WO2016051354A1 - Améliorations des propriétés de surface des billes de verre qui sont utilisées en tant que matériau rétroréfléchissant dans les marquages de chaussée, par revêtement à l'aide d'argile naturelle - Google Patents

Améliorations des propriétés de surface des billes de verre qui sont utilisées en tant que matériau rétroréfléchissant dans les marquages de chaussée, par revêtement à l'aide d'argile naturelle Download PDF

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Publication number
WO2016051354A1
WO2016051354A1 PCT/IB2015/057487 IB2015057487W WO2016051354A1 WO 2016051354 A1 WO2016051354 A1 WO 2016051354A1 IB 2015057487 W IB2015057487 W IB 2015057487W WO 2016051354 A1 WO2016051354 A1 WO 2016051354A1
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WO
WIPO (PCT)
Prior art keywords
montmorillonite
glass beads
paint
glass bead
glass
Prior art date
Application number
PCT/IB2015/057487
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English (en)
Inventor
Alican VATANSEVER
Tülay İNAN
Hacer DOĞAN
Murat Koral
Nuran KÖKER
Original Assignee
Tubitak
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tubitak filed Critical Tubitak
Priority to CN201580052963.9A priority Critical patent/CN107148405B/zh
Priority to JP2017517049A priority patent/JP6381793B2/ja
Priority to RU2017108722A priority patent/RU2661511C1/ru
Publication of WO2016051354A1 publication Critical patent/WO2016051354A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00—Powdered glass; Bead compositions
    • C03C12/02—Reflective beads
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10—Coating or impregnating
    • C04B20/1055—Coating or impregnating with inorganic materials
    • C04B20/1074—Silicates, e.g. glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
    • E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/228—Other specific oxides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/60—Flooring materials

