WO2014021242A1 - Liquid crystal display device, polarizing plates, and polarizer protection film - Google Patents
Liquid crystal display device, polarizing plates, and polarizer protection film Download PDFInfo
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- WO2014021242A1 WO2014021242A1 PCT/JP2013/070428 JP2013070428W WO2014021242A1 WO 2014021242 A1 WO2014021242 A1 WO 2014021242A1 JP 2013070428 W JP2013070428 W JP 2013070428W WO 2014021242 A1 WO2014021242 A1 WO 2014021242A1
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133528—Polarisers
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
- G02F1/133635—Multifunctional compensators
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2413/00—Indexing scheme related to G02F1/13363, i.e. to birefringent elements, e.g. for optical compensation, characterised by the number, position, orientation or value of the compensation plates
- G02F2413/12—Biaxial compensators
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2413/00—Indexing scheme related to G02F1/13363, i.e. to birefringent elements, e.g. for optical compensation, characterised by the number, position, orientation or value of the compensation plates
- G02F2413/14—Negative birefingence
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- Physics & Mathematics (AREA)
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- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Polarising Elements (AREA)
- Liquid Crystal (AREA)
- Polyesters Or Polycarbonates (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
Description
項1.
バックライト光源、2つの偏光板、及び前記2つの偏光板の間に配された液晶セルを有する液晶表示装置であって、
前記バックライト光源は連続した発光スペクトルを有する白色光源であり、
前記偏光板は偏光子の両側に偏光子保護フィルムを積層した構成であり、
入射光側に配される偏光板の偏光子保護フィルムの少なくとも一方、及び出射光側に配される偏光板の偏光子保護フィルムの少なくとも一方が、4000~30000nmのリタデーション及び1.70以下のNz係数を有する配向ポリエステルフィルムである、
液晶表示装置。
項2.
前記入射光側に配される偏光板の入射光側の偏光子保護フィルム及び前記出射光側に配される偏光板の出射光側の偏光子保護フィルムが、4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムである、項1記載の液晶表示装置。
項3.
配向ポリエステルフィルムの面配向度が0.13以下である、項1又は2記載の液晶表示装置。
項4.
前記連続した発光スペクトルを有する白色光源が、白色発光ダイオードである、項1~3のいずれかに記載の液晶表示装置。
項5.
偏光子の両側に偏光子保護フィルムを積層した構成からなり、
少なくとも片側の偏光子保護フィルムが4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムである、連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光板。
項6.
前記配向ポリエステルフィルムの面配向度が0.13以下である、項5記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光板。
項7.
4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムからなる、連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。
項8.
前記配向ポリエステルフィルムの面配向度が0.13以下であることを特徴とする、項7記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。
項9.
前記配向ポリエステルフィルムが易接着層を有する、項7又は8記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。
項10.
前記配向ポリエステルフィルムが少なくとも3層からなり、最外層以外の層に紫外線吸収剤を含有し、380nmの光線透過率が20%以下である、項7~9のいずれかに記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。 The representative present invention is as follows.
Item 1.
A liquid crystal display device having a backlight light source, two polarizing plates, and a liquid crystal cell disposed between the two polarizing plates,
The backlight source is a white light source having a continuous emission spectrum;
The polarizing plate has a structure in which a polarizer protective film is laminated on both sides of a polarizer,
At least one of the polarizer protective films of the polarizing plate arranged on the incident light side, and at least one of the polarizer protective films of the polarizing plate arranged on the outgoing light side have a retardation of 4000 to 30,000 nm and Nz of 1.70 or less. An oriented polyester film having a coefficient,
Liquid crystal display device.
Item 2.
The polarizer protective film on the incident light side of the polarizing plate arranged on the incident light side and the polarizer protective film on the outgoing light side of the polarizing plate arranged on the outgoing light side have a retardation of 4000 to 30000 nm and 1.7. Item 2. The liquid crystal display device according to item 1, which is an oriented polyester film having the following Nz coefficient.
Item 3.
Item 3. The liquid crystal display device according to item 1 or 2, wherein the orientation degree of the oriented polyester film is 0.13 or less.
Item 4.
Item 4. The liquid crystal display device according to any one of Items 1 to 3, wherein the white light source having a continuous emission spectrum is a white light emitting diode.
Item 5.
Consists of a structure in which a polarizer protective film is laminated on both sides of the polarizer,
A polarizing plate for a liquid crystal display device using a white light source having a continuous emission spectrum as a backlight light source, wherein the polarizer protective film on at least one side is an oriented polyester film having a retardation of 4000 to 30000 nm and an Nz coefficient of 1.7 or less.
Item 6.
The polarizing plate for liquid crystal display devices which uses the white light source which has the continuous emission spectrum of claim | item 5 whose planar orientation degree of the said oriented polyester film is 0.13 or less as a backlight light source.
Item 7.
A polarizer protective film for a liquid crystal display device comprising a white light source having a continuous emission spectrum, which comprises an oriented polyester film having a retardation of 4000 to 30000 nm and an Nz coefficient of 1.7 or less, as a backlight source.
Item 8.
Item 8. The polarizer protective film for a liquid crystal display device using the white light source having a continuous emission spectrum according to Item 7 as a backlight light source, wherein the oriented polyester film has a plane orientation degree of 0.13 or less.
Item 9.
Item 9. The polarizer protective film for a liquid crystal display device using the white light source having a continuous emission spectrum according to Item 7 or 8, wherein the oriented polyester film has an easy-adhesion layer.
Item 10.
Item 10. The continuous emission spectrum according to any one of Items 7 to 9, wherein the oriented polyester film comprises at least three layers, contains an ultraviolet absorber in a layer other than the outermost layer, and has a light transmittance of 380 nm of 20% or less. A polarizer protective film for a liquid crystal display device using a white light source having a backlight as a backlight source.
一般に、液晶表示装置は、バックライト光源に対向する側から画像を表示する側(視認側又は出射光側)に向かう順に、後面モジュール、液晶セル及び前面モジュールから構成されている。後面モジュール及び前面モジュールは、一般に、透明基板と、その液晶セル側表面に形成された透明導電膜と、その反対側に配置された偏光板とから構成されている。ここで、偏光板は、後面モジュールでは、バックライト光源に対向する側に配置され、前面モジュールでは、画像を表示する側(視認側又は出射光側)に配置されている。 1. 2. Liquid Crystal Display Device In general, a liquid crystal display device is composed of a rear module, a liquid crystal cell, and a front module in order from the side facing the backlight light source toward the image display side (viewing side or outgoing light side). The rear module and the front module are generally composed of a transparent substrate, a transparent conductive film formed on the liquid crystal cell side surface, and a polarizing plate disposed on the opposite side. Here, the polarizing plate is disposed on the side facing the backlight light source in the rear module, and is disposed on the image display side (viewing side or outgoing light side) in the front module.
