WO2014035213A1 - Transparent stick-form ultraviolet-screening cosmetic composition containing polyamide based gelling agent - Google Patents

Transparent stick-form ultraviolet-screening cosmetic composition containing polyamide based gelling agent Download PDF

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Publication number
WO2014035213A1
WO2014035213A1 PCT/KR2013/007889 KR2013007889W WO2014035213A1 WO 2014035213 A1 WO2014035213 A1 WO 2014035213A1 KR 2013007889 W KR2013007889 W KR 2013007889W WO 2014035213 A1 WO2014035213 A1 WO 2014035213A1
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Prior art keywords
cosmetic composition
gelling agent
stick
transparent
transparent stick
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PCT/KR2013/007889
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French (fr)
Korean (ko)
Inventor
안유진
박명삼
서은주
지진구
Original Assignee
코스맥스 주식회사
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Publication of WO2014035213A1 publication Critical patent/WO2014035213A1/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0229—Sticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88—Polyamides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent

Definitions

  • the present invention relates to a transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, and more particularly, to a transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid-based gelling agent, an organic ultraviolet ray blocking agent. It is easy to fill when the product is in progress and has excellent application to skin and provides a soft feeling of use.
  • the present invention also relates to a transparent stick-type sunscreen cosmetic composition which can be easily applied to the skin and has sufficient stick strength.
  • the present invention relates to a transparent stick-type sunscreen cosmetic composition
  • a transparent stick-type sunscreen cosmetic composition comprising a polyamide gelling agent, an amino acid gelling agent, and an organic ultraviolet ray blocking agent, wherein the tertiary-amide-terminated polyamide copolymers (ATPA) improve the elasticity and stability.
  • Stick strength including dibutyl ethylhexanoyl glutamide, dibutyl lauroyl glutamide and organic UV blocker to improve stability with gelling agent and stick It relates to a transparent stick-type sunscreen cosmetic composition.
  • Ultraviolet radiation is sunlight in the wavelength range of 280 nm to 400 nm and occupies 10% of the energy of solar radiation.
  • the action of ultraviolet rays helps tanning of skin texture to disinfect, treat skin diseases and express healthy beauty, and plays a big role in the synthesis of vitamin D, which is essential for the human body.
  • fine wrinkles, keratin thickening, blemishes, freckles, skin drying, blackening and long-term effects cause skin photoaging and are important environmental factors for skin cancer.
  • Formulations used in sunscreen cosmetics include liquid, cream, cake, solid, spray and stick.
  • liquid and creamy sunscreen cosmetics are inconvenient to use by spreading them on the hands, and cake or solid sunscreen cosmetics repeatedly use the used sponge, which contaminates the sponge itself, causing skin problems.
  • cake or solid sunscreen cosmetics repeatedly use the used sponge, which contaminates the sponge itself, causing skin problems.
  • spray-type sunscreen cosmetics are difficult to apply to the face is limited use.
  • the inorganic UV blocker or wax component has a problem such as reducing the spreadability and causing white cloudy or cloudy look if the skin is not spread well when used.
  • Korean Unexamined Patent Publication No. 10-2010-0028355 (published on March 12, 2010) is a transparent stick type UV blocking cosmetic composition using an organic UV blocker, an amino acid gelling agent and ester oil, which has a transparent appearance, and has excellent spreadability. It provides a soft feeling, but the stability is low, sweating occurs, the content is broken when applied to the skin, such problems are not completely solved.
  • the filling temperature is high at 125 to 130 ° C. during filling, it takes a long time to melt the contents, and it is difficult to set the filling conditions.
  • the present inventors have diligently researched to overcome the problems of the prior arts, and when using a transparent stick type sunscreen agent including a polyamide gelling agent, an amino acid gelling agent and an organic ultraviolet ray shielding agent, the stick gives elasticity to the skin. It was confirmed that it can provide a sunscreen cosmetic composition having the effect of improving the breakage when applied to, and minimize the sweating phenomenon while maintaining a transparent appearance, and completed the present invention.
  • the main object of the present invention is to give a stick of the sunscreen stick elasticity to improve the breakage when applied to the skin, and to minimize the sweating phenomenon while having a transparent stick-type sunscreen cosmetic composition having the effect of maintaining a transparent appearance To provide.
  • Another object of the present invention is dibutylethylhexanoylglutamide for improving stability with strength of the tertiary-amide-terminated polyamide copolymers (ATPA) gelling agent and stick to improve the elasticity and stability ( Dibutyl ethylhexanoyl glutamide) and dibutyl lauroyl glutamide (Dibutyl lauroyl glutamide) and an organic ultraviolet ray blocker using a transparent stick type sunscreen cosmetic composition for providing.
  • tertiary-amide-terminated polyamide copolymers tertiary-amide-terminated polyamide copolymers
  • Dibutyl ethylhexanoyl glutamide Dibutyl lauroyl glutamide
  • dibutyl lauroyl glutamide Dibutyl lauroyl glutamide
  • an organic ultraviolet ray blocker using a transparent stick type sunscreen cosmetic composition for providing.
  • the present invention provides a transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid gelling agent, an organic ultraviolet ray shielding agent and an oil.
  • the tertiary-amide-terminated polyamide copolymers (ATPA) gelling agent may be used any polyamide gelling agent which can be mixed with an oily oil component, preferably ethylenediamine. / Hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine (Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine).
  • the polyamide gelling agent is characterized in that it contains 10 to 50% by weight.
  • the tertiary-amide-terminated polyamide copolymers are included in the gelling agent as a main base to improve elasticity and stability, and can be maintained in the form of a stick form within 10% by weight.
  • the application of the stiffness of the stiffness can not be given a smooth application, there may be a sticky phenomenon during application.
  • the tertiary-amide-terminated polyamide copolymers (APTA) of the present invention can be used as ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amines (Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis- di-C14-C18 alkyl amine) and ethylenediamine / stearyl dimer tallate copolymer are used as raw materials.
  • Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkylamine (Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14- used as a gelling agent in the transparent stick-type sunscreen cosmetic composition of the present invention)
  • C18 alkyl amine is a polyamide oil gelling agent that is solid at room temperature and becomes a slightly yellow liquid when dissolved at high temperature by mixing with an oily oil component. It is possible to paint.
  • any of the amino acid gelling agents that can be mixed with the oily oil component may be used as the amino acid gelling agent, for example, polyacrylamide, acrylamide, preferably dibutylethylhexanoyl glutamide and It is characterized in that it is dibutyl lauroyl glutamide.
  • the amino acid gelling agent is characterized in that it contains 0.1 to 10% by weight.
  • the amino acid-based gelling agent dibutyl ethylhexanoyl glutamide (Dibutyl ethylhexanoyl glutamide) and dibutyl lauroyl glutamide (Dibutyl lauroyl glutamide) does not have strength when broken within 0.1% by weight does not have a problem It may occur, when more than 10% by weight may be a problem that the strength of the product is not too high smoothness.
  • the amino acid gelling agent is dibutyl ethylhexanoyl glutamide (dibutyl ethylhexanoyl glutamide) and dibutyl lauroyl gleam contained in the transparent stick-type UV protection cosmetic composition to increase the stability and strength of the stick
  • Dibutyl lauroyl glutamide is a low-molecular amino acid oil gelling agent that is powdery at room temperature and mixed with oily oil components to give a colorless and transparent liquid when homogeneously dissolved at high temperature. Has characteristics.
  • Example 1 Comparative Examples 1 to 3, which include the conventional transparent stick sunscreen cosmetic composition as shown in Table 2, the results of the stability evaluation, contained a gelling agent corresponding to ETPA in the conventionally used polyamide gelling agent. Compared with Comparative Example 4, the results were lower in stability. Comparative Examples 1 to 4 had lower stability than Comparative Example 5, which contained only the ATPA gelling agent without the amino gelling agent, and the ATPA gelling agent and the amino acid. Examples containing all of the gelling agents show very good results in transparency and safety, indicating that the ATPA gelling agent and the amino acid gelling agent can be mixed to maintain transparency while minimizing sweating.
  • Example 3 Corresponds to ETPA in Comparative Examples 1 to 3 and conventionally used polyamide gelling agents including the conventional transparent stick sunscreen cosmetic composition as shown in Table 4, which is a result of evaluation of the formulation elasticity, spreadability, and usability.
  • Comparative Example 4 which contains a gelling agent, does not include an amino acid gelling agent, and compared to Comparative Example 5 containing an ATPA-based gelling agent alone and an example in which an ATPA-based gelling agent and an amino acid-based gelling agent are mixed with each other.
  • the organic UV-blocking agent provides a transparent stick-type sunscreen cosmetic composition comprising 2 to 90% by weight. If the content of the organic ultraviolet ray shielding agent is less than 2% by weight, it is not possible to obtain a sufficient ultraviolet ray blocking effect. If the amount of the organic ultraviolet ray blocking agent is more than 90% by weight, the content of other components is relatively insufficient, so that a preferable composition cannot be obtained.
