WO2015155546A1 - Compositions intumescentes - Google Patents

Compositions intumescentes Download PDF

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Publication number
WO2015155546A1
WO2015155546A1 PCT/GB2015/051103 GB2015051103W WO2015155546A1 WO 2015155546 A1 WO2015155546 A1 WO 2015155546A1 GB 2015051103 W GB2015051103 W GB 2015051103W WO 2015155546 A1 WO2015155546 A1 WO 2015155546A1
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WO
WIPO (PCT)
Prior art keywords
melamine
intumescent
phosphate
component
ducting
Prior art date
Application number
PCT/GB2015/051103
Other languages
English (en)
Inventor
Kjetil BOGSTAD
Wolodymyr Hluchan
Original Assignee
Polyseam Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyseam Limited filed Critical Polyseam Limited
Publication of WO2015155546A1 publication Critical patent/WO2015155546A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/02—Inorganic materials
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62C—FIRE-FIGHTING
    • A62C2/00—Fire prevention or containment
    • A62C2/06—Physical fire-barriers
    • A62C2/065—Physical fire-barriers having as the main closure device materials, whose characteristics undergo an irreversible change under high temperatures, e.g. intumescent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C09D5/185—Intumescent paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/02—Inorganic materials
    • C09K21/04—Inorganic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/10—Organic materials containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus

Definitions

  • the present invention relates to a novel intumescent composition.
  • the composition relates to an intumescent composition having improved properties.
  • the intumescent material of the present invention finds particular utility in construction.
  • Intumescent materials are substances that swell upon exposure to heat and produce a char. Because the materials swell and char they are poor conductors of heat and are used in passive fire protection. However existing intumescent compositions have a number of drawbacks, which can limit their use in certain applications.
  • the intumescent compositions of the present invention are useful to provide fire retardant barriers in many construction applications, for example in ventilation units, to provide fire resistant sealants around doors and windows, and for use in ducting, air transfer grills and cable transit tubes.
  • Some intumescent compositions of the prior art are not suitable for a range of applications. For example some intumescent materials need to reach very high temperatures before swelling and thus do not protect against fires which are small or at some distance away. These fires may still produce high levels of smoke which may be toxic and can cause significant damage to property. Some intumescent materials only swell by a small volume and thus cannot be used to close large spaces. Some intumescent materials swell only very slowly and thus significant smoke damage can occur before a complete seal is formed. Some materials do not form a very dense char and thus the intumescent material can be blown away causing the barrier to break down. It is also desirable that a fire stop barrier is not too bulky in normal use and does not affect normal operation of the opening which it is intended to seal in the event of a fire.
  • an intumescent composition comprising: (a) an intumescent material comprising phosphorus, sulphur, a halogen, a melamine compound, boron, a polyol or a mixture thereof;
  • an expandable intumescent material selected from graphite, silicate, vermiculite and mixtures thereof;
  • Component (a) is an intumescent material comprising phosphorous, sulfur, a halide, boron, a melamine compound, a polyol or a mixture thereof. Intumescent materials of this type are well known to the person skilled in the art.
  • Component (a) may comprise phosphorus.
  • phosphorus By this we mean to include any compound comprising a phosphorus atom or ion.
  • Such compounds include, but are not limited to, phosphates, polyphosphates and other phosphoric acid salts and derivatives.
  • Component (a) may comprise sulfur. By this we mean to include any compound comprising a sulfur atom or ion. Such compounds include, but are not limited to, sulfates and other sulfuric acid salts and derivatives. Component (a) may comprise boron. By this we mean to include any compound comprising a boron atom or ion. Such compounds include, but are not limited to, borates and other boric acid salts and derivatives.
  • Component (a) may comprise a halogen.
  • a halogen By this we mean to include any compound comprising a halogen atom or halide ion. Such compounds include, but are not limited to, chloride and bromide salts.
