WO2015002620A1 - Vernis à ongles (émail) possédant une toxicité diminuée, une résistance aux uv accrue et qui brille de lui même dans un environnement sans éclairage - Google Patents

Vernis à ongles (émail) possédant une toxicité diminuée, une résistance aux uv accrue et qui brille de lui même dans un environnement sans éclairage Download PDF

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Publication number
WO2015002620A1
WO2015002620A1 PCT/TR2014/000132 TR2014000132W WO2015002620A1 WO 2015002620 A1 WO2015002620 A1 WO 2015002620A1 TR 2014000132 W TR2014000132 W TR 2014000132W WO 2015002620 A1 WO2015002620 A1 WO 2015002620A1
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WO
WIPO (PCT)
Prior art keywords
nail polish
resistance
shining
self
enamel
Prior art date
Application number
PCT/TR2014/000132
Other languages
English (en)
Inventor
Hasan TATAR
Original Assignee
Eysi̇m İthalat İhracat Gida Tarim Ki̇myevi̇ Maddeler Otomoti̇v Taşimacilik Petrol Sanayi̇ Ve Ti̇caret Li̇mi̇ted Şi̇rketi̇
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eysi̇m İthalat İhracat Gida Tarim Ki̇myevi̇ Maddeler Otomoti̇v Taşimacilik Petrol Sanayi̇ Ve Ti̇caret Li̇mi̇ted Şi̇rketi̇ filed Critical Eysi̇m İthalat İhracat Gida Tarim Ki̇myevi̇ Maddeler Otomoti̇v Taşimacilik Petrol Sanayi̇ Ve Ti̇caret Li̇mi̇ted Şi̇rketi̇
Publication of WO2015002620A1 publication Critical patent/WO2015002620A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/58—Metal complex; Coordination compounds

