WO2015020439A1 - 게르마늄 이온수 제조방법 및 게르마늄 이온수를 이용한 농작물 재배방법 - Google Patents
게르마늄 이온수 제조방법 및 게르마늄 이온수를 이용한 농작물 재배방법 Download PDFInfo
- Publication number
- WO2015020439A1 WO2015020439A1 PCT/KR2014/007293 KR2014007293W WO2015020439A1 WO 2015020439 A1 WO2015020439 A1 WO 2015020439A1 KR 2014007293 W KR2014007293 W KR 2014007293W WO 2015020439 A1 WO2015020439 A1 WO 2015020439A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- germanium
- water
- dioxide
- thorium
- reaction vessel
- Prior art date
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Definitions
- the present invention relates to a method for producing germanium ionized water and a method for cultivating crops using germanium ionized water, and more particularly, to a method for producing ionized water by ionizing germanium using ionization of radiation and a method for growing crops using the same.
- Germanium is present in various forms of organic and inorganic substances in stones, soil, plants and animals. About 7 ppm in the earth's crust, 0.6-1.3 mg Ge / kg in soil and 0.004-0.6 mg Ge / L in water, are trace elements.
- Germanium compounds are roughly classified into inorganic germanium compounds and organic germanium compounds. Generally, salts or oxides lacking the germanium-carbon bond are classified as inorganic germanium.
- organic germanium has a germanium-carbon bond, which is a stable group because germanium is a carbon-like group 14, and bonds are not easily broken in vivo. none.
- Organic germanium compounds have anticancer effects and immunomodulatory functions. As a result, they have become known as immunopotentiators with anticancer effects that can prevent the progression of cancer and AIDS and kill cancer cells.
- Organic germanium compounds were first synthesized variously by Mironov of Russia for the first time in the 1950s, and bis (2-carboxyethylgermanium) sesquioxide (O 3 (GeCH 2 CH 2 COOH) 2 ) was synthesized in 1966. Shortly thereafter, in 1967, the same bis (2-carboxyethylgermanium) sesquioxide, (O 3 (GeCH 2 CH 2 COOH) 2 ), was synthesized at the Asai Germanium Research Institute in Tokyo, Japan.
- Ge-132 It was named 132. The chemical structure and physicochemical properties of this Ge-132 compound have already been reported. Since then, a number of studies have been conducted on Ge-132, which has shown that Ge-132 has immunopotentiating efficacy, including interferon induction, increased NK cell activity, production of cytotoxic macrophages, and anticancer efficacy. Have been shown to exhibit a variety of biological efficacy.
- Patent Publication No. 10-2004-0052744 is a method of cultivating a watermelon containing inorganic germanium as a fertilizer, and cultivating watermelon containing organic germanium, the equivalent of 99.999% purity or more of germanium dioxide (GeO 2 ) in water to the concentration It is disclosed that a method of cultivating watermelon by calculating the amount of the inorganic germanium ionized in a hydroponic nutrient fertilizer for fertilization for hydroponic cultivation by heating it into a stainless steel bucket and then heating it.
- Patent Publication No. 10-2004-0028296 discloses a method for preparing germanium functional water by dissolving selenium or germanium using an ionizing solvent, adjusting pH, and filtering impurities to prepare a purified stock solution.
- Korean Utility Model Registration No. 20-0340536 discloses a method of ionizing and dissolving germanium and a catalyst by using an ultrasonic system to ionize and dissolve it, and raising the temperature of water to activate collision, ions, and dissolution.
- germanium or germanium dioxide is dispersed in water to prepare a germanium aqueous solution, in which germanium is difficult to be sufficiently dissolved in water, and there is a hassle to separate the germanium component not dissolved in the solution by a filter separately.
- the present invention has been made to solve the above problems, and an object of the present invention is to provide a method for efficiently producing germanium ion water at a lower cost utilizing the ionizing effect of the radiation of thorium.
- Germanium ionized water production method to achieve the above object is a process for preparing a radiation emitting solution by adding thorium dioxide (ThO 2 ) or thorium ore powder in water, germanium dioxide (GeO 2) in the reaction vessel ) Mixing the powder with water, immersing the reaction vessel so as to be submerged in the radiation emitting solution, and heating the radiation emitting solution.
