WO2014012432A1 - Front-side electrode structure of solar cell sheet and fabrication method therefor - Google Patents

Front-side electrode structure of solar cell sheet and fabrication method therefor Download PDF

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Publication number
WO2014012432A1
WO2014012432A1 PCT/CN2013/078779 CN2013078779W WO2014012432A1 WO 2014012432 A1 WO2014012432 A1 WO 2014012432A1 CN 2013078779 W CN2013078779 W CN 2013078779W WO 2014012432 A1 WO2014012432 A1 WO 2014012432A1
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Prior art keywords
conductive
battery sheet
solar cell
conductive paste
electrode structure
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PCT/CN2013/078779
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French (fr)
Chinese (zh)
Inventor
武宇涛
马勇
秋晨
王磊
武建康
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杭州塞利仕科技有限公司
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Publication of WO2014012432A1 publication Critical patent/WO2014012432A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Definitions

  • the invention relates mainly to the field of solar cells, in particular to a front electrode structure of a solar cell and a manufacturing method for fabricating the same.
  • the structure of the front electrode pattern of the existing solar cell includes a fine gate line and a main gate line, and the fine gate line and the main gate line generally intersect perpendicularly.
  • the function of the fine grid line is to collect the photo-generated current generated by the solar illumination on the surface of the cell sheet
  • the function of the main gate line is to collect and derive the current collected by the fine grid line. Since the fine gate line and the main gate line occupy a certain surface area on the front surface of the solar cell sheet and adhere to the surface of the battery sheet, this has an important influence on the photoelectric conversion efficiency of the solar cell sheet, and therefore, the fine gate is formed in the fabrication process.
  • the fabrication of the line and the main gate line presents different requirements: for the fine grid line, not only a narrower, higher and flatter surface topography is required, but also a lower gate line has lower contact resistance and bulk resistance, which is Requires fine grid wire conductive paste not only has good printing performance In order to make the printed fine grid line have better printing plasticity without collapsing in the subsequent drying and sintering process, it is also required to have better contact performance with the surface of the battery sheet, that is, better ohmic contact characteristics, and more Low contact resistance; for the main gate line, since its width is much larger than the fine gate line, its printing performance is much lower than that of the fine gate line.
  • the current manufacturing process of the industrialized crystalline silicon solar cell includes the following steps: The cell is cleaned and surface-textured to form a surface textured structure to reduce surface reflectance; 2. Diffusion to form a PN junction; 3. Edge etching and cleaning to isolate the positive and negative electrodes of the cell to prevent short circuit; Coating, surface passivation and reduced reflectivity; 5. Screen printing positive and negative electrodes and back electric field; 6. Co-sintering of positive and negative electrodes and back electric field; 7. Test sorting.
  • the front electrode metallization scheme of the prior art crystalline silicon solar cell is mainly realized by a screen printing process.
  • the screen printing process produces a solar cell front electrode which is characterized by: using the permeability of the screen, the conductive paste (generally silver paste) is transmitted through the screen under the pressure of the squeegee, thereby forming on the crystalline silicon solar cell sheet.
  • An electrode pattern having a certain height and spacing.
  • the fine gate line and the main gate line pattern are simultaneously fabricated on one screen, and the same conductive paste, fine gate line and main gate line pattern are used in printing. It is also printed on the battery.
  • this integrated, generalized front electrode fabrication process causes unnecessary technical and technical waste and loss.
  • the existing screen printing process also has its own defects, such as the problem of broken gate and virtual printing generated during the printing process, which causes a certain efficiency loss to the battery chip, and also causes certain components for the subsequent package. Power loss.
  • the instability of the screen printing process itself such as the degradation of the screen tension caused by the continuous pressure during use, and the increase of the width of the grid line, have a great impact on the overall distribution of the efficiency of the cell. , caused a certain reduction in overall efficiency.
  • the width of the fine grid line produced by the screen printing process is limited by the screen and the conductive silver paste, and it is difficult to achieve a certain narrowness while ensuring a certain height of the electrode.
  • the conductive paste must have a certain viscosity, and the greater the viscosity of the conductive paste, the less easy it is.
  • the invention opens up a new process for making a front electrode completely different from the existing screen printing method, avoids many quality problems of the screen printing process, and improves the yield, stability and power output of the photovoltaic product.
  • the present invention has been made in view of the above problems, and provides a solar cell front electrode structure comprising a cell sheet and a conductive filament, the conductive filament coated conductive paste being attached to the front surface of the cell sheet.
  • the entire outer surface of the conductive filament is coated with a conductive paste.
  • the length of the conductive wire adhered to the front surface of the battery sheet is smaller than the size of the battery sheet, and both ends thereof do not protrude from the front edge of the battery sheet.
  • the end edges of the conductive filaments pasted on the front surface of the battery sheet do not enter the etched area of the edge of the battery sheet.
  • both end edges of the conductive filament pasted on the front surface of the battery sheet have a neat discontinuous portion not covering the conductive paste.
  • the distance between the two end edges of the conductive wire covering the conductive paste and the two end edges of the battery sheet is 0.5mm-2mm and symmetrical on both sides.
  • the conductive wire may be a metal wire, a polymer fiber having a certain conductive property, or a metal wire and a polymer fiber having various conductive plating layers, and the conductive paste is a silver paste.
  • the conductive filament has a diameter ranging from 0.01 mm to 0.03 mm.
  • the conductive wire may have a cross-sectional shape of a rectangle, a trapezoid, a triangle, a circle, an ellipse, or other shapes.
  • the conductive filaments are plural, and the spacing between the plurality of conductive filaments ranges from 0.5 mm to 3 mm.
  • the battery sheet may be a polycrystalline silicon battery or a single crystal silicon battery.
  • the front surface of the battery chip includes a main gate line, and the conductive wire is pasted in a direction perpendicular to the main grid line.
  • a portion where the conductive wire intersects the main gate line is embedded inside the main gate line.
  • One of the objects of the present invention is to solve the problems that the current screen printing process has high manufacturing cost, the conversion efficiency of the fabricated solar cell product is low, and the fine grid line is difficult to achieve a certain narrowness.
  • a method for fabricating a front electrode structure of a solar cell comprising:
  • the method further comprises forming a main gate line with a conductive paste on the battery sheet before the conductive filament is adhered to the battery sheet.
  • the method further comprises, after the conductive filaments are adhered to the battery sheet, forming a main gate line on the battery sheet with a conductive paste.
  • the conductive filaments are embedded in the conductive paste of the main gate line when the conductive filaments are adhered to the surface of the battery sheet.
  • the entire outer surface of the conductive filament is uniformly coated with a conductive paste.
  • the length of the conductive filament covering the conductive paste is made smaller than the size of the battery sheet, and both end edges of the conductive filament are made to have a neat discontinuous portion without being covered. Conductive paste.
  • the both end edges of the conductive filament covering the conductive paste do not enter the etched area of the edge of the battery sheet.
  • the distance between the two end edges of the conductive wire covering the conductive paste and the two end edges of the battery sheet is 0.5mm-2mm and symmetrical on both sides.
  • the conductive filaments are arranged in parallel at equal intervals before the conductive paste is coated.
  • the conductive wire used may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers.
  • the conductive filaments used have a diameter ranging from 0.01 mm to 0.03 mm.
  • the cross-sectional shape of the conductive filament may be rectangular, trapezoidal, triangular, circular, elliptical, or the like, or may be other shapes.
  • the conductive paste used as the main gate line and the conductive paste used on the conductive wire may be the same conductive paste, or different conductive pastes may be used separately.
  • the conductive filaments are spaced apart by a pitch of 0.5 mm to 3 mm.
  • the main gate line may be formed on the battery sheet by screen printing, or may be fabricated by other methods such as letterpress printing.
  • the drying step has a drying temperature ranging from 100 °C to 400 °C.
  • the sintering step has a sintering temperature ranging from 400 °C to 950 °C.
  • the solar electrode structure of the present invention and the manufacturing method thereof have the advantages that the width of the front surface of the solar cell of the structure is smaller than the width of the fine grid line of the screen printing, the front light shielding area can be reduced, and the thinning is further improved.
  • the conductivity of the grid line thereby improving the conversion efficiency of the battery; at the same time, the use of conductive wire wrap, reducing the use of conductive paste in screen printing, reducing the use of conductive paste, thereby reducing the solar cell
  • the electrode fabrication cost; on the other hand, the electrode structure of the present invention does not have printing defects such as broken gates and flops.
  • the electrode structure and method of the present invention also provides a new solar cell product product and a new method for fabricating solar cell products that increase efficiency and reduce cost for the current solar cell industry.
  • Figure 1 is a partial cross-sectional view showing the structure of the front electrode of the solar cell
  • FIG. 2 is a schematic view of a row of conductive wires
  • Figure 3 is a schematic view of a conductive filament wrapped with a conductive paste
  • Figure 4 is a schematic view of a battery sheet in which a main gate line is formed
  • Figure 5 is a schematic diagram of a completed complete battery
  • Figure 6 is a cross-sectional view of the fabricated cell sheet along the main gate line
  • Figure 7 is a flow chart showing the structure of the front electrode of a solar cell.
  • FIG. 5 is a schematic structural diagram of a front electrode of a solar cell according to the present invention
  • FIG. 1 A partial cross-sectional view of a solar front electrode structure of the present invention.
  • the front electrode structure of the solar cell includes a battery sheet 3 and a conductive wire 1, and the conductive wire 1 passes through the conductive paste 2 Adhered to the surface of the battery sheet 3, the diameter of the conductive filament 1 ranges from 0.01 mm to 0.03 mm. As can be seen from the cross-sectional view 1, the entire outer surface of the conductive filament 1 is covered with a conductive paste 2 .
  • a plurality of conductive filaments 1 are adhered to the battery sheet 3 at equal intervals in parallel, and the conductive filaments 1 The spacing between them ranges from 0.5mm to 3mm.
  • a main gate line 4 can be printed by screen printing on the uncoated cell sheet 3. It can also be produced by other methods such as letterpress printing.
  • the conductive filament 1 is attached to the battery sheet 3 in a direction perpendicular to the main grid line 4.
  • FIG. 6 it is a cross-sectional view of the fabricated cell sheet along the main gate line when the conductive filament 1 is adhered to have the main gate line 4
  • the conductive wire 1 is embedded in the inside of the conductive paste of the main gate line 4, so that the main gate line 4 and the fine gate line 1 Good contact between them facilitates current flow and reduces power loss.
  • the length of both ends of the conductive wire 1 adhered to the battery piece 3 is smaller than the length dimension of the corresponding battery piece, and the conductive wire
  • the end of the first end, that is, the ends of the ends of the battery piece 3 are not beyond the edge of the battery sheet 3, and the distance between the end edges of the conductive wire 1 and the edge of the battery sheet 3 is 0.5 mm - 2 mm.
  • the two sides are symmetrical.
  • the both end edges of the conductive wire 1 pasted on the front surface of the battery sheet 3 do not enter the etched area at the both end edges of the battery sheet 3, and the conductive wires of the battery sheet 3 are pasted 1
  • the edge of both ends has a neat discontinuity without coating the conductive paste 2 to avoid the leakage of the edge caused by the conductive paste 2 sticking to the etched regions at the both end edges of the battery sheet 3, resulting in inefficiency.
  • Conductive wire 1 It may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers. In the present embodiment, a metal wire is used.
