WO2016004748A1 - 一种发光球 - Google Patents

一种发光球 Download PDF

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Publication number
WO2016004748A1
WO2016004748A1 PCT/CN2015/000496 CN2015000496W WO2016004748A1 WO 2016004748 A1 WO2016004748 A1 WO 2016004748A1 CN 2015000496 W CN2015000496 W CN 2015000496W WO 2016004748 A1 WO2016004748 A1 WO 2016004748A1
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Prior art keywords
spherical shell
luminescent
ball
cavity
chemiluminescent agent
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PCT/CN2015/000496
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English (en)
French (fr)
Inventor
金朝阳
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北京文海阳工贸有限责任公司
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Application filed by 北京文海阳工贸有限责任公司 filed Critical 北京文海阳工贸有限责任公司
Priority to US15/325,707 priority Critical patent/US10286260B2/en
Publication of WO2016004748A1 publication Critical patent/WO2016004748A1/zh

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    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B43/00—Balls with special arrangements
    • A63B43/06—Balls with special arrangements with illuminating devices ; with reflective surfaces
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B39/00—Hollow non-inflatable balls, i.e. having no valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
    • F21K2/06—Non-electric light sources using luminescence; Light sources using electrochemiluminescence using chemiluminescence
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2225/00—Miscellaneous features of sport apparatus, devices or equipment
    • A63B2225/76—Miscellaneous features of sport apparatus, devices or equipment with means enabling use in the dark, other than powered illuminating means

Definitions

  • the invention relates to a luminescent sphere.
  • Chemiluminescence devices have been mostly rod-shaped, and fluorescent bracelets and fluorescent glasses have been derived from the deformation of the fluorescent rods. However, due to the particularity of the spherical structure, chemiluminescence is difficult to start, so the true meaning of the luminous sphere has not appeared.
  • the present invention contemplates a spherical chemiluminescent device that fills this gap. From the viewpoint of internal chemical reaction mechanism, civil chemiluminescence is obtained by a chemical reaction generated by substituting phenyl bis-oxalate, a fluorescent agent, an oxidizing agent, a solvent, or the like.
  • the component containing a substituted phenyl bis-oxalate is generally referred to as a chemiluminescent component, and the component containing an oxidizing agent is referred to as an oxidizing agent component, which are collectively referred to as chemiluminescent agents.
  • chemiluminescent agents include butyl oxalate, 2,4,5-trichlorosalicylate) oxalate (CPPO) or bis (2,4,5-trichlorosalicylic acid).
  • CPPO bis(2,4,5-trichlorosalicylate) oxalate
  • CPPO bis (2,4,5-trichlorosalicylic acid
  • Isoamyl) oxalate CIPO. They are usually stored separately from the oxidant before use, breaking the isolation between them during use, allowing them to mix and illuminate.
  • an object of the present invention is to provide a luminescent ball which is an elastic ball whose internal chemiluminescence system can emit light according to people's requirements.
  • a luminescent sphere comprising a spherical shell composed of an elastic light transmissive material, the spherical shell having a cavity therein, wherein the cavity has a chemiluminescent agent therein
  • the chemiluminescent agent is a mixture of a solid or a liquid or a solid liquid
  • the chemiluminescent agent is a separately packaged two kinds of agents capable of undergoing a chemiluminescent reaction after being mixed, at least one of which is contained in one or more Inside the broken container.
  • a luminescent ball according to the preceding claims characterized in that the cavity is provided with an excitation means for breaking the container.
  • said shelf comprises a fixing means, a rod connected to said fixing means, one end of said rod being directed toward the other end of said breakable container and directed toward the inner wall of said ball housing and Adjacent to or in contact with the inner wall of the ball housing, the fixture catches the breakable container.