Definitions

  • the present invention is related to nail polish (enamel) that is used in the field of cosmetic industry, has decreased toxicity, increased UV resistance and is self-shining in unlighted environment, and the production method thereof.
  • the current nail polishes have been determined as toxic substances that are extremely dangerous for human health by some organizations such as FDA and European Health Organization; they are produced from chemical substances such as formaldehyde, toluene and dibutyl phthalate (DBP) and thus, the health of consumers is inexcellent under serious threat.
  • Another application in the state of art is that the nail polishes are applied on hand and toe nails of people in various colors and patterns.
  • the nail polish which is applied in said colors and patterns can only be seen in lighted environments, and cannot be seen in unlighted environments.
  • the problem experienced in the state of art is that the similar nail polishes lead to unhealthy and undesired conditions called bubbling on the painted harid; apd toe nails due'to particles. This condition creates problems and limits the usage area in the present applications.
  • the invisible bacteria, fungi, microbes and the like hang on the particulate surfaces and threat the health of consumers.
  • the present invention is related to a novelty for nail polishes (enamels) in the cosmetics industry, which meets the abovementioned requirements, eliminates all the disadvantages and offers some additional advantages.
  • the object of the present invention is to have alternative properties to the abovementioned drawbacks and also, to include additional properties: '
  • Another object of the present invention is to decrease the toxic substances that are extremely dangerous for human health according to some organizations such as FDA and European Health Organization and therefore, alternative chemical elements have been applied.
  • the present invention is prevented from comprising substances that are dangerous for health by using short-oil soya based alkyd resin instead of formaldehyde, ethyl alcohol instead of toluene, and acetyl tributyl citrate instead of DBP: Thanks to the nail polish, the human health is prevented from being exposed to toxins as much as possible and even, is protected.
  • Another object of the present invention is to be also visible in unlighted environments by releasing light even if the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment according to the present invention is applied in different color and patterns. It is aimed to increase the satisfaction of the customer and to provide the nail polish with more properties by enabling the use thereof in both lighted and unlighted environments thanks to the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment according to the invention.
  • Another object of the present invention is to prevent bubbling arising from the particles in the hand and toe nails on which the current nail polishes are applied in the state of the art.
  • Said bubbling problem has been limiting the usage by creating disadvantage in the state of art.
  • another negative effect of the particles is that the elements such as invisible bacteria, fungi and microbes that hang thereori threat the health of consumers. Thanks to said invention, the problem of bubbling is minimized as much as possible. Thus, a great advantage has been achieved in protecting the consumer's health.
  • the nail polish (enamel) that is visible in unlighted environment has decreased toxicity and increased UV resistance, and is self-shining in unlighted environment, also transfers its light release in the unlighted environment in direct proportion with the light exposure period and lumen (lighting volume) when it is in lighted environments.
  • Another object of the present invention is to develop the cosmetics industry and create new markets thanks to the invention.
  • the composition required for preparing 500 gr of the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment comprises the following by weight; 2.95 gr titanium dioxide, 0.7675 gr jojoba oil, 0.25 gr of 4% calcium octoate, 0.035 gr of 6% cobalt octoate, 13.01 gr phosphorescent pigment, 1.08 gr long oil soya oil based alkyd resin, 0.03 gr castor oil, 6.535 gr hydrocarbon alkyd resin, 0.18 gr anti-precipitating agent, 3.105 gr synthetic solvent, 0.3075 gr flow additive, 127 gr butyl acetate,115 gr ethyl acetate, 60 gr ethyl alcohol, 40 gr short oil soya based alkyd resin, 7.5 gr stearalkonium hectorite, 20 gr isopropyl alcohol, 65 gr nitrocellulose, 4.75 gr camphor, 30 gr acetyl tributyl cit
  • the production method of said nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment comprises the following process steps;
  • the nail polish (enamel) that is developed for achieving said objects, has decreased toxicity, increased UV resistance and is self-shining in unlighted environment is prepared.
  • nail polish that has decreased toxicity, increased UV resistance arid is self-shining in unlighted environment according to the present invention is only described for the subject to be understood better without any limiting effect.
  • composition of the paint according to the present invention comprises butyl acetate, flow additive, synthetic solvent, anti-precipitating agent, hydrocarbon alkyd resin, ethyl acetate, ethyl alcohol, isopropyl alcohol, short oil soya based alkyd resin, stearalkonium hectrorite, nitrocellulose, camphor, acetyl tributyl citrate, color pigment, black cumin oil, castor oil, long oil soya oil based alkyd resin, phosphorescent pigment, 6% cobalt octoate, 4% calcium octoate, jojoba oil and titanium dioxide.
  • nail polish enamel
  • Titanium Dioxide TiO
  • Titanium dioxide decreases the light release (loss of gloss) of the light absorbed by phosphorescent pigment in the unlighted environment and also increases the rate of light absorbance in the lighted environment within the functioning of the present invention and titanium dioxide contributes to the functioning of the invention by providing conciliating balance between two functions. Moreover, it serves as toner for pastel color together with color pigments within the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment according to the present invention.
  • jojoba oil is created with an alcohol group of long-chain branches and may be said to be the oil that is most resistant against temperature and lights thanks to fatty acid property thereof.
  • jojoba oil is still used in the most developed motor oils of the world and even as lubricant in the rocket motors of NASA. Thanks to said property of jojoba oil, the paint makes the present invention more resistant against UV lights and time.
  • Jojoba oil surpasses similar chemical substances in terms of their functions; moreover, it is not toxic and harmful. Thanks to scientific studies conducted, it is thought that the service life of jojoba oil longs for centuries without losing the properties. In addition, it is stored under several temperatures without losing said property.
  • Jojoba oil provides the mixture it is included with the property of resistance against bacterial and mold growth.
  • jojoba oil serves as catalyzer between the UV lights and the chemical substances withih the invention.
  • This element contributes within the invention thanks to its properties such as binding with other elements, . accepting pigments at a higher level and high resistance against yellowing. In addition, it also contributes to pre-drying and final drying.
