WO2015082491A1 - Kunststoffrohr und herstellverfahren hierfür - Google Patents
Kunststoffrohr und herstellverfahren hierfür Download PDFInfo
- Publication number
- WO2015082491A1 WO2015082491A1 PCT/EP2014/076295 EP2014076295W WO2015082491A1 WO 2015082491 A1 WO2015082491 A1 WO 2015082491A1 EP 2014076295 W EP2014076295 W EP 2014076295W WO 2015082491 A1 WO2015082491 A1 WO 2015082491A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- plastic
- polyamide
- reinforcing structure
- polyethylene
- Prior art date
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 163
- 239000004033 plastic Substances 0.000 title claims abstract description 163
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 129
- 239000004698 Polyethylene Substances 0.000 claims description 50
- 229920000573 polyethylene Polymers 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 49
- -1 polyethylene Polymers 0.000 claims description 41
- 229920001903 high density polyethylene Polymers 0.000 claims description 37
- 239000004700 high-density polyethylene Substances 0.000 claims description 36
- 239000004952 Polyamide Substances 0.000 claims description 34
- 229920002647 polyamide Polymers 0.000 claims description 34
- 229920001684 low density polyethylene Polymers 0.000 claims description 31
- 229920000299 Nylon 12 Polymers 0.000 claims description 29
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 24
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims description 23
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 18
- 230000002787 reinforcement Effects 0.000 claims description 18
- 239000004702 low-density polyethylene Substances 0.000 claims description 13
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 13
- 238000001125 extrusion Methods 0.000 claims description 10
- 239000002318 adhesion promoter Substances 0.000 claims description 9
- 239000007767 bonding agent Substances 0.000 claims description 9
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 238000001746 injection moulding Methods 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 12
- 239000010410 layer Substances 0.000 description 231
- 239000000463 material Substances 0.000 description 21
- 239000000835 fiber Substances 0.000 description 12
- 239000000155 melt Substances 0.000 description 12
- 239000002356 single layer Substances 0.000 description 11
- 238000007711 solidification Methods 0.000 description 11
- 230000004888 barrier function Effects 0.000 description 10
- 230000008023 solidification Effects 0.000 description 10
- 239000004744 fabric Substances 0.000 description 7
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 6
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000002990 reinforced plastic Substances 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
- F16L9/127—Rigid pipes of plastics with or without reinforcement the walls consisting of a single layer
- F16L9/128—Reinforced pipes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
Definitions
- the invention relates to a plastic raw r, which is designed as a high-pressure tube, with a tube wall comprising a first layer of a plastic, and arranged in the tube wall reinforcing structure and a manufacturing method thereof.
- a plastic pipe which has a laminated and multilayer pipe wall.
- a first layer of the tube wall is formed by an inner carrier tube made of plastic.
- the support tube is spirally wound with a reinforcing tape made of a cord material. The subsequently wound on the support tube
- Reinforcing tape is coated with an adhesive and connected thereto to the support tube. Finally, around the carrier tube laminated in this way, a second layer of plastic is externally extruded to protect the reinforcing strip.
- wound reinforcing strip made of plastic are also known from international patent application WO 2009/109609 A1 and the German utility model DE 202 19 222 U1.
- a corresponding multilayer plastic raw r with a wound reinforcing wire is known from the German utility model DE 1 813 312 U.
- a "layer of plastic" with respect to a pipe wall of a plastic pipe refers to that material of the same plastic which is solidified together from a plasticized, melt-shaped state and thereby becomes a load-bearing component of the pipe wall.
- the plastic pipes known from the abovementioned documents all have a multilayer structure whose individual layers of plastic are produced by a plurality of extrusion steps carried out in succession and solidified individually in individual process steps arranged between two successively generated layers of the corresponding tube wall.
- the invention has for its object to provide an improved designed as a high-pressure tube plastic raw r with a tube wall comprising a first layer of a plastic, and provided in the tube wall reinforcing structure to provide its structure and mechanical properties are optimized.
- Another object is to provide a simple manufacturing method for a corresponding reinforced plastic pipe.
- a plastic raw r which is designed as a high-pressure tube, with a tube wall comprising a first layer of a plastic, and one in the
- Tube wall arranged reinforcing structure thereby improving that the
- Reinforcing structure is tubular and is embedded in the first layer.
- Corresponding high-pressure pipes are designed in particular for the passage of fluids, preferably oil, water or gas, at a pressure of up to 60 bar. Due to the embedded reinforcing structure, the plastic tube has an improved
- the reinforcing structure embedded in the first layer makes it possible, in a particularly advantageous manner, to connect so-called welding fittings for connecting two successive plastic pipe ends
- Clamp fittings can be used.