本発明の液晶表示装置は少なくとも、バックライト光源、2つの偏光板、及び2つの偏光板の間に配された液晶セルを構成部材として含む。本発明の液晶表示装置は、これら以外の他の構成部材、例えば、カラーフィルター、レンズフィルム、拡散シート、反射防止フィルム等を適宜有しても構わない。 2. Backlight Light Source The liquid crystal display device of the present invention includes at least a backlight light source, two polarizing plates, and a liquid crystal cell disposed between the two polarizing plates as constituent members. The liquid crystal display device of the present invention may have other constituent members other than these, for example, a color filter, a lens film, a diffusion sheet, an antireflection film and the like as appropriate.
偏光板は、PVA等にヨウ素を染着させた偏光子の両側に2枚の偏光子保護フィルムを積層した構成を有する。本発明で使用される偏光板は、2枚の偏光子保護フィルムの少なくとも一方に、特定範囲のリタデーション及び|ny-nz|/|ny-nx|で表されるNz係数という物性を満たす配向ポリエステルフィルム用いる。 3. Polarizer Protective Film The polarizing plate has a structure in which two polarizer protective films are laminated on both sides of a polarizer in which iodine is dyed on PVA or the like. The polarizing plate used in the present invention is an oriented polyester satisfying at least one of two polarizer protective films having a specific range of retardation and a physical property of Nz coefficient represented by | ny-nz | / | ny-nx |. Use film.
本発明で使用される偏光子保護フィルムに用いられる配向ポリエステルフィルムは、4000~30000nmのリタデーションを有することが好ましい。リタデーションが4000nm未満では、液晶表示装置を斜め方向から観察した時に干渉色を呈するため、良好な視認性を常に確保することができないためである。配向ポリエステルフィルムの好ましいリタデーションは4500nm以上、次に好ましくは5000nm以上、より好ましくは6000nm以上、更に好ましくは8000nm以上、より更に好ましくは10000nm以上である。 3-1. Retardation The oriented polyester film used for the polarizer protective film used in the present invention preferably has a retardation of 4000 to 30000 nm. This is because when the retardation is less than 4000 nm, an interference color is exhibited when the liquid crystal display device is observed from an oblique direction, so that good visibility cannot always be ensured. The preferred retardation of the oriented polyester film is 4500 nm or more, then preferably 5000 nm or more, more preferably 6000 nm or more, still more preferably 8000 nm or more, and even more preferably 10,000 nm or more.
偏光子保護フィルムに用いる配向ポリエステルフィルムは、|ny-nz|/|ny-nx|で表されるNz係数が1.7以下であることが好ましい。Nz係数は次のようにして求めることができる。分子配向計(王子計測器株式会社製、MOA-6004型分子配向計)を用いてフィルムの配向軸方向を求め、配向軸方向とこれに直交する方向の二軸の屈折率(ny、nx、但しny>nx)、及び厚さ方向の屈折率(nz)をアッベ屈折率計(アタゴ社製、NAR-4T、測定波長589nm)によって求める。こうして求めたnx、ny、nzを、|ny-nz|/|ny-nx|で表される式に代入して、Nz係数を求めることができる。 3-2. Nz coefficient The oriented polyester film used for the polarizer protective film preferably has an Nz coefficient represented by | ny-nz | / | ny-nx | of 1.7 or less. The Nz coefficient can be obtained as follows. The orientation axis direction of the film is obtained using a molecular orientation meter (MOA-6004 type molecular orientation meter, manufactured by Oji Scientific Instruments Co., Ltd.), and the biaxial refractive index (ny, nx, However, ny> nx) and the refractive index (nz) in the thickness direction are determined by an Abbe refractometer (manufactured by Atago Co., Ltd., NAR-4T, measurement wavelength 589 nm). The Nz coefficient can be obtained by substituting nx, ny, and nz obtained in this way into an expression represented by | ny−nz | / | ny−nx |.
本発明の液晶表示装置では、上記特定のリタデーション及びNz係数を有する配向ポリエステルフィルムが、一対の偏光板の両方の偏光子保護フィルムとして使用される。一対の偏光板とは、液晶に対して入射光側に配置される偏光板と液晶に対して出射光側に配置される偏光板との組合せを意味する。即ち、当該配向ポリエステルフィルムは、入射光側の偏光板と出射光側の偏光板の両方の偏光板に用いられる。当該配向ポリエステルフィルムは、各偏光板を構成する二枚の偏光子保護フィルムのうち少なくとも一方として使用されていれば良く、その両方に使用されても良い。 3-3. Arrangement of Polarizer Protective Film In the liquid crystal display device of the present invention, the oriented polyester film having the specific retardation and the Nz coefficient is used as both polarizer protective films of a pair of polarizing plates. The pair of polarizing plates means a combination of a polarizing plate disposed on the incident light side with respect to the liquid crystal and a polarizing plate disposed on the outgoing light side with respect to the liquid crystal. That is, the oriented polyester film is used for both a polarizing plate on the incident light side and a polarizing plate on the outgoing light side. The oriented polyester film only needs to be used as at least one of the two polarizer protective films constituting each polarizing plate, and may be used for both.