  • Figure 7 Shown is a flow chart of the method of the present invention, showing the basic flow of a process for fabricating a front electrode of a solar cell sheet, first by coating a conductive paste on a row of cylindrical conductive filaments 1 arranged at equal intervals.
  • the spacing between the conductive filaments 1 ranges from 0.5 mm to 3 mm
  • the diameter of the conductive filaments 1 ranges from 0.01 mm to 0.03 mm, as shown in Fig. 2
  • the conductive filaments 1 are arranged at equal intervals, and the conductive paste 1 is coated on the above-mentioned aligned conductive filaments 1.
  • the conductive paste 2 has excellent electrical conductivity and can be combined with the battery sheet 3.
  • the surface has excellent contact properties and has excellent adhesion to the surface of the cell sheet 3 to avoid the occurrence of detachment of the conductive filament 1 from the surface of the cell sheet 3 after the subsequent sintering process.
  • Figure 3 As shown, it can be seen that the conductive paste 2 has been coated on the row of the conductive filaments 1, better as shown in Fig. 1, which shows the cross-section of the coated conductive filament 1, from which it can be seen Out, conductive wire 1 The outer surface of the outer surface is completely wrapped with conductive paste 2, and the conductive wire 1 is completely covered with the conductive paste to avoid the conductive wire 1 In the subsequent high-temperature sintering process, the conductivity deterioration due to surface oxidation is exposed in a high temperature environment. As shown in Figure 4, it is shown in the cell sheet 3 before the wire is applied.
  • the main gate line 4 is printed on the battery chip 3 by a screen printing method or the like for use in the next step.
  • the conductive wire 1 is made of a metal wire and has a circular cross section, and is used as the conductive paste 2 of the main gate line 4 and for the conductive wire 1
  • the conductive paste 2 on the same uses the same conductive paste.
  • the spacing of the conductive filaments 1 can be determined by considering the conductive filaments 1 The diameter is adjusted by experimentally considering the conversion efficiency and the number of conductive filaments 1 on the battery sheet 3.
  • the main gate line 4 can be first applied to the cell sheet by screen printing.
  • the upper fabrication can also be made by other methods such as letterpress printing, and the main gate line 4 screen printed on the battery sheet 3 is not dried, and the width of the main gate line 4 is 1-3 mm, and the number of the main grid lines is Generally 2-3
  • the battery piece 3 having the main grid line 4 is prepared for use in the manufacturing method of the present invention.
  • the conductive filament 1 which has been coated with the conductive paste 2 is perpendicular to the main grid line 4
  • the direction is pasted on the cell sheet 3 on which the main gate line has been printed.
  • Fig. 1 it can be seen that the conductive filament 1 is bonded to the battery sheet 3 through the conductive paste 2.
  • conductive wire 1 The entire outer surface is completely wrapped around the conductive paste 2 .
  • the conductive filament 1 is embedded in the main grid line 4 Inside the conductive paste, as shown in Fig. 6, the portion where the conductive wire 1 intersects with the main gate line has been completely embedded inside the main gate line 4, which facilitates current flow between the conductive wire 1 and the main gate line 4.
  • the battery sheet 3 of the conductive filament 1 has been pasted (as shown in Fig. 5, the conductive filament 1 has been attached)
  • the battery piece is baked at a temperature of 200-400 ° C, and then sintered at a temperature of 700-900 ° C together with the back electrode, so that the conductive paste and the conductive wire are sintered into a complete conductor, so that the conductive paste is coated.
  • the conductive filament 1 forms a strong alloyed contact and excellent ohmic contact with the main gate line 4 and the surface of the cell sheet 3. At this point, the electrode is completed.
  • the advantage of this embodiment is that the width of the obtained fine grid line (i.e., after the conductive wire 1 is coated with the conductive paste 2 is sintered) is less than 0.06. In millimeters, the shading area of the fine grid lines is greatly reduced, and the conductive wires are used for the fine grid lines, which greatly saves the conductive paste and further reduces the cost.
  • the wire portion of the conductive filament 1 does not wrap the conductive paste 2, as shown in FIG. As shown in the figure, the wire portion is not covered with the conductive paste 2 .
  • the length of the conductive filament 1 is made smaller than the length dimension of the battery sheet 3, and when the conductive filament 2 is attached to the battery sheet 3 When it is up, as shown in Figure 5, the edge of the conductive wire 1 does not extend beyond the edge of the cell 3.
  • the printed main gate line 4 can also be screen printed after the fine grid lines are attached.
  • FIG. 5 is a schematic structural diagram of a front electrode of a solar cell according to the present invention
  • FIG. 1 A partial cross-sectional view of a solar front electrode structure of the present invention.
  • the front electrode structure of the solar cell includes a battery sheet 3 and a conductive wire 1, and the conductive wire 1 passes through the conductive paste 2 Adhered to the surface of the battery sheet 3, the diameter of the conductive filament 1 ranges from 0.01 mm to 0.03 mm. As can be seen from the cross-sectional view 1, the entire outer surface of the conductive filament 1 is covered with a conductive paste 2 .
  • a plurality of conductive filaments 1 are adhered to the battery sheet 3 at equal intervals in parallel, and the conductive filaments 1 The spacing between them ranges from 0.5mm to 3mm.
  • a main gate line 4, a main gate line 4 can be printed by screen printing on the uncoated cell sheet 3. It can also be produced by other methods such as letterpress printing.
  • the conductive filament 1 is attached to the battery sheet 3 in a direction perpendicular to the main grid line 4.
  • Another alternative embodiment is the battery sheet 3 The main grid line 4 is not printed thereon.
  • the conductive wire 1 is pasted on the battery sheet 3, and then the battery sheet 3 to which the conductive filament 1 is adhered is screen-printed, perpendicular to the fine grid line (ie, the conductive wire 1) In the direction of the print, the line is deleted 4 .
  • FIG. 6 it is a cross-sectional view of the fabricated cell sheet along the main gate line when the conductive filament 1 is adhered to have the main gate line 4
  • the conductive wire 1 is embedded in the inside of the conductive paste of the main gate line 4, so that the main gate line 4 and the fine gate line 1 Good contact between them facilitates current flow and reduces power loss.
  • the length of both ends of the conductive wire 1 adhered to the battery piece 3 is smaller than the length dimension of the corresponding battery piece, and the conductive wire
  • the end of the first end, that is, the ends of the two ends of the wire 3 are not beyond the edge of the battery sheet 3, and the distance between the end edges of the conductive wire 1 and the edge of the battery sheet 3 is 0.5 mm - 2 mm, and the two sides are symmetrical.
  • a preferred embodiment is that the end edges of the conductive filament 1 adhered to the front surface of the battery sheet 3 do not enter the battery sheet 3 The etched area at the edges of the ends.
  • a preferred embodiment is that the ends of the conductive filaments 1 pasting the battery sheets 3 have neat discontinuities without coating the conductive paste 2 In order to avoid leakage of the conductive paste 2 to the etched area at the edge of the battery chip 3, the leakage of the edge leads to inefficiency.
  • Conductive wire used in the present invention 1 It may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers.
  • the invention is applicable not only to ordinary types of crystalline silicon solar cells, but also to solar cell electrodes of the invention.
  • Figure 7 Shown is a flow chart of the method of the present invention, showing the basic flow of a process for fabricating a front electrode of a solar cell sheet, first by coating a conductive paste on a row of cylindrical conductive filaments 1 arranged at equal intervals.
  • the spacing between the conductive filaments 1 ranges from 0.5 mm to 3 mm
  • the diameter of the conductive filaments 1 ranges from 0.01 mm to 0.03 mm, as shown in Fig. 2
  • the conductive filaments 1 are arranged at equal intervals, and the conductive paste 1 is coated on the above-mentioned aligned conductive filaments 1.
  • the conductive paste 2 has excellent electrical conductivity and can be combined with the battery sheet 3.
  • the surface has excellent contact properties and has excellent adhesion to the surface of the cell sheet 3 to avoid the occurrence of detachment of the conductive filament 1 from the surface of the cell sheet 3 after the subsequent sintering process.
  • Figure 3 As shown, it can be seen that the conductive paste 2 has been coated on the row of the conductive filaments 1, better as shown in Fig. 1, which shows the cross-section of the coated conductive filament 1, from which it can be seen Out, conductive wire 1 The outer surface of the outer surface is completely wrapped with conductive paste 2, and the conductive wire 1 is completely covered with the conductive paste to avoid the conductive wire 1 In the subsequent high-temperature sintering process, the conductivity deterioration due to surface oxidation is exposed in a high temperature environment. As shown in Figure 4, it is shown in the cell sheet 3 before the wire is applied.
  • the main gate line 4 is printed on the battery chip 3 by a screen printing method or the like for use in the next step.
  • the conductive filament 1 which has been coated with the conductive paste 2 is perpendicular to the main grid line 4 The direction is pasted on the cell sheet 3 on which the main gate line has been printed. As shown in Fig. 1, it can be seen that the conductive filament 1 is bonded to the battery sheet 3 through the conductive paste 2. And conductive wire 1 The entire outer surface is completely wrapped around the conductive paste 2 .
  • the battery sheet 3 of the conductive filament 1 has been pasted (as shown in Fig. 5, the conductive filament 1 has been attached)
  • the battery piece is baked at a temperature of 200-400 ° C, and then sintered at a temperature of 700-900 ° C together with the back electrode, so that the conductive paste and the conductive wire are sintered into a complete conductor, so that the conductive paste is coated.
  • the conductive filament 1 forms a strong alloyed contact and excellent ohmic contact with the main gate line 4 and the surface of the cell sheet 3. At this point, the electrode is completed.
  • the advantage of this embodiment is that the width of the obtained fine grid line (i.e., after the conductive wire 1 is coated with the conductive paste 2 is sintered) is less than 0.06. In millimeters, the shading area of the fine grid lines is greatly reduced, and the conductive wires are used for the fine grid lines, which greatly saves the conductive paste and further reduces the cost.
  • the conductive wire 1 It may be a metal wire, a polymer fiber having a certain electrical conductivity, or a conductive wire made of a conductive material such as a metal wire and a polymer fiber having various conductive plating layers.
  • conductive paste 2 used as the main gate line 4 and the conductive paste for the conductive filament 1 It may be the same conductive paste, or different conductive pastes may be used separately, and different conductive pastes may be used as needed.
  • conductive wire 1 The cross-sectional shape may be a rectangle, a trapezoid, a triangle, a circle, an ellipse or the like, or may be other shapes, and in the example of the present invention, it is preferably a circle.
  • the spacing of the conductive filaments 1 can be determined by considering the conductive filaments 1 The diameter is adjusted by experimentally considering the conversion efficiency and the number of conductive filaments 1 on the battery sheet 3.
  • the main gate line 4 It may be first formed on the battery sheet 3 by screen printing, or may be produced by other methods such as letterpress printing, and the main gate line 4 screen-printed on the battery sheet 3 is not dried, and the main gate line 4 is Width is 1-3 mm, the number of main grid lines is generally 2-3, and the battery sheet 3 having the main grid line 4 is prepared for use in the manufacturing method of the present invention.
  • the conductive wire 1 is embedded inside the conductive paste of the main gate line 4, as shown in Fig. 6, the intersection of the conductive wire 1 and the main gate line has been completely embedded inside the main gate line 4, which is advantageous for the conductive wire 1 Current flow with the main gate line 4.