- plastic pipes in which the reinforcing structure is not embedded in a layer, but is arranged between two successively constructed layers, by so-called
- a stable embedding of the reinforcing structure in the layer of the tube wall also results from the fact that the reinforcing structure has varying distances to an inner surface and an outer surface of the first layer. Because of that
- Reinforcement structure is preferably fabric-like and in particular Having openings, the reinforcement of the tube wall is increased and the reinforcing structure particularly stable embedded in the layer, since the plastic of the layer penetrates the openings.
- the embedding of the reinforcing structure is further improved by the fact that the first layer at least partially, in particular in the region of openings of the
- Reinforcement structure extending continuously between the inner surface and the outer surface.
- the plastic of the first layer comprises EVOH, polyamide, in particular polyamide 12, polyethylene, in particular an LDPE or an HDPE, or a compound of polyethylene, in particular an LDPE or a HDPE, and polyamide, in particular polyamide 12 , If the first layer contains the aforementioned EVOH or preferably polyamide material, this advantageously reduces the gas permeability, especially at high pressure stages, and increases the oil resistance. In this way, the first layer forms a chemically resistant, that is in particular to acids, alkalis and
- EVOH would be particularly useful with respect to helium or hydrogen. If the first layer contains the abovementioned PA and / or PE material, this ensures the mechanical properties of the plastic pipe required in relation to the high pressure prevailing inside the plastic raw res.
- the tube wall comprises a second layer of a plastic, which is preferably arranged on the outside of the first layer, and the plastic of the second layer EVOH, Polyamide, in particular polyamide 12, polyethylene, in particular an LDPE or HDPE, or a compound from
- Polyethylene in particular an LDPE or a HDPE
- polyamide in particular polyamide 12
- the reinforcing structure comprises polyethylene and preferably the first layer and the second layer are connected via a bonding agent made of a plastic, which preferably comprises a thermoplastic, in particular anhydride-modified ethylene
- the first layer advantageously serves as a protective layer for the reinforcing structure embedded therein, in particular opposite production-related influences by the second layer described below.
- a plastic tube can be provided which has optimal properties in terms of the high-pressure medium passed through. If the first layer comprises EVOH or PA, in particular PA12, the first layer also forms a barrier layer.
- the second layer then preferably comprises PE, in particular HDPE, or PA12, in order to ensure the required mechanical properties, in particular high strength, with regard to the high pressure prevailing inside the plastic pipe.
- the mechanical properties of the plastic raw material are also improved by the PE-containing reinforcing structure.
- the first layer comprises EVOH
- the second layer can also comprise PA, in particular PA12, instead of PE, since this has a higher strength than PE. In this case, both layers would also serve as a barrier layer at the same time. Via the bonding agent, the first layer is molecularly and thus materially bonded to the second layer.
- the inner first layer is preferred as
- Barrier layer formed and the second layer of thermoplastic material provided on the outside of the first layer to weld a plurality of pipe sections together.
- the tube wall in addition to the second layer comprises a third layer, which is preferably arranged on the outside of the second layer, and the plastic of the third layer EVOH, polyamide, in particular polyamide 12, polyethylene, in particular an LDPE or a HDPE, or a compound of polyethylene, in particular an LDPE or a HDPE, and polyamide, in particular polyamide 12, and preferably the second layer and the third layer are connected via a bonding agent made of a plastic, preferably a thermoplastic, in particular hydride modified ethylene.
- the second layer preferably forms a barrier layer and comprises the abovementioned PA, in particular PA12, or EVOH material.
- the first and the third layer may each contain one of the above-mentioned plastics and in particular also the same plastic, but preferably one which deviates from the second layer. Due to the then different from layer to layer plastics and the second layer is connected to the third layer via the adhesion promoter. In this way, in principle, a barrier layer can be formed in each case by all, some or individual of the three layers.
- the reinforcing structure is preferably in the in Covered on the plastic tube innermost layer.
- a corresponding reinforced plastic high-pressure pipe can be produced in an advantageous manner in only one working cycle by simultaneously producing and reinforcing a layer of melt-shaped and thus meltable plastic of the pipe wall.
- the tubular reinforcing structure can be prepared in advance irrespective of the production of the plastic raw material and not only by wrapping during the production of two layers.