Definitions

  • the invention relates to coating of glass beads, which will be used in water based road markings to increase night visibility, with natural montmorillonite and/or modified montmorillonite; as a result of this coating, obtaining cheap glass beads that provide increased retoreflectivity and wear resistance for road marking paints when compared to commercial glass beads.
  • Glass beads are spread on the paint soon after the paint application. Glass beads with higher diameters will be seen on the surface whereas glass beads with low diameters will be embedded in the paint. Glass bead application is critical to obtain road paints having high retroreflectivity [1 ,2,3]. Dispersing glass beads in paint can be impossible if glass beads are not free flowing. Moisture may cause small glass beads to agglomerate due to the hydrophilic -OH group on the glass surface. Agglomeration can be prevented by modifying glass bead surface with hydrophobic coatings. However, the adhesion between the coating on the glass surface and the paint should be strong. Otherwise, glass beads could be easily removed under traffic due to the friction. So, retroreflectivity will decrease in case of coating glass beads with hydrophobic material. To overcome this problem, in some situations binding agents are being used. However, binding agent cause a thick coating on the glass surface and retroreflectivity decreases again. Moreover, binding agents cause agglomeration because of being hydrophilic [2].
  • US3253146 discloses that epoxy resins and pigments are used for glass bead coating [4].
  • US3222204 coats glass beads with fluorocarbons. Unfortunately, both these two applications are expensive and have low wear resistance. That means the more the the vehicles roll over road marking paint, the more the glass beads are removed from the surface [5].
  • US20050100709 discloses that poly urethane based polymeric material is obtained by using polyester polyols and aliphatic polyisocyanate. Then, glass bead are coated with this material. However, this method is expensive too and the results of the performance tests are not satisfying [1 ].
  • silane compounds are being used in literature because of their hydrophobic structure.
  • Silane coated glass beads are also popular in industrial applications (US4756931 , US5128203, S4305863, US4713295). Although coating glass bead with silane compounds is practical and cheaper compared to other coating materials, as can be seen in this study, much cheaper, green and natural material can be used.
  • US2005/0158461 uses a commercial silane compound for coating of glass beads.
  • WO01/42349 and GB2208078 glass beads are mixed with silane compounds with benzoyl peroxide.
  • this method is a little bit complex and expensive due to high need for special attention [10,1 1 ].
  • benzoyl peroxide is a volatile and flammable material. Therefore, coating effect will reduce and flame risk will occur.
  • WO01/42349 uses poly vinyl acetate as the coating material. After the coated glass beads were spread out the road paint, night visibilities are measured for a year. According to the results, adherence of poly vinyl acetate coated glass beads to paint is stronger than uncoated glass beads. However, no compare is available between poly vinyl acetate and silane coated glass beads. Poly vinyl acetate could be more expensive than silane compounds [10].
  • Aim of the present invention is to obtain coated glass beads that can be competitive with commercial glass beads, inorganic based, cheap, easily applicable, green and especially highly compatible with water based road paints and have high wear resistance as well as retroreflectivity.
  • glass beads having larger sizes are removed from the surface due to the impact made by the friction of the vehicles.
  • Small glass beads begin to appear on the paint surface due to the wear of paint over time. Consequently, night visibility decreases eventually.
  • the glass spheres are coated with different materials that can provide high compatibility between glass bead and paint [1 ,2,3].
  • affinity generally polymeric structure with organic based materials were preferred.
  • Such materials should be of a structure that is suitable with chemical structure of paint binding so as, at the end of the adhesion between glass beads and paint, some of the glass beads should locate on the paint surface and some of the glass beads should stay in the paint without sinking.
  • the chemical structure of the coating material should be selected so as to adhere to the binder contained in the paint.
  • Such organic coating materials could have yellowing problems caused by the sun and some organic-based components could diffuse into the paint depending on the increase of air temperature.
  • Glass beads in the present invention are coated with inorganic based, nano sized natural sodium montmorillonite (Na-montmorillonite) and montmorillonite modified with quaternary ammonium salt. Afterwards, performance of these glass beads are compared to uncoated glass beads or glass beads coated with silan based polymeric materials which are industrially most used glass beads in road marking paints. According to the performance tests, high wear resistance, thereby more durable paint is provided as well as durable high reflectivity.
  • MMT-1 Montmorillonite modified by quaternary ammonium salt at a concentration equivalent to 1 cation exchange capacity (CEC) of Na- montmorillonite.
  • CK-5 MMT-3 coated glass bead Figure 1.
  • O-H stretching peak of silicate layers is seen in 3700 - 3400 cm “1 .
  • At 917.51 cm "1 octahedral layer peak could be seen explicitly.
  • IR spectras of MMT-1 and MMT-2 are in concordance and shows peaks at 2950-2850 cm “1 and 1470-1370 cm “1 which could not be seen for MMT-3. Peaks observed at 2950-2850 cm-1 represent methylene structure and peaks at 1470-1370 cm "1 are assigned to H-C-H stretching. These peaks are the sign of quaternary ammonium salts within the montmorillonite structure.
  • Figure 2 In the TGA curve, decrease observed between 0-150 °C is due to the divergence of the water between the layers of clay minerals. At 650-850 °C OH ions and impurities such as MgCO3 and CaCO3 has removed from the structure. The decline observed at 200-400 °C for MMT-1 and MMT-2 indicates that ammonium salt is attached to montmorillonite and carbon is burned.
  • Figure 3 In SEM (Scanning Electron Microscope) images, (a) CK-1 , (b) CK-3, (c) CK-4, (d) CK-5 glass beads coated with MMT can be seen. High brightness is seen in SEM of MMT2 coated glass beads due to the high proportion of quaternary ammonium salt.
  • MMT montmorillonite
  • CEC cation exchange capacity
  • glass bead are added to the MMT suspension and mixed to have glass bead/MMT suspension ratios differing from 1 :1 to 1 :4.
  • coating thickness is 0.1 -0.5 pm.
  • the mixture is transferred into a pan where glass bead could spread. Then, the mixture is dried between 80-100 °C. In order to separate agglomerated glass beads, glass beads are grinded very gently soon after drying. Glass beads should not be broken in this process.
  • quaternary ammonium salts are added at 0.5, 1 and 2 CEC of MMT to the MMT suspension described above. After the suspension is mixed at 30-80 °C for 0.5-2 hours, coating process is conducted as described above.
  • the coated glass spheres are spread 33 % by weight to the road marking paint adsorbed onto briquettes.
  • Glass beads are spread to water based road marking paint that consists of water based binder.
  • Wet film thickness of the paint applied to the briquettes is 400-600 pm.
  • Glass beads are in different gradation, that the particle sizes of glass beads range between 150-700 pm.
  • FTIR of MMTs used to coat glass beads are taken on a Perkin Elmer Spectrum One FTIR Spectrometer ( Figure 1 ) Thermal Gravimetric Analysis (TGA)
  • TGA Thermal Gravimetric Analysis
  • thermal gravimetric analysis of MMTs used to coat glass beads are taken Perkin Elmer Pyris 1 by heating the sample till 950 °C ( Figure 2).
  • Wear test is performed under wheel to determine glass bead performance by measuring night visibility values of the paints that are worn at a certain level. At the end of this test simulating the way, night visibility values are measured. Glass beads used with water based paint are listed below ;
  • Produced or purchased glass beads will be mixed at ambient temperature in bentonite suspension. Coated glass beads will be dried after mixing.
  • drying process can be performed by fluidized bed system or constant drying can be used if glass spheres can be separated from each other without breaking. This form of glass beads, are ready to use in road marking paint
  • Retroreflective elements comprising a bonded resin core and pavement markings, US20050100709, 2005

