WO2014048980A1 - Procédé de production de produits basiques pouvant être utilisés à titre d'agent alcalisant e.g. (substitut de soude caustique), pour la stabilisation des sols ou à titre de charge/pigment - Google Patents

Procédé de production de produits basiques pouvant être utilisés à titre d'agent alcalisant e.g. (substitut de soude caustique), pour la stabilisation des sols ou à titre de charge/pigment Download PDF

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Publication number
WO2014048980A1
WO2014048980A1 PCT/EP2013/069949 EP2013069949W WO2014048980A1 WO 2014048980 A1 WO2014048980 A1 WO 2014048980A1 EP 2013069949 W EP2013069949 W EP 2013069949W WO 2014048980 A1 WO2014048980 A1 WO 2014048980A1
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WIPO (PCT)
Prior art keywords
particles
starting material
crushing
synthesis
basic products
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PCT/EP2013/069949
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English (en)
Inventor
Heiko Hilbert
Michael Heberle
Hendrik Krois
Klaus MÜLLER-GOMMERT
Folke ÖRSA
Johann Oberndorfer
Meri Ventola
Original Assignee
Upm-Kymmene Corporation
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Application filed by Upm-Kymmene Corporation filed Critical Upm-Kymmene Corporation
Priority to CN201380050111.7A priority Critical patent/CN104662103A/zh
Priority to US14/431,278 priority patent/US20150259767A1/en
Priority to EP13766966.9A priority patent/EP2900762A1/fr
Publication of WO2014048980A1 publication Critical patent/WO2014048980A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40—Compounds of aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/20—Obtaining alkaline earth metals or magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00—Calcareous fertilisers
    • C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/3009—Physical treatment, e.g. grinding; treatment with ultrasonic vibrations
    • C09C1/3018—Grinding
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • C09C3/041—Grinding
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001—Dry processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/02—Working-up flue dust
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer

Definitions

  • the present invention relates to a method for producing basic products for use e.g. as alkalizing agent (soda lye substitute), for ground stabilization or as filler/pigment.
  • the starting materials can be ashes, calcined basic products, minerals, organic solids and other solids such as pigments and fibers, plastic, rubber, etc.
  • the method relates to the energy-efficient recycling and defined modification of power station ashes, mineral substances such as marble and solids for further product production.
  • a further problem of the conventional wet processes is that they take place under atmospheric conditions, in which air induction into the milling zone can hardly be prevented and therefore a reverse reaction (reagglomeration) of the particles takes place directly during milling.
  • This reverse reaction results in an increased formation of agglomerates so that a defined particle size with a homogeneous size distribution of the basic products cannot be achieved at present or can only be achieved with a high expenditure of energy e.g. by further process steps.
  • the basic products produced according to conventional methods therefore have a low quality and can only be reintroduced into industrial processes to a limited extent.
  • the object of the invention was to provide a method that enables the production of basic products, which have a defined particle size with a homogeneous distribution and a high reactivity and which can therefore be integrated in industrial processes, without requiring a high amount of energy that makes the use uneconomic.
  • the present invention is based on the idea to carry out an energy-efficient crushing of particles, in which directly before the crushing the particles are mixed with a specific dosage of an additive. It is assumed that the particles freshly broken up by the crushing have the largest possible surface as well as the highest possible number of reactive surface areas at the time of crushing and enter a spontaneous reaction on site, i.e. in situ, with additives for synthesis. In this regard, it is supposed to be prevented that due an uncontrolled reaction at the resulting surface a reverse reaction (reagglomeration) takes place. It is further assumed that with the method according to the invention controlled, application-related properties of the basic products, which can also be used for a specific secondary reaction such as crystallization, are achieved.
  • the average particle size for dry particles is determined according to ISO 13320 and for wet particles according to the sedimentation method using x-ray absorption of a usually aqueous slurry containing the product, which is usually set to a measurable consistency by dilution with ethanol to prevent the dissolution of small particles.
  • an average density of 3.0 g/cm 3 is used for ash, and for the liquid phase owing to the strong dilution the data of ethanol (density 0.7764 g/ cm 3 , viscosity 0.9144 mPa-s) are used.