  • a luminescent ball according to any of the preceding claims, wherein the spherical shell is provided with a hole and a sealing plug cooperating with the hole, from which a conduit is provided in the cavity of the spherical shell, a blocking device is disposed at one end of the cavity of the spherical shell, the blocking device is provided with a leak, and a sealing rod is disposed on one side of the spherical shell with a rod, and the end of the rod is provided with a conduit
  • the inner wall cooperates with the moving piston, and the breakable container is located between the piston and the blocking device.
  • a luminescent ball comprises a spherical shell composed of a light transmissive material, the spherical shell having a cavity therein, characterized in that a hole is formed in the spherical shell, A sealing plug is provided on the hole, and a chemiluminescent agent is contained in the cavity.
  • a luminescent ball according to any of the preceding claims, wherein a sealed inflatable bladder is provided in said spherical shell, and said inflatable bladder is provided in said inflatable bladder or between said inflatable bladder and said inner wall of said spherical shell A chemiluminescent agent.
  • the invention adopts the above technical solutions, and has the following advantages: 1.
  • the invention adopts the above technical solutions, and truly realizes the luminous sphere of the luminescent liquid inside, fully exhibiting the special effect of liquid illuminating, especially when the ball rotates and bounces.
  • the luminous effect is very different from the simple flashing of the existing electroluminescence, which greatly increases the entertainment of the ball.
  • the invention adopts a plurality of conical protrusions on the inner wall of the spherical shell, which can greatly reduce the possibility of puncturing the TPU outer shell when the glass ampoules are broken and after the ball is played, because the convex part is framed. Broken glass The shards of the glass make the sharp tip unable to form enough impact to pierce the wall. 3.
  • the invention employs a plastic sheet having a raised or polyhedral or a plurality of dimples or having grooves or/and ribs on the inner wall of the spherical shell and having paper, plastic sheets or small plastic particles placed thereon.
  • the dispersing granules in addition to giving a uniform feeling of dispersing effect, can also provide a certain visual shielding effect on the smashable container and its broken pieces, and reduce the discomfort of the user on, for example, glass shards.
  • Figure 1 is a cross-sectional view of the present invention
  • Figure 2 is a perspective cross-sectional view of a luminescent ball of two breakable containers according to the present invention
  • Figure 3 is a cross-sectional view of the luminescent ball of Figure 2;
  • Figure 4 is a cross-sectional view of a luminescent ball with a support rod type excitation device of the present invention
  • Figure 5 is a perspective cross-sectional view of a luminescent ball of the present invention with two smashable containers and a support rod type excitation device;
  • Figure 6 is a cross-sectional view of the illuminating ball with the support frame and the excitation device of the present invention
  • Figure 7 is a plan view of Figure 6;
  • Figure 8 is a schematic view showing the structure of a luminous ball with a sealing plug of the present invention.
  • Figure 9 is a schematic view showing the structure of a luminous sphere with an inflated bladder and a sealing plug of the present invention.
  • Figure 10 is a schematic view showing the structure of a luminescent sphere with a chemiluminescent liquid in the bladder of the present invention.
  • Figure 11 is a cross-sectional view showing the structure of a luminous sphere provided with a catheter on the spherical shell of the present invention
  • Figure 12 is a schematic view showing the use state of the excitation device of the luminous ball shown in Figure 11;
  • Figure 13 is a cross-sectional view showing a luminescent ball having a convex surface on the inner surface of the spherical shell of the present invention.
  • the present invention provides a luminescent ball comprising a spherical shell 1 composed of a 1.5 mm thick elastic light transmissive material polyethylene (PE), the spherical shell 1 having a diameter of 65 mm and a built-in 1.5.
  • a spherical shell 1 composed of a 1.5 mm thick elastic light transmissive material polyethylene (PE), the spherical shell 1 having a diameter of 65 mm and a built-in 1.5.
  • the chemiluminescent agent 2-B is an oxidizing solution containing hydrogen peroxide.
