WO2014060462A3 - Kohlenwasserstoffkonversionsverfahren in gegenwart einer sauren ionischen flüssigkeit mit vorgeschalteter hydrierung - Google Patents

Kohlenwasserstoffkonversionsverfahren in gegenwart einer sauren ionischen flüssigkeit mit vorgeschalteter hydrierung Download PDF

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Publication number
WO2014060462A3
WO2014060462A3 PCT/EP2013/071604 EP2013071604W WO2014060462A3 WO 2014060462 A3 WO2014060462 A3 WO 2014060462A3 EP 2013071604 W EP2013071604 W EP 2013071604W WO 2014060462 A3 WO2014060462 A3 WO 2014060462A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrocarbon conversion
ionic liquid
hydrogenation
acidic ionic
conversion method
Prior art date
Application number
PCT/EP2013/071604
Other languages
English (en)
French (fr)
Other versions
WO2014060462A2 (de
Inventor
Roman Prochazka
Martin Bock
Steffen Tschirschwitz
Gauthier Luc Maurice Averlant
Joni JONI
Markus Schmitt
Katharina SPUHL
Jochen BÜRKLE
Alois Kindler
Daniela Malkowsky
Stefan Bitterlich
Michael HÜBNER
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to CN201380053628.1A priority Critical patent/CN104755447A/zh
Priority to EP13777060.8A priority patent/EP2909156A2/de
Publication of WO2014060462A2 publication Critical patent/WO2014060462A2/de
Publication of WO2014060462A3 publication Critical patent/WO2014060462A3/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/29—Rearrangement of carbon atoms in the hydrocarbon skeleton changing the number of carbon atoms in a ring while maintaining the number of rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft ein Verfahren zur Kohlenwasserstoffkonversion in Gegenwart einer sauren ionischen Flüssigkeit. Die Kohlenwasserstoffkonversion ist vorzugsweise eine Isomerisierung, insbesondere eine Isomerisierung von Methylcyclopentan (MCP) zu Cyclohexan. Vor der Kohlenwasserstoffkonversion wird eine Hydrierung durchgeführt, vorzugsweise wird Benzol zu Cyclohexan hydriert. Das bei der Hydrierung und/oder Isomerisierung anfallende Cyclohexan wird vorzugsweise aus dem Verfahren isoliert. In einer bevorzugten Ausführungsform der vorliegenden Erfindung werden nach der Hydrierung und vor der Kohlenwasserstoffkonversion, insbesondere vor der Isomerisierung, Leichtsieder, insbesondere C5-C6-Alkane wie Cyclopentan oder iso-Hexane, aus dem zur Kohlenwasserstoffkonversion verwendeten Kohlenwasserstoffgemisch destillativ abgetrennt.
PCT/EP2013/071604 2012-10-18 2013-10-16 Kohlenwasserstoffkonversionsverfahren in gegenwart einer sauren ionischen flüssigkeit mit vorgeschalteter hydrierung WO2014060462A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201380053628.1A CN104755447A (zh) 2012-10-18 2013-10-16 具有在先氢化的在酸性离子液体存在下的烃转化方法
EP13777060.8A EP2909156A2 (de) 2012-10-18 2013-10-16 Kohlenwasserstoffkonversionsverfahren in gegenwart einer sauren ionischen flüssigkeit mit vorgeschalteter hydrierung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12188954.7 2012-10-18
EP12188954 2012-10-18

Publications (2)

Publication Number Publication Date
WO2014060462A2 WO2014060462A2 (de) 2014-04-24
WO2014060462A3 true WO2014060462A3 (de) 2014-06-26

Family

ID=47046426

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/071604 WO2014060462A2 (de) 2012-10-18 2013-10-16 Kohlenwasserstoffkonversionsverfahren in gegenwart einer sauren ionischen flüssigkeit mit vorgeschalteter hydrierung

Country Status (3)

Country Link
EP (1) EP2909156A2 (de)
CN (1) CN104755447A (de)
WO (1) WO2014060462A2 (de)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3311667A (en) * 1963-05-06 1967-03-28 Phillips Petroleum Co Process for the preparation of cyclohexane
WO2011069929A1 (de) * 2009-12-07 2011-06-16 Basf Se Verfahren zur isomerisierung eines gesättigten kohlenwasserstoffs
WO2011069957A1 (de) * 2009-12-07 2011-06-16 Basf Se Verfahren zur isomerisierung eines gesättigten, verzweigten und zyklischen kohlenwasserstoffs

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2001130402A (ru) 2001-11-13 2003-08-20 Хальдор Топсеэ А/С (DK) Способ изомеризации С5-С8 парафинового углеводородного сырья
US6855853B2 (en) 2002-09-18 2005-02-15 Catalytic Distillation Technologies Process for the production of low benzene gasoline
EP1403236A1 (de) 2002-09-25 2004-03-31 Haldor Topsoe A/S Verfahren zur Isomerisierung von paraffinischen Kohelenwasserstoffen katalysiert durch eine ionischen Flüssigkeit in Gegenwart eines cyclischen Kohlenwasserstoffs
CA2625905C (en) 2007-05-18 2012-06-12 Uop Llc Isomerization of benzene-containing feedstocks
CA2628361C (en) 2007-05-18 2012-08-07 Uop Llc Isomerization of benzene-containing feedstocks
US9315741B2 (en) 2008-09-08 2016-04-19 Catalytic Distillation Technologies Process for ultra low benzene reformate using catalytic distillation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3311667A (en) * 1963-05-06 1967-03-28 Phillips Petroleum Co Process for the preparation of cyclohexane
WO2011069929A1 (de) * 2009-12-07 2011-06-16 Basf Se Verfahren zur isomerisierung eines gesättigten kohlenwasserstoffs
WO2011069957A1 (de) * 2009-12-07 2011-06-16 Basf Se Verfahren zur isomerisierung eines gesättigten, verzweigten und zyklischen kohlenwasserstoffs

Also Published As

Publication number Publication date
CN104755447A (zh) 2015-07-01
WO2014060462A2 (de) 2014-04-24
EP2909156A2 (de) 2015-08-26

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