  • This element contributes the functioning of the present invention with its ricinoleic acid property and enables the invention to create a better film on the surface to which . it is applied by ensuring binding between pigments during obtaining mixture.
  • This element strengthens the sticking of the mixture on the nail surface, to which it is applied, and increases the physical resistance thereof. It contributes to the functioning of the present invention by preventing the contact of elements of the invention with air during and after the mixture and preventing the oxygen inhibitors.
  • Hydrocarbon alkyd resins are the leading ones among the alkyd resins with highest resistance.
  • Anti-precipitating agent is the
  • This element contributes to the functioning of the present invention by eliminating the flowing problems while the invention is applied on the nail surfaces thanks to strong thixotropic effect thereof, preventing the precipitation of pigments in the mixture and enabling the mixture to spread better on the surface it is applied.
  • This element contributes to the functioning of the present invention by enabling the other element additives in the mixture to be mixed better. It also provides achieving a complete homogeneity.
  • said element enables to achieve applicable csurface liquidity property on the surface areas, to which the mixture will be applied. In addition, it also contributes within the present invention by controlling the liquidity on the surface areas to be applied.
  • This element contributes to the functioning of the present invention by enabling the other element additives in the mixture to be mixed better.
  • Ethyl alcohol contributes to our invention, because it is diluent.
  • Nitrocellulose solid, activated with 30% isopropyl alcohol, wetted
  • nitrocellulose is the most vital element that enables the nail polish to brighten the nail surface and to stick better, creates film layer on the nail surface thanks to its cellulosic property, and provides the nail polish according to the present invention to have better physical durability and to be more resistant against water.
  • the function of short oil soya based alkyd resin within the present invention is to achieve the liquidity of the nail polish mixture. Another function thereof is to increase the brightness, stickiness and resistance of the nail polish and color durability of color pigments.
  • Short oil alkyd resins lead to film formation as the molecular, weight of alkyd is higher than the molecular weight of oil. Thus, it is understood that short oil alkyd resin dries more rapidly than the triglyceride oils of alkyd resins. Therefore, dry and semi-dried oils can be used in the nail polish formulation. However, formaldehyde does not have said properties and short oil alkyd resin is not toxic as formaldehyde.
  • This element provides connection between the polymer chains in the functioning of present invention and serves a kind of softener. This element contributes by enabling the film layer created after the nail polish dries to be flexible.
  • This element contributes to the functioning of the present invention by providing required flexibility by minimizing the shrinkage of the film after the nail polish creates film,
  • This element comprises color pigments that determine the tone of the color of nail polish. In other words, it gives color to the nail polish mixtures.
  • the substances that are approved by European health organizations are preferred.
  • the resistance of nails against fungi is strengthened within the functioning of the invention and contributes to the invention with its care effect as a protective agent.
  • the production method of said nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment comprises the following process steps;
  • nail polish which is 500 gr in total, for 4 to 9 hours by being protected against sunbeams, humidity and water so as to have minimum 6°C and maximum 30°C.
  • the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self- shining in unlighted environment according to the present invention is applied by being painted on hand and toe nails. Before application, the nail to be painted is required to be dry and clean, and does not have scars or diseases such as fungi and the like.
  • the first drying of the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self-shining in unlighted environment according to the present invention is approximately maximum 10 minutes, and second layer dries in 5 minutes at 20°C and at 65% humidity. Every layer applied is required to be dried for 5 minutes. The total drying period is approximately 30 minutes.
  • the nail polish that has decreased toxicity, increased UV resistance and is self- shining in unlighted environment according to the present invention is required to be applied in two layers. The increase in the layers is in direct proportion with lumen (lighting rate) of the nail polish according to the invention.
  • the nail polish that has decreased toxicity, increased UV resistance and is self- shining in unlighted environment according to the present invention contacts with skin during the application, it is required to be cleaned with a wet cloth immediately. It should not be inhaled directly.
  • the application temperature is between 8°C and 35°C. It should not be applied under direct sunbeam, and windy, dusty and humid air conditions.
  • the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self- shining in unlighted environment can be stored in covered receptacles for 3 years by being protected agaihst cold, mold, freezing air and direct UV lights.
  • the nail polish (enamel) that has decreased toxicity, increased UV resistance and is self- shin ng in unlighted environment according to the present invention has been disclosed for application on hand and toe nails of people; however, it can be used for decorative purposes. Said usage areas are not limited. Alternative elements can be used in the mixtures of our nail polish in the present invention. These are as follows;
  • coconut oil based alkyd resin or sunflower seed oil based alkyd resin instead of short oil soya based alkyd resin can be used. Thanks to said variation, middle oil alkyd resin can also be used.
  • pigment with different colors can also be used instead of pigments.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne la composition d'un vernis à ongles, qui brille de lui même dans un environnement sans éclairage (nuit), qui possède une toxicité diminuée et une résistance aux UV accrue et qui est constitué d'acétate de butyle, d'un agent fluidifiant, d'un solvant synthétique, d'un agent anti-précipitation, d'une résine alkyde hydrocarbonée, d'acétate d'éthyle, d'éthanol, d'isopropanol, d'une résine alkyde à faible teneur en huile de soja, d'une hectorite de stéaralkonium, de nitrocellulose, de camphre, d'acétylcitrate de tributyle, d'un pigment coloré, d'huile de cumin noir, d'huile de ricin, d'une résine alkyde à teneur élevée en huile de soja, d'un pigment phosphorescent, de 6 % d'octoate de cobalt, de 4 % d'octoate de calcium, d'huile de jojoba et de dioxyde de titane et qui est créé dans le domaine du secteur des cosmétiques. L'invention concerne également le procédé de production de ladite composition.
PCT/TR2014/000132 2013-07-01 2014-04-10 Vernis à ongles (émail) possédant une toxicité diminuée, une résistance aux uv accrue et qui brille de lui même dans un environnement sans éclairage WO2015002620A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR201307894 2013-07-01
TR2013/07894 2013-07-01