  • Component (a) may comprise one or more compounds selected from ammonium polyphosphate, phosphoric acid, sulphuric acid, boric acid, salts of boric acid, ammonium tetraborate, potassium tetraborate, sodium tetraborate, ammonium phosphate, ammonium sulphate, ammonium halides, urea, guanylurea phosphate, reaction products of P 2 0 5 and ammonia, tricresyl phosphate, alkyl phosphate, haloalkyl phosphates, melamine, melamine cyanurate, melamine phosphate, melamine pyrophosphate, melamine polyphosphate, dicyandiamide, azodicarbonamide, linear amines (e.g.,
  • ethylene diamine-o-phosphate guanidine phosphate
  • melamine borate melam
  • melem melon
  • pentaerythritol dipentaerythritol
  • tripentaerythritol starch
  • sugar glucose, dextrin
  • sorbitol mannitol
  • phenol formaldehyde resins and methylol melamine.
  • component (a) comprises a phosphorous containing intumescent material.
  • component (a) comprises a phosphate-containing intumescent material.
  • component (a) comprises ammonium polyphosphate.
  • component (a) comprises a melamine compound.
  • component (a) comprises melamine.
  • component (a) comprises a polyol, i.e. a polyhydric alcohol. Suitable polyhydric alcohols include sugars and other carbohydrates.
  • Preferred polyols are pentaerythritol, dipentaerythritol and tripentaerythritol. Pentaerythritol is especially preferred.
  • component (a) comprises a mixture of compounds.
  • component (a) comprises a first material selected from ammonium polyphosphate, phosphoric acid, sulphuric acid, boric acid, salts of boric acid, ammonium tetraborate, potassium tetraborate, sodium tetraborate, ammonium phosphate, ammonium sulphate, ammonium halides, urea, guanylurea phosphate, reaction products of P 2 0 5 and ammonia, tricresyl phosphate, alkyl phosphate and haloalkyl phosphates; a second material selected from melamine, melamine cyanurate, melamine phosphate, melamine pyrophosphate, melamine polyphosphate, dicyandiamide, azodicarbonamide, linear amines (e.g.,
  • ethylene diamine-o-phosphate guanidine phosphate
  • melamine borate melam, melem, melon
  • a third material selected from pentaerythritol, dipentaerythritol, tripentaerythritol, starch, sugar, glucose, dextrin, sorbitol, mannitol, phenol formaldehyde resins, and methylol melamine.
  • component (a) comprises a first material selected from ammonium polyphosphate, ammonium tetraborate and ammonium phosphate; a second material selected from melamine and dicyandiamide; and a third material selected from pentaerythritol, dipentaerythritol and tripentaerythritol.
  • component (a) comprises a phosphate-containing compound and a melamine compound.
  • component (a) comprises ammonium polyphosphate and melamine.
  • component (a) further comprises a polyol.
  • component (a) comprises a phosphate-containing compound, a melamine compound and a pentaerythritol compound.
  • Component (b) comprises an expandable intumescent material selected from graphite, silicate, vermiculite and mixtures thereof. Materials of this type are known to the person skilled in the art. Preferably component (b) comprises an expandable graphite material.
  • Component (c) is a polymeric binder.
  • Suitable polymeric binders include styrene/acrylic copolymers, vinyl acetate polymers, vinyl acetate/VeoVa/acrylate copolymers, acrylic polymers, acrylic/VeoVa copolymers, acrylic/styrene copolymers, styrene/butadiene copolymers, styrene/butadiene/acrylonitrile copolymers, polybutadiene polymers, alkyd polymers, epoxy polymers, polyurethane modified silanes, silicones, polysulphides, polyaspartic polymers and polyurethane polymers.
  • VeoVa refers to the vinyl ester of versatic acid. As the skilled person will appreciate a number of versatic acids are available. Versatic acid 1 0, a highly branched isomer of decanoic acid is preferred.
  • Preferred polymeric binders for use in the compositions of the present invention are styrene/acrylic copolymers.
  • the polymeric binder is preferably incorporated into the composition as an aqueous emulsion.
  • Such an emulsion typically comprises particles of the polymer suspended in an emulsion which coalesce on drying to form the polymeric binder.
  • Component (d) is a fibrous material.
  • Suitable fibrous materials include silicate fibres, mineral fibres, aramid fibres, carbon fibres, imide fibres, cellulosic fibres and diatomaceous earth fibres.
  • Especially preferred fibrous materials are alkaline earth silicate fibres.
