JP6503008B2 - Transparent oily solid cosmetic - Google Patents
Transparent oily solid cosmetic Download PDFInfo
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- JP6503008B2 JP6503008B2 JP2017106401A JP2017106401A JP6503008B2 JP 6503008 B2 JP6503008 B2 JP 6503008B2 JP 2017106401 A JP2017106401 A JP 2017106401A JP 2017106401 A JP2017106401 A JP 2017106401A JP 6503008 B2 JP6503008 B2 JP 6503008B2
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
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Description
本発明は、油性固形化粧料に関する。 The present invention relates to an oily solid cosmetic.
油性固形化粧料は、従来、それぞれの用途目的に応じて様々な物性のものが研究開発されている。 Conventionally, oily solid cosmetics have been researched and developed with various physical properties depending on the purpose of each use.
特許文献1には、アミノ酸系ゲル化剤としてジブチルラウロイルグルタミド(GP−1)およびジブチルエチルヘキサノイルグルタミド(EB−21)、ならびにポリアミド樹脂を含む化粧料が開示されており、アミノ酸ゲル化剤単品を用いた化粧品の脆性をポリアミド樹脂との併用により改善することができること、またそれにより使用感、保存安定性に優れた化粧品を提供できることが記載されている。 Patent Document 1 discloses a cosmetic containing dibutyl lauroyl glutamide (GP-1) and dibutyl ethyl hexanoyl glutamide (EB-21) as an amino acid based gelling agent, and a polyamide resin. It is described that the brittleness of cosmetics using a single agent can be improved by using in combination with a polyamide resin, and that it is also possible to provide cosmetics excellent in feeling in use and storage stability.
また、特許文献2には、ジブチルラウロイルグルタミド(GP−1)およびジブチルエチルヘキサノイルグルタミド(EB−21)を混合したゲル化剤が開示されており、このゲル化剤が優れたゲル強度と透明性を有するゲル状組成物を製造できるゲル化剤であることが記載されている。 Further, Patent Document 2 discloses a gelling agent in which dibutyl lauroyl glutamide (GP-1) and dibutyl ethyl hexanoyl glutamide (EB-21) are mixed, and the gel strength of this gelling agent is excellent. It is described that it is a gelling agent capable of producing a gel-like composition having transparency.
また、特許文献3には、トリシクロ[5.2.1.02,6]デカンのエステル化合物が開示され、優れた発汗抑制力および使用感を有する化合物であることが記載されている。 Further, Patent Document 3, tricyclo [5.2.1.0 2, 6] ester compound decane is disclosed, it is described that a compound having an excellent antiperspirant power and usability.
また、特許文献4には、ポリアミド系ゲル化剤、アミノ酸系ゲル化剤および有機日焼け止めとオイルを含有する透明スティック型紫外線遮断用化粧料組成物が開示されており、具体的にはポリアミドゲル化剤としてビスアルキル(C14−18)アミド(エチレンジアミン/水添ダイマージリノール酸)コポリマー、アミノ酸系ゲル化剤としてジブチルエチルヘキサノイルグルタミドおよびジブチルラウロイルグルタミドが用いられている。 Patent Document 4 discloses a transparent stick type ultraviolet blocking cosmetic composition containing a polyamide gelling agent, an amino acid gelling agent, an organic sunscreen and an oil, and more specifically, a polyamide gel Bisalkyl (C14-18) amide (ethylenediamine / hydrogenated dimer dilinoleic acid) copolymer is used as an agent, and dibutylethyl hexanoyl glutamide and dibutyl lauroyl glutamide are used as an amino acid based gelling agent.
また、特許文献5には、ジブチルラウロイルグルタミド(GP−1)やジブチルエチルヘキサノイルグルタミド(EB−21)などのN−アシルアミノ酸誘導体、ポリアミド樹脂ならびに液状油分を含む固化されて口唇用の棒状製剤となる油性組成物が開示されている。
しかし油性固形化粧料として、透明性に優れ、経時変化による発汗がなく、保存安定性に優れるという各点において十分に満足できる油性固形化粧料はこれまでのところ存在しない。
In addition, Patent Document 5 discloses that N-acylamino acid derivatives such as dibutyl lauroyl glutamide (GP-1) and dibutyl ethyl hexanoyl glutamide (EB-21), polyamide resin, and liquid oil component are solidified for the lip There is disclosed an oily composition which becomes a rod-like preparation.
However, no oily solid cosmetic has been available which is sufficiently satisfactory as an oily solid cosmetic in each point of excellent transparency, no perspiration due to aging, and excellent storage stability.
したがって、本発明の課題は、透明性に優れ、かつ発汗性のない透明油性固形化粧料を提供することにある。さらに、本発明の別の課題は、使用感に優れた油性固形化粧料を提供することにある。 Therefore, an object of the present invention is to provide a transparent oily solid cosmetic which is excellent in transparency and not sweating. Furthermore, another object of the present invention is to provide an oily solid cosmetic composition excellent in feeling in use.
