WO2015150121A1

WO2015150121A1 - Cosmetic preparation for uv-protection based on an acrylate copolymer and hydroxyethyl cellulose

Info

Publication number: WO2015150121A1
Application number: PCT/EP2015/055937
Authority: WO
Inventors: Andreas Bleckmann; Heike Lerg; David SCHLENKER
Original assignee: Beiersdorf Ag
Priority date: 2014-04-01
Filing date: 2015-03-20
Publication date: 2015-10-08
Also published as: EP3125861A1; DE102014206219A1

Abstract

The invention relates to a cosmetic preparation containing a) an acrylate copolymer having a glass transition temperature of between -5 to -15 C°, measured by means of DSC and b) hydroxyethyl cellulose.

Description

description

COSMETIC PREPARATION FOR UV PROTECTION BASED ON ONE

ACRYLATE COPOLYMER AND HYDROXYETHYL CELLULOSE

The present invention relates to a cosmetic preparation comprising an acrylate copolymer having a glass transition temperature of -5 to -15 ° C, measured by means of DSC and hydroxyethyl cellulose.

The desire to look beautiful and attractive is inherently rooted in man. Although the ideal of beauty has undergone changes over time, the pursuit of an impeccable appearance has always been the goal of man. An essential part of a beautiful and attractive appearance is the condition and appearance of the skin.

Skin care products usually consist of emulsions. Emulsions are generally understood to mean heterogeneous systems which consist of two liquids which are immiscible or only to a limited extent miscible with one another, which are usually referred to as phases, and in which one of the two liquids is in the form of very fine droplets in the other

Liquid is dispersed. Viewed externally and with the naked eye, emulsions appear homogeneous.

However, the variety of commercially available skincare products must not obscure the fact that these prior art formulations have a number of disadvantages.

An essential task of skin care products is to moisten the skin over a longer period of time or to keep it moist. A typical, much used one

Skin moisturizer is glycerin. However, glycerin has the disadvantage of being effective skin moisturizing only in higher amounts, but to act very sticky at higher use concentrations. It was therefore the object of the present invention to develop an alternative skin care agent that is less sticky.

A relatively new product form for skincare is the hydrodispersions used in the shower, which are applied to the wet skin after a first showering process, wherein subsequently in a second showering process excess, not fixed on the skin preparation is rinsed off (so-called in-shower products, the analog as shower gels are applied, in contrast to these, however, do not clean, but apply the care product on the skin). These products often have the disadvantage that the skin moisturizing caused by them is inadequate by the product itself and does not last long enough.

It was therefore the object of the present invention to develop an in-shower product which acts as a skin moisturizer stronger and longer than the preparations of the prior art.

A disadvantage of the conventional in-shower products is not least the fact that they can hardly be effectively applied with UV light protection filters for the UV protection of the skin. Most of the UV filters are rinsed more or less completely from the skin during the second showering process, so that virtually no UV protection can occur.

It was therefore the object of the present invention to develop an in-shower product with which larger amounts of UV filters can be effectively applied to the skin. In particular, SPFs of at least SPF 6 should be at a normal

Application can be achieved.

Surprisingly, the objects are achieved by a cosmetic preparation comprising a) an acrylate copolymer having a glass transition temperature of -5 to -15 ° C, measured by means of DSC and

b) hydroxyethylcellulose.

The glass transition temperature according to the invention is determined by means of differential scanning calorimetry. In the context of the present invention (i.e.

according to the invention) was a Mettler DCS 1 device in the temperature cycle mode with a perforated aluminum crucible (40μΙ), at a measurement temperature of -50 ° C to +150 ° C, a heating rate of 10 ° C / min. and nitrogen used as purge gas (nitrogen 5.0). Skin hydration is determined according to the invention by the following method:

First, in a 1. Measurement of skin hydration with the Corneometer C 825 (Courage & Khazaka) on 4 areas on the forearms. This value corresponds to the skin moisture of untreated skin.

Subsequently, the measured areas on the forearms are preconditioned as follows: They are kept under running water, approx. 32-35 ° C, for 10 seconds, then foamed with 2mg / cm ² shower bath, 10s and rinsed under running water for 15s.