  • the conductive yarn 1 is adhered to the battery sheet 3 in accordance with the structure shown in Fig. 1, at 100 °C. Dry at -400 °C and then with the back electrode at 400 °C -950 Sintering at a temperature of °C causes the conductive paste (generally silver paste) to form a good ohmic contact with the cell sheet, while the conductive paste and the conductive filament are sintered into a complete conductor.
  • the conductive paste generally silver paste
  • an optional method step is that the wire portion of the conductive wire 1 does not wrap the conductive paste during the winding process of the conductive filament 1 As shown in Fig. 3, the wire portion is not covered with the conductive paste 2 .
  • another optional method step is to make the length of the conductive filament 1 smaller than the battery sheet 3
  • the printed main gate line 4 can also be screen printed after the fine gate line is pasted.
  • the above manufacturing process of the invention has the advantages of reducing the width of the fine gate line of the front surface of the solar cell, improving the conductivity of the fine gate line, thereby improving the conversion efficiency of the battery, reducing the usage amount of the conductive paste, thereby reducing the amount of the conductive paste.
  • the electrode manufacturing cost of the solar cell avoids printing defects such as broken gates and flops due to defects in the screen printing process itself, and also makes the efficiency distribution of the cells more concentrated by avoiding the use of the screen.
  • the fine gate line and the main gate line can also respectively use the conductive paste which is more matched with its function; more importantly, instead of the conventional screen printing process, the fabrication of the fine gate line of the front electrode of the solar cell is not only It avoids many problems of the screen printing process itself, and provides a new way to increase efficiency and reduce costs for the current solar cell industry.
  • Another advantage of the manufacturing method of the present invention is that the conductive wire strengthens the strength of the battery sheet like the steel bar in the cement, so that the battery sheet is not brittle, and at the same time, because the conductive wire has good toughness, even if the battery sheet is cracked, the wire still has the battery.
  • the sheets are integrated into one body, and the current flows in the same way, thereby avoiding the problem of lowering the photoelectric conversion efficiency due to the crack of the broken gate in the current process, and can reduce the difficulty of the subsequent processing and improve the yield.
  • the solar electrode structure of the present invention and the manufacturing method thereof have the advantages that the width of the front surface of the solar cell of the structure is smaller than the width of the fine grid line of the screen printing, the front light shielding area can be reduced, and the thinning is further improved.
  • the conductivity of the grid line thereby improving the conversion efficiency of the battery; at the same time, the use of conductive wire wrap, reducing the use of conductive paste in screen printing, reducing the use of conductive paste, thereby reducing the solar cell
  • the electrode fabrication cost; on the other hand, the electrode structure of the present invention does not have printing defects such as broken gates and flops.
  • the electrode structure and method of the present invention also provides a new solar cell product product and a new method for fabricating solar cell products that increase efficiency and reduce cost for the current solar cell industry.

Abstract

The present invention relates to a front-side electrode structure of a solar cell sheet and a fabrication method therefor. The structure comprises a cell sheet and a conducting wire, the conducting wire being coated with a conducting paste and adhered to a surface of the cell sheet. A method for fabricating the front-side electrode structure of a cell sheet is also involved, comprising: coating a conducting paste onto the surface of a conducting wire; adhering the conducting wire coated with the conducting paste onto the cell sheet; and placing the fabricated cell sheet into a drying and sintering furnace for drying and sintering. The advantages of the front-side electrode structure of a solar cell sheet and the fabrication method therefor of the present invention are that the width of a front-side fine grid line of a solar cell is reduced greatly, the electric conductivity of the fine grid line is improved and the light receiving surface is increased, thus improving the conversion efficiency of the cell; and the usage amount of a conducting paste in the fabrication process is decreased, thus reducing the electrode fabrication cost of a solar cell sheet.

Description

一种太阳能电池片正面电极结构及其制作方法  Solar cell sheet front electrode structure and manufacturing method thereof 技术领域Technical field
本发明主要是关于太阳能电池领域,尤其涉及太阳能电池片正面电极结构以及制作该结构的制作方法。  The invention relates mainly to the field of solar cells, in particular to a front electrode structure of a solar cell and a manufacturing method for fabricating the same.
背景技术Background technique
现有的太阳能电池的正面电极图案的结构包括细栅线和主栅线,细栅线和主栅线一般垂直交叉。其中,细栅线的作用是收集电池片表面由于太阳光照所产生的光生电流,而主栅线的作用是汇集并导出由细栅线收集的电流。由于细栅线和主栅线会在太阳能电池片的正面占据一定的表面积并粘附在电池片面,这会对太阳能电池片的光电转换效率产生重要的影响,因此,在制作工艺上对细栅线和主栅线的制作提出了不同的要求:对于细栅线,不仅要求具有更窄更高和更平整的表面形貌,也要求细栅线具有更低的接触电阻和体电阻,这就要求细栅线的导电浆料不仅具有良好的印刷性能 ,使印刷出来的细栅线具有更好的印刷塑性而不致于在后续的烘干和烧结过程塌陷,也要求其与电池片表面具有更好的接触性能,即更好的欧姆接触特性,更低的接触电阻;对于主栅线,由于其宽度比细栅线大得多,对于其印刷性能的要求比细栅线的要低得多。 The structure of the front electrode pattern of the existing solar cell includes a fine gate line and a main gate line, and the fine gate line and the main gate line generally intersect perpendicularly. Among them, the function of the fine grid line is to collect the photo-generated current generated by the solar illumination on the surface of the cell sheet, and the function of the main gate line is to collect and derive the current collected by the fine grid line. Since the fine gate line and the main gate line occupy a certain surface area on the front surface of the solar cell sheet and adhere to the surface of the battery sheet, this has an important influence on the photoelectric conversion efficiency of the solar cell sheet, and therefore, the fine gate is formed in the fabrication process. The fabrication of the line and the main gate line presents different requirements: for the fine grid line, not only a narrower, higher and flatter surface topography is required, but also a lower gate line has lower contact resistance and bulk resistance, which is Requires fine grid wire conductive paste not only has good printing performance In order to make the printed fine grid line have better printing plasticity without collapsing in the subsequent drying and sintering process, it is also required to have better contact performance with the surface of the battery sheet, that is, better ohmic contact characteristics, and more Low contact resistance; for the main gate line, since its width is much larger than the fine gate line, its printing performance is much lower than that of the fine gate line.
目前常规的产业化晶体硅太阳能电池的制作工艺包括以下步骤: 1. 电池片清洗和表面制绒,形成表面织构化结构,降低表面反射率; 2. 扩散,形成 PN 结; 3. 边缘刻蚀及清洗,使电池片的正负电极隔离以防短路; 4. 镀膜,表面钝化和降低反射率; 5. 丝网印刷正反电极和背电场; 6. 正反电极及背电场共烧结; 7. 测试分选。  The current manufacturing process of the industrialized crystalline silicon solar cell includes the following steps: The cell is cleaned and surface-textured to form a surface textured structure to reduce surface reflectance; 2. Diffusion to form a PN junction; 3. Edge etching and cleaning to isolate the positive and negative electrodes of the cell to prevent short circuit; Coating, surface passivation and reduced reflectivity; 5. Screen printing positive and negative electrodes and back electric field; 6. Co-sintering of positive and negative electrodes and back electric field; 7. Test sorting.
现有技术的晶体硅太阳能电池的正面电极金属化方案,主要是通过丝网印刷工艺来实现的。丝网印刷工艺制作太阳能电池正面电极的特点是:利用网版的通透性,使导电浆料(一般为银浆)在刮板的压力下透过网版,从而在晶体硅太阳能电池片上形成具有一定高度和间隔的电极图案。 The front electrode metallization scheme of the prior art crystalline silicon solar cell is mainly realized by a screen printing process. The screen printing process produces a solar cell front electrode which is characterized by: using the permeability of the screen, the conductive paste (generally silver paste) is transmitted through the screen under the pressure of the squeegee, thereby forming on the crystalline silicon solar cell sheet. An electrode pattern having a certain height and spacing.
技术问题technical problem
由于现有丝网印刷工艺的限制,在实际生产中,细栅线和主栅线图形同时制作在一块网版上,在印刷时,使用同样的导电浆料,细栅线和主栅线图形也就同时被印刷在电池片上。尤其是对于主栅线,在对成本控制非常严格的情况下,这种一体化的、笼统的正面电极制作工艺造成了不必要的技术性、工艺性的浪费和损失。 Due to the limitations of the existing screen printing process, in actual production, the fine gate line and the main gate line pattern are simultaneously fabricated on one screen, and the same conductive paste, fine gate line and main gate line pattern are used in printing. It is also printed on the battery. Especially for the main gate line, in the case of very strict cost control, this integrated, generalized front electrode fabrication process causes unnecessary technical and technical waste and loss.
另外,现有丝网印刷工艺,也有其本身的缺陷,比如在印刷过程中产生的断栅和虚印等问题,对电池片造成了一定的效率损失,也对后续封装的组件造成了一定的功率损失。另外丝网印刷工艺本身的不稳定性,比如在使用过程中由于持续不断的压力造成的网版张力的退化,以及栅线宽度的增加,都对电池片效率的整体分布产生了很大的影响,对整体效率造成了一定的降低。 In addition, the existing screen printing process also has its own defects, such as the problem of broken gate and virtual printing generated during the printing process, which causes a certain efficiency loss to the battery chip, and also causes certain components for the subsequent package. Power loss. In addition, the instability of the screen printing process itself, such as the degradation of the screen tension caused by the continuous pressure during use, and the increase of the width of the grid line, have a great impact on the overall distribution of the efficiency of the cell. , caused a certain reduction in overall efficiency.
此外,丝网印刷工艺制作的细栅线宽度,由于受到网版和导电银浆的限制,在保证电极一定高度的情况下,很难达到一定的窄度。具体来说主要存在下面这样一个矛盾:制作成的细栅线如果要有良好的塑性和印刷形貌,导电浆料就要有一定大的黏度,而导电浆料黏度越大,就越不容易透过网版。而对于太阳能电池来说,只有降低细栅线的宽度才能减小正面遮光面积,从而提升电池的转换效率。而丝网印刷工艺在降低电池正面电极细栅线宽度方面,面临着巨大的困难和严峻的挑战。 In addition, the width of the fine grid line produced by the screen printing process is limited by the screen and the conductive silver paste, and it is difficult to achieve a certain narrowness while ensuring a certain height of the electrode. Specifically, there is mainly a contradiction in the following: if a fine grid line is formed with good plasticity and printing morphology, the conductive paste must have a certain viscosity, and the greater the viscosity of the conductive paste, the less easy it is. Through the web version. For solar cells, only reducing the width of the fine grid lines can reduce the front light-shielding area, thereby improving the conversion efficiency of the battery. The screen printing process faces enormous difficulties and severe challenges in reducing the width of the fine grid lines on the front side of the battery.
一种能解决上述矛盾的新的电极结构及其制作工艺的出现,也就具有了显著的现实意义。本发明开辟了一种完全不同于现有的丝网印刷的方式制作正面电极的新工艺,规避丝网印刷工艺的诸多质量问题,提高了光伏产品的成品率、稳定性及功率输出。 A new electrode structure and its fabrication process that can solve the above contradictions have significant practical significance. The invention opens up a new process for making a front electrode completely different from the existing screen printing method, avoids many quality problems of the screen printing process, and improves the yield, stability and power output of the photovoltaic product.