  • the fibres are from 1 ⁇ to 1 mm in diameter.
  • the intumescent composition further comprises (e), an inorganic filler.
  • suitable inorganic fillers include titanium dioxide, kaolin, barytes, perlite (aluminium silicate), cenospheres, carbonates (e.g. calcium carbonate and dolomite), metal hydroxides (e.g. aluminium hydroxide, magnesium hydroxide), huntite, hydromagnesite, vermiculite (mica), Portland cement clinker, glass, plaster of paris (gypsum), calcined kaolin, fly ash, slag, calcium sulfate, silica gel, silicates (e.g.
  • silicate calcium silicate
  • silica quartz
  • talc talc
  • wollastonite zinc stearate
  • zinc oxide aluminium oxide
  • zeolite zeolite
  • Ceepree glass frits
  • lead oxide silicon and borates (e.g. potassium tetraborate, potassium borate, ammonium tetraborate, sodium borate).
  • borates e.g. potassium tetraborate, potassium borate, ammonium tetraborate, sodium borate.
  • Component (a) is preferably present in the intumescent composition of the present invention in an amount of at least 5 wt%, suitably at least 10 wt%, preferably at least 15 wt%, preferably at least 20 wt%, more preferably at least 25 wt%, for example at least 30 wt% or at least 35 wt%.
  • Component (a) may be included in the composition in an amount of up to 80 wt%, suitably up to 70 wt%, preferably up to 65 wt%, suitably up to 60 wt%, more preferably up to 55 wt%, for example up to 50 wt% or up to 45 wt%.
  • component (a) comprises a mixture of compounds the above amounts refer to the total of all such compounds present in the composition.
  • the composition comprises ammonium phosphate or ammonium polyphosphate in an amount of from 10 to 40 wt%, suitably from 15 to 35 wt%, preferably from 20 to 30 wt%, for example from 22 to 28 wt%.
  • the composition includes a melamine component in an amount of from 1 to 20 wt% preferably from 2 to 15 wt%, suitably from 5 to 10 wt%.
  • the composition comprises a pentaerythritol component in amount of 1 to 20 wt% preferably from 2 to 15 wt%, suitably from 5 to 10 wt%.
  • the intumescent composition of the present invention comprises from 15 to 35 wt% of ammonium polyphosphate, from 2 to 15 wt% of melamine, and from 2 to 15 wt% of pentaerythritol.
  • Component (b) is preferably present in the intumescent composition of the present invention in amount of at least 1 wt%, suitably at least 2.5 wt%, preferably at least 5 wt%, more preferably at least 7 wt%, for example at least 8 wt% or at least 1 0 wt%.
  • Component (b) may be included in the intumescent composition in an amount of up to 40 wt%, suitably up to 30 wt%, preferably up to 25 wt%, more preferably up to 20 wt%, for example up to 17 wt% or up to 15 wt%.
  • component (b) comprises a mixture of compounds
  • the above amounts refer to the total amounts of all such compounds present in the composition.
  • Component (c) is a polymeric binder. This may suitably be incorporated into the composition in the form of a solution or emulsion, preferably an aqueous emulsion of polymeric binder.
  • the binder is suitably provided as a solution or emulsion comprising from 10 to 80 wt%, preferably from 30 to 70 wt%, typically from 35 to 65 wt% solids.
  • binder precursor composition This solution or emulsion may be described as binder precursor composition.
  • the binder precursor composition is suitably incorporated in the intumescent composition of the present invention in amount of at least 1 wt%, suitably in an amount of at least 5 wt%, preferably at least 10 wt%, more preferably at least 12 wt%, for example at least 15 wt%, at least 20 wt% or at least 25 wt%.
  • the binder precursor composition may be included in the composition in an amount of up to 50 wt%, suitably up to 45 wt%, more preferably up to 40 wt%, for example up to 35 wt%, up to 33 wt% or up to 30 wt%.
  • the binder precursor composition is suitably included in an amount to provide an intumescent composition comprising from 1 to 50 wt%, preferably from 10 to 35 wt%, and more preferably from 15 to 30 wt% polymeric binder.
  • an intumescent composition comprising from 1 to 50 wt%, preferably from 10 to 35 wt%, and more preferably from 15 to 30 wt% polymeric binder.