Subsequently, the wet areas 10s with the preparation to be tested in a

Creaming amount of 2mg / cm ² creams, washed 15s with 32-35 ° C warm water and dabbed dry with a hand towel and measured the skin moisture with the Corneometer C 825. The measurement is repeated after 1 h.

It is advantageous according to the invention if the preparation contains the acrylate copolymer in a concentration of 0.1 to 10% by weight, based on the total weight of the preparation.

It is preferred according to the invention if the preparation contains the acrylate copolymer in a concentration of 0.5 to 5% by weight, based on the total weight of the preparation.

Embodiments of the present invention which are advantageous according to the invention are characterized in that the preparation contains hydroxyethyl cellulose in a concentration of 0.05 to 5% by weight, based on the total weight of the preparation.

Embodiments of the present invention which are preferred according to the invention are characterized in that the preparation contains hydroxyethylcellulose in a concentration of 0.1 to 3% by weight, based on the total weight of the preparation.

According to the invention, the preparation according to the invention may advantageously contain glycerol.

In such a case, advantageous embodiments of the present invention are characterized in that the preparation contains glycerol in a concentration of 0.1 to 20% by weight, based on the total weight of the preparation. Embodiments of the present invention which are preferred according to the invention are characterized in that the preparation contains glycerol in a concentration of 0.5 to 15

% By weight, based on the total weight of the preparation.

It is advantageous for the purposes of the present invention if the acrylate copolymer has a pH of 4.5 to 6.5

The acrylate copolymer according to the invention can be purchased, for example, under the trade name Epitex 66 polymer from Dow.

It is inventively advantageous if the preparation contains one or more UV filters, which are selected from the group of compounds 2-phenylbenzimidazole-5-sulfonic acid and / or salts thereof; Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and its salts; 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid; 2-methyl-5- (2-oxo-3-bornylidene-methyl) sulfonic acid salts; 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol); 2- (2H-Benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [(trimethylsilyl) oxy] disiloxanyl] propyl] -phenol; 3- (4-methylbenzylidene) camphor; 3-benzylidene-camphor; ethylhexyl salicylate; Terephthalidendicamphersulfonsäure; 2-ethylhexyl-2-cyano-3,3-diphenylacrylate; 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester; 4- (dimethylamino) benzoic acid amyl ester; 4-Methoxybenzalmalon-säuredi (2-ethylhexyl) ester; 4-methoxycinnamate (2-ethylhexyl) ester; Isoamyl 4-methoxycinnamate; 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone; 2,2'-dihydroxy-4-methoxybenzophenone; homomenthyl; 2-ethylhexyl 2-hydroxybenzoate;

dimethicodiethylbenzalmalonate; 3- (4- (2,2-ethoxycarbonylvinyl) phenoxy) propenyl) methoxysiloxane / dimethylsiloxane copolymer; 4- (tert-butyl) -4'-methoxydibenzoylmethane; Hexyl 2- (4'-diethylamino-2'-hydroxybenzoyl) benzoate; Dioctylbutylamidotriazone (INCI: diethylhexyl-butamidotriazone); 2,4-bis- [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) imino] -6- (2-ethylhexyl) -imino-1,3,5-triazine having the (CAS No 288254-16-0); 2,4-Bis - {[4- (2-ethylhexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) ; 4,4 ', 4 "- (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester) (also: 2,4,6-tris [anilino] (p-carbo-2'-ethyl-1'-hexyloxy)] - 1, 3,5-triazine (INCI: ethylhexyl triazone); 2, 4, 6-tribiphenyl-4-yl-1,3,5-triazine Merocyanines; titanium dioxide; zinc oxide.

It is inventively preferred if one or more compounds selected from the group 4- (tert-butyl) -4'-methoxydibenzoylmethane, 2-phenylbenzimidazole-5 as UV filter. sulfonic acid and / or salts thereof, ethylhexyl salicylate, homomenthyl salicylate, 2-ethylhexyl-2-cyano-3,3-diphenylacrylate, 4,4 ', 4 "- (1,3,5-triazine-2,4,6-triyltriimino) tris (2-ethylhexyl) tris-benzoate and 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3, 5-triazine can be selected.