- ThO 2 thorium dioxide
- GeO 2 germanium dioxide
- the process of preparing the radiation emitting solution may be to inject the thorium dioxide (ThO 2 ) or thorium ore powder to a height of 5 ⁇ 10 cm in a water tank, and to add water to a height that can be immersed in the reaction vessel.
- ThO 2 thorium dioxide
- thorium ore powder may be to inject the thorium dioxide (ThO 2 ) or thorium ore powder to a height of 5 ⁇ 10 cm in a water tank, and to add water to a height that can be immersed in the reaction vessel.
- the deposition process may be to inject 0.5 ⁇ 1.5g per 1L of germanium dioxide into the reaction vessel.
- the method may further include diluting by further adding water to the prepared germanium ionized water after the heating process.
- the heating temperature may be 50 to 70 ° C., and the heating time may be 3 to 6 hours.
- germanium ionized water may include germanium ions ionized by ionizing by radiation, and the concentration of germanium ions may be 120 ppm or less.
- a method for growing crops using germanium ionized water includes a germanium ion ionized by ionizing by radiation, the concentration of the germanium ion is 120 ppm or less soil in which the crop is planted germanium ionized water Or it is sprayed on the foliar of the crop, it is characterized by cultivating the crop by putting in hydroponic cultivation.
- germanium ionized water using a smaller amount of germanium dioxide than the conventional, it is possible to produce germanium ionized water cheaper and simpler.
- the germanium ionized water thus prepared has an anion-releasing effect and can be used as a role for various anion-releasing materials.
- FIG. 1 is a view schematically showing a germanium ionized water production apparatus according to an embodiment of the present invention.
- the method for preparing germanium ionized water is a process of preparing a radiation emitting solution by dispersing thorium dioxide (ThO 2 ) or thorium ore powder in water and dispersing the germanium dioxide (GeO 2 ) powder in a reaction vessel. Mixing the mixture, depositing the reaction vessel so as to be immersed in the radiation emitting solution, and heating the radiation emitting solution.
- ThO 2 thorium dioxide
- GeO 2 germanium dioxide
- thorium dioxide (ThO 2 ) or thorium light powder are introduced into a large water tank 10 to prepare a radiation emitting solution.
- Thorium (Th) is a natural radiation substance, and the electromagnetic wave emitted from thorium collides with the electrons of germanium, and is a component that directly or indirectly ionizes germanium by ionization.
- the thorium dioxide (ThO 2 ) or thorium light is laid low because the specific gravity is large, the height is preferably 5 ⁇ 10 cm so that the reaction vessel is sufficiently submerged.
- the germanium dioxide (GeO 2 ) powder is mixed with water in the reaction vessel 20, and the reaction vessel 20 is immersed to be immersed in the radiation emitting solution 40 in the water tank 10.
- the reaction vessel 20 used may be a PET bottle of 1L or 2L capacity
- the amount of germanium dioxide is preferably added according to the equivalence ratio according to the concentration of germanium ionized water. In this embodiment, it is preferable to inject 0.5 to 1.5 g of germanium dioxide.
- the reaction vessel 20 into which germanium dioxide and water are added is positioned to be immersed in the radiation emitting solution 40 in the water tank 10.
- the reaction vessel 20 is weakly exposed to the thorium dioxide (ThO 2 ) powder 30 or the thorium light powder. Allow 5 to 6 cm to lock. It is preferable to adjust the amount of water in the water tank 10 so that the reaction vessel 20 does not float in the water in the water tank 10.
- the heater 50 is placed through the abutment 40 in the center of the water tank 10 to heat the radiation emitting solution 30 in the water tank 10. Hold for about 3-6 hours at a temperature of about 50 ⁇ 70 °C.
- germanium dioxide which is a white powder
- germanium dioxide becomes ionized and becomes transparent. Even if the ionized reaction vessel is left in a plastic house for a long time, green algae do not occur.
- the germanium component of the germanium dioxide component is ionized, and the oxygen component is released during the ionization process.