  • the above amount refers to the total amounts of all binders and binder precursor compositions included in the intumescent composition of the present invention.
  • Component (d) is preferably present in the intumescent composition of the present invention in amount of at least 0.1 wt%, preferably at least 0.25 wt%, suitably in an amount of at least 0.5 wt%, preferably at least 0.75 wt%, more preferably at least 1 wt%.
  • Component (d) may be included in the composition in an amount of up to 10 wt%, suitably up to 5 wt%, preferably up to 4 wt%, for example up to 3 wt%, or up to 2 wt%.
  • component (d) comprises a mixture of compounds the above amounts refer to the total of all such compounds present in the composition.
  • Component (e) is preferably present in the intumescent composition of the present invention in amount of at least 0.1 wt%, preferably at least 1 wt%, suitably at least 2.5 wt%, preferably at least 5 wt%, more preferably at least 7 wt%.
  • Component (e) may be included in the composition in an amount of up to 30 wt%, suitably up to 25 wt%, preferably up to 20 wt%, more preferably up to 1 5 wt%, for example up to 12 wt%.
  • component (e) comprises a mixture of compounds the above amounts refer to the total of all such compounds present in the composition.
  • the intumescent composition of the present invention may further comprise one or more solvents. Suitable solvents include water and other water-miscible solvents.
  • the composition comprises at least 1 wt% water, preferably at least 2.5 wt%, more preferably at least 5 wt%.
  • the intumescent composition may comprise up to 30 wt% water, preferably up to 20 wt%, more preferably up to 12 wt%.
  • the above amounts refer to water added to the composition in addition to any water included in other ingredients, for example a binder precursor composition.
  • the intumescent composition of the present invention may comprise one or more further components selected from biocides, fragrances, fillers, adhesion agents, additional intumescents and fire-stop agents, buffers, dispersing agents, surfactants, deaerators, defoamers, surface control additives, hydrophobing agents, wetting additives, rheological additives, anti-cratering additives, radiation curing additives, anti-corrosion additives and anti- graffiti additives.
  • the composition may comprise a pH regulator. Any suitable pH regulator may be used and these will be known to the person skilled in the art. One suitable pH regulator is 2-amino-2- methyl-1 -propanol.
  • the intumescent composition has a pH of from 5 to 13, suitably from 7 to 1 1 .
  • the intumescent composition of the present invention offers a number of advantages over intumescent compositions of the prior art.
  • composition of the present invention intumesces at a relatively low temperature and expands quickly to form a dense char.
  • the char formed by the intumescent composition of the present invention suitably has sufficient structural rigidity to withstand a pressure difference of 300Pa between the fire and non-fire sides of the barrier formed.
  • the composition swells to at least 5 times (500%), preferably at least 7 times (700%) of its original thickness in less than 2 minutes when heated according to the EN1363-1 (ISO 834) fire test.
  • the temperature in the furnace after 1 minute of this test is approximately 349 °C and after 2 minutes it is approximately 445 °C.
  • the intumescent composition of the present invention intumesces at a temperature of 200 S C or less, preferably 150 S C or less, preferably 120 S C or less.
  • the intumescent composition of the present invention may be used in a variety of applications.
  • the composition may be used to seal around a door, window or other opening, in ducting, in air transfer grills and in cable/utility transit tubes.
  • composition of the present invention may be applied to a substrate by any suitable means.
  • a substrate may be painted, dipped or cast into sheets.
  • the present invention finds particular utility in ducting.
  • the intumescent composition of the present invention may suitably be included in a fire damper for ducting.
  • a damper for ducting comprising at least one fin comprising an intumescent composition of the first aspect.
  • the damper of the second aspect may be directly located within the ducting or may be provided in a housing which fits into the ducting or is adapted to connect to the ducting.
  • the damper may be used with any type of ducting.
  • the ducting will typically be tubular in nature. It may have any shape of cross-section. In common embodiments the ducting is of circular cross-section, and substantially cylindrical.
  • the damper comprises at least one fin comprising an intumescent composition. Suitably the plane of the fin is substantially perpendicular to the cross-section of the ducting.