- the plastic of the first layer comprises EVOH, polyamide, in particular polyamide 12, polyethylene, in particular an LDPE or an HDPE, or a compound of polyethylene, in particular an LDPE or a HDPE, and polyamide, in particular polyamide 12 ,
- the plastics mentioned can be processed well.
- melt-shaped first layer and the reinforcing structure embedded therein are brought into a tubular shape by means of a shaping tool.
- the first layer is brought into the desired tube shape and dimension together with the prefabricated tubular reinforcing structure embedded in the first layer.
- the first layer is solidified.
- the solidification of the plastic of the first layer, in which the reinforcing structure is embedded, is therefore immediately associated with its reinforcement and is completed with the solidification.
- Reinforcement structure for example by wrapping with a reinforcing tape, can be provided and then by extruding a further layer of plastic, the reinforcing structure is fixed and protected.
- Plastic raw rs be arranged with arranged in a tube wall reinforcement structure in that the embedded in the layer reinforcing structure by the third step in the tube wall, in particular in the first layer, is fixed. Further method steps for embedding or fixing the reinforcing structure are therefore not required.
- a second layer of a melt-shaped plastic is applied and the plastic of the second layer EVOH, polyamide, in particular polyamide 12, polyethylene, in particular an LDPE or HDPE, or a compound of polyethylene, especially an LDPE or a HDPE, and polyamide, in particular polyamide 12, and preferably the reinforcing structure comprises polyethylene and preferably between the first layer and the second layer, a primer is introduced from a melt-shaped plastic, which is preferably a thermoplastic, in particular
- anhydride-modified ethylene for the reinforcing structure and resistant, but heat-sensitive material such as polyethylene may be used, since the first layer then serves as a protective layer, in particular as a heat protection layer, for the subsequently applied second layer, provided that the plastic of the first layer below the temperature critical for the reinforcing structure is plastifiable and after solidification damage to the
- melt-shaped plastic is applied and the plastic of the third layer comprises EVOH, polyamide, in particular polyamide 12, polyethylene, in particular an LDPE or a HDPE, or a compound of polyethylene, in particular an LDPE or HDPE, and polyamide, in particular polyamide 12, and preferably between the second layer and the third layer, a bonding agent is introduced from a melt-shaped plastic, which preferably comprises a thermoplastic, in particular anhydride-modified ethylene.
- a melt-shaped plastic which preferably comprises a thermoplastic, in particular anhydride-modified ethylene.
- Method is carried out in an extrusion process to which the tubular reinforcing structure is continuously supplied.
- An alternative economic implementation of the method can be carried out by performing the method in an injection molding process, to which the tubular reinforcing structure is fed as a separate tube in each cycle. As a result, in particular moldings can be produced particularly easily.
- Figure 1 is a perspective view of a plastic raw rs with a embedded in the pipe wall reinforcement structure in a first embodiment in partial section
- Figure 2 is an enlarged section of the partial section of the plastic pipe of Figure 1
- Figure 3 is a view of a cross section through the pipe wall of a plastic raw rs in a second embodiment
- Figure 4 is a view of a cross section through the tube wall of a plastic raw rs in a third embodiment.
- FIG. 1 shows a first embodiment of a reinforced plastic raw rs 1 in a perspective view with a partial section through the pipe wall 2.
- Plastic pipe 1 extends with a circular cross-section over a length L.
- the annular cross-section is formed by the pipe wall 2.
- the tube wall 2 is single-layered and thus comprises only a single layer 3 of a plastic, which consequently also has an annular cross-section. It is of course also possible to build the pipe wall 2 in a multi-layered manner, ie not just with a single first layer 3, by laying on an inner surface 3a or a
- a second layer 3e (see Figure 3), in addition a third layer 3f (see FIG. 4) or even more layers are applied.
- the plastic forming the layers 3, 3e and / or 3f of the tube wall 2 essentially comprises polymeric material, preferably thermoplastics and thermosetting plastics.
- Preferred thermoplastics are polyolefins, for example polyethylenes (PE), in particular HDPE (short form for "high density polyethylenes", in English: “high density polyethylene”) or LDPE (short form for "low density polyethylenes").
- Low density polyethylene polyamides, especially polyamide 12, or a
- Compound is referred to herein a mixture of unmixed polymeric base materials, in particular different thermoplastics.
- the layers 3, 3e, 3f is also a mixture of at least one polymeric base material with additional fillers, reinforcing agents or other additives in question.