本発明者らは、上記課題を解決すべく検討を行う中で、優れた透明性と低い発汗性を両立できる油性固形化粧料を製造することは、従来の素材を適宜選択するだけでは困難であるという問題に直面した。かかる問題を解決すべくさらに検討を重ねたところ、透明ゲル化剤に対し、屈折率が高い油剤と体積膨張率が低い油剤とを組み合わせることにより、透明性が高く、かつ発汗性が低い油性固形化粧料を得ることができることを見出し、本発明を完成するに至った。 The present inventors are studying to solve the above-mentioned problems, and it is difficult to produce an oily solid cosmetic that can achieve both excellent transparency and low perspiration, simply by appropriately selecting conventional materials. I was faced with the problem of being there. Further investigations were made to solve the problem, and it was found that an oily solid having high transparency and low sweating property is obtained by combining a transparent gelling agent with an oil agent having a high refractive index and an oil agent having a low volume expansion coefficient. It has been found that cosmetics can be obtained, and the present invention has been completed.
すなわち、本発明は以下に関する。
[1]透明ゲル化剤、20℃における屈折率が1.460以上である油剤、および体積膨張率が0.065%/℃以下である油剤を含む、透明油性固形化粧料。
[2]透明ゲル化剤が、ジブチルラウロイルグルタミドおよび/またはジブチルエチルヘキサノイルグルタミドを含む、[1]に記載の透明油性固形化粧料。
[3]ジブチルラウロイルグルタミドの含有量が、2.0〜7.0重量%である、[2]に記載の透明油性固形化粧料。
[4]ジブチルエチルヘキサノイルグルタミドの含有量が、0.5〜5.0重量%である、[2]または[3]に記載の透明油性固形化粧料。
[5]さらにイソステアリン酸を含む、[1]〜[4]のいずれかに記載の透明油性固形化粧料。
[6]20℃における屈折率が1.460以上である油剤の含有量が、20〜80重量%である、[1]〜[5]のいずれかに記載の透明油性固形化粧料。
[7]体積膨張率が0.065以下である油剤の含有量が、10〜50重量%である、[1]〜[6]のいずれかに記載の透明油性固形化粧料。
[8]さらに12−ヒドロキシステアリン酸を含む、[1]〜[7]のいずれかに記載の透明油性固形化粧料。
[9]12−ヒドロキシステアリン酸の含有量が、2.0〜10.0重量%である、[8]に記載の透明油性固形化粧料。
[10]20℃における屈折率が1.460以上である油剤が、イソノナン酸トリシクロデカンメチルである、[1]〜[9]のいずれかに記載の透明油性固形化粧料。
[11]体積膨張率が0.065以下である油剤が、イソノナン酸イソトリデシルまたはネオペンタン酸イソデシルである、[1]〜[10]のいずれかに記載の透明油性固形化粧料。
[12]20℃における屈折率が1.460以上である油剤と体積膨張率が0.065以下である油剤の重量%における成分比が10:1〜1:1である、[1]〜[11]のいずれかに記載の透明油性固形化粧料。
That is, the present invention relates to the following.
[1] A transparent oily solid cosmetic comprising a transparent gelling agent, an oil agent having a refractive index of 1.460 or more at 20 ° C., and an oil agent having a volume expansion coefficient of 0.065% / ° C. or less.
[2] The transparent oily solid cosmetic according to [1], wherein the transparent gelling agent comprises dibutyl lauroyl glutamide and / or dibutyl ethyl hexanoyl glutamide.
[3] The transparent oily solid cosmetic according to [2], wherein the content of dibutyl lauroyl glutamide is 2.0 to 7.0% by weight.
[4] The transparent oily solid cosmetic according to [2] or [3], wherein the content of dibutylethylhexanoylglutamide is 0.5 to 5.0% by weight.
[5] The transparent oily solid cosmetic according to any one of [1] to [4], further comprising isostearic acid.
[6] The transparent oily solid cosmetic according to any one of [1] to [5], wherein the content of the oil agent having a refractive index of 1.460 or more at 20 ° C. is 20 to 80% by weight.
[7] The transparent oily solid cosmetic according to any one of [1] to [6], wherein the content of the oil agent having a volume expansion coefficient of 0.065 or less is 10 to 50% by weight.
[8] The transparent oily solid cosmetic according to any one of [1] to [7], further containing 12-hydroxystearic acid.
[9] The transparent oily solid cosmetic according to [8], wherein the content of 12-hydroxystearic acid is 2.0 to 10.0% by weight.
[10] The transparent oily solid cosmetic according to any one of [1] to [9], wherein the oil agent having a refractive index of 1.460 or more at 20 ° C is tricyclodecanemethyl isononanoate.
[11] The transparent oily solid cosmetic according to any one of [1] to [10], wherein the oil agent having a volume expansion coefficient of 0.065 or less is isotridecyl isononanoate or isodecyl neopentanoate.
[12] [1] to [1], the component ratio in weight% of the oil having a refractive index of 1.460 or more at 20 ° C. and the oil having a volume expansion coefficient of 0.065 or less [1] to [1] 11] The transparent oily solid cosmetic according to any one of the above.