  • cross-section of the ducting we mean to refer to a plane through the ducting which is substantially perpendicular to the longitudinal axis of the ducting.
  • a cylindrical ducting will typically have a circular cross section.
  • the damper may comprise more than one fin.
  • the plane of the or each fin is preferably substantially perpendicular to the cross section of the ducting. Positioning the fin or fins substantially perpendicular to the cross-section ensures that any reduction of the area of cross-section is minimised and thus air flow through the ducting is not significantly inhibited.
  • any reference to a fin applies as appropriate to each fin, in embodiments in which more than one fin is present.
  • the fin comprises an intumescent composition of the first aspect.
  • the fin may consist essentially of the intumescent composition i.e. it is within the scope of the first aspect of the present invention to provide an intumescent composition of sufficient structural rigidity to be formed into a fin.
  • the fin comprises a substantially planar structure in which the intumescent composition is contained.
  • the substantially planar structure in which the intumescent composition is contained may be made of any suitable material. Such materials include metals, plastics and wood.
  • the fin comprises a substantially planar structure which is coated with the intumescent composition. In some embodiments one face of the fin is coated with the intumescent composition. In preferred embodiments both faces of the fin are coated with the intumescent composition.
  • the fin may comprise a substantially solid planar substrate. However in preferred embodiments the fin comprises one or more apertures. Suitably the fin may be perforated, or in the form of a grid or mesh.
  • apertures in the structure of the fin enables the intumescent composition to expand through the apertures.
  • the fins may be made from any suitable material. Such materials include plastics, wood and metals.
  • the fin is a plastic fin the plastic suitably has a melting point which is at least as high as the temperature at which the composition intumesces.
  • the damper comprises a plurality of fins. These may be positioned in any orientation relative to each other.
  • each fin is substantially perpendicular to the cross-section of the ducting.
  • the damper of the second aspect of the present invention comprises more than one fin.
  • the damper comprises a plurality of fins which are substantially parallel to each other.
  • the fin or each fin is located within a housing.
  • the second aspect of the present invention provides a damper for ducting comprising a housing and at least one fin located within the housing, wherein the fin comprises an intumescent composition
  • the housing is suitably shaped to fit within or connect to the ducting.
  • the damper is shaped to connect to the ducting.
  • the damper will connect two sections of ducting on either side of a fire barrier.
  • the ducting is substantially cylindrical.
  • the housing is ring shaped.
  • the damper of the second aspect comprises a ring shaped housing comprising a plurality of fins which each comprise an intumescent composition.
  • each fin is preferably substantially perpendicular to the circular face defined by the ring of the housing.
  • the fins may be oriented in any position relative to each other. They may form a plurality of spoke or arcs. In some embodiments the fins may form a grid.
  • the damper comprises a plurality of fins which are substantially parallel to each other.
  • the fins are spaced approximately equidistant from each other.
  • the present invention suitably provides a damper comprising a ring shaped housing comprising a plurality of fins which are substantially parallel to each other and substantially perpendicular to the circular cross-section of the ring wherein each fin comprises an intumescent composition.
  • the damper comprises a mesh which extends across the cross- section of the ducting or the housing when present.
  • the mesh is suitably substantially adjacent to the fin or fins.
  • the damper comprises two meshes and the fin or fins are positioned therebetween.
  • the mesh is suitably provided to prevent expanded intumescent material from being blown away through the ducting.
  • the damper of the present invention comprises a ring shaped housing comprising a plurality of fins which comprise an intumescent composition ; wherein each circular face of the housing is closed by a mesh and wherein the fins are substantially parallel to each other and substantially perpendicular to the meshes.
  • the or each fin of the dampers of the present invention comprises an intumescent composition.
  • each fin is coated with the intumescent composition.
  • each side of each fin is coated with the intumescent composition.
  • Figure 1 shows a damper of the present invention
  • Figure 2 shows a cross-sectional view of the damper of figure 2.
  • Figure 3 shows the damper connected to a portion of ducting. Preferred features of this embodiment will now be described. However it will be appreciated that these features may as appropriate apply to other embodiments of the invention.
