WO2014086074A1 - Method of fabricating cmos image sensor - Google Patents

Method of fabricating cmos image sensor Download PDF

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Publication number
WO2014086074A1
WO2014086074A1 PCT/CN2012/087844 CN2012087844W WO2014086074A1 WO 2014086074 A1 WO2014086074 A1 WO 2014086074A1 CN 2012087844 W CN2012087844 W CN 2012087844W WO 2014086074 A1 WO2014086074 A1 WO 2014086074A1
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silicon substrate
bulk silicon
layer
metal
image sensor
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PCT/CN2012/087844
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French (fr)
Chinese (zh)
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李琛
顾学强
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上海集成电路研发中心有限公司
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Publication of WO2014086074A1 publication Critical patent/WO2014086074A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/14636Interconnect structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched

Definitions

  • the present invention relates to the field of image sensors, and in particular to a method of fabricating a CMOS image sensor.
  • Image sensors are an important part of a digital camera. Depending on the component, it can be classified into two types: CCD (Charge Coupled Device) and CMOS (Complementary Metal-Oxide Semiconductor).
  • CCD Charge Coupled Device
  • CMOS Complementary Metal-Oxide Semiconductor
  • One of the preconditions for CMOS sensors to be widely used is their higher sensitivity, shorter exposure times, and shrinking pixel sizes.
  • the pixel sensitivity of one of the important performance indicators of the CMOS image sensor is mainly determined by the product of the fill factor (the ratio of the photosensitive area to the entire pixel area) and the quantum efficiency (the number of electrons generated by the photons bombarding the screen).
  • the fill factor the ratio of the photosensitive area to the entire pixel area
  • the quantum efficiency the number of electrons generated by the photons bombarding the screen.
  • active pixels are used in CMOS image sensors in order to achieve noise levels and sensitivity levels comparable to those of CCD converters.
  • the application of active pixels (pixel cells) inevitably leads to a reduction in the fill factor because a significant portion of the area of the pixel surface is occupied by the amplifier transistors, leaving less space available for the photodiodes. Therefore, an important research direction of today's CMOS sensors is to expand the fill factor.
  • the traditional CMOS image sensor uses the front side illumination (FSI, Front Side Illumination) technology, which is the front-illumination technology.
  • FSI Front Side Illumination
  • the main feature of the front-illumination technology is the sequential fabrication of photodiodes, metal interconnect layers, and color filters on the front side of the wafer.
  • the advantages are: simple process, and CMOS The process is fully compatible; the cost is lower; the color filter filling material has an adjustable refractive index; it is beneficial to increase the transmittance of incident light and reduce crosstalk.
  • the front-illumination technology is a technology compatible with CMOS standard processes and is widely used in the production of various (especially large-pixel) CMOS image sensor chips.
  • the fill factor and sensitivity of the front-illumination technique are generally low because the light first needs to pass through the upper metal interconnect layer to illuminate the underlying photodiode.
  • the main feature of the backlight technology is that the photodiode and the metal interconnection layer are first formed on the front side of the silicon wafer, and then the back surface of the silicon wafer is thinned (usually required to be thinned to 20 ⁇ m or less), and The most important through-silicon via technology (TSV, Through-Silicon-Via) of the back-sensing CMOS sensor interconnects the photodiodes.
  • TSV through-silicon via technology
  • Through-silicon via technology is the latest technology for interconnecting chips by making vertical conduction between the chip and the chip, between the wafer and the wafer. Since the interconnect is placed on the back, the front is left to the photodiode, which achieves the largest possible fill factor.
  • the advantage of the through-silicon via technology is that the incident light that is incident on the photodiode is not affected by the metal interconnection, the sensitivity is high, and the fill factor is high.
  • the through-silicon via technology is more difficult, the requirements for the device are higher, and the cost is relatively high.
  • the general backlighting technique is applied to small pixel image sensors, such as small and medium pixel cameras of smart phones, and cannot be applied to image sensor manufacturing of large pixels.
  • the present invention provides a method of fabricating a CMOS image sensor, comprising the steps of: providing an SOI substrate comprising a thin bulk silicon substrate, a thick silicon substrate, and a silicon dioxide layer; sequentially forming a photodiode region and a first metal bonding layer on the thin silicon substrate; stripping the thick silicon substrate along the SiO 2 layer; providing a bulk silicon substrate,
  • the bulk silicon substrate comprises a photodiode corresponding region and other circuit regions; a corresponding layer of the photodiode on the bulk silicon substrate sequentially forms a polysilicon layer, at least one metal interconnect layer, and forms a layer above the top metal interconnect layer a second metal bonding layer; and metal bonding the thin silicon substrate to the bulk silicon substrate.
  • the step of performing metal bonding on the thin silicon substrate and the bulk silicon substrate comprises: inverting the thin silicon substrate; and the thin silicon substrate and the bulk silicon Substrate alignment; the thin bulk silicon substrate is metal bonded to the bulk silicon substrate by a metal bonding process.
  • the step of aligning the thin bulk silicon substrate with the bulk silicon substrate comprises: forming a first alignment mark outside the photodiode region; forming outside the corresponding region of the photodiode a second alignment mark; aligning the thin bulk silicon substrate with the bulk silicon substrate by the first alignment mark and the second alignment mark.
  • the step of aligning the first metal bonding layer with the second metal bonding layer comprises forming a first layer outside the photodiode region when forming the first metal bonding layer Aligning mark; forming a second alignment mark outside the corresponding area of the photodiode when forming the second metal bonding layer; passing the first alignment mark and the second alignment mark The thin bulk silicon substrate is aligned with the bulk silicon substrate.
  • the first bonding layer and the second bonding layer comprise a Ti layer and an Au layer.
  • the first metal bonding layer and the second metal bonding layer are formed by vapor deposition of a metal film.