- the plastic forming the layers 3, 3e, 3f may also comprise EVOH (abbreviation for "ethylene-vinyl alcohol copolymer") If one of the layers 3, 3e, 3f contains the aforementioned polyamide or EVOH material hereby
- Plastic raw rs 1 is compared to the production of a multilayer plastic raw rs with fewer process steps, preferably with only one process step, possible. According to the above definition of the term "layer" becomes the single-layer
- Pipe wall 2 formed by the fact that the first and possibly single layer 3 of the pipe wall 2 forming plastic material is brought in only one step to solidify.
- Inner diameter ID radially inwardly and the cylindrical outer surface 3b bounded with an outer diameter AD radially outward.
- the outer surface 3b extends concentrically around the inner surface 3a at a distance of a layer thickness s. Due to the single-layer structure of the tube wall 2, the inner surfaces 3b and the outer surface 3b of the layer 3 at the same time form a tube surface 2 radially bounding inner surface 2a with the inner diameter ID and an outer surface 2b with the outer diameter AD. Correspondingly, the tube wall 2 also has a layer thickness s corresponding Wall thickness w.
- the reinforcing structure 4 between the inner surface 3a and the outer surface 3b embedded in the first layer 3 of the tube wall 2 and enclosed by this annular cross-section layer 3.
- the reinforcing structure 4 is tubular and bounded by a lateral surface with a mean tube diameter SD.
- the tube diameter SD is larger than the inner diameter ID of the layer 3 and smaller than the outer diameter AD of the layer 3. Also has the
- the tubular reinforcing structure 4 may be flexible or rigid.
- the plastic of the first layer 3 of the pipe wall 2 which was previously plasticized to a melt, thus solidifies only after the reinforcing structure 4 has been introduced into the plasticized plastic their amplification, therefore, immediately with the solidification of the first
- an inner region 3c and an outer region 3d of the layer 3 are formed, wherein the inner region 3c forms the plastic between the inner side 4a of the reinforcing structure 4 and the
- the plastic between the outer side 4b of the reinforcing structure 4 and the outer surface 3b of the layer 3 comprises.
- the reinforcing structure 4 is connected to the inner region 3c facing the inner surface 3a with the inner region 3c and to the outer surface 3b facing outer surface 4b with the outer region 3d and firmly, resulting in a particularly stable embedding and connection of the reinforcing structure 4 with the first layer 3 of the tube wall 2 results.
- the reinforcing structure 4 is arranged between the inner and outer regions 3c, 3d, because of the co-solidification during manufacture and the existing over the reinforcing structure 4 surface compound form the inner and outer regions 3c, 3d, however, according to the underlying definition of the term "layer” not two layers, but only a single first layer 3, in which the reinforcing structure 4 is integrated or embedded.
- the inner region 3c and the outer region 3d together so form the only one of the tube wall 2 forming the first layer 3 made of plastic, which forms a tubular plastic matrix for the reinforcing structure 4 embedded therein Only on opposite end faces 1 a of the plastic pipe 1, the reinforcing structure 4 from the first layer 3 and the pipe wall 2 emerge.
- Reinforcement structure 4 shown enlarged. So that media such as gas, water or oil can be passed through the plastic pipe 1 at high pressure, the plastic pipe 1 must have a high compressive strength, which is achieved by a reinforcing structure 4 designed to be highly resilient for this purpose. In order to be able to absorb the axial and tangential forces which occur in this case in the tube wall 2, in particular in the direction of the length L and transversely thereto in the circumferential direction, the reinforcing structure 4 is in the
- the reinforcing structure 4 thus comprises at least two thread systems crossed at right angles or at right angles.
- the threads that run essentially in a straight line in the direction of the length L are referred to as warp or warp threads.
- the threads running substantially transversely thereto, but helically or with a constant tube diameter SD helically in the direction of the length L, are referred to as weft or weft threads.
- weft threads weft threads
- the design of the reinforcing structure 4 can be carried out, for example, by a finite element calculation, according to which the relationships with respect to the number of warp threads, weft threads and outer diameter AD of the tube wall 2 and the strength of the respective threads are determined.
- the fabric-like reinforcement structure 4 forms through the intersecting warp and weft threads meshes, which over the lateral surface of the tubular
- the meshes may be dimensioned such that openings 4c of the reinforcing structure 4 are formed therefrom, which for the plastic of the layer 3, during the production of the plastic raw rs 1 in plasticized form as Melt is present, permeable and can be flowed through by it.
- the plastic flows around the threads forming the openings 4c of the fabric, so that the reinforcing structure 4 and the first layer 3 of the pipe wall 2 penetrate each other via the openings 4c ,
- the inner region 3c and the outer region 3d are seamlessly interconnected by the openings 4c, whereby the layer 3 of the tube wall 2 at least partially, in particular in the region of the openings 4c, continuously and continuously between the inner surface 3a and the outer surface 3b extends.