本発明は、透明ゲル化剤と、屈折率が高い油剤と体積膨張率が低い油剤との組み合わせ油剤により、例えばリップスティック、ヘアチック、サンケア製品などの油性固形化粧料において、透明性に優れ、且つ発汗性がなく保存安定性が高い、さらには塗り伸ばしやすくべたつきの少ない、使用感の良い新たな透明油性固形化粧料を提供することができる。屈折率が高い油剤と体積膨張率が低い油剤との組み合わせ油剤による高い透明性と低い発汗性の効果についてのメカニズムは必ずしも明らかではないが、体積膨張率の低い油剤が有する温度の影響を受けにくい性質が低い発汗性に関係していると推測される。
本発明は、油性固形化粧料として必要とされる量の当該油剤が含まれる限り所期の効果を奏する保存安定性の高い、透明な油性固形化粧料を製造することができる。
The present invention is a combination of a transparent gelling agent, an oil agent having a high refractive index and an oil agent having a low volume expansion coefficient, for example, in oil-based solid cosmetics such as lipsticks, hair tics and sun care products, excellent in transparency and It is possible to provide a new transparent oily solid cosmetic which has no perspiration property, high storage stability, and is easy to spread and stick and has a good feeling of use. The combination of oil with high refractive index and oil with low volume expansion: The mechanism for the high transparency and low sweating effect of the oil is not always clear, but it is not susceptible to the temperature of oil with low volume expansion It is speculated that the nature is related to low sweating.
The present invention can produce a clear, oil-based solid cosmetic having high storage stability that exhibits the desired effect as long as the required amount of the oil agent is contained as an oily solid cosmetic.
特に、本発明の20℃における屈折率が1.460以上である油剤、および体積膨張率が0.065以下である油剤を選択しこれらを組み合わせて用いることにより、透明で且つ発汗性が低い高品質な化粧料を提供する。なお、かかる屈折率と体積膨張率の条件を同時に満たす油剤であれば単一の油剤であってもよいことは言うまでもない。 In particular, by selecting and using the oil agent having a refractive index of 1.460 or more at 20 ° C. and the oil agent having a volume expansion coefficient of 0.065 or less according to the present invention, high transparency and low sweating property can be obtained. Provide quality cosmetics. Needless to say, a single oil may be used as long as it satisfies the conditions of the refractive index and the volume expansion coefficient simultaneously.
以下、本発明について、本発明の好適な実施態様に基づき、詳細に説明する。
本発明の透明油性固形化粧料は、ボディ、フェイス、ヘア等のために用いられる化粧料である。
Hereinafter, the present invention will be described in detail based on preferred embodiments of the present invention.
The transparent oily solid cosmetic composition of the present invention is a cosmetic composition used for body, face, hair and the like.
本発明において、「固形化粧料」とは、常温(25℃)において固形形状を保持し得る化粧料である。
本発明において「化粧料」とは、特に、限定されないが、ボディケア製品、スキンケア製品、メーキャップ製品、ヘアケア製品、フレグランス製品などの製造に用いることができる材料である。
ボディケア製品としては、UVケア製品、デオドラント製品、ボディ用スキンケア製品、ボディ用フレグランス製品、ボディ用クレンジング製品などが挙げられるが、これらに限定されない。
スキンケア製品としては、クレンジング製品、洗顔料、美白化粧品、UVケア化粧品、アンチエイジング製品などが挙げられるが、これらに限定されない。
メーキャップ製品としては、ファンデーション、リップカラー、リップスティック、リップクリーム、アイライナーなどが挙げられるが、これらに限定されない。
ヘアケア製品としては、ヘアスタイリングワックス、ヘアチック、ヘアトリートメント剤、ワンデーヘアカラー剤、ヘアグロスなどが挙げられるがこれらに限定されない。
フレグランス製品としては、香水、オードトワレ、オーデコロン、オードパルファム、ロールオンタイプのフレグランス、スティックタイプの練り香水などが挙げられるがこれらに限定されない。
In the present invention, the “solid cosmetic” is a cosmetic which can maintain its solid form at normal temperature (25 ° C.).
In the present invention, "cosmetics" is a material that can be used to manufacture, but not limited to, body care products, skin care products, makeup products, hair care products, fragrance products and the like.
Body care products include, but are not limited to, UV care products, deodorant products, body skin care products, body fragrance products, body cleansing products, and the like.
Skin care products include but are not limited to cleansing products, face cleansers, whitening cosmetics, UV care cosmetics, anti-aging products and the like.
Makeup products include, but are not limited to, foundations, lip colors, lipsticks, lip balms, eyeliners, and the like.
Hair care products include, but are not limited to, hair styling waxes, hairtics, hair treatment agents, one day hair coloring agents, hair gloss and the like.
Fragrances products include, but are not limited to, perfumes, eau de toilette, eau de cologne, eau de parfum, roll-on fragrances, stick-type kneading perfumes and the like.
本発明において「透明」とは、固形化粧料が完全に不透明ではないことを意味し、後に示す透過率60%以上の場合を良好な透明性とした。 In the present invention, "transparent" means that the solid cosmetic is not completely opaque, and the case of the transmittance of 60% or more shown later is regarded as good transparency.