- oxygen dissolved in part of the ionized water is continuously released and green algae are not generated, and ionization and sterilization of germanium by ionization are simultaneously performed in the reaction vessel by radiation generated from thorium.
- the concentration of germanium ions in the germanium ionized water is determined by the amount of germanium dioxide introduced, and when about 1g of germanium is added to 1L of water, it is possible to prepare about 694.1 ppm of germanium ionized water. It is possible to adjust the concentration of germanium ions by adding more water according to the use of germanium ionized water, and to prepare about 6.9 ppm of germanium ionized water by diluting by adding about 100 times the amount of water to the standard amount of water. . Therefore, when the expensive germanium dioxide is prepared according to the embodiment of the present invention, it is possible to lower the production cost up to 1/20 as compared with the production of the conventional germanium solution.
- germanium ionized water according to an embodiment of the present invention has an anion-releasing effect, not only can generate anion by spraying the interior of the building, but also produced by mixing the raw material, such as various interior, exterior materials, paints, etc. Can be used.
- the germanium ionized water according to an embodiment of the present invention is preferably adjusted to various concentrations according to the characteristics of the crop when utilized in crop cultivation. More preferably, the concentration may be 120 ppm or less. When the concentration of the germanium ion water exceeds 120 ppm, the germanium is a semiconductor as the number of electrons of the germanium is excessively sprayed, so that crops having a relatively low potential become difficult to absorb a high potential germanium component.
- the ionized water released from the germanium ionized water was measured using a charged particle measuring device under conditions of 27 ° C, 34% humidity, and 106 / cc of anion water in the air. Indicated.
- Test result KFIM-276 Test method KFIA-FI-1042 Sample name Anion (ION / cc) Germanium ionized water 136
- germanium ionized water according to the present invention is prepared by ionizing a small amount of germanium dioxide absorption rate for the target crop
- germanium ionized water can be drastically reduced, which makes it possible to grow germanium crops at a lower cost.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Forests & Forestry (AREA)
- Ecology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Environmental Sciences (AREA)
- Botany (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Hydroponics (AREA)
- Physical Water Treatments (AREA)
Abstract
Description
시험결과한국원적외선 협회 시험성적서 발급번호 KFIM-276시험방법 KFIA-FI-1042 | |
시료명 | 음이온(ION/cc) |
게르마늄 이온수 | 136 |
구분 | 대상작물 | 게르마늄 이온수의 농도 (ppm) | 주입량(cc) | 게르마늄흡수량(ppm) |
실험예1 | 무싹(2g) | 60 | 200 | 202 |
실험예2 | 무싹(2g) | 10 | 200 | 53 |
실험예3 | 보리싹(2g) | 60 | 200 | 157 |
실험예4 | 보리싹(2g) | 10 | 200 | 34 |
실험예 5 | 콩나물(5g) | 100 | 200 | 19 |
Claims (5)
- 이산화토륨(ThO2) 또는 토륨광 분말을 물에 투입하여 방사선 방출 용액을 제조하는 과정;반응용기에 이산화게르마늄(GeO2) 분말을 물을 혼합하고, 상기 반응용기를 상기 방사선 방출 용액에 잠길 수 있도록 침적시키는 과정 및상기 방사선 방출 용액을 가열하는 과정을 포함하며,상기 방사선 방출 용액을 제조하는 과정은 수조 안에 5~10 cm 높이로 상기 이산화토륨(ThO2) 또는 토륨광 분말을 투입하고, 상기 반응용기가 잠길 수 있는 높이까지 물을 투입하며,상기 침적과정은 상기 반응용기에 상기 이산화게르마늄을 물 1L당 0.5~1.5g을 투입하는 것을 특징으로 하는 게르마늄 이온수 제조방법.
- 청구항 1에 있어서,상기 가열과정 후에 제조된 게르마늄 이온수에 물을 더 첨가하여 희석시키는 과정을 더 포함하는 게르마늄 이온수 제조방법.
- 청구항 1에 있어서,상기 가열과정에서 가열온도는 50~70℃, 가열시간은 3~6시간 인 것을 특징으로 하는 게르마늄 이온수 제조방법.