- the reinforcing structure 4 is not formed like a fabric, no mesh or not sufficiently large for complete penetration and flow around and accordingly no openings 4c is formed and thus closed in the region of the lateral surface.
- the reinforcing structure 4 can thus be formed in the region of the lateral surface with respect to the plastic of the layer 3 as a permeable or non-permeable tube.
- Reinforcement structure 4 are connected to each other flat.
- fabric-like also includes, in particular, a network structure or a lattice structure as well as a punched-out structure
- Mantle surface which may for example be formed by a tubular film, provided that in each case the above-mentioned axial and tangential forces can be absorbed. Under this condition, the tubular film
- Reinforcement structure 4 also be made of a non-fabricated from a scrim, braid, knitted fabric, knitted fabric, woven, Nähgewirke, fleece or felt.
- the meshes or openings 4c can also be rhombic, square or hexagonal, for example.
- the stitches or openings 4c may be knotted or knotless.
- the reinforcing structure 4 can in principle be made of any textile or textile-processed fibers, in particular threads, yarns or threads be, for example, rubber fibers, metal fibers, natural fibers, fibers of natural and synthetic polymers, preferably polyethylene, in particular UHMWPE (short for "ultra-high-molecular-weight polyethylene", in German:
- the reinforcing structure 4 is not formed by a textile tube made of fibers with or without meshes or openings 4c, but instead
- the reinforcing structure 4 can basically be made of a film of the above-mentioned materials with or without openings 4c.
- the flat solid connection with the layer 3 is also produced if the reinforcing structure 4 is not permeable as described above.
- the positive connection With sufficiently large meshes, which form correspondingly permeable openings 4c of the reinforcing structure 4, the positive connection also takes place with the entire weft and warp threads of the fabric-like reinforcing structure 4 and not only with individual superficial fibers thereof.
- FIGS. 1 and 2 the course of the tubular reinforcing structure 4 within the annular cross-section of the first layer 3 of the tube wall 2 in the direction of the length L is shown on an end face 1a of the plastic raw material 1.
- the reinforcing structure 4 seen in the longitudinal direction with respect to a longitudinal axis of the plastic tube 1 has no constant radius and accordingly with its inner side 4a and 4b outside not parallel to the inner surfaces 3a and the outer surfaces 3b of the layer 3, but wavy varying distances between these runs.
- the varying distances result from the fact that the tubular reinforcing structure 4 in itself is not rigid and rigid, but flexible, in particular elastic or limp, is formed.
- the reinforcing structure 4 Since the reinforcing structure 4 is introduced during the production in the melt of plasticized plastic and in this until the solidification of the melt-shaped layer 3 is unstable or flexible with accordingly fluctuates variable distances to the inner surface 3a and outer surface 3b, the reinforcing structure 4 is only by the solidification of the
- the reinforcing structure 4 has a sufficient rigidity, it is also possible for the reinforcing structure 4 to have a constant radius over the entire length L of the plastic tube 1.
- the reinforcing structure 4 may extend in the form of a hollow cylinder within the tube wall 2 and, in particular, concentrically with respect to the tubular layer 3 or at least parallel to its inner surface 3a and outer surface 3b. Also, a non-parallel, oblique orientation of the reinforcing structure 4 within the layer
- the plastic pipe 1 can preferably be produced by means of an extrusion process or by means of an injection molding process. This is in each case in a first
- the plastic material of the layer 3 and the reinforcing structure 4 arranged in such a way around the reinforcing structure 4 and still plasticized are conveyed by means of a
- shaping tool having the desired annular cross section of the tube wall 2, brought into a corresponding tubular shape.
- the layer 3 is then selectively cooled and solidified, whereby the reinforcing structure 4 within the layer 3 of Pipe wall 2 fixed and thus becomes an integral part.
- the reinforcing structure 4 is provided in the form of a tube and continuously drawn during the first process step of the extrusion process in the manner of an endless tube and fed to the extrusion process or the melt. A required for the above-described construction distribution of the layer 3 forming melt to the
- melt feed in the form of an extruder is provided and the melt distributed by the formed in the reinforcing structure 4 openings 4c accordingly.
- the tubular reinforcing structure 4 can be clamped with an end face into a ring (not shown) corresponding to the desired tube geometry, which then serves for threading the reinforcing structure 4 into the tool and then from the subsequent melt through the Tool is pressed. It is also conceivable that an annular lock is provided, via which the reinforcing structure 4 is fed to the melt and drawn into it.