以下の表1に、化粧品業界で用いられる油剤の体積膨張率を示す。
上記のとおり、化粧品業界で用いられる多くの油剤の体積膨張率が通常0.07〜0.08%/℃程度であるのに対し、本発明では体積膨張率が0.065%/℃以下である油剤に着目し、これらを用いることによりその発汗性を抑えることができることを見出した。これは体積膨張率が低い油剤は温度の影響を受けにくいことに由来し、発汗を抑制できたものと考えられる。また、体積膨張率が0.065%/℃以下である油剤を用いたのみでは透明性を維持できないというさらなる課題の解決のため、さらに研究を進めた結果、上記油剤と共に高屈折率、具体的には20℃における屈折率が1.460以上である油剤、好ましくは1.460を超える油剤、さらに好ましくは1.465以上である油剤、最も好ましくは1.470以上の油剤を用いることにより、高い透明性を維持し、且つ発汗性が低く保存安定性の良い固形化粧料が得られることを見出し、本発明を完成するに至った。また、さらに12−ヒドロキシステアリン酸を加えることにより、より発汗性を抑えた透明固形化粧料を得るに至った。 As described above, the volume expansion of many oils used in the cosmetics industry is usually about 0.07 to 0.08% / ° C., whereas the volume expansion of the present invention is 0.065% / ° C. or less. Focusing on a certain oil, it has been found that it is possible to suppress its sweating by using these. It is considered that this is because the oil having a low volume expansion coefficient is less susceptible to temperature, and that sweating can be suppressed. In addition, as a result of further research to solve the further problem that transparency can not be maintained only by using an oil agent having a volume expansion coefficient of 0.065% / ° C. or less, high refractive index with the above-mentioned oil agent, concrete By using an oil agent having a refractive index of 1.460 or more at 20 ° C., preferably an oil agent having a refractive index of 1.460 or more, more preferably an oil agent having a refractive index of 1.465 or more, most preferably 1.470 or more It has been found that a solid cosmetic composition can be obtained which maintains high transparency and is low in sweating ability and storage stability and thus the present invention has been completed. Further, by adding 12-hydroxystearic acid, it became possible to obtain a transparent solid cosmetic with further suppressed sweating property.
本発明における20℃における屈折率は、Anton Paar社製RXA−170を用いて測定した。
以下の表2に、化粧品業界で用いられる油剤の20℃における屈折率を示す。
Table 2 below shows the refractive index at 20 ° C. of the oil used in the cosmetic industry.
20℃における屈折率が1.460以上である油剤の含有量は、好ましくは20〜80重量%、より好ましくは、25〜80重量%、最も好ましくは30〜80重量%である。
また、20℃における屈折率が1.460以上である油剤の20℃における屈折率は、1.460を超えるのが好ましく、1.465以上がより好ましく、1.470以上がさらに好ましい。
The content of the oil having a refractive index of 1.460 or more at 20 ° C. is preferably 20 to 80% by weight, more preferably 25 to 80% by weight, and most preferably 30 to 80% by weight.
The refractive index at 20 ° C. of the oil having a refractive index of 1.460 or more at 20 ° C. preferably exceeds 1.460, more preferably 1.465 or more, and still more preferably 1.470 or more.
本発明における体積膨張率は、液の温度が10〜50℃における比体積(m3/kg)を振動式密度計Anton Paar社製 DMA−4500Mを用いて各々測定し、1℃あたりの体積膨張率を%/℃の単位を用いて示した。
本発明における体積膨張率が0.065%/℃以下である油剤としては、限定されないが、イソノナン酸エチルヘキシル、イソノナン酸イソトリデシル、イソノナン酸イソノニルまたはネオペンタン酸イソデシルを用いることができ、好ましくはイソノナン酸イソトリデシルを用いることができる。
The volume expansion coefficient in the present invention is measured by measuring the specific volume (m 3 / kg) of the solution at a temperature of 10 to 50 ° C. using a vibrating densitometer, DMA-4500M manufactured by Anton Paar, and the volume expansion per 1 ° C. The percentages are expressed in% / ° C. units.
Examples of the oil agent having a volume expansion coefficient of 0.065% / ° C. or less in the present invention include, but are not limited to, ethylhexyl isononanoate, isotridecyl isononanoate, isononyl isononanoate or isodecyl neononate, preferably isotridecyl isononanoate. Can be used.
体積膨張率が0.065%/℃以下である油剤の含有量は、好ましくは10〜50重量%、より好ましくは10〜40重量%、最も好ましくは10〜30重量%である。
また、体積膨張率が0.065%/℃以下である油剤の体積膨張率は、0.060%/℃以下であることが好ましく、0.055%/℃以下がさらに好ましい。
The content of the oil agent having a volume expansion coefficient of 0.065% / ° C. or less is preferably 10 to 50% by weight, more preferably 10 to 40% by weight, and most preferably 10 to 30% by weight.
The volume expansion coefficient of the oil agent having a volume expansion coefficient of 0.065% / ° C. or less is preferably 0.060% / ° C. or less, and more preferably 0.055% / ° C. or less.