  • reactivity is understood as the ability of a substance to enter a spontaneous reaction or a bond at its surface with the medium in which it is located. The larger the reactive surface, the greater the reactivity of a substance.
  • reverse reaction also designated as reagglomeration
  • reagglomeration is understood as a process, in which a substance loses the state brought about by the milling process directly after the milling process.
  • surfaces generated by the milling process for instance can lose their activity e.g. by reaction with the milling medium or by repeated formation of agglomerate.
  • the starting materials are provided in an aqueous solution, e.g. as suspension, dispersion or emulsion, or in the dry state, with the possibilities described in Fig. 2 e.g. to regulate the pressure, the temperature or the dry content of the starting materials and to add additives such as carbon dioxide or reagents to the starting materials.
  • aqueous solution e.g. as suspension, dispersion or emulsion, or in the dry state, with the possibilities described in Fig. 2 e.g. to regulate the pressure, the temperature or the dry content of the starting materials and to add additives such as carbon dioxide or reagents to the starting materials.
  • provision is in the dry state, with the setting of the temperature and/or the dry content taking place e.g. by circulation of the starting material by means of a blower.
  • the starting materials are provided in air or an air/gas atmosphere, C0 2 - containing gases being preferably used.
  • the starting materials are all starting materials in particle form, the method according to the invention being suited in particular for hygroscopic starting materials.
  • starting materials can be recycled, which are selected from one or more calcined basic products, inorganic substances, organic substances, mineral substances and ashes, in particular paper ashes.
  • the ashes comprise all types of incineration ashes and industrial ashes, particularly preferred ashes being such ashes which have a high content of CaO, MgO, A1 2 0 3 , Na 2 0 such as e.g. paper ashes or wood ash with a low inert content (e.g. Si0 2 ) and/or a low heavy metal content.
  • the paper ashes comprise ashes from the recycling of paper/paperboard and their residual substances as well as residues e.g. after thermal aftertreatment.
  • the ashes further comprise ashes from burning processes, which developed at a temperature below or over 850°C.
  • the ashes can be present preferably in a suspension with water.
  • the starting materials furthermore also comprise mineral substances, inorganic and/or organic solids.
  • Inorganic substances comprise preferably calcined substances, which are burnt or reburnt, particularly preferably marble or calcined clay.
  • Organic substances comprise preferably pigments, fibers, plastic, rubber, beans and other solids.
  • Mineral substances comprise preferably unburnt, burnt or sintered mineral substances, particularly preferably marble, clay or clay-containing substances, calcium oxide, calcium hydroxide, magnesium oxide and substances containing these minerals.
  • the starting materials according to the invention can also be mixtures of two or more of the above-stated starting materials, as listed in Fig. 2 under starting materials. Mixtures with ashes are preferred.
  • the starting materials are provided in particle form, according to the invention the provision of a substance in particle form meaning a starting material in the form of a particle of any morphology, preferably the particles have an average particle size from 0.01 ⁇ ⁇ ⁇ to 10 mm, particularly preferably from 0.1 ⁇ to 10 mm and even more preferably from 0.1 ⁇ to 1 mm, the average particle size for dry and wet particles being determined as described below in connection with the separation into fine and finest fractions.
  • the particles of the starting material are optionally supplemented with additives such as C0 2 , C0 2 -containing gases or reagents and precrushed to obtain predetermined breaking points and hairline cracks, by which the method according to the invention becomes more efficient in the use of energy and the crushing of the particles.
  • additives such as C0 2 , C0 2 -containing gases or reagents and precrushed to obtain predetermined breaking points and hairline cracks, by which the method according to the invention becomes more efficient in the use of energy and the crushing of the particles.
  • the crushing of the particles of the starting materials is carried out in both a dry as well as a wet manner by counterrotating rotors with specific internals depending on the material to be milled.