- the reinforcing structure 4 is inserted and positioned as a separate tube section in the tube forming forming tool in each cycle and overmoulded on both the inside 4a and outside 4b with melt of the plastic around the inner and outer areas 3c, 3d Form the layer 3 of the pipe wall 2. Since the encapsulation and thus the embedding of the reinforcing structure 4 in the layer 3 takes place within the tool, superimpose the first and the second process step at least partially. Subsequently, in the third method step, the corresponding arrangement of the melt-shaped layer 3 and the reinforcing structure 4 embedded therein in the tool is solidified by cooling. As previously described with regard to the extrusion process, only one injection unit can be provided as a melt supply and the melt can flow through the openings 4c on both the inside 4a and the melt
- a plurality of appropriately arranged injection units can be provided to cause a complete immersion or encapsulation of the reinforcing structure 4 and to form the inner region 3c and the outer region 3d of the layer 3.
- plastic pipes 1 with short lengths L of approximately 0.5 m so-called fittings
- Other, in particular tube-like, plastic parts can be produced by means of the described injection molding process as so-called fittings.
- melt-floating reinforcing structure 4 may additionally be added prior to the solidification of the melt be positioned and aligned in the tool, for example by applying a tensile force in the direction of the length L of the plastic pipe.
- FIG 3 is a view of a cross section through the pipe wall 2 of a
- the plastic raw r 1 or its tube wall 2 preferably comprises, in addition to the inner first layer 3, an outer second layer 3 e.
- the plastic of the first layer 3 contains essentially EVOH or preferably polyamide, in particular polyamide 12, or a compound of polyethylene, in particular an LDPE or a HDPE, and polyamide, in particular polyamide 12.
- the plastic of the second layer 3e is preferably made of polyethylene, in particular HDPE, manufactured.
- the second layer 3e may also contain one of the other aforementioned plastics, provided that it does not already form the first layer 3.
- the first layer 3 may be formed of polyethylene.
- a suitable adhesion promoter 5 for the two layers 3, 3e is introduced between the first layer 3 and the second layer 3e, via which the two layers 3 and 3e are molecularly and materially bonded be connected to each other.
- the adhesion promoter 5 used is, for example, a thermoplastic extruded onto the first layer 3, in particular anhydride-modified ethylene.
- the two layers 3, 3e are each made of similar plastic such as polyethylene, so that no bonding agent 5 for connecting the two layers 3, 3e is required.
- the plastic of the first layer 3 below that for the
- Reinforcement structure 4 critical temperature be plasticized and the first layer 3 must have a layer thickness s, which prevents after solidification damage to the reinforcing structure 4 by higher temperatures of the melt-applied second layer 3e.
- the first layer 3 may be a polyethylene, in particular LDPE, with a glass transition temperature
- the first layer 3 is the made of polyethylene, preferably UHMWPE, fibers or yarn and formed as a tubular fabric reinforcing structure 4 embedded.
- the reinforcing structure 4 made of UHMWPE has a
- the plastic contains substantially a HDPE and connects to the first layer 3 cohesively.
- the melting point or glass transition temperature of the HDPE is about 135 degrees Celsius. However, since the melted HDPE is above the melting point
- the first layer 3 serves not only the fixation of the reinforcing structure 4, but in particular as a heat-insulating layer, which prevents the polyethylene of the
- Reinforcing structure 4 is heated by the HDPE melt to the critical temperature range to be avoided.
- the reinforcing structure 4 may also be made of UHMWPE if the first layer 3 is made of another of the above Plastics is made.
- FIG. 4 shows a view of a cross section through the tube wall 2 of a plastic raw rs 1 shown in a three-layered third embodiment.
- the pipe wall 2
- each of the three layers 3, 3e and 3f may therefore be made of any of the plastics mentioned, wherein preferably each layer 3, 3e, 3f contains a different plastic or at least the central second layer 3e contains a different plastic than the inner first layer 3 and the outer third layer 3f.
- At least one of the three layers 3, 3e, 3f, particularly preferably the outer third layer 3f comprises polyethylene, in particular HDPE, or polyamide, in particular polyamide 12, in order to ensure the required strength of the plastic pipe 1 formed as a high-pressure pipe.
- all three, two or one of the layers 3, 3e and 3f can serve as barrier layers by appropriate choice of material.
- melt-processable HDPE plastic are produced when the
- the plastic of the first layer 3 must therefore in each case be below the critical temperature for the reinforcing structure 4 to a processable Melt be plasticized.
