US3578962A - Light producing device - Google Patents

Light producing device Download PDF

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Publication number
US3578962A
US3578962A US844810A US3578962DA US3578962A US 3578962 A US3578962 A US 3578962A US 844810 A US844810 A US 844810A US 3578962D A US3578962D A US 3578962DA US 3578962 A US3578962 A US 3578962A
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United States
Prior art keywords
light
flask
producing device
tube
light producing
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Expired - Lifetime
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US844810A
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Robert L Gerber
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ROBERT L GERBER
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ROBERT L GERBER
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
    • F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
    • F21K2/06—Non-electric light sources using luminescence; Light sources using electrochemiluminescence using chemiluminescence

Definitions

  • a chemiluminescent light-producing devicev comprising a glass flask containing an oxalate ester and fluorescer in a solvent and having provided in the neck of said flask a tube holding hydrogen peroxide which when released by appropriate means reacts with the oxalate ester to produce light.
  • the present light sources generally relay upon battery power to provide light for illumination. These devices in many situations have limitations, such as, adversely affecting night vision, awkwardness in carrying and stowing underwater, attracting unwanted attention, etc. Their shelf life is limited due to battery deterioration, bulbs are fragile, and corrosion of electrical contacts reduces reliability. Although such devices have served the purpose, the present invention provides a light producing source which possesses none of the aforementioned disadvantages.
  • FIG. is a sectional view of the preferred embodiment of this invention.
  • Tube I4 extends.
  • Tube I4 is provided with a movable spring operated metal piston 17 which extends centrally therethrough and which has positioned at the top an actuator 18.
  • a closure spring 19 is mounted between the actuator I8 and the top of the stopper 16.
  • the bottom of said aluminum tube 14 is sealed by valve 20.
  • actuator 18 is depressed against the closure spring 19 moving piston I7 against valve 20 thereby releasing the hydrogen peroxide 15 into flask 1] where it mixes with said oxalate ester 13 creating a light.
  • Spring 19 then returns piston 17 to its original position.
  • This flask is of unbreakable clear glass and may have a reflector on one side.
  • a clear plastic flask may also be used.
  • the size varies in accordance with the need; for example, the device may be of pocket size for ease in carrying or may be larger if there is storage room in the craft or vessel in which it is to be used.
  • Modification of the flask includes adding material to make it buoyant or to make it sink once it has served its purpose.
  • the present invention provides a nonbeaming light with increased output and duration over such chemiluminescent materials as the peraminoethylencs, and exhibits low sensitivity to varying environmental factors.
  • a light producing device comprising a nonbreakable clear glass long-necked flask; bis(2,4,5-
  • said tube being provided with a spring actuated piston sealed in the top of said tube and a valve positioned at the base of said tube; said piston being positioned ad acent said valve;

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Luminescent Compositions (AREA)

Abstract

A chemiluminescent light-producing device comprising a glass flask containing an oxalate ester and fluorescer in a solvent and having provided in the neck of said flask a tube holding hydrogen peroxide which when released by appropriate means reacts with the oxalate ester to produce light.

Description

United States Patent C09k 1/02, F21k 2/00 [50] Field of Search 240/225, 26; 252/1883, 188 (X) [56] References Cited UNITED STATES PATENTS 3,511,612 5/1970 Kennerly et a1 252/188.3X
Primary ExaminerLouis R. Prince Assistant Examiner-Frederick Shoon AttorneysEdgar J. Brower and Roy Miller ABSTRACT: A chemiluminescent light-producing devicev comprising a glass flask containing an oxalate ester and fluorescer in a solvent and having provided in the neck of said flask a tube holding hydrogen peroxide which when released by appropriate means reacts with the oxalate ester to produce light.
Patented May 18, 1971 I N VEN 0R. ROBE RT L. GERBER ROY MILLER ATTORNEY.
LIGHT PRODUCING DEVICE GOVERNMENT INTEREST The invention described herein may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of any royalties thereon or therefor.
BACKGROUND OF THE INVENTION The present light sources generally relay upon battery power to provide light for illumination. These devices in many situations have limitations, such as, adversely affecting night vision, awkwardness in carrying and stowing underwater, attracting unwanted attention, etc. Their shelf life is limited due to battery deterioration, bulbs are fragile, and corrosion of electrical contacts reduces reliability. Although such devices have served the purpose, the present invention provides a light producing source which possesses none of the aforementioned disadvantages.
It is therefore an object of the present invention to provide a light source which has indefinite shelf life and requires no maintenance to keep in readiness. Another object is to provide an underwater light source of high intensity with high rcliability as a nonbeaming flashlight, night signal, etc.
DESCRIPTION OF THE DRAWING The single FIG. is a sectional view of the preferred embodiment of this invention.
DESCRIPTION OF THE INVENTION through which said .tube I4 extends. Tube I4 is provided with a movable spring operated metal piston 17 which extends centrally therethrough and which has positioned at the top an actuator 18. A closure spring 19 is mounted between the actuator I8 and the top of the stopper 16. The bottom of said aluminum tube 14 is sealed by valve 20.
In operation actuator 18 is depressed against the closure spring 19 moving piston I7 against valve 20 thereby releasing the hydrogen peroxide 15 into flask 1] where it mixes with said oxalate ester 13 creating a light. Spring 19 then returns piston 17 to its original position.
This flask is of unbreakable clear glass and may have a reflector on one side. A clear plastic flask may also be used. The size varies in accordance with the need; for example, the device may be of pocket size for ease in carrying or may be larger if there is storage room in the craft or vessel in which it is to be used.
Modification of the flask includes adding material to make it buoyant or to make it sink once it has served its purpose.
The present invention provides a nonbeaming light with increased output and duration over such chemiluminescent materials as the peraminoethylencs, and exhibits low sensitivity to varying environmental factors.
Iclaim:
l. A light producing device comprising a nonbreakable clear glass long-necked flask; bis(2,4,5-
trichloro-fi-carbobutoxphcnyl)oxalate partially filling said flask;
a tube substantially filled with hydrogen peroxide sealed in the neck of said flask and extending about midway into said flask;
said tube being provided with a spring actuated piston sealed in the top of said tube and a valve positioned at the base of said tube; said piston being positioned ad acent said valve;
whereby actuation of said piston opens said valve releasing the hydrogen peroxide into said bis(2,4,5-trichloro-6carbobutoxphenyl)oxalate oxalate which reacts to emit light.
2. The device in accordance with claim I wherein said tube is composed of aluminum.