  • the bonding time of the metal bonding of the thin silicon substrate to the bulk silicon substrate is optionally, the CMOS image sensor manufacturing method further includes forming a read circuit, a control circuit, an interconnect, a drain, and a turn on other circuit regions of the bulk silicon substrate.
  • the first metal bonding layer is interconnected with the photodiode region through the interconnect line, and the second metal bonding layer passes through the interconnect line and the bulk silicon substrate a top metal interconnect layer interconnect; a polysilicon region on the bulk silicon substrate, at least one metal interconnect layer being interconnected by the interconnect.
  • the CMOS image sensor manufacturing method further comprises the steps of forming a color filter and forming a microlens above each of the color filters.
  • the CMOS image sensor manufacturing method further comprises the steps of: drawing the wire into the wire to package the CMOS image sensor.
  • the incident light irradiated to the photodiode is not affected by the metal interconnection, and the sensitivity is higher, and the filling factor is higher. high.
  • the pixel unit of the back-illuminated CMOS image sensor manufacturing process is realized under the premise of avoiding complicated and high-cost ultra-thin thinning process and through-silicon via technology. Fill factor performance.
  • the present invention also breaks through the limitation that the back-illuminated CMOS image sensor manufacturing process can only be used for small and medium pixel sensors, and can be widely applied to various types of large-pixel CMOS image sensors. Country deletion
  • Fig. 1 is a cross-sectional view showing the structure of a front-illuminated CMOS image sensor in the prior art.
  • FIG. 2 is a cross-sectional view showing a manufacturing method of a back-illuminated CMOS image sensor in the prior art.
  • 3A to 3E are cross-sectional views showing a method of manufacturing a CMOS image sensor of the present invention.
  • a semiconductor substrate is provided.
  • the semiconductor substrate is an SOI substrate, including a thin bulk silicon substrate 1, a thick silicon substrate 3, and a thin silicon substrate and a thick silicon substrate.
  • a photosensitive diode region 10 for light sensing is formed on the thin silicon substrate 1, and a first metal bonding layer (Metal X) 11 is formed over the photosensitive diode region.
  • the first formed The metal bonding layer 11 is interconnected with the photodiode region 10 for subsequent extraction of the photodiode electrical signals and connection of control signals. Since the size of the photodiode, that is, the pixel unit, is usually large, such as 5umX 5um, the above process on a standard SOI substrate can be completed only by micron-scale process equipment.
  • the thick silicon substrate is peeled off along the silicon dioxide layer, and the remaining thin silicon substrate 1 is used in the next process.
  • the bulk silicon substrate 4 includes Photosensitive diode corresponding area and other circuit areas.
  • a polysilicon layer 40 and one or more metal interconnection layers 41 are sequentially formed in the corresponding regions of the photodiode.
  • the number of layers of the metal interconnection layer 41 formed in this embodiment is 3, and other circuits except the corresponding regions of the photodiodes are formed.
  • the area forms a read circuit (such as an ADC), a control circuit (such as a digital connection, etc.), an interconnect, a 10, and a pad PAD43.
  • the polysilicon layer 40, the first metal interconnect layer M1, the second metal interconnect layer M2, and the top metal interconnect layer M3 of the photodiode corresponding region are interconnected by interconnect lines. Since the read circuit example and the control circuit are generally affected by the process technology, such as the read circuit and the control circuit fabricated by the 55 nm process technology, the area and power consumption are superior to the O.lSum process technology. Therefore, it can be realized by advanced process technology.
  • a second metal bonding layer (Metal Y) is formed over the corresponding region of the photoreceptor of the standard bulk silicon substrate 4, and the second metal bonding layer 42 and the top metal interconnect layer M3 are interconnected by interconnect lines.
  • the first metal bonding layer 11 and the second metal bonding layer 42 may be formed by vapor-depositing a metal film, and the preferred metal film may be a Ti film and an Au film. Specifically, the Ti film is evaporated first, and the Au film is evaporated. Since the Ti film has good adhesion, it can also serve as a diffusion barrier to prevent Au and bonding defects from entering the device.
  • the metal film may be a Pt film, an In film, an In/Sn film, a Cu/Ti film, a Cr/Au film, or the like, and the present invention is not limited thereto.
  • the thin bulk silicon substrate 1 and the standard bulk silicon substrate 4 are metal bonded.
  • the thin silicon substrate 1 prepared with the photodiode 10 and the first metal bonding layer 11 described above is first inverted to prepare for the subsequent metal bonding process.
  • the inverted thin bulk silicon substrate 1 is then aligned with the standard bulk silicon substrate 4.
  • the alignment method is performed by aligning the marks. Specifically, in the above manufacturing process, a first alignment mark is formed outside the photodiode region when the first metal bonding layer 11 is formed; and a photodiode is formed when the second metal bonding layer 42 is formed.
  • a second alignment mark is formed outside the corresponding area of the tube, and then alignment is completed by aligning the first alignment mark and the second alignment mark.
  • the bonding layer 42 corresponds to a bond.
  • the metal bonding process may employ metal diffusion bonding or melting eutectic bonding techniques.
  • the metal bonding process is completed by hot press annealing in a metal bonding apparatus, the annealing temperature is 420 ° C, and the annealing time is 30 to 120 minutes, so that the metal bonding layers are firmly bonded together.
  • the metal bonding layer material is other metals
  • the metal bonding conditions are also changed accordingly.
  • the bonding can also be accomplished directly by heat and pressure in a metal bonding apparatus, which is well known to those skilled in the art and will not be described herein.
  • the bonding of the thin-body silicon substrate 1 to the standard bulk silicon substrate 4 is finally achieved by metal bonding to form a CMOS image sensor.
  • the electrical signal of the photodiode can be effectively extracted through the disk 43 on the standard bulk silicon substrate 4, and the CMOS image sensor is allowed to interact with the external power source and the control signal.