本発明において、油剤としては、20℃における屈折率が1.460以上である油剤および体積膨張率が0.065%/℃以下である油剤が含まれるが、その他の油剤もまた含むことができる。
その他の油剤としては、限定されないが、イソステアリン酸イソステアリル、ヘキサイソノナン酸ジペンタエリスリチル、イソステアリン酸ヘキシルデシル、イソステアリルアルコール、デシルテトラデカノール、ヒドロキシステアリン酸エチルヘキシル、イソステアリン酸、ミリスチン酸オクチルドデシル、ステアリン酸イソセチル、オクチルドデカノール、スクワラン、ミリスチン酸イソセチル、イソステアリルアルコール、トリ(カプリル酸/カプリン酸)グリセリル、トリエチルヘキサン酸トリメチルプロパン、ヘキシルデカノール、イソステアリン酸エチル、パルミチン酸エチルヘキシル、コハク酸ビスエトキシジグリコール、イソステアリン酸イソブチル、ネオペンタン酸イソステアリル、ジカプリン酸ネオペンチルグリコール、トリエチルヘキサノイン、イソステアリン酸イソプロピル、エチルヘキサン酸ヘキシルデシル、コハク酸ジエチルヘキシル、エチルヘキサン酸セチル、ジイソノナン酸ネオペンチルグリコール、イソノナン酸イソデシル、ジエチルヘキサン酸ネオペンチルグリコール、ラウリン酸ヘキシル、パルミチン酸イソプロピル、イソノナン酸イソノニル、ミスチリン酸イソプロピル、アジピン酸ジイソブチル、ネオペンタン酸イソデシル、ジメチコンを用いることができる。
In the present invention, the oil agent includes an oil agent having a refractive index of 1.460 or more at 20 ° C. and an oil agent having a volume expansion coefficient of 0.065% / ° C. or less, but other oil agents may also be contained. .
Other oil agents include, but are not limited to, isostearyl isostearate, dipentaerythrityl hexaisononanoate, hexyl decyl isostearate, isostearyl alcohol, decyl tetradecanol, ethylhexyl hydroxystearate, isostearic acid, octyldodecyl myristate, isocetyl stearate , Octyl dodecanol, squalane, isocetyl myristate, isostearyl alcohol, glyceryl tri (caprylic acid / capric acid), trimethylpropane triethylhexanoate, hexyl decanol, ethyl isostearate, ethylhexyl palmitate, bisethoxy diglycol succinate, isostearic acid Isobutyl, isostearyl neopentanoate, neopentyl glycol dicaprate Triethylhexanoin, isopropyl isostearate, hexyldecyl ethylhexanoate, diethylhexyl succinate, cetyl ethylhexanoate, neopentyl glycol diisononanoate, isodecyl isononanoate, neopentyl glycol diethylhexanoate, hexyl laurate, isopropyl palmitate, isononane Isononyl acid, isopropyl myristate, diisobutyl adipate, isodecyl neopentanoate, dimethicone can be used.
本発明における透明ゲル化剤としては、限定されないが、ジブチルラウロイルグルタミド(GP−1)および/またはジブチルエチルヘキサノイルグルタミド(EB−21)等を含むアミノ酸系ゲル化剤、ポリアミド樹脂を用いることができ、好ましくはジブチルラウロイルグルタミド(GP−1)および/またはジブチルエチルヘキサノイルグルタミド(EB−21)等を含むアミノ酸系ゲル化剤、さらに好ましくはジブチルラウロイルグルタミド(GP−1)および/またはジブチルエチルヘキサノイルグルタミド(EB−21)を用いることができる。 As the transparent gelling agent in the present invention, an amino acid based gelling agent including, but not limited to, dibutyl lauroyl glutamide (GP-1) and / or dibutyl ethyl hexanoyl glutamide (EB-21), etc., and polyamide resin are used. Amino acid based gelling agent containing preferably dibutyl lauroyl glutamide (GP-1) and / or dibutyl ethyl hexanoyl glutamide (EB-21), etc., more preferably dibutyl lauroyl glutamide (GP-1) And / or dibutyl ethyl hexanoyl glutamide (EB-21) can be used.
ジブチルラウロイルグルタミド(GP−1)やジブチルエチルヘキサノイルグルタミド(EB−21)を含む場合においても、油性固形化粧料として必要とされる量の当該油剤が含まれる限り所期の効果を奏する保存安定性の高い、透明な油性固形化粧料を製造することができる。
ジブチルラウロイルグルタミド(GP−1)を含む場合において、その含有量は化粧料全体に対して、好ましくは1.0〜10.0重量%、より好ましくは2.0〜8.0重量%、最も好ましくは2.0〜7.0重量%である。
Even in the case of containing dibutyl lauroyl glutamide (GP-1) or dibutyl ethyl hexanoyl glutamide (EB-21), the desired effect can be obtained as long as the required amount of the oil agent is included as an oily solid cosmetic. It is possible to produce a transparent oily solid cosmetic having high storage stability.
When dibutyl lauroyl glutamide (GP-1) is contained, its content is preferably 1.0 to 10.0% by weight, more preferably 2.0 to 8.0% by weight, based on the total cosmetic. Most preferably, it is 2.0 to 7.0% by weight.
ジブチルエチルヘキサノイルグルタミド(EB−21)を含む場合において、その含有量は化粧料全体に対して、好ましくは0.5〜10.0重量%、より好ましくは0.5〜7.0重量%、最も好ましくは0.5〜5.0重量%である。 When dibutylethyl hexanoyl glutamide (EB-21) is contained, its content is preferably 0.5 to 10.0% by weight, more preferably 0.5 to 7.0% by weight based on the total cosmetic. %, Most preferably 0.5 to 5.0% by weight.