Claims (1)

  1. 2. The device in accordance with claim 1 wherein said tube is composed of aluminum.
US844810A 1969-07-25 1969-07-25 Light producing device Expired - Lifetime US3578962A (en)

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US84481069A 1969-07-25 1969-07-25

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3752406A (en) * 1971-09-17 1973-08-14 American Cyanamid Co Containers for chemical light solutions
US3900728A (en) * 1973-04-13 1975-08-19 Gordon B Holcombe Hand held device for activating a chemiluminescent wand
US3940605A (en) * 1974-12-18 1976-02-24 The United States Of America As Represented By The Secretary Of The Navy Chemiluminescent marker apparatus
US4015111A (en) * 1975-08-19 1977-03-29 Donald Spector Inflatable, chemi-luminescent assembly
USRE30103E (en) * 1975-08-19 1979-09-25 Inflatable, chemi-luminescent assembly
US4505063A (en) * 1983-04-29 1985-03-19 Price Donald L Night fishing signal
US4563726A (en) * 1984-08-20 1986-01-07 Newcomb Nelson F Illuminated chemiluminescent drinking mug
US4758520A (en) * 1986-03-10 1988-07-19 Oread Laboratories, Inc. Chemiluminescence method for assaying compounds containing primary amino groups using 1-cyano-2-substituted benz(f)- or naphth(f)-isoindole fluorescers
US4796161A (en) * 1986-11-04 1989-01-03 Meir Savariego Actuation device for a plurality of chemical light sources
US5001880A (en) * 1990-04-25 1991-03-26 Smith Henry J Method for producing luminescent paintballs
US5029049A (en) * 1990-03-03 1991-07-02 American Cyanamid Company Tubular chemiluminescent lighting element
US5215492A (en) * 1989-07-28 1993-06-01 Kubiatowicz James F Toy balloon with cool illumination
US5381311A (en) * 1993-07-16 1995-01-10 Nihon Kagaku Hakkou K.K. Chemiluminescence device
US20170144032A1 (en) * 2014-07-11 2017-05-25 Beijing Wenhaiyang Industry & Trading Co., Ltd. A type of glow ball

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3511612A (en) * 1967-03-20 1970-05-12 American Cyanamid Co Chemiluminescent systems

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3511612A (en) * 1967-03-20 1970-05-12 American Cyanamid Co Chemiluminescent systems

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3752406A (en) * 1971-09-17 1973-08-14 American Cyanamid Co Containers for chemical light solutions
US3900728A (en) * 1973-04-13 1975-08-19 Gordon B Holcombe Hand held device for activating a chemiluminescent wand
US3940605A (en) * 1974-12-18 1976-02-24 The United States Of America As Represented By The Secretary Of The Navy Chemiluminescent marker apparatus
US4015111A (en) * 1975-08-19 1977-03-29 Donald Spector Inflatable, chemi-luminescent assembly
USRE30103E (en) * 1975-08-19 1979-09-25 Inflatable, chemi-luminescent assembly
US4505063A (en) * 1983-04-29 1985-03-19 Price Donald L Night fishing signal
US4563726A (en) * 1984-08-20 1986-01-07 Newcomb Nelson F Illuminated chemiluminescent drinking mug
US4758520A (en) * 1986-03-10 1988-07-19 Oread Laboratories, Inc. Chemiluminescence method for assaying compounds containing primary amino groups using 1-cyano-2-substituted benz(f)- or naphth(f)-isoindole fluorescers
US4796161A (en) * 1986-11-04 1989-01-03 Meir Savariego Actuation device for a plurality of chemical light sources
US5215492A (en) * 1989-07-28 1993-06-01 Kubiatowicz James F Toy balloon with cool illumination
US5029049A (en) * 1990-03-03 1991-07-02 American Cyanamid Company Tubular chemiluminescent lighting element
US5001880A (en) * 1990-04-25 1991-03-26 Smith Henry J Method for producing luminescent paintballs
US5381311A (en) * 1993-07-16 1995-01-10 Nihon Kagaku Hakkou K.K. Chemiluminescence device
US20170144032A1 (en) * 2014-07-11 2017-05-25 Beijing Wenhaiyang Industry & Trading Co., Ltd. A type of glow ball
US10286260B2 (en) * 2014-07-11 2019-05-14 Beijing Wenhaiyang Industry & Trading Co., Ltd. Type of glow ball

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