  • the CMOS image sensor manufacturing method of the embodiment further includes forming a color filter (color filter) and a microlens above each photodiode region (ie, an image pixel unit) through a color filter process.
  • a color filter color filter
  • a microlens above each photodiode region
  • Process the step of forming a microlens (Micro Len) above each color filter.
  • CMOS image sensor chip is packaged by using a conventional CMOS image sensor package technology to take the metal wire out of the disk 43.
  • the present invention replaces the conventional method by fabricating a photodiode on a thin silicon substrate, forming a read circuit, a control circuit, and the like on another standard silicon substrate, and bonding the two metals together.
  • the illuminating and back-illuminated CMOS image sensor manufacturing process realizes the high fill factor performance of the pixel unit of the back-illuminated CMOS image sensor process.
  • the present invention fabricates an image sensor pixel unit on a standard SOI substrate, which is simple in process, can be realized by a low-cost micro-scale process, and avoids high requirements on process equipment, thereby greatly reducing manufacturing of CMOS images. The cost of the sensor.
  • the present invention also breaks through the limitation that the conventional back-illuminated process can only be used for small and medium pixel sensors, and can be widely applied to the manufacture of various (especially large pixel) CMOS image sensors.

Abstract

Disclosed is a method of fabricating a Complementary Metal-Oxide Semiconductor (CMOS) image sensor, comprising: providing a silicon on insulator (SOI) substrate, the SOI substrate comprising a thin-body silicon substrate, a thick-body silicon substrate, and a silicon dioxide layer; sequentially forming a photodiode region and a first metal bonding layer on the thin-body silicon substrate; stripping the thick-body silicon substrate along the silicon dioxide layer; providing a bulk silicon substrate, the bulk silicon substrate comprising a photodiode corresponding region and other circuit regions; sequentially forming a Poly-Silicon layer and at least one metal interconnection layer in the photodiode corresponding region on the bulk silicon substrate, and forming a second metal bonding layer above the metal interconnection layer on the top; and performing metal bonding between the first thin-body silicon substrate and the bulk silicon substrate. The present invention is simple in process and low in cost, and has found wide application in fabrication of CMOS image sensors of different pixels.

Description

一种 CMOS图像传感器制造 法  CMOS image sensor manufacturing method
技术领域 Technical field
本发明涉及图像传感器领域, 特别涉及一种 CMOS 图像传感器的制造 方法。 技术背景  The present invention relates to the field of image sensors, and in particular to a method of fabricating a CMOS image sensor. technical background
图像传感器是组成数字摄像头的重要组成部分。 根据元件的不同, 可分 为 CCD (Charge Coupled Device, 电荷耦合元件)和 CMOS (Complementary Metal-Oxide Semiconductor, 金属氧化物半导体元件) 两大类。 CMOS传感 器获得广泛应用的一个前提是其所拥有的较高灵敏度、较短曝光时间和日渐 缩小的像素尺寸。  Image sensors are an important part of a digital camera. Depending on the component, it can be classified into two types: CCD (Charge Coupled Device) and CMOS (Complementary Metal-Oxide Semiconductor). One of the preconditions for CMOS sensors to be widely used is their higher sensitivity, shorter exposure times, and shrinking pixel sizes.
其中, CMOS图像传感器重要的性能指标之一的像素灵敏度主要由填充 因子 (感光面积与整个像素面积之比)与量子效率 (由轰击屏幕的光子所生 成的电子的数量) 的乘积来决定。 在 CMOS 图像传感器中, 为了实现堪与 CCD转换器相媲美的噪声指标和灵敏度水平, 在 CMOS图像传感器中应用 了有源像素。 然而有源像素(像素单元) 的应用却不可避免地导致填充因子 降低, 因为像素表面相当大的一部分面积被放大器晶体管所占用, 留给感光 二极管的可用空间较小。 所以, 当今 CMOS传感器的一个重要的研究方向 就是扩大填充因子。  Among them, the pixel sensitivity of one of the important performance indicators of the CMOS image sensor is mainly determined by the product of the fill factor (the ratio of the photosensitive area to the entire pixel area) and the quantum efficiency (the number of electrons generated by the photons bombarding the screen). In CMOS image sensors, active pixels are used in CMOS image sensors in order to achieve noise levels and sensitivity levels comparable to those of CCD converters. However, the application of active pixels (pixel cells) inevitably leads to a reduction in the fill factor because a significant portion of the area of the pixel surface is occupied by the amplifier transistors, leaving less space available for the photodiodes. Therefore, an important research direction of today's CMOS sensors is to expand the fill factor.
传统的 CMOS图像传感器采用的前感光式(FSI, Front Side Illumination) 技术, 即前照技术。 如图 1所示, 前照技术的主要特点是在硅片正面按顺序 制作感光二极管、金属互连层以及彩色滤镜。其优点是:工艺简单,与 CMOS 工艺完全兼容; 成本较低; 彩色滤镜填充材料折射率可调; 有利于提高入射 光的透射率, 减少串扰等。 前照技术是一种与 CMOS标准工艺兼容的技术, 广泛应用于各种 (尤其是大像素) CMOS图像传感器芯片的制作。 然而, 由 于光线首先需要经过上层的金属互连层才能照射到下方的感光二极管, 因此 前照技术的填充因子和灵敏度通常较低。 The traditional CMOS image sensor uses the front side illumination (FSI, Front Side Illumination) technology, which is the front-illumination technology. As shown in Figure 1, the main feature of the front-illumination technology is the sequential fabrication of photodiodes, metal interconnect layers, and color filters on the front side of the wafer. The advantages are: simple process, and CMOS The process is fully compatible; the cost is lower; the color filter filling material has an adjustable refractive index; it is beneficial to increase the transmittance of incident light and reduce crosstalk. The front-illumination technology is a technology compatible with CMOS standard processes and is widely used in the production of various (especially large-pixel) CMOS image sensor chips. However, the fill factor and sensitivity of the front-illumination technique are generally low because the light first needs to pass through the upper metal interconnect layer to illuminate the underlying photodiode.