技术解决方案Technical solution
本发明针对上述问题提出了一种太阳能电池片正面电极结构,所述结构包括电池片和导电丝,所述导电丝裹覆导电浆料粘贴在所述电池片的正面上。 SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and provides a solar cell front electrode structure comprising a cell sheet and a conductive filament, the conductive filament coated conductive paste being attached to the front surface of the cell sheet.
优选地,所述导电丝整个外表面都裹覆有导电浆料。 Preferably, the entire outer surface of the conductive filament is coated with a conductive paste.
优选地,粘贴于所述电池片正面上的所述导电丝的长度小于所述电池片的尺寸,其两端不伸出所述电池片的正面边缘。 Preferably, the length of the conductive wire adhered to the front surface of the battery sheet is smaller than the size of the battery sheet, and both ends thereof do not protrude from the front edge of the battery sheet.
优选地,粘贴于所述电池片正面上的所述导电丝的两端边缘未进入电池片边缘的刻蚀区域。 Preferably, the end edges of the conductive filaments pasted on the front surface of the battery sheet do not enter the etched area of the edge of the battery sheet.
优选地,粘贴所述电池片正面的所述导电丝的两端边缘具有整齐的间断部分没有裹覆所述导电浆料。 Preferably, both end edges of the conductive filament pasted on the front surface of the battery sheet have a neat discontinuous portion not covering the conductive paste.
优选地,裹覆了所述导电浆料的所述导电丝的两端边缘分别与所述电池片两端边缘的距离为 0.5mm-2mm ,且两边对称。 Preferably, the distance between the two end edges of the conductive wire covering the conductive paste and the two end edges of the battery sheet is 0.5mm-2mm and symmetrical on both sides.
优选地,所述导电丝可以是金属丝,也可以是具有一定导电性能的聚合物纤维,也可以是具有各种导电镀层的金属丝和聚合物纤维,所述导电浆料为银浆。 Preferably, the conductive wire may be a metal wire, a polymer fiber having a certain conductive property, or a metal wire and a polymer fiber having various conductive plating layers, and the conductive paste is a silver paste.
优选地,所述导电丝的直径范围为 0.01mm-0.03mm 。 Preferably, the conductive filament has a diameter ranging from 0.01 mm to 0.03 mm.
优选地,所述导电丝的横截面形状可以是矩形、梯形、三角形、圆形、椭圆形,也可以是其他形状。 Preferably, the conductive wire may have a cross-sectional shape of a rectangle, a trapezoid, a triangle, a circle, an ellipse, or other shapes.
优选地,所述导电丝为多根,所述多根导电丝之间的间距范围为 0.5mm-3mm 。 Preferably, the conductive filaments are plural, and the spacing between the plurality of conductive filaments ranges from 0.5 mm to 3 mm.
优选地,所述电池片可以为多晶硅电池片,也可以为单晶硅电池片。 Preferably, the battery sheet may be a polycrystalline silicon battery or a single crystal silicon battery.
优选地,所述电池片的正面包括主栅线,所述导电丝在垂直于所述主栅线方向上粘贴。 Preferably, the front surface of the battery chip includes a main gate line, and the conductive wire is pasted in a direction perpendicular to the main grid line.
优选地,所述导电丝与所述主栅线相交部分嵌入到所述主栅线内部。 Preferably, a portion where the conductive wire intersects the main gate line is embedded inside the main gate line.
本发明的目的之一是为了解决目前丝网印刷工艺存在的制作成本高,制作而成的太阳能电池产品转换效率较低,以及细栅线难以达到一定的窄度等问题,提出一种制作上述太阳能电池片正面电极结构的制作方法,所述方法包括: One of the objects of the present invention is to solve the problems that the current screen printing process has high manufacturing cost, the conversion efficiency of the fabricated solar cell product is low, and the fine grid line is difficult to achieve a certain narrowness. A method for fabricating a front electrode structure of a solar cell, the method comprising:
在导电丝表面上裹覆导电浆料;将裹覆了所述导电浆料的所述导电丝粘附于所述电池片上;将制作好的所述电池片放入到烘干和烧结炉中进行烘干烧结。 Coating a conductive paste on the surface of the conductive wire; adhering the conductive filament coated with the conductive paste to the battery sheet; and placing the fabricated battery piece into a drying and sintering furnace Drying and sintering are carried out.
可选地,所述方法还包括,在所述导电丝粘附于所述电池片上之前,在所述电池片上用导电浆料制作主栅线。 Optionally, the method further comprises forming a main gate line with a conductive paste on the battery sheet before the conductive filament is adhered to the battery sheet.
可选地,所述方法还包括,在所述导电丝粘附于所述电池片上之后,在所述电池片上用导电浆料制作主栅线。 Optionally, the method further comprises, after the conductive filaments are adhered to the battery sheet, forming a main gate line on the battery sheet with a conductive paste.
可选地,将导电丝粘附于电池片表面上时使得所述导电丝嵌入到所述主栅线的导电浆料内部。 Alternatively, the conductive filaments are embedded in the conductive paste of the main gate line when the conductive filaments are adhered to the surface of the battery sheet.
优选地,在所述导电丝表面上裹覆导电浆料时,将所述导电丝的整个外表面均匀地裹上导电浆料。 Preferably, when the conductive paste is coated on the surface of the conductive filament, the entire outer surface of the conductive filament is uniformly coated with a conductive paste.
优选地,将裹覆了所述导电浆料的所述导电丝长度制成小于所述电池片的尺寸,并将所述导电丝的两端边缘制成具有整齐的间断部分没有裹覆所述导电浆料。 Preferably, the length of the conductive filament covering the conductive paste is made smaller than the size of the battery sheet, and both end edges of the conductive filament are made to have a neat discontinuous portion without being covered. Conductive paste.
优选地,当将所述导电丝粘贴于所述电池片正面上时,裹覆了所述导电浆料的所述导电丝的两端边缘未进入电池片边缘的刻蚀区域。 Preferably, when the conductive filament is pasted on the front surface of the battery sheet, the both end edges of the conductive filament covering the conductive paste do not enter the etched area of the edge of the battery sheet.
优选地,裹覆了所述导电浆料的所述导电丝的两端边缘分别与所述电池片的两端边缘的距离为 0.5mm-2mm ,且两边对称。 Preferably, the distance between the two end edges of the conductive wire covering the conductive paste and the two end edges of the battery sheet is 0.5mm-2mm and symmetrical on both sides.
优选地,在裹覆导电浆料之前,将所述导电丝等间距平行排列。 Preferably, the conductive filaments are arranged in parallel at equal intervals before the conductive paste is coated.
优选地,所使用的所述导电丝可以是金属丝,也可以是具有一定导电性能的聚合物纤维,还可以是具有各种导电镀层的金属丝和聚合物纤维。 Preferably, the conductive wire used may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers.
优选地,所使用的所述导电丝的直径范围为 0.01mm-0.03mm 。 Preferably, the conductive filaments used have a diameter ranging from 0.01 mm to 0.03 mm.
优选地,所述导电丝的横截面形状可以是矩形、梯形、三角形、圆形、椭圆形等,也可以是其他形状。 Preferably, the cross-sectional shape of the conductive filament may be rectangular, trapezoidal, triangular, circular, elliptical, or the like, or may be other shapes.
优选地,用做所述主栅线的导电浆料和用于所述导电丝上的导电浆料可以是同一种导电浆料,也可以分别使用不同的导电浆料。 Preferably, the conductive paste used as the main gate line and the conductive paste used on the conductive wire may be the same conductive paste, or different conductive pastes may be used separately.
优选地,将所述导电丝间隔排列的间距为 0.5mm-3mm 。 Preferably, the conductive filaments are spaced apart by a pitch of 0.5 mm to 3 mm.
优选地,所述主栅线可以通过丝网印刷的方法在电池片上制作,也可以通过凸版印刷等其他方法来制作。 Preferably, the main gate line may be formed on the battery sheet by screen printing, or may be fabricated by other methods such as letterpress printing.
优选地,所述烘干步骤,其烘干温度范围为 100 ℃ -400 ℃。 Preferably, the drying step has a drying temperature ranging from 100 °C to 400 °C.
优选地,所述烧结步骤,其烧结温度范围为 400 ℃ -950 ℃。 Preferably, the sintering step has a sintering temperature ranging from 400 °C to 950 °C.
有益效果Beneficial effect
本发明的太阳能电极结构及其制作方法的优点是,该结构的太阳能电池正面细栅线的宽度相对于丝网印刷的细栅线宽度更小,能减小正面遮光面积,并且进一步提高了细栅线的导电率,从而提高了电池的转换效率;同时,使用了导电丝裹浆,减少了丝网印刷全部使用导电浆料的缺陷,减少了导电浆料的使用量,从而降低了太阳能电池的电极制作成本;另一方面,本发明的电极结构不存在断栅和虚印等印刷不良情况。本发明的电极结构和方法也为目前的太阳能电池行业提供了一种全新的增加效率和降低成本的太阳能电池片产品和制作太阳能电池产品的新方法。 The solar electrode structure of the present invention and the manufacturing method thereof have the advantages that the width of the front surface of the solar cell of the structure is smaller than the width of the fine grid line of the screen printing, the front light shielding area can be reduced, and the thinning is further improved. The conductivity of the grid line, thereby improving the conversion efficiency of the battery; at the same time, the use of conductive wire wrap, reducing the use of conductive paste in screen printing, reducing the use of conductive paste, thereby reducing the solar cell The electrode fabrication cost; on the other hand, the electrode structure of the present invention does not have printing defects such as broken gates and flops. The electrode structure and method of the present invention also provides a new solar cell product product and a new method for fabricating solar cell products that increase efficiency and reduce cost for the current solar cell industry.
附图说明DRAWINGS
图 1 是太阳能电池片正面电极结构的局部剖视图; Figure 1 is a partial cross-sectional view showing the structure of the front electrode of the solar cell;
图 2 是导电丝行列示意图; 2 is a schematic view of a row of conductive wires;
图 3 是裹覆了导电浆料的导电丝示意图; Figure 3 is a schematic view of a conductive filament wrapped with a conductive paste;
图 4 是制作了主栅线的电池片示意图; Figure 4 is a schematic view of a battery sheet in which a main gate line is formed;
图 5 是制作好的完整的电池片示意图; Figure 5 is a schematic diagram of a completed complete battery;
图 6 是制作好的电池片沿主栅线的剖视图; Figure 6 is a cross-sectional view of the fabricated cell sheet along the main gate line;
图 7 是制作太阳能电池片正面电极结构的流程图。 Figure 7 is a flow chart showing the structure of the front electrode of a solar cell.
图中附图标记: 1. 导电丝; 2. 导电浆料; 3. 电池片; 4. 主栅线。 Reference numerals in the figure: 1. Conductive wire; 2. Conductive paste; 3. Cell sheet; 4. Main grid line.
本发明的最佳实施方式BEST MODE FOR CARRYING OUT THE INVENTION
如图 5 和图 1 所示,图 5 为本发明提供的一种太阳能电池正面电极结构示意图,图 1 为本发明的太阳能正面电极结构的局部剖视图。 As shown in FIG. 5 and FIG. 1 , FIG. 5 is a schematic structural diagram of a front electrode of a solar cell according to the present invention, FIG. 1 A partial cross-sectional view of a solar front electrode structure of the present invention.