配向ポリエステルフィルムのリタデーション値及びNz係数を上記の特定範囲に制御することに加え、(nx+ny)/2-nzで表される面配向度を特定値以下にすることにより、より確実に一対の偏光板の両方に偏光子保護フィルムとしてポリエステルフィルムを用いた場合の虹斑を完全に解消することができる。ここで、nx、ny及びnzの値は、Nz係数と同様の方法で求められる。配向ポリエステルフィルムの面配向度は0.13以下が好ましく、より好ましくは0.125以下、さらの好ましくは0.12以下である。面配向度が0.13以下にすることで、液晶表示装置を斜め方向から観察した場合に角度によって観察される虹斑を完全に解消することができる。面配向度は0.08以上が好ましく、より好ましくは0.10以上である。面配向度が0.08未満では、フィルム厚みが変動し、リタデーションの値がフィルム面内で不均一になる場合がある。 3-4. Planar orientation coefficient In addition to controlling the retardation value and Nz coefficient of the oriented polyester film to the above specific range, the plane orientation degree represented by (nx + ny) / 2-nz is made to be less than the specific value, thereby ensuring more certainty. Iridescents can be completely eliminated when a polyester film is used as a polarizer protective film for both of the pair of polarizing plates. Here, the values of nx, ny, and nz are obtained by the same method as for the Nz coefficient. The degree of plane orientation of the oriented polyester film is preferably 0.13 or less, more preferably 0.125 or less, and still more preferably 0.12 or less. By setting the degree of plane orientation to 0.13 or less, it is possible to completely eliminate rainbow spots observed depending on the angle when the liquid crystal display device is observed from an oblique direction. The plane orientation degree is preferably 0.08 or more, and more preferably 0.10 or more. If the degree of plane orientation is less than 0.08, the film thickness varies, and the retardation value may be non-uniform in the film plane.
配向ポリエステルフィルムは、そのリタデーション(Re)と厚さ方向リタデーション(Rth)の比(Re/Rth)が、好ましくは0.2以上、より好ましくは0.5以上、さらに好ましくは0.6以上である。上記リタデーションと厚さ方向リタデーションの比(Re/Rth)が大きいほど、複屈折の作用は等方性を増し、観察角度による虹状の色斑の発生が生じ難くなるためである。完全な1軸性(1軸対称)フィルムでは上記リタデーションと厚さ方向リタデーションの比(Re/Rth)は2となる。しかし、後述するように完全な1軸性(1軸対称)フィルムに近づくにつれ配向方向と直行する方向の機械的強度が著しく低下する。 3-5. Retardation ratio The ratio (Re / Rth) of retardation (Re) and thickness direction retardation (Rth) of the oriented polyester film is preferably 0.2 or more, more preferably 0.5 or more, and still more preferably 0.6. That's it. This is because as the ratio of the retardation to the retardation in the thickness direction (Re / Rth) is larger, the birefringence action is more isotropic, and the occurrence of rainbow-like color spots due to the observation angle is less likely to occur. In a complete uniaxial (uniaxial symmetry) film, the ratio of the retardation to the retardation in the thickness direction (Re / Rth) is 2. However, as will be described later, the mechanical strength in the direction orthogonal to the orientation direction is significantly lowered as the film approaches a complete uniaxial (uniaxial symmetry) film.
配向ポリエステルフィルムのリタデーションの変動を抑制する為には、フィルムの厚み斑が小さいことが好ましい。この観点から、配向ポリエステルフィルムの厚み斑は5%以下であることが好ましく、4.5%以下であることがさらに好ましく、4%以下であることがよりさらに好ましく、3%以下であることが特に好ましい。 3-6. Thickness unevenness In order to suppress the variation in retardation of the oriented polyester film, it is preferable that the thickness unevenness of the film is small. In this respect, the uneven thickness of the oriented polyester film is preferably 5% or less, more preferably 4.5% or less, still more preferably 4% or less, and more preferably 3% or less. Particularly preferred.
配向ポリエステルフィルムの厚みは、本発明の効果を妨げない限り特に制限されないが、通常15~300μmであり、好ましくは15~200μmである。フィルム厚みが15μm未満では、フィルムの力学特性の異方性が顕著となり、裂け、破れ等を生じる場合がある。特に好ましい厚みの下限は25μmである。一方、偏光子保護フィルムの厚みの上限は、300μmを超えると偏光板の厚みが厚くなりすぎてしまい好ましくない。偏光子保護フィルムとしての実用性の観点から、厚みの上限は200μmが好ましい。特に好ましい厚みの上限は一般的なTACフィルムと同等程度の100μmである。 3-7. Thickness The thickness of the oriented polyester film is not particularly limited as long as the effects of the present invention are not hindered, but is usually 15 to 300 μm, preferably 15 to 200 μm. When the film thickness is less than 15 μm, the anisotropy of the mechanical properties of the film becomes remarkable, and tearing, tearing, and the like may occur. A particularly preferable lower limit of the thickness is 25 μm. On the other hand, if the upper limit of the thickness of the polarizer protective film exceeds 300 μm, the thickness of the polarizing plate becomes too thick, which is not preferable. From the viewpoint of practicality as a polarizer protective film, the upper limit of the thickness is preferably 200 μm. A particularly preferable upper limit of the thickness is 100 μm, which is about the same as a general TAC film.
本発明に用いられる配向ポリエステルフィルムは、任意のポリエステル樹脂から得ることができる。ポリエステル樹脂の種類は、特に制限されず、ジカルボン酸とジオールとを縮合させて得られる任意のポリエステル樹脂を使用することができる。 3-8. Polyester resin The oriented polyester film used in the present invention can be obtained from any polyester resin. The type of the polyester resin is not particularly limited, and any polyester resin obtained by condensing dicarboxylic acid and diol can be used.
配向ポリエステルフィルムは、偏光子に含まれるヨウ素色素等の光学機能性色素の劣化を抑制する観点から、波長380nmの光線透過率が20%以下であることが望ましい。380nmの光線透過率は15%以下がより好ましく、10%以下がさらに好ましく、5%以下が特に好ましい。前記光線透過率が20%以下であれば、光学機能性色素の紫外線による変質を抑制することができる。光線透過率は、フィルムの平面に対して垂直方法に測定したものであり、分光光度計(例えば、日立U-3500型)を用いて測定することができる。 3-9. Light Transmittance The oriented polyester film desirably has a light transmittance of 20% or less at a wavelength of 380 nm from the viewpoint of suppressing deterioration of optical functional dyes such as iodine dyes contained in the polarizer. The light transmittance at 380 nm is more preferably 15% or less, further preferably 10% or less, and particularly preferably 5% or less. If the light transmittance is 20% or less, the optical functional dye can be prevented from being deteriorated by ultraviolet rays. The light transmittance is measured by a method perpendicular to the plane of the film, and can be measured using a spectrophotometer (for example, Hitachi U-3500 type).