随着像素尺寸的变小, 提高填充因子所来越困难, 目前另一种技术是从 传统的前感光式变为背部感光式 (BSI, Back Side Illumination), 即背照技 术。 如图 2所示, 背照技术的主要特点是首先在硅片正面按顺序制作感光二 极管、金属互连层,然后对硅片背面进行减薄(通常需要减薄至 20um以下), 并通过对于背部感光式 CMOS传感器最重要的硅通孔技术 (TSV, Through -Silicon-Via)将感光二极管进行互连引出。 硅通孔技术是通过在芯片和芯片 之间、 晶圆和晶圆之间制作垂直导通, 实现芯片之间互连的最新技术。 由于 互连电路置于背部, 前部全部留给感光二极管, 这样就实现了尽可能大的填 充因子。 硅通孔技术的优点是照射到感光二极管的入射光不受金属互连影 响, 灵敏度较高, 填充因子较高。 然而, 硅通孔技术难度较高, 对设备的要 求较高, 其成本也相对较高。 而且由于对于超薄硅片的减薄工艺的限制, 通 常背照技术应用于小像素的图像传感器中, 如智能手机的中小像素摄像头, 而无法应用于大像素的图像传感器制造。 发明概要  As the pixel size becomes smaller, it becomes more difficult to increase the fill factor. Another technique is to change from the conventional front-sensing type to the back-side illumination (BSI), which is a back-illumination technique. As shown in Figure 2, the main feature of the backlight technology is that the photodiode and the metal interconnection layer are first formed on the front side of the silicon wafer, and then the back surface of the silicon wafer is thinned (usually required to be thinned to 20 μm or less), and The most important through-silicon via technology (TSV, Through-Silicon-Via) of the back-sensing CMOS sensor interconnects the photodiodes. Through-silicon via technology is the latest technology for interconnecting chips by making vertical conduction between the chip and the chip, between the wafer and the wafer. Since the interconnect is placed on the back, the front is left to the photodiode, which achieves the largest possible fill factor. The advantage of the through-silicon via technology is that the incident light that is incident on the photodiode is not affected by the metal interconnection, the sensitivity is high, and the fill factor is high. However, the through-silicon via technology is more difficult, the requirements for the device are higher, and the cost is relatively high. Moreover, due to the limitation of the thinning process of ultra-thin silicon wafers, the general backlighting technique is applied to small pixel image sensors, such as small and medium pixel cameras of smart phones, and cannot be applied to image sensor manufacturing of large pixels. Summary of invention
为达成上述目的, 本发明提供一种 CMOS 图像传感器制造方法, 包括 如下步骤: 提供 SOI衬底, 所述 SOI衬底包括薄体硅衬底, 厚体硅衬底以及 二氧化硅层; 在所述薄体硅衬底上依次形成感光二极管区及第一金属键合 层; 沿所述 Si02层将所述厚体硅衬底剥离; 提供体硅衬底, 所述体硅衬底 包括感光二极管对应区及其他电路区; 在所述体硅衬底上的感光二极管对应 区依次形成多晶硅层、 至少一层金属互连层, 并在顶层金属互连层上方形成 第二金属键合层; 以及对所述薄体硅衬底与所述体硅衬底进行金属键合。 To achieve the above object, the present invention provides a method of fabricating a CMOS image sensor, comprising the steps of: providing an SOI substrate comprising a thin bulk silicon substrate, a thick silicon substrate, and a silicon dioxide layer; sequentially forming a photodiode region and a first metal bonding layer on the thin silicon substrate; stripping the thick silicon substrate along the SiO 2 layer; providing a bulk silicon substrate, The bulk silicon substrate comprises a photodiode corresponding region and other circuit regions; a corresponding layer of the photodiode on the bulk silicon substrate sequentially forms a polysilicon layer, at least one metal interconnect layer, and forms a layer above the top metal interconnect layer a second metal bonding layer; and metal bonding the thin silicon substrate to the bulk silicon substrate.
可选的, 对所述薄体硅衬底与所述体硅衬底进行金属键合的步骤包括: 将所述薄体硅衬底翻转; 将所述薄体硅衬底与所述体硅衬底对准; 通过金属 键合工艺对所述薄体硅衬底与所述体硅衬底进行金属键合。  Optionally, the step of performing metal bonding on the thin silicon substrate and the bulk silicon substrate comprises: inverting the thin silicon substrate; and the thin silicon substrate and the bulk silicon Substrate alignment; the thin bulk silicon substrate is metal bonded to the bulk silicon substrate by a metal bonding process.
可选的, 将所述薄体硅衬底与所述体硅衬底对准的步骤包括: 在所述感 光二极管区之外形成第一对准标记; 在所述感光二极管对应区之外形成第二 对准标记; 通过所述第一对准标记与所述第二对准标记将所述薄体硅衬底与 所述体硅衬底对准。  Optionally, the step of aligning the thin bulk silicon substrate with the bulk silicon substrate comprises: forming a first alignment mark outside the photodiode region; forming outside the corresponding region of the photodiode a second alignment mark; aligning the thin bulk silicon substrate with the bulk silicon substrate by the first alignment mark and the second alignment mark.
可选的,将所述第一金属键合层与所述第二金属键合层对准的步骤包括 在形成所述第一金属键合层时, 在所述感光二极管区之外形成第一对准标 记; 在形成所述第二金属键合层时, 在所述感光二极管对应区之外形成第二 对准标记; 通过所述第一对准标记与所述第二对准标记将所述薄体硅衬底与 所述体硅衬底对准。  Optionally, the step of aligning the first metal bonding layer with the second metal bonding layer comprises forming a first layer outside the photodiode region when forming the first metal bonding layer Aligning mark; forming a second alignment mark outside the corresponding area of the photodiode when forming the second metal bonding layer; passing the first alignment mark and the second alignment mark The thin bulk silicon substrate is aligned with the bulk silicon substrate.