- 청구항 1의 방법으로 제조되어 이온화된 게르마늄 이온을 포함하고,상기 게르마늄 이온의 농도는 120ppm이하인 것을 특징으로 하는 게르마늄 이온수.
- 청구항 6의 게르마늄 이온수를 활용하여 농작물을 재배하는 방법으로서,상기 게르마늄 이온수를 농작물이 식재되어 있는 토양 또는 농작물의 엽면에 살포하거나, 수경재배액에 투입하여 농작물을 재배하는 것을 특징으로 하는 게르마늄 이온수를 이용한 농작물 재배방법.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201480043677.1A CN105578869A (zh) | 2013-08-06 | 2014-08-06 | 锗离子水生产方法以及用锗离子水培育农作物的方法 |
JP2016533242A JP6163608B2 (ja) | 2013-08-06 | 2014-08-06 | ゲルマニウムイオン水の製造方法及びゲルマニウムイオン水を用いた農作物の栽培方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020130092894A KR101456538B1 (ko) | 2013-08-06 | 2013-08-06 | 게르마늄 이온수 제조방법 및 게르마늄 이온수를 이용한 농작물 재배방법 |
KR10-2013-0092894 | 2013-08-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015020439A1 true WO2015020439A1 (ko) | 2015-02-12 |
Family
ID=51999024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2014/007293 WO2015020439A1 (ko) | 2013-08-06 | 2014-08-06 | 게르마늄 이온수 제조방법 및 게르마늄 이온수를 이용한 농작물 재배방법 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP6163608B2 (ko) |
KR (1) | KR101456538B1 (ko) |
CN (1) | CN105578869A (ko) |
WO (1) | WO2015020439A1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111873121A (zh) * | 2020-07-14 | 2020-11-03 | 安徽葵普科技有限公司 | 一种磁性木材处理工艺 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101820746B1 (ko) | 2016-11-28 | 2018-01-24 | (주)한일시티코리아 | 건강 베개 제조방법 |
KR101968445B1 (ko) | 2018-10-10 | 2019-04-11 | 이창한 | 유기 게르마늄이 함유된 누룩균 조성물의 제조방법과 그 제조방법에 의해 제조된 누룩균 조성물 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0558628A (ja) * | 1991-09-06 | 1993-03-09 | Nippon Create:Kk | ゲルマニウム水溶液の製造方法 |
KR20050052044A (ko) * | 2003-11-28 | 2005-06-02 | 박만조 | ˝환경농업 활성액비 및 그 제조방법˝ |
KR20050052043A (ko) * | 2003-11-28 | 2005-06-02 | 박만조 | ˝환경농업 활성비료 제조방법˝ |
KR20060026104A (ko) * | 2006-03-02 | 2006-03-22 | 박만조 | 토륨광을 주성분으로 한 게르마늄 합성파우더 조성 방법과이를 이용한 농작물 재배방법 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61145108A (ja) * | 1984-12-19 | 1986-07-02 | Norio Someya | 飲料水等の防腐剤 |
KR20040052744A (ko) * | 2004-04-30 | 2004-06-23 | 김현채 | 게르마늄이 함유된 수박의 재배방법 |
KR20050027237A (ko) * | 2005-02-14 | 2005-03-18 | 김현채 | 셀레늄과 게르마늄이 함유된 허브의 재배방법 |
KR20060131533A (ko) * | 2005-06-16 | 2006-12-20 | 삼성전자주식회사 | 유기박막 트랜지스터 및 그 제조방법 |
CN100500623C (zh) * | 2006-12-31 | 2009-06-17 | 沈阳农业大学 | 一种人参富锗专用肥料及其制法 |
JP2008231390A (ja) * | 2007-03-19 | 2008-10-02 | Makoto Sakai | ゲルマニウムとトリウムとペグマタイトによる機能性組成物。 |
CN102068019B (zh) * | 2010-11-23 | 2012-11-14 | 上海心动科技有限公司 | 多种离子养生液、其制备方法及其用途 |
-
2013
- 2013-08-06 KR KR1020130092894A patent/KR101456538B1/ko active IP Right Grant