配向ポリエステルフィルムには、紫外線吸収剤以外に、本発明の効果を妨げない範囲で、各種の添加剤を含有させることも好ましい様態である。添加剤として、例えば、無機粒子、耐熱性高分子粒子、アルカリ金属化合物、アルカリ土類金属化合物、リン化合物、帯電防止剤、耐光剤、難燃剤、熱安定剤、酸化防止剤、ゲル化防止剤、界面活性剤等が挙げられる。また、高い透明性を奏するためにはポリエステルフィルムに実質的に粒子を含有しないことも好ましい。「粒子を実質的に含有させない」とは、例えば無機粒子の場合、ケイ光X線分析で無機元素を定量した場合に50ppm以下、好ましくは10ppm以下、特に好ましくは検出限界以下となる含有量を意味する。 3-10. Other components, etc. In addition to the ultraviolet absorber, it is also preferable to add various additives to the oriented polyester film as long as the effects of the present invention are not hindered. Examples of additives include inorganic particles, heat resistant polymer particles, alkali metal compounds, alkaline earth metal compounds, phosphorus compounds, antistatic agents, light proofing agents, flame retardants, thermal stabilizers, antioxidants, and antigelling agents. And surfactants. Moreover, in order to show high transparency, it is also preferable that a polyester film does not contain a particle | grain substantially. “Substantially free of particles” means, for example, in the case of inorganic particles, a content that is 50 ppm or less, preferably 10 ppm or less, particularly preferably the detection limit or less when inorganic elements are quantified by fluorescent X-ray analysis. means.
本発明においては、偏光子との接着性を改良のために、配向ポリエステルフィルムの少なくとも片面に、ポリエステル樹脂、ポリウレタン樹脂又はポリアクリル樹脂の少なくとも1種類を主成分とする易接着層を有することが好ましい。ここで、「主成分」とは易接着層を構成する固形成分のうち50質量%以上である成分をいう。本発明の易接着層の形成に用いる塗布液は、水溶性又は水分散性の共重合ポリエステル樹脂、アクリル樹脂及びポリウレタン樹脂の内、少なくとも1種を含む水性塗布液が好ましい。これらの塗布液としては、例えば、特許第3567927号公報、特許第3589232号公報、特許第3589233号公報、特許第3900191号公報、特許第4150982号公報等に開示された水溶性又は水分散性共重合ポリエステル樹脂溶液、アクリル樹脂溶液、及びポリウレタン樹脂溶液等が挙げられる。 4). In the present invention, in order to improve the adhesion to the polarizer, at least one surface of the oriented polyester film is provided with an easy adhesion layer mainly composed of at least one of polyester resin, polyurethane resin or polyacrylic resin. It is preferable to have. Here, the “main component” refers to a component that is 50% by mass or more of the solid components constituting the easy-adhesion layer. The coating solution used for forming the easy-adhesion layer of the present invention is preferably an aqueous coating solution containing at least one of water-soluble or water-dispersible copolymerized polyester resin, acrylic resin, and polyurethane resin. Examples of these coating liquids include water-soluble or water-dispersible co-polymers disclosed in Japanese Patent No. 3567927, Japanese Patent No. 3589232, Japanese Patent No. 3589233, Japanese Patent No. 3900191, and Japanese Patent No. 4150982. Examples thereof include a polymerized polyester resin solution, an acrylic resin solution, and a polyurethane resin solution.
本発明に用いられる偏光板には、写り込み防止やギラツキ抑制、キズ抑制等を目的として、種々の機能層、すなわちハードコート層、防眩層、反射防止層、低反射層、低反射防止層、及び反射防止防眩層からなる群より選択される1種以上の機能層を配向ポリエステル表面に設けることも好ましい様態である。種々の機能層を設けるに際して、配向ポリエステルフィルムはその表面に易接着層を有することが好ましい。その際、反射光による干渉を抑える観点から、易接着層の屈折率を、機能層の屈折率と配向ポリエステルフィルムの屈折率の相乗平均近傍になるように調整することが好ましい。易接着層の屈折率の調整は、公知の方法を採用することができ、例えば、バインダー樹脂に、チタンやジルコニウム、その他の金属種を含有させることで容易に調整することができる。 5. Functional layer The polarizing plate used in the present invention has various functional layers, that is, a hard coat layer, an antiglare layer, an antireflection layer, a low reflection layer, a low reflection layer, for the purpose of preventing reflection, suppressing glare, suppressing scratches, and the like. It is also preferable to provide one or more functional layers selected from the group consisting of an anti-reflection layer and an anti-reflection anti-glare layer on the oriented polyester surface. When providing various functional layers, the oriented polyester film preferably has an easy adhesion layer on the surface thereof. At that time, from the viewpoint of suppressing interference due to reflected light, it is preferable to adjust the refractive index of the easy-adhesion layer so that it is close to the geometric mean of the refractive index of the functional layer and the refractive index of the oriented polyester film. The refractive index of the easy-adhesion layer can be adjusted by a known method. For example, the refractive index of the easy-adhesion layer can be easily adjusted by adding titanium, zirconium, or other metal species to the binder resin.
本発明の保護フィルムである配向ポリエステルフィルムは、一般的なポリエステルフィルムの製造方法に従って製造することができる。例えば、ポリエステル樹脂を溶融し、シート状に押出し成形された無配向ポリエステルをガラス転移温度以上の温度において、ロールの速度差を利用して縦方向に延伸した後、テンターにより横方向に延伸し、熱処理を施す方法が挙げられる。 6). The manufacturing method of an oriented polyester film The oriented polyester film which is a protective film of this invention can be manufactured in accordance with the manufacturing method of a general polyester film. For example, the polyester resin is melted and the non-oriented polyester extruded and formed into a sheet shape is stretched in the longitudinal direction by utilizing the speed difference of the roll at a temperature equal to or higher than the glass transition temperature, and then stretched in the transverse direction by a tenter. The method of performing heat processing is mentioned.
(1)リタデーション(Re)
リタデーションとは、フィルム上の直交する二軸の屈折率の異方性(△Nxy=|nx-ny|)とフィルム厚みd(nm)との積(△Nxy×d)で定義されるパラメーターであり、光学的等方性及び異方性を示す尺度である。二軸の屈折率の異方性(△Nxy)は、以下の方法により求めた。分子配向計(王子計測器株式会社製、MOA-6004型分子配向計)を用いてフィルムの配向軸方向を求め、配向軸方向が長辺となるように4cm×2cmの長方形を切り出し、測定用サンプルとした。このサンプルについて、直交する二軸の屈折率(nx,ny)、及び厚さ方向の屈折率(Nz)をアッベ屈折率計(アタゴ社製、NAR-4T、測定波長589nm)を用いて測定し、前記二軸の屈折率の差の絶対値(|nx-ny|)を屈折率の異方性(△Nxy)とした。フィルムの厚みd(nm)は電気マイクロメータ(ファインリューフ社製、ミリトロン1245D)を用いて測定し、単位をnmに換算した。屈折率の異方性(△Nxy)とフィルムの厚みd(nm)の積(△Nxy×d)より、リタデーション(Re)を求めた。 The physical property evaluation methods in the examples are as follows.