Embodiments which are advantageous according to the invention are furthermore characterized in that the preparation is free of propyl and butyl paraben, 3-iodo-2-propynyl butylcarbamate, methylisothiazolinone, 3- (4-methylbenzylidene) camphor and 2-hydroxy-4-methoxybenzophenone (oxybenzone ).

On the other hand, embodiments according to the invention are obtained when the preparation ethylhexylglycerol, propylene glycol, butylene glycol, 2-methylpropane-1,3-diol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and / or 1,2 -Decandiol contains.

In addition, it is advantageous according to the invention if the preparation contains phenoxyethanol and / or methylparaben.

It is advantageous for the purposes of the present invention if the preparation contains one or more active substances selected from the group of the compounds magnolia extract,

Glycyrrhetinic acid, urea, arctiin, alpha-lipoic acid, folic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, caffeine, natural and / or synthetic isoflavonoids, glycerylglucose, creatine, creatinine, taurine, tocopherol, tocopherol acetate, ß-alanine and / or licochalcone A contains.

It is also advantageous according to the invention if the preparation according to the invention contains one or more complexing agents. According to the invention, the use of ethylenediaminetetraacetic acid alkali metal salts (EDTA) is preferred.

According to the invention, the preparation according to the invention preferably contains from 0.02 to 1.5% by weight of EDTA, based on the total weight of the preparation.

It is also advantageous according to the invention if the preparation contains one or more

Emulsifiers selected from the group of compounds glyceryl stearate citrate,

Cetearyl Alcohol, Sodium Cetearyl Sulfate + Glyceryl Stearate, Cetearyl Sulfosuccinate

Sodium stearoyl glutamate, polyglyceryl-3-methyl glucose distearate,

Stearic acid, potassium cetyl phosphate. In this case, a content of polyglyceryl-3-methylglucose distearate is preferred according to the invention. If the preparation according to the invention contains polyglyceryl-3-methylglucose distearate, this emulsifier is used in a concentration of 0.05 to 5% by weight, based on the total weight of the preparation.

It is inventively advantageous if the inventive preparation contains acrylate / C 10-30 alkyl acrylate crosspolymer.

If the preparation contains acrylate / C 10-30 alkyl acrylate crosspolymer, it is

is preferred according to the invention when this compound is used in a concentration of 0.05 to 2.5% by weight, based on the total weight of the preparation.

Embodiments which are advantageous according to the invention are also characterized in that the preparation contains ethanol.

If the preparation contains ethanol, it is preferred according to the invention if these

Compound in a concentration of 1 to 15% by weight, based on the

Total weight of the preparation is used.

The oil phase of the preparation according to the invention may also contain other oil, fat and wax components, for example, polar oils from the group of lecithins or compounds such. Cocoglyceride, caprylic / capric triglyceride, olive oil, sunflower oil, jojoba oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grapeseed oil, thistle oil, evening primrose oil, macadamia nut oil and the like. Also compounds such as phenethyl benzoate, 2-phenylethyl benzoate, isopropyl lauroyl sarcosinate, phenyl trimethicone, cyclomethicone, dibutyl adipate, octyl palmitate, octyl cocoate, octyl isostearate, octyldodeceyl myristate, octyldodecanol, cetearyl isononanoate, isopropyl myristate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, stearyl heptanoate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, tridecyl stearate, tridecyl trimellitate can be used.

Also advantageous according to the invention are z. As natural waxes of animal and vegetable origin, such as beeswax and other insect waxes and berry wax, shea butter and / or lanolin (wool wax). Furthermore, the oil phase can be advantageously selected from the group of dialkyl ethers and dialkyl carbonates, advantageous z. B. dicaprylyl ether (Cetiol OE) and / or Dicaprylyl- carbonate, for example, that available under the trade name Cetiol CC in the company. Cognis.

It is furthermore advantageous to use the oil component or components from the group of isoeicosane, neopentyl glycol diheptanoate, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, C 12-13 -alkyl lactate, di-C 12-13 -alkyl tartrate, triisostearin, dipentaerythrityl Hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethylisosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of Ci2-is-alkyl benzoate.