  • the content according to the type of organic UV blocker is as follows.
  • the type and composition ratio of the above-mentioned organic ultraviolet ray shielding agent may be used alone or in combination of two or more as a type and composition ratio secured safety noticed by the Food and Drug Administration as a functional cosmetic sunscreen raw material.
  • the oil component is characterized in that it is composed of one or more selected from the group consisting of ester oil, hydrocarbon oil, vegetable oil and mixtures thereof.
  • ester-based oils include polyglyceryl-2triisostearate, isononylisononanonate, diisostearyl maleate, ditrimethylol propane isostearate / sebacate, and the like.
  • hydrocarbon oil examples include hydrogenated polyisobutene, pentaerythritol tetraethylhexanoate, and trimethylolpropane tricaprylate / tricaprate.
  • Vegetable oils also include macadamia seed oil, sunflower seed oil and jojoba seed oil.
  • the oil component provides a transparent stick-type sunscreen cosmetic composition comprising 2 to 80% by weight.
  • the content of the oil component is 10 to 85%, preferably 20 to 50% based on the total weight of the cosmetic composition.
  • the oil component is included in less than 10%, it is difficult to form the stick formulation because other components cannot be dissolved, and when the oil component is more than 85%, the content of the other component is relatively insufficient to obtain a composition having a desired strength.
  • a transparent stick-type sunscreen cosmetic composition further comprising at least one component selected from other oil components, alcohols, preservatives, colorants, flavoring agents, cosmetic nutritional components.
  • the transparent stick-type sunscreen cosmetic composition may further include other oil components or alcohols, preservatives, colorants, flavoring agents, cosmetic nutritional ingredients, etc. known in the art, in addition to the above-mentioned main components.
  • the cosmetic of the present invention is a transparent stick type UV blocking cosmetic composition containing a polyamide gelling agent to give a sense of elasticity of the stick to improve the breakage when applied to the skin and improve the spreadability while minimizing sweating phenomenon is more stable.
  • a polyamide gelling agent to give a sense of elasticity of the stick to improve the breakage when applied to the skin and improve the spreadability while minimizing sweating phenomenon is more stable.
  • it gives elasticity to the stick of the transparent stick-type sunscreen, there is no breakage when applied to the skin, it is easy to fill during product progress.
  • each of the sunscreen cosmetic compositions was prepared using the ingredients and contents shown in Table 1 below.
  • Comparative Examples 1 to 3 of Table 1 are components and contents of the conventional transparent stick type sunscreen cosmetic composition
  • Comparative Example 4 is a transparent stick type using a gelling agent corresponding to ETPA of the polyamide gelling agent used in the prior art It is a component and content of a cosmetic composition
  • the comparative example 5 is a component and content of the transparent stick-type cosmetic composition at the time of using an ATPA type gelling agent alone.
  • a transparent stick type sunscreen cosmetic composition using a polyamide gelling agent, including an amino acid gelling agent, an ester oil, and an organic UV blocker.
  • the production method of Comparative Examples 1 to 3 is as follows.
  • the B phase was heated to 125 ° C to 140 ° C to be completely dissolved, and then transparency was confirmed. Then, B phase and C phase were added to the A phase and stirred. After confirming that the complete dissolution and dispersion was cooled to room temperature to prepare a sunscreen cosmetics.
  • Comparative Examples 4 to 5 The production method of Comparative Examples 4 to 5 is as follows. Phase A was heated to 95 ° C to 110 ° C, completely dissolved, and phase C was added and stirred. After confirming that the complete dissolution and dispersion was cooled to room temperature to prepare a sunscreen cosmetics.
  • Example production method of the present invention is as follows. Completely dissolve A phase by heating it to 95 °C ⁇ 110 °C, dissolve B phase completely by heating 125 °C ⁇ 140 °C, check transparency, and then inject A phase and C phase which have not been treated separately. Stirred. After confirming that the complete dissolution and dispersion was cooled to room temperature to prepare a sunscreen cosmetics.
  • Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine is used in hydrocarbon oils, ester oils or mineral oils. It is mixed and dissolved uniformly. It has a melting point of 90 °C or more and becomes a transparent liquid with a light yellow color.
  • Dibutyl ethylhexanoyl glutamide and dibutyl lauroyl glutsamide are uniformly dissolved by mixing with higher alcohols, hydrocarbon oils or ester oils. It becomes a completely transparent liquid.
  • the stability evaluation was stored at -10 ° C, 0 ° C, 25 ° C, and 45 ° C for up to 6 months in a one-month period, and then evaluated the product stability by observing the state of the product. Based on the evaluation criteria below, the stability of the stick formulation and sweating on the surface of the sample were visually observed.
  • the SPF-2999 analyzer was used to spread 2 mg / cm 2 onto the SPF measuring plate according to the method provided in the manual, and then the UV blocking index was measured.
  • the cosmetics prescribed by mixing the polyamide gelling agent and the amino acid gelling agent were generally evaluated in terms of elasticity, spreadability, and usability as compared with the comparative example.
  • Comparative Examples 1 to 5 Filling temperatures of the makeup cosmetic compositions prepared in Comparative Examples 1 to 5 and Examples of the present invention are shown in Table 5 below.
  • Comparative Examples 1 to 3 since the filling temperature is high around 125 to 130 ° C., it is difficult to control the time and filling conditions for melting the contents.
  • Comparative Examples 4 to 5 and the Examples of the present invention since the filling temperature is lower than the case of Comparative Examples 1 to 3 in the vicinity of 90 ⁇ 100 °C, it is easy to melt and fill the contents relatively easily.
  • the transparent stick-type sunscreen cosmetic composition of the present invention is far superior to the comparative examples in terms of overall satisfaction such as transparency, stability, spreadability, and filling conditions.
  • a transparent stick type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid gelling agent, an organic ultraviolet ray shielding agent and an oil gives elasticity and improves the phenomenon of being broken when applied to the skin. It can be used as a cosmetic composition of a transparent stick type sunscreen with such advantages because it has excellent applicability, gives a soft feeling, minimizes sweating, and maintains transparency and is easy to fill.

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Abstract

The present invention relates to a transparent stick-form ultraviolet-screening cosmetic composition containing a polyamide based gelling agent, an amino acid based gelling agent, an organic ultraviolet screening agent and an oil, and, more specifically, relates to a transparent stick-form ultraviolet-screening cosmetic composition comprising a polyamide based gelling agent which has outstanding transparency and elastic feel and an amino acid based gelling agent which has adequate stick strength, and an organic ultraviolet screening agent as the main base. The present invention makes it possible to produce a transparent stick-form ultraviolet-screening cosmetic composition, by using the organic ultraviolet screening agent as the main base and including the polyamide based gelling agent which has outstanding transparency and elastic feel and an amino acid based gelling agent which has adequate stick strength. Consequently, the transparent stick-form ultraviolet-screening cosmetic composition containing the cosmetic composition has the advantages of having a transparent appearance and being easy to fill and also of outstanding spreadability and a high degree of stability without breaking or sweating.

Description

폴리아미드계 겔화제를 함유하는 투명 스틱형 자외선 차단용 화장료 조성물. A transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent.
본 발명은 폴리아미드계 겔화제를 함유하는 투명 스틱형 자외선 차단용 화장료 조성물에 관한 것으로, 더욱 구체적으로 폴리아미드 겔화제, 아미노산계 겔화제, 유기자외선차단제를 포함한 투명 스틱형 자외선 차단용 화장료 조성물로서 제품진행시 충진이 용이하고 피부에 발림성이 우수하고 부드러운 사용감을 제공한다. 또한, 피부에 쉽게 바를 수 있고 충분한 스틱 강도를 갖는 투명 스틱형 자외선 차단용 화장물 조성물에 관한 것이다.The present invention relates to a transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, and more particularly, to a transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid-based gelling agent, an organic ultraviolet ray blocking agent. It is easy to fill when the product is in progress and has excellent application to skin and provides a soft feeling of use. The present invention also relates to a transparent stick-type sunscreen cosmetic composition which can be easily applied to the skin and has sufficient stick strength.
본 발명은 폴리아미드 겔화제, 아미노산계 겔화제, 유기자외선차단제를 포함한 투명 스틱형 자외선 차단용 화장료 조성물에 관한 것으로, 탄성감과 안정도를 향상시켜 주는 제3급-아미드-말단 폴리아미드 공중합체류(ATPA) 겔화제와 스틱의 강도와 함께 안정성을 높이기 위한 디부틸에칠헥사노일글루타마이드(Dibutyl ethylhexanoyl glutamide), 디부틸라우로일글루타마이드(Dibutyl lauroyl glutamide) 및 유기자외선차단제를 포함한 스틱 강도를 갖는 투명 스틱형 자외선 차단용 화장료 조성물에 관한 것이다. The present invention relates to a transparent stick-type sunscreen cosmetic composition comprising a polyamide gelling agent, an amino acid gelling agent, and an organic ultraviolet ray blocking agent, wherein the tertiary-amide-terminated polyamide copolymers (ATPA) improve the elasticity and stability. ) Stick strength including dibutyl ethylhexanoyl glutamide, dibutyl lauroyl glutamide and organic UV blocker to improve stability with gelling agent and stick It relates to a transparent stick-type sunscreen cosmetic composition.
