruding from an end of the electrode, and the junction part may form a step to contact the electrode tab and the electrode.
- the electrode assembly is disposed on the separator to be spaced apart from each other, the width of the separator is set to extend outward from the end of the electrode assembly, the junction portion is stepped to contact both the electrode assembly and the separator Can be formed.
- the surface of the junction portion facing the electrode assembly may be divided into three regions having different step surfaces.
- the disposing step of placing the electrode assembly on the separator A transfer step of continuously transferring the separator in a state in which the electrode assembly is disposed; And a bonding step of bonding the electrode assembly to the separator by applying heat to the entire surface of the electrode assembly on the transport path of the separator, thereby achieving a secondary battery laminating method.
- the electrode assembly may include an electrode and an electrode tab protruding from an end of the electrode, and in the bonding step, the electrode and the electrode tab may be simultaneously in contact with and apply heat.
- a laminating device for a secondary battery that can be more firmly bonded to a separator by pressing the electrode assembly uniformly.
- Figure 1 schematically shows an example of a conventional laminating device for a secondary battery
- FIG 2 shows the pressure applied to the electrode assembly by the conventional secondary battery laminating device of Figure 1
- Figure 3 schematically shows a laminating device for a secondary battery according to an embodiment of the present invention
- FIG. 4 is a view illustrating a portion A of the laminating device for a secondary battery of FIG. 3,
- FIG. 5 is a cross-sectional view taken along a line V-V ′ of the secondary battery laminating device of FIG.
- Figure 3 schematically shows a laminating device for a secondary battery according to an embodiment of the present invention
- Figure 4 shows a portion A of the secondary battery laminating device of Figure 3
- Figure 5 is a secondary battery lakinetic of Figure 4 The section cut along the V-V 'cutting line of the casting device is shown.
- the secondary battery laminating device 100 is a device used to bond the electrode assembly 10 and the separator 20 to each other in the secondary battery process. , The transfer unit 110 and the junction portion 120.
- the transfer unit 110 is for continuously transferring the separator 20 in a state where the electrode assembly 10 is disposed on the upper surface.
- the transfer unit 110 is preferably used in the conveying roller and the conveyor belt structure widely used in the inline process of the art, a detailed description thereof will be omitted.
- the electrode assembly 10 transferred by the transfer unit 110 has a laminated structure in which a separator (not shown) is interposed between the electrodes 11 including the anode and the cathode, and the electrode tab 112 is disposed at an end of the electrode. Is formed.
- the positive electrode may be prepared by, for example, applying a slurry made by mixing a positive electrode mixture with a solvent such as NMP onto a positive electrode current collector, followed by drying and rolling.
- the positive electrode mixture may optionally include a conductive material, a binder, a filler, etc. in addition to the positive electrode active material.
- the conductive material is typically added in an amount of 1 to 30 wt% based on the total weight of the mixture including the positive electrode active material.
- the conductive material is not particularly limited as long as it has conductivity without causing chemical change in the battery.
- graphite such as natural graphite or artificial graphite, carbon black, acetylene black, ketjen black, channel black, furnace Carbon black such as black, lamp black and summer black, conductive fibers such as carbon fiber and metal fiber, metal powder such as carbon fluoride, aluminum and nickel powder, conductive whiskey such as zinc oxide and potassium titanate and conductive metal such as titanium oxide
- Conductive materials such as oxides, polyphenylene derivatives, and the like can be used.
- the binder is a component that assists the bonding of the active material and the conductive material to the current collector, and is generally added in an amount of 1 to 30 wt% based on the total weight of the mixture including the positive electrode active material.
- binders include polyvinylidene fluoride, polyvinyl alcohol, carboxymethyl cellulose (CMC), starch, hydroxypropyl cellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene , Polypropylene, ethylene-propylene-diene terpolymer (EPDM), sulfonated EPDM, styrene butylene rubber, fluorine rubber, various copolymers and the like.
- the filler is optionally used as a component for inhibiting the expansion of the electrode, and is not particularly limited as long as it is a fibrous material without causing chemical change in the battery.
- the filler include olefinic polymers such as polyethylene and polypropylene; Fibrous materials, such as glass fiber and carbon fiber, are used.
- the positive electrode current collector is generally made to a thickness of 3 to 500 ⁇ m. Such a positive electrode current collector is not particularly limited as long as it has conductivity without causing chemical change in the battery.
- the positive electrode current collector may be formed on a surface of stainless steel, aluminum, nickel, titanium, calcined carbon, or aluminum or stainless steel. Surface treated with carbon, nickel, titanium, silver, or the like can be used.
- the current collector may form fine irregularities on its surface to increase the adhesion of the positive electrode active material, and may be in various forms such as a film, a sheet, a foil, a net, a porous body, a foam, and a nonwoven fabric.