(1) Retardation (Re)
Retardation is a parameter defined by the product (ΔNxy × d) of the biaxial refractive index anisotropy (ΔNxy = | nx−ny |) on the film and the film thickness d (nm). Yes, a measure of optical isotropy and anisotropy. The biaxial refractive index anisotropy (ΔNxy) was determined by the following method. Using a molecular orientation meter (MOA-6004 type molecular orientation meter, manufactured by Oji Scientific Instruments Co., Ltd.), the orientation axis direction of the film is obtained, and a 4 cm × 2 cm rectangle is cut out so that the orientation axis direction becomes the long side, for measurement A sample was used. For this sample, the biaxial refractive index (nx, ny) perpendicular to each other and the refractive index (Nz) in the thickness direction were measured using an Abbe refractometer (NAR-4T, manufactured by Atago Co., Ltd., measurement wavelength 589 nm). The absolute value (| nx−ny |) of the difference between the biaxial refractive indexes was defined as the refractive index anisotropy (ΔNxy). The thickness d (nm) of the film was measured using an electric micrometer (manufactured by Fine Reef, Millitron 1245D), and the unit was converted to nm. Retardation (Re) was determined from the product (ΔNxy × d) of refractive index anisotropy (ΔNxy) and film thickness d (nm).
|ny-nz|/|ny-nx|で得られる値をNz係数とした。ただし、ny>nxとなるように、ny及びnxの値を選択した。 (2) The value obtained by Nz coefficient | ny-nz | / | ny-nx | was defined as Nz coefficient. However, the values of ny and nx were selected so that ny> nx.
(nx+ny)/2-nzで得られる値を面配向度(△P)とした。 (3) Degree of plane orientation (ΔP)
The value obtained by (nx + ny) / 2−nz was defined as the degree of plane orientation (ΔP).
厚さ方向リタデーションとは、フィルム厚さ方向断面から見たときの2つの複屈折△Nxz(=|nx-nz|)、△Nyz(=|ny-nz|)にそれぞれフィルム厚さdを掛けて得られるリタデーションの平均を示すパラメーターである。リタデーションの測定と同様の方法でnx、ny、nzとフィルム厚みd(nm)を求め、(△Nxz×d)と(△Nyz×d)との平均値を算出して厚さ方向リタデーション(Rth)を求めた。 (4) Thickness direction retardation (Rth)
Thickness direction retardation refers to two birefringences ΔNxz (= | nx−nz |) and ΔNyz (= | ny−nz |), respectively, when viewed from the cross section in the film thickness direction. It is a parameter which shows the average of retardation obtained. Thickness direction retardation (Rth) is calculated by calculating nx, ny, nz and film thickness d (nm) in the same manner as the retardation measurement, and calculating an average value of (ΔNxz × d) and (ΔNyz × d). )
PVAとヨウ素からなる偏光子の片側に後述する方法で作成したポリエステルフィルムを偏光子の偏光軸とポリエステルフィルムの配向主軸が垂直になるように貼り付け、その反対側の面にTACフィルム(富士フイルム(株)社製、厚み80μm)を貼り付けて偏光板を作成した。得られた偏光板を液晶を挟んで両側に一枚ずつ、各偏光板がクロスニコルの条件下になるよう配置して液晶表示装置を作製した。各偏光板は、前記ポリエステルフィルムが液晶とは反対側(遠位)となるように配置された。液晶表示装置の光源には、青色発光ダイオードとイットリウム・アルミニウム・ガーネット系黄色蛍光体とを組み合わせた発光素子からなる白色LEDを光源(日亜化学、NSPW500CS)に用いた。このような液晶表示装置の正面、及び斜め方向から目視観察し、虹斑の発生有無について、以下のように判定した。 (5) Observation of rainbow spots A polyester film prepared by the method described later is attached to one side of a polarizer made of PVA and iodine so that the polarization axis of the polarizer and the main axis of orientation of the polyester film are perpendicular to each other. A TAC film (manufactured by FUJIFILM Corporation, thickness 80 μm) was attached to the substrate to prepare a polarizing plate. The obtained polarizing plate was placed on both sides of the liquid crystal so that each polarizing plate was in a crossed Nicols condition to produce a liquid crystal display device. Each polarizing plate was arrange | positioned so that the said polyester film might be on the opposite side (distal) from a liquid crystal. As a light source of the liquid crystal display device, a white LED composed of a light emitting element in which a blue light emitting diode and a yttrium / aluminum / garnet yellow phosphor were combined was used as a light source (Nichia Chemical, NSPW500CS). The liquid crystal display device was visually observed from the front and oblique directions, and the presence or absence of rainbow spots was determined as follows.
A’:斜め方向から観察したときに、角度によって極薄い虹斑が観察される。
B: 斜め方向から観察したときに、角度によって薄い虹斑が観察される。
C: 斜め方向から観察したときに、虹斑が観察される。
D: 正面方向及び斜め方向から観察したときに、虹斑が観察される。 A: No iridescence from any direction.
A ′: When observed from an oblique direction, very thin rainbow spots are observed depending on the angle.
B: When observed from an oblique direction, a thin iridescence is observed depending on the angle.
C: When observed from an oblique direction, rainbow spots are observed.
D: When observed from the front direction and the oblique direction, rainbow spots are observed.
東洋精機製作所製エレメンドルフ引裂試験機を用いて、JIS P-8116に従い、各フィルムの引裂き強度を測定した。引裂き方向はフィルムの配向主軸方向と平行となるように行ない、以下のように判定した。なお、配向主軸方向の測定は分子配向計(王子計測器株式会社製、MOA-6004型分子配向計)で測定した。
○:引裂き強度が50mN以上
×:引裂き強度が50mN未満 (6) Tear Strength The tear strength of each film was measured according to JIS P-8116 using an Elmendorf tear tester manufactured by Toyo Seiki Seisakusho. The tearing direction was performed so as to be parallel to the orientation main axis direction of the film, and was determined as follows. The measurement in the orientation main axis direction was performed with a molecular orientation meter (MOA-6004 type molecular orientation meter, manufactured by Oji Scientific Instruments).