최근 각종 환경오염에 따른 오존층 파괴 문제가 대두 되면서, 자외선 차단에 대한 관심이 높아지면서 자외선 차단 제품에 대한 대중들의 관심이 증가하였다.Recently, as the ozone layer destruction problem has been raised due to various environmental pollution, the interest in UV protection has increased and the public's interest in UV protection products has increased.
자외선은 280nm 내지 400nm 파장 범위의 태양광선으로서 태양광방사의 10% 에너지를 차지하고 있다. 자외선의 작용으로는 살균작용, 피부병치료 및 건강미를 표현하도록 피부결의 태닝을 돕고, 인체 필수인 비타민 D 합성에도 큰 역할을 하고 있다. 반면에, 잔주름, 각질 비후, 기미, 주근깨합성, 피부건조, 흑화 및 장기적인 영향으로는 피부 광노화를 일으키고 피부암의 중요한 환경요인이기도 하다.Ultraviolet radiation is sunlight in the wavelength range of 280 nm to 400 nm and occupies 10% of the energy of solar radiation. The action of ultraviolet rays helps tanning of skin texture to disinfect, treat skin diseases and express healthy beauty, and plays a big role in the synthesis of vitamin D, which is essential for the human body. On the other hand, fine wrinkles, keratin thickening, blemishes, freckles, skin drying, blackening and long-term effects cause skin photoaging and are important environmental factors for skin cancer.
자외선 차단용 화장품에 사용되고 있는 제형으로는 액상, 크림상, 케익상, 고형상, 스프레이형, 스틱형이 있다. 그러나 액상 및 크림상 자외선 차단용 화장품은 손에 덜어 펴서 발라야 하는 사용상의 불편함이 있고 케익상이나 고형상의 자외선 차단용 화장품은 사용한 스펀지를 반복적으로 사용하기 때문에 스펀지 자체가 오염되어 피부 트러블을 유발하는 단점이 있다. 또한 스프레이형 자외선 차단용 화장품의 경우에는 안면에 적용이 어려워 용도가 제한적이다.Formulations used in sunscreen cosmetics include liquid, cream, cake, solid, spray and stick. However, liquid and creamy sunscreen cosmetics are inconvenient to use by spreading them on the hands, and cake or solid sunscreen cosmetics repeatedly use the used sponge, which contaminates the sponge itself, causing skin problems. There are disadvantages. In addition, spray-type sunscreen cosmetics are difficult to apply to the face is limited use.
한편, 무기자외선차단제 혹은 왁스 성분은 발림성을 감소시키고 사용시 잘 펴서 바르지 않으면 피부가 하얗거나 뿌옇게 보이는 백탁현상을 유발하는 등의 문제점을 갖고 있다.  On the other hand, the inorganic UV blocker or wax component has a problem such as reducing the spreadability and causing white cloudy or cloudy look if the skin is not spread well when used.
따라서 이러한 문제점을 해결하고자 기존의 동물성, 식물성 및/또는 광물성 에스테르 계열의 왁스 성분을 대체하여 스틱형태의 제형을 유지할 수 있을 정도의 강도를 제공하면서도 부드러운 발림성을 갖고 유기자외선 차단제만 사용한 투명 스틱형 자외선 차단제 화장료 조성물이 출현하였다. Therefore, in order to solve this problem, the transparent stick type ultraviolet light using only an organic UV blocker while providing soft enough to replace the existing wax components of animal, vegetable and / or mineral esters to maintain a stick-type formulation. Blocker cosmetic compositions have emerged.
대한민국 공개특허공보 10-2010-0028355(2010. 3. 12. 공개)에는 유기자외선차단제, 아미노산계 겔화제 및 에스테르 오일을 사용한 투명 스틱형 자외선 차단용 화장료 조성물로서 투명한 외관을 가지고, 발림성이 우수하며 부드러운 사용감을 제공하나 안정성이 낮아 발한이 일어나고, 피부에 도포 시 내용물이 부서지는 등 이러한 문제점이 완전히 해결되지 않았다. 또한 충진시 내용물 온도가 125 ~ 130℃로 충진온도가 높기 때문에 내용물을 녹이는 데 걸리는 시간이 길고, 충진 조건을 잡는데도 어려움이 있다.Korean Unexamined Patent Publication No. 10-2010-0028355 (published on March 12, 2010) is a transparent stick type UV blocking cosmetic composition using an organic UV blocker, an amino acid gelling agent and ester oil, which has a transparent appearance, and has excellent spreadability. It provides a soft feeling, but the stability is low, sweating occurs, the content is broken when applied to the skin, such problems are not completely solved. In addition, since the filling temperature is high at 125 to 130 ° C. during filling, it takes a long time to melt the contents, and it is difficult to set the filling conditions.
이에, 본 발명자들은 상기 종래기술들의 문제점들을 극복하기 위하여 예의 연구 노력한 결과, 폴리아미드계 겔화제, 아미노산계 겔화제, 유기자외선차단제를 포함한 투명 스틱형 자외선 차단제를 이용하는 경우, 스틱의 탄성감을 주어 피부에 도포시 부서지는 현상을 개선하고, 발한 현상을 최소화하면서도 투명한 외관을 유지할 수 있는 효과를 갖는 자외선 차단용 화장료 조성물을 제공할 수 있음을 확인하고, 본　발명을 완성하게 되었다.Accordingly, the present inventors have diligently researched to overcome the problems of the prior arts, and when using a transparent stick type sunscreen agent including a polyamide gelling agent, an amino acid gelling agent and an organic ultraviolet ray shielding agent, the stick gives elasticity to the skin. It was confirmed that it can provide a sunscreen cosmetic composition having the effect of improving the breakage when applied to, and minimize the sweating phenomenon while maintaining a transparent appearance, and completed the present invention.
따라서, 본 발명의 주된 목적은 스틱 자외선 차단제의 스틱에 탄성감을 주어 피부에 도포 시 부서지는 현상을 개선하고, 발한 현상을 최소화하면서도 투명한 외관을 유지할 수 있는 효과를 갖는 투명 스틱형 자외선 차단제 화장료 조성물을 제공하는 데 있다.Therefore, the main object of the present invention is to give a stick of the sunscreen stick elasticity to improve the breakage when applied to the skin, and to minimize the sweating phenomenon while having a transparent stick-type sunscreen cosmetic composition having the effect of maintaining a transparent appearance To provide.
본 발명의 다른 목적은 상기 탄성감과 안정도를 향상시켜 주는 제3급-아미드-말단 폴리아미드 공중합체류(ATPA) 겔화제와 스틱의 강도와 함께 안정성을 높이기 위한 디부틸에칠헥사노일글루타마이드(Dibutyl ethylhexanoyl glutamide) 및 디부틸라우로일글루타마이드(Dibutyl lauroyl glutamide)와 유기자외선차단제를 이용한 투명 스틱형 자외선 차단용 화장료 조성물을 제공하는데 있다.Another object of the present invention is dibutylethylhexanoylglutamide for improving stability with strength of the tertiary-amide-terminated polyamide copolymers (ATPA) gelling agent and stick to improve the elasticity and stability ( Dibutyl ethylhexanoyl glutamide) and dibutyl lauroyl glutamide (Dibutyl lauroyl glutamide) and an organic ultraviolet ray blocker using a transparent stick type sunscreen cosmetic composition for providing.
본 발명의 한 양태에 따르면, 본 발명은 폴리아미드계 겔화제, 아미노산계 겔화제, 유기자외선차단제 및 오일을 함유하는 투명 스틱형 자외선 차단용 화장료 조성물을 제공한다. According to one aspect of the present invention, the present invention provides a transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid gelling agent, an organic ultraviolet ray shielding agent and an oil.
본 발명에 있어서, 상기 폴리아미드계 겔화제로는 제3급-아미드-말단 폴리아미드 공중합체류(ATPA) 겔화제는 유성 오일 성분과 혼합 가능한 어떠한 폴리아미드계 겔화제도 사용될 수 있으며, 바람직하게는 에칠렌디아민/하이드로제네이티드 다이머 디리놀리에이트 코폴리머 비스-디-C14-C18 알킬 아민(Ethylenediamine/hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine)인 것을 특징으로 한다.In the present invention, as the polyamide gelling agent, the tertiary-amide-terminated polyamide copolymers (ATPA) gelling agent may be used any polyamide gelling agent which can be mixed with an oily oil component, preferably ethylenediamine. / Hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine (Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine).
본 발명에 있어서, 상기 폴리아미드계 겔화제는 10 ~ 50중량% 함유하는 것을 특징으로 한다. In the present invention, the polyamide gelling agent is characterized in that it contains 10 to 50% by weight.