  • high-frequency pressure impulses e.g. with a frequency greater than 8kHz
  • HFPI or HFPI crusher high frequence pressure impulse crusher
  • undirected pressure impulses in a dry manner preferably under a high airflow, in a vibration-transmitting medium, which is followed by an in situ separation, as designated in Fig. 2 as "HFPI crusher with in situ separation".
  • the crushing of the particles of the starting material is carried out in a non-contact manner by pressure waves.
  • High-frequency impact pressure fronts e.g. with a frequency greater than 8kHz, are understood as pressure waves or also pressure impulses.
  • pressure waves By using pressure waves, natural frequency disintegrations, crystal water disintegrations and interactive stimulation of oscillation between the particles contribute to crushing and increasing the microporosity of the material to be milled.
  • the crushing by pressure waves takes places in a vibration-transmitting medium.
  • Such a non-contact milling or disintegration process is described, for instance, in DE 102 59 456 Al, in which impact pressure fronts (pressure waves) with an impulse duration of less than ⁇ and a subsequent frequency of greater than 8kHz strike the particles.
  • the subsequent frequency can vary.
  • a further process for crushing is described, for instance, in WO 91/07223, which is preferably suited to be able to crush particles in a wet manner.
  • Vibration-transmitting media are liquids such as e.g. water, water-solvent mixtures, in which one or more solvents are optionally emulsified, as well as solvent mixtures of two or more solvents, mixtures of air or air/gas.
  • Particularly preferred media are mixtures of air, air/gas and/or gas in any combination, preferred are air/gas mixtures with CO 2 - containing gases. If C0 2 is contained, it is possible to protect the particles from a reverse reaction by passivation.
  • the crushing of the starting materials is carried out preferably in the dry state and in particular under high airflow.
  • the execution of the HFPI crushing in the dry manner as well as in the wet manner can be carried out in one step or in several steps, several steps in that the HFPI crushing is carried out in several HFPI crushers connected subsequently in a row or in a cascade.
  • additives are optionally added before, during or after the crushing, which either directly react with the particles or which protect the particles e.g. by passivation.
  • the additives are in particular one or more gases or concentrated gases, preferably carbon dioxide containing gases, particularly preferably CO 2 -containing waste gases and flue gases from e.g. thermal power stations, steam power stations and biogas plants. Similar to that stated above, the addition of carbon dioxide containing gases or the addition of, for instance, carbon dioxide containing gases concentrated from waste gases results in the protection of the particles from a reverse reaction.
  • the crushing is carried out in a dry manner, preferably moist, CO 2 -containing gas or moist, concentrated CO 2 -containing gas are used as additives to use the high reactivity of the new surfaces and to prevent reverse reactions.
  • the particles crushed in the HFPI crusher can optionally be used directly for further processing in their present state or preferably in a dispersion, as designated in Fig. 2 as "for further processing".
  • a dispersion is preferably prepared by feeding the particles into a dispersing medium without induction of foreign air or foreign gas.
  • Precrushing in the HFPI crusher is particularly energy-efficient, and therefore the energy balance of the method according to the invention in combination with the HFPI crusher is particularly favorable. Due to precrushing, the reaction times in the method according to the invention are moreover shortened, which results in a potentially higher throughput.
  • the particles crushed in the HFPI crusher are separated in situ into at least two fractions which are different in the average particle size.
  • situ is to be understood as the separation of the particles directly subsequent to the crushing. This means that there is no procedural gap between the crushing of the particles and the separation. This has in particular the advantage that the individual fractions can be directly used for further processing without further processes reducing the reactivity of the basic products.
  • the separation in an energetic process is possible without additional energy for a separate module being necessary (since it is in the same airflow).
  • the dry HFPI process generates a high air through-put in the particle crushing. This airflow is used in situ to separate the fine particles in the subsequent separation in the cyclone (after the expansion of air/pressure removal). The airflow is subsequently recycled. In a separate module (e.g. air separator), on the other hand, the airflow required for this would have to be additionally generated.
  • a further advantage is that the applied temperature can be held and, if necessary, be used for a further production (modification) step e.g. in a moist medium, without additional energy having to be supplied. Since the airflow is recycled, no (cold) fresh air has to be supplied that causes cooling of the product.