Advantageous oil components are also z. Isopropyl palmitate, myristyl myristate,

Butyl octyl salicylate (for example that available under the trade name Hallbrite BHB from the company CP Hall), tridecyl salicylate (which is available under the trade name Cosmacol ESI from the company. Sasol), C12-C15 alkyl salicylate (under the trade name Dermol NS in the company Alzo available), hexadecyl benzoate and butyl octyl benzoate and mixtures thereof (Hallstar AB).

Any mixtures of such oil and wax components are also advantageous to use in the context of the present invention.

Furthermore, the oil phase can also advantageously contain non-polar oils, for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes, C13- 16 isoparaffin and isohexadecane. Among the polyolefins, polydecenes are the preferred substances.

It is preferred according to the invention if the preparation according to the invention

Dialkyl carbonate, dialkyl adipate and / or dialkylglutarate contains.

According to the invention it is particularly preferred if the preparation according to the invention contains di-n-octyl carbonate (INCI dicaprylyl carbonates) and / or di-n-butyl adipate (INCI dibutyl adipate).

In addition, the preparation according to the invention may contain the customary ingredients and be composed as a conventional preparation. The preparation of the invention can be used particularly advantageously as a daily care product or sunscreen.

It is particularly preferred according to the invention to use the preparation according to the invention as an in-shower product. Therefore, in-shower products are based on a

Inventive cosmetic preparation according to the invention.

The use of the cosmetic according to the invention is also according to the invention

Preparation as ln-shower product.

Contains the preparation of the invention one or more UV filters, so is the

Use of this preparation according to the invention for protecting the skin from UV radiation according to the invention.

According to the invention, the method for moistening and care of the skin, which is characterized in that the preparation according to the invention is applied to the wet skin after showering and then excess residues of the preparation are rinsed off again by means of a water shower.

According to the invention, the method for protecting the skin from UV radiation, which is characterized in that a preparation according to the invention containing one or more of the present invention advantageous UV filter is applied to the wet skin after showering and then excess residues of the Preparation be rinsed by means of a water shower again.

According to the invention, the drying of the skin (preferably by means of a towel) preferably follows in both methods as a further method step.

Comparative test

The effect of the invention was demonstrated by way of example with the following experiment: The following formulations were prepared: 1 2 3

INCI m [%] m [%] m [%]

Epitex 66 Acrylates Copolymer ¹ 2.00

Comparative Polymer Acrylates 2.00

Copolymer ²

Polyglyceryl-3 methylglucose 0.10 0.10 0.10

Distearate

Perfume 0.40 0.40 0.40

Glycerine + Aqua 1.00 1.00 1.00

Aqua + Sodium Hydroxide 0.30 0.30 0.30

Phenoxyethanol 0.50 0.50 0.50

Hydroxyethylcellulose 0.10 0.10 0.10

Acrylates / C10-30 alkyl acrylates 0.20 0.20 0.20

Crosspolymer

Carbomer 0.10 0.10 0.10

Aqua 52,27 50,47 56,27

Alcohol Denat. + Aqua 10.00 10.00 10.00

Trisodium EDTA 1.00 1.00 1.00

Butyl Methoxydibenzoylmethane 3.50 3.50 3.50

Phenylbenzimidazole sulfonic acid 0.10 0.10 0.10

Ethylhexyl salicylate 4.50 4.50 4.50

Ethylhexyl triazone 1.00 1.00 1.00

Octocrylene 9.00 9.00 9.00

Homosalats 9,00 9,00 9,00

Bis-ethylhexyloxyphenol 1.00 1.00 1.00

Methoxyphenyl triazines

Diethylhexyl butamido triazone 0.50 0.50 0.50

Diethylamino Hydroxybenzoyl Hexyl 1.00 1.00 1.00

Benzoate

Titanium Dioxide (nano) + Silica + 0.43 0.43 0.43

Methicone + Aqua

Amount used Epitex 66 = 4.4% by weight. This then corresponds to the specified acrylates

Crosspolymer concentration of 2% by weight (effective value)

² Daitosol 3000SLPN from Daitosakai with a glass transition temperature of + 14.5

Of these preparations, the skin moisturizing performance was as follows

Method determines:

First, in a 1. Measurement of skin hydration with the Corneometer C 825 (Courage & Khazaka) on 4 areas on the forearms. This value corresponds to the skin moisture of untreated skin. Subsequently, the measured areas on the forearms are preconditioned as follows: They are kept under running water, approx. 32-35 ° C, for 10 seconds, then foamed with 2mg / cm ² shower bath, 10s and rinsed under running water for 15s.