본 발명에 있어서, 상기 3급-아미드-말단 폴리아미드 공중합체류(ATPA)는 겔화제에 주 베이스로 함유하여 탄성감과 안정도를 향상시켜 주는 것으로 10중량% 이내이면 스틱형태의 제형을 유지할 수 있을 정도의 강도를 제공할 수 없고, 50중량% 초과 시에는 발림성이 뻣뻣하여 부드러운 발림성을 부여할 수 없으며, 도포 시 끈적거리는 현상이 있을 수 있다.In the present invention, the tertiary-amide-terminated polyamide copolymers (ATPA) are included in the gelling agent as a main base to improve elasticity and stability, and can be maintained in the form of a stick form within 10% by weight. When it is not possible to provide the strength of 50% by weight, the application of the stiffness of the stiffness can not be given a smooth application, there may be a sticky phenomenon during application.
본 발명의 사용 가능한 제3급-아미드-말단 폴리아미드 공중합체류(APTA)는 에칠렌디아민/하이드로제네이티드 다이머 디리놀리에이트 코폴리머 비스-디-C14-C18 알킬 아민(Ethylenediamine/hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine), 에칠렌디아민/스테아릴 다이머 탈레이트 코폴리머(Ethylenediamine/stearyl dimer tallate copolymer)를 원료로 사용한다.The tertiary-amide-terminated polyamide copolymers (APTA) of the present invention can be used as ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amines (Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis- di-C14-C18 alkyl amine) and ethylenediamine / stearyl dimer tallate copolymer are used as raw materials.
본 발명의 투명 스틱형 자외선 차단용 화장료 조성물에서 겔화제로 사용되는 에칠렌디아민/하이드로제네이티드 다이머 디리놀리에이트 코폴리머 비스-디-C14-C18 알킬 아민(Ethylenediamine/hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine)은 폴리아미드계 오일 겔화제로서 상온에서는 고형상이며, 유성 오일 성분과 혼합하여 고온에서 용해시 약간 옐로우한 액상이 되고, 이를 용기에 충진하여 냉각하면 탄성감을 갖는 투명상의 스틱으로 제형화가 가능한 특성을 갖는다. Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkylamine (Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14- used as a gelling agent in the transparent stick-type sunscreen cosmetic composition of the present invention) C18 alkyl amine) is a polyamide oil gelling agent that is solid at room temperature and becomes a slightly yellow liquid when dissolved at high temperature by mixing with an oily oil component. It is possible to paint.
본 발명에 있어서, 상기 아미노산계 겔화제로는 유성 오일 성분과 혼합 가능한 어떠한 아미노산계 겔화제도 사용될 수 있으며, 예컨대, 폴리아크릴아마이드, 아크릴아마이드가 있으며 바람직하게는, 디부틸에칠헥사노일글루타마이드 및 디부틸라우로일글루타마이드인 것을 특징으로 한다.In the present invention, any of the amino acid gelling agents that can be mixed with the oily oil component may be used as the amino acid gelling agent, for example, polyacrylamide, acrylamide, preferably dibutylethylhexanoyl glutamide and It is characterized in that it is dibutyl lauroyl glutamide.
본 발명에 있어서, 상기 아미노산계 겔화제는 0.1 ~ 10중량% 함유하는 것을 특징으로 한다.In the present invention, the amino acid gelling agent is characterized in that it contains 0.1 to 10% by weight.
본 발명에 있어서, 상기 아미노산계 겔화제인 디부틸에칠헥사노일글루타마이드(Dibutyl ethylhexanoyl glutamide) 및 디부틸라우로일글루타마이드(Dibutyl lauroyl glutamide)는 0.1중량% 이내이면 강도를 가지지 못해 부러지는 문제가 발생할 수 있으며, 10중량% 초과 시에는 제품의 강도가 너무 높아 발림성이 부드럽지 않은 문제가 있을 수 있다.In the present invention, the amino acid-based gelling agent dibutyl ethylhexanoyl glutamide (Dibutyl ethylhexanoyl glutamide) and dibutyl lauroyl glutamide (Dibutyl lauroyl glutamide) does not have strength when broken within 0.1% by weight does not have a problem It may occur, when more than 10% by weight may be a problem that the strength of the product is not too high smoothness.
본 발명에 있어서, 상기 아미노산 겔화제는 투명 스틱형 자외선 차단용 화장료 조성물에서 스틱의 강도와 함께 안정성을 높이기 위해 함유되는 디부틸에칠헥사노일글루타마이드(Dibutyl ethylhexanoyl glutamide) 및 디부틸라우로일글루타마이드(Dibutyl lauroyl glutamide)는 저분자 아미노산계 오일 겔화제로서 상온에서는 분말상이며 유성 오일 성분과 혼합하여 고온에서 균일 용해시 무색 투명한 액상이 되고, 이를 용기에 충진하여 냉각하면 투명상의 스틱으로 제형화가 가능한 특성을 갖는다.In the present invention, the amino acid gelling agent is dibutyl ethylhexanoyl glutamide (dibutyl ethylhexanoyl glutamide) and dibutyl lauroyl gleam contained in the transparent stick-type UV protection cosmetic composition to increase the stability and strength of the stick Dibutyl lauroyl glutamide is a low-molecular amino acid oil gelling agent that is powdery at room temperature and mixed with oily oil components to give a colorless and transparent liquid when homogeneously dissolved at high temperature. Has characteristics.
실시예1 안정성 평가에 대한 결과인 표 2에서 나타나는 것과 같이 종래의 투명 스틱 자외선 차단제 화장료 조성물이 포함된 비교예 1 내지 3은 종래에 사용한 폴리아미드계 겔화제 중 ETPA에 해당하는 겔화제를 함유한 비교예4에 비해 안정성에서 낮은 결과를 나타내며 비교예 1 내지 4는 아미노계 겔화제를 포함하지 않고 ATPA계 겔화제를 단독으로 함유하는 비교예5에 비해 안정성이 낮으며, ATPA 계 겔화제와 아미노산계 겔화제를 모두 함유하는 실시예는 투명성과 안전성에 있어서 매우 양호한 결과를 나타냄으로써 ATPA계 겔화제와 아미노산계 겔화제를 혼합하여 사용 시 발한현상을 최소화하면서 투명도를 유지할 수 있음을 나타낸다.Example 1 Comparative Examples 1 to 3, which include the conventional transparent stick sunscreen cosmetic composition as shown in Table 2, the results of the stability evaluation, contained a gelling agent corresponding to ETPA in the conventionally used polyamide gelling agent. Compared with Comparative Example 4, the results were lower in stability. Comparative Examples 1 to 4 had lower stability than Comparative Example 5, which contained only the ATPA gelling agent without the amino gelling agent, and the ATPA gelling agent and the amino acid. Examples containing all of the gelling agents show very good results in transparency and safety, indicating that the ATPA gelling agent and the amino acid gelling agent can be mixed to maintain transparency while minimizing sweating.
실시예 3 제형 탄성감 및 발림성, 사용감 평가에 대한 결과인 표 4에서 나타나는 것과 같이 종래의 투명스틱 자외선 차단제 화장료 조성물이 포함된 비교예 1 내지 3과 종래에 사용한 폴리아미드계 겔화제 중 ETPA에 해당하는 겔화제를 함유한 비교예 4는 아미노산 겔화제를 포함하지 않고 ATPA계 겔화제를 단독으로 함유하는 비교예 5와 ATPA계 겔화제와 아미노산계 겔화제를 혼합하여 사용한 실시예에 비해 탄성감이 현저하게 떨어지며 비교예 5는 비교예 1 내지 4에 비해 탄성감은 높으나 경도가 낮아 부서지는 현상이 발생하여 발림성 및 사용감이 떨어지는 반면에 실시예는 탄성감도 높으면서 스틱의 강도를 유지하여 발림성이 우수하고 폴리아미드계 겔화제가 피부에 가볍고 얇게 피막형성을 하면서 밀착력이 우수하여 사용감 및 지속성이 높게 나타나는 것을 알 수 있다.Example 3 Corresponds to ETPA in Comparative Examples 1 to 3 and conventionally used polyamide gelling agents including the conventional transparent stick sunscreen cosmetic composition as shown in Table 4, which is a result of evaluation of the formulation elasticity, spreadability, and usability. Comparative Example 4, which contains a gelling agent, does not include an amino acid gelling agent, and compared to Comparative Example 5 containing an ATPA-based gelling agent alone and an example in which an ATPA-based gelling agent and an amino acid-based gelling agent are mixed with each other. Compared with Comparative Examples 5, although the elasticity is higher than Comparative Examples 1 to 4, but the hardness is low, the brittleness occurs due to the phenomena of brittleness and the feeling of use decreases, while the Example has a high elasticity and maintains the strength of the stick while maintaining the strength of the stick. Amide-based gelling agent forms light and thin film on the skin and has excellent adhesion and high use and durability. It can be seen that.