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Road Signs Or Road Markings (AREA)
  • Paints Or Removers (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Surface Treatment Of Glass (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Road Paving Structures (AREA)
  • Road Repair (AREA)

Abstract

Cette invention concerne des billes de verre revêtues de montmorillonite naturelle et organiquement modifiée, rivalisant avec des produits du commerce, facilement appliquées, compatibles avec des peintures de marquage de chaussée à base d'eau respectueuses de l'environnement, présentant une grande résistance à l'usure et un caractère rétroréfléchissant élevé. Des billes de verre revêtues sont étalées sur la peinture à base d'eau qui est appliquée sur des briquettes de 10 x 50 cm, peu après le processus d'application de peinture. Le rapport des billes de verre à la peinture est de 33 % en poids. Après séchage de la peinture, afin de simuler le passage, une roue avec une pression de 6 bars effectue des va-et-vient sur la peinture. À l'issue de ce processus, la visibilité de nuit est mesurée. Après 10 000 cycles de va-et-vient, la visibilité de nuit de la peinture comprenant les billes de verre revêtues de montmorillonite à base d'eau est supérieure aux peintures contenant des billes de verre du commerce revêtues de montmorillonite modifiée et non revêtue, revêtues de silane. Les billes de verre revêtues de montmorillonite modifiée procurent une visibilité de nuit similaire lorsqu'elles sont comparées à des billes de verre du commerce à base de silane et la visibilité de nuit est plus élevée que celle des billes de verre non revêtues.
PCT/IB2015/057487 2014-09-30 2015-09-30 Améliorations des propriétés de surface des billes de verre qui sont utilisées en tant que matériau rétroréfléchissant dans les marquages de chaussée, par revêtement à l'aide d'argile naturelle WO2016051354A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201580052963.9A CN107148405B (zh) 2014-09-30 2015-09-30 通过天然粘土涂覆改进用作道路标记中逆反射材料的玻璃珠的表面性能
JP2017517049A JP6381793B2 (ja) 2014-09-30 2015-09-30 モンモリロナイトおよび／または改質モンモリロナイトでコーティングされたガラスビーズの製造方法
RU2017108722A RU2661511C1 (ru) 2014-09-30 2015-09-30 Усовершенствование поверхностных свойств стеклошариков, используемых в качестве световозвращающего материала для дорожной разметки, путем нанесения покрытия из природной глины

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2014/11519A TR201411519A2 (tr) 2014-09-30 2014-09-30 Yol çizgi boyalarında retroreflektif malzeme olarak kullanılan cam kürelerin doğal bir ürün olan kil ile kaplanarak yüzey özelliklerinin iyileştirilmesi.
TRTR2014/11519 2014-09-30

Publications (1)

Publication Number Publication Date
WO2016051354A1 true WO2016051354A1 (fr) 2016-04-07

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PCT/IB2015/057487 WO2016051354A1 (fr) 2014-09-30 2015-09-30 Améliorations des propriétés de surface des billes de verre qui sont utilisées en tant que matériau rétroréfléchissant dans les marquages de chaussée, par revêtement à l'aide d'argile naturelle

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JP (1) JP6381793B2 (fr)
CN (1) CN107148405B (fr)
RU (1) RU2661511C1 (fr)
TR (1) TR201411519A2 (fr)
WO (1) WO2016051354A1 (fr)

Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN112940439A (zh) * 2021-03-02 2021-06-11 宁波福尔达智能科技有限公司 阻燃型abs复合材料及其制备工艺
IT202200006584A1 (it) 2022-04-04 2023-10-04 Team Segnal S R L Materiali retroriflettenti e loro uso nella segnaletica stradale orizzontale

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Publication number Priority date Publication date Assignee Title
CN112985973A (zh) * 2021-01-29 2021-06-18 金华市公路与运输管理中心 一种标线涂料与玻璃珠粘附性能评价指标及方法
CN114410144B (zh) * 2022-02-25 2023-03-10 山西中涂交通科技股份有限公司 热熔型标线涂料用防沉降玻璃珠
CN116514464B (zh) * 2023-04-27 2024-10-11 重庆交通大学 一种反光水泥胶浆及反光半柔性路面材料