- the critical temperature is controlled by cooling the first layer 3. If the layers 3, 3e and / or 3f of the tube wall 2 and the reinforcing structure 4 may consist of the same materials Plastic raw r 1 also be recycled in a simple manner.
- the methods described above are only to supplement the fourth and optionally fifth method step, in which applied to the first layer 3 with the reinforcing structure 4 of the adhesion promoter 5 and then the second layer 3e, preferably extruded.
- the first layer 3 is superficially melted on the inner surface 3a or the outer surface 3b, so that in this area the bonding agent 5 can mix with the melts of the first and second layers 3 and 3e and a molecular, cohesive connection of the two layers 3 and 3e is produced.
- the bonding agent 5 can be dispensed with the bonding agent 5 also. It is also conceivable to apply the third layer 3f inside on the first layer 3 or subsequently the
- Diffusion resistance of the inner first layer 3 to improve, for example by applying a so-called nano-coating.
- Reinforcing structure 4 is reinforced, is preferably used as a high-strength high-pressure pipe for the passage or transport of oil, gas and water.
- the plastic tube 1 in terms of its dimensions to the respective
- the plastic pipe 1 can be designed for pressures up to 60 bar and the pipe wall 2 have an outer diameter AD of up to 800 mm.
- thermoplastic layer 3, 3e or 3f is specified by said DIN. If a second layer 3e and / or a third layer 3f is provided, the wall thickness w increases and the inner diameter ID of the tube wall 2 decreases
- the barrier layer which in the case of a multilayer pipe wall 2
- the first layer 3 is preferably formed by the first layer 3, has a layer thickness s of about 4 mm.
- An optionally provided adhesion promoter 5 is introduced in each case with a thickness of 0.5 mm between the layers 3, 3e and / or 3f, whereby the
- the structure described for the plastic raw r 1 with an embedded in the first layer 3 reinforcing structure 4 is of course transferable to any other, in particular rotationally symmetrical, plastic body by means of a method according to the invention, in particular extrusion process or
- annular cross-section of such a plastic body or plastic tube 1 also oval or angular
- the barrier layers instead of EVOH or polyamide rubber, in particular synthetic rubber such as NBR (short for "nitrile butadiene rubber”, “nitrile-butadiene rubber”), EPDM (short form for "ethylene propylene diene monomer ", in German:” ethylene-propylene-diene monomer rubber "), SBR (short for” styrene butadiene rubber ", in German” styrene-butadiene rubber ”) or a compound with these rubbers or a selection of these Include rubbers.
- NBR nonitrile butadiene rubber
- EPDM short form for "ethylene propylene diene monomer ", in German:” ethylene-propylene-diene monomer rubber "
- SBR short for" styrene butadiene rubber ", in German” styrene-butadiene rubber ”
- a compound with these rubbers or a selection of these Include rubbers or a selection of these Include rubbers.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/101,651 US20160305578A1 (en) | 2013-12-06 | 2014-12-02 | Plastic pipe and production method therefor |
JP2016536647A JP2017506723A (ja) | 2013-12-06 | 2014-12-02 | 合成材料管およびその製造方法 |
CA2969866A CA2969866A1 (en) | 2013-12-06 | 2014-12-02 | Synthetic material pipe and production method therefor |
CN201480075061.2A CN106068179A (zh) | 2013-12-06 | 2014-12-02 | 合成材料管道和用于该合成材料管道的生产方法 |
EP14806257.3A EP3077196A1 (de) | 2013-12-06 | 2014-12-02 | Kunststoffrohr und herstellverfahren hierfür |
RU2016126536A RU2650139C1 (ru) | 2013-12-06 | 2014-12-02 | Труба из синтетического материала и способ её изготовления |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013113664.8 | 2013-12-06 | ||
DE102013113664.8A DE102013113664A1 (de) | 2013-12-06 | 2013-12-06 | Kunststoffrohr und Herstellverfahren hierfür |
DE102014105338.9 | 2014-04-15 | ||
DE102014105338 | 2014-04-15 |