可选的, 所述第一键合层和所述第二键合层包括 Ti层和 Au层。  Optionally, the first bonding layer and the second bonding layer comprise a Ti layer and an Au layer.
可选的, 通过蒸镀金属膜形成所述第一金属键合层及所述第二金属键合 层。  Alternatively, the first metal bonding layer and the second metal bonding layer are formed by vapor deposition of a metal film.
可选的,对所述薄体硅衬底与所述体硅衬底进行金属键合的键合时间为 可选的, 所述 CMOS 图像传感器制造方法还包括在所述体硅衬底的其 他电路区形成读取电路、 控制电路、 互连线、 10及悍盘。 Optionally, the bonding time of the metal bonding of the thin silicon substrate to the bulk silicon substrate is Optionally, the CMOS image sensor manufacturing method further includes forming a read circuit, a control circuit, an interconnect, a drain, and a turn on other circuit regions of the bulk silicon substrate.
可选的, 所述第一金属键合层通过所述互连线与所述感光二极管区互 连,所述第二金属键合层通过所述互连线与所述体硅衬底上的顶层金属互连 层互连; 所述体硅衬底上的多晶硅区、 至少一层金属互连层通过所述互连线 互连。  Optionally, the first metal bonding layer is interconnected with the photodiode region through the interconnect line, and the second metal bonding layer passes through the interconnect line and the bulk silicon substrate a top metal interconnect layer interconnect; a polysilicon region on the bulk silicon substrate, at least one metal interconnect layer being interconnected by the interconnect.
可选的, 所述 CMOS 图像传感器制造方法还包括形成彩色滤镜以及在 每个所述彩色滤镜上方形成微透镜的步骤。  Optionally, the CMOS image sensor manufacturing method further comprises the steps of forming a color filter and forming a microlens above each of the color filters.
可选的, 所述 CMOS 图像传感器制造方法还包括将所述悍盘进行金属 线引出以对所述 CMOS图像传感器进行封装的步骤。  Optionally, the CMOS image sensor manufacturing method further comprises the steps of: drawing the wire into the wire to package the CMOS image sensor.
本发明的有益效果在于,  The beneficial effects of the present invention are that
( 1 ) 采用先进的工艺技术在标准体硅衬底制作对工艺要求较高的读取 电路、控制电路等, 而以低成本的微米级工艺在 SOI衬底制作图像传感器像 素单元, 因此对图像传感器像素单元的制作节省了大量工艺成本。  (1) Using advanced process technology to fabricate the read circuit and control circuit with high requirements on the standard bulk silicon substrate, and fabricate the image sensor pixel unit on the SOI substrate in a low-cost micro-scale process, thus the image The fabrication of sensor pixel units saves a lot of process costs.
(2) 通过将标准体硅衬底和 SOI衬底金属键合的方法代替传统前照、 背照工艺,使得照射到感光二极管的入射光不受金属互连影响,灵敏度较高, 填充因子较高。 且与背照式 CMOS 图像传感器制造工艺相比, 在避免了复 杂、 高成本的超薄减薄工艺、 硅通孔技术前提下, 实现了背照式 CMOS 图 像传感器制造工艺所具有的像素单元高填充因子性能。 此外, 本发明也突破 了背照式 CMOS 图像传感器制造工艺只能用于中小像素传感器的限制, 可 以广泛应用于各种尤其是大像素 CMOS图像传感器的制作。 國删 (2) By replacing the traditional front-illumination and back-illumination processes with the standard body silicon substrate and the SOI substrate metal bonding method, the incident light irradiated to the photodiode is not affected by the metal interconnection, and the sensitivity is higher, and the filling factor is higher. high. Compared with the back-illuminated CMOS image sensor manufacturing process, the pixel unit of the back-illuminated CMOS image sensor manufacturing process is realized under the premise of avoiding complicated and high-cost ultra-thin thinning process and through-silicon via technology. Fill factor performance. In addition, the present invention also breaks through the limitation that the back-illuminated CMOS image sensor manufacturing process can only be used for small and medium pixel sensors, and can be widely applied to various types of large-pixel CMOS image sensors. Country deletion
图 1所示为现有技术中前照式 CMOS图像传感器的结构剖视图。  Fig. 1 is a cross-sectional view showing the structure of a front-illuminated CMOS image sensor in the prior art.
图 2所示为现有技术中背照式 CMOS图像传感器制造方法的剖视图。 图 3A〜图 3E所示为本发明的 CMOS图像传感器制造方法的剖视图。  2 is a cross-sectional view showing a manufacturing method of a back-illuminated CMOS image sensor in the prior art. 3A to 3E are cross-sectional views showing a method of manufacturing a CMOS image sensor of the present invention.
为使本发明的内容更加清楚易懂, 以下结合说明书附图, 对本发明的内 容作进一步说明。 当然本发明并不局限于该具体实施例, 本领域内的技术人 员所熟知的一般替换也涵盖在本发明的保护范围内。 In order to make the content of the present invention clearer and easier to understand, the contents of the present invention will be further described below in conjunction with the accompanying drawings. Of course, the invention is not limited to the specific embodiment, and general replacements well known to those skilled in the art are also encompassed within the scope of the invention.
下面将参照图 3A至图 3E描述根据本发明的用于制造新型 CMOS图像 传感器的方法。  A method for manufacturing a novel CMOS image sensor according to the present invention will be described below with reference to Figs. 3A to 3E.