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3222204A (en) 1960-04-20 1965-12-07 Minnesota Mining & Mfg Process of making beaded coatings and films from glass beads treated with oleophobic sizing agent
US3253146A (en) 1962-08-16 1966-05-24 Prismo Safety Corp Fluorescent marker pigment for roadways
US4305863A (en) 1979-06-15 1981-12-15 Dainippon Ink & Chemicals, Inc. Glass bead-filled resin composition
US4609587A (en) * 1984-11-30 1986-09-02 Potters Industries, Inc. Retroreflective materials and use
US4713295A (en) 1985-03-28 1987-12-15 Glaverbel Method of modifying the wettability of glass beads, glass beads polymeric material incorporating such glass beads, and method of applying reflective markings to a surface
US4756931A (en) 1984-11-30 1988-07-12 Potters Industries, Inc. Retroreflective materials and methods for their production and use
GB2208078A (en) 1987-05-14 1989-02-22 Glaverbel Forming a polymeric matrix containing filler material
US5128203A (en) 1988-02-19 1992-07-07 Glaverbel Marking comprising glass beads in a matrix
WO2001042349A1 (fr) 1999-12-10 2001-06-14 Abildgaard Roadvision Aps Marquage reflectorise et procede de production et d'application d'une composition renfermant ledit marquage reflectorise
US20050100709A1 (en) 2003-11-06 2005-05-12 3M Innovative Properties Company Retroreflective elements comprising a bonded resin core and pavement markings
US20050158461A1 (en) 2004-01-21 2005-07-21 3M Innovative Properties Company Methods of making reflective elements

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4025476A (en) * 1975-10-03 1977-05-24 Prismo Universal Corporation Traffic paint method and composition
DE3419196A1 (de) * 1984-05-23 1985-11-28 Klein, Walter, 5439 Langenhahn Reflexperlenbeschichtung von betonteilen der din 483 und nicht genormten betonteilen im strassen- u. verkehrswesen mit stark lichtbrechenden glasperlen mit brechungsindex angenaehert gleich 1,9 mittels einer weissen betonschutzbeschichtung nach vob/c din 18363 2.4.6 auf fluessiger kaliumsilicatbasis
US5077117A (en) * 1990-04-05 1991-12-31 Minnesota Mining And Manufacturing Company Pavement marking material with rupturing top layer
JPH07295487A (ja) * 1994-04-27 1995-11-10 Aisin Chem Co Ltd 光再帰性反射塗膜及びその形成方法
JP2003268311A (ja) * 2002-03-15 2003-09-25 Seitoo Kk 路面標示用塗料
CN100513311C (zh) * 2005-11-04 2009-07-15 浙江海力生制药有限公司 改性蒙脱石及其制备方法和其应用
US7563508B2 (en) * 2007-05-30 2009-07-21 Chung Shan Institute Of Science And Technology, Armaments Bureau, M.N.D. Diffusion beads with core-shell structure
RU2422269C1 (ru) * 2010-03-17 2011-06-27 Государственное образовательное учреждение высшего профессионального образования "Тверской государственный технический университет" Способ изготовления дорожной плиты
JP2015148115A (ja) * 2014-02-07 2015-08-20 株式会社キクテック 路面ライン標示用塗料及び路面ライン標示

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3222204A (en) 1960-04-20 1965-12-07 Minnesota Mining & Mfg Process of making beaded coatings and films from glass beads treated with oleophobic sizing agent
US3253146A (en) 1962-08-16 1966-05-24 Prismo Safety Corp Fluorescent marker pigment for roadways
US4305863A (en) 1979-06-15 1981-12-15 Dainippon Ink & Chemicals, Inc. Glass bead-filled resin composition
US4609587A (en) * 1984-11-30 1986-09-02 Potters Industries, Inc. Retroreflective materials and use
US4756931A (en) 1984-11-30 1988-07-12 Potters Industries, Inc. Retroreflective materials and methods for their production and use
US4713295A (en) 1985-03-28 1987-12-15 Glaverbel Method of modifying the wettability of glass beads, glass beads polymeric material incorporating such glass beads, and method of applying reflective markings to a surface
GB2208078A (en) 1987-05-14 1989-02-22 Glaverbel Forming a polymeric matrix containing filler material
US5128203A (en) 1988-02-19 1992-07-07 Glaverbel Marking comprising glass beads in a matrix
WO2001042349A1 (fr) 1999-12-10 2001-06-14 Abildgaard Roadvision Aps Marquage reflectorise et procede de production et d'application d'une composition renfermant ledit marquage reflectorise
US20050100709A1 (en) 2003-11-06 2005-05-12 3M Innovative Properties Company Retroreflective elements comprising a bonded resin core and pavement markings
US20050158461A1 (en) 2004-01-21 2005-07-21 3M Innovative Properties Company Methods of making reflective elements

Cited By (3)

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CN112940439A (zh) * 2021-03-02 2021-06-11 宁波福尔达智能科技有限公司 阻燃型abs复合材料及其制备工艺
CN112940439B (zh) * 2021-03-02 2021-09-28 宁波福尔达智能科技股份有限公司 阻燃型abs复合材料及其制备工艺
IT202200006584A1 (it) 2022-04-04 2023-10-04 Team Segnal S R L Materiali retroriflettenti e loro uso nella segnaletica stradale orizzontale

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CN107148405B (zh) 2019-12-31
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