Subsequently, the wet areas 10s with the preparation to be tested in a

Creaming amount of 2mg / cm2 creams, wash 15s with 32-35 ° C warm water and dabbed dry with a hand towel and measured the skin moisture with the Corneometer C 825. The measurement is repeated after 1 h.

Skin moisture measurement with Corneometer C 825

N = 5

Acrylates copolymer

Examples

The following examples are intended to illustrate the present invention without limiting it. Unless indicated otherwise, all amounts, proportions and percentages are based on the weight and the total amount or on the total weight of the preparations.

Crosspolymer concentration of 2% by weight (effective value)

9 10 11 12

INCI m [%] m [%] m [%] m [%]

Epitex 66 (Acrylates Crosspolymer) ¹ 2.0 2.0 2.0 2.0

Polyglyceryl-3 methylglucose 0.1 0.1 0.1 0.1 distearate

Perfume 0.4 0.4 0.4

Glycerol + Aqua 9.0 5.0 5.0 4.6

Aqua + Sodium Hydroxide 0.3 0.3 0.3 0.3

Phenoxyethanol 0.5 0.5 0.5 0.5

Hydroxyethyl cellulose 0.1 0.1 0.1 0.1

Acrylates / C10-30 Alkyl Acrylates 0.2 0.2 0.2 0.2 Crosspolymer

Carbomer 0.1 0.1 0.1 0.1

Alcohol Denat. + Aqua 10.0 10.0 10.0 10.0

Trisodium EDTA 1.0 1.0 1.0 1.0

Butyl Methoxydibenzoylmethane 2.5 3.5 4.3 4.9

Ethyl hexyl salicylate 4,5 4,5

Ethyl hexyl triazone 1.0 1.0 1.0

Octocrylene 2.3 9.0 5.0 9.0

Homosalates 9.0 9.0 9.0

Bis-ethylhexyloxyphenol 1.0 1.0 1.0 1.0 methoxyphenyl triazines

Diethylhexyl butamido triazone 0.5 0.5 0.5 0.5

Diethylamino Hydroxybenzoyl Hexyl 1.0 1.0 1.0 1.0 Benzoate

Phenylbenzimidazole sulfonic acid 1.0 2.0

Disodium phenyl dibenzimidazole 0.2 0.5

Tetrasulfonate

Methylene bis-benzotriazolyl 3.0 4.4 tetramethyl butylphenol

Tris-biphenyl triazines 1.0 3.0

Titanium Dioxide 3.0 3.2

Aqua ad 100 ad 100 ad 100 ad 100 Amount used Epitex 66 = 4.4% by weight. This then corresponds to the indicated acrylates crosspolymer concentration of 2% by weight (effective value)

Claims

claims

1 . Contains cosmetic preparation

a) an acrylate copolymer having a glass transition temperature of -5 to -15 C °, measured by DSC and

b) hydroxyethylcellulose.

2. Cosmetic preparation according to claim 1, characterized in that the

Preparation containing the acrylate copolymer in a concentration of 0.5 to 5% by weight, based on the total weight of the preparation.

3. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation contains hydroxyethylcellulose in a concentration of 0.05 to 5% by weight, based on the total weight of the preparation.

4. Cosmetic preparation according to one of the preceding claims, characterized

characterized in that the acrylate copolymer has a pH of 4.5 to 6.5

5. Cosmetic preparation according to one of the preceding claims, characterized

characterized in that the preparation contains glycerol.