  • the rupturable container 3 disposed in the spherical shell 1 is a glass ampule having a wall thickness of 0.3 mm, a length of 50 mm, and a diameter of 9 mm, and a glass ampule is sealed with 1.6 g of a chemiluminescent agent 2-A.
  • the chemiluminescent agent 2-A is a luminescent agent component containing a bis-oxalate and a fluorescent agent, which may be a mixed component of a solid or may be liquid after being dissolved in a solvent.
  • the shattered glass fragments are also applied to the inner wall surface of the casing to glitter.
  • This luminescent ball does not puncture through the wall of the ball due to its lack of support inside.
  • two glass ampoules can also be used to separately package the chemiluminescent agents 2-A and 2-B, so that when used, crushing two glass ampoules to release the chemiluminescent agent can also obtain beautiful liquid and glass broken. The luminescent effect of slag mixing.
  • a pair of support frames 4 are provided in the spherical shell 1, and the support frame 4 is an excitation device.
  • the spherical shell 1 is composed of a 3 mm thick elastic light-transmitting material thermoplastic polyurethane TPU, and the spherical shell 1 has a diameter of 150 mm.
  • the two crushable containers 3 disposed inside the spherical shell 1 have a wall thickness of 0.5 mm, a length of 140 mm, and a diameter of 12 mm.
  • the breakable container 3 disposed inside the spherical shell 1 is a glass ampoule sealed at both ends of a wall thickness of 0.45 mm, a length of 50 mm, and a diameter of 9 mm, and is internally sealed with 1.6 g of a chemiluminescent agent 2-A, and the chemiluminescent agent 2 -A is a luminescent agent component containing bisoxalate and a fluorescer.