Publications (1)

Publication Number Publication Date
WO2015002620A1 true WO2015002620A1 (fr) 2015-01-08

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PCT/TR2014/000132 WO2015002620A1 (fr) 2013-07-01 2014-04-10 Vernis à ongles (émail) possédant une toxicité diminuée, une résistance aux uv accrue et qui brille de lui même dans un environnement sans éclairage

Country Status (1)

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WO (1) WO2015002620A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3366351A1 (fr) * 2017-02-23 2018-08-29 International Lacquers S.A. Méthode de stabilisation de la coloration de vernis à ongles
US20190077963A1 (en) * 2016-04-15 2019-03-14 Eckart Gmbh Surface-modified effect pigment and nail varnish composition
US11617707B2 (en) 2017-10-18 2023-04-04 Eckart Gmbh Nail varnish composition containing embossed effect pigments and surface-modified embossed effect pigments

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB832203A (en) * 1956-04-26 1960-04-06 American Cyanamid Co Water-soluble melamine-formaldehyde condensation polymers
US3338937A (en) * 1965-07-06 1967-08-29 Hercules Inc Method for producing a crystalline nickel salt of 1-nitroso-2-naphthol
US5730961A (en) * 1997-01-24 1998-03-24 Goudjil; Kamal Metamorphic nail polish
EP1424372A1 (fr) * 2001-08-10 2004-06-02 Nihonkoken Kougyo Kabushiki Kaisha Composition d'oxyde de titane presentant une couleur a brillance elevee, composition comprenant un revetement et composition cosmetique et procede de preparation de ces compositions
EP2289484A1 (fr) * 2008-05-21 2011-03-02 Miyoshi Kasei, Inc. Poudre traitée en surface et cosmétique comprenant celle-ci

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB832203A (en) * 1956-04-26 1960-04-06 American Cyanamid Co Water-soluble melamine-formaldehyde condensation polymers
US3338937A (en) * 1965-07-06 1967-08-29 Hercules Inc Method for producing a crystalline nickel salt of 1-nitroso-2-naphthol
US5730961A (en) * 1997-01-24 1998-03-24 Goudjil; Kamal Metamorphic nail polish
EP1424372A1 (fr) * 2001-08-10 2004-06-02 Nihonkoken Kougyo Kabushiki Kaisha Composition d'oxyde de titane presentant une couleur a brillance elevee, composition comprenant un revetement et composition cosmetique et procede de preparation de ces compositions
EP2289484A1 (fr) * 2008-05-21 2011-03-02 Miyoshi Kasei, Inc. Poudre traitée en surface et cosmétique comprenant celle-ci

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE GNPD [online] MINTEL; December 2012 (2012-12-01), AVON: "Nail Enamel", XP002729831, Database accession no. 1966979 *
DATABASE GNPD [online] MINTEL; January 2003 (2003-01-01), CLINIQUE: "Glossy Nail Enamel", XP002729832, Database accession no. 183664 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190077963A1 (en) * 2016-04-15 2019-03-14 Eckart Gmbh Surface-modified effect pigment and nail varnish composition
US11111390B2 (en) * 2016-04-15 2021-09-07 Eckart Gmbh Surface-modified effect pigment and nail varnish composition
EP3366351A1 (fr) * 2017-02-23 2018-08-29 International Lacquers S.A. Méthode de stabilisation de la coloration de vernis à ongles
LU100108B1 (fr) * 2017-02-23 2018-10-02 Int Lacquers S A Méthode de stabilisation de la coloration de vernis à ongles
US11617707B2 (en) 2017-10-18 2023-04-04 Eckart Gmbh Nail varnish composition containing embossed effect pigments and surface-modified embossed effect pigments

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