ジブチルラウロイルグルタミド(GP−1)およびジブチルエチルヘキサノイルグルタミド(EB−21)を含む場合において、その配合比は透過率の観点から定められるところ、その配合比(GP−1:EB−21)は、好ましくは75:25〜25:75であり、より好ましくは75:25〜50:50である。この範囲の配合比率で用いることにより透明性の高い化粧料を製造することができる。 In the case where dibutyl lauroyl glutamide (GP-1) and dibutyl ethyl hexanoyl glutamide (EB-21) are contained, the compounding ratio (GP-1: EB-21) can be determined from the viewpoint of transmittance. Is preferably 75:25 to 25:75, more preferably 75:25 to 50:50. By using it by the compounding ratio of this range, cosmetics with high transparency can be manufactured.
本発明において、溶解剤を用いることによりゲル化剤の調製を温和な条件で行うことができる。溶解剤としては、限定されないが、オクチルドデカノール、セタノール、イソステアリン酸などの高級脂肪酸等を用いることができ、好ましくは、イソステアリン酸などの高級脂肪酸またはオクチルドデカノール、特に好ましくはイソステアリン酸を用いることができる。透明性および利便性の観点から、イソステアリン酸を含む高級脂肪酸を用いるのが特に好ましい。
溶解剤の含有率は、好ましくは5.0〜30.0重量%、より好ましくは5.0〜20.0重量%、最も好ましくは5.0〜17.0重量%である。
In the present invention, the preparation of the gelling agent can be carried out under mild conditions by using a solubilizer. The solubilizer may be, but is not limited to, higher fatty acids such as octyl dodecanol, cetanol, isostearic acid and the like, preferably higher fatty acids such as isostearic acid or octyl dodecanol, particularly preferably isostearic acid. Can. It is particularly preferable to use higher fatty acids including isostearic acid from the viewpoint of transparency and convenience.
The content of the solubilizer is preferably 5.0 to 30.0% by weight, more preferably 5.0 to 20.0% by weight, and most preferably 5.0 to 17.0% by weight.
本発明において、20℃における屈折率が1.460以上である油剤と体積膨張率が0.065以下である油剤の重量%における成分比は、好ましくは10:1〜1:1である。 In the present invention, the component ratio in weight% of an oil having a refractive index of 1.460 or more at 20 ° C. and an oil having a volume expansion coefficient of 0.065 or less is preferably 10: 1 to 1: 1.
本発明における化粧料には、限定されないが、さらに各種添加剤を含むことができる。
各種添加剤とは、防腐剤、抗炎症剤、抗菌剤、抗酸化剤、紫外線吸収剤、制汗剤、ビタミン、香料、着色剤、パール化剤などの装飾剤、美白薬剤、抗老化薬剤、その他油溶性薬剤、その他油溶性成分などを含む、一般的に化粧料に汎用されている公知のあらゆる物質を意味する。
The cosmetic according to the present invention may further include, but is not limited to, various additives.
Various additives include preservatives, anti-inflammatory agents, antibacterial agents, anti-oxidants, ultraviolet absorbers, antiperspirants, vitamins, fragrances, coloring agents, decorative agents such as pearlescent agents, whitening agents, anti-aging agents, The term means any known substance generally used in cosmetics, including other oil-soluble drugs and other oil-soluble ingredients.
以上、本発明について好適な実施態様に基づき詳細に説明したが、本発明はこれらに限定されず、各構成は、同様の機能を発揮し得る任意のものと置換でき、または任意の構成を付加することもできる。 As mentioned above, although the present invention was explained in detail based on a suitable embodiment, the present invention is not limited to these, each composition can be replaced with arbitrary things which can exhibit the same function, or add arbitrary composition. You can also
以下の処方で実施例1〜12、比較例1〜7、および実施例13〜15のスティック型のサンケア化粧料を調製し、透過率、発汗性試験および使用感を評価した。なお、成分(A)はジブチルラウロイルグルタミド、成分(B)はジブチルエチルヘキサノイルグルタミド、成分(C)はイソステアリン酸、成分(D)は20℃における屈折率が1.460以上である油剤、成分(E)は体積膨張率が0.065以下である油剤とした。 The stick-type sun care cosmetics of Examples 1 to 12, Comparative Examples 1 to 7, and Examples 13 to 15 were prepared according to the following formulations, and the transmittance, the sweating test, and the feeling in use were evaluated. Component (A) is dibutyl lauroyl glutamide, component (B) is dibutyl ethyl hexanoyl glutamide, component (C) is isostearic acid, and component (D) is an oil with a refractive index of 1.460 or more at 20 ° C. The component (E) was an oil having a volume expansion coefficient of 0.065 or less.