○: Tear strength is 50 mN or more ×: Tear strength is less than 50 mN
エステル化反応缶を昇温し200℃に到達した時点で、テレフタル酸を86.4質量部及びエチレングリコール64.6質量部を仕込み、撹拌しながら触媒として三酸化アンチモンを0.017質量部、酢酸マグネシウム4水和物を0.064質量部、トリエチルアミン0.16質量部を仕込んだ。ついで、加圧昇温を行いゲージ圧0.34MPa、240℃の条件で加圧エステル化反応を行った後、エステル化反応缶を常圧に戻し、リン酸0.014質量部を添加した。さらに、15分かけて260℃に昇温し、リン酸トリメチル0.012質量部を添加した。次いで15分後に、高圧分散機で分散処理を行い、15分後、得られたエステル化反応生成物を重縮合反応缶に移送し、280℃で減圧下重縮合反応を行った。 (Production Example 1-Polyester A)
When the temperature of the esterification reactor was raised to 200 ° C., 86.4 parts by mass of terephthalic acid and 64.6 parts by mass of ethylene glycol were charged and 0.017 parts by mass of antimony trioxide as a catalyst while stirring. 0.064 parts by mass of magnesium acetate tetrahydrate and 0.16 parts by mass of triethylamine were charged. Next, the pressure was raised and the pressure esterification reaction was carried out under the conditions of gauge pressure 0.34 MPa and 240 ° C., then the esterification reaction can was returned to normal pressure, and 0.014 parts by mass of phosphoric acid was added. Furthermore, it heated up to 260 degreeC over 15 minutes, and 0.012 mass part of trimethyl phosphate was added. Then, after 15 minutes, dispersion treatment was performed with a high-pressure disperser, and after 15 minutes, the obtained esterification reaction product was transferred to a polycondensation reaction can and subjected to polycondensation reaction at 280 ° C. under reduced pressure.
乾燥させた紫外線吸収剤(2,2’-(1,4-フェニレン)ビス(4H-3,1-ベンズオキサジノン-4-オン)10質量部、粒子を含有しないPET(A)(固有粘度が0.62dl/g)90質量部を混合し、混練押出機を用い、紫外線吸収剤含有するポリエチレンテレフタレート樹脂(B)を得た。(以後、PET(B)と略す。) (Production Example 2-Polyester B)
10 parts by weight of a dried UV absorber (2,2 ′-(1,4-phenylene) bis (4H-3,1-benzoxazinon-4-one), PET (A) containing no particles (inherent viscosity Was 0.62 dl / g) and 90 parts by mass were mixed, and a polyethylene terephthalate resin (B) containing an ultraviolet absorber was obtained using a kneading extruder (hereinafter abbreviated as PET (B)).
常法によりエステル交換反応及び重縮合反応を行って、ジカルボン酸成分として(ジカルボン酸成分全体に対して)テレフタル酸46モル%、イソフタル酸46モル%及び5-スルホナトイソフタル酸ナトリウム8モル%、グリコール成分として(グリコール成分全体に対して)エチレングリコール50モル%及びネオペンチルグリコール50モル%の組成の水分散性スルホン酸金属塩基含有共重合ポリエステル樹脂を調製した。次いで、水51.4質量部、イソプロピルアルコール38質量部、n-ブチルセルソルブ5質量部、ノニオン系界面活性剤0.06質量部を混合した後、加熱撹拌し、77℃に達したら、上記水分散性スルホン酸金属塩基含有共重合ポリエステル樹脂5質量部を加え、樹脂の固まりが無くなるまで撹拌し続けた後、樹脂水分散液を常温まで冷却して、固形分濃度5.0質量%の均一な水分散性共重合ポリエステル樹脂液を得た。さらに、凝集体シリカ粒子(富士シリシア(株)社製、サイリシア310)3質量部を水50質量部に分散させた後、上記水分散性共重合ポリエステル樹脂液99.46質量部にサイリシア310の水分散液0.54質量部を加えて、撹拌しながら水20質量部を加えて、接着性改質塗布液を得た。 (Production Example 3-Adjustment of Adhesive Modification Coating Solution)
A transesterification reaction and a polycondensation reaction were carried out by a conventional method, and as a dicarboxylic acid component (based on the whole dicarboxylic acid component) 46 mol% terephthalic acid, 46 mol% isophthalic acid and 8 mol% sodium 5-sulfonatoisophthalate, A water-dispersible sulfonic acid metal group-containing copolymer polyester resin having a composition of 50 mol% ethylene glycol and 50 mol% neopentyl glycol (relative to the entire glycol component) was prepared as a glycol component. Next, 51.4 parts by mass of water, 38 parts by mass of isopropyl alcohol, 5 parts by mass of n-butyl cellosolve, 0.06 parts by mass of a nonionic surfactant were mixed and then heated and stirred. After adding 5 parts by mass of a water-dispersible sulfonic acid metal base-containing copolymer polyester resin and continuing to stir until the resin is no longer agglomerated, the resin water dispersion is cooled to room temperature to obtain a solid content concentration of 5.0% by mass. A uniform water-dispersible copolymerized polyester resin liquid was obtained. Furthermore, after dispersing 3 parts by mass of aggregated silica particles (Silicia 310, manufactured by Fuji Silysia Co., Ltd.) in 50 parts by mass of water, 99.46 parts by mass of the water-dispersible copolyester resin solution was mixed with 99.46 parts by mass of the silicia 310. 0.54 parts by mass of the aqueous dispersion was added, and 20 parts by mass of water was added with stirring to obtain an adhesive modified coating solution.