  • a subsequent process e.g. in situ synthesis crushing (hereinafter also abbreviated as ISC) or alkalization with warm ash can be carried out. Cooling happens only when the ash is removed from the system (e.g. by storage in the silo).
  • the separation is carried out e.g. via a cyclone, preferably via a cyclone with air recycling.
  • additional air separators are used to enable a further separation of the particles into additional fractions.
  • separating units so-called gravity separators
  • hydrocyclones cleanings
  • centrifuges centrifuges
  • upstream classifiers
  • additives are added during the separation, which are selected from the above- stated additives according to the invention.
  • Preferred additives are CO 2 -containing gases or gas mixtures, preferably CO 2 -containing waste gases or flue gases.
  • a concentration of CO 2 from flue gases and waste gases from biogas plants is preferably used for some processes (CaCO 3 formation).
  • the entire system for the reproduction of the method according to the invention is closed. Pressure variations are optionally balanced by filter elements. Pressure, temperature, degree of dryness and atmosphere are optionally and continuously controlled in the method according to the invention to optimize the production of the basic products.
  • the above-described separation is carried out preferably into a first fraction, the finest fraction, which has an average particle size in the range from 0.1 to 8 ⁇ and a second fraction, the fine fraction, which has an average particle size in the range from 8 to 100 ⁇ .
  • the average particle size for the dry particles and/or the basic product is measured according to ISO 13320.
  • the determination of the particle size is based on the physical principles of laser diffraction.
  • the HELOS analyzers developed by Sympatec are used in combination with the RODOS dry dispersing unit and operated according to the manufacturer's instructions (Sympatec GmbH, Augsburg, Germany).
  • the sedimentation method is employed using x-ray absorption of an aqueous slurry containing the particles, which is usually set to a measurable consistency by dilution with ethanol to prevent the dissolution of small particles.
  • an average density of 3.0 g/cm 3 is used for ash, and for the liquid phase owing to the strong dilution the data of ethanol (density 0.7764 g/ cm 3 , viscosity 0.9144 mPa s) are used.
  • the particle sizes can be determined in particular by means of a Sedigraph 5100 of Micromeritics, U.S.A. For more detailed information, reference is made to the operator's manual (Micromeritics, Sedigraph 5100, Particle Size Analysis System, Operator's Manual v3.07, 1994).
  • fractions obtained in the separation are optionally resupplied to the crushing step as often as desired, as designated in Fig. 2 as "x-fold recycling".
  • the obtained fine and finest fractions are optionally used directly as basic product in the further product production e.g. as Cinerit® or Elurit®.
  • These basic products are designated as basic products 1+2 in Fig. 2.
  • the basic products 1+2 can be mixed with other basic products, which is preferably carried out in a dispersion without induction of foreign air or foreign gas.
  • the basic products according to the invention are respectively designated with two numbers, here "1+2".
  • Cinerit is understood as the basic product obtained in the fine fraction
  • Elurit is understood as the basic product obtained in the finest fraction.
  • the finer fraction is separated from the coarser fraction by in situ air separation in the process without requiring additional energy in the circulating flow (same airflow).
  • the pretreated particles are preferably provided in an aqueous slurry.
  • aqueous slurries so-called dispersions
  • the slurries can optionally also contain stabilizers e.g. citric acid, dispersants e.g. polyacrylates, polyphosphates or polycarbonates, solvents and solvent combinations, e.g.
  • alcohols preferably of ethanol, isopropanol, alkoxypropanols, of ketones, preferably acetone, of amines, preferably triethylamine as solvent and anticorrosive, or of silanes and siloxanes in benzine or isoparrafin.
  • the thus provided starting materials are mixed with at least one additive for synthesis and are supplied to directly subsequent crushing.
  • This crushing is carried out in an in situ synthesis crusher (ISC), in a step as designated in Fig. 2 as "in situ synthesis crushing”.
  • ISC in situ synthesis crusher
  • situ synthesis crushing is understood as the crushing of the particles and the reaction of the thus newly created, reactive surfaces with the previously added additives for synthesis on site.