  • the spherical shell 1 is composed of a 1.5 mm thick elastic light-transmitting material silica gel, and the spherical shell 1 has a diameter of 80 mm.
  • the spherical shell 1 is filled with 2 ml of a chemiluminescent agent that is undergoing a luminescent reaction.
  • a hole 7 is formed in the hollow spherical shell 1.

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  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)

Abstract

一种发光球，包括一个由弹性透光材料构成的球体壳（1），该球体壳（1）内部具有空腔，所述空腔内有化学发光药剂（2-A,2-B），所述的化学发光药剂（2-A,2-B）是固体或液体或固体液体混合的，所述的化学发光药剂（2-A,2-B）为分别封装的两种混合后可发生化学发光反应的药剂，它们至少有一种装在一个或多个可破碎容器（3）内。采用在球壳体（1）内壁带有凸起（16）或多面体的或带有多个凹坑的或带有凹槽或／和凸筋的以及放置有纸片、塑料片、或小的塑料颗粒等分散碎粒，除了给人以均匀的分散效果感觉外还可以对可破碎容器（3）的及其破碎后的碎片起到一定的视觉遮蔽效果，减少使用者对例如玻璃碎片的不适观感。

Description

一种发光球 技术领域
本发明涉及一种发光球。
背景技术
一直以来化学发光装置大多为棒状，由荧光棒的变形而衍生出荧光手镯、荧光眼镜等产品，但由于球形结构的特殊性，化学发光难以启动，所以真正意义的发光球却一直没有出现。本发明设计了一种球状化学发光装置，填补了这一空白。从内部化学反应机制来看，民用化学发光是由取代苯基双草酸酯、荧光剂、氧化剂、溶剂等所产生的化学反应而获得。通常把含有取代苯基双草酸酯的组份叫做化学发光剂组份，把含有氧化剂的组份叫做氧化剂组份，它们统称化学发光药剂。在不同环境下，可以通过使用不同的溶剂或分散剂甚至不使用溶剂来获得高粘度或固体发光的效果。目前使用最广泛的取代苯基双草酸酯是双(2,4,5-三氯水杨酸正戊酯)草酸酯(CPPO)或双(2,4,5-三氯水杨酸异戊酯)草酸酯(CIPO)。使用前它们通常是与氧化剂分开存储的，使用时打破它们之间的隔离，使它们混合发光。
发明内容
针对上述问题，本发明的目的是提供一种发光球，该发光球为弹性球，其内部的化学发光系统可以按人们的要求来发光。
为实现上述目的，本发明采取以下技术方案：一种发光球，包括一个由弹性透光材料构成的球体壳，该球体壳内部具有空腔，其特征在于，所述空腔内有化学发光药剂，所述的化学发光药剂是固体或液体或固体液体混合的，所述的化学发光药剂为分别封装的两种混合后能发生化学发光反应的药剂，它们至少有一种装在一个或多个可破碎容器内。
根据上述权利要求所述的发光球，其特征在于，所述可破碎容器是密封的玻璃容器或薄膜囊。
根据上述权利要求所述的发光球，其特征在于，所述空腔内设有可破碎容器的激发装置。
根据上述权利要求所述的发光球，其特征在于，所述激发装置是一个能支撑和/或固定可破碎容器的架子。
根据上述权利要求所述的发光球，其特征在于，所述架子包括固定装置，与该固定装置相连的杆，所述杆的一端指向所述可破碎容器另一端指向所述球壳体内壁且靠近或接触到所述球壳体内壁，所述固定装置卡住所述可破碎容器。