6. Cosmetic preparation according to one of the preceding claims, characterized

characterized in that the preparation contains one or more UV filters selected from the group of the compounds 2-phenylbenzimidazole-5-sulphonic acid and / or salts thereof; Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and its salts; 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid; 2-methyl-5- (2-oxo-3-bornylidenemethyl) sulfonic acid salts; 2,2'-methylene-bis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol); 2- (2H-Benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [(trimethylsilyl) oxy] disiloxanyl] propyl] phenol ; 3- (4-methylbenzylidene) camphor; 3-benzylidenecamphor; ethylhexyl salicylate;

Terephthalidendicamphersulfonsäure; 2-ethylhexyl-2-cyano-3,3-diphenylacrylate; 2-ethylhexyl 4- (dimethylamino) benzoate; 4- (dimethylamino) benzoic acid amyl ester; 4-Methoxybenzalmalon-säuredi (2-ethylhexyl) ester; 2-ethylhexyl 4-methoxycinnamate; Isoamyl 4-methoxycinnamate; 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone;2,2'-dihydroxy-4-methoxybenzophenone;homomenthyl; 2-ethylhexyl 2-hydroxybenzoate; dimethicodiethylbenzalmalonate; 3- (4- (2,2-ethoxycarbonylvinyl) phenoxy) propenyl) methoxysiloxane / dimethylsiloxane copolymer; 4- (tert-butyl) -4'-methoxydibenzoylmethane; 2- (4'-diethylamino-2'-hydroxybenzoyl) benzoic acid hexyl ester; Dioctylbutylamidotriazone (INCI: diethylhexylbutamidotriazone); 2,4-bis [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) -imino] -6- (2-ethylhexyl) -imino-1,3,5-triazine with (CAS No. 288254-16-0); 2,4-Bis - {[4- (2-ethylhexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) ; 4,4 ', 4 "- (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester) (also: 2,4,6-tris [anilino] (p-carbo-2'-ethyl-1'-hexyloxy)] - 1, 3,5-triazine (INCI: ethylhexyl triazone); 2,4,6-tribiphenyl-4-yl-1,3,5-triazine Merocyanines; titanium dioxide; zinc oxide.

7. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation is free from propyl and butyl paraben, 3-iodo-2-propynyl butylcarbamate, methylisothiazolinone, 3- (4-methylbenzylidene) camphor and 2-hydroxy-4-methoxybenzophenone (oxybenzone).

8. Cosmetic preparation according to one of the preceding claims, characterized

characterized in that the preparation ethylhexylglycerol, propylene glycol,

Butylene glycol, 2-methylpropane-1, 3-diol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-octanediol and / or 1, 2-decanediol.

9. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation comprises one or more active substances selected from the group of the compounds magnolia extract, glycyrrhetinic acid, urea, arctiin, alpha-lipoic acid, folic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, caffeine, natural and / or synthetic isoflavonoids,

Glyceryl glucose, creatine, creatinine, taurine, tocopherol, tocopherol acetate, β-alanine and / or licochalcone A.

10. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation contains phenoxyethanol and / or methylparaben.

1 1. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation contains one or more complexing agents.

12. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation comprises one or more emulsifiers selected from the group of the compounds glyceryl stearate citrate, cetearyl alcohol

Sodium Cetearyl Sulfate + Glyceryl Stearate, Cetearyl Sulfosuccinate

Sodium stearoyl glutamate, polyglyceryl-3-methyl glucose distearate,

Stearic acid, potassium cetyl phosphate.

13. Cosmetic preparation according to one of the preceding claims, characterized

in that the preparation contains acrylate / C 10-30 alkyl acrylate crosspolymer.

14. Cosmetic preparation according to one of the preceding claims, characterized

characterized in that the preparation contains ethanol.

15. In-shower product based on a cosmetic preparation according to one of claims 1 to 14.

16. Use of a cosmetic preparation according to one of the preceding claims as an in-shower product.

17. Use of a preparation according to any one of claims 6 to 16 for protecting the skin from UV radiation.

18. A method for moistening and care of the skin, characterized in that a preparation according to claim 1 to 15 after showering is applied to the wet skin and then excess residues of the preparation are rinsed by means of a water shower again.

19. A method for protecting the skin from UV radiation, characterized in that a preparation according to claim 6 to 16 after showering is applied to the wet skin and then excess residues of the preparation are rinsed by means of a water shower again.