본 발명에 있어서, 상기 유기자외선차단제는 글리세릴파바, 드로메트리졸, 디갈로일트리올레이트, 3-(4-메칠벤질리덴)-캄파, 메틸안트라닐레이트, 디에칠아미노하이드록시벤조일헥실벤조에이트, 벤조페논-3, 벤조페논-4, 벤조페논-8, 부틸메톡시디벤조일메탄, 시녹세이트, 에칠헥실트리아존, 옥토크릴렌, 옥틸디메칠파바, 에칠헥실메톡시신나메이트, 에칠헥실살리실레이트, 파라아미노안식향산, 2-페닐벤즈이미다졸-5-설폰산, 호모살레이트, 이소아밀-p-메톡시신신나메이트, 비스에칠헥실옥시페놀메톡시페닐트리아진, 드로메트리졸트리실록산, 및 폴리실리콘-15 로 이루어진 군으로부터 선택되는 1종 이상인 것을 특징으로 한다.In the present invention, the organic ultraviolet blocker glyceryl pava, dromethazole, digalloyl trioleate, 3- (4-methylbenzylidene) -campa, methyl anthranilate, diethylaminohydroxybenzoylhexylbenzo Eate, Benzophenone-3, Benzophenone-4, Benzophenone-8, Butylmethoxydibenzoylmethane, Synoxate, Ethyl hexyltriazone, Octocrylene, Octyl dimethyl fava, Ethyl hexyl methoxy cinnamate, Ethyl hexyl sal Lysylate, paraaminobenzoic acid, 2-phenylbenzimidazole-5-sulfonic acid, homosalate, isoamyl-p-methoxycinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, dromethazole trisiloxane And it is characterized in that at least one member selected from the group consisting of polysilicon-15.
본 발명에 있어서, 상기 유기자외선차단제는 2 ~ 90 중량% 함유하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물을 제공한다. 유기자외선차단제는 함량이 2중량% 미만이면 충분한 자외선 차단효과를 얻을 수 없고 90중량%를 초과하면 다른 성분의 함량이 상대적으로 부족하여 바람직한 조성물을 얻을 수 없다.In the present invention, the organic UV-blocking agent provides a transparent stick-type sunscreen cosmetic composition comprising 2 to 90% by weight. If the content of the organic ultraviolet ray shielding agent is less than 2% by weight, it is not possible to obtain a sufficient ultraviolet ray blocking effect. If the amount of the organic ultraviolet ray blocking agent is more than 90% by weight, the content of other components is relatively insufficient, so that a preferable composition cannot be obtained.
본 발명에 있어서, 상기 유기자외선차단제 종류에 따른 함량은 다음과 같다. In the present invention, the content according to the type of organic UV blocker is as follows.
에칠헥실메톡시신나메이트 0.5~7.5중량%, 글리세릴파바 0.5~3.0중량%, 드로메트리졸 0.5~7.0중량%, 호모살레이트 0.5~10.0중량%, 디갈로일트리올레이트 0.5~7.0중량%, 3-(4-메칠벤질리덴)-캄파 0.5%5.0중량%, 메틸안트라닐레이트 0.5~5.0중량%, 디에칠아미노하이드록시벤조일헥실벤조에이트 0.5~10%, 벤조페논-3 0.5~5.0중량%, 에칠헥실살리실레이트 0.5~5.0중량%, 벤조페논-4 0.5~5.0중량%, 2-페닐벤즈이미다졸-5-설폰산 0.5~4.0중량%, 벤조페논-8 0.5~3.0중량%, 부틸메톡시디벤조일메탄 0.5~5.0중량%, 시녹세이트 0.5~5.0중량%, 에칠헥실트리아존 0.5~5.0중량%, 옥토크릴렌 0.5~10중량%, 옥틸디메칠파바 0.5~8.0중량%, 파라아미노안식향산 0.5~5.0중량%, 이소아밀-p-메톡시신신나메이트 0.0~10.0중량%, 비스에칠헥실옥시페놀메톡시페닐트리아진 0.0~10.0중량%, 드로메트리졸트리실록산 0.0~15.0중량%, 및 폴리실리콘-15 0.0~10.0중량% 인 것을 특징으로 한다.Ethyl hexyl methoxycinnamate 0.5 to 7.5% by weight, glyceryl paba 0.5 to 3.0% by weight, drometrizol 0.5 to 7.0% by weight, homosalate 0.5 to 10.0% by weight, digaloyl trioleate 0.5 to 7.0% by weight , 3- (4-methylbenzylidene) -campa 0.5% 5.0% by weight, methyl anthranilate 0.5-5.0% by weight, dimethylaminohydroxybenzoylhexylbenzoate 0.5-10%, benzophenone-3 0.5-5.0% %, Ethylhexyl salicylate 0.5-5.0 wt%, benzophenone-4 0.5-5.0 wt%, 2-phenylbenzimidazole-5-sulfonic acid 0.5-4.0 wt%, benzophenone-8 0.5-3.0 wt%, 0.5-5.0% by weight of butylmethoxydibenzoylmethane, 0.5-5.0% by weight of synoxate, 0.5-5.0% by weight of ethhexyltriazone, 0.5-10% by weight of octocrylene, 0.5-8.0% by weight of octyldimethylmethyl, paraamino 0.5 ~ 5.0 wt% of benzoic acid, 0.0-10.0 wt% of isoamyl-p-methoxycinnamate, 0.0-10.0 wt% of bisethylhexyloxyphenol methoxyphenyltriazine, 0.0-15.0 wt% of drometrizol trisiloxane, And poly Characterized in that the silicone -15 0.0 ~ 10.0% by weight.
본 발명에 있어서, 상기의 유기자외선차단제의 종류 및 조성비는 식품의약품안정청에 기능성화장품 자외선 차단원료로 고시되어 있는 안전성이 확보된 종류 및 조성비로서 1종 단독으로 또는 2종 이상이 함께 사용될 수 있다.In the present invention, the type and composition ratio of the above-mentioned organic ultraviolet ray shielding agent may be used alone or in combination of two or more as a type and composition ratio secured safety noticed by the Food and Drug Administration as a functional cosmetic sunscreen raw material.
본 발명에 있어서, 오일성분은 에스테르 계열의 오일, 탄화수소계 오일, 식물성 오일 및 이들의 혼합물로 이루어진 군으로부터 선택된 1종 이상으로 구성되는 것을 특징으로 한다.In the present invention, the oil component is characterized in that it is composed of one or more selected from the group consisting of ester oil, hydrocarbon oil, vegetable oil and mixtures thereof.
본 발명에 있어서, 상기 에스테르 계열 오일로는 폴리글리세릴-2트리이소스테아레이트, 이소노닐이소노나노에이트, 디이소스테아릴말레이트, 디트리메칠올프로판이소스테아레이트/세바케이트 등이 있으며, 탄화수소계 오일로는 하이드로제네이티드 폴리이소부텐, 펜타에리스리틸테트라에칠헥사노에이트, 트리메칠올프로판트리카프릴레이트/트리카프레이트 등을 들 수 있다. 또한 식물성 오일로는 마카다미아씨오일, 해바라기씨오일, 호호바씨오일 등이 있다.In the present invention, the ester-based oils include polyglyceryl-2triisostearate, isononylisononanonate, diisostearyl maleate, ditrimethylol propane isostearate / sebacate, and the like. Examples of the hydrocarbon oil include hydrogenated polyisobutene, pentaerythritol tetraethylhexanoate, and trimethylolpropane tricaprylate / tricaprate. Vegetable oils also include macadamia seed oil, sunflower seed oil and jojoba seed oil.
본 발명에 있어서, 상기 오일성분은 2 ~ 80중량% 함유하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물을 제공한다.In the present invention, the oil component provides a transparent stick-type sunscreen cosmetic composition comprising 2 to 80% by weight.
본 발명의 실시예에 따르면, 상기 오일 성분의 함량은 화장료 조성물 총 중량에 대하여 10 내지 85%, 바람직하게는 20 내지 50%가 좋다. 오일 성분이 10% 미만으로 포함되면 다른 성분을 녹일 수 없어서 스틱 제형을 형성하기 어려우며, 85%를 초과하면 다른 성분의 함량이 상대적으로 부족하여 바람직한 강도를 갖는 조성물을 얻을 수 없다. According to an embodiment of the present invention, the content of the oil component is 10 to 85%, preferably 20 to 50% based on the total weight of the cosmetic composition. When the oil component is included in less than 10%, it is difficult to form the stick formulation because other components cannot be dissolved, and when the oil component is more than 85%, the content of the other component is relatively insufficient to obtain a composition having a desired strength.
본 발명에 있어서, 기타 오일성분이나 알코올류, 보존제, 착색제, 착향제, 미용영양성분으로부터 선택되는 1종 이상의 성분을 더 포함하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물을 제공한다In the present invention, it provides a transparent stick-type sunscreen cosmetic composition further comprising at least one component selected from other oil components, alcohols, preservatives, colorants, flavoring agents, cosmetic nutritional components.