根据上述权利要求所述的发光球，其特征在于，在所述球体壳上设有孔和与该孔相配合的密封塞，从该孔向球体壳的空腔内设有导管，在该导管位于所述球体壳空腔内的一端设有阻挡装置，该阻挡装置上设有漏隙，所述密封塞位于球体壳内的一面设有一杆，该杆的端部设有一能与所述导管的内壁相配合运动的活塞，所述可破碎容器位于该活塞与所述阻挡装置之间。
为了达到本发明的目的所采取的技术方案，一种发光球包括一个由透光材料构成的球体壳，该球体壳内部具有空腔，其特征在于，在所述球体壳上开设有孔，在该孔上设有密封塞，在所述空腔内装有化学发光药剂。
根据上述权利要求所述的发光球，其特征在于，在所述球体壳内设有密封的充气囊，在所述充气囊内或在所述充气囊与所述球体壳内壁之间装有所述化学发光药剂。
根据上述权利要求所述的发光球，其特征在于，所述球体壳内开设有孔，该孔上设有密封塞，所述球体壳内设有密封的充气囊，所述充气囊内设有化学发光药剂，所述的化学发光药剂为分别封装的两种混合后能发生化学发光反应的药剂，它们至少有一种装在一个或多个可破碎薄膜囊内。
根据上述权利要求所述的发光球，其特征在于，所述球体壳的外形为圆球形或椭球形或橄榄形或多面体形，其内表面是多面体的或带有多个凹坑或/和突起，或带有凹槽或/和凸筋。
本发明由于采取以上技术方案，其具有以下优点：1、本发明采用以上技术方案，真正实现了发光液体在内部的发光球体，充分展现了液体发光的特殊效果，尤其是球类转动弹跳时的发光效果，与现有电发光单纯的闪动等非常不同，大大增加了球类的娱乐性。2、本发明采用在球体壳内壁上设置多个圆锥状凸起，这样可以大大降低玻璃安培瓶破碎时和之后球玩耍时刺漏TPU外壳的可能性，其原因是因为凸起的部分架住了破碎的玻 璃碎片使其锐利的尖端无法形成足够的冲击力刺穿球壁。3、本发明采用在球壳体内壁带有凸起或多面体的或带有多个凹坑的或带有凹槽或/和凸筋的以及放置有纸片、塑料片、或小的塑料颗粒等分散碎粒，除了给人与均匀的分散效果感觉外还可以对可破碎容器的及其破碎后的碎片起到一定的视觉遮蔽效果，减少使用者对例如玻璃碎片的不适观感。
附图说明
图1是本发明的剖视图；
图2是本发明内容两个可破碎容器的发光球立体剖视图；
图3是图2所示发光球的剖视图；
图4是本发明带有支撑杆式激发装置的发光球剖视图；
图5是本发明带有两支可破碎容器和支撑杆式激发装置的发光球立体剖视图；
图6是本发明带有支撑架暨激发装置的发光球剖视图；
图7是图6的俯视图；
图8是本发明带有密封塞的发光球结构示意图；
图9是本发明带有充气内胆和密封塞的发光球结构示意图；
图10是本发明充气囊内胆带有化学发光液的发光球结构示意图；
图11是本发明球壳上设有导管的发光球结构剖面示意图；
图12是图11所示发光球的激发装置使用状态示意图；
图13是本发明球体壳内表面带有凸起的发光球剖视图。
本发明最佳实施方式
下面结合附图和实施例对本发明进行详细的描述。
如图1所示，本发明提供一种发光球，其包括球体壳1，该球体壳1由1.5mm厚的弹性透光材料聚乙烯(PE)构成，球体壳1的直径为65mm，内置1.5ml的化学发光药剂2-B，该化学发光药剂2-B是含有过氧化氢的氧化液。设置在球体壳1内的可破碎容器3是壁厚为0.3mm，长度为50mm，直径为9mm的两端封口的玻璃安培瓶，玻璃安培瓶内部密封有1.6g的化学发光药剂2-A，该化学发光药剂2-A是含有双草酸酯和荧光剂的发光剂组分，它们可以是固体的混合组分，也可以是溶于溶剂后成为液体的。使 用时向地面或墙面使劲投掷球体，击碎内部的玻璃安培瓶使化学发光药剂2-A释放，化学发光药剂2-A与化学发光药剂2-B混合后产生化学发光反应，释放可见光。发光球弹跳滚动使发光的液体分布在球体壳1内表面，非常美丽，震碎的玻璃碎片贴敷在壳体内壁表面也会闪闪发光。这种发光球由于其内部没有支撑，不会扎穿球壳壁。在该实施例中也可以使用两只玻璃安培瓶来分别封装化学发光药剂2-A与2-B，这样使用时击碎两只玻璃安培瓶释放化学发光药剂也可以获得美丽的液体与玻璃碎渣混合的发光效果。