基材フィルム中間層用原料として粒子を含有しないPET(A)樹脂ペレット90質量部と紫外線吸収剤を含有したPET(B)樹脂ペレット10質量部を135℃で6時間減圧乾燥(1Torr)した後、押出機2(中間層II層用)に供給し、また、PET(A)を常法により乾燥して押出機1(外層I層及び外層III用)にそれぞれ供給し、285℃で溶解した。この2種のポリマーを、それぞれステンレス焼結体の濾材(公称濾過精度10μm粒子95%カット)で濾過し、2種3層合流ブロックにて、積層し、口金よりシート状にして押し出した後、静電印加キャスト法を用いて表面温度30℃のキャスティングドラムに巻きつけて冷却固化し、未延伸フィルムを作った。この時、I層、II層、III層の厚さの比は10:80:10となるように各押し出し機の吐出量を調整した。 (Polarizer protective film 1)
After drying 90 parts by mass of PET (A) resin pellets containing no particles as a raw material for the base film intermediate layer and 10 parts by mass of PET (B) resin pellets containing an ultraviolet absorber at 135 ° C. for 6 hours under reduced pressure (1 Torr) , And supplied to the extruder 2 (for the intermediate layer II layer). Also, the PET (A) was dried by a conventional method and supplied to the extruder 1 (for the outer layer I layer and the outer layer III) and dissolved at 285 ° C. . After filtering these two kinds of polymers with a filter medium made of a sintered stainless steel (nominal filtration accuracy of 10 μm particles 95% cut), laminating them in a two-kind / three-layer confluence block, and extruding them into a sheet form from a die, The film was wound around a casting drum having a surface temperature of 30 ° C. using an electrostatic application casting method, and then cooled and solidified to produce an unstretched film. At this time, the discharge amount of each extruder was adjusted so that the thickness ratio of the I layer, the II layer, and the III layer was 10:80:10.
未延伸フィルムの厚みを変更することにより、厚み約100μmとすること以外は偏光子保護フィルム1と同様にして一軸配向PETフィルムを得た。 (Polarizer protective film 2)
By changing the thickness of the unstretched film, a uniaxially oriented PET film was obtained in the same manner as the polarizer protective film 1 except that the thickness was about 100 μm.
偏光子保護フィルム1と同様の方法により作製された未延伸フィルムを、加熱されたロール群及び赤外線ヒーターを用いて105℃に加熱し、その後周速差のあるロール群で走行方向に1.5倍延伸した後、偏光子保護フィルム1と同様の方法で幅方向に4.0倍延伸して、フィルム厚み約50μmの二軸配向PETフィルムを得た。 (Polarizer protective film 3)
An unstretched film produced by the same method as that for the polarizer protective film 1 is heated to 105 ° C. using a heated roll group and an infrared heater, and then 1.5 rolls in the traveling direction with a roll group having a difference in peripheral speed. After being double-stretched, the film was stretched 4.0 times in the width direction in the same manner as the polarizer protective film 1 to obtain a biaxially oriented PET film having a film thickness of about 50 μm.
偏光子保護フィルム3と同様の方法で、走行方向に2.0倍、幅方向に4.0倍延伸して、フィルム厚み約50μmの二軸配向PETフィルムを得た。 (Polarizer protective film 4)
In the same manner as for the polarizer protective film 3, the film was stretched 2.0 times in the running direction and 4.0 times in the width direction to obtain a biaxially oriented PET film having a film thickness of about 50 μm.
偏光子保護フィルム1と同様の方法で、中間層に紫外線吸収剤を含有するPET樹脂(B)を用いずに、フィルム厚み50μmの一軸配向PETフィルムを得た。 (Polarizer protective film 5)
A uniaxially oriented PET film having a film thickness of 50 μm was obtained in the same manner as in the polarizer protective film 1 without using a PET resin (B) containing an ultraviolet absorber in the intermediate layer.
偏光子保護フィルム3と同様の方法で、走行方向に4.0倍、幅方向に1.0倍延伸して、フィルム厚み約100μmの一軸配向PETフィルムを得た。 (Polarizer protective film 6)
In the same manner as the polarizer protective film 3, the film was stretched 4.0 times in the running direction and 1.0 times in the width direction to obtain a uniaxially oriented PET film having a film thickness of about 100 μm.
偏光子保護フィルム1と同様の方法で、走行方向に1.0倍、幅方向に3.5倍延伸して、フィルム厚み約75μmの一軸配向PETフィルムを得た。 (Polarizer protective film 7)
In the same manner as for the polarizer protective film 1, the film was stretched 1.0 times in the running direction and 3.5 times in the width direction to obtain a uniaxially oriented PET film having a film thickness of about 75 μm.
偏光子保護フィルム1と同様の方法を用い、未延伸フィルムの厚みを変更し、横延伸倍率を3.8倍、延伸温度を135℃として、厚み約100μmの一軸配向PETフィルムを得た。 (Polarizer protective film 8)
Using the same method as for the polarizer protective film 1, the thickness of the unstretched film was changed, the transverse stretch ratio was 3.8 times, the stretch temperature was 135 ° C., and a uniaxially oriented PET film having a thickness of about 100 μm was obtained.
偏光子保護フィルム1と同様の方法を用い、横延伸倍率を3.8倍、延伸温度を135℃として、厚み約50μmの一軸配向PETフィルムを得た。 (Polarizer protective film 9)
A method similar to that for the polarizer protective film 1 was used to obtain a uniaxially oriented PET film having a thickness of about 50 μm at a lateral stretching ratio of 3.8 times and a stretching temperature of 135 ° C.
偏光子保護フィルム1と同様の方法を用い、横延伸倍率を3.8倍として、厚み50μmの一軸配向PETフィルムを得た。 (Polarizer protective film 10)
A method similar to that for the polarizer protective film 1 was used, and the transverse stretch ratio was 3.8 times to obtain a uniaxially oriented PET film having a thickness of 50 μm.
偏光子保護フィルム1と同様の方法を用い、横延伸倍率を4.2倍、延伸温度を135℃として、厚み約50μmの一軸配向PETフィルムを得た。 (Polarizer protective film 11)
A method similar to that for the polarizer protective film 1 was used, and a lateral stretching ratio of 4.2 times and a stretching temperature of 135 ° C. were obtained to obtain a uniaxially oriented PET film having a thickness of about 50 μm.
偏光子保護フィルム1と同様の方法を用い、未延伸フィルムの厚みを変更し、横延伸倍率を3.8倍に変更することにより、厚み38μmの一軸配向PETフィルムを得た。 (Polarizer protective film 12)
Using the same method as for the polarizer protective film 1, the thickness of the unstretched film was changed, and the lateral stretch ratio was changed to 3.8 times to obtain a uniaxially oriented PET film having a thickness of 38 μm.
偏光子保護フィルム1と同様の方法を用い、未延伸フィルムの厚みを変更することにより、厚みを38μmの一軸配向PETフィルムを得た。 (Polarizer protective film 13)
Using a method similar to that for the polarizer protective film 1 and changing the thickness of the unstretched film, a uniaxially oriented PET film having a thickness of 38 μm was obtained.