请参考图 3A, 首先, 提供半导体衬底, 半导体衬底为 SOI衬底, 包括 薄体硅衬底 1, 厚体硅衬底 3以及薄体硅衬底和厚体硅衬底之间引入的一层 二氧化硅层 2。 接着在薄体硅衬底 1上形成用于感光的感光二极管区 10, 并 在感光二极管区的上方形成第一金属键合层 (Metal X)l l , 在本实施例中, 所 形成的第一金属键合层 11与感光二极管区 10互连, 用于后续感光二极管电 信号的引出和控制信号的连接。 由于感光二极管也即是像素单元的尺寸通常 较大, 如 5umX 5um, 因此上述在标准的 SOI衬底上的工艺只需微米级的工 艺设备即可完成。  Referring to FIG. 3A, first, a semiconductor substrate is provided. The semiconductor substrate is an SOI substrate, including a thin bulk silicon substrate 1, a thick silicon substrate 3, and a thin silicon substrate and a thick silicon substrate. A layer of silicon dioxide 2. Next, a photosensitive diode region 10 for light sensing is formed on the thin silicon substrate 1, and a first metal bonding layer (Metal X) 11 is formed over the photosensitive diode region. In this embodiment, the first formed The metal bonding layer 11 is interconnected with the photodiode region 10 for subsequent extraction of the photodiode electrical signals and connection of control signals. Since the size of the photodiode, that is, the pixel unit, is usually large, such as 5umX 5um, the above process on a standard SOI substrate can be completed only by micron-scale process equipment.
接下来, 请参考图 3B, 沿二氧化硅层将厚体硅衬底剥离, 剩余的薄体 硅衬底 1用于下一步工艺。  Next, referring to Fig. 3B, the thick silicon substrate is peeled off along the silicon dioxide layer, and the remaining thin silicon substrate 1 is used in the next process.
请参考图 3C, 接着, 提供另一个标准的体硅衬底 4, 该体硅衬底 4包括 感光二极管对应区及其他电路区。在感光二极管对应区依次形成多晶硅层 40 以及一层或多层金属互连层 41, 在本实施例中形成的金属互连层 41的层数 为 3, 在除感光二极管对应区以外的其他电路区域形成读取电路(如 ADC), 控制电路(如数字连线等), 互连线、 10及悍盘 PAD43等。 感光二极管对应 区的多晶硅层 40、 第一金属互连层 Ml、 第二金属互连层 M2、 顶层金属互 连层 M3间通过互连线互连。 由于读取电路例、 控制电路等通常受工艺技术 影响较大, 如 55nm的工艺技术带制作的读取电路、 控制电路等, 在面积、 功耗上都要优于 O.lSum的工艺技术, 因此可以采用先进的工艺技术实现。 Please refer to FIG. 3C. Next, another standard bulk silicon substrate 4 is provided. The bulk silicon substrate 4 includes Photosensitive diode corresponding area and other circuit areas. A polysilicon layer 40 and one or more metal interconnection layers 41 are sequentially formed in the corresponding regions of the photodiode. The number of layers of the metal interconnection layer 41 formed in this embodiment is 3, and other circuits except the corresponding regions of the photodiodes are formed. The area forms a read circuit (such as an ADC), a control circuit (such as a digital connection, etc.), an interconnect, a 10, and a pad PAD43. The polysilicon layer 40, the first metal interconnect layer M1, the second metal interconnect layer M2, and the top metal interconnect layer M3 of the photodiode corresponding region are interconnected by interconnect lines. Since the read circuit example and the control circuit are generally affected by the process technology, such as the read circuit and the control circuit fabricated by the 55 nm process technology, the area and power consumption are superior to the O.lSum process technology. Therefore, it can be realized by advanced process technology.
接着, 在标准体硅衬底 4感光二极管对应区的上方, 形成第二金属键合 层 (Metal Y) 42, 第二金属键合层 42与顶层金属互连层 M3通过互连线互 连。  Next, a second metal bonding layer (Metal Y) is formed over the corresponding region of the photoreceptor of the standard bulk silicon substrate 4, and the second metal bonding layer 42 and the top metal interconnect layer M3 are interconnected by interconnect lines.
其中, 第一金属键合层 11和第二金属键合层 42都可通过蒸镀金属膜形 成, 较佳的金属膜可为 Ti膜和 Au膜。 具体来说, 先蒸镀 Ti膜, 再蒸镀 Au 膜, 由于 Ti膜的粘附性较好, 还可作为扩散阻挡层防止 Au及键合缺陷进入 器件。 当然, 在本发明的其他实施例中, 金属膜也可为 Pt膜, In膜, In/Sn 膜, Cu/Ti膜, Cr/Au膜等, 本发明并不限于此。  The first metal bonding layer 11 and the second metal bonding layer 42 may be formed by vapor-depositing a metal film, and the preferred metal film may be a Ti film and an Au film. Specifically, the Ti film is evaporated first, and the Au film is evaporated. Since the Ti film has good adhesion, it can also serve as a diffusion barrier to prevent Au and bonding defects from entering the device. Of course, in other embodiments of the present invention, the metal film may be a Pt film, an In film, an In/Sn film, a Cu/Ti film, a Cr/Au film, or the like, and the present invention is not limited thereto.