본 발명에 있어서, 투명 스틱형 자외선 차단용 화장료 조성물에는 상기에서 언급한 주요성분 외에도 이 분야에서 공지된 기타 오일성분이나 알코올류, 보존제, 착색제, 착향제, 미용영양성분 등이 더 포함될 수 있다.In the present invention, the transparent stick-type sunscreen cosmetic composition may further include other oil components or alcohols, preservatives, colorants, flavoring agents, cosmetic nutritional ingredients, etc. known in the art, in addition to the above-mentioned main components.
본 발명의 화장료는 폴리아미드계 겔화제를 포함하는 투명 스틱형 자외선 차단용 화장료 조성물로 스틱의 탄성감을 주어 피부에 도포시 부서지는 현상을 개선하고 발림성도 향상시키면서 발한 현상을 최소화하여 보다 안정하다. 또한, 투명 스틱형 자외선 차단제의 스틱에 탄성감을 주어 피부에 도포시 부서지는 현상이 없으며, 제품진행시 충진이 용이하다. The cosmetic of the present invention is a transparent stick type UV blocking cosmetic composition containing a polyamide gelling agent to give a sense of elasticity of the stick to improve the breakage when applied to the skin and improve the spreadability while minimizing sweating phenomenon is more stable. In addition, it gives elasticity to the stick of the transparent stick-type sunscreen, there is no breakage when applied to the skin, it is easy to fill during product progress.
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하기로 한다. 이들 실시예는 단지 본 발명을 예시하기 위한 것이므로, 본 발명의 범위가 이들 실시예에 의해 제한되는 것으로 해석되지는 않는다.Hereinafter, the present invention will be described in more detail with reference to Examples. Since these examples are only for illustrating the present invention, the scope of the present invention is not to be construed as being limited by these examples.
제조예1: 비교예 1 내지 5 및 본 발명의 실시예Preparation Example 1 Comparative Examples 1 to 5 and Examples of the present invention
비교예 1 내지 5와 본 발명의 실시예에서는 하기 표 1의 성분 및 함량으로 각각의 자외선 차단제 화장료 조성물을 제조하였다.In Comparative Examples 1 to 5 and Examples of the present invention, each of the sunscreen cosmetic compositions was prepared using the ingredients and contents shown in Table 1 below.
이때, 하기 표 1의 비교예 1 내지 3은 종래의 투명 스틱형 자외선 차단제 화장료 조성물의 성분 및 함량이고, 비교예 4는 종래 사용되던 폴리아미드계겔화제 중 ETPA에 해당하는 겔화제를 이용한 투명 스틱형 화장료 조성물의 성분 및 함량이며, 비교예 5는 ATPA계 겔화제를 단독으로 사용했을 때의 투명 스틱형 화장료 조성물의 성분 및 함량이다.At this time, Comparative Examples 1 to 3 of Table 1 are components and contents of the conventional transparent stick type sunscreen cosmetic composition, Comparative Example 4 is a transparent stick type using a gelling agent corresponding to ETPA of the polyamide gelling agent used in the prior art It is a component and content of a cosmetic composition, and the comparative example 5 is a component and content of the transparent stick-type cosmetic composition at the time of using an ATPA type gelling agent alone.
본 발명의 실시예 경우는 폴리아미드계 겔화제를 포함하여 아미노산계 겔화제, 에스테르계 오일, 유기자외선차단제를 사용 처방한 투명 스틱형 자외선 차단제 화장료 조성물이다.In the embodiment of the present invention, a transparent stick type sunscreen cosmetic composition using a polyamide gelling agent, including an amino acid gelling agent, an ester oil, and an organic UV blocker.
표 1
구분 원료명 비교예1 비교예2 비교예3 비교예4 비교예5 실시예
A상 에칠렌디아민/하이드로제네이티드 다이머 디리놀리에이트 코폴리머 비스-디-C14-C18 알킬 아민 - - - - 25.0 25.0
에칠렌디아민/스테아릴 다이머 디리놀리에이트 코폴리머 - - - 25.0 - -
이소트리데실이소노나노에이트 - - - 5.0 5.0 5.0
폴리글리세릴-2트리이소스테아레이트 - - - 5.0 5.0 5.0
이소노닐이소노나노에이트 - - - 2.0 2.0 2.0
부틸렌글라이콜디카프릴레이트/디카프레이트 - - - to 100 to 100 to 100
네오펜틸글라이콜디헵타노에이트 - - - 1.0 1.0 1.0
B상 디부틸에칠헥사노일글루타마이드 3.0 3.0 3.0 - - 3.0
디부틸라우로일글루타마이드 3.0 3.0 3.0 - - 3.0
옥틸도데칸올 20.0 20.0 20.0 - - 15.0
디이소스테아릴말레이트 to 100 to 100 to 100 - - -
C상 에칠헥실메톡시신나메이트 7.5 7.5 - 7.0 7.0 7.0
에칠헥실살리실레이트 5.0 5.0 5.0 - - -
비스에칠헥실옥시페놀메톡시페닐트리아진 - 5.0 - - - -
옥토크릴렌 5.0 10.0 10.0 7.0 7.0 7.0
폴리실리콘-15 10.0 - 5.0 - - -
부틸메톡시디벤조일메탄 - - 4.0 - - -
호모살레이트 - - - 8.5 8.5 8.5
디에칠아미노하이드록시벤조일헥실벤조에이트 - - - 3.0 3.0 3.0
Table 1
division Raw material name Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example
A phase Ethylenediamine / hydrogenated Dimer Dilinoleate Copolymer Bis-di-C14-C18 Alkyl Amine - - - - 25.0 25.0
Ethylenediamine / Stearyl Dimer Dilinoleate Copolymer - - - 25.0 - -
Isotridecyl isononanoate - - - 5.0 5.0 5.0
Polyglyceryl-2 Triisostearate - - - 5.0 5.0 5.0
Isononylisononanoate - - - 2.0 2.0 2.0
Butylene Glycol Dicaprylate / Dicaprate - - - to 100 to 100 to 100
Neopentylglycoldiheptanoate - - - 1.0 1.0 1.0
B phase Dibutylethylhexanoylglutamide 3.0 3.0 3.0 - - 3.0
Dibutyllauroylglutamide 3.0 3.0 3.0 - - 3.0
Octyldodecanol 20.0 20.0 20.0 - - 15.0
Diisostearyl maleate to 100 to 100 to 100 - - -
C phase Ethylhexylmethoxycinnamate 7.5 7.5 - 7.0 7.0 7.0
Ethylhexylsalicylate 5.0 5.0 5.0 - - -
Bisethylhexyloxyphenol methoxyphenyl triazine - 5.0 - - - -
Octocrylene 5.0 10.0 10.0 7.0 7.0 7.0
Polysilicon-15 10.0 - 5.0 - - -
Butylmethoxydibenzoylmethane - - 4.0 - - -
Homosalate - - - 8.5 8.5 8.5
Diethylaminohydroxybenzoylhexylbenzoate - - - 3.0 3.0 3.0
상기 비교예 1 내지 3의 제조방법은 다음과 같다. B상을 125℃ ~ 140℃로 가열하여 완전히 용해시킨 후 투명성을 확인한 다음, A상에 B상과 C상을 투입하여 교반하였다. 완전히 용해 분산된 것을 확인한 후 실온까지 냉각시켜 자외선 차단제 화장료를 제조하였다. The production method of Comparative Examples 1 to 3 is as follows. The B phase was heated to 125 ° C to 140 ° C to be completely dissolved, and then transparency was confirmed. Then, B phase and C phase were added to the A phase and stirred. After confirming that the complete dissolution and dispersion was cooled to room temperature to prepare a sunscreen cosmetics.
상기 비교예 4 내지 5의 제조방법은 다음과 같다. A상을 95℃ ~ 110℃로 가열하여 완전히 용해시키고, C상을 투입하여 교반하였다. 완전히 용해 분산된 것을 확인한 후 실온까지 냉각시켜 자외선 차단제 화장료를 제조하였다.The production method of Comparative Examples 4 to 5 is as follows. Phase A was heated to 95 ° C to 110 ° C, completely dissolved, and phase C was added and stirred. After confirming that the complete dissolution and dispersion was cooled to room temperature to prepare a sunscreen cosmetics.
본 발명의 실시예 제조방법은 다음과 같다. A상을 95℃ ~ 110℃로 가열하여 완전히 용해시키고, B상을 125℃ ~ 140℃로 가열하여 완전히 용해시킨 후 투명성을 확인한 다음, A상에 B상과 따로 처리하지 않은 C상을 투입하여 교반하였다. 완전히 용해 분산된 것을 확인한 후 실온까지 냉각시켜 자외선 차단제 화장료를 제조하였다.Example production method of the present invention is as follows. Completely dissolve A phase by heating it to 95 ℃ ~ 110 ℃, dissolve B phase completely by heating 125 ℃ ~ 140 ℃, check transparency, and then inject A phase and C phase which have not been treated separately. Stirred. After confirming that the complete dissolution and dispersion was cooled to room temperature to prepare a sunscreen cosmetics.