- the negative electrode is prepared by, for example, applying a negative electrode mixture containing a negative electrode active material on a negative electrode current collector and then drying the negative electrode mixture.
- the negative electrode mixture may include, as necessary, a conductive material, a binder, a filler, and the like. The components of may be included.
- the negative electrode active material examples include carbon and graphite materials such as natural graphite, artificial graphite, expanded graphite, carbon fiber, non-graphitizable carbon, carbon black, carbon nanotube, fullerene, and activated carbon; Metals such as Al, Si, Sn, Ag, Bi, Mg, Zn, In, Ge, Pb, Pd, Pt, Ti which can be alloyed with lithium, and compounds containing these elements; Complexes of metals and compounds thereof with carbon and graphite materials; Lithium-containing nitrides; and the like.
- carbon-based active materials, silicon-based active materials, tin-based active materials, or silicon-carbon-based active materials are more preferable, and these may be used alone or in combination of two or more.
- the negative electrode current collector is generally made to a thickness of 3 to 500 ⁇ m.
- a negative electrode current collector is not particularly limited as long as it has high conductivity without causing chemical change in the battery.
- copper, stainless steel, aluminum, nickel, titanium, calcined carbon, copper or stainless steel Surface-treated with carbon, nickel, titanium, silver and the like on the surface, aluminum-cadmium alloy and the like can be used.
- fine concavities and convexities may be formed on the surface to enhance the bonding strength of the negative electrode active material, and may be used in various forms such as a film, a sheet, a foil, a net, a porous body, a foam, and a nonwoven fabric.
- the separator (not shown) constituting the electrode assembly 10 that is, the separator (not shown) interposed between the positive electrode and the negative electrode is preferably made of the same material as the separator 20 to be the electrode assembly to be bonded, An insulating thin film having high ion permeability and mechanical strength can be used.
- the pore diameter of the separator is generally from 0.01 to 10 ⁇ m ⁇ m, thickness is generally 5 ⁇ 300 ⁇ m.
- a separator for example, a sheet, a nonwoven fabric, or the like made of an olefin polymer such as polypropylene having chemical resistance and hydrophobicity, glass fiber or polyethylene, or the like is used.
- materials and structures of the electrode assembly 10 and the separator 20 described above are just examples, and structures and materials well known in the secondary battery art may be used as the electrode assembly and the separator.
- a thinner electrode tab 12 protrudes outward in the width direction of the separator 20 than the electrode 11 at an end portion of the electrode 11 including the anode and the cathode.
- the junction part 120 is disposed on a transfer path of the transfer part 110 and pressurizes the electrode assembly 10 so that the stacked structures of the electrode assembly 10 and the separator 20 to be transferred may be bonded to each other. Apply heat.
- the junction 120 may have a size corresponding to the width of the separation membrane 20 transferred by the transfer unit 110.
- the surface of the junction portion 120 that faces the transfer portion 110 is defined and described as a junction surface 121, and the junction surface 121 is divided into three regions along the longitudinal direction.
- the bonding surface 121 includes a first region 122, a second region 123, and a third region 124 that are divided in order along the longitudinal direction.
- the first region 122 is a region in which the electrode tab 12 is in contact during the bonding process, and the second region 123 is in contact with a surface of the uppermost electrode 11 exposed to the outside of the anode or the cathode. This is the area where contact takes place.
- the third region 124 is a region where direct contact with the separator of the region in which the electrode 11 is not located.
- the electrode assembly 10 or the separation membrane 20 in contact with the bonding surface 121 is different from the height of the uppermost, so that the first region 122 forming the bonding surface 121 in order to contact the surfaces of different heights at the same time
- the second region 123 and the third region 124 form steps from neighboring regions.
- the height of the separator 20 and the electrode assembly 10 to be bonded increases gradually in the order of the separator 20, the electrode tab 12, and the electrode 11.
- the third region 124 protrudes the most, the second region 123 protrudes the least, and each region forms a step due to the difference in the degree of protruding from the neighboring region.
- the laminating method of the secondary battery using the secondary battery laminating apparatus includes a batch step, a transfer step and a bonding step.
- the separator 20 is disposed on the transfer part 110, and the plurality of electrode assemblies 10 are arranged on the separator 20.
- the plurality of electrode assemblies 10 are arranged to be spaced apart from each other along the conveying direction, and the separation interval between the electrode assemblies 10 may include the speed of conveying, the size of the electrode assembly, and the structure of the final secondary battery (eg, jelly roll form, Determine whether it is in the form of stack and folding).
- the separator 110 and the electrode assembly 10 disposed on the separator 20 are continuously transferred using the transfer part 110.