-
2014
- 2014-08-06 WO PCT/KR2014/007293 patent/WO2015020439A1/ko active Application Filing
- 2014-08-06 JP JP2016533242A patent/JP6163608B2/ja not_active Expired - Fee Related
- 2014-08-06 CN CN201480043677.1A patent/CN105578869A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0558628A (ja) * | 1991-09-06 | 1993-03-09 | Nippon Create:Kk | ゲルマニウム水溶液の製造方法 |
KR20050052044A (ko) * | 2003-11-28 | 2005-06-02 | 박만조 | ˝환경농업 활성액비 및 그 제조방법˝ |
KR20050052043A (ko) * | 2003-11-28 | 2005-06-02 | 박만조 | ˝환경농업 활성비료 제조방법˝ |
KR20060026104A (ko) * | 2006-03-02 | 2006-03-22 | 박만조 | 토륨광을 주성분으로 한 게르마늄 합성파우더 조성 방법과이를 이용한 농작물 재배방법 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111873121A (zh) * | 2020-07-14 | 2020-11-03 | 安徽葵普科技有限公司 | 一种磁性木材处理工艺 |
Also Published As
Publication number | Publication date |
---|---|
JP6163608B2 (ja) | 2017-07-12 |
CN105578869A (zh) | 2016-05-11 |
JP2016532550A (ja) | 2016-10-20 |
KR101456538B1 (ko) | 2014-10-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102351613B (zh) | 用于滨海盐土抑盐与灭杀地下害虫的有机肥及其制备方法 | |
CN104926724B (zh) | 一种含萘二甲酰胺双季铵盐型植物生长调节剂 | |
CN103609561B (zh) | 一种稻瘟病的防治药剂 | |
WO2015020439A1 (ko) | 게르마늄 이온수 제조방법 및 게르마늄 이온수를 이용한 농작물 재배방법 | |
KR100553289B1 (ko) | 식물 성장 조절 조성물 | |
CN105851002B (zh) | 一种水稻重金属吸收阻隔剂及其使用方法 | |
CN104938428A (zh) | 一种池塘网箱养殖水蛭技术方法 | |
CN105409557B (zh) | 以亚磷酸盐作为激发子诱导辣椒系统抗病性的方法 | |
CN103524417B (zh) | 一组3-甲基-4-甲酰吡唑化合物 | |
CN102408497B (zh) | 一种载药纳米胶束溶液及其制备方法与应用 | |
CN101955494A (zh) | 用作放射性药物和抗生素的n-杂环卡宾的金属配合物 | |
CN1994083B (zh) | 一种复配杀菌剂 | |
CN103524418A (zh) | 一组3-甲基吡唑化合物 | |
CN111771905B (zh) | 一种固态过氧化氢及其制备方法和应用 | |
CN103554026B (zh) | 一组3-三氟甲基-4-甲酰吡唑化合物 | |
CN103571769A (zh) | 一种寡养单胞菌及其在降解啶虫脒中的应用 | |
CN103271080B (zh) | 一种磷酸酯盐植物生长调节剂及其应用 | |
CN102702297B (zh) | 胆酸-萘酰亚胺类化合物的制备方法 | |
CN1371607A (zh) | 一种抗稻瘟病的药物,其制备方法及其应用 | |
CN108566955A (zh) | 一种防治蚜虫的沼液组合物及其应用 | |
CN109762015A (zh) | 一种阿维菌素B2a磷酸化修饰物及其制备方法和应用 | |
WO2021154001A4 (ko) | 나노유기게르마늄 및 나노유기셀레늄을 이용한 기능성 작물의 재배방법 | |
CN113349210B (zh) | 一种天然生物除草剂及其制备方法 | |
RU2463758C2 (ru) | Способ повышения экологической безопасности семенного урожая в техногенно загрязненных агроценозах | |
RU2764468C1 (ru) | Жидкое комплексное удобрение |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 201480043677.1 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14833668 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2016533242 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 14833668 Country of ref document: EP Kind code of ref document: A1 |