如图 1 所示,太阳能电池正面电极结构包括电池片 3 和导电丝 1 ,导电丝 1 通过导电浆料 2 粘附在电池片 3 的表面上,导电丝 1 的直径大小范围为 0.01mm-0.03mm ,从剖视图 1 中可以看出,导电丝 1 的整个外表面都裹覆有导电浆料 2 。 As shown in FIG. 1, the front electrode structure of the solar cell includes a battery sheet 3 and a conductive wire 1, and the conductive wire 1 passes through the conductive paste 2 Adhered to the surface of the battery sheet 3, the diameter of the conductive filament 1 ranges from 0.01 mm to 0.03 mm. As can be seen from the cross-sectional view 1, the entire outer surface of the conductive filament 1 is covered with a conductive paste 2 .
如图 2 和图 5 所示,多根导电丝 1 等间距平行排列地粘附在电池片 3 上,所述导电丝 1 之间的间距范围为 0.5mm-3mm 。 As shown in FIG. 2 and FIG. 5, a plurality of conductive filaments 1 are adhered to the battery sheet 3 at equal intervals in parallel, and the conductive filaments 1 The spacing between them ranges from 0.5mm to 3mm.
如图 4 所示,在未贴丝的电池片 3 上可以通过丝网印刷印刷有主栅线 4 ,主栅线 4 也可以通过其他方法比如凸版印刷的方法来制作,如图 5 所示,导电丝 1 在垂直于主栅线 4 的方向上粘贴到电池片 3 上。 As shown in FIG. 4, a main gate line 4, a main gate line 4, can be printed by screen printing on the uncoated cell sheet 3. It can also be produced by other methods such as letterpress printing. As shown in Fig. 5, the conductive filament 1 is attached to the battery sheet 3 in a direction perpendicular to the main grid line 4.
另一方面,如图 6 所示,其是制作好的电池片沿主栅线的剖视图,当导电丝 1 粘附到具有主栅线 4 的电池片 3 上时,使得导电丝 1 嵌入主栅线 4 的导电浆料的内部,使得主栅线 4 和细栅线 1 之间具有良好的接触,便于电流的流通以及降低电力损失。 On the other hand, as shown in Fig. 6, it is a cross-sectional view of the fabricated cell sheet along the main gate line when the conductive filament 1 is adhered to have the main gate line 4 On the battery sheet 3, the conductive wire 1 is embedded in the inside of the conductive paste of the main gate line 4, so that the main gate line 4 and the fine gate line 1 Good contact between them facilitates current flow and reduces power loss.
回到图 5 所示,粘附在电池片 3 上的导电丝 1 两端的长度小于对应的电池片的长度尺寸,并且导电丝 1 的末端,即两端丝头没有超出电池片 3 的两端边缘,导电丝 1 的两端边缘分别与电池片 3 两端边缘的距离范围为 0.5mm-2mm ,且两边对称。粘贴于电池片 3 正面上的导电丝 1 的两端边缘未进入电池片 3 两端边缘的刻蚀区域,粘贴电池片 3 的导电丝 1 的两端边缘具有整齐的间断性没有裹覆导电浆料 2 ,以避免导电浆料 2 粘到电池片 3 两端边缘的刻蚀区而引起的边缘漏电导致效率低下现象。 Returning to Fig. 5, the length of both ends of the conductive wire 1 adhered to the battery piece 3 is smaller than the length dimension of the corresponding battery piece, and the conductive wire The end of the first end, that is, the ends of the ends of the battery piece 3 are not beyond the edge of the battery sheet 3, and the distance between the end edges of the conductive wire 1 and the edge of the battery sheet 3 is 0.5 mm - 2 mm. And the two sides are symmetrical. The both end edges of the conductive wire 1 pasted on the front surface of the battery sheet 3 do not enter the etched area at the both end edges of the battery sheet 3, and the conductive wires of the battery sheet 3 are pasted 1 The edge of both ends has a neat discontinuity without coating the conductive paste 2 to avoid the leakage of the edge caused by the conductive paste 2 sticking to the etched regions at the both end edges of the battery sheet 3, resulting in inefficiency.
导电丝 1 可以是金属丝,也可以是具有一定导电性能的聚合物纤维,也可以是具有各种导电镀层的金属丝和聚合物纤维,本实施例中所使用的是金属丝。 Conductive wire 1 It may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers. In the present embodiment, a metal wire is used.
如图 7 所示,其是本发明方法的流程图,其示出了制作太阳能电池片正面电极的工艺方法的基本流程,首先是在等间距排列的圆柱形导电丝 1 行列上裹覆导电浆料 2 ,其中,导电丝 1 之间的间距范围为 0.5mm-3mm ,导电丝 1 的直径范围为 0.01mm-0.03mm ,如图 2 所示,其中示出了等间距排列的导电丝 1 ,在上述排列好的导电丝 1 上裹覆导电浆料 2 ,导电浆料 2 具有优良的导电性能,能与电池片 3 表面具有优良接触性能,并且要与电池片 3 表面具有优良的附着性能,以避免后续烧结过程后出现的导电丝 1 与电池片 3 表面出现脱离的情况。如图 3 所示,可以看出在导电丝 1 的行列上已经裹覆有导电浆料 2 ,更好的如图 1 所示,其示出了已裹浆的导电丝 1 的横截面情况,从中可以看出,导电丝 1 的外表面周围已经全部包裹有导电浆料 2 ,导电丝 1 完全裹覆导电浆料以避免导电丝 1 在后续的高温烧结过程中裸露在高温环境下由于表面氧化而造成的导电性能下降的情况。如图 4 所示,其示出了在贴丝之前,在电池片 3 上通过丝网印刷方法或其他方法将主栅线 4 印刷在电池片 3 上,以备下一步贴丝使用。 Figure 7 Shown is a flow chart of the method of the present invention, showing the basic flow of a process for fabricating a front electrode of a solar cell sheet, first by coating a conductive paste on a row of cylindrical conductive filaments 1 arranged at equal intervals. Wherein, the spacing between the conductive filaments 1 ranges from 0.5 mm to 3 mm, and the diameter of the conductive filaments 1 ranges from 0.01 mm to 0.03 mm, as shown in Fig. 2 As shown therein, the conductive filaments 1 are arranged at equal intervals, and the conductive paste 1 is coated on the above-mentioned aligned conductive filaments 1. The conductive paste 2 has excellent electrical conductivity and can be combined with the battery sheet 3. The surface has excellent contact properties and has excellent adhesion to the surface of the cell sheet 3 to avoid the occurrence of detachment of the conductive filament 1 from the surface of the cell sheet 3 after the subsequent sintering process. Figure 3 As shown, it can be seen that the conductive paste 2 has been coated on the row of the conductive filaments 1, better as shown in Fig. 1, which shows the cross-section of the coated conductive filament 1, from which it can be seen Out, conductive wire 1 The outer surface of the outer surface is completely wrapped with conductive paste 2, and the conductive wire 1 is completely covered with the conductive paste to avoid the conductive wire 1 In the subsequent high-temperature sintering process, the conductivity deterioration due to surface oxidation is exposed in a high temperature environment. As shown in Figure 4, it is shown in the cell sheet 3 before the wire is applied. The main gate line 4 is printed on the battery chip 3 by a screen printing method or the like for use in the next step.
步骤一中,导电丝 1 用金属丝且横截面形状为圆形,用做主栅线 4 的导电浆料 2 和用于导电丝 1 上的导电浆料 2 采用同一种导电浆料。 In the first step, the conductive wire 1 is made of a metal wire and has a circular cross section, and is used as the conductive paste 2 of the main gate line 4 and for the conductive wire 1 The conductive paste 2 on the same uses the same conductive paste.
在上述制作步骤一中,将导电丝 1 间隔排列间距可以通过考虑导电丝 1 的直径和通过实验考虑转换效率以及电池片 3 上的导电丝 1 的根数来调整其间距。 In the above manufacturing step 1, the spacing of the conductive filaments 1 can be determined by considering the conductive filaments 1 The diameter is adjusted by experimentally considering the conversion efficiency and the number of conductive filaments 1 on the battery sheet 3.
在本实施例的步骤一中,如图 4 所示,主栅线 4 可以首先就通过丝网印刷的方法在电池片 3 上制作,也可以通过凸版印刷等其他方法来制作,在电池片 3 上丝网印刷的主栅线 4 不进行烘干,主栅线 4 的宽度为 1-3 毫米,主栅线的根数一般为 2-3 根,制作好的具有主栅线 4 的电池片 3 以备在本发明的制作方法中使用。 In the first step of the embodiment, as shown in FIG. 4, the main gate line 4 can be first applied to the cell sheet by screen printing. The upper fabrication can also be made by other methods such as letterpress printing, and the main gate line 4 screen printed on the battery sheet 3 is not dried, and the width of the main gate line 4 is 1-3 mm, and the number of the main grid lines is Generally 2-3 The battery piece 3 having the main grid line 4 is prepared for use in the manufacturing method of the present invention.
本发明方法的第二个步骤,将已裹覆有导电浆料 2 的导电丝 1 在垂直于主栅线 4 的方向上粘贴在已印刷有主栅线的电池片 3 上面。如图 1 所示,可以看出导电丝 1 通过导电浆料 2 粘合到电池片 3 上。并且导电丝 1 的整个外表面周围完全包裹导电浆料 2 。当已裹浆的导电丝 1 在垂直于主栅线 4 的方向上贴合到电池片 3 上面时,导电丝 1 嵌入到主栅线 4 的导电浆料内部,如图 6 所示,导电丝 1 与主栅线相交部分已经完全嵌入到主栅线 4 的内部,这样有利于导电丝 1 与主栅线 4 之间的电流流通。 In the second step of the method of the present invention, the conductive filament 1 which has been coated with the conductive paste 2 is perpendicular to the main grid line 4 The direction is pasted on the cell sheet 3 on which the main gate line has been printed. As shown in Fig. 1, it can be seen that the conductive filament 1 is bonded to the battery sheet 3 through the conductive paste 2. And conductive wire 1 The entire outer surface is completely wrapped around the conductive paste 2 . When the wrapped conductive filament 1 is attached to the battery sheet 3 in a direction perpendicular to the main grid line 4, the conductive filament 1 is embedded in the main grid line 4 Inside the conductive paste, as shown in Fig. 6, the portion where the conductive wire 1 intersects with the main gate line has been completely embedded inside the main gate line 4, which facilitates current flow between the conductive wire 1 and the main gate line 4.
本发明方法的第三个步骤,将已经贴好导电丝 1 的电池片 3 (如图 5 所示,已经贴好导电丝 1 的电池片)在 200-400 ℃的温度下烘干,然后与背电极一起在 700-900 ℃的温度下烧结,使同时导电浆料与导电丝烧结成完整导体,使涂覆了导电浆料 2 的导电丝 1 和主栅线 4 以及电池片 3 表面形成牢固的合金化接触和优良的欧姆接触。至此,电极制作完毕。 In the third step of the method of the present invention, the battery sheet 3 of the conductive filament 1 has been pasted (as shown in Fig. 5, the conductive filament 1 has been attached) The battery piece is baked at a temperature of 200-400 ° C, and then sintered at a temperature of 700-900 ° C together with the back electrode, so that the conductive paste and the conductive wire are sintered into a complete conductor, so that the conductive paste is coated. 2 The conductive filament 1 forms a strong alloyed contact and excellent ohmic contact with the main gate line 4 and the surface of the cell sheet 3. At this point, the electrode is completed.