  • the step of in situ synthesis crushing can comprise wet milling or dry milling, preferably wet milling. Furthermore, the in situ synthesis crusher can optionally be followed by a downstream reactor and/or crystallizer.
  • any gases, aerosols, liquids and/or solids are suited as additives for synthesis, preferred are such that contain carbon dioxide, hydrogen fluoride, hydrogen carbonate, hydrogen bicarbonate, alkylalkoxysilanes or bleaches such as e.g. H 2 0 2 or sodium dithionite or a mixture thereof.
  • Particularly preferred additives are C0 2 -containing gases, concentrated gases or gas mixtures, preferably C0 2 -containing waste gases or flue gases.
  • the additives for synthesis can be variably dosed to control the processes such as chemical changes, settings of the pH value and phase mixtures.
  • one or more additives selected from citric acid, polyacrylates, polyphosphates, polycarbonates, alcohols, in particular ethanol, isopropanols, alkoxypropanols, ketones, in particular acetone, amines, in particular triethylamine, silanes and siloxanes in benzine or isoparrafin, sulfuric acid, sulfates, in particular lignosulfates, alums, in particular aluminium sulfate, phosphoric acid, phosphates, soluble metallic salts, calcium oxide, calcium hydroxide and magnesium oxide can be added to the additives for synthesis at any point.
  • additives selected from citric acid, polyacrylates, polyphosphates, polycarbonates, alcohols, in particular ethanol, isopropanols, alkoxypropanols, ketones, in particular acetone, amines, in particular triethylamine, silanes and siloxanes in benzine or isoparrafin
  • metallic salts can be used in particular for controlling the crystal structure.
  • the added reagents can also serve to provide reaction options such as crystallizations, preferably H 3 P0 4 being added for the precipitation of calcium phosphates, lignin sulfonates for the precipitation of calcium lignin sulfonates and alums such as aluminium sulfate for the precipitation of calcium aluminium sulfate (Ca(Al 2 [(OH) 2 (S0 4 ) 2 ]x 26 H 2 0).
  • Particularly preferred additives are excipients such as CaO, Ca(OH) 2 or MgO, which are used to optimize the process.
  • milling balls liable to wear which preferably consist of zirconium oxide.
  • the milling ball sizes vary and possibly also the slot sizes in the milling basket, with the slot size being smaller than the smallest milling ball.
  • Milling balls preferably have an average size of 0.1 to 30 mm, preferably approximately 1-2 mm, determined by the defined sieving and image analysis assessment.
  • a surface (36) as smooth and turbulence-free as possible is created on the suspension (3) by diversion of the product flow by the flow breakers (6) on the container bottom, which prevents an undesired induction of air from the air into the suspension (3) during operation of the plant.
  • the execution of the in situ synthesis crushing in the dry manner as well as in the wet manner can optionally be carried out in one step or in several steps, several steps in that the in situ synthesis crushing is carried out in several in situ synthesis crushers connected subsequently in a row or in a cascade.
  • basic products with a defined particle size and a high, controlled reactivity can be produced, which preferably have an average particle size with a lower limit of 0,01 ⁇ , preferably 0.05 ⁇ , particularly preferably 0.1 ⁇ and even more preferably 0.2 ⁇ , and an upper limit of 50 ⁇ , preferably 25 ⁇ , particularly preferably 20 ⁇ and even more preferably 10 ⁇ .
  • the limits of the particles depend on the later use.
  • the average particle size of the basic products is determined as described above in connection with the separation into the fine and finest fractions.
  • the particles obtained after the in situ crushing synthesis can be supplied as often as desired either to HFPI crushing with in situ separation or again to the in situ crushing synthesis in the ISC, as designated in Fig. 2 as "x-fold recycling" after the in situ crushing synthesis.
  • the particles of the fine and finest fractions obtained in the pretreatment avoid the in situ synthesis crushing, as designated in Fig. 2 as "avoiding ISC".
  • the particles of the fine and finest fractions, which have avoided in situ synthesis crushing, are optionally united with the particles treated in the ISC and thus form the basic products 5+6 in Fig. 2.
