WO2016016811A1 - Perfectionnement du procédé pour la fabrication de dalles d'aggloméré - Google Patents

Perfectionnement du procédé pour la fabrication de dalles d'aggloméré Download PDF

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Publication number
WO2016016811A1
WO2016016811A1 PCT/IB2015/055709 IB2015055709W WO2016016811A1 WO 2016016811 A1 WO2016016811 A1 WO 2016016811A1 IB 2015055709 W IB2015055709 W IB 2015055709W WO 2016016811 A1 WO2016016811 A1 WO 2016016811A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixture
sheet
paper
containment element
film
Prior art date
Application number
PCT/IB2015/055709
Other languages
English (en)
Inventor
Luca Toncelli
Angelo LUISON
Original Assignee
Breton Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Breton Spa filed Critical Breton Spa
Priority to EP15762740.7A priority Critical patent/EP3174683B1/fr
Priority to ES15762740T priority patent/ES2948674T3/es
Priority to US15/329,405 priority patent/US11325285B2/en
Publication of WO2016016811A1 publication Critical patent/WO2016016811A1/fr
Priority to IL250191A priority patent/IL250191B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0067—Using separating agents during or after moulding; Applying separating agents on preforms or articles, e.g. to prevent sticking to each other
    • B29C37/0075—Using separating agents during or after moulding; Applying separating agents on preforms or articles, e.g. to prevent sticking to each other using release sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/56—Compression moulding under special conditions, e.g. vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/242—Moulding mineral aggregates bonded with resin, e.g. resin concrete
    • B29C67/243—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length
    • B29C67/244—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length by vibrating the composition before or during moulding
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0067—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability making use of vibrations
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/02—Selection of the hardening environment
    • C04B40/0263—Hardening promoted by a rise in temperature
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/04—Preventing evaporation of the mixing water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/56—Compression moulding under special conditions, e.g. vacuum
    • B29C2043/561—Compression moulding under special conditions, e.g. vacuum under vacuum conditions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B29K2509/14—Stones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2911/00—Use of natural products or their composites, not provided for in groups B29K2801/00 - B29K2809/00, as mould material
    • B29K2911/12—Paper, e.g. cardboard
    • B29K2911/123—Coated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0017—Heat stable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0063—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0065—Permeability to gases
    • B29K2995/0067—Permeability to gases non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0068—Permeability to liquids; Adsorption
    • B29K2995/0069—Permeability to liquids; Adsorption non-permeable