偏光子保護フィルム3と同様の方法で、走行方向に1.8倍、幅方向に2.0倍延伸して、フィルム厚み約275μmの二軸配向PETフィルムを得た。 (Polarizer protective film 14)
In the same manner as for the polarizer protective film 3, the film was stretched 1.8 times in the running direction and 2.0 times in the width direction to obtain a biaxially oriented PET film having a film thickness of about 275 μm.
偏光子保護フィルム3と同様の方法で、走行方向に3.6倍、幅方向に4.0倍延伸して、フィルム厚み約38μmの二軸配向PETフィルムを得た。 (Polarizer protective film 15)
In the same manner as for the polarizer protective film 3, the film was stretched 3.6 times in the running direction and 4.0 times in the width direction to obtain a biaxially oriented PET film having a film thickness of about 38 μm.
偏光子保護フィルム1と同様の方法を用い、未延伸フィルムの厚みを変更することにより、厚み約10μmの一軸配向PETフィルムを得た。 (Polarizer protective film 16)
A uniaxially oriented PET film having a thickness of about 10 μm was obtained by changing the thickness of the unstretched film using the same method as for the polarizer protective film 1.
Claims (10)
- バックライト光源、2つの偏光板、及び前記2つの偏光板の間に配された液晶セルを有する液晶表示装置であって、
前記バックライト光源は連続した発光スペクトルを有する白色光源であり、
前記偏光板は偏光子の両側に偏光子保護フィルムを積層した構成であり、
入射光側に配される偏光板の偏光子保護フィルムの少なくとも一方、及び出射光側に配される偏光板の偏光子保護フィルムの少なくとも一方が、4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムである、
液晶表示装置。 A liquid crystal display device having a backlight light source, two polarizing plates, and a liquid crystal cell disposed between the two polarizing plates,
The backlight source is a white light source having a continuous emission spectrum;
The polarizing plate has a structure in which a polarizer protective film is laminated on both sides of a polarizer,
At least one of the polarizer protective films of the polarizing plate arranged on the incident light side, and at least one of the polarizer protective films of the polarizing plate arranged on the outgoing light side have a retardation of 4000 to 30,000 nm and Nz of 1.7 or less. An oriented polyester film having a coefficient,
Liquid crystal display device. - 前記入射光側に配される偏光板の入射光側の偏光子保護フィルム及び前記出射光側に配される偏光板の出射光側の偏光子保護フィルムが、4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムである、請求項1記載の液晶表示装置。 The polarizer protective film on the incident light side of the polarizing plate arranged on the incident light side and the polarizer protective film on the outgoing light side of the polarizing plate arranged on the outgoing light side have a retardation of 4000 to 30000 nm and 1.7. The liquid crystal display device according to claim 1, which is an oriented polyester film having the following Nz coefficient.
- 配向ポリエステルフィルムの面配向度が0.13以下である、請求項1又は2記載の液晶表示装置。 The liquid crystal display device according to claim 1 or 2, wherein the orientation degree of the oriented polyester film is 0.13 or less.
- 前記連続した発光スペクトルを有する白色光源が、白色発光ダイオードである、請求項1~3のいずれかに記載の液晶表示装置。 The liquid crystal display device according to any one of claims 1 to 3, wherein the white light source having a continuous emission spectrum is a white light emitting diode.
- 偏光子の両側に偏光子保護フィルムを積層した構成からなり、
少なくとも片側の偏光子保護フィルムが4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムである、連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光板。 Consists of a structure in which a polarizer protective film is laminated on both sides of the polarizer,
A polarizing plate for a liquid crystal display device using a white light source having a continuous emission spectrum as a backlight light source, wherein the polarizer protective film on at least one side is an oriented polyester film having a retardation of 4000 to 30000 nm and an Nz coefficient of 1.7 or less. - 前記配向ポリエステルフィルムの面配向度が0.13以下である、請求項5記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光板。 The polarizing plate for liquid crystal display devices which uses as a backlight light source the white light source which has the continuous emission spectrum of Claim 5 whose surface orientation degree of the said oriented polyester film is 0.13 or less.
- 4000~30000nmのリタデーション及び1.7以下のNz係数を有する配向ポリエステルフィルムからなる、連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。 A polarizer protective film for a liquid crystal display device comprising a white light source having a continuous emission spectrum, which comprises an oriented polyester film having a retardation of 4000 to 30000 nm and an Nz coefficient of 1.7 or less, as a backlight source.
- 前記配向ポリエステルフィルムの面配向度が0.13以下であることを特徴とする、請求項7記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。 The polarizer protective film for a liquid crystal display device using a white light source having a continuous emission spectrum according to claim 7 as a backlight light source, wherein the orientation degree of the oriented polyester film is 0.13 or less.
- 前記配向ポリエステルフィルムが易接着層を有する、請求項7又は8記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。 The polarizer protective film for liquid crystal display devices which uses as a backlight light source the white light source which has the continuous emission spectrum of Claim 7 or 8 in which the said orientation polyester film has an easily bonding layer.
- 前記配向ポリエステルフィルムが少なくとも3層からなり、最外層以外の層に紫外線吸収剤を含有し、380nmの光線透過率が20%以下である、請求項7~9のいずれかに記載の連続した発光スペクトルを有する白色光源をバックライト光源とする液晶表示装置用偏光子保護フィルム。
The continuous light emission according to any one of claims 7 to 9, wherein the oriented polyester film comprises at least three layers, contains an ultraviolet absorber in a layer other than the outermost layer, and has a light transmittance of 380 nm of 20% or less. A polarizer protective film for a liquid crystal display device using a white light source having a spectrum as a backlight source.
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Also Published As
Publication number | Publication date |
---|---|
CN108845451A (en) | 2018-11-20 |
KR102149433B1 (en) | 2020-10-14 |
JPWO2014021242A1 (en) | 2016-07-21 |
CN104508545B (en) | 2018-07-27 |
JP2020098344A (en) | 2020-06-25 |
JP2022050579A (en) | 2022-03-30 |
KR102097392B1 (en) | 2020-04-06 |
KR20150041791A (en) | 2015-04-17 |
JP7272474B2 (en) | 2023-05-12 |
CN104508545A (en) | 2015-04-08 |
TW201411202A (en) | 2014-03-16 |
JP6443048B2 (en) | 2018-12-26 |
JP7070590B2 (en) | 2022-05-18 |
TWI530716B (en) | 2016-04-21 |
KR20200035477A (en) | 2020-04-03 |
JP2019028472A (en) | 2019-02-21 |
CN108845451B (en) | 2021-12-10 |
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