Publications (1)
Publication Number | Publication Date |
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WO2015082491A1 true WO2015082491A1 (de) | 2015-06-11 |
Family
ID=52003773
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2014/076295 WO2015082491A1 (de) | 2013-12-06 | 2014-12-02 | Kunststoffrohr und herstellverfahren hierfür |
Country Status (7)
Country | Link |
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US (1) | US20160305578A1 (de) |
EP (1) | EP3077196A1 (de) |
JP (1) | JP2017506723A (de) |
CN (1) | CN106068179A (de) |
CA (1) | CA2969866A1 (de) |
RU (1) | RU2650139C1 (de) |
WO (1) | WO2015082491A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017217544A1 (de) * | 2017-10-02 | 2019-04-04 | Bänninger Kunststoff-Produkte GmbH | Rohrleitung und Verfahren zur Herstellung |
DE102019105266A1 (de) * | 2019-03-01 | 2020-09-03 | Naturspeicher Gmbh | Hochdruckrohr |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102514750B1 (ko) * | 2015-10-26 | 2023-03-27 | 도요보 가부시키가이샤 | 접착제 조성물 및 핫멜트 접착제 |
CN112963632A (zh) * | 2021-03-11 | 2021-06-15 | 四川泰鑫实业发展有限责任公司 | 一种柔性复合管及其生产方法和生产装置 |
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DE1813312U (de) | 1960-03-09 | 1960-06-15 | Hermann Berstorff Maschb Ansta | Vorrichtung zur herstellung von kunststoffrohren mit drahteinlagen. |
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DE4214383C2 (de) * | 1992-04-30 | 1996-08-14 | Inventa Ag | Koextrudiertes Mehrschicht-Polymer-Rohr |
JPH08224846A (ja) * | 1994-12-19 | 1996-09-03 | Toppan Printing Co Ltd | 積層体 |
US6455115B1 (en) * | 2001-01-26 | 2002-09-24 | Milliken & Company | Textile reinforced thermoplastic or thermoset pipes |
CZ293343B6 (cs) * | 2001-03-29 | 2004-04-14 | Tomáš Novotný | Vícevrstvá trubka z polyolefinů |
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CN101600566B (zh) * | 2006-11-29 | 2012-11-14 | 3M创新有限公司 | 包含微球的绝缘材料 |
GB2452685A (en) * | 2007-09-12 | 2009-03-18 | Netafim Ltd | Cross-laminate film for irrigation pipe |
JP5247537B2 (ja) * | 2008-11-05 | 2013-07-24 | 横浜ゴム株式会社 | 熱可塑性樹脂組成物、それを用いた積層体およびタイヤ |
CN101644359B (zh) * | 2009-09-18 | 2011-05-04 | 谢志树 | 自体法兰式钢网增强塑料压力管及其制造方法 |
-
2014
- 2014-12-02 EP EP14806257.3A patent/EP3077196A1/de active Pending
- 2014-12-02 US US15/101,651 patent/US20160305578A1/en not_active Abandoned
- 2014-12-02 JP JP2016536647A patent/JP2017506723A/ja active Pending
- 2014-12-02 RU RU2016126536A patent/RU2650139C1/ru not_active IP Right Cessation
- 2014-12-02 CA CA2969866A patent/CA2969866A1/en not_active Abandoned
- 2014-12-02 CN CN201480075061.2A patent/CN106068179A/zh active Pending
- 2014-12-02 WO PCT/EP2014/076295 patent/WO2015082491A1/de active Application Filing
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DE1813312U (de) | 1960-03-09 | 1960-06-15 | Hermann Berstorff Maschb Ansta | Vorrichtung zur herstellung von kunststoffrohren mit drahteinlagen. |
DE60121579T2 (de) | 2001-08-23 | 2007-06-21 | Milliken Europe N.V. | Garne und Textilstoffe zur Verstärkung von Schläuchen und Rohren |
DE20219222U1 (de) | 2002-12-12 | 2003-03-13 | Egeplast Werner Strumann GmbH & Co. KG, 48268 Greven | Rohr aus Polyolefinen mit Verstärkungseinlage |
WO2008132120A1 (de) * | 2007-04-27 | 2008-11-06 | The Thomas Machines S.A. | Verfahren zur herstellung eines metallverstärkten kunststoff-verbundrohrs und metallverstärktes kunststoff-verbundrohr |
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DE102017217544A1 (de) * | 2017-10-02 | 2019-04-04 | Bänninger Kunststoff-Produkte GmbH | Rohrleitung und Verfahren zur Herstellung |
DE102019105266A1 (de) * | 2019-03-01 | 2020-09-03 | Naturspeicher Gmbh | Hochdruckrohr |
Also Published As
Publication number | Publication date |
---|---|
US20160305578A1 (en) | 2016-10-20 |
RU2650139C1 (ru) | 2018-04-09 |
CN106068179A (zh) | 2016-11-02 |
JP2017506723A (ja) | 2017-03-09 |
CA2969866A1 (en) | 2015-06-11 |
EP3077196A1 (de) | 2016-10-12 |
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