- the separator 20, which receives the transfer force from the transfer unit 110, is continuously transferred to pass through the lower portion of the junction 120.
- the bonding step bonding between the electrode assembly 10 and the separator 20 is performed, and the bonding surface 121, which is the lower surface of the bonding unit 120, is brought into contact with the electrode assembly 10 and the separator 20.
- the electrode assembly 10 is bonded to the separator 20 by applying pressure and simultaneously applying heat.
- the first region 122 of the bonding surface 121 is in close contact with the electrode tab 12
- the second region 123 is in close contact with the top end surface of the electrode 11
- the third region 123 is in contact with the electrode tab 12. Since it is not located, it is in close contact with the separator 20 exposed to the outside. Therefore, the uniform bonding force may be provided to the electrode assembly 10 and the separator 20 by all regions of the bonding surface 121 participating in the bonding process.
- the electrode assembly 10 is formed by pressing the electrode tab 12 and the electrode 11 having different heights at the same time as the first region 122 and the second region 123 protruding to different degrees. Uniform pressing force may be provided over the entire surface, and thus, the electrode assembly 10 may be more firmly bonded to the separator 20. In addition, by pressing the separator 20 itself, in which the third region 124 is exposed to the outside, durability of the separator 20 itself may also be improved.
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Abstract
Description
Claims (6)
- 전극 조립체와 분리막을 접합하기 위한 장치에 있어서,상기 전극 조립체를 상기 분리막 상에 배치한 상태에서 이송하는 이송부;상기 이송부의 이송경로 상에 배치되며, 상기 전극 조립체의 전면(全面)에 접촉하여 열을 가함으로써 상기 전극 조립체를 상기 분리막에 접합하는 접합부;를 포함하는 것을 특징으로 하는 이차전지용 라미네이팅 장치.
- 청구항 1에 있어서,상기 전극 조립체는 전극과, 상기 전극의 단부로부터 돌출되는 전극탭을 포함하고,상기 접합부는 상기 전극탭과 상기 전극에 접촉하도록 단차를 형성하는 것을 특징으로 하는 이차전지용 라미네이팅 장치.
- 청구항 2에 있어서,상기 전극 조립체는 상기 분리막 상에 복수개가 서로 이격되도록 배치되고,상기 분리막의 폭은 상기 전극 조립체의 단부로부터 외측으로 연장되도록 설정되며,상기 접합부는 상기 전극 조립체와 상기 분리막에 모두 접촉하도록 단차를 형성하는 것을 특징으로 하는 이차전지용 라미네이팅 장치.
- 청구항 3에 있어서,상기 전극 조립체와 대향하는 상기 접합부의 면은 서로 다른 단차면을 갖는 3개의 영역으로 분할되는 것을 특징으로 하는 이차전지용 라미네이팅 장치.
- 분리막 상에 전극 조립체를 배치하는 배치단계;상기 전극 조립체를 배치한 상태에서 상기 분리막을 연속적으로 이송하는 이송단계;상기 분리막의 이송경로 상에서 상기 전극 조립체의 전면(全面)에 접촉하여 열을 가함으로써 상기 전극 조립체를 상기 분리막에 접합하는 접합단계;를 포함하는 것을 특징으로 하는 이차전지의 라미네이팅 방법.
- 청구항 5에 있어서,상기 전극 조립체는 전극과, 상기 전극의 단부로부터 돌출되는 전극탭을 포함하고,상기 접합단계에서는 상기 전극과 상기 전극탭에 동시에 접촉하여 열을 가하는 것을 특징으로 하는 이차전지의 라미네이팅 방법.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201580005149.1A CN106415914B (zh) | 2014-10-02 | 2015-10-02 | 二次电池层叠装置和二次电池层叠方法 |
EP15845536.0A EP3079196B1 (en) | 2014-10-02 | 2015-10-02 | Secondary battery laminating device and secondary battery laminating method |
PL15845536T PL3079196T3 (pl) | 2014-10-02 | 2015-10-02 | Urządzenie do laminowania baterii wtórnej i sposób laminowania baterii wtórnej |
JP2016548621A JP6461171B2 (ja) | 2014-10-02 | 2015-10-02 | 二次電池用ラミネーティング装置及び二次電池のラミネーティング方法 |
US15/110,457 US10014550B2 (en) | 2014-10-02 | 2015-10-02 | Secondary battery laminating device and secondary battery laminating method |
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KR20140133023 | 2014-10-02 | ||
KR10-2014-0133023 | 2014-10-02 | ||
KR10-2015-0130400 | 2015-09-15 | ||
KR1020150130400A KR101775230B1 (ko) | 2014-10-02 | 2015-09-15 | 이차전지용 라미네이팅 장치 및 이차전지의 라미네이팅 방법 |
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