透過率は、 JASCO社製 spectrometer V−650を用いて、吸収波長350nm〜800nmの範囲で測定し、380nm〜750nmにおける値の平均値を固形化粧料の透過率(%)とした。また透過率60%以上の場合、目視において良好な透明性を示した。発汗性試験は、プラスティック製のセルに直径1mm、深さ10mmのホールを形成させ、そのサンプルを45℃の恒温槽に1か月間放置し、常温(25℃)にて24時間後にその外観を目視で評価した。また、使用感は、塗り伸ばしやすさ、べたつき感のなさについて専門パネラー10名(各5名)による4段階の官能評価を用いて評価した。なお、評価は以下の基準で行った。
肌または髪への塗り伸ばすさ
◎:肌または髪への塗り伸ばしやすさが良好と認めた人数が5名全員
○:肌または髪への塗り伸ばしやすさが良好と認めた人数が4名
△:肌または髪への塗り伸ばしやすさが良好と認めた人数が2〜3名
×:肌または髪への塗り伸ばしやすさが良好と認めた人数が1名以下
肌または髪へのべたつき感のなさ
◎:肌または髪へのべたつき感がないと認めた人数が5名全員
○:肌または髪へのべたつき感がないと認めた人数が4名
△:肌または髪へのべたつき感がないと認めた人数が2〜3名
×:肌または髪へのべたつき感がないと認めた人数が1名以下
The transmittance was measured in the absorption wavelength range of 350 nm to 800 nm using a spectrometer V-650 manufactured by JASCO, and the average value of the values at 380 nm to 750 nm was defined as the transmittance (%) of the solid cosmetic. Moreover, when the transmittance | permeability was 60% or more, it showed favorable transparency in visual observation. In the perspiration test, a hole of 1 mm in diameter and 10 mm in depth is formed in a plastic cell, the sample is left in a 45 ° C. thermostatic bath for 1 month, and its appearance is observed after 24 hours at normal temperature (25 ° C.) It evaluated visually. In addition, the feeling in use was evaluated using a four-step sensory evaluation by 10 expert panelists (5 each) for ease of spreading and lack of stickiness. The evaluation was made based on the following criteria.
Filliness to skin or hair ◎: All five people found that the ease of spreading on skin or hair was good ○: Four people found that ease of spreading on skin or hair was good △ : 2 to 3 people who found that the ease of spreading on the skin or hair was good x: 1 or less persons found that the ease of spreading on the skin or hair was good or less Sticky feeling to the skin or hair N o :: All five people found no stickiness on skin or hair ○: Four people found no stickiness on skin or hair 感: No stickiness on skin or hair 2 to 3 recognized number of people x: 1 or less number of people who recognized that there was no stickiness to skin or hair
実施例1〜12
成分(A)〜(E)を含み、成分(D)と成分(E)の重量%における成分比が10:1〜1:1の間である化粧料について透過率、発汗性試験および使用感を評価した。
Permeability, sweating test and feeling of use for a cosmetic comprising the components (A) to (E) and the component ratio of the component (D) to the component (E) in weight% is between 10: 1 and 1: 1 Was evaluated.
比較例1〜7
以下の比較例1〜7の処方でスティック型のサンケア化粧料を調製し、透過率、発汗性試験および使用感を評価した。
A stick-type sun care cosmetic was prepared according to the formulations of Comparative Examples 1 to 7 below, and the transmittance, the perspiration test and the feeling in use were evaluated.
20℃における屈折率が1.460以上である油剤[成分(D)]を含まない場合、体積膨張率が0.065以下である油剤[成分(E)]を含む比較例1および成分(E)を含まない比較例2のいずれの場合も発汗性は示さなかったが、透明性は悪かった。また、成分(D)を含み、成分(E)を含まない比較例3〜5および7の場合、透明性が良好であっても発汗性を示した。 Comparative Example 1 and Component (E) containing an oil agent having a volume expansion coefficient of 0.065 or less [Component (E)] when it does not contain an oil agent having a refractive index of 1.460 or more at 20 ° C. [Component (D)] Although the sweating property was not shown in any case of Comparative Example 2 not including the above, transparency was bad. Moreover, in the case of Comparative Examples 3-5 and 7 which do not contain a component (D) but a component (E), even if transparency was favorable, it showed perspiration property.
実施例13〜15では、成分(D)と成分(E)との比率が1より大きい化粧料を調製し、透過率、発汗性試験および使用感を評価した。
本発明の透明ゲル化剤、20℃における屈折率が1.460以上である油剤、および体積膨張率が0.065%/℃以下である油剤を組み合わせて利用することにより、透明で発汗性のない固形化粧料を提供することが可能になる。 A transparent and sweaty agent is obtained by using the transparent gelling agent of the present invention, an oil agent having a refractive index of 1.460 or more at 20 ° C., and an oil agent having a volume expansion coefficient of 0.065% / ° C. or less It becomes possible to provide no solid cosmetic.
Claims (10)
Component ratio oil and volumetric expansion refractive index of 1.460 or more at 20 ° C. is in wt% of oil is 0.065 or less 10: 1 to 1: 1, claim 1-9 Transparent oily solid cosmetic composition according to one item.