  • the damper comprises a ring shaped housing 1 which is made of steel. Within the housing are a plurality of parallel fins 2 which are affixed to the internal surface of the housing 3. The fins each comprise a number of apertures 4. However it will be appreciated that fins which are solid or which are in the form of a grid or mesh could also be used.
  • the fins in a preferred embodiment are made of steel but alternative materials may be used. In the embodiment shown the fins are spot-welded onto the inside of the housing, but other methods of fixing the fins into the housing are within the scope of the invention.
  • Each fin is coated on both sides with a layer of intumescent material 5. This is only shown on the bottom fin in figure 2. However embodiments in which only one face of the fin is coated are also within the scope of the invention.
  • the intumescent material may be coated onto the fin by any suitable means, for example painting, dipping or casting into sheets.
  • the intumescent composition is structurally rigid and may itself be formed directly into a fin, rather than being applied to a separate substrate.
  • the fin may be cast, moulded or extruded. It may be made by any other suitable method.
  • Each face of the damper housing is closed by a mesh 6 which can be seen in figure 2 but is not shown in figure 1 .
  • the mesh is suitably a metal or other material which can withstand high temperatures likely to arise in a fire.
  • the mesh may be held in position by a plurality of metal fingers (not shown).
  • the distance between the fins is preferably approximately equal. The distance is suitably selected to ensure that a char is able to form quickly and close the gaps between the fins.
  • the distance between the fins is preferably at least 0.5cm, preferably at least 1 cm, suitably at least 1 .5cm, for example at least 2cm or at least 2.5cm.
  • the distance between the fins may be up to 10cm, suitably up to 8cm, preferably up to 7cm, suitably up to 6cm, for example up to 5cm or up to 4.5 cm.
  • the coating of intumescent compositions on each fin is preferably at least 0.1 mm thick, suitably at least 0.25mm, for example at least 0.5mm.
  • the coating suitably has a thickness of less than 10mm, preferably less than 5mm.
  • ducting comprising a damper of the second aspect.
  • An intumescent composition of the invention was prepared comprising the following components:
  • Figure 4B shows the damper after the test which clearly shows that a dense char has formed closing the ducting.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
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Abstract

La présente invention concerne une composition intumescente comprenant : (a) un matériau intumescent comprenant du phosphore, du soufre, un halogène, un composé de mélamine, du bore, un polyol ou un mélange de ceux-ci ; (b) un matériau intumescent expansible choisi parmi le graphite, le silicate, la vermiculite et des mélanges de ceux-ci ; (c) un liant polymère ; et (d) un matériau fibreux.
PCT/GB2015/051103 2014-04-11 2015-04-10 Compositions intumescentes WO2015155546A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1406542.9A GB201406542D0 (en) 2014-04-11 2014-04-11 Intumescent compositions
GB1406542.9 2014-04-11

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WO2015155546A1 true WO2015155546A1 (fr) 2015-10-15

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN107163655A (zh) * 2017-06-26 2017-09-15 东莞市道尔新材料科技有限公司 Dopo基膨胀阻燃剂
WO2020201422A1 (fr) * 2019-04-03 2020-10-08 Sika Technology Ag Évent à revêtement intumescent pour véhicules de transport de passagers de grande capacité
US11814837B2 (en) 2016-08-05 2023-11-14 1824930 Alberta Ltd. Intumescent grid

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US11814837B2 (en) 2016-08-05 2023-11-14 1824930 Alberta Ltd. Intumescent grid
CN107163655A (zh) * 2017-06-26 2017-09-15 东莞市道尔新材料科技有限公司 Dopo基膨胀阻燃剂
CN107163655B (zh) * 2017-06-26 2019-08-13 东莞市道尔新材料科技有限公司 Dopo基膨胀阻燃剂
WO2020201422A1 (fr) * 2019-04-03 2020-10-08 Sika Technology Ag Évent à revêtement intumescent pour véhicules de transport de passagers de grande capacité
CN113412311A (zh) * 2019-04-03 2021-09-17 Sika技术股份公司 用于大型客车的膨胀型涂层涂覆的通风口
JP2022525837A (ja) * 2019-04-03 2022-05-20 シーカ テクノロジー アクチェンゲゼルシャフト 大型乗用車のための発泡性コーティングを有するベント

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