WO2014202628A3 - Bifunktionale katalysatoren für die elektrokatalytische reduktion von sauerstoff und die oxidation von wasser - Google Patents

Bifunktionale katalysatoren für die elektrokatalytische reduktion von sauerstoff und die oxidation von wasser Download PDF

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Publication number
WO2014202628A3
WO2014202628A3 PCT/EP2014/062750 EP2014062750W WO2014202628A3 WO 2014202628 A3 WO2014202628 A3 WO 2014202628A3 EP 2014062750 W EP2014062750 W EP 2014062750W WO 2014202628 A3 WO2014202628 A3 WO 2014202628A3
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WO
WIPO (PCT)
Prior art keywords
oxidation
oxygen
water
electro
catalytic reduction
Prior art date
Application number
PCT/EP2014/062750
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English (en)
French (fr)
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WO2014202628A2 (de
Inventor
Justus Masa
Wolfgang Schuhmann
Wei Xia
Martin Muhler
Original Assignee
RUHR-UNIVERSITäT BOCHUM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RUHR-UNIVERSITäT BOCHUM filed Critical RUHR-UNIVERSITäT BOCHUM
Priority to DE112014002888.6T priority Critical patent/DE112014002888B4/de
Publication of WO2014202628A2 publication Critical patent/WO2014202628A2/de
Publication of WO2014202628A3 publication Critical patent/WO2014202628A3/de

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
    • H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33—Electric or magnetic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)

Abstract

Die Erfindung betrifft bifunktionale Katalysatoren für die Sauerstoffreduktion und die Wasseroxidation, die durch Pyrolyse von Metallporphyrinen bzw. -phthalocyaninen auf stickstoffangereichertem Kohlenstoff erhältlich sind, deren Herstellung und Verwendung zur Sauerstoffreduktion und Wasseroxidation, insbesondere in reversiblen Metall-Luft-Batterien und regenerativen Brennstoffzellensowie Elektrolyseuren.
PCT/EP2014/062750 2013-06-18 2014-06-17 Bifunktionale katalysatoren für die elektrokatalytische reduktion von sauerstoff und die oxidation von wasser WO2014202628A2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE112014002888.6T DE112014002888B4 (de) 2013-06-18 2014-06-17 Bifunktionale Katalysatoren für die elektrokatalytische Reduktion von Sauerstoff und die Oxidation von Wasser

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013211356.0A DE102013211356A1 (de) 2013-06-18 2013-06-18 Bifunktionale katalysatoren für die elektrokatalytische reduktion von sauerstoff und die oxidation von wasser
DE102013211356.0 2013-06-18

Publications (2)

Publication Number Publication Date
WO2014202628A2 WO2014202628A2 (de) 2014-12-24
WO2014202628A3 true WO2014202628A3 (de) 2015-02-19

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PCT/EP2014/062750 WO2014202628A2 (de) 2013-06-18 2014-06-17 Bifunktionale katalysatoren für die elektrokatalytische reduktion von sauerstoff und die oxidation von wasser

Country Status (2)

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DE (2) DE102013211356A1 (de)
WO (1) WO2014202628A2 (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110544774B (zh) * 2019-09-09 2020-11-10 长春理工大学 一种过渡金属纳米晶-氮掺杂碳纳米管复合双功能催化剂及其制备方法和应用
CN111408375A (zh) * 2020-04-18 2020-07-14 台州学院 一种CoFe/C电催化剂的制备方法
CN112331869A (zh) * 2020-11-06 2021-02-05 五邑大学 一种钴氮双掺杂的杂化碳材料及其制备方法
CN113381031B (zh) * 2021-06-11 2022-08-19 郑州大学 一种林木衍生空气电极材料及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080113859A1 (en) * 2006-05-08 2008-05-15 University Of South Carolina Composite catalysts supported on modified carbon substrates and methods of making the same
US20100048380A1 (en) * 2008-08-21 2010-02-25 Board Of Trustees Of Michigan State University Novel catalyst for oxygen reduction reaction in fuel cells
US20120140378A1 (en) * 2010-12-03 2012-06-07 Imra America, Inc. rechargeable electrochemical energy storage device

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8709295B2 (en) * 2010-04-26 2014-04-29 Los Alamos National Security, Llc Nitrogen-doped carbon-supported cobalt-iron oxygen reduction catalyst
KR101239966B1 (ko) * 2010-11-04 2013-03-06 삼성전자주식회사 리튬 공기 전지용 양극, 그 제조방법 및 이를 채용한 리튬 공기 전지

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080113859A1 (en) * 2006-05-08 2008-05-15 University Of South Carolina Composite catalysts supported on modified carbon substrates and methods of making the same
US20100048380A1 (en) * 2008-08-21 2010-02-25 Board Of Trustees Of Michigan State University Novel catalyst for oxygen reduction reaction in fuel cells
US20120140378A1 (en) * 2010-12-03 2012-06-07 Imra America, Inc. rechargeable electrochemical energy storage device

Also Published As

Publication number Publication date
WO2014202628A2 (de) 2014-12-24
DE112014002888B4 (de) 2019-10-31
DE102013211356A1 (de) 2014-12-18
DE112014002888A5 (de) 2016-03-10

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