Definitions

  • the present invention relates to an improvement to the method for manufacturing conglomerate stone slabs using the Bretonstone technology and more specifically to an improvement to the temporary substrate for supporting the mixture, used in this technology.
  • this technology envisages a first stage for preparation of a mixture consisting mainly of granules of stone material (for example marble or granite or quartz) with a predefined grain size and a binder which may be organic or inorganic.
  • a binder which may be organic or inorganic.
  • inorganic binder it consists of a cement binder which has the same hardening characteristics as cement articles, while in the first case (organic binder) it consists here of a resin, preferably a styrene polyester resin, hardening of which is normally performed under hot conditions with the aid of a catalyst.
  • the mixture is poured in the form of a layer with a predefined thickness onto a support which may be temporary and on which the mixture undergoes vacuum vibrocompression.
  • the third and final stage (irrespective of the subsequent stages involving specific machining and finishing of the resultant rough-formed slabs) consists in the aforementioned hardening operation.
  • the first process is performed by means of a less expensive plant but has not insignificant drawbacks, especially in the case of resin-based binders.
  • catalysis step is performed in suitable ovens consisting of several heating surfaces, where the slab is enclosed between two surfaces.
  • the temperature reached is usually about 80-140°C so that fluidization of the resin occurs and organic vapours (in particular styrene vapours if a polyester resin is used) are generated.
  • Paper since it is porous, does not form a barrier to the vapours of solvents or other chemical compounds and to migration of the resin, so that these agents pass easily through the sheet of paper and are deposited on the surfaces of the catalysis oven.
  • a layer of insulating material is formed and prevents the uniform transmission of heat from the heating surfaces to the slab.
  • the compacted and hardened slab is extracted from the tray before being sized and smoothed
  • the slab, lined with paper on both sides enters instead directly into the sizing and smoothing lines where the sizing and smoothing tools, with the aid of the cooling water, grind and reduce to a mash the sheets of paper which cover the slabs.
  • waste mixture composed principally not only of the components of the catalysed starting mixture and cooling water used to cool the tools of the sizing and smoothing machines, but also the ground paper, and therefore the mixture is substantially composed of water, powder stone material (e.g. marble or granite or quartz), bonding resin and paper.
  • powder stone material e.g. marble or granite or quartz
  • waste products in the form of sludges
  • sludges waste products are decanted, filter-pressed and finally disposed of in suitable waste collection and disposal centres.
  • Patent Application No. PCT/EP08/61112 which relates to a method and a plant for treating and recycling machining sludges by means of drying and incineration
  • Patent Application No. PCT/IB2010/50961 which relates to a method and a plant for treating the aforementioned machining sludges, in which it is envisaged adding an inorganic binder to the sludges so as to convert them into inert granules to be used in the building sector.
  • the main object of the invention is therefore to provide a containment element for the mixture to be used in Bretonstone technology and therefore in the methods and the plants hitherto designed to use the top and bottom paper sheets, while eliminating however the abovementioned drawbacks and therefore preventing the aforementioned chemical agents from coming into contact with the oven shelves, so as to eliminate the need for cleaning thereof and consequent stoppage of the plant.
  • the invention consists in using, instead of the aforementioned top and/or bottom paper sheets, a temporary containment element for the aforementioned mixture, consisting of a composite sheet, namely a sheet of paper which has, applied on at least one of its surfaces, a film of plastic material which is impermeable both to organic vapours, in particular to styrene vapours, and to resin, while maintaining this characteristic feature also at high catalysis temperatures.
  • a temporary containment element for the aforementioned mixture consisting of a composite sheet, namely a sheet of paper which has, applied on at least one of its surfaces, a film of plastic material which is impermeable both to organic vapours, in particular to styrene vapours, and to resin, while maintaining this characteristic feature also at high catalysis temperatures.
  • the present invention constitutes an improvement to the method of manufacturing conglomerate slabs using the Bretonstone technology, characterized in that the temporary upper and/or lower containment element for the mixture consists of a sheet of paper or equivalent material, having the known support and resistance characteristics in relation to vibrocompression mechanical stresses, at least one of its surfaces having, applied thereon, a film of plastic material which is:
  • the plastic material forming said film is also water-soluble, in particular at room temperature.
  • the latter is still lined on both surfaces with the aforementioned composite sheet and is transferred for the usual sizing and smoothing operations.
  • the film of plastic material may form fragments and machining waste which may obstruct and block up the water cooling system for the tools of the sizing and smoothing machines with obvious problems and damage.
  • the material of the plastic film is able to decompose or dissolve in water, especially in water at room temperature.
  • a material which has these characteristics is polyvinyl alcohol (PVA).
  • the plastic film preferably has a basis weight of 10-50 g/m 2 and a thickness of 10-50
  • the paper instead has a basis weight which may be in the range 70-200 g/ m 2 .
  • the film of plastic material may be applied to both the surfaces of the usual paper sheet, normally used as top and bottom sheet in the known Bretonstone technology mentioned above.
  • said film may be applied to only one of the surfaces of the paper sheet and preferably onto the outer surface, namely the surface which does not come into contact with the mixture.
  • Paper instead, because of its nature, may absorb the aforementioned frictional stresses during vacuum vibrocompression without damage or tearing.
  • the plastic film it is preferably water-soluble, such as PVA, it being understood that any polymer or polymerizable material which gives rise to a water-soluble plastic film may be used.
  • PVA polymer or polymerizable material which gives rise to a water-soluble plastic film
  • the second component namely the paper
  • another material such as a non-woven fabric, which performs the same function as the conventional layer of paper which is resistant to the stresses during vibrocompression, while the plastic film ensures the impermeability to chemical agents so as to safeguard the surfaces of the catalysis oven.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Forging (AREA)
  • Cold Cathode And The Manufacture (AREA)