  • additives such as carbon dioxide or carbon dioxide containing gases or reagents can in turn optionally be added to the optionally united fractions consisting of the particles of the in situ synthesis crushing, which are optionally united with the particles of the fine and/or finest fraction, which is designated in Fig. 2 as "optional".
  • aqueous dispersions can be produced separately and optionally without air contact or air induction in that the basic products are fed into an aqueous medium.
  • separating agents can additionally be added to the obtained fractions or to the dispersions containing the particles.
  • these particles or the prepared dispersions can be preferably subjected to a subsequent milling process for further reduction of the particle size.
  • the basic products 1-9 can, independent of each other, further be mixed with each other in any ratio and in any form to produce a basic product of the method according to the invention.
  • the basic products according to the invention are essentially used directly as alkalizing agents for instance instead of soda lye (soda lye substitute) in e.g. deinking processes, for the alkalization of fiber and wood substances and for the stabilization of wastewater purification plants or as alkaline adsorption agent instead of lime (DE 10 2005 029 500 Al).
  • the basic product obtained from said finest fraction is used for this.
  • the basic products are essentially used directly as adsorption agent, as filler, in particular as paper filler, as pigment, as plaster, in composites/synthetics, in fiber plates, as binders and/or as jointing material.
  • One advantage of the present invention is that the production of the basic products is particularly energy-efficient. For instance, in the production of CaO-based components via the burnt lime process (PCC production via Ca(OH) 2 ) according to conventional methods approximately 1250- 1300 kWh/t as well as approximately 200 kWh/t for the subsequent milling, i.e. in total approximately 1500 kWh/t, are necessary, whereas by comparison only 1 10 kWh/t are required for the basic product production according to the invention.
  • a further unexpected advantage of the invention is that particles with physical-chemical advantages are obtained, which cannot be obtained with conventional methods. For instance, new interior surfaces are formed for the produced particles due to an increase of the material diffusion by increasing the microporosity, in which water and other reactive substances such as e.g. CO 2 (dissolved or gaseous) can be diffused. Through processes such as hydration, carbonation, sulfation, etc. an increase in volume and interior disintegrations due to the volume pressure in the particles occur. Through these chemical reactions, an additional particle crushing of the starting material takes place.
  • the basic products produced by the invention thus have a defined formation of exterior and interior surfaces, the increased reactivity of which can furthermore be used by in situ synthesis and thus results in particles with increased quality.
  • the basic products produced according to the invention have e.g. an increased degree of whiteness vis-a-vis the conventional method of wet milling, which indicates that reactive and/or latent sites are exposed, which can be reacted with additives and reagents such as C0 2 .
  • a particular advantage of the method according to the invention is the production of basic products with defined particle size distribution for the definition of specific properties for basic or end products e.g. the definition of the paper properties (gloss, whiteness, opacity, printability, strengths, integration of the paper structure) or the definition of the surface structure for water absorption and setting of ground materials in ground stabilization.
  • a particular advantage is moreover that the increased reactivity, which is obtained in the precrushing of the starting materials e.g. in the HFPI crusher, can be used by the method according to the invention.
  • a further advantage of this invention is that an agglomerate or aggregate formation, which occurs in the crushing according to conventional methods with grinding units such as ball mills, does not take place or only takes place to a very minor extent. This provides technical advantages in the recycling process, since e.g. almost no machine downtimes are caused by deposition, cakings or by abrasive wear of the milling tool.
  • basic products with a defined particle size i.e. a defined average particle size and defined maximum particle size
  • these basic products are reintroduced into industrial processes, they do not generate a disruption of the industrial process steps which occur e.g. with particles and agglomerates having a too large diameter.
  • Fig. 1 shows a sketch of the principle of the in situ synthesis crusher that is suited for carrying out the method according to the invention.
  • Fig. 2 schematically shows possible workflows of the method according to the invention for the production of basic products.
  • Fig. 3 shows a test set-up of a plant for providing the starting material for the method according to the invention.