接下来, 请参考图 3D, 将薄体硅衬底 1和标准的体硅衬底 4进行金属 键合。 具体来说, 首先将上述制备有感光二极管 10、 第一金属键合层 11的 薄体硅衬底 1进行翻转, 为后续金属键合工艺做准备。 之后将已翻转的薄体 硅衬底 1与标准体硅衬底 4进行对准。 较佳的, 对准方法是通过对准标记来 进行。 具体来说, 在上述制造过程中, 在形成第一金属键合层 11 时在感光 二极管区之外形成第一对准标记; 在形成第二金属键合层 42时在感光二极 管对应区之外形成第二对准标记, 然后通过将第一对准标记和第二对准标记 对准来完成对准。在对准了薄体硅衬底 1与标准体硅衬底 4后, 通过金属键 合工艺将薄体硅衬底上的第一金属键合层 11 与标准体硅衬底上的第二金属 键合层 42对应键合。 其中金属键合工艺可采用金属扩散键合或熔化共熔晶 键合技术。在本实施例中, 通过在金属键合装置中进行热压退火完成金属键 合工艺, 退火温度为 420°C, 退火时间为 30〜120分钟, 使金属键合层牢靠地 键合在一起。 当然, 在金属键合层材料为其他金属时, 其金属键合条件也相 应改变。 在其他实施例中, 也可直接通过在金属键合装置中加热加压来完成 键合, 金属键合工艺为本领域技术人员所熟知, 在此不作赘述。 最终通过金 属键合实现薄体硅衬底 1与标准体硅衬底 4的结合以形成 CMOS图像传感 器。 Next, referring to FIG. 3D, the thin bulk silicon substrate 1 and the standard bulk silicon substrate 4 are metal bonded. Specifically, the thin silicon substrate 1 prepared with the photodiode 10 and the first metal bonding layer 11 described above is first inverted to prepare for the subsequent metal bonding process. The inverted thin bulk silicon substrate 1 is then aligned with the standard bulk silicon substrate 4. Preferably, the alignment method is performed by aligning the marks. Specifically, in the above manufacturing process, a first alignment mark is formed outside the photodiode region when the first metal bonding layer 11 is formed; and a photodiode is formed when the second metal bonding layer 42 is formed. A second alignment mark is formed outside the corresponding area of the tube, and then alignment is completed by aligning the first alignment mark and the second alignment mark. After aligning the thin bulk silicon substrate 1 with the standard bulk silicon substrate 4, the first metal bonding layer 11 on the thin bulk silicon substrate and the second metal on the standard bulk silicon substrate are bonded by a metal bonding process The bonding layer 42 corresponds to a bond. The metal bonding process may employ metal diffusion bonding or melting eutectic bonding techniques. In the present embodiment, the metal bonding process is completed by hot press annealing in a metal bonding apparatus, the annealing temperature is 420 ° C, and the annealing time is 30 to 120 minutes, so that the metal bonding layers are firmly bonded together. Of course, when the metal bonding layer material is other metals, the metal bonding conditions are also changed accordingly. In other embodiments, the bonding can also be accomplished directly by heat and pressure in a metal bonding apparatus, which is well known to those skilled in the art and will not be described herein. The bonding of the thin-body silicon substrate 1 to the standard bulk silicon substrate 4 is finally achieved by metal bonding to form a CMOS image sensor.
在形成 CMOS图像传感器后, 还可通过标准体硅衬底 4上的悍盘 43有 效将感光二极管的电信号引出, 同时实现了 CMOS 图像传感器与外界电源 和控制信号交互。  After the CMOS image sensor is formed, the electrical signal of the photodiode can be effectively extracted through the disk 43 on the standard bulk silicon substrate 4, and the CMOS image sensor is allowed to interact with the external power source and the control signal.
此外, 请参考图 3E, 本实施例的 CMOS图像传感器制造方法还包括通 过彩色滤镜工艺, 在每个感光二极管区 (即图像像素单元)上方形成彩色滤 镜 (Color Filter) , 以及通过微透镜工艺, 在每个彩色滤镜上方形成微透镜 (Micro Len) 的步骤。  In addition, referring to FIG. 3E, the CMOS image sensor manufacturing method of the embodiment further includes forming a color filter (color filter) and a microlens above each photodiode region (ie, an image pixel unit) through a color filter process. Process, the step of forming a microlens (Micro Len) above each color filter.
最后, 采用传统的 CMOS图像传感器封装技术, 将悍盘 43进行金属线 引出, 对该 CMOS图像传感器芯片进行封装。  Finally, the CMOS image sensor chip is packaged by using a conventional CMOS image sensor package technology to take the metal wire out of the disk 43.
综上所述, 本发明通过分别在薄体硅衬底制作感光二极管, 在另一标准 硅片衬底制作读取电路、 控制电路等, 并将两者金属键合的方法代替传统前 照式、 背照式 CMOS图像传感器制造工艺, 实现了背照式 CMOS图像传感 器工艺的像素单元高填充因子性能。此外, 本发明在标准的 SOI衬底上制作 图像传感器像素单元, 工艺简便, 只需低成本的微米级工艺就可以实现, 更 避免了对工艺设备的较高要求, 从而大幅降低了制造 CMOS 图像传感器的 成本。 另一方面, 本发明还突破了传统背照式工艺只能用于中小像素传感器 的限制, 能广泛应用于各种 (尤其是大像素) CMOS图像传感器的制造。 In summary, the present invention replaces the conventional method by fabricating a photodiode on a thin silicon substrate, forming a read circuit, a control circuit, and the like on another standard silicon substrate, and bonding the two metals together. The illuminating and back-illuminated CMOS image sensor manufacturing process realizes the high fill factor performance of the pixel unit of the back-illuminated CMOS image sensor process. In addition, the present invention fabricates an image sensor pixel unit on a standard SOI substrate, which is simple in process, can be realized by a low-cost micro-scale process, and avoids high requirements on process equipment, thereby greatly reducing manufacturing of CMOS images. The cost of the sensor. On the other hand, the present invention also breaks through the limitation that the conventional back-illuminated process can only be used for small and medium pixel sensors, and can be widely applied to the manufacture of various (especially large pixel) CMOS image sensors.
虽然本发明已以较佳实施例揭示如上, 然所述诸多实施例仅为了便于说 明而举例而已, 并非用以限定本发明, 本领域的技术人员在不脱离本发明精 神和范围的前提下可作若干的更动与润饰,本发明所主张的保护范围应以权 利要求书所述为准。  The present invention has been described in terms of the preferred embodiments of the present invention. The present invention is not limited by the scope of the present invention. In the case of a number of changes and refinements, the scope of protection claimed in the present invention shall be as defined in the claims.