如图2、图3所示，在本发明的另一优选实施例中，在球体壳1内设置有一对支撑架4，该支撑架4为激发装置。球体壳1由3mm厚的弹性透光材料热塑性聚氨酯TPU构成，球体壳1直径150mm，设置在球体壳1内部的两个可破碎容器3是壁厚为0.5mm，长度为140mm，直径为12mm的两端封口的玻璃安培瓶，其中一支内部密封有10ml的化学发光药剂2-A，该化学发光药剂是含有双草酸酯和荧光剂的发光剂组分；另一支内部密封有10ml的化学发光药剂2-B，该化学发光药剂是含有过氧化氢的氧化液。在支撑架4内嵌入了上述的两只玻璃安培瓶，使它们相对球体壳1固定，支撑架4可以焊接或粘接在球体壳内壁上，也可以是制造球体壳1时一起制造出来的一体的。使用时向地面或墙面使劲投掷球体，击碎玻璃安培使化学发光药剂2-A和化学发光药剂2-B释放，化学发光药剂2-A与化学发光药剂2-B混合后产生化学发光反应，释放可见光。
一方面，支撑架4在产品运输时保护了玻璃安培，使产品可以安全的被运输；另一方面，在使用时，带有支撑架4的产品在撞击时更加容易使用户找到投掷方向，因为使玻璃安培瓶在水平方向受力时更加容易破碎，所以带有支撑架4的发光球对于用户来说更加容易使用。
如图4所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料热塑性聚氨酯TPU构成，球体壳1直径为65mm，内置1.5ml的化学发光药剂2-B，该化学发光药剂2-B是含有过氧化氢的氧化液。设置在球体壳1内部的可破碎容器3为壁厚0.45mm，长度50mm，直径9mm的两端密封的玻璃安培瓶，其内部密封有1.6g的化学发光药剂2-A，该化学发光药剂2-A是含有双草酸酯和荧光剂的发光剂组分。玻璃安培瓶的两端接触球体壳1内表面且被球体壳1架空，激发装置4为一可固定玻璃安 培瓶的支架，它包括一个管状的固定装置4-1，固定装置4-1套住或卡住玻璃安培瓶的中间部位，延管状的固定装置4-1的径向有一杆4-2，杆端延伸至球体壳1内壁接触位置。使用时，用手按压球体壳1，球体壳1凹陷挤压杆4-2，杆4-2移动使管状固定装置4-1压碎玻璃安培瓶，使化学发光药剂2-A释放，化学发光药剂2-A与球体壳1内的化学发光药剂2-B混合后产生化学发光反应，释放可见光。
如图5所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料热塑性聚氨酯TPU构成，球体壳1直径65mm。设置在球体壳1内的两支可破碎容器3是壁厚为0.45mm，长度为50mm，直径为9mm的两端封口的玻璃安培瓶，其中一支玻璃安培瓶内有1.5ml的化学发光药剂2-B，该化学发光药剂2-B是含有过氧化氢的氧化液，另一支玻璃安培瓶内部密封有1.6g的化学发光药剂2-A，该化学发光药剂2-A是含有双草酸酯和荧光剂的发光剂组分。玻璃安培瓶的两端接触球体壳1内表面且被球壳架空。激发装置4也是固定玻璃安培瓶的支架，该支架包含固定装置4-1，和与固定装置4-1相连接的杆4-2。在本实施例中，固定装置4-1为扁管状，它套住或卡住两支玻璃安培瓶的中间部位，杆4-2端延伸至球体壳1内壁接触位置，且在杆端设置有按钮6，放大直径的按钮6使用户更加容易操作使用按压，同时也加强了激发装置4与球体壳1的固定效果。使用时，用手按压球体壳1，球体壳1凹陷挤压按钮6，带动杆4-2移动使扁管状固定装置4-1压碎两支玻璃安培瓶，使化学发光药剂2-A和化学发光药剂2-B释放，化学发光药剂2-A与化学发光药剂2-B混合后产生化学发光反应，释放可见光。