Abstract

Selon l'invention, dans le procédé de fabrication de dalles de pierre d'aggloméré à l'aide de la technologie de Bretonstone, dans la variante où le mélange de départ est confiné entre deux feuilles de papier, le perfectionnement selon l'invention consiste à remplacer chaque feuille de papier par un élément de confinement constitué d'une feuille de papier, sur une surface de laquelle est appliqué un film de matière plastique qui est imperméable aux vapeurs organiques, imperméable aux liquides et en particulier à la résine liquide constituant le liant dudit mélange, résistant aux températures de catalyse de ladite résine et résistant aux solvants chauds et aux vapeurs chimiques. De préférence, ladite matière plastique est hydrosoluble, en particulier il s'agit de poly(alcool vinylique).
PCT/IB2015/055709 2014-07-30 2015-07-29 Perfectionnement du procédé pour la fabrication de dalles d'aggloméré WO2016016811A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP15762740.7A EP3174683B1 (fr) 2014-07-30 2015-07-29 Perfectionnement du procédé pour la fabrication de dalles d'aggloméré
ES15762740T ES2948674T3 (es) 2014-07-30 2015-07-29 Mejora del procedimiento de fabricación de losas de conglomerado
US15/329,405 US11325285B2 (en) 2014-07-30 2015-07-29 Method for manufacturing conglomerate slabs
IL250191A IL250191B (en) 2014-07-30 2017-01-19 Improvement of a method for making conglomerate pieces

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITTV20140115 2014-07-30
ITTV2014000115 2014-07-30

Publications (1)

Publication Number Publication Date
WO2016016811A1 true WO2016016811A1 (fr) 2016-02-04

Family

ID=51663385

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2015/055709 WO2016016811A1 (fr) 2014-07-30 2015-07-29 Perfectionnement du procédé pour la fabrication de dalles d'aggloméré

Country Status (4)

Country Link
US (1) US11325285B2 (fr)
EP (1) EP3174683B1 (fr)
ES (1) ES2948674T3 (fr)
WO (1) WO2016016811A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9186819B1 (en) 2014-08-19 2015-11-17 Cambria Company Llc Synthetic molded slabs, and systems and methods related thereto
US9289923B1 (en) 2015-01-30 2016-03-22 Cambria Company Llc Synthetic molded slabs, and systems and methods related thereto

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Publication number Priority date Publication date Assignee Title
US4112173A (en) * 1975-02-04 1978-09-05 Champion International Corporation Concrete module unit
US4204820A (en) 1977-04-22 1980-05-27 Marcello Toncelli Slab forming conveying line
US4434119A (en) * 1980-03-03 1984-02-28 Teare John W Method for producing concrete panels
US5756214A (en) * 1989-09-04 1998-05-26 Imperial Chemical Industries Plc Release film comprising polycarbonate-silicone-urethane resin
EP0786325A1 (fr) * 1996-01-29 1997-07-30 TONCELLI, Marcello Méthode et dispositif pour la fabrication de carreaux à partir d'aggrégats minéraux et/ou de sable et de résine durcissable
IT1288566B1 (it) 1996-01-29 1998-09-23 Marcello Toncelli Procedimento ed impianto per la produzione di lastre di granulati e/o sabbie di materiale lapideo legato con una resina induribile
EP1027205A1 (fr) 1997-10-27 2000-08-16 Luca Toncelli Procede de production de dalles en materiaux de pierre granulee et/ou de sable lie avec une resine durcissante, et feuille profilee pour ladite production
IT1311857B1 (it) 1999-09-03 2002-03-19 Luca Toncelli Agente distaccante utilizzabile nella fabbricazione di manufatti inlastre costituite da un granulato o sabbie di materiale lapideo legate
US20040169303A1 (en) * 2001-07-04 2004-09-02 Franco Brutti Method for producing slabs of marble conglomerate
EP2283986A2 (fr) * 2009-08-13 2011-02-16 Selcuk Iplik San Ve Tic AS Procédé de fabrication d'une plaque de pierre composite texturée

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ES2948674T3 (es) 2023-09-15
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US11325285B2 (en) 2022-05-10
EP3174683A1 (fr) 2017-06-07

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