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US15/823,688 US10792235B2 (en) | 2017-05-30 | 2017-11-28 | Transparent oily solid cosmetics |
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JP2017106401A Expired - Fee Related JP6503008B2 (en) | 2017-05-30 | 2017-05-30 | Transparent oily solid cosmetic |
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US (1) | US10792235B2 (en) |
EP (1) | EP3409263A1 (en) |
JP (1) | JP6503008B2 (en) |
KR (1) | KR102079513B1 (en) |
CN (1) | CN108969394A (en) |
SG (1) | SG10201804533VA (en) |
TW (1) | TWI688408B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019065027A (en) * | 2018-12-20 | 2019-04-25 | 高級アルコール工業株式会社 | Transparent oily solid cosmetic |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109562035A (en) * | 2016-08-08 | 2019-04-02 | 株式会社资生堂 | Transparent solid composition |
EP4159823A1 (en) * | 2016-10-24 | 2023-04-05 | Ajinomoto Co., Inc. | Gel composition comprising a glutamide |
US20230052833A1 (en) * | 2019-12-27 | 2023-02-16 | Shiseido Company, Ltd. | Oil-based particles and external composition |
US20230329980A1 (en) * | 2020-09-01 | 2023-10-19 | Ocean View Holdings, Llc (Dba Dew Mighty) | Solid cosmetic |
WO2023229014A1 (en) * | 2022-05-26 | 2023-11-30 | 味の素株式会社 | Gelation agent composition |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5288484A (en) | 1976-01-17 | 1977-07-23 | Iseki & Co Ltd | Detecting device for opening of grain bag |
US4174994A (en) | 1976-11-05 | 1979-11-20 | Savelkouls Leonardus J | Apparatus for metal coatings |
JP2584262B2 (en) * | 1987-12-21 | 1997-02-26 | 株式会社資生堂 | Transparent base and cosmetic using the same |
HU204054B (en) * | 1989-08-10 | 1991-11-28 | Richter Gedeon Vegyeszet | Process for producing new 1-oxa-2-oxo-8-azaspiro(4,5)decane derivatives and pharmaceutical compositions comprising same |
US5663111A (en) | 1995-09-07 | 1997-09-02 | Southern Clay Products, Inc. | Organoclay compositions |
JP2001172128A (en) * | 1999-12-17 | 2001-06-26 | Jo Cosmetics Kk | Transparent solid cosmetic |
FR2820739B1 (en) | 2001-02-13 | 2004-01-02 | Ajinomoto Kk | AMINO ACID DERIVATIVE AND GEL, GEL COMPOSITION AND COSMETIC CONTAINING THE SAME, AND METHODS OF PREPARING THE SAME |
JP4174994B2 (en) | 2001-02-13 | 2008-11-05 | 味の素株式会社 | Oily base gelling agent |
KR101333441B1 (en) * | 2005-06-14 | 2013-11-27 | 고큐 아르코르 고교 가부시키가이샤 | Transparent oily solid cosmetic |
JP5117004B2 (en) * | 2006-07-21 | 2013-01-09 | ホソカワミクロン株式会社 | Solid powder cosmetic |
JP5759721B2 (en) | 2008-05-12 | 2015-08-05 | 高級アルコール工業株式会社 | Cosmetics with excellent usability and storage stability and method for producing the same |
CN102413809A (en) | 2009-05-08 | 2012-04-11 | 乐敦制药株式会社 | Oily composition and rod-shaped medicinal preparation |
KR101454199B1 (en) | 2012-09-03 | 2014-10-21 | 코스맥스 주식회사 | transparent sticks sunscreen agent cosmetic composition comprising polyamide gelling agent |
JP5663111B1 (en) | 2014-07-08 | 2015-02-04 | 高級アルコール工業株式会社 | Novel ester compound and cosmetics and cosmetics containing the same |
US10010493B2 (en) | 2014-01-20 | 2018-07-03 | Kokyu Alcohol Kogyo Co., Ltd. | Ester compound, and cosmetic component and cosmetic product each containing same |
KR101727027B1 (en) * | 2016-08-09 | 2017-04-17 | 주식회사 코스온 | Powder make-up cosmetic composition of the three-dimensional molding type |
EP4159823A1 (en) | 2016-10-24 | 2023-04-05 | Ajinomoto Co., Inc. | Gel composition comprising a glutamide |
-
2017
- 2017-05-30 JP JP2017106401A patent/JP6503008B2/en not_active Expired - Fee Related
- 2017-10-23 TW TW106136374A patent/TWI688408B/en not_active IP Right Cessation
- 2017-11-17 KR KR1020170153829A patent/KR102079513B1/en active IP Right Grant
- 2017-11-27 EP EP17203693.1A patent/EP3409263A1/en not_active Withdrawn
- 2017-11-28 US US15/823,688 patent/US10792235B2/en active Active
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2018
- 2018-05-28 SG SG10201804533VA patent/SG10201804533VA/en unknown
- 2018-05-29 CN CN201810534080.7A patent/CN108969394A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019065027A (en) * | 2018-12-20 | 2019-04-25 | 高級アルコール工業株式会社 | Transparent oily solid cosmetic |
Also Published As
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KR102079513B1 (en) | 2020-02-20 |
US20180344601A1 (en) | 2018-12-06 |
US10792235B2 (en) | 2020-10-06 |
TW201900148A (en) | 2019-01-01 |
SG10201804533VA (en) | 2018-12-28 |
EP3409263A1 (en) | 2018-12-05 |
CN108969394A (en) | 2018-12-11 |
KR20180131338A (en) | 2018-12-10 |
JP2018203619A (en) | 2018-12-27 |
TWI688408B (en) | 2020-03-21 |
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