本实施例的优点是所得细栅线(即导电丝 1 涂覆导电浆料 2 烧结后)的宽度小于 0.06 毫米,大幅度减少了细栅线的遮光面积,并且细栅线使用导电丝,大大节省了导电浆料,进一步降低了成本。 The advantage of this embodiment is that the width of the obtained fine grid line (i.e., after the conductive wire 1 is coated with the conductive paste 2 is sintered) is less than 0.06. In millimeters, the shading area of the fine grid lines is greatly reduced, and the conductive wires are used for the fine grid lines, which greatly saves the conductive paste and further reduces the cost.
在上述制作方法中,在导电丝 1 裹浆过程中,导电丝 1 的丝头部分不包裹导电浆料 2 ,如图 3 中所示,丝头部分没有裹覆导电浆料 2 。 In the above manufacturing method, during the winding process of the conductive filament 1, the wire portion of the conductive filament 1 does not wrap the conductive paste 2, as shown in FIG. As shown in the figure, the wire portion is not covered with the conductive paste 2 .
在上述制作方法中,将导电丝 1 的长度制成长度小于电池片 3 的长度尺寸,当将导电丝 2 粘贴于电池片 3 上时,如图 5 所示,导电丝 1 的边缘不会超出电池片 3 的边缘。 In the above manufacturing method, the length of the conductive filament 1 is made smaller than the length dimension of the battery sheet 3, and when the conductive filament 2 is attached to the battery sheet 3 When it is up, as shown in Figure 5, the edge of the conductive wire 1 does not extend beyond the edge of the cell 3.
印刷主栅线 4 也可以在贴好细栅线后再进行丝网印刷。 The printed main gate line 4 can also be screen printed after the fine grid lines are attached.
本发明的实施方式Embodiments of the invention
下面结合附图以及具体实施例来对本发明进行详细说明。 The invention will be described in detail below with reference to the drawings and specific embodiments.
如图 5 和图 1 所示,图 5 为本发明提供的一种太阳能电池正面电极结构示意图,图 1 为本发明的太阳能正面电极结构的局部剖视图。 As shown in FIG. 5 and FIG. 1 , FIG. 5 is a schematic structural diagram of a front electrode of a solar cell according to the present invention, FIG. 1 A partial cross-sectional view of a solar front electrode structure of the present invention.
如图 1 所示,太阳能电池正面电极结构包括电池片 3 和导电丝 1 ,导电丝 1 通过导电浆料 2 粘附在电池片 3 的表面上,导电丝 1 的直径大小范围为 0.01mm-0.03mm ,从剖视图 1 中可以看出,导电丝 1 的整个外表面都裹覆有导电浆料 2 。 As shown in FIG. 1, the front electrode structure of the solar cell includes a battery sheet 3 and a conductive wire 1, and the conductive wire 1 passes through the conductive paste 2 Adhered to the surface of the battery sheet 3, the diameter of the conductive filament 1 ranges from 0.01 mm to 0.03 mm. As can be seen from the cross-sectional view 1, the entire outer surface of the conductive filament 1 is covered with a conductive paste 2 .
如图 2 和图 5 所示,多根导电丝 1 等间距平行排列地粘附在电池片 3 上,所述导电丝 1 之间的间距范围为 0.5mm-3mm 。 As shown in FIG. 2 and FIG. 5, a plurality of conductive filaments 1 are adhered to the battery sheet 3 at equal intervals in parallel, and the conductive filaments 1 The spacing between them ranges from 0.5mm to 3mm.
如图 4 所示,在未贴丝的电池片 3 上可以通过丝网印刷印刷有主栅线 4 ,主栅线 4 也可以通过其他方法比如凸版印刷的方法来制作,如图 5 所示,导电丝 1 在垂直于主栅线 4 的方向上粘贴到电池片 3 上。可选的另一种实施方式是电池片 3 上没有印刷有主栅线 4 ,先在电池片 3 上粘贴导电丝 1 ,然后再将粘附有导电丝 1 的电池片 3 进行丝网印刷,在垂直于细栅线(即导电丝 1 )的方向上印刷上删线 4 。 As shown in FIG. 4, a main gate line 4, a main gate line 4, can be printed by screen printing on the uncoated cell sheet 3. It can also be produced by other methods such as letterpress printing. As shown in Fig. 5, the conductive filament 1 is attached to the battery sheet 3 in a direction perpendicular to the main grid line 4. Another alternative embodiment is the battery sheet 3 The main grid line 4 is not printed thereon. First, the conductive wire 1 is pasted on the battery sheet 3, and then the battery sheet 3 to which the conductive filament 1 is adhered is screen-printed, perpendicular to the fine grid line (ie, the conductive wire 1) In the direction of the print, the line is deleted 4 .
另一方面,如图 6 所示,其是制作好的电池片沿主栅线的剖视图,当导电丝 1 粘附到具有主栅线 4 的电池片 3 上时,使得导电丝 1 嵌入主栅线 4 的导电浆料的内部,使得主栅线 4 和细栅线 1 之间具有良好的接触,便于电流的流通以及降低电力损失。 On the other hand, as shown in Fig. 6, it is a cross-sectional view of the fabricated cell sheet along the main gate line when the conductive filament 1 is adhered to have the main gate line 4 On the battery sheet 3, the conductive wire 1 is embedded in the inside of the conductive paste of the main gate line 4, so that the main gate line 4 and the fine gate line 1 Good contact between them facilitates current flow and reduces power loss.
回到图 5 所示,粘附在电池片 3 上的导电丝 1 两端的长度小于对应的电池片的长度尺寸,并且导电丝 1 的末端,即两端丝头没有超出电池片 3 的两端边缘,导电丝 1 的两端边缘分别与电池片 3 两端边缘的距离范围为 0.5mm-2mm ,且两边对称。 Returning to Fig. 5, the length of both ends of the conductive wire 1 adhered to the battery piece 3 is smaller than the length dimension of the corresponding battery piece, and the conductive wire The end of the first end, that is, the ends of the two ends of the wire 3 are not beyond the edge of the battery sheet 3, and the distance between the end edges of the conductive wire 1 and the edge of the battery sheet 3 is 0.5 mm - 2 mm, and the two sides are symmetrical.
优选的实施例为粘贴于电池片 3 正面上的导电丝 1 的两端边缘未进入电池片 3 两端边缘的刻蚀区域。 A preferred embodiment is that the end edges of the conductive filament 1 adhered to the front surface of the battery sheet 3 do not enter the battery sheet 3 The etched area at the edges of the ends.
优选的另一实施例为粘贴电池片 3 的导电丝 1 的两端边缘具有整齐的间断性没有裹覆导电浆料 2 ,以避免导电浆料 2 粘到电池片 3 两端边缘的刻蚀区而引起的边缘漏电导致效率低下现象。 A preferred embodiment is that the ends of the conductive filaments 1 pasting the battery sheets 3 have neat discontinuities without coating the conductive paste 2 In order to avoid leakage of the conductive paste 2 to the etched area at the edge of the battery chip 3, the leakage of the edge leads to inefficiency.
本发明中所使用的导电丝 1 可以是金属丝,也可以是具有一定导电性能的聚合物纤维,也可以是具有各种导电镀层的金属丝和聚合物纤维。 Conductive wire used in the present invention 1 It may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers.
本发明不仅适用于普通各类晶体硅太阳电池,化合物太阳电池同样可以用本发明的方法制作太阳电池电极。 The invention is applicable not only to ordinary types of crystalline silicon solar cells, but also to solar cell electrodes of the invention.
如图 7 所示,其是本发明方法的流程图,其示出了制作太阳能电池片正面电极的工艺方法的基本流程,首先是在等间距排列的圆柱形导电丝 1 行列上裹覆导电浆料 2 ,其中,导电丝 1 之间的间距范围为 0.5mm-3mm ,导电丝 1 的直径范围为 0.01mm-0.03mm ,如图 2 所示,其中示出了等间距排列的导电丝 1 ,在上述排列好的导电丝 1 上裹覆导电浆料 2 ,导电浆料 2 具有优良的导电性能,能与电池片 3 表面具有优良接触性能,并且要与电池片 3 表面具有优良的附着性能,以避免后续烧结过程后出现的导电丝 1 与电池片 3 表面出现脱离的情况。如图 3 所示,可以看出在导电丝 1 的行列上已经裹覆有导电浆料 2 ,更好的如图 1 所示,其示出了已裹浆的导电丝 1 的横截面情况,从中可以看出,导电丝 1 的外表面周围已经全部包裹有导电浆料 2 ,导电丝 1 完全裹覆导电浆料以避免导电丝 1 在后续的高温烧结过程中裸露在高温环境下由于表面氧化而造成的导电性能下降的情况。如图 4 所示,其示出了在贴丝之前,在电池片 3 上通过丝网印刷方法或其他方法将主栅线 4 印刷在电池片 3 上,以备下一步贴丝使用。 Figure 7 Shown is a flow chart of the method of the present invention, showing the basic flow of a process for fabricating a front electrode of a solar cell sheet, first by coating a conductive paste on a row of cylindrical conductive filaments 1 arranged at equal intervals. Wherein, the spacing between the conductive filaments 1 ranges from 0.5 mm to 3 mm, and the diameter of the conductive filaments 1 ranges from 0.01 mm to 0.03 mm, as shown in Fig. 2 As shown therein, the conductive filaments 1 are arranged at equal intervals, and the conductive paste 1 is coated on the above-mentioned aligned conductive filaments 1. The conductive paste 2 has excellent electrical conductivity and can be combined with the battery sheet 3. The surface has excellent contact properties and has excellent adhesion to the surface of the cell sheet 3 to avoid the occurrence of detachment of the conductive filament 1 from the surface of the cell sheet 3 after the subsequent sintering process. Figure 3 As shown, it can be seen that the conductive paste 2 has been coated on the row of the conductive filaments 1, better as shown in Fig. 1, which shows the cross-section of the coated conductive filament 1, from which it can be seen Out, conductive wire 1 The outer surface of the outer surface is completely wrapped with conductive paste 2, and the conductive wire 1 is completely covered with the conductive paste to avoid the conductive wire 1 In the subsequent high-temperature sintering process, the conductivity deterioration due to surface oxidation is exposed in a high temperature environment. As shown in Figure 4, it is shown in the cell sheet 3 before the wire is applied. The main gate line 4 is printed on the battery chip 3 by a screen printing method or the like for use in the next step.
本发明方法的第二个步骤,将已裹覆有导电浆料 2 的导电丝 1 在垂直于主栅线 4 的方向上粘贴在已印刷有主栅线的电池片 3 上面。如图 1 所示,可以看出导电丝 1 通过导电浆料 2 粘合到电池片 3 上。并且导电丝 1 的整个外表面周围完全包裹导电浆料 2 。 In the second step of the method of the present invention, the conductive filament 1 which has been coated with the conductive paste 2 is perpendicular to the main grid line 4 The direction is pasted on the cell sheet 3 on which the main gate line has been printed. As shown in Fig. 1, it can be seen that the conductive filament 1 is bonded to the battery sheet 3 through the conductive paste 2. And conductive wire 1 The entire outer surface is completely wrapped around the conductive paste 2 .