  • the particles of the starting material are subjected to crushing in an in situ synthesis crusher (1) (also ISC), with an additive for synthesis (32) being supplied directly into the milling zone of the ISC and foreign air induction during milling being prevented.
  • ISC in situ synthesis crusher
  • the starting material (3) is transported uniformly from the surface downwardly into the center.
  • This product flow moves through the inlet tube (17) of the stator to directly before the dispersing disk (13), where it is deflected radially outwards (15) and is set into rotation by the blades (14) of the dispersing disk (13).
  • the product flow (24) absorbs the additives (32) and enables a synthesis between the additives (32) and the particles (28) carried along in the product flow.
  • the product flow flows into the hollow space (22) of the ring chamber (21), with high shear forces occurring within the product flow in the transition from the rotating dispersing disk (13) to the stationary ring chamber (21).
  • the starting material ash is supplied from a silo (1) (hereinafter referring to Fig. 3) as starting material for temperature setting in an ash cooler.
  • the ash is circulated with a blower in the ash cooler (2) and, if necessary, the temperature is reduced from approximately 140°C to 70°C by means of cooling water.
  • the thus whirled up and cooled ash is supplied via a rotary feeder into the tube chain conveyor (5).
  • the exhaust air is purified of finest particles via a reverse flow cartridge filter (3).
  • the finest particles are supplied to the finest fraction (8), which is downstream of the crushing, via a valve.
  • the supply to the HFPI crusher (6) is carried out consistently via chain conveyor (5).
  • the entire system is closed, pressure variations are compensated by a filter element at this point.
  • the crushing in the HFPI crusher (6) is carried out by means of counterrotating rotors with specific internals adapted according to the required basic or end product in an air atmosphere under high airflow.
  • the ash crushed in a non-contact manner is separated in a subsequent step into a fine fraction (8) (Cinerit) and a finest fraction (9) (Elurit) without a procedural gap, i.e. in situ.
  • the separation into fine fraction and finest fraction is carried out via a cyclone.
  • the finest fraction (9) there is an air recycling (7) to the HFPI crusher.
  • a further filter element is located which can be optionally connected to the existing exhaust air filter system and serves for pressure compensation.
  • Ash which corresponds to the properties of the fine fraction and is yielded in a filter (3) during ash cooling, can optionally be directly supplied to the Cinerit container (8).
  • the fine and/or finest fraction is optionally suspended with water and dispersed in a dissolution plant, transported to the ring chamber dispersing mill (1) (hereinafter referring to Fig. 1) and filled into the ring chamber dispersing mill (1) via the filler inlet (4).
  • the in situ synthesis crushing according to the invention follows.
  • the energy for the filler/pigment production according to the conventional burnt lime process is calculated via the sum for providing the basic product CaC0 3 , which is stoichoimetrically calculated in relation to the CaO input, and the energy required for the wet milling of Ca(OH) 2 from CaO. The additional energy for transport and slaking is not included in the calculation.
  • the energy for the method according to the invention is calculated from the combination of the energy required for the low-energy pretreatment in the HFPI crusher and for the crushing in the in situ synthesis crusher according to the method according to the invention.
  • ash is used as starting material.
  • the ash on which the following examples are based, is obtained in a 56 MW thermal power station with a fluidized-bed boiler by incineration of fiber residues (fibers yielded as loss in the waste paper recycling system) as well as waste wood and sawdust. Furthermore, removed color particles and sorted-out synthetic materials from the waste paper are contained in the material to be incinerated.
  • the ash essentially consists of approximately 48% CaO (free lime content approximately 8%), 5% MgO, 14% A1 2 0 3 , 1% Na 2 0, 0.2% K 2 0, 35% Si0 2 and typical minor components of ash, as determined by X-ray fluorescence analysis.
  • the starting material ash is provided by the crushing in the H P PI crusher, which is carried out by means of counterrotating rotors with specific internals in an air atmosphere under high airflow.
  • the in situ synthesis crushing is subsequently carried out according to the above-described method according to the invention in the presence of the additive for synthesis C0 2 , added as 99.9% C0 2 gas (Linde gas cylinder).