如图6、图7所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料聚丙烯PP构成，球体壳1直径80mm。球体壳1内注有10ml的化学发光药剂2-B，该化学发光药剂2-B是含有过氧化氢的氧化液；设置在球体壳1内的可破碎容器3是一个装有16ml的化学发光药剂2-A的0.5mm厚的复合铝箔薄的薄膜密封囊，发光剂组分是含有双草酸酯和荧光剂和柠檬酸三乙酯溶剂的溶液。支撑架即激发装置4是一组由硬塑料构成的机构，它包含固定装置4-1和可用来穿刺的杆4-2，杆4-2的尖端位于薄膜密封囊上方，另一端接触在球体壳1内表面。在杆4-2与固定装置4-1连接处设置有支撑架的导向孔8，杆4-2穿过该导向孔8。使用时，从 球体壳1外部按压杆4-2，其通过支撑架导向孔8向下滑动，杆4-2的下尖端刺穿薄膜密封囊构成的可破碎容器3，化学发光药剂2-A释放，化学发光药剂2-A与化学发光药剂2-B混合后产生化学发光反应，释放可见光。
如图8所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料硅胶构成，球体壳1直径为80mm。球体壳1内注有正在进行发光反应的化学发光药剂50ml。空心的球体壳1上开有孔7，并以密封塞9密封。该发光球的优点是发光停止后可以打开密封塞9倒出已经停止发光的化学发光药剂后重新装入新的化学发光药剂从而反复使用。
如图9所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料硅胶构成，球体壳1直径为80mm。球体壳1内注有正在进行发光反应的化学发光药剂2ml。空心球体壳1上开有孔7。充气囊10是由0.1mm厚的聚乙烯制成的密封气囊，充气囊10薄膜囊在瘪时从孔7中塞入，从气门芯(单向进气口)11给充气囊10充气，气囊鼓起后会将化学发光药剂挤压至球体壳1的内壁与充气囊10之间，以密封塞9密封球壳后即可玩耍。该发光球的优点是发光可以最大面积的均匀的分布在球壳内部。
如图10所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料聚氯乙烯PVC构成，球体壳1直径为80mm。空心的球体壳1上开有孔7。充气囊10是由0.1mm厚的聚乙烯制成的，囊内有正在进行发光反应的化学发光药剂20ml，充气囊10充气前从孔7中塞入，从气门芯(单向进气口)11给充气囊充气，充气囊鼓起后以密封塞9密封球壳后即可玩耍。该发光球的优点是可以更换带有化学发光药剂的充气囊10，使发光球可以重复使用。充气囊10内的两种可以相互反应发生发光反应的化学发光药剂可以事先设置在分别密封的可破碎薄膜囊内，使用前从冲气囊10外压破可破碎薄膜囊，使化学发光药剂混合发光。由于该方案可以避免化学发光药剂接触球体壳1，所以本实施例中球体壳1的材料还可以是聚酯PET或聚醋酸乙烯酯EVA或热塑橡胶TPR。
如图11、图12所示，在本发明的另一优选实施例中，球体壳1由1.5mm厚的弹性透光材料聚丙烯PP构成，球体壳1直径80mm。空心的球体壳1上开有直径为15mm的孔7。其中在孔7位置上设置有向球体壳1内部延伸的长40mm导管12，导管12的顶端设置有阻挡装置13，阻挡装置13上设有漏隙14；在导管12内还设置有活塞15，该活塞15的顶端设置有密封 塞9，活塞15的下端设有两个可破碎容器3，两个可破碎容器3内分别装有化学发光药剂2-A和2-B，可破碎容器可以是玻璃安培瓶或薄膜密封囊。使用时压下密封塞9，从而推动活塞15压碎可破碎容器释放化学发光药剂，该化学发光药剂通过漏隙14流入球壳内部混合发光，同时密封塞9堵住开口7使之成为一个密封完整的球体。
如图13所示，在本发明的另一优选实施例中，球体壳1由2mm厚的弹性透光材料热塑性聚氨酯TPU构成，球体壳1直径为100mm。设置在球体壳1内的可破碎容器3是壁厚为0.5mm，长度为85mm，直径为10mm的两端封口的玻璃安培瓶，其中密封有4g的化学发光药剂2-A，该化学发光药剂2-A是含有双草酸酯和荧光剂的发光剂组分。化学发光药剂2-B是含有过氧化氢的氧化液4ml，球体壳1内壁上设有多个圆锥状凸起16，启动装置发光后，内壁的圆锥状凸起16可以更好的分散发光液体使之减慢向下流动聚集，使发光更加均匀。同理，球体壳1的内表面还可以是多面体的或带有多个凹坑的或带有凹槽或/和凸筋的，这都可以使发光液体或固体分布得更加均匀。