本发明方法的第三个步骤,将已经贴好导电丝 1 的电池片 3 (如图 5 所示,已经贴好导电丝 1 的电池片)在 200-400 ℃的温度下烘干,然后与背电极一起在 700-900 ℃的温度下烧结,使同时导电浆料与导电丝烧结成完整导体,使涂覆了导电浆料 2 的导电丝 1 和主栅线 4 以及电池片 3 表面形成牢固的合金化接触和优良的欧姆接触。至此,电极制作完毕。 In the third step of the method of the present invention, the battery sheet 3 of the conductive filament 1 has been pasted (as shown in Fig. 5, the conductive filament 1 has been attached) The battery piece is baked at a temperature of 200-400 ° C, and then sintered at a temperature of 700-900 ° C together with the back electrode, so that the conductive paste and the conductive wire are sintered into a complete conductor, so that the conductive paste is coated. 2 The conductive filament 1 forms a strong alloyed contact and excellent ohmic contact with the main gate line 4 and the surface of the cell sheet 3. At this point, the electrode is completed.
本实施例的优点是所得细栅线(即导电丝 1 涂覆导电浆料 2 烧结后)的宽度小于 0.06 毫米,大幅度减少了细栅线的遮光面积,并且细栅线使用导电丝,大大节省了导电浆料,进一步降低了成本。 The advantage of this embodiment is that the width of the obtained fine grid line (i.e., after the conductive wire 1 is coated with the conductive paste 2 is sintered) is less than 0.06. In millimeters, the shading area of the fine grid lines is greatly reduced, and the conductive wires are used for the fine grid lines, which greatly saves the conductive paste and further reduces the cost.
在上述制作步骤一中,其中导电丝 1 可以是金属丝,也可以是具有一定导电性能的聚合物纤维,还可以是具有各种导电镀层的金属丝和聚合物纤维等导电材料制成的导电丝。 In the above production step 1, wherein the conductive wire 1 It may be a metal wire, a polymer fiber having a certain electrical conductivity, or a conductive wire made of a conductive material such as a metal wire and a polymer fiber having various conductive plating layers.
并且其中用做主栅线 4 的导电浆料 2 和用于导电丝 1 上的导电浆料 2 可以是同一种导电浆料,也可以分别使用不同的导电浆料,根据需要可以使用不同的导电浆料。并且导电丝 1 的横截面形状可以是矩形、梯形、三角形、圆形、椭圆形等,也可以是其他形状,在本发明的示例中,优选为圆形。 And the conductive paste 2 used as the main gate line 4 and the conductive paste for the conductive filament 1 It may be the same conductive paste, or different conductive pastes may be used separately, and different conductive pastes may be used as needed. And conductive wire 1 The cross-sectional shape may be a rectangle, a trapezoid, a triangle, a circle, an ellipse or the like, or may be other shapes, and in the example of the present invention, it is preferably a circle.
在上述制作步骤一中,将导电丝 1 间隔排列间距可以通过考虑导电丝 1 的直径和通过实验考虑转换效率以及电池片 3 上的导电丝 1 的根数来调整其间距。 In the above manufacturing step 1, the spacing of the conductive filaments 1 can be determined by considering the conductive filaments 1 The diameter is adjusted by experimentally considering the conversion efficiency and the number of conductive filaments 1 on the battery sheet 3.
优选地,在本发明的上述实施例中的步骤一中,如图 4 所示,主栅线 4 可以首先就通过丝网印刷的方法在电池片 3 上制作,也可以通过凸版印刷等其他方法来制作,在电池片 3 上丝网印刷的主栅线 4 不进行烘干,主栅线 4 的宽度为 1-3 毫米,主栅线的根数一般为 2-3 根,制作好的具有主栅线 4 的电池片 3 以备在本发明的制作方法中使用。 Preferably, in the first step in the above embodiment of the present invention, as shown in FIG. 4, the main gate line 4 It may be first formed on the battery sheet 3 by screen printing, or may be produced by other methods such as letterpress printing, and the main gate line 4 screen-printed on the battery sheet 3 is not dried, and the main gate line 4 is Width is 1-3 mm, the number of main grid lines is generally 2-3, and the battery sheet 3 having the main grid line 4 is prepared for use in the manufacturing method of the present invention.
优选地,在本发明上述的步骤二中,当已裹浆的导电丝 1 在垂直于主栅线 4 的方向上贴合到电池片 3 上面时,导电丝 1 嵌入到主栅线 4 的导电浆料内部,如图 6 所示,导电丝 1 与主栅线相交部分已经完全嵌入到主栅线 4 的内部,这样有利于导电丝 1 与主栅线 4 之间的电流流通。 Preferably, in the above step 2 of the present invention, when the wrapped conductive filament 1 is attached to the battery sheet 3 in a direction perpendicular to the main grid line 4 Above, the conductive wire 1 is embedded inside the conductive paste of the main gate line 4, as shown in Fig. 6, the intersection of the conductive wire 1 and the main gate line has been completely embedded inside the main gate line 4, which is advantageous for the conductive wire 1 Current flow with the main gate line 4.
在本发明的上述步骤三中,导电丝 1 按照图 1 所示的结构粘附在电池片 3 上,在 100 ℃ -400 ℃的温度下烘干,然后与背电极一起在 400 ℃ -950 ℃的温度下烧结,使导电浆料(一般为银浆)与电池片形成良好的欧姆接触,同时导电浆料与导电丝烧结成完整导体。 In the above step three of the present invention, the conductive yarn 1 is adhered to the battery sheet 3 in accordance with the structure shown in Fig. 1, at 100 °C. Dry at -400 °C and then with the back electrode at 400 °C -950 Sintering at a temperature of °C causes the conductive paste (generally silver paste) to form a good ohmic contact with the cell sheet, while the conductive paste and the conductive filament are sintered into a complete conductor.
在上述制作方法中,可选的方法步骤是在导电丝 1 裹浆过程中,导电丝 1 的丝头部分不包裹导电浆料 2 ,如图 3 中所示,丝头部分没有裹覆导电浆料 2 。 In the above manufacturing method, an optional method step is that the wire portion of the conductive wire 1 does not wrap the conductive paste during the winding process of the conductive filament 1 As shown in Fig. 3, the wire portion is not covered with the conductive paste 2 .
在上述制作方法中,可选的另一方法步骤是将导电丝 1 的长度制成长度小于电池片 3 的长度尺寸,当将导电丝 2 粘贴于电池片 3 上时,如图 5 所示,导电丝 1 的边缘不会超出电池片 3 的边缘。 In the above manufacturing method, another optional method step is to make the length of the conductive filament 1 smaller than the battery sheet 3 The length dimension, when the conductive filament 2 is attached to the battery sheet 3, as shown in Fig. 5, the edge of the conductive filament 1 does not extend beyond the edge of the battery sheet 3.
在本实施例中,印刷主栅线 4 也可以在贴好细栅线后再进行丝网印刷。 In this embodiment, the printed main gate line 4 can also be screen printed after the fine gate line is pasted.
本发明的上述制作工艺的优点是,降低了太阳能电池正面细栅线的宽度,提高了细栅线的导电率,从而提高了电池的转换效率;减少了导电浆料的使用量,从而降低了太阳能电池的电极制作成本;避免了由于丝网印刷工艺本身缺陷造成的诸如断栅和虚印等印刷不良情况,另外由于避免了网版的使用,也能使电池片的效率分布更加集中。同时细栅线和主栅线也可以分别使用与其功能更匹配的导电浆料;更主要的是,由于在太阳能电池正面电极的细栅线的制作方面,替代了传统的丝网印刷工艺,不仅规避掉了丝网印刷工艺本身的诸多问题,也为目前的太阳能电池行业提供了新的增加效率和降低成本的途径。 The above manufacturing process of the invention has the advantages of reducing the width of the fine gate line of the front surface of the solar cell, improving the conductivity of the fine gate line, thereby improving the conversion efficiency of the battery, reducing the usage amount of the conductive paste, thereby reducing the amount of the conductive paste. The electrode manufacturing cost of the solar cell avoids printing defects such as broken gates and flops due to defects in the screen printing process itself, and also makes the efficiency distribution of the cells more concentrated by avoiding the use of the screen. At the same time, the fine gate line and the main gate line can also respectively use the conductive paste which is more matched with its function; more importantly, instead of the conventional screen printing process, the fabrication of the fine gate line of the front electrode of the solar cell is not only It avoids many problems of the screen printing process itself, and provides a new way to increase efficiency and reduce costs for the current solar cell industry.
本发明制作方法的另外的优点在于导电丝像水泥中的钢筋一样加强了电池片的强度,使电池片不易碎,同时由于导电丝具有良好的韧性,即使电池片裂缝,金属丝仍然会把电池片连成一体,电流一样汇流而出,这样避免了目前工艺中由于断栅裂纹带来的光电转换效率降低的问题,并且可以降低后道加工难度,提高成品率。 Another advantage of the manufacturing method of the present invention is that the conductive wire strengthens the strength of the battery sheet like the steel bar in the cement, so that the battery sheet is not brittle, and at the same time, because the conductive wire has good toughness, even if the battery sheet is cracked, the wire still has the battery. The sheets are integrated into one body, and the current flows in the same way, thereby avoiding the problem of lowering the photoelectric conversion efficiency due to the crack of the broken gate in the current process, and can reduce the difficulty of the subsequent processing and improve the yield.
本发明并不限于上述特定实施例,在不背离本发明精神及其情况下,本领域的普通技术人员可根据本发明作出的改变和变形,都应属于本发明权利要求的保护范围之内。 The present invention is not limited to the specific embodiments described above, and variations and modifications may be made by those skilled in the art without departing from the spirit and scope of the invention.
工业实用性Industrial applicability
本发明的太阳能电极结构及其制作方法的优点是,该结构的太阳能电池正面细栅线的宽度相对于丝网印刷的细栅线宽度更小,能减小正面遮光面积,并且进一步提高了细栅线的导电率,从而提高了电池的转换效率;同时,使用了导电丝裹浆,减少了丝网印刷全部使用导电浆料的缺陷,减少了导电浆料的使用量,从而降低了太阳能电池的电极制作成本;另一方面,本发明的电极结构不存在断栅和虚印等印刷不良情况。本发明的电极结构和方法也为目前的太阳能电池行业提供了一种全新的增加效率和降低成本的太阳能电池片产品和制作太阳能电池产品的新方法。 The solar electrode structure of the present invention and the manufacturing method thereof have the advantages that the width of the front surface of the solar cell of the structure is smaller than the width of the fine grid line of the screen printing, the front light shielding area can be reduced, and the thinning is further improved. The conductivity of the grid line, thereby improving the conversion efficiency of the battery; at the same time, the use of conductive wire wrap, reducing the use of conductive paste in screen printing, reducing the use of conductive paste, thereby reducing the solar cell The electrode fabrication cost; on the other hand, the electrode structure of the present invention does not have printing defects such as broken gates and flops. The electrode structure and method of the present invention also provides a new solar cell product product and a new method for fabricating solar cell products that increase efficiency and reduce cost for the current solar cell industry.