  • Comparative Example 1 the ash recycling is carried out according to Example 1, with the difference that C0 2 is not present during the process.
  • Comparative Example 3 the ash recycling is carried out according to Comparative Example 2, with the difference that C0 2 is present during the process.
  • the degree of whiteness was determined after reaction of the product with air and the C0 2 contained therein.
  • the optical properties of the degree of whiteness R457 were determined by means of an L&W Elrepho/pulsed xenon lamp with D65 diffuse standard illuminant and 10° viewing.
  • the ash that has been recycled using the method according to the invention can, as an alkaline component, replace the use of soda lye by using the alkali and alkaline earth oxide contents, e.g. in paper and wood production.
  • the prerequisite for the use of ash in ground stabilization is a defined degree of particle size, which can only be achieved with the method according to the invention, but not with conventional methods such as ball mills.
  • the ash product according to the invention replaces burnt lime (CaO) here in ground stabilization, as a result of which it is possible to reduce the amount of energy required from conventionally 1391 kWh/t to only 80 kWh/t according to the invention.
  • CaO burnt lime
  • the ash according to the invention can be used directly as filler in paper production by direct substitution of chalk/kaolin or indirectly by substitution of burnt lime in PCC processes (precipitated calcium carbonate).

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Abstract

Cette invention concerne un procédé de production de produits basiques à partir de cendres, de minéraux, de solides organiques et autres solides, qui comprend l'utilisation d'un matériau de départ sous forme de particules, le mélange du matériau de départ avec un additif de synthèse et le broyage des particules du matériau de départ, la modification des particules par les additifs de synthèse ajoutés s'opérant directement lors du broyage. Le procédé selon l'invention permet la production à bon rendement énergétique d'un produit basique ayant une taille de particule définie et une réactivité élevée. Les produits basiques ainsi produits peuvent être utilisés directement pour produire un autre produit, par ex. à titre d'agent alcalinisant, pour la stabilisation des sols ou à titre de charge/pigments.
PCT/EP2013/069949 2012-09-25 2013-09-25 Procédé de production de produits basiques pouvant être utilisés à titre d'agent alcalisant e.g. (substitut de soude caustique), pour la stabilisation des sols ou à titre de charge/pigment WO2014048980A1 (fr)

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CN201380050111.7A CN104662103A (zh) 2012-09-25 2013-09-25 用作例如碱化剂(碱水替代品),用于地基加固或者用作填料/颜料的碱性产品的生产方法
US14/431,278 US20150259767A1 (en) 2012-09-25 2013-09-25 Method for producing basic products for use as e.g. alkalizing agent (soda lye substitute), for ground stabilization or as filler/pigment
EP13766966.9A EP2900762A1 (fr) 2012-09-25 2013-09-25 Procédé de production de produits basiques pouvant être utilisés à titre d'agent alcalisant e.g. (substitut de soude caustique), pour la stabilisation des sols ou à titre de charge/pigment

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DE102012217302.1A DE102012217302A1 (de) 2012-09-25 2012-09-25 Verfahren zur Herstellung von Basisprodukten zur Verwendung als beispielsweise Alkalisierungsmittel (Natronlaugenersatz), zur Bodenstabilisierung oder als Füllstoff/Pigment

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US10384985B2 (en) 2014-06-06 2019-08-20 B.K. Consultants, Inc. Methods and compositions for increasing the yield of, and beneficial chemical composition of, certain plants
US10040728B2 (en) * 2014-06-06 2018-08-07 Todd Frank Ovokaitys Methods and compositions for increasing the bioactivity of nutrients
CA2961753C (fr) * 2014-09-29 2023-06-13 Specialty Minerals (Michigan) Inc. Procede de preparation d'un produit composite de pcc
CN115212713B (zh) * 2022-05-30 2024-03-26 湖北工业大学 一种水泥厂湿磨窑灰固碳减排的方法
CN116283139B (zh) * 2023-03-03 2024-04-19 湖北工业大学 一种蒸压加气混凝土废料碳化再利用方法

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