에칠렌디아민/하이드로제네이티드 다이머 디리놀리에이트 코폴리머 비스-디-C14-C18 알킬 아민(Ethylenediamine/hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine)은 탄화수소계 오일이나 에스테르계 오일 또는 미네랄 오일에 혼합되어 균일하게 용해되며, 녹는점은 90℃이상이며 녹아서 연한 노란색을 띄는 투명한 액상이 된다. Ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine is used in hydrocarbon oils, ester oils or mineral oils. It is mixed and dissolved uniformly. It has a melting point of 90 ℃ or more and becomes a transparent liquid with a light yellow color.
디부틸에칠헥사노일글루타마이드 및 디부틸라우로일글루타마이드(Dibutyl lauroyl glutsamide)는 고급 알코올류, 탄화수소계 오일 또는 에스테르계 오일에 혼합되어 균일하게 용해되며, 녹는점은 120℃이상이며 녹아서 완전히 투명한 액상이 된다.Dibutyl ethylhexanoyl glutamide and dibutyl lauroyl glutsamide are uniformly dissolved by mixing with higher alcohols, hydrocarbon oils or ester oils. It becomes a completely transparent liquid.
실시예 1: 안정성 평가Example 1 Stability Assessment
안정성 평가는 -10℃, 0℃, 25℃, 45℃에서 1개월 기간으로 6개월까지 보관한 후 제품의 상태를 관찰하여 제품의 안정성을 평가하였다. 아래 평가기준으로 스틱 제형의 안정도와 시료 표면의 발한 현상을 육안 관찰하였다.The stability evaluation was stored at -10 ° C, 0 ° C, 25 ° C, and 45 ° C for up to 6 months in a one-month period, and then evaluated the product stability by observing the state of the product. Based on the evaluation criteria below, the stability of the stick formulation and sweating on the surface of the sample were visually observed.
<평가기준><Evaluation Criteria>
◎ : 투명도가 높음, 발한현상이 없음. ◎: High transparency, no sweating phenomenon.
○ : 투명하지만 조금 흐릿함, 발한현상이 적어 오일 방울을 볼 수 없음. (Circle): It is transparent but it is a little blurry and there is little sweating and oil droplets are not seen.
△ : 반투명함, 발한 현상이 관찰됨. (Triangle | delta): Translucency and sweating phenomenon are observed.
X : 불투명함, 발한 현상이 심함. X: Opacity, severe sweating.
표 2
비교예 1 비교예 2 비교예 3 비교예 4 비교예 5 실시예
투명도 -10℃ ○ ○ ○ ◎ ◎ ◎
0℃ ◎ ◎ ◎ ◎ ◎ ◎
25℃ ◎ ◎ ◎ ◎ ◎ ◎
45℃ ◎ ◎ ◎ ◎ ◎ ◎
발한성 -10℃ ◎ ◎ ◎ ◎ ◎ ◎
0℃ ◎ ◎ ◎ ◎ ◎ ◎
25℃ ○ ○ ○ ○ ◎ ◎
45℃ ○ ○ ○ ○ ○ ◎
TABLE 2
Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example
transparency -10 ℃ ○ ○ ○ ◎ ◎ ◎
0 ℃ ◎ ◎ ◎ ◎ ◎ ◎
25 ℃ ◎ ◎ ◎ ◎ ◎ ◎
45 ℃ ◎ ◎ ◎ ◎ ◎ ◎
Sweating -10 ℃ ◎ ◎ ◎ ◎ ◎ ◎
0 ℃ ◎ ◎ ◎ ◎ ◎ ◎
25 ℃ ○ ○ ○ ○ ◎ ◎
45 ℃ ○ ○ ○ ○ ○ ◎
상기 표 2에서 나타낸 바와 같이, 폴리아미드계 겔화제와 아미노산계 겔화제를 혼합하여 사용 처방한 화장료가 투명도와 안정성에 있어서 매우 양호한 결과를 나타냈다. As shown in Table 2, the cosmetics prescribed by mixing the polyamide gelling agent and the amino acid gelling agent showed very good results in transparency and stability.
실시예2 : 투명 스틱형 자외선 차단용 화장료 조성물의 SPF 측정Example 2: SPF measurement of the transparent stick-type sunscreen cosmetic composition
SPF-2999 analyzer 기계를 이용하여 메뉴얼에 제공된 방법에 따라 SPF 측정 판에 2mg/cm2를 펴발라 준 후 자외선차단지수를 측정하였다.The SPF-2999 analyzer was used to spread 2 mg / cm 2 onto the SPF measuring plate according to the method provided in the manual, and then the UV blocking index was measured.
표 3
비교예 1 비교예 2 비교예 3 비교예 4 비교예 5 실시예
자외선차단지수 A + + - ++ ++ ++
자외선차단지수 B 15 29 40 36 37 37
TABLE 3
Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example
UV Protection Index A + + - ++ ++ ++
UV Protection Index B 15 29 40 36 37 37
상기 표 3에서 확인할 수 있는 것처럼, 유기자외선차단제의 종류 및 함량에 따라서 자외선 차단지수에 차이가 생기는 것을 알 수 있으며, 실시예의 경우에는 자외선차단지수 A 및 B에서 우수한 값이 나왔음을 확인할 수 있었다.As can be seen in Table 3, it can be seen that the difference in the UV blocking index according to the type and content of the organic UV blocking agent, in the case of the embodiment was confirmed that the excellent values in the UV blocking index A and B.
실시예3 : 제형 탄성감 및 발림성, 사용감 평가Example 3 Evaluation of Formulation Elasticity and Application, and Usability
상기 비교예 1 내지 5 및 본원 발명의 실시예에서 제조한 메이크업 화장료 조성물의 탄성감과 발림성, 사용감에 대하여 패널 20명(25 ~ 45세의 여성)이 비교 평가하여, 그 결과를 하기 표 4에 나타내었다. 이때, 가장 좋지 않은 평가 점수를 1로 하고 가장 좋은 평가 점수를 9로 하는 점수 법을 사용하여 평가하였다.Twenty panelists (women aged 25 to 45 years) compared and evaluated the elasticity, applicability, and usability of the makeup cosmetic compositions prepared in Examples 1 to 5 and Examples of the present invention, and the results are shown in Table 4 below. It was. At this time, the worst evaluation score was 1 and the best evaluation score was 9 using a scoring method.
표 4
비교예 1 비교예 2 비교예 3 비교예 4 비교예 5 실시예
탄성감 3.1 3.2 3.0 4.0 9.0 9.0
발림성 7.8 7.0 7.4 8.2 8.5 8.7
사용감 7.7 7.4 7.3 7.8 7.9 8.4
지속성 7.4 7.4 7.3 7.2 7.5 7.8
Table 4
Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example
Elasticity 3.1 3.2 3.0 4.0 9.0 9.0
Application 7.8 7.0 7.4 8.2 8.5 8.7
Feeling 7.7 7.4 7.3 7.8 7.9 8.4
Persistence 7.4 7.4 7.3 7.2 7.5 7.8
상기 표 4에서 나타낸 바와 같이, 폴리아미드계 겔화제와 아미노산계 겔화제를 혼합하여 사용 처방한 화장료가 비교예에 비해서 탄성감이나 발림성, 사용감에서 전체적으로 높게 평가되었다.As shown in Table 4, the cosmetics prescribed by mixing the polyamide gelling agent and the amino acid gelling agent were generally evaluated in terms of elasticity, spreadability, and usability as compared with the comparative example.
화장료의 발림성 결과, 실시예의 경우가 비교예 1 내지 3보다 높게 평가된 것은 화장료의 탄성감이 좋아 피부 도포 시 부드럽게 도포되는 이유로 높게 평가된 것으로 판단되며, 비교예 5의 경우는 탄성감은 좋으나 내용물의 경도가 낮아 쉽게 부러지는 단점이 있다. 사용감 평가는 비교예 1 내지 5의 경우 매끄럽게 발리기는 하나, 내용물이 쪼개지거나 부서지는 현상이 있었고, 실시예의 경우에는 점도가 낮은 에스테르 오일과 폴리아미드계 겔화제가 피부에 가볍고 얇게 피막형성을 하면서 밀착력이 우수하여 사용감 및 지속성이 높게 평가된 것으로 판단된다.As a result of the applicability of the cosmetics, it was judged that the Example was evaluated higher than Comparative Examples 1 to 3 because the elasticity of the cosmetic was good and it was judged to be high because it was smoothly applied when the skin was applied. Low hardness has the disadvantage of easily broken. In the evaluation of the feeling of use, in the case of Comparative Examples 1 to 5, but smoothly applied, there was a phenomenon that the contents are split or broken, in the case of the example, a low viscosity ester oil and a polyamide gelling agent lightly and thinly formed on the skin while the adhesion It is judged to be highly evaluated for its feeling of use and durability.