序列表自由内容Sequence table free content

Claims (1)

  1. 1. 一种太阳能电池片正面电极结构,其特征在于,所述结构包括电池片和导电丝,所述导电丝裹覆导电浆料粘贴在所述电池片的正面上。1. A solar cell front electrode structure, characterized in that the structure comprises a battery sheet and a conductive wire, and the conductive filament coated conductive paste is adhered to the front surface of the battery sheet.
    2. 根据权利要求 1 所述的太阳能电池电极结构,其特征在于,所述导电丝整个外表面都裹覆有导电浆料。2. According to claim 1 The solar cell electrode structure is characterized in that the entire outer surface of the conductive wire is covered with a conductive paste.
    3. 根据权利要求 1-2 任一项所述的太阳能电池片正面电极结构,其特征在于,粘贴于所述电池片正面上的所述导电丝的长度小于所述电池片的尺寸,其两端不伸出所述电池片的正面边缘。3. According to claim 1-2 The solar cell front electrode structure according to any one of the preceding claims, wherein the length of the conductive wire attached to the front surface of the battery sheet is smaller than the size of the battery sheet, and the two ends do not protrude from the battery sheet. The front edge.
    4. 根据权利要求 3 所述的太阳能电池片正面电极结构,其特征在于,粘贴于所述电池片正面上的所述导电丝的两端边缘未进入电池片边缘的刻蚀区域。4. According to claim 3 The front electrode structure of the solar cell sheet is characterized in that both end edges of the conductive wire adhered to the front surface of the battery sheet do not enter an etched area of the edge of the battery sheet.
    5. 根据权利要求 3 所述的太阳能电池片正面电极结构,其特征在于,粘贴所述电池片正面的所述导电丝的两端边缘具有整齐的间断部分没有裹覆所述导电浆料。5. According to claim 3 The front electrode structure of the solar cell sheet is characterized in that both end edges of the conductive wire pasting the front surface of the battery sheet have a neat discontinuous portion without coating the conductive paste.
    6. 根据权利要求 3 所述的太阳能电池片正面电极结构,其特征在于,裹覆了所述导电浆料的所述导电丝的两端边缘分别与所述电池片两端边缘的距离为 0.5mm-2mm ,且两边对称。6. According to claim 3 The front electrode structure of the solar cell sheet is characterized in that the distance between the two end edges of the conductive wire covering the conductive paste and the edge of the battery sheet are respectively 0.5 mm - 2 mm And the two sides are symmetrical.
    7. 根据权利要求 1 所述的太阳能电池片正面电极结构,其特征在于,所述导电丝可以是金属丝,也可以是具有一定导电性能的聚合物纤维,也可以是具有各种导电镀层的金属丝和聚合物纤维,所述导电浆料为银浆。7. According to claim 1 The solar cell front electrode structure is characterized in that the conductive wire may be a metal wire, a polymer fiber having a certain conductive property, or a metal wire and a polymer fiber having various conductive plating layers. The conductive paste is a silver paste.
    8. 根据权利要求 1 所述的太阳能电池片正面电极结构,其特征在于,所述导电丝的直径范围为 0.01mm-0.03mm 。8. The solar cell front electrode structure according to claim 1, wherein the conductive wire has a diameter ranging from 0.01 mm to 0.03 mm. .
    9. 根据权利要求 1 所述的太阳能电池片正面电极结构,其特征在于,所述导电丝的横截面形状可以是矩形、梯形、三角形、圆形、椭圆形。9. According to claim 1 The solar cell front electrode structure is characterized in that the conductive wire has a cross-sectional shape of a rectangle, a trapezoid, a triangle, a circle, and an ellipse.
    10. 根据权利要求 1 所述的太阳能电池片正面电极结构,其特征在于,所述导电丝为多根,所述多根导电丝之间的间距范围为 0.5mm-3mm 。10. The solar cell front electrode structure according to claim 1, wherein the plurality of conductive filaments are plural, and a spacing range between the plurality of conductive filaments is 0.5mm-3mm.
    11. 根据权利要求 1 所述的太阳能电池片正面电极结构,其特征在于,所述电池片可以为多晶硅电池片,也可以为单晶硅电池片。11. According to claim 1 The solar cell front electrode structure is characterized in that the cell sheet can be a polycrystalline silicon cell or a monocrystalline silicon cell.
    12. 根据权利要求 3 所述的太阳能电池片正面电极结构,其特征在于,所述电池片的正面包括主栅线,所述导电丝在垂直于所述主栅线方向上粘贴。12. According to claim 3 The solar cell front electrode structure is characterized in that the front surface of the cell sheet comprises a main gate line, and the conductive wire is pasted in a direction perpendicular to the main grid line.
    13. 根据权利要求 12 所述的太阳能电池片正面电极结构,其特征在于,所述导电丝与所述主栅线相交部分嵌入到所述主栅线内部。13. According to claim 12 The solar cell front electrode structure is characterized in that a portion where the conductive wire intersects with the main gate line is embedded inside the main gate line.
    14. 一种制作太阳能电池片正面电极结构的制作方法,其特征在于,所述方法包括:在导电丝表面上裹覆导电浆料;将裹覆了所述导电浆料的所述导电丝粘附于所述电池片上;将制作好的所述电池片放入到烘干和烧结炉中进行烘干烧结。14. A method for fabricating a front electrode structure of a solar cell, characterized in that the method comprises: coating a conductive paste on a surface of a conductive wire; and adhering the conductive wire coated with the conductive paste to The battery piece is placed on the battery; the prepared battery piece is placed in a drying and sintering furnace for drying and sintering.
    15. 根据权利要求 14 所述的制作方法,其特征在于,所述方法还包括,在所述导电丝粘附于所述电池片上之前,在所述电池片上用导电浆料制作主栅线。15. According to claim 14 The manufacturing method is characterized in that the method further comprises: forming a main gate line on the battery sheet with a conductive paste before the conductive filament is adhered to the battery sheet.
    16. 根据权利要求 14 所述的制作方法,其特征在于,所述方法还包括,在所述导电丝粘附于所述电池片上之后,在所述电池片上用导电浆料制作主栅线。16. According to claim 14 The manufacturing method is characterized in that the method further comprises: after the conductive filament is adhered to the battery sheet, forming a main grid line on the battery sheet with a conductive paste.
    17. 根据权利要求 15 或 16 所述的制作方法,其特征在于,所述方法还包括,将所述导电丝嵌入到所述主栅线的导电浆料内部。17. According to claim 15 or 16 The manufacturing method is characterized in that the method further comprises embedding the conductive filament inside the conductive paste of the main gate line.
    18. 根据权利要求 14-16 任一项所述的制作方法,其特征在于,在所述导电丝表面上裹覆导电浆料时,将所述导电丝的整个外表面均匀地裹上导电浆料。18. according to claims 14-16 The manufacturing method according to any one of the preceding claims, wherein, when the conductive paste is coated on the surface of the conductive filament, the entire outer surface of the conductive filament is uniformly coated with a conductive paste.
    19. 根据权利要求 14-16 任一项所述的制作方法,其特征在于,将裹覆了所述导电浆料的所述导电丝长度制成小于所述电池片的尺寸,并将所述导电丝的两端边缘制成具有整齐的间断部分没有裹覆所述导电浆料。19. According to claims 14-16 The manufacturing method according to any one of the preceding claims, wherein a length of said conductive filament coated with said conductive paste is made smaller than a size of said battery sheet, and both end edges of said conductive filament are made The electrically conductive paste is not coated with a neat discontinuous portion.
    20. 根据权利要求 19 所述的制作方法,其特征在于,当将所述导电丝粘贴于所述电池片正面上时,裹覆了所述导电浆料的所述导电丝的两端边缘未进入电池片边缘的刻蚀区域。20. According to claim 19 The manufacturing method is characterized in that when the conductive wire is pasted on the front surface of the battery sheet, the edges of the two ends of the conductive filament covering the conductive paste do not enter the edge of the battery sheet. Eclipse area.
    21. 根据权利要求 19 所述的制作方法,其特征在于,裹覆了所述导电浆料的所述导电丝的两端边缘分别与所述电池片的两端边缘的距离为 0.5mm-2mm ,且两边对称。21. According to claim 19 The manufacturing method is characterized in that the distance between the two end edges of the conductive wire covering the conductive paste and the two end edges of the battery sheet is 0.5 mm - 2 mm And the two sides are symmetrical.
    22. 根据权利要求 14 所述的制作方法,其特征在于,在裹覆导电浆料之前,将所述导电丝等间距平行排列。22. According to claim 14 The manufacturing method is characterized in that the conductive wires are arranged in parallel at equal intervals before the conductive paste is coated.
    23. 根据权利要求 22 所述的方法,其特征在于,所使用的所述导电丝可以是金属丝,也可以是具有一定导电性能的聚合物纤维,还可以是具有各种导电镀层的金属丝和聚合物纤维。23. According to claim 22 The method is characterized in that the conductive wire used may be a metal wire, a polymer fiber having a certain electrical conductivity, or a metal wire and a polymer fiber having various conductive plating layers.
    24. 根据权利要求 23 所述的制作方法,其特征在于,所使用的所述导电丝的直径范围为 0.01mm-0.03mm 。24. The manufacturing method according to claim 23, wherein the conductive wire used has a diameter ranging from 0.01 mm to 0.03 mm. .
    25. 根据权利要求 23 所述的制作方法,其特征在于,所述导电丝的横截面形状可以是矩形、梯形、三角形、圆形、椭圆形等,也可以是其他形状。25. According to claim 23 The manufacturing method is characterized in that the cross-sectional shape of the conductive wire may be a rectangle, a trapezoid, a triangle, a circle, an ellipse or the like, or may be other shapes.
    26. 根据权利要求 15 或 16 所述的制作方法,其特征在于,用做所述主栅线的导电浆料和用于所述导电丝上的导电浆料可以是同一种导电浆料,也可以分别使用不同的导电浆料。26. According to claim 15 or 16 The manufacturing method is characterized in that the conductive paste used as the main gate line and the conductive paste used on the conductive wire may be the same conductive paste, or different conductive pastes may be used separately. .
    27. 根据权利要求 22 所述的制作方法,其特征在于,将所述导电丝间隔排列的间距为 0.5mm-3mm 。27. The manufacturing method according to claim 22, wherein the spacing of the conductive filaments is 0.5 mm to 3 mm. .
    28. 根据权利要求 15 或 16 所述的制作方法,其特征在于,所述主栅线可以通过丝网印刷的方法在所述电池片上制作,也可以通过凸版印刷等其他方法来在所述电池片上制作。28. According to claim 15 or 16 In the above manufacturing method, the main gate line may be formed on the battery sheet by a screen printing method, or may be fabricated on the battery sheet by other methods such as letterpress printing.
    29. 根据权利要求 14 所述的制作方法,其特征在于,所述烘干步骤,其烘干温度范围为 100 ℃ -400 ℃。29. The method according to claim 14, wherein the drying step has a drying temperature range of 100 ° C -400 °C.
    30. 根据权利要求 14 所述的制作方法,其特征在于,所述烧结步骤,其烧结温度范围为 400 ℃ -950 ℃。 30. The method according to claim 14, wherein the sintering step has a sintering temperature ranging from 400 ° C to 950 ° C.
PCT/CN2013/078779 2012-07-16 2013-07-04 Front-side electrode structure of solar cell sheet and fabrication method therefor WO2014012432A1 (en)

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