在球体壳1内壁上设置多个圆锥状凸起16还可以大大降低玻璃安培瓶破碎时和之后球玩耍时刺漏TPU外壳的可能性，其原因是因为凸起的部分架住了破碎的玻璃碎片使其锐利的尖端无法形成足够的冲击力刺穿球壁。在一个球体壳1直径为65mm、壁厚为2mm的TPU球中放置两只直径为10mm壁厚为0.35mm长度为60mm的玻璃安培瓶，安培瓶内各装有发光药剂2ml，球内充气2kg/cm^2；另一对比测试的球壳是直径65mm，壁厚1.8mm的，内壁布满多个直径1.2mm高1.2mm的凸圆柱，圆柱间隔1.2mm，球内装有与前述相同的玻璃安培瓶并充气。上述两种球各500个，在击碎内部安培瓶后在从4米高处掷向地面100次，之后检查球壁刺漏情况，没有内部凸起的球有4个被检出球壁有微小的破口，而内壁带有凸起圆柱的球则没有发现刺漏的情况。
球体壳1外形可以是球形或椭球形或橄榄状的或多面体的。在球体壳1内部空腔内还可以放置分散碎粒，也可以使发光液体或固体分布得更加均匀或有趣。其中碎粒可以是纸片、塑料片、或小的塑料颗粒等等。复杂的外形或内部的分散碎粒可以使发光液体或固体分布得更加均匀或流动更加有趣。内壁带有凸起或多面体的或带有多个凹坑的或带有凹槽或/和 凸筋的以及放置有纸片、塑料片、或小的塑料颗粒等分散碎粒，除了给人与均匀的分散效果感觉外还可以对可破碎容器的及其破碎后的碎片起到一定的视觉遮蔽效果，减少使用者对例如玻璃碎片的不适观感。
最后所应说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的精神和范围，其均应涵盖在本发明的权利要求范围当中。

Claims (10)

  1. 一种发光球，包括一个由弹性透光材料构成的球体壳，该球体壳内部具有空腔，其特征在于，所述空腔内有化学发光药剂，所述的化学发光药剂是固体或液体或固体液体混合的，所述的化学发光药剂为分别封装的两种混合后能发生化学发光反应的药剂，它们至少有一种装在一个或多个可破碎容器内。
  2. 根据权利要求1所述的发光球，其特征在于，所述可破碎容器是密封的玻璃容器或薄膜囊。
  3. 根据权利要求1所述的发光球，其特征在于，所述空腔内设有可破碎容器的激发装置。
  4. 根据权利要求3所述的发光球，其特征在于，所述激发装置是一个能支撑和/或固定可破碎容器的架子。
  5. 根据权利要求4所述的发光球，其特征在于，所述架子包括固定装置，与该固定装置相连的杆，所述杆的一端指向所述可破碎容器另一端指向所述球壳体内壁且靠近或接触到所述球壳体内壁，所述固定装置卡住所述可破碎容器。
  6. 根据权利要求1所述的发光球，其特征在于，在所述球体壳上设有孔和与该孔相配合的密封塞，从该孔向球体壳的空腔内设有导管，在该导管位于所述球体壳空腔内的一端设有阻挡装置，该阻挡装置上设有漏隙，所述密封塞位于球体壳内的一面设有一杆，该杆的端部设有一能与所述导管的内壁相配合运动的活塞，所述可破碎容器位于该活塞与所述阻挡装置之间。
  7. 一种发光球，包括一个由透光材料构成的球体壳，该球体壳内部具有空腔，其特征在于，在所述球体壳上开设有孔，在该孔上设有密封塞，在所述空腔内装有化学发光药剂。
  8. 根据权利要求7所述的发光球，其特征在于，在所述球体壳内设有密封的充气囊，在所述充气囊内或在所述充气囊与所述球体壳内壁之间装有所述化学发光药剂。
  9. 根据权利要求7所述的发光球，其特征在于，所述球体壳内开设有孔，该孔上设有密封塞，所述球体壳内设有密封的充气囊，所述充气囊 内设有化学发光药剂，所述的化学发光药剂为分别封装的两种混合后能发生化学发光反应的药剂，它们至少有一种装在一个或多个可破碎薄膜囊内。
  10. 根据权利要求1或9所述的发光球，其特征在于，所述球体壳的外形为圆球形或椭球形或橄榄形或多面体形，其内表面是多面体的或带有多个凹坑或/和突起，或带有凹槽或/和凸筋。
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