실시예4 : 충진 용이성 평가Example 4 Evaluation of Filling Ease
상기 비교예 1 내지 5 및 본원 발명의 실시예에서 제조한 메이크업 화장료 조성물의 충진온도를 하기 표 5에 나타내었다. 비교예 1 내지 3의 경우에는 125 ~ 130℃ 부근으로 충진온도가 높기 때문에 내용물을 녹이는 데 걸리는 시간과 충진조건을 조절하기가 어렵다. 반면, 비교예 4 내지 5와 본원 발명의 실시예는 90 ~ 100 ℃ 부근으로 충진온도가 비교예 1 내지 3의 경우보다 낮기 때문에, 비교적 쉽게 내용물을 녹이고 충진하기가 용이하다.Filling temperatures of the makeup cosmetic compositions prepared in Comparative Examples 1 to 5 and Examples of the present invention are shown in Table 5 below. In Comparative Examples 1 to 3, since the filling temperature is high around 125 to 130 ° C., it is difficult to control the time and filling conditions for melting the contents. On the other hand, Comparative Examples 4 to 5 and the Examples of the present invention, since the filling temperature is lower than the case of Comparative Examples 1 to 3 in the vicinity of 90 ~ 100 ℃, it is easy to melt and fill the contents relatively easily.
표 5
비교예 1 비교예 2 비교예 3 비교예 4 비교예 5 실시예
충진온도(℃) 125~130 125~130 125~130 90~95 0~95 95~100
Table 5
Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example
Filling temperature (℃) 125-130 125-130 125-130 90-95 0-95 95-100
상기 실험의 결과 본 발명의 투명 스틱형 자외선 차단용 화장료 조성물은 투명성, 안정성, 발림성, 충진조건 등 전반적인 만족도 측면에서, 비교예들에 비하여 훨씬 우수한 것임을 알 수 있다.As a result of the experiment, it can be seen that the transparent stick-type sunscreen cosmetic composition of the present invention is far superior to the comparative examples in terms of overall satisfaction such as transparency, stability, spreadability, and filling conditions.
이상에서 설명한 본 발명은 단지 본 발명의 예시적인 것으로서, 이는 단지 본 발명을 설명하기 위한 목적에서 사용된 것이지 의미 한정이나 특허청구범위에 기재된 본 발명의 범위를 제한하기 위하여 사용된 것은 아니다. 그러므로 본 기술 분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 이해할 것이다. 따라서 본 발명의 진정한 기술적 보호 범위는 첨부된 특허청구범위의 기술적 사상에 의해 정해져야 할 것이다.The present invention described above is merely exemplary of the present invention, which is used only for the purpose of illustrating the present invention, and is not used to limit the scope of the present invention described in the meaning or claims. Therefore, those skilled in the art will understand that various modifications and equivalent other embodiments are possible from this. Therefore, the true technical protection scope of the present invention will be defined by the technical spirit of the appended claims.
이상 설명한 바와 같이, 본 발명에 따르면 폴리아미드계 겔화제, 아미노산계 겔화제, 유기자외선차단제 및 오일을 함유하는 투명 스틱형 자외선 차단용 화장료 조성물은 탄성감을 주어 피부에 도포 시 부서지는 현상을 개선하면서 발림성이 우수하고 부드러운 사용감을 주며 발한 현상을 최소화 하며 투명성을 유지하면서도 충진시 용이한 이점이 있기 때문에 이러한 장점을 갖춘 투명 스틱형 자외선 차단제의 화장료 조성물로 활용할 수 있다.As described above, according to the present invention, a transparent stick type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid gelling agent, an organic ultraviolet ray shielding agent and an oil gives elasticity and improves the phenomenon of being broken when applied to the skin. It can be used as a cosmetic composition of a transparent stick type sunscreen with such advantages because it has excellent applicability, gives a soft feeling, minimizes sweating, and maintains transparency and is easy to fill.

Claims (11)

  1. 폴리아미드계 겔화제, 아미노산계 겔화제, 유기자외선차단제 및 오일을 함유하는 투명 스틱형 자외선 차단용 화장료 조성물.A transparent stick-type sunscreen cosmetic composition containing a polyamide gelling agent, an amino acid gelling agent, an organic ultraviolet ray shielding agent and an oil.
  2. 제 1항에 있어서, 상기 폴리아미드계 겔화제는 제3급-아미드-말단 폴리아미드 공중합체류(ATPA) 겔화제인 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물.The cosmetic composition of claim 1, wherein the polyamide gelling agent is a tertiary-amide-terminated polyamide copolymer (ATPA) gelling agent.
  3. 2항에 있어서, 상기 제3급-아미드-말단 폴리아미드 공중합체류(ATPA) 겔화제는 에칠렌디아민/하이드로제네이티드 다이머 디리놀리에이트 코폴리머 비스-디-C14-C18 알킬 아민(Ethylenediamine/hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine)인 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물. 3. The tertiary-amide-terminated polyamide copolymers (ATPA) gelling agent of claim 2 is an ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-C18 alkyl amine (Ethylenediamine / hydrogenated dimer dilinoleate). Copolymer bis-di-C14-C18 alkyl amine), characterized in that the transparent stick-type sunscreen cosmetic composition.
  4. 제 1항에 있어서, 상기 폴리아미드계 겔화제는 10 ~ 50중량% 함유하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물.The cosmetic composition of claim 1, wherein the polyamide gelling agent is contained in an amount of 10 to 50% by weight.
  5. 제 1항에 있어서, 상기 아미노산계 겔화제는 디부틸에칠헥사노일글루타마이드 및 디부틸라우로일글루타마이드인 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물.The cosmetic composition of claim 1, wherein the amino acid gelling agent is dibutylethylhexanoylglutamide and dibutyllauroylglutamide.
  6. 제 1항에 있어서, 상기 아미노산계 겔화제는 0.1 ~ 10중량% 함유하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물.The cosmetic composition of claim 1, wherein the amino acid gelling agent is contained in an amount of 0.1 to 10% by weight.
  7. 제 1항에 있어서, 유기자외선차단제는 글리세릴파바, 드로메트리졸, 디갈로일트리올레이트, 3-(4-메칠벤질리덴)-캄파, 메틸안트라닐레이트, 디에칠아미노하이드록시벤조일헥실벤조에이트, 벤조페논-3, 벤조페논-4, 벤조페논-8, 부틸메톡시디벤조일메탄, 시녹세이트, 에칠헥실트리아존, 옥토크릴렌, 옥틸디메칠파바, 에칠헥실메톡시신나메이트, 에칠헥실살리실레이트, 파라아미노안식향산, 2-페닐벤즈이미다졸-5-설폰산, 호모살레이트, 이소아밀-p-메톡시신신나메이트, 비스에칠헥실옥시페놀메톡시페닐트리아진, 드로메트리졸트리실록산, 및 폴리실리콘-15 로 이루어진 군으로부터 선택되는 1종 이상인 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물. The method of claim 1, wherein the organic sunscreen agent is glyceryl pava, drrometrizole, digaloyltrioleate, 3- (4-methylbenzylidene) -campa, methyl anthranilate, diethylaminohydroxybenzoylhexylbenzo Eate, Benzophenone-3, Benzophenone-4, Benzophenone-8, Butylmethoxydibenzoylmethane, Synoxate, Ethyl hexyltriazone, Octocrylene, Octyl dimethyl fava, Ethyl hexyl methoxy cinnamate, Ethyl hexyl sal Lysylate, paraaminobenzoic acid, 2-phenylbenzimidazole-5-sulfonic acid, homosalate, isoamyl-p-methoxycinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, dromethazole trisiloxane And, and polysilicone-15 transparent stick-type sunscreen cosmetic composition, characterized in that at least one member selected from the group consisting of.
  8. 제 7항에 있어서, 상기 유기자외선차단제는 2 ~ 90중량% 함유하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물. 8. The transparent stick type sunscreen cosmetic composition according to claim 7, wherein the organic UV blocker contains 2 to 90% by weight.
  9. 제 1항에 있어서, 상기 오일성분은 에스테르 계열의 오일, 탄화수소계 오일, 식물성 오일 및 이들의 혼합물로 이루어진 군으로부터 선택된 1종 이상으로 구성되는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물.According to claim 1, wherein the oil component is a transparent stick type sunscreen cosmetic composition, characterized in that composed of one or more selected from the group consisting of ester-based oils, hydrocarbon-based oils, vegetable oils and mixtures thereof.
  10. 제 9항에 있어서, 상기 오일성분은 2 ~ 80중량%를 함유하는 것을 특징으로 하는 투명 스틱형 자외선 차단용 화장료 조성물.10. The transparent stick-type sunscreen cosmetic composition according to claim 9, wherein the oil component contains 2 to 80 wt%.
  11. 제 1항에 있어서, 상기 화장료 조성물은 기타 오일성분이나 알코올류, 보존제, 착색제, 착향제, 미용영양성분으로부터 선택되는 1종 이상의 성분을 더 포함하는 것을 특징으로 하는 투명 스틱형 자외선 차다용 화장료 조성물.The cosmetic composition of claim 1, wherein the cosmetic composition further comprises one or more components selected from other oil components, alcohols, preservatives, colorants, flavoring agents, and cosmetic nutritional components. .
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