Claims

权利要求 Rights request
1. 一种 CMOS图像传感器制造方法, 其特征在于, 包括以下步骤: 提供 SOI衬底,所述 SOI衬底包括薄体硅衬底,厚体硅衬底以及二氧化 硅层; A CMOS image sensor manufacturing method, comprising the steps of: providing an SOI substrate, the SOI substrate comprising a thin bulk silicon substrate, a thick silicon substrate, and a silicon dioxide layer;
在所述薄体硅衬底上依次形成感光二极管区及第一金属键合层; 沿所述二氧化硅层将所述厚体硅衬底剥离;  Forming a photodiode region and a first metal bonding layer on the thin silicon substrate; peeling the thick silicon substrate along the silicon dioxide layer;
提供体硅衬底, 所述体硅衬底包括感光二极管对应区及其他电路区; 在所述体硅衬底上的感光二极管对应区依次形成多晶硅层、至少一层金 属互连层, 并在顶层金属互连层上方形成第二金属键合层; 以及  Providing a bulk silicon substrate, the bulk silicon substrate includes a photodiode corresponding region and other circuit regions; a photodiode corresponding region on the bulk silicon substrate sequentially forms a polysilicon layer, at least one metal interconnect layer, and Forming a second metal bonding layer over the top metal interconnect layer;
对所述薄体硅衬底与所述体硅衬底进行金属键合。  The thin bulk silicon substrate is metal bonded to the bulk silicon substrate.
2. 根据权利要求 1所述的 CMOS图像传感器制造方法, 其特征在于, 对所述薄体硅衬底与所述体硅衬底进行金属键合的步骤包括:  2. The CMOS image sensor manufacturing method according to claim 1, wherein the step of metal bonding the thin silicon substrate to the bulk silicon substrate comprises:
将所述薄体硅衬底翻转;  Inverting the thin silicon substrate;
将所述薄体硅衬底与所述体硅衬底对准;  Aligning the thin bulk silicon substrate with the bulk silicon substrate;
通过金属键合工艺对所述薄体硅衬底与所述体硅衬底进行金属键合。 The thin bulk silicon substrate is metal bonded to the bulk silicon substrate by a metal bonding process.
3. 根据权利要求 2所述的 CMOS图像传感器制造方法, 其特征在于, 将所述薄体硅衬底与所述体硅衬底对准的步骤包括: 3. The CMOS image sensor manufacturing method according to claim 2, wherein the step of aligning the thin silicon substrate with the bulk silicon substrate comprises:
在所述感光二极管区之外形成第一对准标记;  Forming a first alignment mark outside the photodiode region;
在所述感光二极管对应区之外形成第二对准标记;  Forming a second alignment mark outside the corresponding region of the photodiode;
通过所述第一对准标记与所述第二对准标记将所述薄体硅衬底与所述 体硅衬底对准。  The thin bulk silicon substrate is aligned with the bulk silicon substrate by the first alignment mark and the second alignment mark.
4. 根据权利要求 1所述的 CMOS图像传感器制造方法, 其特征在于, 所述第一键合层和所述第二键合层包括 Ti层和 Au层。  4. The CMOS image sensor manufacturing method according to claim 1, wherein the first bonding layer and the second bonding layer comprise a Ti layer and an Au layer.
5. 根据权利要求 4所述的 CMOS图像传感器制造方法, 其特征在于, 通过蒸镀金属膜形成所述第一金属键合层及所述第二金属键合层。  The CMOS image sensor manufacturing method according to claim 4, wherein the first metal bonding layer and the second metal bonding layer are formed by vapor deposition of a metal film.
6. 根据权利要求 1所述的 CMOS图像传感器制造方法, 其特征在于, 对所述薄体硅衬底与所述体硅衬底进行金属键合的键合时间为 30〜120分钟, 键合温度为 420°C。 6. The CMOS image sensor manufacturing method according to claim 1, wherein: The bonding time of the metal bonding of the thin silicon substrate to the bulk silicon substrate is 30 to 120 minutes, and the bonding temperature is 420 °C.
7. 根据权利要求 1所述的 CMOS图像传感器制造方法, 其特征在于, 所述制造方法还包括:  The CMOS image sensor manufacturing method according to claim 1, wherein the manufacturing method further comprises:
在所述体硅衬底的其他电路区形成读取电路、 控制电路、 互连线、 10 及悍盘。  Read circuits, control circuits, interconnect lines, 10 and pads are formed in other circuit regions of the bulk silicon substrate.
8. 根据权利要求 7所述的 CMOS图像传感器制造方法, 其特征在于, 所述第一金属键合层通过所述互连线与所述感光二极管区互连,所述第二金 属键合层通过所述互连线与所述体硅衬底上的顶层金属互连层互连;所述体 硅衬底上的多晶硅区、 至少一层金属互连层通过所述互连线互连。  8. The CMOS image sensor manufacturing method according to claim 7, wherein the first metal bonding layer is interconnected with the photodiode region through the interconnect line, the second metal bonding layer Interconnecting with a top metal interconnect layer on the bulk silicon substrate through the interconnect; a polysilicon region on the bulk silicon substrate, at least one metal interconnect layer being interconnected by the interconnect.
9. 根据权利要求 1所述的 CMOS图像传感器制造方法, 其特征在于, 还包括形成彩色滤镜以及在每个所述彩色滤镜上方形成微透镜的步骤。  9. The CMOS image sensor manufacturing method according to claim 1, further comprising the step of forming a color filter and forming a microlens over each of the color filters.
10. 根据权利要求 1所述的 CMOS图像传感器制造方法, 其特征在于, 还包括将所述悍盘进行金属线引出以对所述 CMOS 图像传感器进行封装的 步骤。  10. The method of fabricating a CMOS image sensor according to claim 1, further comprising the step of conducting the metal wire from the disk to package the CMOS image sensor.
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